The dynamic rheological measurements have been a preferred approach to the characterization of the structure and properties for multi-component or multi-phase polymer systems,due to its sensitive response to changes o...The dynamic rheological measurements have been a preferred approach to the characterization of the structure and properties for multi-component or multi-phase polymer systems,due to its sensitive response to changes of structure for these heterogeneous polymers.In the present article,recent progresses in the studies on dynamic rheology for heterogeneous polymer systems including polymeric composites filled with inorganic particles,thermo-oxidized polyolefins,phase- separated polymeric blends and functional polymers with the scaling and percolation behavior are reviewed,mainly depending on the results by the authors' group.By means of rheological measurements,not only some new fingerprints responsible for the evolution of morphology and structure concerning these polymer systems are obtained,the corresponding results are also significant for the design and preparation of novel polymer-based composites and functional materials.展开更多
Dynamic rheological properties of asphalt modified by Supramolecular UV resistant material—layered double hydroxides（LDHs） was studied by means of the dynamic shear rheometer（DSR） test.Two typical base asphalts w...Dynamic rheological properties of asphalt modified by Supramolecular UV resistant material—layered double hydroxides（LDHs） was studied by means of the dynamic shear rheometer（DSR） test.Two typical base asphalts were chosen and modified by 2 different LDHs contents.DSR tests were performed on the original samples,samples after exposed to outdoor and samples after the artificial accelerated UV aging tests respectively to analyze the rheological properties.It is found that when the LDHs content is between 3wt% and 5wt% of asphalt weight,the high temperature performance and fatigue resistant property of the modified asphalt become better,the UV aging resistance properties are improved.展开更多
The influence of temperature and mass fraction of Pluonic F127 on the rheological properties of polyvinyl butyric （PVB）/Pluronic F127/polyethylene glycol （PEG） 200 blend systems was investigated by a rotational rh...The influence of temperature and mass fraction of Pluonic F127 on the rheological properties of polyvinyl butyric （PVB）/Pluronic F127/polyethylene glycol （PEG） 200 blend systems was investigated by a rotational rheometer with parallel plates. The results show that the blend systems approach homogeneous state at 140, 150 and 160℃while the rheological properties of the blend systems significantly deviate from the homogeneous systems at 120℃. Shear thinning behavior is observed for all the blend systems at different temperatures and is enhanced by increasing Pluronic F127 content. The complex viscosity, storage modulus, loss modulus, zero-shear activation energy and flow recovery of the blend systems increase with the increase of Pluronic F127 content. There is a crossing point for the loss modulus and the storage modulus of each sample at high frequency, which is called specified frequency （SF）. The loss modulus is larger than the storage modulus when the frequency is less than the SF, and when frequency is more than SF, the loss modulus is smaller than the storage modulus.展开更多
Rheological measurement has been a preferred approach to the characterization of the structure and phase behaviors for multi-component/multi-phase polymer systems, due to its sensitive response to the changes of struc...Rheological measurement has been a preferred approach to the characterization of the structure and phase behaviors for multi-component/multi-phase polymer systems, due to its sensitive response to the changes of structure for these heterogeneous polymers. In the present article, recent progresses in the studies on rheology for heterogeneous polymer systems including phase-separated polymeric blends and block copolymers are reviewed, mainly depending on the results by the authors＇ research group. By means of rheological measurements, not only some new fingerprints responsible for the evolution of morphology and structure concerning these polymer systems are obtained, also the corresponding results are significant for design and preparation of novel polymeric structural materials and functional materials.展开更多
The dynamic rheological properties of peanut protein isolate(PPI)suspension and acid-induced PPI gels were studied.In frequency sweep test,the storage modulus(G′)and the loss modulus(G″)of PPI aggregation suspension...The dynamic rheological properties of peanut protein isolate(PPI)suspension and acid-induced PPI gels were studied.In frequency sweep test,the storage modulus(G′)and the loss modulus(G″)of PPI aggregation suspensions at different concentrations increased with the increase of frequency.The steady state shear flow test showed that PPI aggregation suspension had a thinning behavior of the shear,and the image of steady shear curve fitted the Carreau model.After gel formation,acid-induced PPI gels showed a typical Type I behavior(strain thinning)in strain sweep test,meaning that PPI gel got easily broken down,and there was a very small opportunity for the protein molecules to re-establish the network.Compared with the strain sweep of PPI aggregation suspensions and gels,the range of the storage modulus existed a dramatic difference,which could get about tenfold.As the frequency increased,both elasticity and viscosity increased in frequency sweep test,which indicated that the frequency dependence of the storage modulus increased with the increase of concentration.展开更多
基金This work was supported by the National Natural Science Foundation for Distinguished Young Scholars(No.50125312)Key Program of National Science Foundation of China(No.50133020)National Natural Science Foundation of China(No.50373037)
文摘The dynamic rheological measurements have been a preferred approach to the characterization of the structure and properties for multi-component or multi-phase polymer systems,due to its sensitive response to changes of structure for these heterogeneous polymers.In the present article,recent progresses in the studies on dynamic rheology for heterogeneous polymer systems including polymeric composites filled with inorganic particles,thermo-oxidized polyolefins,phase- separated polymeric blends and functional polymers with the scaling and percolation behavior are reviewed,mainly depending on the results by the authors' group.By means of rheological measurements,not only some new fingerprints responsible for the evolution of morphology and structure concerning these polymer systems are obtained,the corresponding results are also significant for the design and preparation of novel polymer-based composites and functional materials.
文摘Dynamic rheological properties of asphalt modified by Supramolecular UV resistant material—layered double hydroxides（LDHs） was studied by means of the dynamic shear rheometer（DSR） test.Two typical base asphalts were chosen and modified by 2 different LDHs contents.DSR tests were performed on the original samples,samples after exposed to outdoor and samples after the artificial accelerated UV aging tests respectively to analyze the rheological properties.It is found that when the LDHs content is between 3wt% and 5wt% of asphalt weight,the high temperature performance and fatigue resistant property of the modified asphalt become better,the UV aging resistance properties are improved.
基金Project(20776161) supported by the National Natural Science Foundation of China
文摘The influence of temperature and mass fraction of Pluonic F127 on the rheological properties of polyvinyl butyric （PVB）/Pluronic F127/polyethylene glycol （PEG） 200 blend systems was investigated by a rotational rheometer with parallel plates. The results show that the blend systems approach homogeneous state at 140, 150 and 160℃while the rheological properties of the blend systems significantly deviate from the homogeneous systems at 120℃. Shear thinning behavior is observed for all the blend systems at different temperatures and is enhanced by increasing Pluronic F127 content. The complex viscosity, storage modulus, loss modulus, zero-shear activation energy and flow recovery of the blend systems increase with the increase of Pluronic F127 content. There is a crossing point for the loss modulus and the storage modulus of each sample at high frequency, which is called specified frequency （SF）. The loss modulus is larger than the storage modulus when the frequency is less than the SF, and when frequency is more than SF, the loss modulus is smaller than the storage modulus.
基金This work was supported by the Special Funds for Major Stale Basic Research Projects (No. 2005CB623802) National Natural Science Foundation of China (No. 50373037).
文摘Rheological measurement has been a preferred approach to the characterization of the structure and phase behaviors for multi-component/multi-phase polymer systems, due to its sensitive response to the changes of structure for these heterogeneous polymers. In the present article, recent progresses in the studies on rheology for heterogeneous polymer systems including phase-separated polymeric blends and block copolymers are reviewed, mainly depending on the results by the authors＇ research group. By means of rheological measurements, not only some new fingerprints responsible for the evolution of morphology and structure concerning these polymer systems are obtained, also the corresponding results are significant for design and preparation of novel polymeric structural materials and functional materials.
基金This research project was supported bythe 2021 Postgraduate Research Ability Improvement Program BTBU,General Project of Scientific Research Program of Beijing Education Commission(Grant No.KM201910011003,KM201910011001)Joint Program of Beijing Natural Science Foundation Committee and Beijing Education Committee(Grant No.KZ201810011017)This research project was also supported by Beijing Excellent Talent Training Project(Grant No.2017000020124G100).
文摘The dynamic rheological properties of peanut protein isolate(PPI)suspension and acid-induced PPI gels were studied.In frequency sweep test,the storage modulus(G′)and the loss modulus(G″)of PPI aggregation suspensions at different concentrations increased with the increase of frequency.The steady state shear flow test showed that PPI aggregation suspension had a thinning behavior of the shear,and the image of steady shear curve fitted the Carreau model.After gel formation,acid-induced PPI gels showed a typical Type I behavior(strain thinning)in strain sweep test,meaning that PPI gel got easily broken down,and there was a very small opportunity for the protein molecules to re-establish the network.Compared with the strain sweep of PPI aggregation suspensions and gels,the range of the storage modulus existed a dramatic difference,which could get about tenfold.As the frequency increased,both elasticity and viscosity increased in frequency sweep test,which indicated that the frequency dependence of the storage modulus increased with the increase of concentration.
