Flow softening behavior of a homogenized Mg-7Gd-4Y-1Nd-0.5Zr alloy under compression to a final strain of∼1.8 at elevated temperatures of 450∼550℃ and a constant strain rate of 2s^(−1) has been investigated by opti...Flow softening behavior of a homogenized Mg-7Gd-4Y-1Nd-0.5Zr alloy under compression to a final strain of∼1.8 at elevated temperatures of 450∼550℃ and a constant strain rate of 2s^(−1) has been investigated by optical microscopy,scanning electron microscopy,electron back-scattered diffraction and transmission electron microscopy.The results show that true stress first rises to the peak point and then drops to the bottom value and increases again with further increasing strain at each temperature.Twinning dynamic recrystallization(DRX)and continuous DRX contribute to the formation of new fine grains at temperatures 450∼475℃ when the restoration is caused by both DRX and texture change due to extension twinning,resulting in the larger softening degrees compared with the softening effects owing to continuous DRX and discontinuous DRX at 500∼550℃ when twinning activation is suppressed.500℃ is the transition temperature denoting a significant decline in the contribution of twinning and TDRX to the strain with increasing temperature.The cuboid-shape phase exists in both homogenized and compressed samples,while the compositions are varied.展开更多
CO_2 capture with ionic liquids(ILs) has attracted many attentions, and most works focused on absorption ability at ambient temperatures, while seldom research was concerned at elevated temperatures.This not only limi...CO_2 capture with ionic liquids(ILs) has attracted many attentions, and most works focused on absorption ability at ambient temperatures, while seldom research was concerned at elevated temperatures.This not only limits the CO_2 absorption application at elevated temperature, but also the determination of the operation condition of the CO_2 desorption generally occurring at higher temperature. This work mainly reported CO_2 solubilities in ILs at elevated temperatures and related properties were also provided. 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide([CnMIm][Tf_2N]) ILs were selected as physical absorbents for CO_2 capture in this work due to their relative higher CO_2 absorption capacities and good thermal stabilities. The long-term stability tests showed that [CnMIm][Tf_2N] is thermally stable at 393.15 K for long time. CO_2 solubilities in [CnMIm][Tf_2N] were systematically determined at temperatures from 353.15 K to 393.15 K. It demonstrated that CO_2 solubility obviously increases with the increase of pressure while slightly decreases with increase of temperature. As the length of alkyl chain on the cation increases, CO_2 solubility in ILs increases. Additionally, the thermodynamic properties including the Gibbs free energy, enthalpy, and entropy of CO_2 were also calculated.展开更多
The tensile response, the low cycle fatigue(LCF) resistance, and the creep behavior of an aluminum(Al) cast alloy are studied at ambient and elevated temperatures.A non-contact real-time optical extensometer based on ...The tensile response, the low cycle fatigue(LCF) resistance, and the creep behavior of an aluminum(Al) cast alloy are studied at ambient and elevated temperatures.A non-contact real-time optical extensometer based on the digital image correlation(DIC)is developed to achieve strain measurements without damage to the specimen. The optical extensometer is validated and used to monitor dynamic strains during the mechanical experiments. Results show that Young's modulus of the cast alloy decreases with the increasing temperature, and the percentage elongation to fracture at 100℃ is the lowest over the temperature range evaluated from 25℃ to 300℃. In the LCF test, the fatigue strength coefficient decreases, whereas the fatigue strength exponent increases with the rising temperature. The fatigue ductility coefficient and exponent reach maximum values at 100℃. As expected, the resistance to creep decreases with the increasing temperature and changes from 200℃ to 300℃.展开更多
The impact of temperature and particle size on minimumfluidizing velocity was studied and analyzed in a small pilot scale of bubbling fluidized bed reactor.This study was devoted to providing some data about fluidizat...The impact of temperature and particle size on minimumfluidizing velocity was studied and analyzed in a small pilot scale of bubbling fluidized bed reactor.This study was devoted to providing some data about fluidization to the literature under high temperature conditions.The experiments were carried out to evaluate the minimum fluidizing velocity over a vast range of temperature levels from 20℃ to 850℃ using silica sand with a particle size of 300-425μm,425-500μm,500-600μm,and 600-710μm.Furthermore,the variation in the minimumfluidized voidage was determined experimentally at the same conditions.The experimental data revealed that the Umf directly varied with particle size and inversely with temperature,whileεmf increases slightly with temperature based on the measurements of height at incipient fluidization.However,for all particle sizes used in this test,temperatures above 700℃ has a marginal effect on Umf.The results were compared with many empirical equations,and it was found that the experimental result is still in an acceptable range of empirical equations used.In which,our findings are not well predicted by the widely accepted correlations reported in the literature.Therefore,a new predicted equation has been developed that also accounts for the affecting of mean particle size in addition to other parameters.A good mean relative deviation of 5.473% between the experimental data and the predicted values was estimated from the correlation of the effective dimensionless group.Furthermore,the experimental work revealed that the minimum fluidizing velocity was not affected by the height of the bed even at high temperature.展开更多
The development of lightweight magnesium(Mg)alloys capable of operating at elevated temperatures of 200-300℃and the ability of using high pressure die casting for high-volume manufacturing are the most advanced devel...The development of lightweight magnesium(Mg)alloys capable of operating at elevated temperatures of 200-300℃and the ability of using high pressure die casting for high-volume manufacturing are the most advanced developments in manufacturing critical parts for internal combustion engines used in power tools.Here we report the microstructure and mechanical properties of a newly developed die-cast Mg-RE(La,Ce,Nd,Gd)-Al alloy capable of working at higher elevated temperatures of 200-300℃.The new alloy delivers the yield strength of 94 MPa at 300℃,which demonstrates a 42%increase over the benchmark AE44 high temperature die-cast Mg alloy.The new alloy also has good stiffness at elevated temperatures with its modulus only decreasing linearly by 13%from room temperature up to 300℃.Thermal analysis shows a minor peak at 364.7℃in the specific heat curve of the new alloy,indicating a good phase stability of the alloy up to 300℃.Nd and Gd have more affinity to Al for the formation of the minority of divorced Al-RE(Nd,Gd)based compounds,and the stable Al-poor Mg_(12)RE(La_(0.22)Ce_(0.13)Nd_(0.31)Gd_(0.31))Zn_(0.39)Al_(0.13)compound acts as the continuous inter-dendritic network,which contribute to the high mechanical performance and stability of the new die-cast Mg alloy at 200-300℃.展开更多
High-nickel single-crystal layered oxide material has become the most promising cathode material for electric vehicle power battery due to its high energy density.However,this material still suffers from structural de...High-nickel single-crystal layered oxide material has become the most promising cathode material for electric vehicle power battery due to its high energy density.However,this material still suffers from structural degradation during cycling and especially the severe interfacial reactions at elevated temperatures that exacerbate irreversible capacity loss.Here,a simple strategy was used to construct a dualfunction Li_(1.5)Al_(0.5)Ge_(1.5)P_(3)O_(12)(LAGP)protective layer on the surface of the high-nickel single-crystal(SC)cathode material,leading to SC@LAGP material.The strong Al-O bonding effectively inhibits the release of lattice oxygen(O)at elevated temperatures,which is supported by the positive formation energy of O vacancy from first-principal calculations.Besides,theoretical calculations demonstrate that the appropriate amount of Al doping accelerates the electron and Li^(+)transport,and thus reduces the kinetic barriers.In addition,the LAGP protective layer alleviates the stress accumulation during cycling and effectively reduces the erosion of materials from the electrolyte decomposition at elevated temperatures.The obtained SC@LAGP cathode material demonstrates much enhanced cycling stability even at high voltage(4.6 V)and elevated temperature(55℃),with a high capacity retention of 91.3%after 100 cycles.This work reports a simple dual-function coating strategy that simultaneously stabilizes the structure and interface of the single-crystal cathode material,which can be applied to design other cathode materials.展开更多
The behaviour of hydrogen permeation and diffusion in amorphous alloy Ni68Cr7Si8B14Fe3 hasbeen investigated by an ultrahigh vacuum gas permeation technique. A comparison experimentwas carried out between the as-quench...The behaviour of hydrogen permeation and diffusion in amorphous alloy Ni68Cr7Si8B14Fe3 hasbeen investigated by an ultrahigh vacuum gas permeation technique. A comparison experimentwas carried out between the as-quenched and annealed States (400℃/2h) of the amorphousalloy. The results show that, for both states of the amorphous alloy in the temperature rangeof 200～350℃, the diffusivity and permeability of hydrogen are in agreement with Arrheniusrelationship, there does not exist H-trapping effect, and the activation energies of diffusion andpermeation almost keep the same.展开更多
The behavior of cold⁃formed steel(CFS)stud⁃to⁃sheathing connections at elevated temperatures is an important parameter for the fire resistance design and modeling of mid⁃rise CFS structures.In this paper,three kinds o...The behavior of cold⁃formed steel(CFS)stud⁃to⁃sheathing connections at elevated temperatures is an important parameter for the fire resistance design and modeling of mid⁃rise CFS structures.In this paper,three kinds of sheathings,namely,medium⁃and low⁃density calcium⁃silicate boards and oriented strand board,were selected for double⁃shear experiments on the mechanical properties of 253 screw connections at ambient and elevated temperatures.The effects of the shear direction,screw edge distance and the number of screws on the behavior of the connections were studied.The results showed that the shear direction and the screw edge distance more significantly influenced the peak deformation,while their impacts on the peak load varied with the type of sheathings.Compared with the single⁃screw connections,the peak loads of the specimens with double⁃screw connections obviously increased but did not double.Finally,a simplified load⁃displacement curve model of stud⁃to⁃sheathing connections at elevated temperature was generated first by establishing the prediction formula for characteristic parameters,such as the peak load,the peak deformation and the elastic stiffness,and then by considering whether the curves corresponded to stiffness increase phenomena.The present investigation provides basic data for future studies on the numerical modeling of CFS structures under fire conditions.展开更多
The hydrolysis rate of Co-bearing ferrous chloride at elevated temperature and the conditionsof separation of Co from Fe have been investigated. The hydrolysis process is comprised of theinterfacial chemical reaction ...The hydrolysis rate of Co-bearing ferrous chloride at elevated temperature and the conditionsof separation of Co from Fe have been investigated. The hydrolysis process is comprised of theinterfacial chemical reaction and the intra-grain diffusion. At the stage under the control of theinterfacial chemical reaction, the apparent rate constant k equals to 198.79exp(-80.57/RT). Theeffects of the temperature, the partial pressure ratio of water vapor and the reaction time on theCo recovery and the separation of Co from Fe are examined. The optimum hydrolysis conditionsare determined.展开更多
The lubricant behaviour at elevated temperatures was investigated by conducting pin-on-disc tests between P20 tool steel and AA7075 aluminium alloy. The effects of temperature, initial lubricant volume, contact pressu...The lubricant behaviour at elevated temperatures was investigated by conducting pin-on-disc tests between P20 tool steel and AA7075 aluminium alloy. The effects of temperature, initial lubricant volume, contact pressure and sliding speed on the lubricant behaviour(i.e. evolutions of the coefficient of friction(COF) and the breakdown phenomenon) were experimentally studied. The evolutions of COF at elevated temperatures consisted of three distinct stages with different friction mechanisms. The first stage(stage Ⅰ) occurred with low friction when the boundary lubrication was present. The second stage(stage Ⅱ) was the transition process in which the COF rapidly increased as the lubricant film thickness decreased to a critical value. In the final plateau stage(stage Ⅲ), lubricant breakdown occurred and intimate contact at the interface led to high friction values. At the low friction stage(stage Ⅰ), the value of COF increased with increasing temperature. The increase in temperature, contact pressure and sliding speed as well as the decrease in initial lubricant volume accelerated the lubricant breakdown.展开更多
T Parallel wire strands(PWSs),which are widely used in prestressed steel structures,are typically in highstress states.Under fire conditions,significant creep effects occur,reducing the prestress and influencing the m...T Parallel wire strands(PWSs),which are widely used in prestressed steel structures,are typically in highstress states.Under fire conditions,significant creep effects occur,reducing the prestress and influencing the mechanical behavior of PWSs.As there is no existing approach to analyze their creep behavior,this study experimentally investigated the elevated temperature creep model of PWSs.A charge-coupled camera system was incorporated to accurately obtain the deformation of the specimen during the elevated temperature creep test.It was concluded that the temperature level had a more significant effect on the creep strain than the stress level,and 450℃ was the key segment point where the creep rate varied significantly.By comparing the elevated temperature creep test results for PWSs and steel strands,it was found that the creep strain of PWSs was lower than that of steel strands at the same temperature and stress levels.The parameters in the general empirical formula,the Bailey–Norton model,and the composite timehardening model were fitted based on the experimental results.By evaluating the accuracy and form of the models,the composite time-hardening model,which can simultaneously consider temperature,stress,and time,is recommended for use in the fire-resistance design of pre-tensioned structures with PWSs.展开更多
The deformation mechanisms and dynamic recrystallization(DRX)behavior of specifically grown bicrystals with a symmetric 90°<1010>and 90°<1120>tilt grain boundary,respectively,were investigated un...The deformation mechanisms and dynamic recrystallization(DRX)behavior of specifically grown bicrystals with a symmetric 90°<1010>and 90°<1120>tilt grain boundary,respectively,were investigated under deformation in plane strain compression at 200℃and 400℃.The microstructures were analyzed by panoramic optical microscopy and large-area electron backscatter diffraction(EBSD)orientation mapping.The analysis employed a meticulous approach utilizing hundreds of individual,small EBSD maps with a small step size that were stitched together to provide comprehensive access to orientation and misorientation data on a macroscopic scale.Basal slip primarily governed the early stages of deformation at the two temperatures,and the resulting shear induced lattice rotation around the transverse direction(TD)of the sample.The existence of the grain boundary gave rise to dislocation pile-up in its vicinity,leading to much larger TD-lattice rotations within the boundary region compared to the bulk.With increasing temperature,the deformation was generally more uniform towards the bulk due to enhanced dislocation mobility and more uniform stress distribution.Dynamic recrystallization at 200℃was initiated in{1011}-compression twins at strains of 40%and higher.At 400℃,DRX consumed the entire grain boundary region and gradually replaced the deformed microstructure with progressing deformation.The recrystallized grains displayed characteristic orientations,such that their c-axes were perpendicular to the TD and additionally scattered between 0°and 60°from the loading axis.These recrystallized grains displayed mutual rotations of up to 30°around the c-axes of the initial grains,forming a discernible basal fiber texture component,prominently visible in the{1120}pole figure.It is noteworthy that the deformation and DRX behaviors of the two analyzed bicrystals exhibited marginal variations in response to strain and deformation temperature.展开更多
The tribo-characteristics of metal forming at high temperatures have not yet been well understood due to the complex nature of thermal,microstructural,interaction,and process parameters.This is a review paper on the e...The tribo-characteristics of metal forming at high temperatures have not yet been well understood due to the complex nature of thermal,microstructural,interaction,and process parameters.This is a review paper on the effects of temperature,coating,and lubrication to the tribological characteristics in hot forming as well as the tribometers for different metal forming processes at elevated temperatures mainly based on the experimental work.The tribological behaviors of oxides in hot forming,such as rolling and stamping,were reviewed and presented.Some commonly used surface coatings and lubricants in hot forming were given.Many types of tribometer were selected and presented and some of them provided a great potential to characterize friction and wear at elevated temperatures.Nevertheless,more testing conditions should be further investigated by developing new tribometers.Eventually,experimental results obtained from reliable tribometers could be used in theory and model developments for different forming processes and materials at high temperatures.The review also showed the great potential in further investigations and innovation in tribology.展开更多
Coralline algae(CA),a type of primary calcifying producer presented in coastal ecosystems,are considered one of the highly sensitive organisms to marine environmental change.However,experimental studies on coralline a...Coralline algae(CA),a type of primary calcifying producer presented in coastal ecosystems,are considered one of the highly sensitive organisms to marine environmental change.However,experimental studies on coralline algae responses to elevated seawater temperature and reduced pH have documented either contradictory or opposite results.In this study,we analysed the growth and physiological responses of coralline algae Porolithon onkodes to the elevated temperature(30.8°C)and reduced pH(7.8).The aim of this analysis was to observe the direct and combined effects,while elucidating the growth and photosynthesis in this response.It was demonstrated that the algae thallus growth rate and photosynthesis under elevated temperature were depressed by 21.5%and 14.9%respectively.High pCO2 enhanced the growth and photosynthesis of the thallus at ambient temperature,while they were deceased when both temperature and pCO2 were elevated.CA is among the most sensitive organisms to ocean acidification(OA)because of their precipitate high Mg-calcite.We hypothesize that coralline algae could increase their calcification rate in order to counteract the effects of moderate acidification,but offset by the effect of elevated temperature.Accordingly,our results also support the conclusion that global warming(GW)is a stronger threat to algal performance than OA.Our findings are also proposed that coralline algae may be more resilient under OA than GW.展开更多
In this study,we prepare the specimens of three-dimensional random fibrous(3D RF)material along its through-the-thickness(TTT)and in-plane(IP)directions.The experimental tests of tensile and compressive properties as ...In this study,we prepare the specimens of three-dimensional random fibrous(3D RF)material along its through-the-thickness(TTT)and in-plane(IP)directions.The experimental tests of tensile and compressive properties as well as fracture toughness of 3D RF material are performed at elevated temperatures.Then,the porosity(83%,87%and 89%)and temperature dependence of the tensile and compressive strength,elastic modulus,fracture toughness and fracture surface energy of the 3D RF materials for both the TTT and IP directions are analyzed.From the results of the tensile strength and elastic modulus versus material porosities at various temperatures,we find that tensile strength and elastic modulus for the TTT direction are more sensitive to the porosity,but not for the IP direction.Fracture toughness increases firstly and then decreases at a certain critical temperature.Such critical temperature is found to be the lowest for the porosity of 83%.On the other hand,at below 1073 K,the temperature-dependent fracture surface energies with three porosities for the TTT direction show similar variation trends.展开更多
High-temperature structural metals remain in high demand for aerospace aircraft,gas turbine engines,and nuclear power plants.Refractory high-entropy alloys(RHEAs)with superior mechanical properties at elevated tempera...High-temperature structural metals remain in high demand for aerospace aircraft,gas turbine engines,and nuclear power plants.Refractory high-entropy alloys(RHEAs)with superior mechanical properties at elevated temperatures are promising candidates for high-temperature structural materials.In this work,a WTaMoNbTi RHEA with adequate room temperature plasticity and considerable strength at 1600℃was fabricated by vacuum arc-melting.The room temperature fracture strain of the as-cast WTaMoNbTi RHEA was 7.8%,which was about 5.2 times that of the NbMoTaW alloy.The alloy exhibited a strong resistance to high-temperature softening,with a high yield strength of 173 MPa and compressive strength of 218 MPa at 1600℃.The WTaMoNbTi RHEA possessed excellent phase stability in the range of room temperature to 2000℃.The dendritic grains grew into equiaxed grains after compression test at 1600℃due to the dynamic recrystallization process at high temperature.This work presents a promising high-temperature structural material that can be applied at 1600℃.展开更多
The microstructures of an Mg-4Y-3Nd-0.5Zr alloy by differential pressure casting were investigated using scanning electron microscopy(SEM) and transmission electron microscopy(TEM), and its tensile deformation behavio...The microstructures of an Mg-4Y-3Nd-0.5Zr alloy by differential pressure casting were investigated using scanning electron microscopy(SEM) and transmission electron microscopy(TEM), and its tensile deformation behavior was measured using a Gleeble1500 D themo-simulation machine in the temperature range of 200 to 400 °C at initial strain rates of 5×10-4 to 10-1 s-1. Results show that the as-cast microstructure consists of primary α-Mg phase and bone-shaped Mg5 RE eutectic phase distributed along the grain boundary. The eutectic phase is dissolved into the matrix after solution treatment and subsequently precipitates during peak aging. Tensile deformation tests show that the strain rate has little effect on stress under 300 °C. Tensile stress decreases with an increase in temperature and the higher strain rate leads to an increase in stress above 300 °C. The fracture mechanism exhibits a mixed quasi-cleavage fracture at 200 °C, while the fracture above 300 °C is a ductile fracture. The dimples are melted at 400 °C with the lowest strain rate of 10-4 s-1.展开更多
A total of 540 nonlinear steady-state finite element analyses were performed to study the influence of temperature and dimensionless geometrical parameters(β,γ,θ,andτ)on the ultimate strength,failure modes,and ini...A total of 540 nonlinear steady-state finite element analyses were performed to study the influence of temperature and dimensionless geometrical parameters(β,γ,θ,andτ)on the ultimate strength,failure modes,and initial stiffness of two-planar tubular KT-joints.The joints were analyzed under two types of axial loading and five different temperatures(20℃,200℃,400℃,550℃,and 700℃).So far,there has not been any equation available for calculating the ultimate strength of two-planar tubular KT-joints at elevated temperatures.Hence,after parametric study,a set of design formulas were developed through nonlinear regression analyses,to calculate the ultimate strength of two-planar tubular KT-joints subjected to axial loading at elevated temperatures.展开更多
A new approach for predicting forming limit curves(FLCs)at elevated temperatures was proposed herein.FLCs are often used to predict failure and determine the optimal forming parameters of automotive parts.First,a grap...A new approach for predicting forming limit curves(FLCs)at elevated temperatures was proposed herein.FLCs are often used to predict failure and determine the optimal forming parameters of automotive parts.First,a graphical method based on a modified maximum force criterion was applied to estimate the FLCs of 22MnB5 boron steel sheets at room temperature using various hardening laws.Subsequently,the predicted FLC data at room temperature were compared with corresponding data obtained from Nakazima's tests to obtain the best prediction.To estimate the FLC at elevated temperatures,tensile tests were conducted at various temperatures to determine the ratios of equivalent fracture strains between the corresponding elevated temperatures and room temperature.FLCs at elevated temperatures could be established based on obtained ratios.However,the predicted FLCs at elevated temperatures did not agree well with the corresponding FLC experimental data of Zhou et al.A new method was proposed herein to improve the prediction of FLCs at elevated temperatures.An FLC calculated at room tem-perature was utilized to predict the failure of Nakazima's samples via finite element simulation.Based on the simulation results at room temperature,the mathematical relationships between the equivalent ductile fracture strain versus stress triaxiality and strain ratio were established and then combined with ratios between elevated and room temperatures to calculate the FLCs at different temperatures.The predicted FLCs at elevated temperatures agree well with the corresponding experimental FLC data.展开更多
基金This work was supported by the Changsha University Talent Introduction Project(50800-92808)the Excellent youth project of Hunan Provincial Department of Education(19B055,18B418,19C0156)the Natural Science Foundation of Hunan Province of China(2020JJ4645).
文摘Flow softening behavior of a homogenized Mg-7Gd-4Y-1Nd-0.5Zr alloy under compression to a final strain of∼1.8 at elevated temperatures of 450∼550℃ and a constant strain rate of 2s^(−1) has been investigated by optical microscopy,scanning electron microscopy,electron back-scattered diffraction and transmission electron microscopy.The results show that true stress first rises to the peak point and then drops to the bottom value and increases again with further increasing strain at each temperature.Twinning dynamic recrystallization(DRX)and continuous DRX contribute to the formation of new fine grains at temperatures 450∼475℃ when the restoration is caused by both DRX and texture change due to extension twinning,resulting in the larger softening degrees compared with the softening effects owing to continuous DRX and discontinuous DRX at 500∼550℃ when twinning activation is suppressed.500℃ is the transition temperature denoting a significant decline in the contribution of twinning and TDRX to the strain with increasing temperature.The cuboid-shape phase exists in both homogenized and compressed samples,while the compositions are varied.
基金supported by the National Natural Science Foundation of China (21606233, 21436010)the National Natural Science Fund for Distinguished Young Scholars (21425625)the Research Council of Norway through the CLIMIT program (215732)
文摘CO_2 capture with ionic liquids(ILs) has attracted many attentions, and most works focused on absorption ability at ambient temperatures, while seldom research was concerned at elevated temperatures.This not only limits the CO_2 absorption application at elevated temperature, but also the determination of the operation condition of the CO_2 desorption generally occurring at higher temperature. This work mainly reported CO_2 solubilities in ILs at elevated temperatures and related properties were also provided. 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide([CnMIm][Tf_2N]) ILs were selected as physical absorbents for CO_2 capture in this work due to their relative higher CO_2 absorption capacities and good thermal stabilities. The long-term stability tests showed that [CnMIm][Tf_2N] is thermally stable at 393.15 K for long time. CO_2 solubilities in [CnMIm][Tf_2N] were systematically determined at temperatures from 353.15 K to 393.15 K. It demonstrated that CO_2 solubility obviously increases with the increase of pressure while slightly decreases with increase of temperature. As the length of alkyl chain on the cation increases, CO_2 solubility in ILs increases. Additionally, the thermodynamic properties including the Gibbs free energy, enthalpy, and entropy of CO_2 were also calculated.
基金supported by the National Natural Science Foundation of China(Nos.11372173,11672347,and 11727804)the Science and Technology Development Foundation of Shanghai Automobile Industry(No.1514)
文摘The tensile response, the low cycle fatigue(LCF) resistance, and the creep behavior of an aluminum(Al) cast alloy are studied at ambient and elevated temperatures.A non-contact real-time optical extensometer based on the digital image correlation(DIC)is developed to achieve strain measurements without damage to the specimen. The optical extensometer is validated and used to monitor dynamic strains during the mechanical experiments. Results show that Young's modulus of the cast alloy decreases with the increasing temperature, and the percentage elongation to fracture at 100℃ is the lowest over the temperature range evaluated from 25℃ to 300℃. In the LCF test, the fatigue strength coefficient decreases, whereas the fatigue strength exponent increases with the rising temperature. The fatigue ductility coefficient and exponent reach maximum values at 100℃. As expected, the resistance to creep decreases with the increasing temperature and changes from 200℃ to 300℃.
文摘The impact of temperature and particle size on minimumfluidizing velocity was studied and analyzed in a small pilot scale of bubbling fluidized bed reactor.This study was devoted to providing some data about fluidization to the literature under high temperature conditions.The experiments were carried out to evaluate the minimum fluidizing velocity over a vast range of temperature levels from 20℃ to 850℃ using silica sand with a particle size of 300-425μm,425-500μm,500-600μm,and 600-710μm.Furthermore,the variation in the minimumfluidized voidage was determined experimentally at the same conditions.The experimental data revealed that the Umf directly varied with particle size and inversely with temperature,whileεmf increases slightly with temperature based on the measurements of height at incipient fluidization.However,for all particle sizes used in this test,temperatures above 700℃ has a marginal effect on Umf.The results were compared with many empirical equations,and it was found that the experimental result is still in an acceptable range of empirical equations used.In which,our findings are not well predicted by the widely accepted correlations reported in the literature.Therefore,a new predicted equation has been developed that also accounts for the affecting of mean particle size in addition to other parameters.A good mean relative deviation of 5.473% between the experimental data and the predicted values was estimated from the correlation of the effective dimensionless group.Furthermore,the experimental work revealed that the minimum fluidizing velocity was not affected by the height of the bed even at high temperature.
文摘The development of lightweight magnesium(Mg)alloys capable of operating at elevated temperatures of 200-300℃and the ability of using high pressure die casting for high-volume manufacturing are the most advanced developments in manufacturing critical parts for internal combustion engines used in power tools.Here we report the microstructure and mechanical properties of a newly developed die-cast Mg-RE(La,Ce,Nd,Gd)-Al alloy capable of working at higher elevated temperatures of 200-300℃.The new alloy delivers the yield strength of 94 MPa at 300℃,which demonstrates a 42%increase over the benchmark AE44 high temperature die-cast Mg alloy.The new alloy also has good stiffness at elevated temperatures with its modulus only decreasing linearly by 13%from room temperature up to 300℃.Thermal analysis shows a minor peak at 364.7℃in the specific heat curve of the new alloy,indicating a good phase stability of the alloy up to 300℃.Nd and Gd have more affinity to Al for the formation of the minority of divorced Al-RE(Nd,Gd)based compounds,and the stable Al-poor Mg_(12)RE(La_(0.22)Ce_(0.13)Nd_(0.31)Gd_(0.31))Zn_(0.39)Al_(0.13)compound acts as the continuous inter-dendritic network,which contribute to the high mechanical performance and stability of the new die-cast Mg alloy at 200-300℃.
基金financially supported by the National Natural Science Foundation of China(51974368,51774333)the Hunan Provincial Natural Science Foundation of China(2020JJ2048)。
文摘High-nickel single-crystal layered oxide material has become the most promising cathode material for electric vehicle power battery due to its high energy density.However,this material still suffers from structural degradation during cycling and especially the severe interfacial reactions at elevated temperatures that exacerbate irreversible capacity loss.Here,a simple strategy was used to construct a dualfunction Li_(1.5)Al_(0.5)Ge_(1.5)P_(3)O_(12)(LAGP)protective layer on the surface of the high-nickel single-crystal(SC)cathode material,leading to SC@LAGP material.The strong Al-O bonding effectively inhibits the release of lattice oxygen(O)at elevated temperatures,which is supported by the positive formation energy of O vacancy from first-principal calculations.Besides,theoretical calculations demonstrate that the appropriate amount of Al doping accelerates the electron and Li^(+)transport,and thus reduces the kinetic barriers.In addition,the LAGP protective layer alleviates the stress accumulation during cycling and effectively reduces the erosion of materials from the electrolyte decomposition at elevated temperatures.The obtained SC@LAGP cathode material demonstrates much enhanced cycling stability even at high voltage(4.6 V)and elevated temperature(55℃),with a high capacity retention of 91.3%after 100 cycles.This work reports a simple dual-function coating strategy that simultaneously stabilizes the structure and interface of the single-crystal cathode material,which can be applied to design other cathode materials.
文摘The behaviour of hydrogen permeation and diffusion in amorphous alloy Ni68Cr7Si8B14Fe3 hasbeen investigated by an ultrahigh vacuum gas permeation technique. A comparison experimentwas carried out between the as-quenched and annealed States (400℃/2h) of the amorphousalloy. The results show that, for both states of the amorphous alloy in the temperature rangeof 200～350℃, the diffusivity and permeability of hydrogen are in agreement with Arrheniusrelationship, there does not exist H-trapping effect, and the activation energies of diffusion andpermeation almost keep the same.
基金the National Natural Science Foundation of China(Grant No.51978655)the Natural Science Foundation of Jiangsu Province of China(Grant No.BK20201347)+1 种基金the Xuzhou Science and Technology Project(Grant No.KC20175)the China Postdoctoral Science Foundation Funded Project(Grant No.2019M652007).
文摘The behavior of cold⁃formed steel(CFS)stud⁃to⁃sheathing connections at elevated temperatures is an important parameter for the fire resistance design and modeling of mid⁃rise CFS structures.In this paper,three kinds of sheathings,namely,medium⁃and low⁃density calcium⁃silicate boards and oriented strand board,were selected for double⁃shear experiments on the mechanical properties of 253 screw connections at ambient and elevated temperatures.The effects of the shear direction,screw edge distance and the number of screws on the behavior of the connections were studied.The results showed that the shear direction and the screw edge distance more significantly influenced the peak deformation,while their impacts on the peak load varied with the type of sheathings.Compared with the single⁃screw connections,the peak loads of the specimens with double⁃screw connections obviously increased but did not double.Finally,a simplified load⁃displacement curve model of stud⁃to⁃sheathing connections at elevated temperature was generated first by establishing the prediction formula for characteristic parameters,such as the peak load,the peak deformation and the elastic stiffness,and then by considering whether the curves corresponded to stiffness increase phenomena.The present investigation provides basic data for future studies on the numerical modeling of CFS structures under fire conditions.
文摘The hydrolysis rate of Co-bearing ferrous chloride at elevated temperature and the conditionsof separation of Co from Fe have been investigated. The hydrolysis process is comprised of theinterfacial chemical reaction and the intra-grain diffusion. At the stage under the control of theinterfacial chemical reaction, the apparent rate constant k equals to 198.79exp(-80.57/RT). Theeffects of the temperature, the partial pressure ratio of water vapor and the reaction time on theCo recovery and the separation of Co from Fe are examined. The optimum hydrolysis conditionsare determined.
基金supported by the China Scholarship Council (Grant CSC No. 201706230235): a nonprofit institution that enables talented Chinese students to participate in overseas Ph D programs。
文摘The lubricant behaviour at elevated temperatures was investigated by conducting pin-on-disc tests between P20 tool steel and AA7075 aluminium alloy. The effects of temperature, initial lubricant volume, contact pressure and sliding speed on the lubricant behaviour(i.e. evolutions of the coefficient of friction(COF) and the breakdown phenomenon) were experimentally studied. The evolutions of COF at elevated temperatures consisted of three distinct stages with different friction mechanisms. The first stage(stage Ⅰ) occurred with low friction when the boundary lubrication was present. The second stage(stage Ⅱ) was the transition process in which the COF rapidly increased as the lubricant film thickness decreased to a critical value. In the final plateau stage(stage Ⅲ), lubricant breakdown occurred and intimate contact at the interface led to high friction values. At the low friction stage(stage Ⅰ), the value of COF increased with increasing temperature. The increase in temperature, contact pressure and sliding speed as well as the decrease in initial lubricant volume accelerated the lubricant breakdown.
基金support provided by the National Natural Science Foundation of China(Grant No.51878348)the Shanghai Pujiang Program(No.22PJ1414000).
文摘T Parallel wire strands(PWSs),which are widely used in prestressed steel structures,are typically in highstress states.Under fire conditions,significant creep effects occur,reducing the prestress and influencing the mechanical behavior of PWSs.As there is no existing approach to analyze their creep behavior,this study experimentally investigated the elevated temperature creep model of PWSs.A charge-coupled camera system was incorporated to accurately obtain the deformation of the specimen during the elevated temperature creep test.It was concluded that the temperature level had a more significant effect on the creep strain than the stress level,and 450℃ was the key segment point where the creep rate varied significantly.By comparing the elevated temperature creep test results for PWSs and steel strands,it was found that the creep strain of PWSs was lower than that of steel strands at the same temperature and stress levels.The parameters in the general empirical formula,the Bailey–Norton model,and the composite timehardening model were fitted based on the experimental results.By evaluating the accuracy and form of the models,the composite time-hardening model,which can simultaneously consider temperature,stress,and time,is recommended for use in the fire-resistance design of pre-tensioned structures with PWSs.
基金the Deutsche Forschungsgemeinschaft(DFG)for financial support(MO 848/18-2)。
文摘The deformation mechanisms and dynamic recrystallization(DRX)behavior of specifically grown bicrystals with a symmetric 90°<1010>and 90°<1120>tilt grain boundary,respectively,were investigated under deformation in plane strain compression at 200℃and 400℃.The microstructures were analyzed by panoramic optical microscopy and large-area electron backscatter diffraction(EBSD)orientation mapping.The analysis employed a meticulous approach utilizing hundreds of individual,small EBSD maps with a small step size that were stitched together to provide comprehensive access to orientation and misorientation data on a macroscopic scale.Basal slip primarily governed the early stages of deformation at the two temperatures,and the resulting shear induced lattice rotation around the transverse direction(TD)of the sample.The existence of the grain boundary gave rise to dislocation pile-up in its vicinity,leading to much larger TD-lattice rotations within the boundary region compared to the bulk.With increasing temperature,the deformation was generally more uniform towards the bulk due to enhanced dislocation mobility and more uniform stress distribution.Dynamic recrystallization at 200℃was initiated in{1011}-compression twins at strains of 40%and higher.At 400℃,DRX consumed the entire grain boundary region and gradually replaced the deformed microstructure with progressing deformation.The recrystallized grains displayed characteristic orientations,such that their c-axes were perpendicular to the TD and additionally scattered between 0°and 60°from the loading axis.These recrystallized grains displayed mutual rotations of up to 30°around the c-axes of the initial grains,forming a discernible basal fiber texture component,prominently visible in the{1120}pole figure.It is noteworthy that the deformation and DRX behaviors of the two analyzed bicrystals exhibited marginal variations in response to strain and deformation temperature.
文摘The tribo-characteristics of metal forming at high temperatures have not yet been well understood due to the complex nature of thermal,microstructural,interaction,and process parameters.This is a review paper on the effects of temperature,coating,and lubrication to the tribological characteristics in hot forming as well as the tribometers for different metal forming processes at elevated temperatures mainly based on the experimental work.The tribological behaviors of oxides in hot forming,such as rolling and stamping,were reviewed and presented.Some commonly used surface coatings and lubricants in hot forming were given.Many types of tribometer were selected and presented and some of them provided a great potential to characterize friction and wear at elevated temperatures.Nevertheless,more testing conditions should be further investigated by developing new tribometers.Eventually,experimental results obtained from reliable tribometers could be used in theory and model developments for different forming processes and materials at high temperatures.The review also showed the great potential in further investigations and innovation in tribology.
基金The National Natural Science Foundation of China(NSFC)under contract Nos 41306144 and 41676150the National Key Research and Development Plan under contract No.2017YFC0506301+1 种基金the Strategic Priority Research Program of the Chinese Academy of Sciences under contract No.XDA13020402the Guangdong Basic and Applied Basic Research Foundation under contract No.2019A1515011532
文摘Coralline algae(CA),a type of primary calcifying producer presented in coastal ecosystems,are considered one of the highly sensitive organisms to marine environmental change.However,experimental studies on coralline algae responses to elevated seawater temperature and reduced pH have documented either contradictory or opposite results.In this study,we analysed the growth and physiological responses of coralline algae Porolithon onkodes to the elevated temperature(30.8°C)and reduced pH(7.8).The aim of this analysis was to observe the direct and combined effects,while elucidating the growth and photosynthesis in this response.It was demonstrated that the algae thallus growth rate and photosynthesis under elevated temperature were depressed by 21.5%and 14.9%respectively.High pCO2 enhanced the growth and photosynthesis of the thallus at ambient temperature,while they were deceased when both temperature and pCO2 were elevated.CA is among the most sensitive organisms to ocean acidification(OA)because of their precipitate high Mg-calcite.We hypothesize that coralline algae could increase their calcification rate in order to counteract the effects of moderate acidification,but offset by the effect of elevated temperature.Accordingly,our results also support the conclusion that global warming(GW)is a stronger threat to algal performance than OA.Our findings are also proposed that coralline algae may be more resilient under OA than GW.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.11902046,11632014,11372238 and 11872049)the Chang Jiang Scholar Program and the 111 Project(Grant No.B18040)This work was also supported by the Fundam ental Research Funds for the Central Universities,CHD(Grant No.300102259302).
文摘In this study,we prepare the specimens of three-dimensional random fibrous(3D RF)material along its through-the-thickness(TTT)and in-plane(IP)directions.The experimental tests of tensile and compressive properties as well as fracture toughness of 3D RF material are performed at elevated temperatures.Then,the porosity(83%,87%and 89%)and temperature dependence of the tensile and compressive strength,elastic modulus,fracture toughness and fracture surface energy of the 3D RF materials for both the TTT and IP directions are analyzed.From the results of the tensile strength and elastic modulus versus material porosities at various temperatures,we find that tensile strength and elastic modulus for the TTT direction are more sensitive to the porosity,but not for the IP direction.Fracture toughness increases firstly and then decreases at a certain critical temperature.Such critical temperature is found to be the lowest for the porosity of 83%.On the other hand,at below 1073 K,the temperature-dependent fracture surface energies with three porosities for the TTT direction show similar variation trends.
基金financially supported by the National Key Research and Development Program of China(Grant No.2018YFC1902400)the National Natural Science Foundation of China(Grant No.51975582)。
文摘High-temperature structural metals remain in high demand for aerospace aircraft,gas turbine engines,and nuclear power plants.Refractory high-entropy alloys(RHEAs)with superior mechanical properties at elevated temperatures are promising candidates for high-temperature structural materials.In this work,a WTaMoNbTi RHEA with adequate room temperature plasticity and considerable strength at 1600℃was fabricated by vacuum arc-melting.The room temperature fracture strain of the as-cast WTaMoNbTi RHEA was 7.8%,which was about 5.2 times that of the NbMoTaW alloy.The alloy exhibited a strong resistance to high-temperature softening,with a high yield strength of 173 MPa and compressive strength of 218 MPa at 1600℃.The WTaMoNbTi RHEA possessed excellent phase stability in the range of room temperature to 2000℃.The dendritic grains grew into equiaxed grains after compression test at 1600℃due to the dynamic recrystallization process at high temperature.This work presents a promising high-temperature structural material that can be applied at 1600℃.
基金supported by the Ministry of Science and Technology of China through Grant 2009GJB 2001.1
文摘The microstructures of an Mg-4Y-3Nd-0.5Zr alloy by differential pressure casting were investigated using scanning electron microscopy(SEM) and transmission electron microscopy(TEM), and its tensile deformation behavior was measured using a Gleeble1500 D themo-simulation machine in the temperature range of 200 to 400 °C at initial strain rates of 5×10-4 to 10-1 s-1. Results show that the as-cast microstructure consists of primary α-Mg phase and bone-shaped Mg5 RE eutectic phase distributed along the grain boundary. The eutectic phase is dissolved into the matrix after solution treatment and subsequently precipitates during peak aging. Tensile deformation tests show that the strain rate has little effect on stress under 300 °C. Tensile stress decreases with an increase in temperature and the higher strain rate leads to an increase in stress above 300 °C. The fracture mechanism exhibits a mixed quasi-cleavage fracture at 200 °C, while the fracture above 300 °C is a ductile fracture. The dimples are melted at 400 °C with the lowest strain rate of 10-4 s-1.
文摘A total of 540 nonlinear steady-state finite element analyses were performed to study the influence of temperature and dimensionless geometrical parameters(β,γ,θ,andτ)on the ultimate strength,failure modes,and initial stiffness of two-planar tubular KT-joints.The joints were analyzed under two types of axial loading and five different temperatures(20℃,200℃,400℃,550℃,and 700℃).So far,there has not been any equation available for calculating the ultimate strength of two-planar tubular KT-joints at elevated temperatures.Hence,after parametric study,a set of design formulas were developed through nonlinear regression analyses,to calculate the ultimate strength of two-planar tubular KT-joints subjected to axial loading at elevated temperatures.
基金funded by Vietnam National Foundation for Science and Technology Development(NAFOSTED)under Grant Number 107.02-2019.300.
文摘A new approach for predicting forming limit curves(FLCs)at elevated temperatures was proposed herein.FLCs are often used to predict failure and determine the optimal forming parameters of automotive parts.First,a graphical method based on a modified maximum force criterion was applied to estimate the FLCs of 22MnB5 boron steel sheets at room temperature using various hardening laws.Subsequently,the predicted FLC data at room temperature were compared with corresponding data obtained from Nakazima's tests to obtain the best prediction.To estimate the FLC at elevated temperatures,tensile tests were conducted at various temperatures to determine the ratios of equivalent fracture strains between the corresponding elevated temperatures and room temperature.FLCs at elevated temperatures could be established based on obtained ratios.However,the predicted FLCs at elevated temperatures did not agree well with the corresponding FLC experimental data of Zhou et al.A new method was proposed herein to improve the prediction of FLCs at elevated temperatures.An FLC calculated at room tem-perature was utilized to predict the failure of Nakazima's samples via finite element simulation.Based on the simulation results at room temperature,the mathematical relationships between the equivalent ductile fracture strain versus stress triaxiality and strain ratio were established and then combined with ratios between elevated and room temperatures to calculate the FLCs at different temperatures.The predicted FLCs at elevated temperatures agree well with the corresponding experimental FLC data.
