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Chiral fluorescent sensor Tb^(3+)@Cd‑CP based on camphoric acid for the enantioselective recognition of R‑and S‑propylene glycol
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作者 LI Junying CHEN Xinyan +5 位作者 DIAO Xihui Yaseen Muhammad CHEN Chao WANG Hao QI Chuansong LI Wei 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第12期2497-2504,共8页
Herein,a layered chiral coordination polymer,[Cd2(D‑cam)_(2)(2,2′‑bipy)_(2)]_(n)(Cd‑CP),was synthesized using a solvothermal method with camphoric acid(D‑H_(2)cam),2,2′‑bipyridine(2,2′‑bipy)and Cd^(2+),and Tb^(3+)@... Herein,a layered chiral coordination polymer,[Cd2(D‑cam)_(2)(2,2′‑bipy)_(2)]_(n)(Cd‑CP),was synthesized using a solvothermal method with camphoric acid(D‑H_(2)cam),2,2′‑bipyridine(2,2′‑bipy)and Cd^(2+),and Tb^(3+)@Cd‑CP was in‑situ synthesized introducing Tb^(3+)ions.The fluorescence experiments revealed that compared to Cd‑CP,Tb^(3+)@Cd‑CP exhibited ultra‑high fluorescence performance.The luminescence sensing performance demonstrated that Tb^(3+)@Cd‑CP could distinguish R/S‑propylene glycol(R/S‑PG)by fluorescence responses,with fluorescence quenching constant of 5.3×10^(3)and 2.0×10^(3)L·mol^(-1)respectively and the enantioselectivity factor(α)of 2.65.Moreover,Tb^(3+)@Cd‑CP demonstrated limits of detection of 9.3 and 19.0μmol·L^(-1)for R‑PG and S‑PG,respectively,and showed good reproducibility. 展开更多
关键词 camphoric acid coordination polymer ENANTIOSELECTIVITY propylene glycol
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Operationally Simple Enantioselective Silane Reduction of Ketones by the [Ir(OMe)(cod)]2/Azolium Catalytic System
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作者 Satoshi Sakaguchi Chika Nagao +1 位作者 Ryo Ichihara Shogo Matsuo 《International Journal of Organic Chemistry》 2024年第1期1-19,共19页
An operationally simple protocol was designed for the enantioselective silane reduction (ESR) of ketones using air- and moisture-stable [Ir(OMe)(cod)]<sub>2</sub> (cod = 1,5-cyclooctadiene) (3) as a metal ... An operationally simple protocol was designed for the enantioselective silane reduction (ESR) of ketones using air- and moisture-stable [Ir(OMe)(cod)]<sub>2</sub> (cod = 1,5-cyclooctadiene) (3) as a metal catalyst precursor. This reaction was driven by chiral hydroxyamide-functionalized azolium salt 2. The catalytic ESR reaction could be performed under benchtop conditions at room temperature. Treatment of 2 with 3 in THF yielded the monodentate IrCl(NHC)(cod) (NHC = N-heterocyclic carbene) complex 4 in 93% yield, herein the anionic methoxy ligand of 3 serves as an internal base that deprotonates the azolium ring of 2. The well-defined Ir complex 4 catalyzed the ESR reaction of propiophenone (6) with (EtO)<sub>2</sub>MeSiH using the pre-mixing reaction procedure. Based on this success, the catalytic ESR reaction was designed and implemented using an in situ-generated NHC/Ir catalyst derived from 2 and 3. Thus, a wide variety of aryl ketones could be reduced to the corresponding optically active alcohols in moderate to excellent stereoselectivities at room temperature without temperature control. Since the high catalytic activity of 3 was observed, we next evaluated several other transition metal catalyst precursors for the catalytic ESR reaction under the influence of 2. This evaluation revealed that Ir(acac)(cod) (acac = acetylacetonate) (28) and [IrCl(cod)]<sub>2</sub> (5) can be successfully used as metal catalyst precursors in the ESR reaction. 展开更多
关键词 Asymmetric Catalysis enantioselective Reduction Hydrosilylation Reaction N-Heterocyclic Carbene IRIDIUM
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Promoting dynamic recrystallization and improving strength and ductility of Mg-7Bi alloy through Al addition
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作者 Gun Woong An Sang-Cheol Jin +2 位作者 Hyun Ji Kim Sumi Jo Sung Hyuk Park 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第8期3339-3356,共18页
This study investigated the influence of the addition of Al to a Mg-7Bi(B7,wt%)alloy,particularly its recrystallization behavior during extrusion and its resulting mechanical properties.The addition of 2 wt%Al to the ... This study investigated the influence of the addition of Al to a Mg-7Bi(B7,wt%)alloy,particularly its recrystallization behavior during extrusion and its resulting mechanical properties.The addition of 2 wt%Al to the B7 alloy resulted in a lower grain size,a reduction in the number density of fine Mg3Bi2 particles,and a higher area fraction of relatively coarse Mg3Bi2 particles in the extrusion billet.These microstructural changes increased the nucleation sites for recrystallization,reduced the Zener pinning effect,and enhanced particle-stimulated nucleation,all of which promoted dynamic recrystallization behavior during extrusion.As a result,the area fraction of recrystallized grains in the extruded alloy increased from 77%to 94%.The extruded B7 alloy exhibited a strong<10-10>fiber texture,whereas the extruded Mg-7Bi-2Al(BA72)alloy had a weak<10-10>-<2-1-10>texture,which was attributed to the minimal presence of unrecrystallized grains and the dispersed orientation of the recrystallized grains.The tensile yield strength(TYS)of the extruded BA72 alloy was higher than that of the extruded B7 alloy(170 and 124 MPa,respectively),which resulted from the enhanced grain-boundary and solid-solution strengthening effects.The tensile elongation(EL)of the BA72 alloy also exceeded that of the B7 alloy(20.3%and 6.1%,respectively),the result of the uniform formation of fine twins under tension in the former and the formation of a few coarse twins among the unrecrystallized grains in the latter.Consequently,the addition of a small amount of Al to the B7 alloy significantly improved both the strength and ductility of the extruded alloy,resulting in a remarkable increase in the product of the TYS and EL from 756 to 3451 MPa%and expanding its potential range of applications as a lightweight extruded structural component. 展开更多
关键词 Mg-7Bi alloy Al addition Extrusion Recrystallization Microstructure
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Effect of Fe Addition on Dehydrogenation Performance of Methylcyclohexance over Pt/Al_(2)O_(3)
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作者 Tong Fengya Tian Hao +2 位作者 Wang Hao Miao Changxi Song Lei 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2024年第1期12-18,共7页
Catalysts with varying Fe contents were prepared using a sequential impregnation method to investigate the effects of Fe addition on the physicochemical properties of Pt/Al_(2)O_(3) and their performance in methylcycl... Catalysts with varying Fe contents were prepared using a sequential impregnation method to investigate the effects of Fe addition on the physicochemical properties of Pt/Al_(2)O_(3) and their performance in methylcyclohexane(MCH)dehydrogenation.The results demonstrated that the addition of Fe to Pt/Al_(2)O_(3) enhanced the electron density of Pt and improved catalytic activity,while exhibiting negligible influence on the catalytic selectivity for toluene.When the Fe content was 0.057%,the catalyst exhibited the highest MCH consumption rate,which was approximately two times higher than that of the catalyst without Fe.Additionally,the incorporation of Fe inhibited the formation of coke and reduced the quantity of coke deposits on the catalyst,thereby improving its catalytic durability.Overall,Fe shows promise as a prospective secondary element for Pt/Al_(2)O_(3) to enhance the MCH dehydrogenation performance. 展开更多
关键词 methylcyclohexane dehydrogenation hydrogen storage DEACTIVATION Fe addition
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Effect of defatted flaxseed gum powder addition on the quality of sesame paste
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作者 Haichao He Mingkai Sun +5 位作者 Jiahui Wang Yan Tang Yashu Chen Qianchun Deng Qingde Huang Hu Tang 《Oil Crop Science》 CSCD 2024年第1期1-7,共7页
The study explored the influence of defatted flaxseed gum powder(DFGP) on the stability and quality of sesame paste by measuring and analyzing its composition, color, texture, particle size, centrifugal oil separation... The study explored the influence of defatted flaxseed gum powder(DFGP) on the stability and quality of sesame paste by measuring and analyzing its composition, color, texture, particle size, centrifugal oil separation rate,rheological properties, and microstructure. The results showed that the moisture and polysaccharide content of sesame paste was increased as the DFGP increased. Additionally, the hardness, gumminess, and chewiness of the sesame paste was improved, while the presence of particles with small particle size(1–100 μm) was decreased.The rate of oil precipitation was reduced by 28.99% when the amount of DFGP was 6%. The sesame paste samples exhibited pseudoplastic behavior, demonstrating shear thinning. As the shear rate increased, the apparent viscosity of sesame paste gradually decreased. Both the storage modulus(G’) and the loss modulus(G’’) increased as the shear frequency increased. The microstructure observation revealed that protein and oil were evenly distributed in the sesame paste system, and the addition of DFGP enhanced the bonding between oil and protein.This study can provide valuable references for high-quality sesame paste products in the food industry. 展开更多
关键词 Flaxseed gum powder Sesame paste QUALITY addition
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Soil bacterial and fungal communities resilience to long-term nitrogen addition in subtropical forests in China
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作者 Xinlei Fu Yunze Dai +3 位作者 Jun Cui Pengfei Deng Wei Fan Xiaoniu Xu 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第2期95-108,共14页
Atmospheric nitrogen(N)deposition is predicted to increase,especially in the subtropics.However,the responses of soil microorganisms to long-term N addition at the molecular level in N-rich subtropical forests have no... Atmospheric nitrogen(N)deposition is predicted to increase,especially in the subtropics.However,the responses of soil microorganisms to long-term N addition at the molecular level in N-rich subtropical forests have not been clarified.A long-term nutrient addition experiment was conducted in a subtropical evergreen old-growth forest in China.The four treatments were:control,low N(50 kg N ha^(-1)a^(-1)),high N(100 kg N ha^(-1)a^(-1)),and combined N and phosphorus(P)(100 kg N ha^(-1)a^(-1)+50 kg P ha^(-1)a^(-1)).Metagenomic sequencing characterized diversity and composition of soil microbial communities and used to construct bacterial/fungal co-occurrence networks.Nutrient-treated soils were more acidic and had higher levels of dissolved organic carbon than controls.There were no significant differences in microbial diversity and community composition across treatments.The addition of nutrients increased the abundance of copiotrophic bacteria and potentially beneficial microorganisms(e.g.,Gemmatimonadetes,Chaetomium,and Aureobasidium).Low N addition increased microbiome network connectivity.Three rare fungi were identified as module hubs under nutrient addition,indicating that low abundance fungi were more sensitive to increased nutrients.The results indicate that the overall composition of microbial communities was stable but not static to long-term N addition.Our findings provide new insights that can aid predictions of the response of soil microbial communities to long-term N addition. 展开更多
关键词 Long-term nitrogen addition Old-growth subtropical forest METAGENOMICS Beneficial microorganisms Co-occurrence network
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Effect of addition temperature on dispersion behavior and grain refinement efficiency of MgO introduced into Mg alloy
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作者 Le ZAI Xin TONG +1 位作者 Yun WANG Xiao-huai XUE 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第8期2491-2506,共16页
The effect of addition temperature of MgO particles(MgOp)on their dispersion behavior and the efficiency of grain refinement in AZ31 Mg alloy was investigated.In addition,the grain refinement mechanism was systematica... The effect of addition temperature of MgO particles(MgOp)on their dispersion behavior and the efficiency of grain refinement in AZ31 Mg alloy was investigated.In addition,the grain refinement mechanism was systematically studied by microstructure characterization,thermodynamic calculation,and analysis of solidification curves.The results show that the grain size of AZ31 Mg alloy initially decreases and then increases as the MgOp addition temperature is increased from 720 to 810℃,exhibiting a minimum value of 136μm at 780℃.The improved grain refinement efficiency with increasing MgOp addition temperature can be attributed to the reduced Mg melt viscosity and enhanced wettability between MgOp and Mg melt.Furthermore,a corresponding physical model describing the solidification behavior and grain refinement mechanism was proposed. 展开更多
关键词 grain refinement MgO nucleation particles AZ31 alloy addition temperature dispersion behavior
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Belowground Bud Bank Is Insensitive to Short-Term Nutrient Addition in the Meadow Steppe of Inner Mongolia
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作者 Jin Tao Jiatai Tian +6 位作者 Dongmei Li Jinlei Zhu Qun Ma Zhiming Zhang Jungang Chen Yipeng Liu Jianqiang Qian 《Phyton-International Journal of Experimental Botany》 SCIE 2024年第6期1129-1141,共13页
Human activities and industrialization have significantly increased soil nutrients,such as nitrogen(N)and phos-phorus(P),profoundly impacting the composition and structure of plant community,as well as the ecosystem fu... Human activities and industrialization have significantly increased soil nutrients,such as nitrogen(N)and phos-phorus(P),profoundly impacting the composition and structure of plant community,as well as the ecosystem functions,especially in nutrient-limited ecosystems.However,as the key propagule pool of perennial grasslands,how belowground bud bank and its relationship with aboveground vegetation respond to short-term changes in soil nutrients was still unclear.In this study,we conducted a short-term(2021–2022)soil fertilization experiment with N addition(10 g N m^(-2) yr^(-1))and P addition(5 g N m^(-2) yr^(-1))in the meadow steppe of Inner Mongolia,China,to explore the responses of belowground bud bank,aboveground shoot population and their relationships(represented by the ratio of bud to shoot density-meristem limitation index(MLI))for the whole community and three plant functional groups(perennial rhizomatous grasses-PR,perennial bunchgrasses-PB,and perennial forbs-PF)to nutrient addition.The short-term nutrient addition had no significant influences on belowground bud density,aboveground shoot density,and MLI of the whole plant community.Plant functional groups showed different responses to soil fertilization.Specifically,N addition significantly increased the bud density and shoot density of PR,especially in combination with P addition.N addition reduced the shoot density of PF but had no influence on its bud density and MLI.Nutrient addition had significant effects on the three indicators of PB.Our study indicates that the belowground bud bank and its relationship with aboveground vegetation in temperate meadow steppe are insensitive to short-term soil fertilization,but plant functional groups exhibit specific responses in terms of population regeneration,which implies that plant community composition and ecosystem functions will be changed under the ongoing global change. 展开更多
关键词 Clonal trait population regeneration community dynamics soil resource availability nitrogen addition
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How Prime Numbers Are Interconnected and Built with Two Equations: Addition and Subtraction Rules the Function (6µ)
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作者 John Richard Wisdom 《Advances in Pure Mathematics》 2024年第4期228-241,共14页
Are all prime numbers linked by four simple functions? Can we predict when a prime will appear in a sequence of primes? If we classify primes into two groups, Group 1 for all primes that appear before ζ (such that , ... Are all prime numbers linked by four simple functions? Can we predict when a prime will appear in a sequence of primes? If we classify primes into two groups, Group 1 for all primes that appear before ζ (such that , for instance 5, ), an even number divisible by 3 and 2, and Group 2 for all primes that are after ζ (such that , for instance 7), then we find a simple function: for each prime in each group, , where n is any natural number. If we start a sequence of primes with 5 for Group 1 and 7 for Group 2, we can attribute a μ value for each prime. The μ value can be attributed to every prime greater than 7. Thus for Group 1, and . Using this formula, all the primes appear for , where μ is any natural number. 展开更多
关键词 Number Theory Prime Number Groups Twin Primes Prime Structure and Sequence Prime Subtraction and addition
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Stromal lenticule addition keratoplasty with corneal crosslinking for corneal ectasia secondary to FS-LASIK:a case series
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作者 Li-Xiang Wang Ying-Ping Deng +5 位作者 Meng-Zhen Xie Ke Ma Hong-Bo Yin Qiong Wang Rui Gong Jing Tang 《International Journal of Ophthalmology(English edition)》 SCIE CAS 2024年第3期596-602,共7页
●AIM:To explore the clinical efficacy and safety of stromal lenticule addition keratoplasty(SLAK)with corneal crosslinking(CXL)on patients with corneal ectasia secondary to femtosecond laser-assisted in situ keratomi... ●AIM:To explore the clinical efficacy and safety of stromal lenticule addition keratoplasty(SLAK)with corneal crosslinking(CXL)on patients with corneal ectasia secondary to femtosecond laser-assisted in situ keratomileusis(FS-LASIK).●METHODS:A series of 5 patients undertaking SLAK with CXL for the treatment of corneal ectasia secondary to FS-LASIK were followed for 4-9mo.The lenticules were collected from patients undertaking small incision lenticule extraction(SMILE)for the correction of myopia.Adding a stromal lenticule was aimed at improving the corneal thickness for the safe application of crosslinking and compensating for the thin cornea to improve its mechanical strength.●RESULTS:All surgeries were conducted successfully with no significant complications.Their best corrected visual acuity(BCVA)ranged from 0.05 to 0.8-2 before surgery.The pre-operational total corneal thickness ranged from 345-404μm and maximum keratometry(Kmax)ranged from 50.8 to 86.3.After the combination surgery,both the corneal keratometry(range 55.9 to 92.8)and total corneal thickness(range 413-482μm)significantly increased.Four out of 5 patients had improvement of corneal biomechanical parameters(reflected by stiffness parameter A1 in Corvis ST).However,3 patients showed decreased BCVA after surgery due to the development of irregular astigmatism and transient haze.Despite the onset of corneal edema right after SLAK,the corneal topography and thickness generally stabilized after 3mo.●CONCLUSION:SLAK with CXL is a potentially beneficial and safe therapy for advanced corneal ectasia.Future work needs to address the poor predictability of corneal refractometry and compare the outcomes of different surgical modes. 展开更多
关键词 corneal ectasia femtosecond laserassisted in situ keratomileusis stromal lenticule addition keratoplasty corneal crosslinking corneal thickness corneal biomechanics
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Thiazolidine Derivatives as Chiral Catalysts in the Enantioselective Addition of Diethylzinc to Benzaldehyde
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作者 Qing Lin MENG Yue Lan LI +1 位作者 Yan HE Ye Di GUAN Department of Chemistry, Peking University, Beijing 100871 State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 《Chinese Chemical Letters》 SCIE CAS CSCD 2000年第9期761-764,共4页
Four types of chiral thiazolidine derivatives were synthesized conveniently from natural L-cysteine and showed good enantioselectivity in up to 90% ee in the addition of diethylzine to benzaldehyde. Their enantioselec... Four types of chiral thiazolidine derivatives were synthesized conveniently from natural L-cysteine and showed good enantioselectivity in up to 90% ee in the addition of diethylzine to benzaldehyde. Their enantioselectivity was affected by the bulkiness of R and the thiazolidine ring systems in their molecules. 展开更多
关键词 chiral catalysts enantioselective addition % ee (enantiomeric excess) thiazolidine derivatives
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Synthesis of Chiral N-Ferrocenylmethylaminoalcohols and their Application in Enantioselective Addition of Diethylzinc to Aldehydes
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作者 JianFengGE ZongXuanSHEN YaWenZHANG 《Chinese Chemical Letters》 SCIE CAS CSCD 2004年第9期1025-1028,共4页
Three chiral N-ferrocenylmethylaminoalcohols were synthesized from readily available natural L-valine, leucine and phenylanine, and used as chiral ligands in the enantioselective addition of diethylzinc to aldehydes.
关键词 N-Ferrocenylmethylaminoalcohol asymmetric synthesis enantioselective addition DIETHYLZINC
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The Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by 2-Methylquinoline Derived Chiral Ligands
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作者 Qian Yong XU Guo Xing WANG Xin Fu PAN 《Chinese Chemical Letters》 SCIE CAS CSCD 2001年第5期395-396,共2页
Readily available 2-methylquinoline derived chiral ligands 1 and 2 have been applied in the enantioselective addition of diethylzinc to aldehydes with up to 91.4% ee being recorded.
关键词 Methylquinoline enantioselective addition diethylzinc.
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Chiral Ligands from Abrine.4. Heterocycle-Containing 1,2,3,4-Tetrahydro-β-Carboline Methyl Ester Used for Catalysis of Enantioselective Addition of Diethylzinc to Benzaldehyde
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作者 Bi Tao ZHAO Hua Jie ZHU +2 位作者 Xing HONG Jun ZHOU Xiao Jiang HAO(KunAnng Institute of Botany, Chinese Academy of Sciences, Heilongtan, Kunming 650204) 《Chinese Chemical Letters》 SCIE CAS CSCD 1998年第6期527-528,共2页
Four 1, 2,3,4-tetrahydro - β - c arboline amino acid esters with a heterocycle at the C- 1position were used as chiral ligands in the enantioselective addition reactions. The differentpositions of the heteroatoms gav... Four 1, 2,3,4-tetrahydro - β - c arboline amino acid esters with a heterocycle at the C- 1position were used as chiral ligands in the enantioselective addition reactions. The differentpositions of the heteroatoms gave different effects, and medium but opposite enantioselectivitywas recorded. 展开更多
关键词 enantioselective addition DIETHYLZINC 1 2 3 4-tetrahydro-β-carboline ester
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Chiral Bronsted acid-catalyzed conjugate addition of indoles to azadienes:Enantioselective synthesis of hetero-triarylmethanes 被引量:1
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作者 Huan-Ping Xie Bo Wu +1 位作者 Xin-Wei Wang Yong-Gui Zhou 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2019年第10期1566-1575,共10页
An efficient chiral Br?nsted acid-catalyzed conjugate addition of indoles to azadienes has been successfully developed,which enables a facile approach to optically active hetero-triarylmethanes with excellent enantios... An efficient chiral Br?nsted acid-catalyzed conjugate addition of indoles to azadienes has been successfully developed,which enables a facile approach to optically active hetero-triarylmethanes with excellent enantioselectivities and broad substrate scope.This chiral Br?nsted acid catalytic system provides a new opportunity for the development of asymmetric reactions of azadienes. 展开更多
关键词 Conjugate addition Hetero-triarylmethane AZADIENE INDOLE Chiral Brnsted acid
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Enantioselective Aldol Reactions and Michael Additions Using Proline Derivatives as Organocatalysts
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作者 Mathieu Wagner Yohan Contie +1 位作者 Clotilde Ferroud Gilbert Revial 《International Journal of Organic Chemistry》 2014年第1期55-67,共13页
Six compounds including five proline derivatives have been prepared and tested as chiral organocatalysts for enantioselective aldol reactions and Michael additions. The enantiomeric excesses, which are highly dependen... Six compounds including five proline derivatives have been prepared and tested as chiral organocatalysts for enantioselective aldol reactions and Michael additions. The enantiomeric excesses, which are highly dependent on the molecular structure of catalysts as well as experimental conditions, have reached over 98%. 展开更多
关键词 ALDOL Reactions MICHAEL additionS enantioselective ORGANOCATALYSTS PROLINE Derivatives
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The Steric Effect of trans-(1S,2S)-1-Substituted-2-(N,N-dialkyl-amino)-1-indanol Derivatives as Chiral Ligands in the Catalytic Enantioselective Addition of Diethylzinc to Aldehydes
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作者 Qian Yong XU Hong Fang YANG +1 位作者 Xin Fu PAN Guang Ming ZHU 《Chinese Chemical Letters》 SCIE CAS CSCD 2002年第11期1029-1032,共4页
Optically active trans-(1S,2S)-1-substituted-2-(N,N-dialkylamino)-1-indanol derivatives have been prepared and used in the asymmetric addition of diethylzinc to aldehydes to give sec-alcohol in good yield with up to 9... Optically active trans-(1S,2S)-1-substituted-2-(N,N-dialkylamino)-1-indanol derivatives have been prepared and used in the asymmetric addition of diethylzinc to aldehydes to give sec-alcohol in good yield with up to 93.1% enantiomeric excess. 展开更多
关键词 DIETHYLZINC enantioselective alkylation indanol derivative.
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Enantioselective Addition of Diethylzinc to Benzaldehyde by Catalysts of Chiral Heterocyclic Ligands
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作者 Yan HE Yue Lan LI Ye Di GUAN(Department of Chemistry, Peking University, Beijing 100871) 《Chinese Chemical Letters》 SCIE CAS CSCD 1999年第9期717-718,共2页
Several kinds of chiral heterocyclic ligands without hydroxyl group have been synthesized and used as catalysts for the asymmetric addition of diethylzinc to benzaldehyde. These ligands promoted the formation of (S)-1... Several kinds of chiral heterocyclic ligands without hydroxyl group have been synthesized and used as catalysts for the asymmetric addition of diethylzinc to benzaldehyde. These ligands promoted the formation of (S)-1-phenylpropanols in good yields and medium to good enantioselectivities (50 similar to 86 % ee.). 展开更多
关键词 chiral heterocyclic ligands hydroxyl group asymmetric catalysis ENANTIOSELECTIVITY
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Enantioselective addition of diethylzinc to aryl aldehydes catalyzed by 1,2,3,4-tetrahydroisoquinoline β-amino alcohol
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作者 Geng Xu Zhan Zhu Liu 《Chinese Chemical Letters》 SCIE CAS CSCD 2010年第3期309-311,共3页
A highly effective,new chiral 1,2,3,4-tetrahydroisoquinoline catalyst 1 for the diethylzinc addition to aryl aldehydes has been investigated.Using 10 mol%of this chiral catalyst,secondary alcohols can be obtained in u... A highly effective,new chiral 1,2,3,4-tetrahydroisoquinoline catalyst 1 for the diethylzinc addition to aryl aldehydes has been investigated.Using 10 mol%of this chiral catalyst,secondary alcohols can be obtained in up to 87%yield and 99.5%ee under mild conditions. 展开更多
关键词 β-Amino alcohol TETRAHYDROISOQUINOLINE DIETHYLZINC Asymmetric addition
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Crystal Structure of (R)-3,3′-Bis(benzyloxymethyl)-1,1′-bi-2,2′-naphthol and Its Applications in Enantioselective Lewis Acid Catalyzed Addition of Diethylzinc to Aldehydes
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作者 LIU Guo-Hua YU Han XUE Yun-Ning YAO Mei FANG Hai-Bin 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 北大核心 2007年第2期133-138,共6页
The title compound (R)-3,3'-bis(benzyloxymethyl)-1,1'-bi-2,2'-naphthol (R)-3 has been synthesized through the deprotection of MOM group by iprOH/HCl in 83% isolated yield and the suitable single crystals for ... The title compound (R)-3,3'-bis(benzyloxymethyl)-1,1'-bi-2,2'-naphthol (R)-3 has been synthesized through the deprotection of MOM group by iprOH/HCl in 83% isolated yield and the suitable single crystals for X-ray diffraction were obtained by recrystallization at room temperature from the mixture solvents. Crystallographic data for (R)-3: C36H30O4, Mr = 526.60, triclinic, space group P1, a = 10.057(6), b = 11.934(7), c = 12.314(6) A, α = 85.52(2), β = 70.245(13), γ = 76.554(11)°, Z= 2, V 1352.8(13) A^3, Dc = 1.293 g/cm^3, F(000) = 556, R = 0.0745, wR = 0.1933 and #(MoKa) = 0.083 mm^-1. The title compound (R)-3 was found to be effective in the enantioselective addition of diethylzinc to aldehydes both in the presence and absence of Ti(Oipr)4. In the latter case, (R)-3 showed much higher catalytic activity and enantioselectivity than (R)-BINOL's. 展开更多
关键词 crystal structure BINOL derivative asymmetric addition
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