Longling is characterized by a wide distribution of hydrothermal areas, among which the Banglazhang hydrothermal system is the most geothermally active. Banglazhang is marked by intensive hydrothermal activities inclu...Longling is characterized by a wide distribution of hydrothermal areas, among which the Banglazhang hydrothermal system is the most geothermally active. Banglazhang is marked by intensive hydrothermal activities including hot springs, geysers, fumaroles and hydrothermal explosions. The geothermal waters from the Longling region are mainly HCO3-Na type with low but comparable SO4 and Cl concentrations. Calculations based on a variety of chemical geothermometers and a K-Ca geobarometer indicate that the Banglazhang hydrothermal system has much higher subsurface temperature and CO2 pressure compared to the other systems such as Daheba, Dazhulin and Huangcaoba. However, geothermal water samples collected from all these alternative hydrothermal areas are either partially equilibrated with reservoir minerals or are immature. The silica-enthalpy relationships of Banglazhang geothermal waters indicate the presence of a deep geothermal fluid with an enthalpy value and silica concentration of 945 J/g（up to around 220 °C） and 339 mg/L. Our work indicates the Banglazhang area is a promising source in terms of long-term utilization of hydrothermal resources.展开更多
Process heating constitutes a significant share of final energy consumption in the industrial sector around the world.In this paper,a high-temperature heat pump(HTHP)using flash tank vapor injection technology(FTVI)is...Process heating constitutes a significant share of final energy consumption in the industrial sector around the world.In this paper,a high-temperature heat pump(HTHP)using flash tank vapor injection technology(FTVI)is proposed to develop low-temperature geothermal source for industrial process heating with temperature above 100°C.With heat sink output temperatures between 120°C and 150°C,the thermo-economic performance of the FTVI HTHP system using R1234ze(Z)as refrigerant is analyzed and also compared to the single-stage vapor compression(SSVC)system by employing the developed mathematical model.The coefficient of performance(COP),exergy efficiency(ηexe),net present value(NPV)and payback period(PBP)are used as performance indicators.The results show that under the typical working conditions,the COP andηexe of FTVI HTHP system are 3.00 and 59.66%,respectively,and the corresponding NPV and PBP reach 8.13×106 CNY and 4.13 years,respectively.Under the high-temperature heating conditions,the thermo-economic performance of the FTVI HTHP system is significantly better than that of the SSVC system,and the larger the temperature lift,the greater the thermo-economic advantage of the FTVI HTHP system.Additionally,the FTVI HTHP system is more capable than the SSVC system in absorbing the financial risks associated with changes of electricity price and natural gas price.展开更多
The Xi'an Depression in the Guanzhong Basin of western China has been suggested to contain geothermal resources that could aid China in achieving carbon neutrality and optimizing energy structure.However,the high ...The Xi'an Depression in the Guanzhong Basin of western China has been suggested to contain geothermal resources that could aid China in achieving carbon neutrality and optimizing energy structure.However,the high concentration of total dissolved solids(TDS)and scale-forming ions in geothermal water from the depression causes severe scaling problems in harvesting geothermal energy.To reduce scale-related problems,accurate identification of scale types and prediction of scaling during geothermal energy utilization are crucial.This study starts with identifying the types and trends of scaling in the study area,using index-based discriminant methods and hydrogeochemical simulation to calculate and analyze the mineral saturation index of water samples from some wellheads and of reconstructed fluid samples of geothermal reservoirs.The results indicate that the scales are mostly calcium carbonate scales rather than sulfate scales as a result of temperature changes.Several portions of the geothermal water systems are found to have distinct mineral scaling components.Quartz and chalcedony are formed in low temperature areas,while carbonate minerals are in high temperature areas.Despite the low iron content of geothermal water samples from the study area,scaling is very common due to scaling-prone iron minerals.The findings can be used to evaluate geothermal drainage systems and guide anti-scaling during geothermal energy utilization in similar settings.展开更多
To study the mechanism of bio-clogging in a porous medium during the reinjection of geothermal water and to improve reinjection efficiency, an indoor one-dimensional reinjection experiment was conducted based on the g...To study the mechanism of bio-clogging in a porous medium during the reinjection of geothermal water and to improve reinjection efficiency, an indoor one-dimensional reinjection experiment was conducted based on the geological model of the geothermal reinjection demonstration project in Dezhou City. The biological process of porous media clogging was investigated by analyzing the variation of permeability within the medium, the main indexes of nutrient salts, and the content of extracellular polymeric substances (EPS). High-throughput sequencing, based on 16S rRNA, was used to analyze the characteristics and succession of microbial communities during the reinjection of geothermal water. The results of the study show that significant bio-clogging occurs during the reinjection of geothermal water, with an increase in the heterogeneity of the thermal reservoir medium, and a decrease in permeability. The extent of clogging gradually reduces with an increase in seepage path. Thus, thermal reservoir clogging is more serious closer to the water inlet. With an increase in the duration of reinjection, the permeability of the porous medium undergoes three stages: “rapid”, “decline-slow”, and “decrease-stable”. The results show that the richness and diversity of the bacterial community increase and decrease, respectively, during the reinjection process. Bacterial community succession occurs, and the bacterial communities mainly include the Proteobacteria and Bacteroidetes phyla. <em>Pseudomonas</em> and <em>Devosia</em> are respectively the dominant bacteria in the early and late stages of geothermal water reinjection.展开更多
In the present study, a dual-pressure organic Rankine cycle (DORC) driven by geothermal hot water for electricity production is developed, investigated and optimized from the energy, exergy and exergoeconomic viewpoin...In the present study, a dual-pressure organic Rankine cycle (DORC) driven by geothermal hot water for electricity production is developed, investigated and optimized from the energy, exergy and exergoeconomic viewpoint. A parametric study is conducted to determine the effect of high-stage pressure<span><span><span style="font-family:;" "=""><span></span><span><span> </span>and low-stage pressure</span><span></span><span><span> </span>variation on the system thermodynamic and exergoeconomic performance. The DORC is further optimized to obtain maximum exergy efficiency optimized design (EEOD case) and minimum product cost</span></span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "="">optimized design (PCOD case). The exergy efficiency and unit cost of power produced for the optimization of EEOD case and PCOD case are 33.03% and 3.059 cent/kWh, which are 0.3% and 17.4% improvement over base case, respectively. The PCOD case proved to be the best, with respect to minimum unit cost of power produced and net power output over the base case and EEOD case.展开更多
This study aimed to elucidate the influence of inflow water on the salinity concentration process of a saline lake and the mass balance of Lake Issyk-Kul,a tectonic saltwater lake in Kyrgyzstan.Based on the survey res...This study aimed to elucidate the influence of inflow water on the salinity concentration process of a saline lake and the mass balance of Lake Issyk-Kul,a tectonic saltwater lake in Kyrgyzstan.Based on the survey results and meteorological data from 2012 to 2015,we analyzed the dissolved chemical composition loads due to water inflow.Then,we discussed the relationship between the increase in salinity and water inflow into the lake.Through the water quality analysis data,we used the tank model to estimate the river inflow and analyze the loads by the L-Q curve.The groundwater loads were then estimated from the average annual increase in salinity of the lake over a period of 30 a.The results suggest that Lake Issyk-Kul was temporarily freshened between about AD 1500 and 1800 when an outflowing river existed,and thereafter,it became a closed lake in AD 1800 and continued to remain a saline lake until present.The chemical components that cause salinization are supplied from the rivers and groundwater in the catchment area,and when they flow into the lake,Ca^(2+),HCO_(3)−and Mg^(2+)precipitate as CaCO_(3) and MgCO_(3).These compounds were confirmed to have been left on the lakeshore as evaporite.The model analysis showed that 1.67 mg/L of Ca^(2+)and Mg^(2+)supplied from rivers and groundwater are precipitated as evaporite and in other forms per year.On the other hand,salinity continues to remain in the lake water at a rate of 27.5 mg/L per year.These are the main causes of increased salinity in Lake Issyk-Kul.Since Na^(+)and Cl^(-)are considered to be derived from geothermal water,they will continue to flow in regardless of the effects of human activities.Therefore,as long as these components are accumulated in Lake Issyk-Kul as a closed lake,the salinity will continue to increase in the future.展开更多
Study on the Nuanquanzi geothermal field in the Yanshan uplift is of great significance for understanding the origin of geothermal fluid in the intracontinental orogenic belt of the fault depression basin margin in No...Study on the Nuanquanzi geothermal field in the Yanshan uplift is of great significance for understanding the origin of geothermal fluid in the intracontinental orogenic belt of the fault depression basin margin in North China.The geochemical characteristics and formation mechanism of the Nuanquanzi geothermal system were elucidated by classical hydrogeochemical analysis,multi-isotopes approach(δD,δ^(18)O,δ^(13)C,δ^(87)Sr/^(86)Sr),14CAMSdating,and integrated geophysical prospecting of surface-soil radon gas measurement and CSAMT inversion.The results show that the Nuanquanzi geothermal field is a medium-low temperature convection-fault semi-enclosed geothermal system.The hydrochemical type of thermal water is primarily HCO_(3)-Na,and rich in soluble SiO_(2),F^(-)and Cl^(-).The geothermal water primarily originated from the recharging meteoric water with a maximum circulation depth of 2400-3200 m,but affected by the mixing of endogenous sedimentary water.The reservoir temperature calculated by Na-K and quartz geothermometer of the Nuanquanzi geothermal system was determined to be 73.39-92.87℃.The conduction-cooling and shallow cold-water mixing processes occurred during the parent geothermal fluid ascent to surface,and the proportion of cold-water mixing during circulation was approximately 88.3%to 92.2%.The high-anomaly radon zones matched well to the low apparentresistance areas and hiding faults,indicating that the Nuanquanzi geothermal field was dominated by a graben basin restricted by multiple faults.展开更多
High residual concentration of arsenic and fluoride is a tricky problem to be solved in the process of reinjection after geothermal water utilization.We develop a method to simultaneously remove As(V)and F-from geothe...High residual concentration of arsenic and fluoride is a tricky problem to be solved in the process of reinjection after geothermal water utilization.We develop a method to simultaneously remove As(V)and F-from geothermal water using magnetic Fe_(3)O_(4)@MgO adsorbent,fabricated via a one-step method.The effects of pH,contact time,adsorbent dose and temperature on the removal efficiency were investigated systematically.The results show that the Fe_(3)O_(4)@MgO composite has a wide range of pH(2-11),ultrafast removal dynamics(As(V):2 min;F-:30 min),and high removal efficiency(As(V):99.9%;F-:96.6%).The adsorption kinetics follows the pseudo-secondorder kinetics model,and the adsorption isotherm model fits Freundlich.The adsorption capacity of As(V)and F-can reach 123 and 98.4 mg/g,respectively.The exchange of As(V)and F-with Mg-hydroxyl groups hydrolysis by MgO was determined the adsorption mechanism.The Fe_(3)O_(4)@MgO adsorbent was capable of achieving the adsorption efficiency as high as 99.9%for As(V)and 97.3%for F-in real geothermal water,respectively.Hence,the proposed Fe_(3)O_(4)@MgO composite exhibited as an excellent adsorbent for the remediation of As-and F-contaminated geothermal water.展开更多
基金financially supported by the National Natural Science Foundation of China (No. 41120124003, 41572335 and 41521001)the research program of China Power Investment Corporation (2015-138-HHS-KJ-X)the research program of State Key Laboratory of Biogeology and Environmental Geology of China
文摘Longling is characterized by a wide distribution of hydrothermal areas, among which the Banglazhang hydrothermal system is the most geothermally active. Banglazhang is marked by intensive hydrothermal activities including hot springs, geysers, fumaroles and hydrothermal explosions. The geothermal waters from the Longling region are mainly HCO3-Na type with low but comparable SO4 and Cl concentrations. Calculations based on a variety of chemical geothermometers and a K-Ca geobarometer indicate that the Banglazhang hydrothermal system has much higher subsurface temperature and CO2 pressure compared to the other systems such as Daheba, Dazhulin and Huangcaoba. However, geothermal water samples collected from all these alternative hydrothermal areas are either partially equilibrated with reservoir minerals or are immature. The silica-enthalpy relationships of Banglazhang geothermal waters indicate the presence of a deep geothermal fluid with an enthalpy value and silica concentration of 945 J/g（up to around 220 °C） and 339 mg/L. Our work indicates the Banglazhang area is a promising source in terms of long-term utilization of hydrothermal resources.
基金supported by the Carbon Peak and Carbon Neutralization Science and Technology Innovation Special Fund of Jiangsu Province,China(No.BE2022859)Natural Science Foundation of Guangdong Province,China(No.2021A1515011763).
文摘Process heating constitutes a significant share of final energy consumption in the industrial sector around the world.In this paper,a high-temperature heat pump(HTHP)using flash tank vapor injection technology(FTVI)is proposed to develop low-temperature geothermal source for industrial process heating with temperature above 100°C.With heat sink output temperatures between 120°C and 150°C,the thermo-economic performance of the FTVI HTHP system using R1234ze(Z)as refrigerant is analyzed and also compared to the single-stage vapor compression(SSVC)system by employing the developed mathematical model.The coefficient of performance(COP),exergy efficiency(ηexe),net present value(NPV)and payback period(PBP)are used as performance indicators.The results show that under the typical working conditions,the COP andηexe of FTVI HTHP system are 3.00 and 59.66%,respectively,and the corresponding NPV and PBP reach 8.13×106 CNY and 4.13 years,respectively.Under the high-temperature heating conditions,the thermo-economic performance of the FTVI HTHP system is significantly better than that of the SSVC system,and the larger the temperature lift,the greater the thermo-economic advantage of the FTVI HTHP system.Additionally,the FTVI HTHP system is more capable than the SSVC system in absorbing the financial risks associated with changes of electricity price and natural gas price.
基金supported by the Research Project on Middle and Deep Geothermal Energy Utilization in Guanzhong Area of Shaanxi ProvincedSpecial Study on Sandstone Thermal Storage Recharge(No.21152920349)the Special Fund for Basic Scientific Research Operating Expenses of Central Universities of Chang'an University(Grant No.300102292903)+1 种基金the Basic Research Plan of Natural Sciences of Shaanxi Province General Project“Study on Loess Landslide Chronology Based on OSL Dating Technology”(Grant No.2017JM4018)the Open Fund of State Key Laboratory of Loess and Quaternary Geology(Grant No.SKLLQG1933).
文摘The Xi'an Depression in the Guanzhong Basin of western China has been suggested to contain geothermal resources that could aid China in achieving carbon neutrality and optimizing energy structure.However,the high concentration of total dissolved solids(TDS)and scale-forming ions in geothermal water from the depression causes severe scaling problems in harvesting geothermal energy.To reduce scale-related problems,accurate identification of scale types and prediction of scaling during geothermal energy utilization are crucial.This study starts with identifying the types and trends of scaling in the study area,using index-based discriminant methods and hydrogeochemical simulation to calculate and analyze the mineral saturation index of water samples from some wellheads and of reconstructed fluid samples of geothermal reservoirs.The results indicate that the scales are mostly calcium carbonate scales rather than sulfate scales as a result of temperature changes.Several portions of the geothermal water systems are found to have distinct mineral scaling components.Quartz and chalcedony are formed in low temperature areas,while carbonate minerals are in high temperature areas.Despite the low iron content of geothermal water samples from the study area,scaling is very common due to scaling-prone iron minerals.The findings can be used to evaluate geothermal drainage systems and guide anti-scaling during geothermal energy utilization in similar settings.
文摘To study the mechanism of bio-clogging in a porous medium during the reinjection of geothermal water and to improve reinjection efficiency, an indoor one-dimensional reinjection experiment was conducted based on the geological model of the geothermal reinjection demonstration project in Dezhou City. The biological process of porous media clogging was investigated by analyzing the variation of permeability within the medium, the main indexes of nutrient salts, and the content of extracellular polymeric substances (EPS). High-throughput sequencing, based on 16S rRNA, was used to analyze the characteristics and succession of microbial communities during the reinjection of geothermal water. The results of the study show that significant bio-clogging occurs during the reinjection of geothermal water, with an increase in the heterogeneity of the thermal reservoir medium, and a decrease in permeability. The extent of clogging gradually reduces with an increase in seepage path. Thus, thermal reservoir clogging is more serious closer to the water inlet. With an increase in the duration of reinjection, the permeability of the porous medium undergoes three stages: “rapid”, “decline-slow”, and “decrease-stable”. The results show that the richness and diversity of the bacterial community increase and decrease, respectively, during the reinjection process. Bacterial community succession occurs, and the bacterial communities mainly include the Proteobacteria and Bacteroidetes phyla. <em>Pseudomonas</em> and <em>Devosia</em> are respectively the dominant bacteria in the early and late stages of geothermal water reinjection.
文摘In the present study, a dual-pressure organic Rankine cycle (DORC) driven by geothermal hot water for electricity production is developed, investigated and optimized from the energy, exergy and exergoeconomic viewpoint. A parametric study is conducted to determine the effect of high-stage pressure<span><span><span style="font-family:;" "=""><span></span><span><span> </span>and low-stage pressure</span><span></span><span><span> </span>variation on the system thermodynamic and exergoeconomic performance. The DORC is further optimized to obtain maximum exergy efficiency optimized design (EEOD case) and minimum product cost</span></span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "="">optimized design (PCOD case). The exergy efficiency and unit cost of power produced for the optimization of EEOD case and PCOD case are 33.03% and 3.059 cent/kWh, which are 0.3% and 17.4% improvement over base case, respectively. The PCOD case proved to be the best, with respect to minimum unit cost of power produced and net power output over the base case and EEOD case.
基金This study was supported in part by a research grant from the Graduate School of Humanities,Hosei University and Japan Society for the Promotion of Science(JSPS,JP21K13150).
文摘This study aimed to elucidate the influence of inflow water on the salinity concentration process of a saline lake and the mass balance of Lake Issyk-Kul,a tectonic saltwater lake in Kyrgyzstan.Based on the survey results and meteorological data from 2012 to 2015,we analyzed the dissolved chemical composition loads due to water inflow.Then,we discussed the relationship between the increase in salinity and water inflow into the lake.Through the water quality analysis data,we used the tank model to estimate the river inflow and analyze the loads by the L-Q curve.The groundwater loads were then estimated from the average annual increase in salinity of the lake over a period of 30 a.The results suggest that Lake Issyk-Kul was temporarily freshened between about AD 1500 and 1800 when an outflowing river existed,and thereafter,it became a closed lake in AD 1800 and continued to remain a saline lake until present.The chemical components that cause salinization are supplied from the rivers and groundwater in the catchment area,and when they flow into the lake,Ca^(2+),HCO_(3)−and Mg^(2+)precipitate as CaCO_(3) and MgCO_(3).These compounds were confirmed to have been left on the lakeshore as evaporite.The model analysis showed that 1.67 mg/L of Ca^(2+)and Mg^(2+)supplied from rivers and groundwater are precipitated as evaporite and in other forms per year.On the other hand,salinity continues to remain in the lake water at a rate of 27.5 mg/L per year.These are the main causes of increased salinity in Lake Issyk-Kul.Since Na^(+)and Cl^(-)are considered to be derived from geothermal water,they will continue to flow in regardless of the effects of human activities.Therefore,as long as these components are accumulated in Lake Issyk-Kul as a closed lake,the salinity will continue to increase in the future.
基金financially supported by the China Geological Survey(Nos.DD20190822 and DD20190536)the Key Research Program of Hebei Science and Technology Department(No.19224205D)。
文摘Study on the Nuanquanzi geothermal field in the Yanshan uplift is of great significance for understanding the origin of geothermal fluid in the intracontinental orogenic belt of the fault depression basin margin in North China.The geochemical characteristics and formation mechanism of the Nuanquanzi geothermal system were elucidated by classical hydrogeochemical analysis,multi-isotopes approach(δD,δ^(18)O,δ^(13)C,δ^(87)Sr/^(86)Sr),14CAMSdating,and integrated geophysical prospecting of surface-soil radon gas measurement and CSAMT inversion.The results show that the Nuanquanzi geothermal field is a medium-low temperature convection-fault semi-enclosed geothermal system.The hydrochemical type of thermal water is primarily HCO_(3)-Na,and rich in soluble SiO_(2),F^(-)and Cl^(-).The geothermal water primarily originated from the recharging meteoric water with a maximum circulation depth of 2400-3200 m,but affected by the mixing of endogenous sedimentary water.The reservoir temperature calculated by Na-K and quartz geothermometer of the Nuanquanzi geothermal system was determined to be 73.39-92.87℃.The conduction-cooling and shallow cold-water mixing processes occurred during the parent geothermal fluid ascent to surface,and the proportion of cold-water mixing during circulation was approximately 88.3%to 92.2%.The high-anomaly radon zones matched well to the low apparentresistance areas and hiding faults,indicating that the Nuanquanzi geothermal field was dominated by a graben basin restricted by multiple faults.
基金funded by the Second Comprehensive Scientific Investigation Project of Qinghai-Tibet Plateau(No.2019QZKK0603)the National Natural Science Foundation of China(No.22066022)+2 种基金Science and Technology Plan Projects of Tibet Autonomous Region(No.ZYYD2022000255)Key Projects of“Science and Technology Help Economy 2020”(No.SQ2020YFF0423891)Key Projects of Solid Waste Recycling(No.2019YFC1904103-04)。
文摘High residual concentration of arsenic and fluoride is a tricky problem to be solved in the process of reinjection after geothermal water utilization.We develop a method to simultaneously remove As(V)and F-from geothermal water using magnetic Fe_(3)O_(4)@MgO adsorbent,fabricated via a one-step method.The effects of pH,contact time,adsorbent dose and temperature on the removal efficiency were investigated systematically.The results show that the Fe_(3)O_(4)@MgO composite has a wide range of pH(2-11),ultrafast removal dynamics(As(V):2 min;F-:30 min),and high removal efficiency(As(V):99.9%;F-:96.6%).The adsorption kinetics follows the pseudo-secondorder kinetics model,and the adsorption isotherm model fits Freundlich.The adsorption capacity of As(V)and F-can reach 123 and 98.4 mg/g,respectively.The exchange of As(V)and F-with Mg-hydroxyl groups hydrolysis by MgO was determined the adsorption mechanism.The Fe_(3)O_(4)@MgO adsorbent was capable of achieving the adsorption efficiency as high as 99.9%for As(V)and 97.3%for F-in real geothermal water,respectively.Hence,the proposed Fe_(3)O_(4)@MgO composite exhibited as an excellent adsorbent for the remediation of As-and F-contaminated geothermal water.
