The Yueguang gold deposit is located in Fengjia,Xinhua County,Hunan Province,South China.It represents a recently discovered small-scale gold deposit situated in the southwestern region of the Jiangnan Orogenic Belt,w...The Yueguang gold deposit is located in Fengjia,Xinhua County,Hunan Province,South China.It represents a recently discovered small-scale gold deposit situated in the southwestern region of the Jiangnan Orogenic Belt,west of the Baimashan granitic batholith.In order to discern the characteristics of the ore-formingfluids,the underlying mineralization processes,and establish a foundation for the origin of the Yueguang gold depositfluid inclusion micro-thermometry,as well as quartz hydrogen and oxygen isotope analysis,have been carried out on samples obtained from various stages of mineralization.The hydrothermal miner-alization stages within the Yueguang gold deposit can be categorized into three stages:(i)the barren,pre-ore quartz-pyrite stage(Stage Ⅰ),the quartz-pyrite-gold stage(Stage Ⅱ),and the post-ore quartz-carbonate stage(Stage Ⅲ),with the second stage being the main mineralization stage.Thefluid inclusions identified in samples from the main min-eralization stage can predominantly be described with the NaCl–H_(2)O and CO_(2)–NaCl–H_(2)O systems.These inclusions display homogenization temperatures ranging from 158.8 to 334.9℃,and thefluid salinity ranges from 0.3%to 4.0%(wt.%NaCl equiv.).Laser Raman spectroscopy analysis of individual inclusions further reveals the presence of gas-phases such as CO_(2),CH_(4),and N_(2).Isotopic analysis indicatesδ^(18)Ofluid values ranging from 3.95 to 6.7‰ and δDH_(2)O values ranging from-71.9 to-55.7‰.These results indi-cate that the ore-formingfluid of the Yueguang gold deposit belongs to metamorphic hydrothermalfluids of middle-low temperature and low salinity.In the process of ore formation,gold is transported in the form of Au(HS)2-complexes,with gold deposition being driven byfluid immiscibility.Therefore,the Yueguang gold deposit is categorized as an orogenic gold deposit dominated by metamorphic hydrother-malfluid.It may become a new target for gold exploration in the Baimashan region,central Hunan Province.展开更多
Lamprophyres typically appear in hydrothermal gold deposits.The relationship between lamprophyres and gold deposits is investigated widely.Some researchers suggest that the emplacement of lamprophyres triggers gold mi...Lamprophyres typically appear in hydrothermal gold deposits.The relationship between lamprophyres and gold deposits is investigated widely.Some researchers suggest that the emplacement of lamprophyres triggers gold mineralization,whereas others hypothesize that the formation of lamprophyres increases the fertility of mantle sources and ore-forming fluids.K-feldspar veins,with ages between those of lamprophyres and gold deposits,appear in lamprophyres in Zhenyuan.Therefore,K-feldspar veins are ideal for investigating the relationship between lamprophyres and gold deposits.Phlogopite in K-feldspar veins has lower Mg#,Ni,and Cr contents and higher TiO2,Li,Ba,Sr,Sc,Zr,Nb,and Cs contents than phlogopite in lamprophyres.The in-situ Sr isotopic values of apatites(0.7063–0.7066)in K-feldspar veins are within the range for apatites(0.7064–0.7078)from lamprophyres.High large-ion lithophile element concentrations and low Nb and Ta concentrations in phlogopite from lamprophyres,in addition to high(87Sr/86Sr)i values of apatite(0.7064–0.7078),indicate that the magma parental to these phlogopite and apatite crystals is derived from an enriched mantle.Kfeldspar veins are genetically correlated with lamprophyres,whereas sulfide mineral assemblage and trace element compositions of pyrite in K-feldspar veins suggest that K-feldspar veins in lamprophyres are not directly related to gold mineralization of the Zhenyuan deposit.展开更多
The Dayingezhuang gold deposit,hosted mainly by Late Jurassic granitoids on Jiaodong Peninsula in eastern China,contains an estimated 170 t of gold and is one of the largest deposits within the Zhaoping fracture zone....The Dayingezhuang gold deposit,hosted mainly by Late Jurassic granitoids on Jiaodong Peninsula in eastern China,contains an estimated 170 t of gold and is one of the largest deposits within the Zhaoping fracture zone.The orebodies consist of auriferous altered pyrite–sericite–quartz granites that show Jiaojia-type(i.e.,disseminated and veinlet)mineralization.Mineralization and alteration are structurally controlled by the NE-to NNE-striking Linglong detachment fault.The mineralization can be divided into four stages:(K-feldspar)–pyrite–sericite–quartz,quartz–gold–pyrite,quartz–gold–polymetallic sulfide,and quartz–carbonate,with the majority of the gold being produced in the second and third stages.Based on a combination of petrography,microthermometry,and laser Raman spectroscopy,three types of fluid inclusion were identified in the vein minerals:NaCl–H2 O(A-type),CO2–H2 O–NaCl(AC-type),and pure CO2(PC-type).Quartz crystals in veinlets that formed during the first stage contain mainly AC-type fluid inclusions,with rare PC-type inclusions.These fluid inclusions homogenize at temperatures of 251°C–403°C and have low salinities of 2.2–9.4 wt%NaCl equivalent.Quartz crystals that formed in the second and third stages contain all three types of fluid inclusions,with total homogenization temperatures of 216°C–339°C and salinities of 1.8–13.8 wt%NaCl equivalent for the second stage and homogenization temperatures of 195°C–321°C and salinities of 1.4–13.3 wt%NaCl equivalent for the third stage.In contrast,quartz crystals that formed in the fourth stage contains mainly A-type fluid inclusions,with minor occurrences of AC-type inclusions;these inclusions have homogenization temperatures of 106°C–287°C and salinities of 0.5–7.7 wt%NaCl equivalent.Gold in the ore-forming fluids may have changed from Au(HS)0 as the dominant species under acidic conditions and at relatively high temperatures and f O2 in the early stages,to Au(HS)2–under neutral-pH conditions at lower temperatures and f O2 in the later stages.The precipitation of gold and other metals is inferred to be caused by a combination of fluid immiscibility and water–rock interaction.展开更多
A new expression for calculating suspended fine-sediment deposition rate is developed based on theoretic analysis and experiments. The resulting equation is applied to simulation of fine sediment deposition in the rec...A new expression for calculating suspended fine-sediment deposition rate is developed based on theoretic analysis and experiments. The resulting equation is applied to simulation of fine sediment deposition in the reclaimed land in the Hangzhou Bay, China. The hydrodynamic environment in this area is solved by use of a long wave model, which gives the 2D-velocity field and considers bathymetric changes due to fine sediment deposition. The expression is proved convenient to use in engineering practice, and the predicted deposition rate agrees with the annual data available from field measurements from the first year to the third year after the construction of the long groin as a reclaiming method.展开更多
An accelerator storage ring needs clean ultrahigh vacuum.A TiZrV non-evaporable getter(NEG) film deposited on interior walls of the chamber can realize distributed pumping,effective vacuum improvement and reduced long...An accelerator storage ring needs clean ultrahigh vacuum.A TiZrV non-evaporable getter(NEG) film deposited on interior walls of the chamber can realize distributed pumping,effective vacuum improvement and reduced longitudinal pressure gradient.But accumulation of pollutants such as N_2 and O_2 will decrease the adsorption ability of the NEG,leading to a reduction of NEG lifetime.Therefore,an NEG thin film coated with a layer of Pd,which has high diffusion rate and absorption ability for H_2,can extend the service life of NEG and improve the pumping rate of H_2 as well.In this paper,with argon as discharge gas,a magnetron sputtering method is adopted to prepare TiZrV-Pd films in a long straight pipe.By SEM measurement,deposition rates of TiZrV-Pd films are analyzed under different deposition parameters,such as magnetic field strength,gas flow rate,discharge current,discharge voltage and working pressure.By comparing the experimental results with the simulation results based on Sigmund's theory,the Pd deposition rate C can be estimated by the sputtered depth.展开更多
Filling high-aspect-ratio trenches with gold is a frequent requirement in the fabrication of X-ray optics as well as micro-electronic components and other fabrication processes. Conformal electrodeposition of gold in ...Filling high-aspect-ratio trenches with gold is a frequent requirement in the fabrication of X-ray optics as well as micro-electronic components and other fabrication processes. Conformal electrodeposition of gold in sub-micron-width silicon trenches with an aspect ratio greater than 35 over a grating area of several square centimeters is challenging and has not been described in the literature previously. A comparison of pulsed plating and constant current plating led to a gold electroplating protocol that reliably filled trenches for such structures.展开更多
The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted hi...The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted high-precision ground magnetic measurements to delineate fault structures and favorable prospecting targets,utilized induced polarization(IP)intermediate gradient to roughly determine the distribution and extension of the tectonic altered zone and gold ore(mineralized)bodies,and further carried out IP sounding and magnetotelluric sounding to locate the tectonic altered zone and gold ore(mineralized)bodies.The anomalous gradient belt of the combination of positive and negative micromagnetic measurements reflects the detail of shallow surface tectonic alteration zone and gold mineralization body.Micromagnetic profile anomalies indicate the spatial location and occurrence of concealed tectonic alteration zone and gold(mineralized)ore bodies.Soil geochemical measurements indicate that the ore-forming element Au correlates well with As and Sb,and As and Sb anomalies have a good indication to gold orebodies.Based on the multi-source geological-geophysical-geochemical information of the Nyasirori gold deposit,this work established an integrated prospecting model and proposed a set of geophysical and geochemical methods for optimizing prospecting targets.展开更多
A new kind of plasma technology with both high deposition rate and low dilution ratio was developed under the calculation and analysis of the arc flame characteristics of plasma arc,the kinematics behavior of powder a...A new kind of plasma technology with both high deposition rate and low dilution ratio was developed under the calculation and analysis of the arc flame characteristics of plasma arc,the kinematics behavior of powder and powder’s heating in the arc. Compared with normal plasma surfacing method, the idea using constricting nozzle with small orifice diameter, long plasma arc and increasing the distance from meeting point of the two beams of powder to workpiece, to achieve the goals of high deposition rate and low dilution ratio, was put forward here. In order to prove this idea, a set of experimental system was built up and obtained satisfied results including high deposition rate(more than 25 kg/h )and low dilution ratio(less than 5%). The success of this study offers a promising prospect for developing the powder plasma surface welding in China and may open a way to improve this technology further in efficiency and quality.展开更多
Carbon nanotubes (CNTs) were synthesized through the catalytic decomposition of a ferrocene-xylene mixture in a horizontal chemical va- por deposition reactor. The deposition rate of CNTs along the axial direction was...Carbon nanotubes (CNTs) were synthesized through the catalytic decomposition of a ferrocene-xylene mixture in a horizontal chemical va- por deposition reactor. The deposition rate of CNTs along the axial direction was measured. The morphology of CNTs was observed by scan- ning electron microscopy (SEM) and transmission electron microscopy (TEM). The results showed that the deposition rate of CNTs along the axial direction first increased and later decreased, the position achieving the maximum deposition rate was influenced by the operating conditions. The morphologies of CNTs also changed along the axial direction.展开更多
The southwestern Iran is one of the regions that are most prone to dust events.The objective of this study is the analysis of the spatial and temporal distributions of dust deposition rate as a key factor for finding ...The southwestern Iran is one of the regions that are most prone to dust events.The objective of this study is the analysis of the spatial and temporal distributions of dust deposition rate as a key factor for finding the relative impact of the dust.First,the monthly mean aerosol optical thickness(AOT)from Moderate Resolution Imaging Spectroradiometer(MODIS)was analyzed and compared with the dust amount variations from ground deposition rate(GDR),and the results were further used to investigate the spatial and temporal distributions of dust events in southwestern Iran for the period between 2014 and 2015.Moving air mass trajectories,using the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)model,were proven to be a discriminator of their local and regional origin.The results from GDR analysis produced a correlation coefficient between dust event history and deposition rates at dust magnitudes of>0.93 that is meaningful at the 95%confidence level.Furthermore,the deposition rates varied from 3 g/m2 per month in summer to 10 g/m2 per month in spring and gave insight into the transport direction of the dust.Within the same time series,AOT correspondences with MODIS on Terra in four aerosol thickness layers(clean,thin,thick,and strong thick)were shown in relation to each other.The deepest mixed layers were observed in spring and summer with a thickness of approximately 3500 m above ground level in the study area.Investigations of ground-based observations were correlated with the same variations for each aerosol thickness layer from MODIS images and they can be applied to discriminate layers of aeolian dust from layers of other aerosols.Together,dust distribution plots from AOT participated to enhance mass calculations and estimation deposition rates from the thick and strong thick aerosol thickness layers using the results from GDR.Despite all the advances of AOT,under certain circumstances,ground-based observations are better able to represent aerosol conditions over the study area,which were tested in southwestern Iran,even though the low number of observations is a commonly acknowledged drawback of GDR.展开更多
Analysis of the anomalous magnetic mineral intensities and geochemistry for placer gold deposits are presented for those of the Attock area at the confluence of the Indus and Kabul rivers in northwestern Pakistan.Two ...Analysis of the anomalous magnetic mineral intensities and geochemistry for placer gold deposits are presented for those of the Attock area at the confluence of the Indus and Kabul rivers in northwestern Pakistan.Two grids covering an area of 10 x18 m2 and 8 x10 m2 were analyzed using a G-858 Cesium Vapor Magnetometer.The anomalous zones obtained were plotted on contour maps,2 D and 3 D magnetic intensity maps.Based on the magnetic anomalies,grid-1 of the study area was sampled at three different anomalous zones for geochemical analysis.These zones contain gold concentrations,ranging from 2.11 ppm to 6.109 ppm with an average of 4.01 ppm.Increase in gold concentration in the subsurface within the anomalous zones indicates that magnetometer survey followed by a geochemical analysis can potentially narrow down the gold-bearing anomalous zones.展开更多
In order to understand the mechanism(s) of gold precipitation in the anorthosite-hosted Sangchon gold deposits in the Hadong area, Korea, chemical speciation and reaction path calculations were accomplished by geochem...In order to understand the mechanism(s) of gold precipitation in the anorthosite-hosted Sangchon gold deposits in the Hadong area, Korea, chemical speciation and reaction path calculations were accomplished by geochemical modeling. The modeling consisted of three-step procedures: reaction with anorthosite, then the simple cooling of the reacted fluid, and finally the boiling of metalliferous fluid. The principal vein minerals of the Sangchon deposits consist of quartz, sericite, kaolinite, pyrite, galena, chalcopyrite, sphalerite and acanthite. The sulfide mineralization is typically zoned from pyrite (preferentially at vein margins) to galena and sphalerite (toward vein center). Electrum is intimately associated with pyrite ± chalcopyrite and sphalerite. By comparing the results of modeling with the observed mineral assemblages and paragenesis, the most appropriate evolution path of ore fluids was suggested as follow: reaction of a single fluid with anorthosite at 300℃, then the isobaric cooling of the fluid at temperatures from 250° to 100℃, and then the boiling and cooling of the fluid due to the decrease of pressure and temperature. Calculations also show that all of the observed alteration minerals formed due to fluid-anorthosite interaction at early period, whereas most of sulfides and electrum were precipitated mainly due to cooling. The abundance of gold in veins depends critically on the ratio of total base metals plus iron to sulfide in the aqueous phase, because gold is transported as Au(HS) 2 -whose solubility is very sensitive to the sulfide activity. Our results of geochemical modeling generally fit to the observed mineral assemblages and mineral composition, indicating the usefulness of numerical simulation for elucidating the genesis of gold deposits.展开更多
In welding, so many factors contribute to good quality welds. The deposition rate is the rate of weld metal deposit at fusion zone during welding, which also is a key factors affecting the quality of welded joints. To...In welding, so many factors contribute to good quality welds. The deposition rate is the rate of weld metal deposit at fusion zone during welding, which also is a key factors affecting the quality of welded joints. Too high or low deposition rate compromises the integrity of weld. This study was carried out with the aim of providing an approach for producing better weldments by optimizing and predicting deposition rate of low carbon steel using Response Surface Methodology (RSM). 30 sets of experiments were done, adopting the central composite experimental design. The tungsten inert gas welding equipment was used to produce the welded joints. Argon gas was supplied to the welding process to shield the weld from atmospheric interference. Mild steel coupons measuring 60 × 40 × 10 mm was used for the experiments. The results obtained show that the voltage and current have very strong influence on the deposition rate. The models developed possess a variance inflation factor of 1. And P-value is less than 0.05, indicating that the model is significant. The models also possessed a high goodness of fit with R2 (Coefficient of determination) values of 91%. The model produced numerically obtained optimal solution of current of 160.00 Amp, voltage of 20 volts and a gas flow rate of 17 L/min produces a welded material having deposition rate of 0.4637 kg/hr. This solution was selected by design expert as the optimal solution with a desirability value of 98.8%. A weld simulation using the optimum value obtained produced a weld with good quality.展开更多
Based on X-ray diffraction,optical microscopy and scanning electron microscopy analysis of the Dachang gold ore,it is showed that the sulfide of ore is the main carrier minerals of gold. A majority of gold is embedded...Based on X-ray diffraction,optical microscopy and scanning electron microscopy analysis of the Dachang gold ore,it is showed that the sulfide of ore is the main carrier minerals of gold. A majority of gold is embedded in pyrite and tetrahedrite as the form of inclusion and a small amount intergrowth with pyrite and gangue mineral,occasionally the presence is in form of monomer natural gold. The main factors which influence the recovery rate are sulfide mineral particle size,and the fine grained sulfide is beneficial for the dissociation and flotation of gold bearing minerals. The monomer dissociation degree of gold bearing minerals can reach91. 3%,when the grinding fineness is less than 0. 074 mm and grain level accounts as 80%. It is not conducive to the flotation of sulfide if the grinding fineness is low or high. It is difficult to completely dissociate the monomer if there is a small amount of pyrite and arsenopyrite in the ore. Therefore,before leaching the gold,it must conduct pretreatment to reach the ideal recovery rate of the gold,like roasting oxidation,pressure oxidation and biological oxidation. The fine microscopic gold has little influence on the gold recovery rate.展开更多
The Xinlong gold deposit is located in Niyma County,Naqu area of Tibet and was discovered by the Institute of Mineral Resources,Chinese Academy of Geological Sciences through the 1∶50000 mineral geological survey.The...The Xinlong gold deposit is located in Niyma County,Naqu area of Tibet and was discovered by the Institute of Mineral Resources,Chinese Academy of Geological Sciences through the 1∶50000 mineral geological survey.The ore bodies occur in the Zenong Group volcanic rocks in the middle section of the central Lhasa subterrane and are structurally controlled by the NNW-striking faults.Four ore bodies have been found,exhibiting cloddy,dense-sparse,disseminated,and breccia structures.The ore minerals are mainly tetrahedrite group minerals,and other ore minerals include pyrite,chalcopyrite,nevskite,bornite,anglesite,native gold,and silver-gold bearing selenide,etc.The types of alteration are dominated by silicification,as well as middle-and high-graded argillization.The alteration mineral assemblages contain quzrtz,pyrophyllite,and kaolinite.The Zaliela Formation volcanic rocks of Zenong Group are silicified by later hydrothermal fluid with vuggy quartz in some fractured zones.The middle-and high-graded argillization are characterized by pyrophyllitization and kaolinization.The Xinlong gold deposit shows great metallogenetic potentiality and has been revealed by 1∶10000 geological mapping,IP sounding,and trial trenching in the mining area.Combined with the regional metallogenic geological setting,we suppose that a potential epithermal gold belt probably exists in the middle of the Lhasa terrane.The discovery of the Xinlong gold deposit opens a new chapter for the gold prospecting in Northern Tibet.展开更多
To shed light on the genesis of the Dongping deposit and reveal the behaviour of CO_(2),Au and other ore elements(e.g.,Cu,Fe,Zn,As,Sb,Co etc.)in ore-forming fluids,petrographic,microthermometric and synchrotron radiat...To shed light on the genesis of the Dongping deposit and reveal the behaviour of CO_(2),Au and other ore elements(e.g.,Cu,Fe,Zn,As,Sb,Co etc.)in ore-forming fluids,petrographic,microthermometric and synchrotron radiation X-ray fluorescence(SRXRF)analyses of fluid inclusions were conducted.The ore-forming fluid is characterized as an H_(2)O-CO_(2)-NaCl system with medium-high temperatures and low salinity.Four mineralization stages are identified,namely,feldsparquartz(stage 1);pyrite-white quartz(stage 2);sulfide-smoky grey quartz(stage 3);and carbonate-quartz(stage 4).Three types of inclusions were distinguished,based on fluid composition,phase assemblages and mode of homogenization.Type A:H_(2)O-rich fluid inclusions show 2 phases(liquid H_(2)O(LH_(2)O)+vapour H_(2)O(VH_(2)O))at room temperature and homogenize to the liquid phase.Type B:H_(2)O-CO_(2)fluid inclusions contain 2–3 phases(liquid H_(2)O(LH_(2)O)+vapour CO_(2)(VCO_(2));liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2)));liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2))+vapour CO_(2)(VCO_(2)))at room temperature and homogenized to the liquid H_(2)O phase.Type C:H_(2)O-CO_(2)fluid inclusions show 2 phases(liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2))at room temperature and homogenize to a critical state.CO_(2)is clearly more enriched in the fluid inclusions of stages 2 and 3 than in stage 1.Stage 1 is dominated by type A(H_(2)O-rich)inclusions with homogenization temperatures(Th)of 220–359℃and salinities of 1.1–3.1 wt%NaCl equivalent.Type B(CO_(2)-rich)inclusions gradually increase in stages 2 and 3.The Th range of type B inclusions in stage 2 is 241–397℃with salinities of 2.2–6.9 wt%NaCl equivalent;the Th range of type A inclusions is 217–373℃with salinities of 1.2–8.1 wt%NaCl equivalent.The Th range of type B inclusions in stage 3 is 215–361℃with salinities of 2.9–6.1 wt%NaCl equivalent;the range of type A inclusions is 158–351℃with a salinity of 0.7–5.5 wt%NaCl equivalent.Stage 4 is characterized by type A with Th of 151–250℃and salinities of 0.9–8.3 wt%NaCl equivalent.The mapping results show that elements As,Te and Sb are more concentrated in vapour CO_(2)than in liquid H_(2)O at room temperature,which suggests that vapour components are more able to transport elements when phase separation occurs.The SRXRF quantitative results show that Au,Cl,S and some other metals are obviously more enriched in the fluid inclusions of stages 2 and 3 than those in stage 1.Additionally,the contents of S in stages 1–3 are much lower than those of Cl,which suggests that gold might migrate mainly in the form of a gold-chloride complex.Au is more enriched in type B fluid inclusions than in type A fluid inclusions,which suggests that the enrichment and migration of gold are closely related to CO_(2)and CO_(2)plays a critical role in the migration and enrichment of gold.The trace elements in the fluid have a similar change trend to those in the Yanshanian syenogranite distributed in the southeastern part of the mining area,which may provide some evidence for an intrusion-related genesis for the Dongping gold deposit.展开更多
Hydrothermal alteration with bleaching of host rocks is the most important prospecting indicator for gold deposits in the Jiangnan Orogen Belt.The alteration has been identified as pre-ore carbonate(siderite)-sericiti...Hydrothermal alteration with bleaching of host rocks is the most important prospecting indicator for gold deposits in the Jiangnan Orogen Belt.The alteration has been identified as pre-ore carbonate(siderite)-sericitization and the Fe of siderite in the alteration zone is derived from the host rocks rather than fluids.In addition,such alteration decreases in intensity and width with depth and gold mineralization also occur in the non-bleached rocks,casting doubt on the reliability of the prospecting indicator.Detailed petrographic work and SEM analysis on the Wangu deposit indicate that there are two types of siderites,i.e.,Sd1 and Sd2.Among them,Sd1 grains are relatively small and distributed along the planes of unaltered host rocks,while Sd2 grains,only occurring in the altered slates,are commonly larger.Both types of siderites were altered by auriferous fluids,producing porous cores and minerals such as pyrite,quartz,and ankerite.Compared with unaltered parts,the altered parts have lower Fe,but higher U,Pb,and REE.In addition,Sd1 and Sd2 are similar in Mn,Na,V,and Sr concentrations but different in Fe and Mg.The occurrence and geochemical compositions of both siderites indicate that Sd1 could be transformed into Sd2 by pre-mineralization alteration through dissolution-reprecipitation.Chlorite is another important Fe-bearing mineral in the host rocks,and EPMA analysis suggests that it is ripidolite with relatively high Fe contents.Consequently,chlorite can also provide Fe to form the pre-ore carbonate(siderite)-sericitization.Geochemical modeling demonstrates that both ripidolite and siderite can result in sulfidation and therefore gold precipitation.As a result,this study demonstrates that pre-ore alteration with characterized bleaching is not a prerequisite for gold mineralization despite of its prominent features.Due to the presence of Fe-bearing Sd1 and chlorite,gold mineralization could still occur through sulfidation in the unaltered rocks.展开更多
Located along the southern part of the West Qinling orogenic belt,the Yangshan gold deposit is one of the largest in China.The major gold ores of Yangshan are disseminated in metasedimentary host rocks with minor nati...Located along the southern part of the West Qinling orogenic belt,the Yangshan gold deposit is one of the largest in China.The major gold ores of Yangshan are disseminated in metasedimentary host rocks with minor native gold amounts in stibnite-gold quartz veins.Pyrite and arsenopyrite are the major Au-bearing minerals.Hydrothermal muscovite from gold-bearing quartz veins was dated using the in situ Rb-Sr method to determine the formation age of the Yangshan gold deposit.The Rb-Sr isochron date of the muscovite yielded 210.1±5.6 Ma(MSWD=1.2).This date is near the lower end of the period of the mineralized granitic dykes(210.49-213.10 Ma).Two stages of gold enriching process are recognized in the gold-bearing pyrite:the first is incorporated with the Co,Cu,As,Ni enrichment;and the second is accompanied by Bi,Co,Ni,Pb,Cu,Sb concentration.The in-situ sulfur isotopic values of pyrites show a restrictedΔ34s range of-1.43‰to 2.86‰with a mean value of 0.43‰.Trace-element mapping and in-situ sulfur isotopic analysis of pyrite suggest that the sulfur deposits are likely derived from a magmatic source and likely assimilated by sulfur from the sedimentary bedrock.Thus,magmatism plays a critical role in the formation of the Yangshan gold deposit.展开更多
By studying both the microscopic physical and chemical typomorphic characteristics of typical mineral pyrite samples associated with representative gold deposits on the north-central margin of the North China Platform...By studying both the microscopic physical and chemical typomorphic characteristics of typical mineral pyrite samples associated with representative gold deposits on the north-central margin of the North China Platform,this paper seeks to identify macroscopic metallogenic mechanisms of gold deposits and to reveal the formation mechanism of lattice gold in pyrite.Typomorphic characteristics of pyrite reveal that pyrite grain size has a negative correlation with gold content.Cubic pyrite,as the dominant crystal form,contains more gold than pentagonal dodecahedral pyrite.Both pyrite crystal forms and chemical compositions indicate that the replacement style of gold deposit formed in a low saturability,low sulfur fugacity,and at temperatures either much higher or much lower than its best forming temperature;comparatively,that of the quartz vein style of gold deposit occurred under conditions with the best temperature,rich in sulfur,and with high sulfur fugacity.The Au/Ag ratios of the pyrites show that both the replacement and quartz vein styles of deposits are mesothermal and hypothermal,while the Co/Ni ratios of the pyrites indicate that the quartz vein style is of magmatic-hydrothermal origin.The X-ray diffraction intensity of pyrite rich in gold is lower than that of pyrite poor in gold at the quartz vein style.In general,with an increase in gold content in pyrite,the total sum intensityΣI decreases.The pyroelectricity coefficient has a negative correlation trend with the values of(Co+Ni+Se+Te)-As and(Co+Ni+Se+Te)/As.The pyrite pyroelectricity of the replacement style is N-type,indicating that it formed under low sulfur fugacity,while that of the quartz vein style is a mixture of P-N types,indicating that it formed under high sulfur fugacity.On the pyroelectricity-temperature diagram,pyrite of the replacement style is mainly distributed between 200 and 270°C,while that of the quartz vein style varies between 90–118 and274–386°C,demonstrating a multistage forming process.In contrast to previous researchers'conclusions,the authors confirm the existence of lattice gold in pyrites through the use of an electron paramagnetic resonance(EPR)test.Au in the form of Au~+,entering pyrite as an isomorph and producing electron–hole centers,makes the centers produce spin resonance absorption and results in EPR absorption peak II.The intensity of auriferous pyrite absorption peak II has certain direct positive correlations with pyrite gold content.The#I and#III absorption peaks of pyrites possibly result from the existence of Ni^(2+)and/or Cu^(2+).γ1,γ2,andγ3 are the strongest and most typical absorption peaks of the infrared spectra of the pyrites.Generally,with the increase in gold content in the pyrite samples,γ1,γ2,andγ3 tend to shift to higher wavenumbers,and the gold content in the pyrite samples has a positive correlation with their relative absorbance.展开更多
Southwestern Guizhou province is one of China’s most important distribution areas of Carlin-type gold deposits. The Nibao deposit is a typical gold deposit in southwestern Guizhou. To elucidate the genesis of the Nib...Southwestern Guizhou province is one of China’s most important distribution areas of Carlin-type gold deposits. The Nibao deposit is a typical gold deposit in southwestern Guizhou. To elucidate the genesis of the Nibao gold deposit, establish a metallogenic model, and guide prospecting prediction, we systematically collected previously reported geological, geochemical, and dating data and discussed the genesis of the Nibao gold deposit,based on which we proposed the metallogenic model.Earlier works show that the Nibao anticline, F1 fault, and its hanging wall dragged anticline(Erlongqiangbao anticline) were formed before or simultaneously with gold mineralization, while F2, F3, and F4 faults postdate gold mineralization. Regional geophysical data showed extensive low resistivity anomaly areas near the SBT(the product of tectonic slippage and hydrothermal alteration)between the P2/P3 and the strata of the Longtan Formation in the SSE direction of Nibao anticline in the lower plate of F1 and hanging wall dragged anticline(Erlongqiangbao anticline), and the anomaly areas are distributed within the influence range of anticlines. Simultaneously, soil and structural geochemistry show that F1, Nibao anticline,Erlongqiangbao anticline, and their transition areas all show good metallogenic elements(Au, As, and S) assemblage anomalies, with good metallogenic space and prospecting possibilities. There are five main hypotheses about the source of ore-forming fluids and Au in the Nibao gold deposit:(1) related to the Emeishan mantle plume activity;(2) source from the Emeishan basalt;(3) metamorphic fluid mineralization;(4) basin fluid mineralization;(5) related to deep concealed magmatic rocks;of these, the mainstream understanding is the fifth speculation. It is acknowledged that the ore-forming fluids are hydrothermal fluids with medium–low temperature, high pressure, medium–low salinity, low density, low oxygen fugacity, weak acidity, weak reduction, and rich in CO_(2)and CH_(4). The fluid pressure is 2–96.54 MPa, corresponding to depths of 0.23–3.64 km. The dating results show that the metallogenic age is ~141 Ma, the extensional tectonic environment related to the westward subduction of the Pacific Plate. Based on the above explanation, the genetic model related to deep concealed magmatic rocks of the Nibao gold deposit is established, and favorable prospecting areas are outlined;this is of great significance for regional mineral exploration and studying the genesis of gold deposits.展开更多
基金support from several sources,including the Backbone Teacher Training Program(10912-SJGG2021-04233)the Teaching Reform Project of Chengdu University of Technology(JG2130131)+1 种基金the University-Industry Collaborative Education Project,Ministry of Education,China(22097130210756)National Natural Science Foundation of China(42272129).
文摘The Yueguang gold deposit is located in Fengjia,Xinhua County,Hunan Province,South China.It represents a recently discovered small-scale gold deposit situated in the southwestern region of the Jiangnan Orogenic Belt,west of the Baimashan granitic batholith.In order to discern the characteristics of the ore-formingfluids,the underlying mineralization processes,and establish a foundation for the origin of the Yueguang gold depositfluid inclusion micro-thermometry,as well as quartz hydrogen and oxygen isotope analysis,have been carried out on samples obtained from various stages of mineralization.The hydrothermal miner-alization stages within the Yueguang gold deposit can be categorized into three stages:(i)the barren,pre-ore quartz-pyrite stage(Stage Ⅰ),the quartz-pyrite-gold stage(Stage Ⅱ),and the post-ore quartz-carbonate stage(Stage Ⅲ),with the second stage being the main mineralization stage.Thefluid inclusions identified in samples from the main min-eralization stage can predominantly be described with the NaCl–H_(2)O and CO_(2)–NaCl–H_(2)O systems.These inclusions display homogenization temperatures ranging from 158.8 to 334.9℃,and thefluid salinity ranges from 0.3%to 4.0%(wt.%NaCl equiv.).Laser Raman spectroscopy analysis of individual inclusions further reveals the presence of gas-phases such as CO_(2),CH_(4),and N_(2).Isotopic analysis indicatesδ^(18)Ofluid values ranging from 3.95 to 6.7‰ and δDH_(2)O values ranging from-71.9 to-55.7‰.These results indi-cate that the ore-formingfluid of the Yueguang gold deposit belongs to metamorphic hydrothermalfluids of middle-low temperature and low salinity.In the process of ore formation,gold is transported in the form of Au(HS)2-complexes,with gold deposition being driven byfluid immiscibility.Therefore,the Yueguang gold deposit is categorized as an orogenic gold deposit dominated by metamorphic hydrother-malfluid.It may become a new target for gold exploration in the Baimashan region,central Hunan Province.
基金supported by the National Natural Science Foundation of China(Grant No.41973045)Basic Science and Technology Research Funding of the CAGS(Grant No.JKYZD202312)+1 种基金the National Key Research and Development Project of China(Grant No.2022YFF0800903)National Natural Science Foundation of China(Grant Nos.41802113,42073053,42273073 and 42261144669).
文摘Lamprophyres typically appear in hydrothermal gold deposits.The relationship between lamprophyres and gold deposits is investigated widely.Some researchers suggest that the emplacement of lamprophyres triggers gold mineralization,whereas others hypothesize that the formation of lamprophyres increases the fertility of mantle sources and ore-forming fluids.K-feldspar veins,with ages between those of lamprophyres and gold deposits,appear in lamprophyres in Zhenyuan.Therefore,K-feldspar veins are ideal for investigating the relationship between lamprophyres and gold deposits.Phlogopite in K-feldspar veins has lower Mg#,Ni,and Cr contents and higher TiO2,Li,Ba,Sr,Sc,Zr,Nb,and Cs contents than phlogopite in lamprophyres.The in-situ Sr isotopic values of apatites(0.7063–0.7066)in K-feldspar veins are within the range for apatites(0.7064–0.7078)from lamprophyres.High large-ion lithophile element concentrations and low Nb and Ta concentrations in phlogopite from lamprophyres,in addition to high(87Sr/86Sr)i values of apatite(0.7064–0.7078),indicate that the magma parental to these phlogopite and apatite crystals is derived from an enriched mantle.Kfeldspar veins are genetically correlated with lamprophyres,whereas sulfide mineral assemblage and trace element compositions of pyrite in K-feldspar veins suggest that K-feldspar veins in lamprophyres are not directly related to gold mineralization of the Zhenyuan deposit.
基金jointly supported by the Strategic Priority Research Program of Chinese Academy of Sciences(Grant no.XDA20070304)the China Geological Survey(DD20160024 and grant no.121201102000150011)+1 种基金the China Postdoctoral Science Foundation funded project(Grant no.2016M590119)the National Natural Science Foundation of China(Grant no.41320104004,41602084)
文摘The Dayingezhuang gold deposit,hosted mainly by Late Jurassic granitoids on Jiaodong Peninsula in eastern China,contains an estimated 170 t of gold and is one of the largest deposits within the Zhaoping fracture zone.The orebodies consist of auriferous altered pyrite–sericite–quartz granites that show Jiaojia-type(i.e.,disseminated and veinlet)mineralization.Mineralization and alteration are structurally controlled by the NE-to NNE-striking Linglong detachment fault.The mineralization can be divided into four stages:(K-feldspar)–pyrite–sericite–quartz,quartz–gold–pyrite,quartz–gold–polymetallic sulfide,and quartz–carbonate,with the majority of the gold being produced in the second and third stages.Based on a combination of petrography,microthermometry,and laser Raman spectroscopy,three types of fluid inclusion were identified in the vein minerals:NaCl–H2 O(A-type),CO2–H2 O–NaCl(AC-type),and pure CO2(PC-type).Quartz crystals in veinlets that formed during the first stage contain mainly AC-type fluid inclusions,with rare PC-type inclusions.These fluid inclusions homogenize at temperatures of 251°C–403°C and have low salinities of 2.2–9.4 wt%NaCl equivalent.Quartz crystals that formed in the second and third stages contain all three types of fluid inclusions,with total homogenization temperatures of 216°C–339°C and salinities of 1.8–13.8 wt%NaCl equivalent for the second stage and homogenization temperatures of 195°C–321°C and salinities of 1.4–13.3 wt%NaCl equivalent for the third stage.In contrast,quartz crystals that formed in the fourth stage contains mainly A-type fluid inclusions,with minor occurrences of AC-type inclusions;these inclusions have homogenization temperatures of 106°C–287°C and salinities of 0.5–7.7 wt%NaCl equivalent.Gold in the ore-forming fluids may have changed from Au(HS)0 as the dominant species under acidic conditions and at relatively high temperatures and f O2 in the early stages,to Au(HS)2–under neutral-pH conditions at lower temperatures and f O2 in the later stages.The precipitation of gold and other metals is inferred to be caused by a combination of fluid immiscibility and water–rock interaction.
文摘A new expression for calculating suspended fine-sediment deposition rate is developed based on theoretic analysis and experiments. The resulting equation is applied to simulation of fine sediment deposition in the reclaimed land in the Hangzhou Bay, China. The hydrodynamic environment in this area is solved by use of a long wave model, which gives the 2D-velocity field and considers bathymetric changes due to fine sediment deposition. The expression is proved convenient to use in engineering practice, and the predicted deposition rate agrees with the annual data available from field measurements from the first year to the third year after the construction of the long groin as a reclaiming method.
基金supported by the National Natural Science Funds of China(No.11205155)Fundamental Research Funds for the Central Universities(WK2310000041)
文摘An accelerator storage ring needs clean ultrahigh vacuum.A TiZrV non-evaporable getter(NEG) film deposited on interior walls of the chamber can realize distributed pumping,effective vacuum improvement and reduced longitudinal pressure gradient.But accumulation of pollutants such as N_2 and O_2 will decrease the adsorption ability of the NEG,leading to a reduction of NEG lifetime.Therefore,an NEG thin film coated with a layer of Pd,which has high diffusion rate and absorption ability for H_2,can extend the service life of NEG and improve the pumping rate of H_2 as well.In this paper,with argon as discharge gas,a magnetron sputtering method is adopted to prepare TiZrV-Pd films in a long straight pipe.By SEM measurement,deposition rates of TiZrV-Pd films are analyzed under different deposition parameters,such as magnetic field strength,gas flow rate,discharge current,discharge voltage and working pressure.By comparing the experimental results with the simulation results based on Sigmund's theory,the Pd deposition rate C can be estimated by the sputtered depth.
文摘Filling high-aspect-ratio trenches with gold is a frequent requirement in the fabrication of X-ray optics as well as micro-electronic components and other fabrication processes. Conformal electrodeposition of gold in sub-micron-width silicon trenches with an aspect ratio greater than 35 over a grating area of several square centimeters is challenging and has not been described in the literature previously. A comparison of pulsed plating and constant current plating led to a gold electroplating protocol that reliably filled trenches for such structures.
基金This work is financially supported by the Special Fund for Foreign Mineral Resources Risk Exploration(201210B01600234).
文摘The Nyasirori gold deposit,located in the middle-western end of the Musoma-Mara Archean greenstone belt in Tanzania,is a tectonic altered rock type gold deposit controlled by shear tectonic zone.This work conducted high-precision ground magnetic measurements to delineate fault structures and favorable prospecting targets,utilized induced polarization(IP)intermediate gradient to roughly determine the distribution and extension of the tectonic altered zone and gold ore(mineralized)bodies,and further carried out IP sounding and magnetotelluric sounding to locate the tectonic altered zone and gold ore(mineralized)bodies.The anomalous gradient belt of the combination of positive and negative micromagnetic measurements reflects the detail of shallow surface tectonic alteration zone and gold mineralization body.Micromagnetic profile anomalies indicate the spatial location and occurrence of concealed tectonic alteration zone and gold(mineralized)ore bodies.Soil geochemical measurements indicate that the ore-forming element Au correlates well with As and Sb,and As and Sb anomalies have a good indication to gold orebodies.Based on the multi-source geological-geophysical-geochemical information of the Nyasirori gold deposit,this work established an integrated prospecting model and proposed a set of geophysical and geochemical methods for optimizing prospecting targets.
文摘A new kind of plasma technology with both high deposition rate and low dilution ratio was developed under the calculation and analysis of the arc flame characteristics of plasma arc,the kinematics behavior of powder and powder’s heating in the arc. Compared with normal plasma surfacing method, the idea using constricting nozzle with small orifice diameter, long plasma arc and increasing the distance from meeting point of the two beams of powder to workpiece, to achieve the goals of high deposition rate and low dilution ratio, was put forward here. In order to prove this idea, a set of experimental system was built up and obtained satisfied results including high deposition rate(more than 25 kg/h )and low dilution ratio(less than 5%). The success of this study offers a promising prospect for developing the powder plasma surface welding in China and may open a way to improve this technology further in efficiency and quality.
文摘Carbon nanotubes (CNTs) were synthesized through the catalytic decomposition of a ferrocene-xylene mixture in a horizontal chemical va- por deposition reactor. The deposition rate of CNTs along the axial direction was measured. The morphology of CNTs was observed by scan- ning electron microscopy (SEM) and transmission electron microscopy (TEM). The results showed that the deposition rate of CNTs along the axial direction first increased and later decreased, the position achieving the maximum deposition rate was influenced by the operating conditions. The morphologies of CNTs also changed along the axial direction.
文摘The southwestern Iran is one of the regions that are most prone to dust events.The objective of this study is the analysis of the spatial and temporal distributions of dust deposition rate as a key factor for finding the relative impact of the dust.First,the monthly mean aerosol optical thickness(AOT)from Moderate Resolution Imaging Spectroradiometer(MODIS)was analyzed and compared with the dust amount variations from ground deposition rate(GDR),and the results were further used to investigate the spatial and temporal distributions of dust events in southwestern Iran for the period between 2014 and 2015.Moving air mass trajectories,using the Hybrid Single-Particle Lagrangian Integrated Trajectory(HYSPLIT)model,were proven to be a discriminator of their local and regional origin.The results from GDR analysis produced a correlation coefficient between dust event history and deposition rates at dust magnitudes of>0.93 that is meaningful at the 95%confidence level.Furthermore,the deposition rates varied from 3 g/m2 per month in summer to 10 g/m2 per month in spring and gave insight into the transport direction of the dust.Within the same time series,AOT correspondences with MODIS on Terra in four aerosol thickness layers(clean,thin,thick,and strong thick)were shown in relation to each other.The deepest mixed layers were observed in spring and summer with a thickness of approximately 3500 m above ground level in the study area.Investigations of ground-based observations were correlated with the same variations for each aerosol thickness layer from MODIS images and they can be applied to discriminate layers of aeolian dust from layers of other aerosols.Together,dust distribution plots from AOT participated to enhance mass calculations and estimation deposition rates from the thick and strong thick aerosol thickness layers using the results from GDR.Despite all the advances of AOT,under certain circumstances,ground-based observations are better able to represent aerosol conditions over the study area,which were tested in southwestern Iran,even though the low number of observations is a commonly acknowledged drawback of GDR.
基金financial support provided by the Department of Geology and the National Centre of Excellence in Geology,University of Peshawar。
文摘Analysis of the anomalous magnetic mineral intensities and geochemistry for placer gold deposits are presented for those of the Attock area at the confluence of the Indus and Kabul rivers in northwestern Pakistan.Two grids covering an area of 10 x18 m2 and 8 x10 m2 were analyzed using a G-858 Cesium Vapor Magnetometer.The anomalous zones obtained were plotted on contour maps,2 D and 3 D magnetic intensity maps.Based on the magnetic anomalies,grid-1 of the study area was sampled at three different anomalous zones for geochemical analysis.These zones contain gold concentrations,ranging from 2.11 ppm to 6.109 ppm with an average of 4.01 ppm.Increase in gold concentration in the subsurface within the anomalous zones indicates that magnetometer survey followed by a geochemical analysis can potentially narrow down the gold-bearing anomalous zones.
文摘In order to understand the mechanism(s) of gold precipitation in the anorthosite-hosted Sangchon gold deposits in the Hadong area, Korea, chemical speciation and reaction path calculations were accomplished by geochemical modeling. The modeling consisted of three-step procedures: reaction with anorthosite, then the simple cooling of the reacted fluid, and finally the boiling of metalliferous fluid. The principal vein minerals of the Sangchon deposits consist of quartz, sericite, kaolinite, pyrite, galena, chalcopyrite, sphalerite and acanthite. The sulfide mineralization is typically zoned from pyrite (preferentially at vein margins) to galena and sphalerite (toward vein center). Electrum is intimately associated with pyrite ± chalcopyrite and sphalerite. By comparing the results of modeling with the observed mineral assemblages and paragenesis, the most appropriate evolution path of ore fluids was suggested as follow: reaction of a single fluid with anorthosite at 300℃, then the isobaric cooling of the fluid at temperatures from 250° to 100℃, and then the boiling and cooling of the fluid due to the decrease of pressure and temperature. Calculations also show that all of the observed alteration minerals formed due to fluid-anorthosite interaction at early period, whereas most of sulfides and electrum were precipitated mainly due to cooling. The abundance of gold in veins depends critically on the ratio of total base metals plus iron to sulfide in the aqueous phase, because gold is transported as Au(HS) 2 -whose solubility is very sensitive to the sulfide activity. Our results of geochemical modeling generally fit to the observed mineral assemblages and mineral composition, indicating the usefulness of numerical simulation for elucidating the genesis of gold deposits.
文摘In welding, so many factors contribute to good quality welds. The deposition rate is the rate of weld metal deposit at fusion zone during welding, which also is a key factors affecting the quality of welded joints. Too high or low deposition rate compromises the integrity of weld. This study was carried out with the aim of providing an approach for producing better weldments by optimizing and predicting deposition rate of low carbon steel using Response Surface Methodology (RSM). 30 sets of experiments were done, adopting the central composite experimental design. The tungsten inert gas welding equipment was used to produce the welded joints. Argon gas was supplied to the welding process to shield the weld from atmospheric interference. Mild steel coupons measuring 60 × 40 × 10 mm was used for the experiments. The results obtained show that the voltage and current have very strong influence on the deposition rate. The models developed possess a variance inflation factor of 1. And P-value is less than 0.05, indicating that the model is significant. The models also possessed a high goodness of fit with R2 (Coefficient of determination) values of 91%. The model produced numerically obtained optimal solution of current of 160.00 Amp, voltage of 20 volts and a gas flow rate of 17 L/min produces a welded material having deposition rate of 0.4637 kg/hr. This solution was selected by design expert as the optimal solution with a desirability value of 98.8%. A weld simulation using the optimum value obtained produced a weld with good quality.
文摘Based on X-ray diffraction,optical microscopy and scanning electron microscopy analysis of the Dachang gold ore,it is showed that the sulfide of ore is the main carrier minerals of gold. A majority of gold is embedded in pyrite and tetrahedrite as the form of inclusion and a small amount intergrowth with pyrite and gangue mineral,occasionally the presence is in form of monomer natural gold. The main factors which influence the recovery rate are sulfide mineral particle size,and the fine grained sulfide is beneficial for the dissociation and flotation of gold bearing minerals. The monomer dissociation degree of gold bearing minerals can reach91. 3%,when the grinding fineness is less than 0. 074 mm and grain level accounts as 80%. It is not conducive to the flotation of sulfide if the grinding fineness is low or high. It is difficult to completely dissociate the monomer if there is a small amount of pyrite and arsenopyrite in the ore. Therefore,before leaching the gold,it must conduct pretreatment to reach the ideal recovery rate of the gold,like roasting oxidation,pressure oxidation and biological oxidation. The fine microscopic gold has little influence on the gold recovery rate.
基金funded by the National Natural Science Foundation of China(41902099)the China Geological Survey Project(DD20230054)Fundamental Research Funds from the Institute of Mineral Resources and Chinese Academy of Geological Sciences(No.KK2215).
文摘The Xinlong gold deposit is located in Niyma County,Naqu area of Tibet and was discovered by the Institute of Mineral Resources,Chinese Academy of Geological Sciences through the 1∶50000 mineral geological survey.The ore bodies occur in the Zenong Group volcanic rocks in the middle section of the central Lhasa subterrane and are structurally controlled by the NNW-striking faults.Four ore bodies have been found,exhibiting cloddy,dense-sparse,disseminated,and breccia structures.The ore minerals are mainly tetrahedrite group minerals,and other ore minerals include pyrite,chalcopyrite,nevskite,bornite,anglesite,native gold,and silver-gold bearing selenide,etc.The types of alteration are dominated by silicification,as well as middle-and high-graded argillization.The alteration mineral assemblages contain quzrtz,pyrophyllite,and kaolinite.The Zaliela Formation volcanic rocks of Zenong Group are silicified by later hydrothermal fluid with vuggy quartz in some fractured zones.The middle-and high-graded argillization are characterized by pyrophyllitization and kaolinization.The Xinlong gold deposit shows great metallogenetic potentiality and has been revealed by 1∶10000 geological mapping,IP sounding,and trial trenching in the mining area.Combined with the regional metallogenic geological setting,we suppose that a potential epithermal gold belt probably exists in the middle of the Lhasa terrane.The discovery of the Xinlong gold deposit opens a new chapter for the gold prospecting in Northern Tibet.
基金funded by a Natural Science Foundation of Hebei Province(Grant No.D2020403019)the Natural Science Foundation of Hebei Province(Grant Nos.D2020403101 and D2019403041)+2 种基金the Science and Technology Project of Hebei Education Department(Grant No.ZD2020134)the National Natural Science Foundation of China(Grant Nos.41702094 and 41672070)the Science and Technology Innovation Team Project of Hebei GEO University(Grant No.KJCXTD-2021-02)。
文摘To shed light on the genesis of the Dongping deposit and reveal the behaviour of CO_(2),Au and other ore elements(e.g.,Cu,Fe,Zn,As,Sb,Co etc.)in ore-forming fluids,petrographic,microthermometric and synchrotron radiation X-ray fluorescence(SRXRF)analyses of fluid inclusions were conducted.The ore-forming fluid is characterized as an H_(2)O-CO_(2)-NaCl system with medium-high temperatures and low salinity.Four mineralization stages are identified,namely,feldsparquartz(stage 1);pyrite-white quartz(stage 2);sulfide-smoky grey quartz(stage 3);and carbonate-quartz(stage 4).Three types of inclusions were distinguished,based on fluid composition,phase assemblages and mode of homogenization.Type A:H_(2)O-rich fluid inclusions show 2 phases(liquid H_(2)O(LH_(2)O)+vapour H_(2)O(VH_(2)O))at room temperature and homogenize to the liquid phase.Type B:H_(2)O-CO_(2)fluid inclusions contain 2–3 phases(liquid H_(2)O(LH_(2)O)+vapour CO_(2)(VCO_(2));liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2)));liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2))+vapour CO_(2)(VCO_(2)))at room temperature and homogenized to the liquid H_(2)O phase.Type C:H_(2)O-CO_(2)fluid inclusions show 2 phases(liquid H_(2)O(LH_(2)O)+liquid CO_(2)(LCO_(2))at room temperature and homogenize to a critical state.CO_(2)is clearly more enriched in the fluid inclusions of stages 2 and 3 than in stage 1.Stage 1 is dominated by type A(H_(2)O-rich)inclusions with homogenization temperatures(Th)of 220–359℃and salinities of 1.1–3.1 wt%NaCl equivalent.Type B(CO_(2)-rich)inclusions gradually increase in stages 2 and 3.The Th range of type B inclusions in stage 2 is 241–397℃with salinities of 2.2–6.9 wt%NaCl equivalent;the Th range of type A inclusions is 217–373℃with salinities of 1.2–8.1 wt%NaCl equivalent.The Th range of type B inclusions in stage 3 is 215–361℃with salinities of 2.9–6.1 wt%NaCl equivalent;the range of type A inclusions is 158–351℃with a salinity of 0.7–5.5 wt%NaCl equivalent.Stage 4 is characterized by type A with Th of 151–250℃and salinities of 0.9–8.3 wt%NaCl equivalent.The mapping results show that elements As,Te and Sb are more concentrated in vapour CO_(2)than in liquid H_(2)O at room temperature,which suggests that vapour components are more able to transport elements when phase separation occurs.The SRXRF quantitative results show that Au,Cl,S and some other metals are obviously more enriched in the fluid inclusions of stages 2 and 3 than those in stage 1.Additionally,the contents of S in stages 1–3 are much lower than those of Cl,which suggests that gold might migrate mainly in the form of a gold-chloride complex.Au is more enriched in type B fluid inclusions than in type A fluid inclusions,which suggests that the enrichment and migration of gold are closely related to CO_(2)and CO_(2)plays a critical role in the migration and enrichment of gold.The trace elements in the fluid have a similar change trend to those in the Yanshanian syenogranite distributed in the southeastern part of the mining area,which may provide some evidence for an intrusion-related genesis for the Dongping gold deposit.
基金co-founded by the National Natural Science Foundation of China(42002090,41930428)National Key Research and Development Program of China(No.2018YFC0604200)+3 种基金Open Research Fund Program of State Key Laboratory of Nuclear Resources and Environment,East China University of Technology(No.NRE1915)Open Research Fund Program of Jiangxi Engineering Laboratory on Radioactive Geoscience and Big Data Technology(JELRGBDT202006)International Geoscience Programme(IGCP675)Jiangxi province graduate student innovation special fund project(YC2019-S271,DHYC-202001)。
文摘Hydrothermal alteration with bleaching of host rocks is the most important prospecting indicator for gold deposits in the Jiangnan Orogen Belt.The alteration has been identified as pre-ore carbonate(siderite)-sericitization and the Fe of siderite in the alteration zone is derived from the host rocks rather than fluids.In addition,such alteration decreases in intensity and width with depth and gold mineralization also occur in the non-bleached rocks,casting doubt on the reliability of the prospecting indicator.Detailed petrographic work and SEM analysis on the Wangu deposit indicate that there are two types of siderites,i.e.,Sd1 and Sd2.Among them,Sd1 grains are relatively small and distributed along the planes of unaltered host rocks,while Sd2 grains,only occurring in the altered slates,are commonly larger.Both types of siderites were altered by auriferous fluids,producing porous cores and minerals such as pyrite,quartz,and ankerite.Compared with unaltered parts,the altered parts have lower Fe,but higher U,Pb,and REE.In addition,Sd1 and Sd2 are similar in Mn,Na,V,and Sr concentrations but different in Fe and Mg.The occurrence and geochemical compositions of both siderites indicate that Sd1 could be transformed into Sd2 by pre-mineralization alteration through dissolution-reprecipitation.Chlorite is another important Fe-bearing mineral in the host rocks,and EPMA analysis suggests that it is ripidolite with relatively high Fe contents.Consequently,chlorite can also provide Fe to form the pre-ore carbonate(siderite)-sericitization.Geochemical modeling demonstrates that both ripidolite and siderite can result in sulfidation and therefore gold precipitation.As a result,this study demonstrates that pre-ore alteration with characterized bleaching is not a prerequisite for gold mineralization despite of its prominent features.Due to the presence of Fe-bearing Sd1 and chlorite,gold mineralization could still occur through sulfidation in the unaltered rocks.
基金financially supported by China Geological Survey Project(Grant No.DD20220971)。
文摘Located along the southern part of the West Qinling orogenic belt,the Yangshan gold deposit is one of the largest in China.The major gold ores of Yangshan are disseminated in metasedimentary host rocks with minor native gold amounts in stibnite-gold quartz veins.Pyrite and arsenopyrite are the major Au-bearing minerals.Hydrothermal muscovite from gold-bearing quartz veins was dated using the in situ Rb-Sr method to determine the formation age of the Yangshan gold deposit.The Rb-Sr isochron date of the muscovite yielded 210.1±5.6 Ma(MSWD=1.2).This date is near the lower end of the period of the mineralized granitic dykes(210.49-213.10 Ma).Two stages of gold enriching process are recognized in the gold-bearing pyrite:the first is incorporated with the Co,Cu,As,Ni enrichment;and the second is accompanied by Bi,Co,Ni,Pb,Cu,Sb concentration.The in-situ sulfur isotopic values of pyrites show a restrictedΔ34s range of-1.43‰to 2.86‰with a mean value of 0.43‰.Trace-element mapping and in-situ sulfur isotopic analysis of pyrite suggest that the sulfur deposits are likely derived from a magmatic source and likely assimilated by sulfur from the sedimentary bedrock.Thus,magmatism plays a critical role in the formation of the Yangshan gold deposit.
基金Support for this study was received from the China National Ph.D.Foundations。
文摘By studying both the microscopic physical and chemical typomorphic characteristics of typical mineral pyrite samples associated with representative gold deposits on the north-central margin of the North China Platform,this paper seeks to identify macroscopic metallogenic mechanisms of gold deposits and to reveal the formation mechanism of lattice gold in pyrite.Typomorphic characteristics of pyrite reveal that pyrite grain size has a negative correlation with gold content.Cubic pyrite,as the dominant crystal form,contains more gold than pentagonal dodecahedral pyrite.Both pyrite crystal forms and chemical compositions indicate that the replacement style of gold deposit formed in a low saturability,low sulfur fugacity,and at temperatures either much higher or much lower than its best forming temperature;comparatively,that of the quartz vein style of gold deposit occurred under conditions with the best temperature,rich in sulfur,and with high sulfur fugacity.The Au/Ag ratios of the pyrites show that both the replacement and quartz vein styles of deposits are mesothermal and hypothermal,while the Co/Ni ratios of the pyrites indicate that the quartz vein style is of magmatic-hydrothermal origin.The X-ray diffraction intensity of pyrite rich in gold is lower than that of pyrite poor in gold at the quartz vein style.In general,with an increase in gold content in pyrite,the total sum intensityΣI decreases.The pyroelectricity coefficient has a negative correlation trend with the values of(Co+Ni+Se+Te)-As and(Co+Ni+Se+Te)/As.The pyrite pyroelectricity of the replacement style is N-type,indicating that it formed under low sulfur fugacity,while that of the quartz vein style is a mixture of P-N types,indicating that it formed under high sulfur fugacity.On the pyroelectricity-temperature diagram,pyrite of the replacement style is mainly distributed between 200 and 270°C,while that of the quartz vein style varies between 90–118 and274–386°C,demonstrating a multistage forming process.In contrast to previous researchers'conclusions,the authors confirm the existence of lattice gold in pyrites through the use of an electron paramagnetic resonance(EPR)test.Au in the form of Au~+,entering pyrite as an isomorph and producing electron–hole centers,makes the centers produce spin resonance absorption and results in EPR absorption peak II.The intensity of auriferous pyrite absorption peak II has certain direct positive correlations with pyrite gold content.The#I and#III absorption peaks of pyrites possibly result from the existence of Ni^(2+)and/or Cu^(2+).γ1,γ2,andγ3 are the strongest and most typical absorption peaks of the infrared spectra of the pyrites.Generally,with the increase in gold content in the pyrite samples,γ1,γ2,andγ3 tend to shift to higher wavenumbers,and the gold content in the pyrite samples has a positive correlation with their relative absorbance.
基金supported by the National Natural Science Fund of China (41962008)the Talent Team Program of Guizhou Science and Technology Fund (Qianke Pingtairen Caixintang[2021]007)+3 种基金the Geological Exploration Fund Project of Guizhou Province (520000214TLCOG7DGTDRG)the National Natural Science Foundation of China (U1812402)Scientific Research Project of Hubei Geological Bureau (KJ2022-21)the Graduate Research Fund of Guizhou Province (YJSCXJH [2020] 095)。
文摘Southwestern Guizhou province is one of China’s most important distribution areas of Carlin-type gold deposits. The Nibao deposit is a typical gold deposit in southwestern Guizhou. To elucidate the genesis of the Nibao gold deposit, establish a metallogenic model, and guide prospecting prediction, we systematically collected previously reported geological, geochemical, and dating data and discussed the genesis of the Nibao gold deposit,based on which we proposed the metallogenic model.Earlier works show that the Nibao anticline, F1 fault, and its hanging wall dragged anticline(Erlongqiangbao anticline) were formed before or simultaneously with gold mineralization, while F2, F3, and F4 faults postdate gold mineralization. Regional geophysical data showed extensive low resistivity anomaly areas near the SBT(the product of tectonic slippage and hydrothermal alteration)between the P2/P3 and the strata of the Longtan Formation in the SSE direction of Nibao anticline in the lower plate of F1 and hanging wall dragged anticline(Erlongqiangbao anticline), and the anomaly areas are distributed within the influence range of anticlines. Simultaneously, soil and structural geochemistry show that F1, Nibao anticline,Erlongqiangbao anticline, and their transition areas all show good metallogenic elements(Au, As, and S) assemblage anomalies, with good metallogenic space and prospecting possibilities. There are five main hypotheses about the source of ore-forming fluids and Au in the Nibao gold deposit:(1) related to the Emeishan mantle plume activity;(2) source from the Emeishan basalt;(3) metamorphic fluid mineralization;(4) basin fluid mineralization;(5) related to deep concealed magmatic rocks;of these, the mainstream understanding is the fifth speculation. It is acknowledged that the ore-forming fluids are hydrothermal fluids with medium–low temperature, high pressure, medium–low salinity, low density, low oxygen fugacity, weak acidity, weak reduction, and rich in CO_(2)and CH_(4). The fluid pressure is 2–96.54 MPa, corresponding to depths of 0.23–3.64 km. The dating results show that the metallogenic age is ~141 Ma, the extensional tectonic environment related to the westward subduction of the Pacific Plate. Based on the above explanation, the genetic model related to deep concealed magmatic rocks of the Nibao gold deposit is established, and favorable prospecting areas are outlined;this is of great significance for regional mineral exploration and studying the genesis of gold deposits.
