The characterization of the relationships between mineralization and hydrothermal alteration is an essential element in understanding gold deposits. In south-west Burkina Faso, the Napélépéra mineralisa...The characterization of the relationships between mineralization and hydrothermal alteration is an essential element in understanding gold deposits. In south-west Burkina Faso, the Napélépéra mineralisation, the mobility of chemical elements and alteration-mineralization relationships were studied by means of selected core drilling and geochemical analyses using ICP-MS (Inductively Coupled Plasma Mass Spectrometry) and ICP-AES (Inductively coupled plasma atomic emission spectroscopy). The mineralised granodiorite is grey porphyroid with quartz, plagioclase, biotite and amphibole. It is metaluminous and located in the tholeiitic series. The Na<sub>2</sub>O + CaO versus Fe<sub>2</sub>O<sub>3</sub> + MgO alteration diagram divides the samples according to alteration dominance. Chloritisation and carbonation are the main alterations. There is a relationship between gold mineralisation at Napélépéra and alteration, and the paragenesis of gold + pyrite ± carbonate ± silica ± sericite is the main characteristic. Carbonation is the result of fluid input in the shear corridor of the mineralised zone. The mass balance of comparative metals in the proximal and distal zones of the mineralisation shows the absence of metals, while As, Hg, Ag and Bi are strongly enriched from the distal zone to the mineralised zone. The oxides associated with the mineralisation are mainly NaO, SrO and CaO.展开更多
1 Introduction 1The Sanjiang region in SE Tibet Plateau and NW Yunnan is known to have formed by amalgamation of Gongwanaderived continental blocks and arc terranes as a result of oceanic subduction followed by
A systematic study combining U-Pb zircon dating,lithogeochemical and Sr-Nd isotopic analyses was carried out upon the Xinping granodiorite porphyry in the Dayaoshan metallogenic belt to understand its petrogenesis and...A systematic study combining U-Pb zircon dating,lithogeochemical and Sr-Nd isotopic analyses was carried out upon the Xinping granodiorite porphyry in the Dayaoshan metallogenic belt to understand its petrogenesis and tectonic significance.LA-ICP-MS U-Pb zircon dating yielded a 442.7±5.8 Ma age,indicating that the granodiorite porphyry was emplaced during the Llandovery Silurian of the Early Paleozoic.The granodiorite porphyry shares the same geochemical characteristics such as Eu negative anomaly as other syn-tectonic granite plutons in the region,including the granodiorite porphyry in Dawangding and granite porphyries in the Dali Cu-Mo deposit and Longtoushang old deposit,indicating a similar magma evolution process.The Xinping granodiorite porphyry has high contents of SiO2(67.871.8%)and K2O(1.78-3.42%)and is metaluminous-peraluminous with A/CNK ratios ranging from 0.97 to 1.06,indicative of high-potassium calc-alkaline to calc-alkaline affinity.It is a I-type granite enriched in large ion lithophile elements Rb,Sr,while depleted in Ba and high field-strength element Nb.Tectonically,a collision between the Yunkai Block from the south and the Guangxi Yunnan-North Vietnam Block from the north during the Early Paleozoic was followed by uplifting of the Dayaoshan terrane.The Xinping granodiorite porphyry was likely emplaced during the collision.Sr-Nd isotopic analyses show that the granodiorite porphyry has initial 87Sr/86Sr ratios(Isr)of 0.7080-0.7104,εNd(t)range from-0.08 to-4.09,and t2DM between 1.19 and 1.51 Ga,well within the north-east low-value zone of the Cathaysia block,indicating a Paleoproterozoic Cathaysia basement source and an involvement of under plating mantle magma.Field observations,geochronological data,and 3D spatial distribution all lead to the conclusion that the Early Paleozoic Xinping granodiorite porphyry does not have any metallogenic and temporal relationships with the Xinping gold deposit(which has a Jurassic-Early Cretaceous age based on previous studies)but a close metallogenic relation to W-Mo mineralization.展开更多
Zircon U-Pb geochronology and geochemistry of the granodiorites in Xiarihamu Cu-Ni mining area are studied to determine the formation age,genesis and tectonic setting. The results show that the granodiorites formed in...Zircon U-Pb geochronology and geochemistry of the granodiorites in Xiarihamu Cu-Ni mining area are studied to determine the formation age,genesis and tectonic setting. The results show that the granodiorites formed in the Middle Triassic with weighted average age of 242 ± 1 Ma. The granodiorites comprise of SiO_2 of 61. 34%--62. 54%,Al_2 O_3 of 16. 46%--16. 87%,MgO of 2. 37%--2. 66%,( Na_2 O + K_2 O) of 5. 39%--5. 74%with the Na2 O/K_2 O of 1. 46--1. 88,Mg~# of 47. 03--48. 04,and show metaluminous characteristics with A/CNK of 0. 94--0. 96,belonging to calc-alkaline I-type granites geochemically. The light and heavy rare earth elements in the rocks are distinctly fractionated and have " right-inclined" distribution patterns with weak negative Eu anomalies( δEu = 0. 84--0. 91). Moreover,these samples show enrichments in LILEs( e. g.,Rb,Ba,K and Sr),especially in Sr [( 343--452) × 10^(-6)],and obvious depletions in HFSEs( e. g.,Nb,Ta,Ti and P),indicating geochemical characteristics similar to subduction-related magmatic rocks. According to the regional tectonic evolution,the Xiarihamu granodiorites were emplaced under an Andean-type active continental margin environment in the early Indosinian,possessing a crust-mantle mixing origin.展开更多
A large number of granitoids constitutes a giant granitic belt trending EW in the Inner Mongolia.As a representative of those intrusions,the Damiao granitoid in Siziwangqi area may serve as a natural laboratory for th...A large number of granitoids constitutes a giant granitic belt trending EW in the Inner Mongolia.As a representative of those intrusions,the Damiao granitoid in Siziwangqi area may serve as a natural laboratory for the study of genesis of granite and evolution of crust.It is mainly composed of mid-coarse grained granodiorite with abundant展开更多
A large area of Late Paleozoic intrusions occursalong the Kalamaili fault in North Xinjiang,which is divided into I-type and A-type granite(Liu et al.,2013),and are the ideal objects for revealing the geological evolu...A large area of Late Paleozoic intrusions occursalong the Kalamaili fault in North Xinjiang,which is divided into I-type and A-type granite(Liu et al.,2013),and are the ideal objects for revealing the geological evolution of this region.However,the study of the granodioritic pluton in East Junggar is particularly weak.展开更多
Magmatic microgranular enclaves(MMEs)are widely developed in the Shaocunwu granodiorite at the northeast margin of the eastern Jiangnan orogenic belt.Field geology showed that the MMEs occur as irregular ellipsoids ne...Magmatic microgranular enclaves(MMEs)are widely developed in the Shaocunwu granodiorite at the northeast margin of the eastern Jiangnan orogenic belt.Field geology showed that the MMEs occur as irregular ellipsoids near the edge of the intrusion,and consist of diorite,dominantly composed of amphibole,biotite,and plagioclase grains,with minor acicular apatite.Zircon U-Pb dating showed the ages of the host granodiorites and MMEs are 145.9±1.1 Ma and 145.6±2.5 Ma,respectively,indicating both originated during coeval late Jurassic magmatism.Whole-rock geochemical results show that the host granodiorite and MMEs have similar rare earth and trace element partition curves in spider grams,and similar 87Sr/86Sr,and 147Nd/144Nd isotope ratios,and their zircon 177Hf/176Hf isotopic ratios are similar.Geochemical studies indicate that both the host granodiorite and MMEs formed by mixing of coeval magma.Zircon Ti thermometers and oxygen fugacity of the host granodiorite and the MMEs show high oxygen fugacity,similar to that of W-Cu(Mo)mineralized granitoids in the eastern Jiangnan orogenic belt.A similar magma mixing process was probably one of the mechanisms that generated the W-Cu(Mo)fertile melts.展开更多
1 Introduction Qilian Block is located in between the South China Craton and the North China Craton and the Tarim Craton(Fig.1a),which is one of the key area to study the tectonic evolution of China.The Phanerozoic te...1 Introduction Qilian Block is located in between the South China Craton and the North China Craton and the Tarim Craton(Fig.1a),which is one of the key area to study the tectonic evolution of China.The Phanerozoic tectonic展开更多
The Wulonggou area located in the Eastern Kunlun Orogen in NW China is characterized by extensive granitoid magmatism,ductile faulting and orogenic gold mineralization.The Huanglonggou granodiorite is cut by an orogen...The Wulonggou area located in the Eastern Kunlun Orogen in NW China is characterized by extensive granitoid magmatism,ductile faulting and orogenic gold mineralization.The Huanglonggou granodiorite is cut by an orogenic gold-bearing fault.This study investigated the major and trace-element compositions,zircon U-Pb dates and zircon Hf isotopic compositions of the Huanglonggou granodiorite.One Huanglonggou granodiorite sample yielded a weighted mean U-Pb zircon age of^221 Ma(Carnian).The Carnian granodiorite is metaluminous,with high alkalis contents of 6.37%--8.86%,high Al_2O_3contents of 15.41%--16.19%,high Sr contents of(426--475)×10^(-6),relatively high Sr/Y ratios,high(La/Yb)_Nvalues and low HREE,suggesting an adakite type high-Si O_2granite.The Huanglonggou granodiorite sample has zirconε_(Hf)(t)values ranging from-4.4 to+1.1.These Hf isotopic data suggest that the Carnian granodiorite was likely derived from the partial melting of subducted Paleo-Tethys oceanic slab.It is suggested that the Late Triassic granodiorite was emplaced during the northward subduction of Paleo-Tethys oceanic slab.Orogenic gold mineralization in the Wulonggou area formed after the emplacement of the Late Triassic intrusive rocks.展开更多
Post-collision felsic rocks in Southeastern Yunnan province contain granodiorites. U-Pb zircon ages, geochemical data and Sr-Nd isotopic data for these rocks are reported in the present paper. Laser ablation inductive...Post-collision felsic rocks in Southeastern Yunnan province contain granodiorites. U-Pb zircon ages, geochemical data and Sr-Nd isotopic data for these rocks are reported in the present paper. Laser ablation inductively coupled plasma mass spectrometry U-Pb zircon analyses yielded consistent age 252.5 ± 1.0 Ma for one sample of the felsic rocks. The granodiorites were characterized by variational and high (87Sr/86Sr)i, ranging from 0.7223 to 0.7236 and very low εNd (t) values from –29.1 to –30.4. In addition, these rocks are characterized by slight Eu negative anomalies, Nb, Ta, Ti and Sr negative anomalies on primitive mantle normalization spider. Geochemical and isotopic characteristics suggest that these rocks were derived from an enriched crust source. The granodiorites resulted from the fractionation of potassium feldspar, plagioclase and ilmenite or rutile. However, the granodiorites were unaffected by visible crustal contamination during ascent. As a result, the granodiorites may have been formed due to partial melting of crust-derived sedimentary rocks beneath southeastern Yunnan province, southern China.展开更多
The mining company Sama Nickel-CI during its exploration activities in the Bounta area (Biankouma department, western Côte d’Ivoire) identified rocks with magmatic and metamorphic characteristics of felsic t...The mining company Sama Nickel-CI during its exploration activities in the Bounta area (Biankouma department, western Côte d’Ivoire) identified rocks with magmatic and metamorphic characteristics of felsic to mafic compositions mineralized in sulfide but unknown in the region. Thus, the petrographic characterization of these rocks of Bounta as well as the sulfides they contain, was carried out from macroscopic to microscopic observations. Petrographic analysis of these rocks has shown that these rocks are trondhjemite, tonalite and granodiorite (TTG) suites, composed of the main minerals (quartz, plagioclase, orthopyroxene, amphibole, feldspar) and accessory minerals (biotite, garnet) with magmatic textures supplanted by metamorphic textures. They were set up by fractional crystallization and would be products of Archean crustal anatexis formed from the partial melting of basaltic protocrust during the Liberian orogeny. The Bounta’s series of trondhjemite, tonalite and granodiorite (TTG) contain speckles of sulfide (pyrite and pyrrhotite) which are disseminated in places and are relatively abundant, as well as iron oxides (magnetite) which are of low proportion.展开更多
The 7200-m-deep Well Tacan 1 in the central Tarim Basin is the deepest in China. Purplish gray medium-grained granodiorite containing dark gray fine-grained diorite xenolith is revealed at the base of the well (7169―...The 7200-m-deep Well Tacan 1 in the central Tarim Basin is the deepest in China. Purplish gray medium-grained granodiorite containing dark gray fine-grained diorite xenolith is revealed at the base of the well (7169―7200 m), and they are results of the Jinning magmatic activities. Trace-element geochemistry and REE profiles of both rock types are similar, indicating that they are calc-alkaline series I-type granitoid. Proxies of diorite signify the development of a magmatic arc due to subduction at ca. 1200 Ma. The granodiorite was formed before 890―932 Ma. However, more study is needed to clarify if the arc diorite represents a ca. 300 Ma extension of the subduction or a reactivation during the orogenic collision event at ca. 900 Ma.展开更多
Mixing-fractional crystallization composite processes generate 6 complex patterns,which aresynthesized into 3 models,on C<sup>2</sup><sub>1</sub>/C<sup>3</sup><sub>1</sub&g...Mixing-fractional crystallization composite processes generate 6 complex patterns,which aresynthesized into 3 models,on C<sup>2</sup><sub>1</sub>/C<sup>3</sup><sub>1</sub>-C<sup>1</sup><sub>1</sub>/C<sup>3</sup><sub>1</sub> ratio correlation plots of trace eleroents E<sub>1</sub>,E<sub>2</sub>,E<sub>3</sub> according totheir relative incompatibility.Three of the six effects are clearly displayed on ratio-ratio correlation plots oftrace elements in the Kalaan granodiorite pluton,indicative of a source mixing-fractional crystallization compositeprocess.The overlying lithospheric mantle was modified by the subduction of oceanic plate during Palaeozoic.The incompatibility order of the 7 concerned trace elements is D<sub>Ta</sub>【D<sub>Th</sub>【D<sub>Hf</sub>【D<sub>Zr</sub>【D<sub>Nb</sub>≌D<sub>La</sub>【D<sub>Y</sub>.展开更多
This paper report paleomagnetic data from late Cretaceous diorite dykes that sub-vertically intrude granodiorites in the eastern Gangdese belt near the city of Lhasa.Our research goals are to provide further constrain...This paper report paleomagnetic data from late Cretaceous diorite dykes that sub-vertically intrude granodiorites in the eastern Gangdese belt near the city of Lhasa.Our research goals are to provide further constraints on pre-collisional structure of the southern margin of Asia and the onset of the India-Asia collision.Magnetite is identified as the main magnetic carrier in our study.The magnetite shows no evidence of metamorphism or alteration as determined from optical and scanning electron microscope observations.A strong mineral orientation is revealed by anisotropy of magnetic susceptibility analysis both for the intruded dykes and the country rocks.The authors interpret this AMS fabric to have formed during intrusion rather than deformation.Fifteen of 23 sites yield acceptable site mean characteristic remanences with dual polarities.A scatter analysis of the virtual geomagnetic poles suggests that the mean result adequately averaged paleosecular variation.The paleomagnetic pole from the Gangdese dykes yields a paleolatitude of 14.3°N±5.8°N for the southern margin of Asia near Lhasa.The paleolatitude corresponds to an in-between position of the Lhasa terrane during about 130‒60 Ma.Furthermore,the mean declination of the characteristic remanent magnetization reveals a significant counterclockwise rotation of 18°±9°for the sampling location since about 83 Ma.In the light of tectonic setting of the dykes,the strike of the southern margin of Asia near Lhasa is restored to trend approximately about 310°,which is compatible with the hypothesis that the southern margin of Eurasia had a quasi-linear structure prior to its collision with India.展开更多
The Daheishan supergiant porphyry molybdenum deposit(also referred to as the Daheishan deposit)is the second largest molybdenum deposit in Asia and ranks fifth among the top seven molybdenum deposits globally with tot...The Daheishan supergiant porphyry molybdenum deposit(also referred to as the Daheishan deposit)is the second largest molybdenum deposit in Asia and ranks fifth among the top seven molybdenum deposits globally with total molybdenum reserves of 1.65 billion tons,an average molybdenum ore grade of 0.081%,and molybdenum resources of 1.09 million tons.The main ore body is housed in the granodiorite porphyry plutons and their surrounding inequigranular granodiorite plutons,with high-grade ores largely located in the ore-bearing granodiorite porphyries in the middle-upper part of the porphyry plutons.Specifically,it appears as an ore pipe with a large upper part and a small lower part,measuring about 1700 m in length and width,extending for about 500 m vertically,and covering an area of 2.3 km^(2).Mineralogically,the main ore body consists of molybdenite,chalcopyrite,and sphalerite horizontally from its center outward and exhibits molybdenite,azurite,and pyrite vertically from top to bottom.The primary ore minerals include pyrite and molybdenite,and the secondary ore minerals include sphalerite,chalcopyrite,tetrahedrite,and scheelite,with average grades of molybdenum,copper,sulfur,gallium,and rhenium being 0.081%,0.033%,1.67%,0.001%,and 0.0012%,respectively.The ore-forming fluids of the Daheishan deposit originated as the CO_(2)-H_(2)O-NaCl multiphase magmatic fluid system,rich in CO_(2)and bearing minor amounts of CH4,N2,and H2S,and later mixed with meteoric precipitation.In various mineralization stages,the ore-forming fluids had homogenization temperatures of>420℃‒400℃,360℃‒350℃,340℃‒230℃,220℃‒210℃,and 180℃‒160℃and salinities of>41.05%‒9.8%NaCleqv,38.16%‒4.48%NaCleqv,35.78%‒4.49%NaCleqv,7.43%NaCleqv,and 7.8%‒9.5%NaCleqv,respectively.The mineralization of the Daheishan deposit occurred at 186‒167 Ma.The granites closely related to the mineralization include granodiorites(granodiorite porphyries)and monzogranites(monzogranite porphyries),which were mineralized after magmatic evolution(189‒167 Ma).Moreover,these mineralization-related granites exhibit low initial strontium content and high initial neodymium content,indicating that these granites underwent crust-mantle mixing.The Daheishan deposit formed during the Early-Middle Jurassic,during which basaltic magma underplating induced the lower-crust melting,leading to the formation of magma chambers.After the fractional crystallization of magmas,ore-bearing fluids formed.As the temperature and pressure decreased,the ore-bearing fluids boiled drops while ascending,leading to massive unloading of metal elements.Consequently,brecciated and veinlet-disseminated ore bodies formed.展开更多
The Truong Son Fold Belt,located at the northeastern margin of the Indochina Block,is considered to be tectonically linked to the subduction of the Paleotethys Ocean and subsequent collision.Sepon is one of the most i...The Truong Son Fold Belt,located at the northeastern margin of the Indochina Block,is considered to be tectonically linked to the subduction of the Paleotethys Ocean and subsequent collision.Sepon is one of the most important super large deposits of the Truong Son Fold Belt.Our LA-ICP-MS zircon U-Pb dating results show that granodiorite porphyry samples from the Sepon deposit have ages of 302.1-4-2.9 Ma, which is a crucial phase for magmatic-tectonical activities from the Late Carboniferous to Early Permian and has avital influence on the mineralization of copper and gold.Zircon from granodiorite porphyry yields εHf (t)values of 4.32 to 9.64,and TDM2 has an average age of 914 Ma,suggesting that the source of the granodiorite porphyry in the region were mainly mantle components but underwent mixing and contamination of crust materials.The Ce^4+/Ce^3+ value of zircon in the granodiorite porphyry varys greatly from 2.4 to 1438.29,which shows magma mixing might occur.Considering the characteristics of trace elements in the zircon and the whole rock geochemical characteristics of intrusion rocks as well as the characteristics of regional volcanic-sedimentary association,it is indicated that the tectonic setting may be the continental arc environment.The Sepon Au-Cu deposit is derived from emplacement of calc-alkaline intermediate-acid magma with coming from deep sources in the subduction process of the Paleotethys Ocean,forming porphyry Mo-Cu,skam Cu-Au mineralization and a hydrothermal sedimentary-hosted Au mineralization in the wall rocks.展开更多
Zircons from granodiorite and biotite granite in the Yeniutan granitic intrusion in the western North Qilian Mountains yielded a weighted mean 206Pb/238U apparent age of 460±3 Ma, suggesting that the intrusion or...Zircons from granodiorite and biotite granite in the Yeniutan granitic intrusion in the western North Qilian Mountains yielded a weighted mean 206Pb/238U apparent age of 460±3 Ma, suggesting that the intrusion originated during the late stage of plate subduction. Its related Ta’ergou and Xiaoliugou deposits are two of the few large tungsten deposits formed in the plate subduction environment in the world. The U-Pb dating of the zircons from the biotite granite gave a discordant lower intercept age of 183±4 Ma, which implies that the Yanshanian event was probably superimposed on the North Qilian region.展开更多
The Gabal Marwa area is located in the southeastern part of Sinai,Egypt.It comprises gneisses and migmatites,granodiorites and monzogranites.Field,petrographic,mineralogic and chemical investigations indicated that th...The Gabal Marwa area is located in the southeastern part of Sinai,Egypt.It comprises gneisses and migmatites,granodiorites and monzogranites.Field,petrographic,mineralogic and chemical investigations indicated that the Gabal Marwa granites are classified as granodiorites and monzogranites.The monzogranites constitute the most predominant rock unit exposed in the study area.They have been subjected to hydrothermal alterations,especially along the shear zones.Sericitization,desilicification,nametasomatism and development of spotty or dendritic manganese oxides are the most pronounced alteration features.These alterations resulted in the increase of TiO2,Al2O3,FeOt,MnO,CaO,MgO,Na2O,K2O and Cr,Zr,Rb,Y and Sr and the decrease of SiO2,P2O5,Ni,Zn,Ba and Nb.Radiometric studies indicated that the altered granites belong to high thorium,high uranium granites.The U,Th,U and Th,Th/U,Th and U-K variation diagrams suggested that magmatic processes controlled the distribution of these elements but the effect of hydrothermal alteration processes were clearly distinct.The Scanning Electron Microscope and X-ray Diffraction analyses indicated that the most important radioactive minerals include uranothorite,thorite,zircon,monazite and samarskite.Cinnabar and Mn minerals were also found.From the U,Th,Ra and K activity concentrations obtained for all the studied granitic samples,radium equivalent activity(Raeq),external hazard index(Hex),and internal hazard index(Hin),were calculated to assess the radiation hazard to human beings living in dwellings made of the studied granites.Altered monzogranites have radioactivity above the proposed acceptable level and,therefore,caution must be taken when these granites are used as building materials.展开更多
Granitoids between the central and western arm of Ramagiri schist belt in its central part, are broadly classified into the migmatite gneiss, grey granodiorite and pink monzogranite, based on field characteristics and...Granitoids between the central and western arm of Ramagiri schist belt in its central part, are broadly classified into the migmatite gneiss, grey granodiorite and pink monzogranite, based on field characteristics and petrographic features. These granitoids belong to the Tonalite-Granodiorite-Monzogranite (TGM) suite of PGC-II. All the samples are fresh as per the CIA values, PC1-PC2 binary plot and MFW ternary plot. The granodiorites occupy the expected field in the normative IUGS, TAS, and R<sub>1</sub>-R<sub>2</sub> classification diagrams, but the monzogranites occupy the monzogranite field in the normative IUGS classification diagram and granite to alkali granite field in the rest. The granodiorites exhibit both ferroan to magnesian, alkali-calcic nature with metaluminous I type features and falls in the calc-alkaline to high K calc-alkaline series. They have high ΣREE (an average 327.905 ppm) content, and show LREE enrichment ((La/Sm)<sub>N</sub> = 3.1 - 6.8) with enriched but relatively flat HREE ((Gd/Yb)<sub>N</sub> = 1.75 - 5.26) patterns and weak negative to positive Eu anomaly (Eu/Eu* = 0.62 - 1.18). The monzogranites, on the other hand, are peraluminous, alkalic, ferroan, high K calc-alkaline, S-type granites, exhibiting relatively low ΣREE (an average 118.693 ppm) contents, strongly fractionated REE patterns with highly enriched LREE ((La/Sm)<sub>N</sub> =1.74 - 9.76), depleted HREE ((Gd/Yb)<sub>N</sub> = 0.43 - 2.21) patterns having concave upward shape, and strong negative Eu anomaly (Eu/Eu* = 0.23 - 0.89). Geothermobarometry revealed the average emplacement temperature and pressure of the granodiorites and monzogranites as 812.5℃, 8.14 ± 0.6 kbar and 775℃, 3.14 kbar, respectively. Based, on the observations, it can be concluded that the granodiorites have formed in volcanic arc setting by partial melting of the lower crust and S-type monzogranites have been produced at a relatively shallower depth in the crust, by continental crust recycling due to hydrothermal influx.展开更多
文摘The characterization of the relationships between mineralization and hydrothermal alteration is an essential element in understanding gold deposits. In south-west Burkina Faso, the Napélépéra mineralisation, the mobility of chemical elements and alteration-mineralization relationships were studied by means of selected core drilling and geochemical analyses using ICP-MS (Inductively Coupled Plasma Mass Spectrometry) and ICP-AES (Inductively coupled plasma atomic emission spectroscopy). The mineralised granodiorite is grey porphyroid with quartz, plagioclase, biotite and amphibole. It is metaluminous and located in the tholeiitic series. The Na<sub>2</sub>O + CaO versus Fe<sub>2</sub>O<sub>3</sub> + MgO alteration diagram divides the samples according to alteration dominance. Chloritisation and carbonation are the main alterations. There is a relationship between gold mineralisation at Napélépéra and alteration, and the paragenesis of gold + pyrite ± carbonate ± silica ± sericite is the main characteristic. Carbonation is the result of fluid input in the shear corridor of the mineralised zone. The mass balance of comparative metals in the proximal and distal zones of the mineralisation shows the absence of metals, while As, Hg, Ag and Bi are strongly enriched from the distal zone to the mineralised zone. The oxides associated with the mineralisation are mainly NaO, SrO and CaO.
基金financially supported by the Open Funds of Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry (Grant No. GLMPM-009)the Open Funds of State Key Laboratory of Ore Deposit Geochemistry (Grant No. 201505)
文摘1 Introduction 1The Sanjiang region in SE Tibet Plateau and NW Yunnan is known to have formed by amalgamation of Gongwanaderived continental blocks and arc terranes as a result of oceanic subduction followed by
基金supported by the National Key R&D Program of China(2016YFC0600603)the Guangxi Science Foundation(2014GXNSFBA118230)the Foundation of Guilin University of Technology(GUTQDJJ2019166)。
文摘A systematic study combining U-Pb zircon dating,lithogeochemical and Sr-Nd isotopic analyses was carried out upon the Xinping granodiorite porphyry in the Dayaoshan metallogenic belt to understand its petrogenesis and tectonic significance.LA-ICP-MS U-Pb zircon dating yielded a 442.7±5.8 Ma age,indicating that the granodiorite porphyry was emplaced during the Llandovery Silurian of the Early Paleozoic.The granodiorite porphyry shares the same geochemical characteristics such as Eu negative anomaly as other syn-tectonic granite plutons in the region,including the granodiorite porphyry in Dawangding and granite porphyries in the Dali Cu-Mo deposit and Longtoushang old deposit,indicating a similar magma evolution process.The Xinping granodiorite porphyry has high contents of SiO2(67.871.8%)and K2O(1.78-3.42%)and is metaluminous-peraluminous with A/CNK ratios ranging from 0.97 to 1.06,indicative of high-potassium calc-alkaline to calc-alkaline affinity.It is a I-type granite enriched in large ion lithophile elements Rb,Sr,while depleted in Ba and high field-strength element Nb.Tectonically,a collision between the Yunkai Block from the south and the Guangxi Yunnan-North Vietnam Block from the north during the Early Paleozoic was followed by uplifting of the Dayaoshan terrane.The Xinping granodiorite porphyry was likely emplaced during the collision.Sr-Nd isotopic analyses show that the granodiorite porphyry has initial 87Sr/86Sr ratios(Isr)of 0.7080-0.7104,εNd(t)range from-0.08 to-4.09,and t2DM between 1.19 and 1.51 Ga,well within the north-east low-value zone of the Cathaysia block,indicating a Paleoproterozoic Cathaysia basement source and an involvement of under plating mantle magma.Field observations,geochronological data,and 3D spatial distribution all lead to the conclusion that the Early Paleozoic Xinping granodiorite porphyry does not have any metallogenic and temporal relationships with the Xinping gold deposit(which has a Jurassic-Early Cretaceous age based on previous studies)but a close metallogenic relation to W-Mo mineralization.
基金Supported by Project of Qinghai Bureau of Geological Survey,2017
文摘Zircon U-Pb geochronology and geochemistry of the granodiorites in Xiarihamu Cu-Ni mining area are studied to determine the formation age,genesis and tectonic setting. The results show that the granodiorites formed in the Middle Triassic with weighted average age of 242 ± 1 Ma. The granodiorites comprise of SiO_2 of 61. 34%--62. 54%,Al_2 O_3 of 16. 46%--16. 87%,MgO of 2. 37%--2. 66%,( Na_2 O + K_2 O) of 5. 39%--5. 74%with the Na2 O/K_2 O of 1. 46--1. 88,Mg~# of 47. 03--48. 04,and show metaluminous characteristics with A/CNK of 0. 94--0. 96,belonging to calc-alkaline I-type granites geochemically. The light and heavy rare earth elements in the rocks are distinctly fractionated and have " right-inclined" distribution patterns with weak negative Eu anomalies( δEu = 0. 84--0. 91). Moreover,these samples show enrichments in LILEs( e. g.,Rb,Ba,K and Sr),especially in Sr [( 343--452) × 10^(-6)],and obvious depletions in HFSEs( e. g.,Nb,Ta,Ti and P),indicating geochemical characteristics similar to subduction-related magmatic rocks. According to the regional tectonic evolution,the Xiarihamu granodiorites were emplaced under an Andean-type active continental margin environment in the early Indosinian,possessing a crust-mantle mixing origin.
文摘A large number of granitoids constitutes a giant granitic belt trending EW in the Inner Mongolia.As a representative of those intrusions,the Damiao granitoid in Siziwangqi area may serve as a natural laboratory for the study of genesis of granite and evolution of crust.It is mainly composed of mid-coarse grained granodiorite with abundant
基金supported financially by the NSFC projects(Grant Nos.U1403291,41830216,and 41802074)projects of the China Geological Survey(Grant Nos.DD20160024,DD20160123,and DD20160345)IGCP 662.
文摘A large area of Late Paleozoic intrusions occursalong the Kalamaili fault in North Xinjiang,which is divided into I-type and A-type granite(Liu et al.,2013),and are the ideal objects for revealing the geological evolution of this region.However,the study of the granodioritic pluton in East Junggar is particularly weak.
基金This study is supported by the National Key Research and Development Program(2016YFC0600206)Natural Science Foundation of China(41341390441,41302050,41872081)Supporting Program for the Fundamental Research Funds for Central Universities(JZ2016HGTB0730).
文摘Magmatic microgranular enclaves(MMEs)are widely developed in the Shaocunwu granodiorite at the northeast margin of the eastern Jiangnan orogenic belt.Field geology showed that the MMEs occur as irregular ellipsoids near the edge of the intrusion,and consist of diorite,dominantly composed of amphibole,biotite,and plagioclase grains,with minor acicular apatite.Zircon U-Pb dating showed the ages of the host granodiorites and MMEs are 145.9±1.1 Ma and 145.6±2.5 Ma,respectively,indicating both originated during coeval late Jurassic magmatism.Whole-rock geochemical results show that the host granodiorite and MMEs have similar rare earth and trace element partition curves in spider grams,and similar 87Sr/86Sr,and 147Nd/144Nd isotope ratios,and their zircon 177Hf/176Hf isotopic ratios are similar.Geochemical studies indicate that both the host granodiorite and MMEs formed by mixing of coeval magma.Zircon Ti thermometers and oxygen fugacity of the host granodiorite and the MMEs show high oxygen fugacity,similar to that of W-Cu(Mo)mineralized granitoids in the eastern Jiangnan orogenic belt.A similar magma mixing process was probably one of the mechanisms that generated the W-Cu(Mo)fertile melts.
基金supported by the China Geological Survey (1212011086065, 12120113033004, 121201010000150014-40)
文摘1 Introduction Qilian Block is located in between the South China Craton and the North China Craton and the Tarim Craton(Fig.1a),which is one of the key area to study the tectonic evolution of China.The Phanerozoic tectonic
基金Supported by Project of National Natural Science Foundation of China(No.41572056)
文摘The Wulonggou area located in the Eastern Kunlun Orogen in NW China is characterized by extensive granitoid magmatism,ductile faulting and orogenic gold mineralization.The Huanglonggou granodiorite is cut by an orogenic gold-bearing fault.This study investigated the major and trace-element compositions,zircon U-Pb dates and zircon Hf isotopic compositions of the Huanglonggou granodiorite.One Huanglonggou granodiorite sample yielded a weighted mean U-Pb zircon age of^221 Ma(Carnian).The Carnian granodiorite is metaluminous,with high alkalis contents of 6.37%--8.86%,high Al_2O_3contents of 15.41%--16.19%,high Sr contents of(426--475)×10^(-6),relatively high Sr/Y ratios,high(La/Yb)_Nvalues and low HREE,suggesting an adakite type high-Si O_2granite.The Huanglonggou granodiorite sample has zirconε_(Hf)(t)values ranging from-4.4 to+1.1.These Hf isotopic data suggest that the Carnian granodiorite was likely derived from the partial melting of subducted Paleo-Tethys oceanic slab.It is suggested that the Late Triassic granodiorite was emplaced during the northward subduction of Paleo-Tethys oceanic slab.Orogenic gold mineralization in the Wulonggou area formed after the emplacement of the Late Triassic intrusive rocks.
文摘Post-collision felsic rocks in Southeastern Yunnan province contain granodiorites. U-Pb zircon ages, geochemical data and Sr-Nd isotopic data for these rocks are reported in the present paper. Laser ablation inductively coupled plasma mass spectrometry U-Pb zircon analyses yielded consistent age 252.5 ± 1.0 Ma for one sample of the felsic rocks. The granodiorites were characterized by variational and high (87Sr/86Sr)i, ranging from 0.7223 to 0.7236 and very low εNd (t) values from –29.1 to –30.4. In addition, these rocks are characterized by slight Eu negative anomalies, Nb, Ta, Ti and Sr negative anomalies on primitive mantle normalization spider. Geochemical and isotopic characteristics suggest that these rocks were derived from an enriched crust source. The granodiorites resulted from the fractionation of potassium feldspar, plagioclase and ilmenite or rutile. However, the granodiorites were unaffected by visible crustal contamination during ascent. As a result, the granodiorites may have been formed due to partial melting of crust-derived sedimentary rocks beneath southeastern Yunnan province, southern China.
文摘The mining company Sama Nickel-CI during its exploration activities in the Bounta area (Biankouma department, western Côte d’Ivoire) identified rocks with magmatic and metamorphic characteristics of felsic to mafic compositions mineralized in sulfide but unknown in the region. Thus, the petrographic characterization of these rocks of Bounta as well as the sulfides they contain, was carried out from macroscopic to microscopic observations. Petrographic analysis of these rocks has shown that these rocks are trondhjemite, tonalite and granodiorite (TTG) suites, composed of the main minerals (quartz, plagioclase, orthopyroxene, amphibole, feldspar) and accessory minerals (biotite, garnet) with magmatic textures supplanted by metamorphic textures. They were set up by fractional crystallization and would be products of Archean crustal anatexis formed from the partial melting of basaltic protocrust during the Liberian orogeny. The Bounta’s series of trondhjemite, tonalite and granodiorite (TTG) contain speckles of sulfide (pyrite and pyrrhotite) which are disseminated in places and are relatively abundant, as well as iron oxides (magnetite) which are of low proportion.
基金This work was supported by the National Natural Science Foundation of China(Grant No.40072077).
文摘The 7200-m-deep Well Tacan 1 in the central Tarim Basin is the deepest in China. Purplish gray medium-grained granodiorite containing dark gray fine-grained diorite xenolith is revealed at the base of the well (7169―7200 m), and they are results of the Jinning magmatic activities. Trace-element geochemistry and REE profiles of both rock types are similar, indicating that they are calc-alkaline series I-type granitoid. Proxies of diorite signify the development of a magmatic arc due to subduction at ca. 1200 Ma. The granodiorite was formed before 890―932 Ma. However, more study is needed to clarify if the arc diorite represents a ca. 300 Ma extension of the subduction or a reactivation during the orogenic collision event at ca. 900 Ma.
基金the President's Funds,Chinese Academy of Sciencesthe National Natural Science Foundation of China
文摘Mixing-fractional crystallization composite processes generate 6 complex patterns,which aresynthesized into 3 models,on C<sup>2</sup><sub>1</sub>/C<sup>3</sup><sub>1</sub>-C<sup>1</sup><sub>1</sub>/C<sup>3</sup><sub>1</sub> ratio correlation plots of trace eleroents E<sub>1</sub>,E<sub>2</sub>,E<sub>3</sub> according totheir relative incompatibility.Three of the six effects are clearly displayed on ratio-ratio correlation plots oftrace elements in the Kalaan granodiorite pluton,indicative of a source mixing-fractional crystallization compositeprocess.The overlying lithospheric mantle was modified by the subduction of oceanic plate during Palaeozoic.The incompatibility order of the 7 concerned trace elements is D<sub>Ta</sub>【D<sub>Th</sub>【D<sub>Hf</sub>【D<sub>Zr</sub>【D<sub>Nb</sub>≌D<sub>La</sub>【D<sub>Y</sub>.
基金financially supported by the National Science Foundation of China(92055205,41672223)the start-up funding from Sun Yat-sen University(74110-18841244).
文摘This paper report paleomagnetic data from late Cretaceous diorite dykes that sub-vertically intrude granodiorites in the eastern Gangdese belt near the city of Lhasa.Our research goals are to provide further constraints on pre-collisional structure of the southern margin of Asia and the onset of the India-Asia collision.Magnetite is identified as the main magnetic carrier in our study.The magnetite shows no evidence of metamorphism or alteration as determined from optical and scanning electron microscope observations.A strong mineral orientation is revealed by anisotropy of magnetic susceptibility analysis both for the intruded dykes and the country rocks.The authors interpret this AMS fabric to have formed during intrusion rather than deformation.Fifteen of 23 sites yield acceptable site mean characteristic remanences with dual polarities.A scatter analysis of the virtual geomagnetic poles suggests that the mean result adequately averaged paleosecular variation.The paleomagnetic pole from the Gangdese dykes yields a paleolatitude of 14.3°N±5.8°N for the southern margin of Asia near Lhasa.The paleolatitude corresponds to an in-between position of the Lhasa terrane during about 130‒60 Ma.Furthermore,the mean declination of the characteristic remanent magnetization reveals a significant counterclockwise rotation of 18°±9°for the sampling location since about 83 Ma.In the light of tectonic setting of the dykes,the strike of the southern margin of Asia near Lhasa is restored to trend approximately about 310°,which is compatible with the hypothesis that the southern margin of Eurasia had a quasi-linear structure prior to its collision with India.
基金This study was jointly funded by a project of the National Natural Science Foundation of China(42102087)a project of the China Postdoctoral Science Foundation(2022M712966)a key special project of the Ministry of Science and Technology of China(2021QZKK0304).
文摘The Daheishan supergiant porphyry molybdenum deposit(also referred to as the Daheishan deposit)is the second largest molybdenum deposit in Asia and ranks fifth among the top seven molybdenum deposits globally with total molybdenum reserves of 1.65 billion tons,an average molybdenum ore grade of 0.081%,and molybdenum resources of 1.09 million tons.The main ore body is housed in the granodiorite porphyry plutons and their surrounding inequigranular granodiorite plutons,with high-grade ores largely located in the ore-bearing granodiorite porphyries in the middle-upper part of the porphyry plutons.Specifically,it appears as an ore pipe with a large upper part and a small lower part,measuring about 1700 m in length and width,extending for about 500 m vertically,and covering an area of 2.3 km^(2).Mineralogically,the main ore body consists of molybdenite,chalcopyrite,and sphalerite horizontally from its center outward and exhibits molybdenite,azurite,and pyrite vertically from top to bottom.The primary ore minerals include pyrite and molybdenite,and the secondary ore minerals include sphalerite,chalcopyrite,tetrahedrite,and scheelite,with average grades of molybdenum,copper,sulfur,gallium,and rhenium being 0.081%,0.033%,1.67%,0.001%,and 0.0012%,respectively.The ore-forming fluids of the Daheishan deposit originated as the CO_(2)-H_(2)O-NaCl multiphase magmatic fluid system,rich in CO_(2)and bearing minor amounts of CH4,N2,and H2S,and later mixed with meteoric precipitation.In various mineralization stages,the ore-forming fluids had homogenization temperatures of>420℃‒400℃,360℃‒350℃,340℃‒230℃,220℃‒210℃,and 180℃‒160℃and salinities of>41.05%‒9.8%NaCleqv,38.16%‒4.48%NaCleqv,35.78%‒4.49%NaCleqv,7.43%NaCleqv,and 7.8%‒9.5%NaCleqv,respectively.The mineralization of the Daheishan deposit occurred at 186‒167 Ma.The granites closely related to the mineralization include granodiorites(granodiorite porphyries)and monzogranites(monzogranite porphyries),which were mineralized after magmatic evolution(189‒167 Ma).Moreover,these mineralization-related granites exhibit low initial strontium content and high initial neodymium content,indicating that these granites underwent crust-mantle mixing.The Daheishan deposit formed during the Early-Middle Jurassic,during which basaltic magma underplating induced the lower-crust melting,leading to the formation of magma chambers.After the fractional crystallization of magmas,ore-bearing fluids formed.As the temperature and pressure decreased,the ore-bearing fluids boiled drops while ascending,leading to massive unloading of metal elements.Consequently,brecciated and veinlet-disseminated ore bodies formed.
基金the National Science Foundation of China (41373036, 41002027)the Geological Survey of China Geological Survey Project (121201103000150006,121201066307).
文摘The Truong Son Fold Belt,located at the northeastern margin of the Indochina Block,is considered to be tectonically linked to the subduction of the Paleotethys Ocean and subsequent collision.Sepon is one of the most important super large deposits of the Truong Son Fold Belt.Our LA-ICP-MS zircon U-Pb dating results show that granodiorite porphyry samples from the Sepon deposit have ages of 302.1-4-2.9 Ma, which is a crucial phase for magmatic-tectonical activities from the Late Carboniferous to Early Permian and has avital influence on the mineralization of copper and gold.Zircon from granodiorite porphyry yields εHf (t)values of 4.32 to 9.64,and TDM2 has an average age of 914 Ma,suggesting that the source of the granodiorite porphyry in the region were mainly mantle components but underwent mixing and contamination of crust materials.The Ce^4+/Ce^3+ value of zircon in the granodiorite porphyry varys greatly from 2.4 to 1438.29,which shows magma mixing might occur.Considering the characteristics of trace elements in the zircon and the whole rock geochemical characteristics of intrusion rocks as well as the characteristics of regional volcanic-sedimentary association,it is indicated that the tectonic setting may be the continental arc environment.The Sepon Au-Cu deposit is derived from emplacement of calc-alkaline intermediate-acid magma with coming from deep sources in the subduction process of the Paleotethys Ocean,forming porphyry Mo-Cu,skam Cu-Au mineralization and a hydrothermal sedimentary-hosted Au mineralization in the wall rocks.
基金a part of research results of a state key research project(No.G1999043200)
文摘Zircons from granodiorite and biotite granite in the Yeniutan granitic intrusion in the western North Qilian Mountains yielded a weighted mean 206Pb/238U apparent age of 460±3 Ma, suggesting that the intrusion originated during the late stage of plate subduction. Its related Ta’ergou and Xiaoliugou deposits are two of the few large tungsten deposits formed in the plate subduction environment in the world. The U-Pb dating of the zircons from the biotite granite gave a discordant lower intercept age of 183±4 Ma, which implies that the Yanshanian event was probably superimposed on the North Qilian region.
文摘The Gabal Marwa area is located in the southeastern part of Sinai,Egypt.It comprises gneisses and migmatites,granodiorites and monzogranites.Field,petrographic,mineralogic and chemical investigations indicated that the Gabal Marwa granites are classified as granodiorites and monzogranites.The monzogranites constitute the most predominant rock unit exposed in the study area.They have been subjected to hydrothermal alterations,especially along the shear zones.Sericitization,desilicification,nametasomatism and development of spotty or dendritic manganese oxides are the most pronounced alteration features.These alterations resulted in the increase of TiO2,Al2O3,FeOt,MnO,CaO,MgO,Na2O,K2O and Cr,Zr,Rb,Y and Sr and the decrease of SiO2,P2O5,Ni,Zn,Ba and Nb.Radiometric studies indicated that the altered granites belong to high thorium,high uranium granites.The U,Th,U and Th,Th/U,Th and U-K variation diagrams suggested that magmatic processes controlled the distribution of these elements but the effect of hydrothermal alteration processes were clearly distinct.The Scanning Electron Microscope and X-ray Diffraction analyses indicated that the most important radioactive minerals include uranothorite,thorite,zircon,monazite and samarskite.Cinnabar and Mn minerals were also found.From the U,Th,Ra and K activity concentrations obtained for all the studied granitic samples,radium equivalent activity(Raeq),external hazard index(Hex),and internal hazard index(Hin),were calculated to assess the radiation hazard to human beings living in dwellings made of the studied granites.Altered monzogranites have radioactivity above the proposed acceptable level and,therefore,caution must be taken when these granites are used as building materials.
文摘Granitoids between the central and western arm of Ramagiri schist belt in its central part, are broadly classified into the migmatite gneiss, grey granodiorite and pink monzogranite, based on field characteristics and petrographic features. These granitoids belong to the Tonalite-Granodiorite-Monzogranite (TGM) suite of PGC-II. All the samples are fresh as per the CIA values, PC1-PC2 binary plot and MFW ternary plot. The granodiorites occupy the expected field in the normative IUGS, TAS, and R<sub>1</sub>-R<sub>2</sub> classification diagrams, but the monzogranites occupy the monzogranite field in the normative IUGS classification diagram and granite to alkali granite field in the rest. The granodiorites exhibit both ferroan to magnesian, alkali-calcic nature with metaluminous I type features and falls in the calc-alkaline to high K calc-alkaline series. They have high ΣREE (an average 327.905 ppm) content, and show LREE enrichment ((La/Sm)<sub>N</sub> = 3.1 - 6.8) with enriched but relatively flat HREE ((Gd/Yb)<sub>N</sub> = 1.75 - 5.26) patterns and weak negative to positive Eu anomaly (Eu/Eu* = 0.62 - 1.18). The monzogranites, on the other hand, are peraluminous, alkalic, ferroan, high K calc-alkaline, S-type granites, exhibiting relatively low ΣREE (an average 118.693 ppm) contents, strongly fractionated REE patterns with highly enriched LREE ((La/Sm)<sub>N</sub> =1.74 - 9.76), depleted HREE ((Gd/Yb)<sub>N</sub> = 0.43 - 2.21) patterns having concave upward shape, and strong negative Eu anomaly (Eu/Eu* = 0.23 - 0.89). Geothermobarometry revealed the average emplacement temperature and pressure of the granodiorites and monzogranites as 812.5℃, 8.14 ± 0.6 kbar and 775℃, 3.14 kbar, respectively. Based, on the observations, it can be concluded that the granodiorites have formed in volcanic arc setting by partial melting of the lower crust and S-type monzogranites have been produced at a relatively shallower depth in the crust, by continental crust recycling due to hydrothermal influx.
