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Lignin and holocellulose from coir pith involved in trimethylamine(fishy odor) adsorption
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作者 Nuttapong Santawee Chairat Treesubsuntorn Paitip Thiravetyan 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2019年第5期43-53,共11页
Coir pith is a highly potential adsorbent for adsorbing trimethylamine(TMA). It harbors a higher adsorption capacity for TMA compared to commercial activated carbon(CAC). It was found that lignin and holocellulose ext... Coir pith is a highly potential adsorbent for adsorbing trimethylamine(TMA). It harbors a higher adsorption capacity for TMA compared to commercial activated carbon(CAC). It was found that lignin and holocellulose extracted from coir pith played an important role in TMA adsorption. Lignin itself had the highest TMA adsorption capacity(269.01 mg/g)followed by holocellulose(75.43 mg/g), coir pith(14.3 mg/g) and CAC(10.26 mg/g),respectively. The pseudo-first-and second orders were applied to the kinetic data. For the adsorption of TMA by coir pith, the best fit was achieved by the pseudo-second order.Thermodynamic studies showed an endothermic and physico-chemical adsorption process between TMA and the coir pith. TMA desorption study suggested that only 14%–47% of TMA was desorbed with distilled water. In addition, Fourier transform-infrared(FT-IR) spectra showed that C–H bond(methyl group), C–O bond from phenolic alcohol and C–O bond from tertiary alcohol in lignin and holocellulose were involved in TMA adsorption. Coir pithbased filter showed high TMA adsorption efficiency(98%) and kept constant for more than48 days in a continuous system. Pilot scale experiment, coir pith beads filter could be succesfully applied as a packing material for TMA removal. Therefore, coir pith can be used as a promising packing material for TMA treatment at contaminated site. 展开更多
关键词 Trimethylamine(TMA) Fishy ODOR LIGNIN COIR PITH holocellulose
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Application of Wavelength Selection Combined with DS Algorithm for Model Transfer between NIR Instruments
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作者 Honghong Wang Zhixin Xiong +2 位作者 Yunchao Hu Zhijian Liu Long Liang 《Journal of Renewable Materials》 SCIE EI 2023年第6期2713-2727,共15页
This study aims to realize the sharing of near-infrared analysis models of lignin and holocellulose content in pulp wood on two different batches of spectrometers and proposes a combined algorithm of SPA-DS,MCUVE-DS a... This study aims to realize the sharing of near-infrared analysis models of lignin and holocellulose content in pulp wood on two different batches of spectrometers and proposes a combined algorithm of SPA-DS,MCUVE-DS and SiPLS-DS.The Successive Projection Algorithm(SPA),the Monte-Carlo of Uninformative Variable Elimination(MCUVE)and the Synergy Interval Partial Least Squares(SiPLS)algorithms are respectively used to reduce the adverse effects of redundant information in the transmission process of the full spectrum DS algorithm model.These three algorithms can improve model transfer accuracy and efficiency and reduce the manpower and material consumption required for modeling.These results show that the modeling effects of the characteristic wavelengths screened by the SPA,MCUVE and SiPLS algorithms are all greatly improved compared with the full-spectrum modeling,in which the SPA-PLS result in the best prediction with RPDs above 6.5 for both components.The three wavelength selection methods combined with the DS algorithm are used to transfer the models of the two instruments.Among them,the MCUVE combined with the DS algorithm has the best transfer effect.After the model transfer,the RMSEP of lignin is 0.701,and the RMSEP of holocellulose is 0.839,which was improved significantly than the full-spectrum model transfer of 0.759 and 0.918. 展开更多
关键词 Near infrared spectroscopy holocellulose LIGNIN model transfer wavelength optimization direct standardization algorithm
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Research of Biomass Accumulation and Saccharification Characteristics of Triarrhena lutarioriparia in Dongting Lake
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作者 苏小军 蔡柳 +2 位作者 田开忠 胡秋龙 熊兴耀 《Agricultural Science & Technology》 CAS 2013年第10期1436-1438,1464,共4页
[Objective] The aim was to analyze biomass accumulation, degradation and saccharification characteristics of Triarrhena lutarioriparia. [Method] With Triarrhena lutarioriparia as materials, samples were collected from... [Objective] The aim was to analyze biomass accumulation, degradation and saccharification characteristics of Triarrhena lutarioriparia. [Method] With Triarrhena lutarioriparia as materials, samples were collected from April 2012 to November 2012 to explore monthly biomass changes and degradation and saccharification of Triarrhena lutarioriparia. [Result] Plant height was improving upon time; holocellulose and cellulose contents were increasing with dry weight of shoot system increasing and achieved the peak at 78.1% and 40% in September. It can be concluded that NaOH pre-treatment efficiency is better, when Triarrhena lutarionparia was treated with 2% NaOH at 100 ℃ for 20 min and reducing sugar yield achieved 178,42 mg/g. [Conclusion] Triarrhena lutarioriparia can be materials for ethyl alcohol production and the optimal harvest time is from middle September to middle October. 展开更多
关键词 Triarrhena lutarioriparia BIOMASS CELLULOSE holocellulose Saccharify
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Biochemical Fractionation of Soil Organic Matter after Incorporation of Organic Residues
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作者 Serge-étienne Parent Léon E. Parent 《Open Journal of Soil Science》 2015年第6期135-143,共9页
Soil organic matter (SOM) is a key factor for building and maintaining soil quality. The SOM quality is commonly assessed using densitometric and sieving separation methods, but such methods do not inform on the bioch... Soil organic matter (SOM) is a key factor for building and maintaining soil quality. The SOM quality is commonly assessed using densitometric and sieving separation methods, but such methods do not inform on the biochemical composition of SOM. Our objective was to evaluate the van Soest extraction procedure for soluble (SOL), holocellulose (HOLO) and lignin/cutin (LIC) fractions of SOM after incorporating crop residues and animal wastes into a C-depleted loamy sand. Millet cuttings, oat straw, fresh cattle manure and cattle manure compost were dried, sieved to obtain 53 - 250 and 250 - 2000 μm size fractions and characterized biochemically using a modified NDF-ADF-ADL van Soest method. Soil was also sieved into 53 - 250 and 250 - 2000 μm fractions. On a dry mass basis, crop residues contained 60% - 70% holocellulose while animal wastes contained more than 40% ash. Each soil fraction was combined with three rates of the corresponding organic fraction (2, 4, and 6 Mg&#183ha&#451 millet forage cuttings or oat straw and 5, 10, and 15 Mg&#183ha&#451 of cattle manure or cattle manure compost). Changes in soil biochemical components were analyzed using the balance method of compositional data analysis. Amendment, application rate and size fraction influenced significantly (p < 0.05) the [SOL | HOLO] balance but did not significantly affect the [SOL,HOLO | LIC] balance. The [SOL | HOLO] increased linearly with addition rate of crop residues, and decreased linearly with addition rate of animal wastes. This approach of balancing biochemical SOM components is a promising method to monitor the changes in SOM quality after the incorporation of organic residues and to elaborate beneficial practices for managing crop residues and animal wastes in agro-ecosystems. 展开更多
关键词 Soil ORGANIC MATTER VAN Soest holocellulose LIGNIN Compositional Data Analysis
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Lignin-phenol monomers govern the pyrolytic conversion of natural biomass from lignocellulose to products 被引量:1
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作者 Hualing Hu Wenbing Tan Beidou Xi 《Environmental Science and Ecotechnology》 2021年第4期110-118,共9页
The effect of the interaction between lignin-phenol monomers and holocellulose in natural biomass on the distribution of pyrolysis products remains unknown.The results of this study showed that the interaction between... The effect of the interaction between lignin-phenol monomers and holocellulose in natural biomass on the distribution of pyrolysis products remains unknown.The results of this study showed that the interaction between lignin and holocellulose during the pyrolysis of natural biomass became more pronounced as the pyrolysis temperature increased.The interaction between lignin and holocellulose in the natural crosslinked structure promoted the generation of CO and inhibited the generation of CO2 at 750C.Lignin inhibited the decarboxylic reaction of hemicellulose during pyrolysis but was important for the generation of levoglucosan during cellulose pyrolysis.Holocellulose slowed the demethoxyreaction of lignin guaiacol but promoted the removal of aliphatic hydrocarbon substituents from the aromatic ring.The cinnamyl phenol monomers of lignin increased the rates of change of biomass pyrolysis products with the lignin mass fraction at 400C.However,when the pyrolysis temperature increased to 750C,all types of lignin phenol monomers increased the rates of change of the biomass pyrolysis products.Our results provide new insights that have implications for the development of pyrolysis techniques for the resource recycling of various types of biomass for the preparation of high-grade gaseous and liquid fuels. 展开更多
关键词 Natural biomass Pyrolysis Lignin monomers holocellulose Original interaction
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Analysis on Chemical Composition of Guadua amplexifolia Planted in China
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作者 XU Jinmei ZHAO Rongjun FEI Benhua 《Chinese Forestry Science and Technology》 2007年第3期45-50,共6页
The objective of this study is to determine the properties of G. amplexifolia. In this paper; the chemical composition, including holocellulose, acid-insoluble lignin, 1% NaOH solubility, benzene-ethanol extractives a... The objective of this study is to determine the properties of G. amplexifolia. In this paper; the chemical composition, including holocellulose, acid-insoluble lignin, 1% NaOH solubility, benzene-ethanol extractives and ash content, was considered for the variability with respect to positions along bamboo culm height (bottom, middle and top), parts along radial direction (inner part and outer part)and ages (1-year and 2- year). The test results were also compared to those of moso that is commonly planted and used in China. This study indicated that both the holocellulosecontent and the lignin content in inner part were lower than ; in outer part, but for extractives and ash content, the reverse was true. Bamboo age also had effect on chemical composition; both the holocellulose content and the ash content in the culm of 1- year were higher than those of 2-year; while the lignin content and the extractive content m the culm of 1- year were higher than those of 2-year. High holocellulose content, low lignin contentand extractive content were advantages of G. amplexifolia. 展开更多
关键词 Guadua amplexifolia moso (PhyllostaChys pubescens) holocellulose acid-insoluble LIGNIN EXTRACTIVES ASH CONTENT
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