Geological explorations have revealed plentiful Neogene formation waters in anticlines in the central Qaidam Basin(QB).However,the hydrochemistry and origin of these waters are obscure.In this study,the hydrochemistry...Geological explorations have revealed plentiful Neogene formation waters in anticlines in the central Qaidam Basin(QB).However,the hydrochemistry and origin of these waters are obscure.In this study,the hydrochemistry and DO-S-Sr isotopes of these formation waters were determined to study their origin and evolution.The formation waters are enriched in Na-Ca-Cl,and depleted in Mg-K-SO4-HCO3ions with elevated Li-B-Br-Sr elements.The D-O isotopes prove that the formation waters originated from weak-evaporated meteoric waters,and experienced water-rock interactions.Ion comparisons and Caexcess-Nadeficitdiagrams suggest that solute sources of these waters include evaporite dissolution,waterrock interaction,and minor residual lake brines.Bacterial sulfate reduction and water-rock interactions are supported by the high S-Sr isotopes.The enriched Li-B-Br-Sr concentrations of these waters are in accord with the high geochemical background values of the QB.Regarding the genesis of the formation waters,it can be concluded that meteoric waters from the southern Kunlun Mountains were discharged into the basin,weakly evaporated,and then infiltrated into the Neogene strata through faults leaching the soluble ions and mixing with residual lake brines,and all experienced water-rock interactions and a sulphate reduction process.展开更多
In this paper the authors classify saline lake sediments into the cold, warm and eurythermal phases, reveal the consistency between the zoning of hydrochemical types of modern saline lake water and climatic zoning and...In this paper the authors classify saline lake sediments into the cold, warm and eurythermal phases, reveal the consistency between the zoning of hydrochemical types of modern saline lake water and climatic zoning and give climatic parameters under the conditions of typical cold phase (mirabilite and natron), warm phase (thenar-dite) and slightly warm phase (bloedite) saline lake deposition.展开更多
In glacierized catchments, glacier runoff typically shows a strong diurnal cycle in the ablation season(June-September). To elucidate the effect of these processes on the chemical weathering, fresh snowfall and water ...In glacierized catchments, glacier runoff typically shows a strong diurnal cycle in the ablation season(June-September). To elucidate the effect of these processes on the chemical weathering, fresh snowfall and water samples were collected and studied from the supraglacial river, proglacial river,and gauging site in Qiyi glacierized catchment Qilian Mountains, Northwestern China, in the summer of2011. The pH and electronic conductivity(EC) were determined in the field, and the concentrations of major ions(Na^+, K^+, Mg^(2+), Ca^(2+), Cl^-, SO_4^(2-), NO_3^-) were measured. The results indicated that EC linearly increased with increasing distance from the glacial snout, and the concentrations of major ions increased with increasing water-rock interaction time. Along the flow path of the glacier runoff, Na^+ and Cl^-are more concentrated than other ions in the supraglacial river while Mg^(2+) and SO_4^(2-)are more concentrated than other ions at the gauging site. The discharge, pH, EC,and the concentrations of major ions exhibited significant diurnal variation along the flow path. On the other hand, the amplitude of variation diminished from upstream to downstream along the flow path.The chemical weathering rate(Na^++K^++Mg^(2+)+Ca^(2+))was determined to be 10.9 t/yr/km^2. Moreover,further research indicated that the sampling method influenced the assessment of chemical weathering rates. When the sample was collected randomly in one diurnal cycle of hydrography, the estimated ionic flux could deviate-47%~73% based on estimated hourly data. In contrast, if three samples were collected at peak, base flow and the discharge decreasing rate starts to slow down in one diurnal cycle of hydrography, respectively, the deviation would be less than 15%. The smaller the diurnal variation of discharge, the smaller deviation calculated.展开更多
The results of water sample analyses and investigation in the head area of the Changjiang River reveal that the characteristics of hydrochemistry of the river vary with drainage basins. In the drainage basin of the Tu...The results of water sample analyses and investigation in the head area of the Changjiang River reveal that the characteristics of hydrochemistry of the river vary with drainage basins. In the drainage basin of the Tuotuo River, the mineral concentration of water is generally high, ions of Cl and Na+ are obviously dominant. The water tends to be salty, and the type of hydrochemistry is rather complex. In the drainage basin of the Dam River, the mineral concentration is mainly in a low and middle level, ions of HCO3- and Ca2+ are higher than others, and the type of hydrochemistry is relatively simple. The ground water in deep layers plays an important role in recharging surface water, and the stable recharging results in little change in chemical composition of surface water.展开更多
King George Island, situated in the South Shetland Islands archipelago, is one of the most visited sites in Antarctica. Antarctica attracts much attention because it is one of the most sensitive areas under the influe...King George Island, situated in the South Shetland Islands archipelago, is one of the most visited sites in Antarctica. Antarctica attracts much attention because it is one of the most sensitive areas under the influence of global warming. To understand its hydrochemistry characteristics, we collected various types of water samples, including samples from streams, meltwaters, ground waters, snow and ice from around the Great Wall Station, Fildes Peninsula, King George Island, from January to February, 2015. Major ions, alkalinities, silicate, pH, dissolved oxygen, temperature, and electric conductivities were measured. Several approaches were applied to identify processes that af fect the hydrochemistry on Fildes Peninsula, including ternary diagrams, principal components analysis and cluster analysis. Our data suggest that atmospheric seasalt deposition is the main factor controlling the hydrochemistry on Fildes Peninsula. After atmospheric influences were corrected for seasalt, we defined the weathering of local rocks to be another important factor on the Peninsula's hydrochemistry. Processes such as Ca dissolution from the Ca-bearing basalt, Si loss through secondary mineralization and biological uptake influence the chemical composition of runof fs on the peninsula. Cluster analysis identified 4 groups of streams based on their hydrochemical features, which reflect their original weathering characters under icecap and the combined effects with melt snow, biological activity and the anthropogenic input.展开更多
The atmospheric pollution in Baghdad was investigated by using rainwater as a media for monitoring of pollution and also compared with the atmosphere pollution at reference stations of Al-Sulaimaniya in north of Iraq ...The atmospheric pollution in Baghdad was investigated by using rainwater as a media for monitoring of pollution and also compared with the atmosphere pollution at reference stations of Al-Sulaimaniya in north of Iraq and Al-Rutbah in Western Desert of Iraq. Rainwater sampling carried out at period extended from Nov.2007 to April 2008.Thirty five samples of rainwater were collected at seven monitoring展开更多
Four locations were chosen according to geomorphologic and engineering criterion to store the water on the midstream of Tharthar valley, water samples were collected from the four locations to evaluate the hydrochemic...Four locations were chosen according to geomorphologic and engineering criterion to store the water on the midstream of Tharthar valley, water samples were collected from the four locations to evaluate the hydrochemical properties as indicator to select the more suitable location, these locations are Hatra, Abu-Hamam, Tlol Al-Baj and Al-Sukkariah from the north to the south respectively. Also, the groundwater samples were collected from two shallow wells on the banks. The samples were analyzed to determine the concentrations of most common anions and cations in the water Ca2+, Mg2+, Na+, K+, CO32-, HCO3-, Cl–, SO42+. Also, pH, EC and TDS were measured. The results reflect high variations in concentrations of the soluble materials, the concentrations of these components are highly increased in locations of Tlol Al-Baj and Al-Sukkariah in comparison with the locations of Hatra and Abu-Hamam. The variation in geology of the area along the valley was represented a main role on the quality of water. These results can help to select the suitable locations of small dam (dams) to store the water in the valley and prevent the problem of salinity. According to the results, the northern part of midstream (north of Abu-Hamam) is suitable for water storage and the dam construction. While the locations of the downstream enriched by local sources of salts.展开更多
The study was undertaken to assess the physicochemical and chemical quality of the Tannur dam water in southern Jordan. The water samples were collected in two intervals the first during May 2015 and the second during...The study was undertaken to assess the physicochemical and chemical quality of the Tannur dam water in southern Jordan. The water samples were collected in two intervals the first during May 2015 and the second during September 2015. All samples were analyzed for temperature, conductivity, dissolved oxygen, pH, major cations (Ca2+, Mg2+, K+, Na+), and major anions (Cl-, NO3-, HCO3- and SO42-). The hydrogeochemical analyses of thirty-six water samples were used to determine the properties and type of water in the Tannur dam. The ion concentration in the water samples was from dissolution of carbonate rocks and ion exchange processes in clay. The general chemistry of water samples was typical alkaline earth waters with prevailing bicarbonate chloride. The PHREEQC Hydrogeochemical modeling was used to obtain the saturation indices of specific mineral phases, which might be related to interaction with water and aquifer, and to identify the chemical species of the dissolved ions. Calcite and dolomite solubility were assessed in terms of saturation index where they show positive values indication oversaturated SI > 0. The hydrogeochemistry behavior is rather complicated and is affected by anthropogenic and natural sources. The positive correlation values between various parameters indicate that most of ions result from same lithological sources. The abundance of the major ions in water samples is in the following order: HCO3-> Ca2+ > Cl- > NO3- > SO42-) > Na+ > Mg2+ > K+. Water samples of the Tannur dam are generally very hard, high to very high saline and medium alkaline in nature. High total hardness (TH) and total dissolved solids (TDS) in some samples identify the permissible for domestic and irrigation purposes. According to the residual sodium carbonate, SAR and conductivity values, the studied water is suitable for agricultural purposes.展开更多
Umm Er Radhuma Aquifer (UER) is the most important groundwater aquifer in Saudi Arabia, extending over 1.6 M<span style="font-size:10.5pt;font-family:;" "=""><span style="color:#...Umm Er Radhuma Aquifer (UER) is the most important groundwater aquifer in Saudi Arabia, extending over 1.6 M<span style="font-size:10.5pt;font-family:;" "=""><span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"=""><span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"="">·</span></span></span>km<sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> in the eastern part of the Arabian Peninsula, forming the main aquifer throughout the Rub’ Al-Khali (RAK). </span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">Groundwater salinity increased from west to east, reaching more than 27,000 mg/L near the border with the United Arab Emirates, where a Na</span><sup><span style="font-family:Verdana;">+</span></sup><span style="font-family:Verdana;">-Ca</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;">Cl<span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"="">ˉ</span></span><span style="font-family:Verdana;">-<img src="Edit_c1bbc858-a8a7-45ca-be57-e2bb456cbddb.bmp" alt="" /></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> </span></span></span></span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">water type dominated. Gibbs diagrams indicated that the dissolution/precipitation of carbonates and evaporation/precipitation of minerals, especially anhydrite, gypsum, and halite account for the solutes and salinity in groundwater. Most of the samples plot above the 1:1 line of (Ca</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;"> + Mg</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;">) against <img src="Edit_5405b197-c8d5-436d-8648-dd95afefb8e6.bmp" alt="" /></span></span></span></span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">, indicating other sources of Ca</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;"> and Mg</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;"> in the groundwater along with dolomite and calcium carbonate minerals. Phreeqc model indicated that the main clay minerals are kaolinite and gibbsite which had major effect on the cation exchange process as indicated by the Chloro-Alkaline index (CAI), where most of groundwater samples had values greater than zero which indicated the occurrence of reverse ion exchange between the groundwater and its host aquifer. The water type Na</span><sup><span style="font-family:Verdana;">+</span></sup><span style="font-family:Verdana;">-Ca</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;">Cl</span><sup><span style="font-family:Verdana;"><span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"="">ˉ</span></span></sup><span style="font-family:Verdana;">-<img src="Edit_e8c17a28-24a8-4e14-a615-24c0e0817331.bmp" alt="" /></span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">dominated in the eastern part of the aquifer as the anaerobic conditions prevailed and the reduction of sulphate took place.</span></span></span></span>展开更多
The expected water mixing process between Red/Dead Sea water during the proposed conveyance projects is the main target of this research. The project will ensue transporting Red Sea water to recover and maintain certa...The expected water mixing process between Red/Dead Sea water during the proposed conveyance projects is the main target of this research. The project will ensue transporting Red Sea water to recover and maintain certain level of the Dead Sea, mostly will reach <span><span><span style="font-family:;" "=""><span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#ffffff;"="">-</span></span></span></span><span style="font-family:;" "="">395</span><span style="font-family:;" "=""> </span><span style="font-family:;" "="">m. It is found that, the two different water bodies with different EC values or different densities (salinities) are relatively divided by stable plane. This plane is defined as the BARZACH PLANE. In this study, the mixing process occurred between the Red Sea with the Dead Sea waters, located at 20</span><span style="font-family:;" "="">% </span><span style="font-family:;" "="">-</span><span style="font-family:;" "=""> </span><span style="font-family:;" "="">24% of the Dead Sea column depth based on the Barzach Plane level. During a laboratory experimental work, it is found that the mixed Red/Dead Sea water evaporates in a high rate until certain level where the solution attains oversaturated conditions with different dissolved solids. At this stage, a thin layer of solids suddenly formed and floated at the surface of the dense brine. The salinity of the captured water is so dense that floated salt layer cannot be dissolved. In addition, the formed floated salt layer at the surface prevents the below captured water to evaporate and at this stage, stalactites start to form until the excess dissolved solids are not oversaturated with any mineral.</span>展开更多
Groundwater contamination in urban cities is imminent in the phase of increased anthropogenic activities apart from the contribution of geogenic contaminants. This study examined the sanitary surveys and hydrochemistr...Groundwater contamination in urban cities is imminent in the phase of increased anthropogenic activities apart from the contribution of geogenic contaminants. This study examined the sanitary surveys and hydrochemistry of groundwater in Ado-Ekiti and Ijero-Ekiti to establish the contaminants’ sources, decipher the effects of urbanization on population and explain any relationship between the surveys and the groundwater chemistry. Sanitary surveys of 30 randomly selected wells each from Ado-Ekiti and Ijero-Ekiti were executed by administering and processing appropriately designed questionnaires that addressed salient problems of hygiene and sanitation. The results of the surveys were grouped into very high risk, high risk, intermediate risk, and low risk classes. Subsequently, at each location, in situ parameters (temperature (°C), pH and EC (μS/cm)) were measured using a portable Multi-parameter TestrTM 35 Series S/N: 1382654. At each well, water samples were collected into clean polyethylene bottles in triplicates for cation, anions and e-coli evaluations, respectively. Water samples for cations were acidified by adding two drops of concentrated nitric acid. All samples were kept in a refrigerator at a low temperature of about 4°C before being taken to the Federal University of Technology, Akure, for analyses. Ion chromatography was employed for the anions analysis while the cations were determined using an Atomic Absorption Spectrophotometer Buck 210 model. Membrane filter technique was employed for the e-coli estimation. From the results of the hydrochemistry, the Nitrate Pollution Index (NPI) and Modified Nitrate Pollution Index (MNPI) were estimated and classified into;clean unpolluted, light pollution, moderate pollution, significant pollution, very significant pollution waters. Sanitary surveys in the two cities showed that in the very low risk, intermediate and high-risk categories, Ado-Ekiti had 33.33%, 56.67% and 10% representations, while Ijero-Ekiti had 50%, 23.33% and 26.67% representations, respectively. This observation showed that Ado-Ekiti with higher population and humans’ activities compared to Ijero-Ekiti was less susceptible to pollution. Urbanization has no direct effects on sanitary surveys. The pH of wells’ water in Ado-Ekiti ranged from 4.8 - 8.2, EC (μS/cm) from 101 - 1008, while at Ijero-Ekiti, the pH and EC (μS/cm) varied from 2.1 - 13.8 and 80 - 1008 respectively. Ado-Ekiti wells’ water was more acidic than that of Ijero-Ekiti. Chemical concentrations (mg/L) of Ca<sup>2+</sup>, Mg<sup>2+</sup>, Na<sup>+</sup>, K<sup>+</sup>, , and Cl<sup>ˉ</sup> of the wells’ water in both cities were within WHO-approved standards for drinking water. However, with average concentrations of 142.17 (mg/L) and 252.71 (mg/L) at Ado-Ekiti and Ijero-Ekiti, respectively, exceeded the standard in many locations. Susceptibility to pollution classification employing TDS, NPI and MNPI showed that Ijero-Ekiti was more susceptible to pollution compared to Ado-Ekiti. This assertion was supported by statistical analysis employing correlation, cluster analysis, and principal component analysis. This study showed that urbanization had no direct effects on sanitary surveys and groundwater quality. Pollution of wells’ water in the two cities was, mainly from anthropogenic activities. However, Ijero-Ekiti, with significant anthropogenic activities, had its wells’ water more susceptible to pollution. Sanitary surveys are a complementary method to water quality monitoring.展开更多
This review presented a detailed re-assessment of the hydrogeology and hydrochemistry of the Tropical Anambra Basin.It identified and discussed the major geological formations and their groundwater potentials.The geol...This review presented a detailed re-assessment of the hydrogeology and hydrochemistry of the Tropical Anambra Basin.It identified and discussed the major geological formations and their groundwater potentials.The geological examination showed that the Ajali Formation is confined in places forming an artesian condition;the potentials of this aquifer decline in the western basin due to a decrease in thickness.The sandstone associates of the Nsukka Formation are aquiferous and have produced high-pressure artesian boreholes along the Oji River.The Imo Shale is characterized by permeability stability all over much of the intermediate unit.The Bende-Ameki aquifer has a lesser amount of groundwater when equated to other formations;the geologic characteristics do not produce favorable hydrogeological conditions for groundwater occurrence.The stratigraphical and structural framework suggested the presence of an efficient throughflow in the basin.Based on physical and chemical parameters of water quality,the basin holds water of acceptable quality.While there are considerable investigations on the hydrogeology and hydrochemistry,studies are short of analysis of the hydrogeochemical evolution of groundwater,water quality index,heavy metals pollution index as well as total hazard quotient.Suitability of groundwater based on agricultural water quality indices(e.g.SAR)is also salient.Therefore,future studies should address these owing to increasing dependence on groundwater.展开更多
This review attempted a detailed description of geological and hydrogeological configurations of Cross River and Imo-Akwa Ibo basins.It presented a synthesis of hydrochemistry and a description of the hydrogeological ...This review attempted a detailed description of geological and hydrogeological configurations of Cross River and Imo-Akwa Ibo basins.It presented a synthesis of hydrochemistry and a description of the hydrogeological configurations of the two basins.Hydrogeologically,most areas under Cross River and Imo-Kwa-Ibo are poor in terms of groundwater potentials.Based on the hydrochemistry,the basins hold water of excellent quality.Groundwater sources fall in soft to moderately hard classes.The entire sources groundwater has a TDS concentration of less than 500 mg/l.Groundwater classification based on electrical conductivity(EC)showed EC levels were less than 500μS/cm.Most of the examined cations and anions are within WHO reference guidelines for drinking water quality.However,no broad analysis of water quality based on water quality indices.Also,studies modeling pollution or the impact of land use changes on groundwater quality are wanting.Thus,further analysis of the hydrochemistry of groundwater aquifers is recommended.展开更多
The Turpan Basin is located in the arid zone of northwestern China and is a typical closed inland basin surrounded by high mountains. It is one of the most arid regions in the world and, as a result, the groundwater i...The Turpan Basin is located in the arid zone of northwestern China and is a typical closed inland basin surrounded by high mountains. It is one of the most arid regions in the world and, as a result, the groundwater in this area is very important for both domestic and agricultural uses. In the present study, the relationships of major elements(K+, Na+, Ca2+, Mg2+, HCO3-, SO42- and Cl-) and environmental isotopes(δ18O, δ2H and T) in groundwater were analyzed to investigate the evolution of the regional hydrochemistry within the Turpan Basin. The hydrochemistry results demonstrate that groundwater with high total dissolved solids(TDS) concentration is dominated by sodium chloride(Na-Cl) and sodium sulfate(Na-SO4) type water, whereas that with low TDS concentration(typically from near mountain areas) is dominated by calcium bicarbonate(Ca-HCO3) type water. The evolution of groundwater hydrochemistry within the Turpan Basin is a result of calcium carbonate precipitation, evaporation concentration, cation exchange and dissolution of evaporites(i.e. halite, mirabilite and gypsum). Furthermore, evaporite dissolution associated with irrigation practice plays a key role in the groundwater salinization, especially in the central part of the basin. Environmental isotopes reveal that the groundwater is recharged by precipitation in the mountain areas and fast vertical infiltration of irrigation return flow. In the southern sub-basin the shallow groundwater and the deep groundwater is separated at a depth of about 40 m, with substantial differences in terms of hydrochemical and isotopic characteristics. The results are useful for decision making related to sustainable water resource utilization in the Turpan Basin and other regions in northwestern China.展开更多
The Tibetan Plateau is one of the most complicated geographical units worldwide in terms of its tectonic and environmental background.Although a hotspot for continental weathering and carbon cycling studies,accurate d...The Tibetan Plateau is one of the most complicated geographical units worldwide in terms of its tectonic and environmental background.Although a hotspot for continental weathering and carbon cycling studies,accurate determination of the weathering carbon budget is challenging in this area,especially sink and source flux quantification and the controlling mechanisms.Compared with other major rivers on the plateau,the Nujiang River is characterized by less human disturbance and maintains a relatively pristine state.This study investigates the high spatiotemporal resolution hydrochemistry and dual-carbon isotope composition(δ~(13)C_(DIC)andΔ~(14)C_(DIC))of river water in the Nujiang River Basin.The results revealed that the solutes and dissolved inorganic carbon in the river water are predominantly derived from rock weathering by carbonic and sulfuric acids,mainly due to the carbonate weathering process,and significantly enhanced by deep carbon sourcing from hot springs in the fault zone.The average contributions of geological and modern carbon in the main stream of the Nujiang River are 35.2%and 64.8%,respectively,and sulfide oxidation contributes>90%of sulfate ions in the river water.After considering the involvement of sulfuric acid generated by sulfide oxidation during rock weathering,the calculated consumption fluxes of atmospheric CO_(2) by silicate and carbonate weathering in the watershed were decreased by approximately 52.0%and 37.4%,respectively,compared with those calculated ignoring this process.Rock weathering of the Nujiang River Basin is a“CO_(2) sink”on a short time scale,while the participation of sulfuric acid makes it a“CO_(2) source”on a geological time scale.The high-frequency observations of ion concentrations,elemental ratios,and calculated contributions of different rock weathering materials indicate that carbonate rock weathering is more sensitive to temperature and runoff variations than silicate rock weathering,with the solute contribution from carbonate weathering increasing significantly during monsoon period.The material input from different rock types is dominated by the hydrological pathways and water-rock reaction times in the basin.This study reveals the river solute origins and weathering CO_(2) sequestration effect in response to a monsoonal climate in one of the most representative pristine plateau watersheds in the world,which is of great importance for elucidating the weathering control mechanisms and CO_(2) net sourcesink effect in plateau watersheds.展开更多
In the Tano River Basin,groundwater serves as a crucial resource;however,its quantity and quality with regard to trace elements and microbiological loadings remain poorly understood due to the lack of groundwater logs...In the Tano River Basin,groundwater serves as a crucial resource;however,its quantity and quality with regard to trace elements and microbiological loadings remain poorly understood due to the lack of groundwater logs and limited water research.This study presents a comprehensive analysis of the Tano River Basin,focusing on three key objectives.First,it investigated the aquifer hydraulic parameters and the results showed significant spatial variations in borehole depths,yields,transmissivity,hydraulic conductivity,and specific capacity.Deeper boreholes were concentrated in the northeastern and southeastern zones,while geological formations,particu-larly the Apollonian Formation,exhibit a strong influence on borehole yields.The study identified areas with high transmissivity and hydraulic conductivity in the southern and eastern regions,suggesting good groundwater avail-ability and suitability for sustainable water supply.Sec-ondly,the research investigated the groundwater quality and observed that the majority of borehole samples fall within WHO(Guidelines for Drinking-water Quality,Environmental Health Criteria,Geneva,2011,2017.http://www.who.int)limit.However,some samples have pH levels below the standards,although the groundwater generally qualifies as freshwater.The study further explores hydrochemical facies and health risk assessment,highlighting the dominance of Ca–HCO3 water type.Trace element analysis reveals minimal health risks from most elements,with chromium(Cr)as the primary contributor to chronic health risk.Overall,this study has provided a key insights into the Tano River Basin’s hydrogeology and associated health risks.The outcome of this research has contributed to the broader understanding of hydrogeologi-cal dynamics and the importance of managing groundwater resources sustainably in complex geological environments.展开更多
基金supported by the Second Tibetan Plateau Scientific Expedition and Research Program(STEP,Grant No.2019QZKK0805)the Special Project of Qinghai Scholars(Grant No.QHS201802)+1 种基金National Natural Science Foundation of China(NSFC,Grant Nos.41872093,U21A2018)Foundation of Qinghai Science&Technology Department(Grant No.2021-ZJ-932)。
文摘Geological explorations have revealed plentiful Neogene formation waters in anticlines in the central Qaidam Basin(QB).However,the hydrochemistry and origin of these waters are obscure.In this study,the hydrochemistry and DO-S-Sr isotopes of these formation waters were determined to study their origin and evolution.The formation waters are enriched in Na-Ca-Cl,and depleted in Mg-K-SO4-HCO3ions with elevated Li-B-Br-Sr elements.The D-O isotopes prove that the formation waters originated from weak-evaporated meteoric waters,and experienced water-rock interactions.Ion comparisons and Caexcess-Nadeficitdiagrams suggest that solute sources of these waters include evaporite dissolution,waterrock interaction,and minor residual lake brines.Bacterial sulfate reduction and water-rock interactions are supported by the high S-Sr isotopes.The enriched Li-B-Br-Sr concentrations of these waters are in accord with the high geochemical background values of the QB.Regarding the genesis of the formation waters,it can be concluded that meteoric waters from the southern Kunlun Mountains were discharged into the basin,weakly evaporated,and then infiltrated into the Neogene strata through faults leaching the soluble ions and mixing with residual lake brines,and all experienced water-rock interactions and a sulphate reduction process.
文摘In this paper the authors classify saline lake sediments into the cold, warm and eurythermal phases, reveal the consistency between the zoning of hydrochemical types of modern saline lake water and climatic zoning and give climatic parameters under the conditions of typical cold phase (mirabilite and natron), warm phase (thenar-dite) and slightly warm phase (bloedite) saline lake deposition.
基金supported by theNatural Science Foundation of China(Grant Nos.41471057,41571076,41201063)
文摘In glacierized catchments, glacier runoff typically shows a strong diurnal cycle in the ablation season(June-September). To elucidate the effect of these processes on the chemical weathering, fresh snowfall and water samples were collected and studied from the supraglacial river, proglacial river,and gauging site in Qiyi glacierized catchment Qilian Mountains, Northwestern China, in the summer of2011. The pH and electronic conductivity(EC) were determined in the field, and the concentrations of major ions(Na^+, K^+, Mg^(2+), Ca^(2+), Cl^-, SO_4^(2-), NO_3^-) were measured. The results indicated that EC linearly increased with increasing distance from the glacial snout, and the concentrations of major ions increased with increasing water-rock interaction time. Along the flow path of the glacier runoff, Na^+ and Cl^-are more concentrated than other ions in the supraglacial river while Mg^(2+) and SO_4^(2-)are more concentrated than other ions at the gauging site. The discharge, pH, EC,and the concentrations of major ions exhibited significant diurnal variation along the flow path. On the other hand, the amplitude of variation diminished from upstream to downstream along the flow path.The chemical weathering rate(Na^++K^++Mg^(2+)+Ca^(2+))was determined to be 10.9 t/yr/km^2. Moreover,further research indicated that the sampling method influenced the assessment of chemical weathering rates. When the sample was collected randomly in one diurnal cycle of hydrography, the estimated ionic flux could deviate-47%~73% based on estimated hourly data. In contrast, if three samples were collected at peak, base flow and the discharge decreasing rate starts to slow down in one diurnal cycle of hydrography, respectively, the deviation would be less than 15%. The smaller the diurnal variation of discharge, the smaller deviation calculated.
文摘The results of water sample analyses and investigation in the head area of the Changjiang River reveal that the characteristics of hydrochemistry of the river vary with drainage basins. In the drainage basin of the Tuotuo River, the mineral concentration of water is generally high, ions of Cl and Na+ are obviously dominant. The water tends to be salty, and the type of hydrochemistry is rather complex. In the drainage basin of the Dam River, the mineral concentration is mainly in a low and middle level, ions of HCO3- and Ca2+ are higher than others, and the type of hydrochemistry is relatively simple. The ground water in deep layers plays an important role in recharging surface water, and the stable recharging results in little change in chemical composition of surface water.
基金Supported by the Chinese Arctic and Antarctic Administration(No.2014GW08008)the SKLEC/ECNU(No.2011KYYW02)the National Natural Science Foundation of China(No.41676175)
文摘King George Island, situated in the South Shetland Islands archipelago, is one of the most visited sites in Antarctica. Antarctica attracts much attention because it is one of the most sensitive areas under the influence of global warming. To understand its hydrochemistry characteristics, we collected various types of water samples, including samples from streams, meltwaters, ground waters, snow and ice from around the Great Wall Station, Fildes Peninsula, King George Island, from January to February, 2015. Major ions, alkalinities, silicate, pH, dissolved oxygen, temperature, and electric conductivities were measured. Several approaches were applied to identify processes that af fect the hydrochemistry on Fildes Peninsula, including ternary diagrams, principal components analysis and cluster analysis. Our data suggest that atmospheric seasalt deposition is the main factor controlling the hydrochemistry on Fildes Peninsula. After atmospheric influences were corrected for seasalt, we defined the weathering of local rocks to be another important factor on the Peninsula's hydrochemistry. Processes such as Ca dissolution from the Ca-bearing basalt, Si loss through secondary mineralization and biological uptake influence the chemical composition of runof fs on the peninsula. Cluster analysis identified 4 groups of streams based on their hydrochemical features, which reflect their original weathering characters under icecap and the combined effects with melt snow, biological activity and the anthropogenic input.
文摘The atmospheric pollution in Baghdad was investigated by using rainwater as a media for monitoring of pollution and also compared with the atmosphere pollution at reference stations of Al-Sulaimaniya in north of Iraq and Al-Rutbah in Western Desert of Iraq. Rainwater sampling carried out at period extended from Nov.2007 to April 2008.Thirty five samples of rainwater were collected at seven monitoring
文摘Four locations were chosen according to geomorphologic and engineering criterion to store the water on the midstream of Tharthar valley, water samples were collected from the four locations to evaluate the hydrochemical properties as indicator to select the more suitable location, these locations are Hatra, Abu-Hamam, Tlol Al-Baj and Al-Sukkariah from the north to the south respectively. Also, the groundwater samples were collected from two shallow wells on the banks. The samples were analyzed to determine the concentrations of most common anions and cations in the water Ca2+, Mg2+, Na+, K+, CO32-, HCO3-, Cl–, SO42+. Also, pH, EC and TDS were measured. The results reflect high variations in concentrations of the soluble materials, the concentrations of these components are highly increased in locations of Tlol Al-Baj and Al-Sukkariah in comparison with the locations of Hatra and Abu-Hamam. The variation in geology of the area along the valley was represented a main role on the quality of water. These results can help to select the suitable locations of small dam (dams) to store the water in the valley and prevent the problem of salinity. According to the results, the northern part of midstream (north of Abu-Hamam) is suitable for water storage and the dam construction. While the locations of the downstream enriched by local sources of salts.
文摘The study was undertaken to assess the physicochemical and chemical quality of the Tannur dam water in southern Jordan. The water samples were collected in two intervals the first during May 2015 and the second during September 2015. All samples were analyzed for temperature, conductivity, dissolved oxygen, pH, major cations (Ca2+, Mg2+, K+, Na+), and major anions (Cl-, NO3-, HCO3- and SO42-). The hydrogeochemical analyses of thirty-six water samples were used to determine the properties and type of water in the Tannur dam. The ion concentration in the water samples was from dissolution of carbonate rocks and ion exchange processes in clay. The general chemistry of water samples was typical alkaline earth waters with prevailing bicarbonate chloride. The PHREEQC Hydrogeochemical modeling was used to obtain the saturation indices of specific mineral phases, which might be related to interaction with water and aquifer, and to identify the chemical species of the dissolved ions. Calcite and dolomite solubility were assessed in terms of saturation index where they show positive values indication oversaturated SI > 0. The hydrogeochemistry behavior is rather complicated and is affected by anthropogenic and natural sources. The positive correlation values between various parameters indicate that most of ions result from same lithological sources. The abundance of the major ions in water samples is in the following order: HCO3-> Ca2+ > Cl- > NO3- > SO42-) > Na+ > Mg2+ > K+. Water samples of the Tannur dam are generally very hard, high to very high saline and medium alkaline in nature. High total hardness (TH) and total dissolved solids (TDS) in some samples identify the permissible for domestic and irrigation purposes. According to the residual sodium carbonate, SAR and conductivity values, the studied water is suitable for agricultural purposes.
文摘Umm Er Radhuma Aquifer (UER) is the most important groundwater aquifer in Saudi Arabia, extending over 1.6 M<span style="font-size:10.5pt;font-family:;" "=""><span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"=""><span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"="">·</span></span></span>km<sup><span style="font-family:Verdana;">2</span></sup><span style="font-family:Verdana;"> in the eastern part of the Arabian Peninsula, forming the main aquifer throughout the Rub’ Al-Khali (RAK). </span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">Groundwater salinity increased from west to east, reaching more than 27,000 mg/L near the border with the United Arab Emirates, where a Na</span><sup><span style="font-family:Verdana;">+</span></sup><span style="font-family:Verdana;">-Ca</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;">Cl<span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"="">ˉ</span></span><span style="font-family:Verdana;">-<img src="Edit_c1bbc858-a8a7-45ca-be57-e2bb456cbddb.bmp" alt="" /></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;"> </span></span></span></span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">water type dominated. Gibbs diagrams indicated that the dissolution/precipitation of carbonates and evaporation/precipitation of minerals, especially anhydrite, gypsum, and halite account for the solutes and salinity in groundwater. Most of the samples plot above the 1:1 line of (Ca</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;"> + Mg</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;">) against <img src="Edit_5405b197-c8d5-436d-8648-dd95afefb8e6.bmp" alt="" /></span></span></span></span><span><span><span style="font-family:;" "=""><span style="font-family:Verdana;">, indicating other sources of Ca</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;"> and Mg</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;"> in the groundwater along with dolomite and calcium carbonate minerals. Phreeqc model indicated that the main clay minerals are kaolinite and gibbsite which had major effect on the cation exchange process as indicated by the Chloro-Alkaline index (CAI), where most of groundwater samples had values greater than zero which indicated the occurrence of reverse ion exchange between the groundwater and its host aquifer. The water type Na</span><sup><span style="font-family:Verdana;">+</span></sup><span style="font-family:Verdana;">-Ca</span><sup><span style="font-family:Verdana;">2+</span></sup><span style="font-family:Verdana;">Cl</span><sup><span style="font-family:Verdana;"><span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#f7f7f7;"="">ˉ</span></span></sup><span style="font-family:Verdana;">-<img src="Edit_e8c17a28-24a8-4e14-a615-24c0e0817331.bmp" alt="" /></span></span></span></span><span style="font-family:Verdana;"><span style="font-family:Verdana;"><span style="font-family:Verdana;">dominated in the eastern part of the aquifer as the anaerobic conditions prevailed and the reduction of sulphate took place.</span></span></span></span>
文摘The expected water mixing process between Red/Dead Sea water during the proposed conveyance projects is the main target of this research. The project will ensue transporting Red Sea water to recover and maintain certain level of the Dead Sea, mostly will reach <span><span><span style="font-family:;" "=""><span style="color:#4F4F4F;font-family:-apple-system, " font-size:16px;white-space:normal;background-color:#ffffff;"="">-</span></span></span></span><span style="font-family:;" "="">395</span><span style="font-family:;" "=""> </span><span style="font-family:;" "="">m. It is found that, the two different water bodies with different EC values or different densities (salinities) are relatively divided by stable plane. This plane is defined as the BARZACH PLANE. In this study, the mixing process occurred between the Red Sea with the Dead Sea waters, located at 20</span><span style="font-family:;" "="">% </span><span style="font-family:;" "="">-</span><span style="font-family:;" "=""> </span><span style="font-family:;" "="">24% of the Dead Sea column depth based on the Barzach Plane level. During a laboratory experimental work, it is found that the mixed Red/Dead Sea water evaporates in a high rate until certain level where the solution attains oversaturated conditions with different dissolved solids. At this stage, a thin layer of solids suddenly formed and floated at the surface of the dense brine. The salinity of the captured water is so dense that floated salt layer cannot be dissolved. In addition, the formed floated salt layer at the surface prevents the below captured water to evaporate and at this stage, stalactites start to form until the excess dissolved solids are not oversaturated with any mineral.</span>
文摘Groundwater contamination in urban cities is imminent in the phase of increased anthropogenic activities apart from the contribution of geogenic contaminants. This study examined the sanitary surveys and hydrochemistry of groundwater in Ado-Ekiti and Ijero-Ekiti to establish the contaminants’ sources, decipher the effects of urbanization on population and explain any relationship between the surveys and the groundwater chemistry. Sanitary surveys of 30 randomly selected wells each from Ado-Ekiti and Ijero-Ekiti were executed by administering and processing appropriately designed questionnaires that addressed salient problems of hygiene and sanitation. The results of the surveys were grouped into very high risk, high risk, intermediate risk, and low risk classes. Subsequently, at each location, in situ parameters (temperature (°C), pH and EC (μS/cm)) were measured using a portable Multi-parameter TestrTM 35 Series S/N: 1382654. At each well, water samples were collected into clean polyethylene bottles in triplicates for cation, anions and e-coli evaluations, respectively. Water samples for cations were acidified by adding two drops of concentrated nitric acid. All samples were kept in a refrigerator at a low temperature of about 4°C before being taken to the Federal University of Technology, Akure, for analyses. Ion chromatography was employed for the anions analysis while the cations were determined using an Atomic Absorption Spectrophotometer Buck 210 model. Membrane filter technique was employed for the e-coli estimation. From the results of the hydrochemistry, the Nitrate Pollution Index (NPI) and Modified Nitrate Pollution Index (MNPI) were estimated and classified into;clean unpolluted, light pollution, moderate pollution, significant pollution, very significant pollution waters. Sanitary surveys in the two cities showed that in the very low risk, intermediate and high-risk categories, Ado-Ekiti had 33.33%, 56.67% and 10% representations, while Ijero-Ekiti had 50%, 23.33% and 26.67% representations, respectively. This observation showed that Ado-Ekiti with higher population and humans’ activities compared to Ijero-Ekiti was less susceptible to pollution. Urbanization has no direct effects on sanitary surveys. The pH of wells’ water in Ado-Ekiti ranged from 4.8 - 8.2, EC (μS/cm) from 101 - 1008, while at Ijero-Ekiti, the pH and EC (μS/cm) varied from 2.1 - 13.8 and 80 - 1008 respectively. Ado-Ekiti wells’ water was more acidic than that of Ijero-Ekiti. Chemical concentrations (mg/L) of Ca<sup>2+</sup>, Mg<sup>2+</sup>, Na<sup>+</sup>, K<sup>+</sup>, , and Cl<sup>ˉ</sup> of the wells’ water in both cities were within WHO-approved standards for drinking water. However, with average concentrations of 142.17 (mg/L) and 252.71 (mg/L) at Ado-Ekiti and Ijero-Ekiti, respectively, exceeded the standard in many locations. Susceptibility to pollution classification employing TDS, NPI and MNPI showed that Ijero-Ekiti was more susceptible to pollution compared to Ado-Ekiti. This assertion was supported by statistical analysis employing correlation, cluster analysis, and principal component analysis. This study showed that urbanization had no direct effects on sanitary surveys and groundwater quality. Pollution of wells’ water in the two cities was, mainly from anthropogenic activities. However, Ijero-Ekiti, with significant anthropogenic activities, had its wells’ water more susceptible to pollution. Sanitary surveys are a complementary method to water quality monitoring.
基金supported by Federal University Birnin kebbi.Many thanks to anonymous contributors.
文摘This review presented a detailed re-assessment of the hydrogeology and hydrochemistry of the Tropical Anambra Basin.It identified and discussed the major geological formations and their groundwater potentials.The geological examination showed that the Ajali Formation is confined in places forming an artesian condition;the potentials of this aquifer decline in the western basin due to a decrease in thickness.The sandstone associates of the Nsukka Formation are aquiferous and have produced high-pressure artesian boreholes along the Oji River.The Imo Shale is characterized by permeability stability all over much of the intermediate unit.The Bende-Ameki aquifer has a lesser amount of groundwater when equated to other formations;the geologic characteristics do not produce favorable hydrogeological conditions for groundwater occurrence.The stratigraphical and structural framework suggested the presence of an efficient throughflow in the basin.Based on physical and chemical parameters of water quality,the basin holds water of acceptable quality.While there are considerable investigations on the hydrogeology and hydrochemistry,studies are short of analysis of the hydrogeochemical evolution of groundwater,water quality index,heavy metals pollution index as well as total hazard quotient.Suitability of groundwater based on agricultural water quality indices(e.g.SAR)is also salient.Therefore,future studies should address these owing to increasing dependence on groundwater.
文摘This review attempted a detailed description of geological and hydrogeological configurations of Cross River and Imo-Akwa Ibo basins.It presented a synthesis of hydrochemistry and a description of the hydrogeological configurations of the two basins.Hydrogeologically,most areas under Cross River and Imo-Kwa-Ibo are poor in terms of groundwater potentials.Based on the hydrochemistry,the basins hold water of excellent quality.Groundwater sources fall in soft to moderately hard classes.The entire sources groundwater has a TDS concentration of less than 500 mg/l.Groundwater classification based on electrical conductivity(EC)showed EC levels were less than 500μS/cm.Most of the examined cations and anions are within WHO reference guidelines for drinking water quality.However,no broad analysis of water quality based on water quality indices.Also,studies modeling pollution or the impact of land use changes on groundwater quality are wanting.Thus,further analysis of the hydrochemistry of groundwater aquifers is recommended.
基金funded by Coal Base Groundwater Exploration (Eastern Xinjiang) under the Xinjiang Uygur Autonomous Region 358 Project
文摘The Turpan Basin is located in the arid zone of northwestern China and is a typical closed inland basin surrounded by high mountains. It is one of the most arid regions in the world and, as a result, the groundwater in this area is very important for both domestic and agricultural uses. In the present study, the relationships of major elements(K+, Na+, Ca2+, Mg2+, HCO3-, SO42- and Cl-) and environmental isotopes(δ18O, δ2H and T) in groundwater were analyzed to investigate the evolution of the regional hydrochemistry within the Turpan Basin. The hydrochemistry results demonstrate that groundwater with high total dissolved solids(TDS) concentration is dominated by sodium chloride(Na-Cl) and sodium sulfate(Na-SO4) type water, whereas that with low TDS concentration(typically from near mountain areas) is dominated by calcium bicarbonate(Ca-HCO3) type water. The evolution of groundwater hydrochemistry within the Turpan Basin is a result of calcium carbonate precipitation, evaporation concentration, cation exchange and dissolution of evaporites(i.e. halite, mirabilite and gypsum). Furthermore, evaporite dissolution associated with irrigation practice plays a key role in the groundwater salinization, especially in the central part of the basin. Environmental isotopes reveal that the groundwater is recharged by precipitation in the mountain areas and fast vertical infiltration of irrigation return flow. In the southern sub-basin the shallow groundwater and the deep groundwater is separated at a depth of about 40 m, with substantial differences in terms of hydrochemical and isotopic characteristics. The results are useful for decision making related to sustainable water resource utilization in the Turpan Basin and other regions in northwestern China.
基金supported by the National Key Research and Development Program of China (Grant No.2020YFA0607700)the National Basic Science Center Program of Natural Science Foundation of China (Grant No.41888101)+2 种基金the National Natural Science Foundation of China (Grant No.41730857)the Key Research Program of the Institute of Geology&Geophysics,CAS (Grant No.IGGCAS-202204)support from the Youth Innovation Promotion Association CAS (Grant No.2019067)。
文摘The Tibetan Plateau is one of the most complicated geographical units worldwide in terms of its tectonic and environmental background.Although a hotspot for continental weathering and carbon cycling studies,accurate determination of the weathering carbon budget is challenging in this area,especially sink and source flux quantification and the controlling mechanisms.Compared with other major rivers on the plateau,the Nujiang River is characterized by less human disturbance and maintains a relatively pristine state.This study investigates the high spatiotemporal resolution hydrochemistry and dual-carbon isotope composition(δ~(13)C_(DIC)andΔ~(14)C_(DIC))of river water in the Nujiang River Basin.The results revealed that the solutes and dissolved inorganic carbon in the river water are predominantly derived from rock weathering by carbonic and sulfuric acids,mainly due to the carbonate weathering process,and significantly enhanced by deep carbon sourcing from hot springs in the fault zone.The average contributions of geological and modern carbon in the main stream of the Nujiang River are 35.2%and 64.8%,respectively,and sulfide oxidation contributes>90%of sulfate ions in the river water.After considering the involvement of sulfuric acid generated by sulfide oxidation during rock weathering,the calculated consumption fluxes of atmospheric CO_(2) by silicate and carbonate weathering in the watershed were decreased by approximately 52.0%and 37.4%,respectively,compared with those calculated ignoring this process.Rock weathering of the Nujiang River Basin is a“CO_(2) sink”on a short time scale,while the participation of sulfuric acid makes it a“CO_(2) source”on a geological time scale.The high-frequency observations of ion concentrations,elemental ratios,and calculated contributions of different rock weathering materials indicate that carbonate rock weathering is more sensitive to temperature and runoff variations than silicate rock weathering,with the solute contribution from carbonate weathering increasing significantly during monsoon period.The material input from different rock types is dominated by the hydrological pathways and water-rock reaction times in the basin.This study reveals the river solute origins and weathering CO_(2) sequestration effect in response to a monsoonal climate in one of the most representative pristine plateau watersheds in the world,which is of great importance for elucidating the weathering control mechanisms and CO_(2) net sourcesink effect in plateau watersheds.
文摘In the Tano River Basin,groundwater serves as a crucial resource;however,its quantity and quality with regard to trace elements and microbiological loadings remain poorly understood due to the lack of groundwater logs and limited water research.This study presents a comprehensive analysis of the Tano River Basin,focusing on three key objectives.First,it investigated the aquifer hydraulic parameters and the results showed significant spatial variations in borehole depths,yields,transmissivity,hydraulic conductivity,and specific capacity.Deeper boreholes were concentrated in the northeastern and southeastern zones,while geological formations,particu-larly the Apollonian Formation,exhibit a strong influence on borehole yields.The study identified areas with high transmissivity and hydraulic conductivity in the southern and eastern regions,suggesting good groundwater avail-ability and suitability for sustainable water supply.Sec-ondly,the research investigated the groundwater quality and observed that the majority of borehole samples fall within WHO(Guidelines for Drinking-water Quality,Environmental Health Criteria,Geneva,2011,2017.http://www.who.int)limit.However,some samples have pH levels below the standards,although the groundwater generally qualifies as freshwater.The study further explores hydrochemical facies and health risk assessment,highlighting the dominance of Ca–HCO3 water type.Trace element analysis reveals minimal health risks from most elements,with chromium(Cr)as the primary contributor to chronic health risk.Overall,this study has provided a key insights into the Tano River Basin’s hydrogeology and associated health risks.The outcome of this research has contributed to the broader understanding of hydrogeologi-cal dynamics and the importance of managing groundwater resources sustainably in complex geological environments.
