The phase diagram of InCl3-MBIC was constructed by DSC method. A clear, colorless and mobile ionic liquid was obtained and liquid down to 258 K. Both Raman scattering and ab initio calculations indicate that InCl4- ...The phase diagram of InCl3-MBIC was constructed by DSC method. A clear, colorless and mobile ionic liquid was obtained and liquid down to 258 K. Both Raman scattering and ab initio calculations indicate that InCl4- is the predominant anion.展开更多
A unified strategy toward the construction of the [5.7.6]tricyclic skeleton of liphagal is reported,featuring InCl3-mediated intramolecular Friedel-Crafts-type cyclization.
An efficient and straightforward procedure has been developed for the synthesis of highly substituted mono- and bis-N-aryl-3-aminodihydropyrrol-2-one-4-carboxylates via a one-pot, four-component domino reaction of ami...An efficient and straightforward procedure has been developed for the synthesis of highly substituted mono- and bis-N-aryl-3-aminodihydropyrrol-2-one-4-carboxylates via a one-pot, four-component domino reaction of amines, dialkyl acetylenedicarboxylates and formaldehyde in the presence of InCl3 （20 mol%） in MeOH at ambient temperature. The salient advantages of this method are mild reaction conditions, environmentally benign, high to excellent yields, shorter reaction times, easy operation and no column chromatographic separation.展开更多
基金supportcd by NSFC(20041005)．by NSF of Liaoning provincc(20011O2O35)；by Education Burcau of Liaoning prox，incc．
文摘The phase diagram of InCl3-MBIC was constructed by DSC method. A clear, colorless and mobile ionic liquid was obtained and liquid down to 258 K. Both Raman scattering and ab initio calculations indicate that InCl4- is the predominant anion.
基金supported by the grants of National Basic Research Program(973 Program,2010CB833201 & 2009CB940904)the National Science and Technology Major Project "Development of Key Technology for the Combinatorial Synthesis of Privileged Scaffolds" (2009ZX09501-012)the National Natural Science Foundation of China(20821062,20832003 and 20902007)
文摘A unified strategy toward the construction of the [5.7.6]tricyclic skeleton of liphagal is reported,featuring InCl3-mediated intramolecular Friedel-Crafts-type cyclization.
基金support from the Research Council of University of Sistan and Baluchestan and Payame Noor University
文摘An efficient and straightforward procedure has been developed for the synthesis of highly substituted mono- and bis-N-aryl-3-aminodihydropyrrol-2-one-4-carboxylates via a one-pot, four-component domino reaction of amines, dialkyl acetylenedicarboxylates and formaldehyde in the presence of InCl3 （20 mol%） in MeOH at ambient temperature. The salient advantages of this method are mild reaction conditions, environmentally benign, high to excellent yields, shorter reaction times, easy operation and no column chromatographic separation.
