5-（Hydroxymethyl） isophthalic acid （H2HIA） as a novel organic ligand was prepared from 3,5-bis（methoxycarbonyl）benzoic acid by a two-step method. And then, a 3D helical coor- dination polymer with a 3-fold inter...5-（Hydroxymethyl） isophthalic acid （H2HIA） as a novel organic ligand was prepared from 3,5-bis（methoxycarbonyl）benzoic acid by a two-step method. And then, a 3D helical coor- dination polymer with a 3-fold interpenetration structure, namely [Zn1/2（HIA）1/2（DPEE）1/2]n （1）, was hydrothermally synthesized at 160 ℃, using H2HIA ligands to assemble with DPEE ligands and Zn2＋ ions. Complex 1 crystalizes in orthorhombic system, space group Pnna, with a = 8.2118（5）, b = 17.1698（7）, c =14.9922（7） ？, V = 2113.82（18） ？3, μ = 1.194 mm-1, Z = 4 and S = 0.967. Moreover, some physical characteristics of complex 1, such as powder X-ray diffraction （PXRD）, thermogravimetry analyses （TGA） and photoluminescent properties, were also investigated.展开更多
Three indium metal-organic frameworks （In-MOFs）, [In（BTB）（2,2＇-bipy）]？NMP （1）, [In（BTB）（2,2＇-bipy）]？NMP？2H2O （2）, and [In（BTB）（NMP）]·0.5NMP （3）, have been constructed by the solvothermal ...Three indium metal-organic frameworks （In-MOFs）, [In（BTB）（2,2＇-bipy）]？NMP （1）, [In（BTB）（2,2＇-bipy）]？NMP？2H2O （2）, and [In（BTB）（NMP）]·0.5NMP （3）, have been constructed by the solvothermal reaction of In（NO3）3·5H2O and 1,3,5-benzenetribenzoic acid （H3BTB） in similar reaction conditions, and characterized by single-crystal X-ray crystallography, power X-ray diffraction （PXRD）, infrared spectroscopy （IR）, elemental analysis （EA） and thermogravimetry analysis （TGA）. Complex 1 bears a two-dimensional （2D） layered structure of 6,3-connected hcb net topology, and complexes 2 and 3 have 2-fold interpenetrating structures based on 6,3-connected layer, which display the same net topologies with the C3-symmetric H3BTB ligands as 3-connected linkers and the In（Ⅲ） ions as 6-connected nodes. Moreover, the fluorescent properties of 1～3 have also been studied.展开更多
The concept of entanglement provides the basis of our current understanding of the flow behavior of polymer melts, Current techniques developed to investigate the degree of interpenetration of polymer chains only prov...The concept of entanglement provides the basis of our current understanding of the flow behavior of polymer melts, Current techniques developed to investigate the degree of interpenetration of polymer chains only provide indirectly the information of the degree of entanglement in a relatively large scale （several to tens of nanometer）. In this article, we report ^1H-NMR spectroscopy with dipolar filters under fast magic angle spinning for probing chain interpenetration of polymer glasses at the molecular level.展开更多
The effects of atomic-level rnixing are systemically investigated in a multifluid interpenetration mix model ,and results are compared with the single-fluid model＇s simulations and experimental data. It is shown that...The effects of atomic-level rnixing are systemically investigated in a multifluid interpenetration mix model ,and results are compared with the single-fluid model＇s simulations and experimental data. It is shown that increasing the model free parameter α, shock Mach number, and the initial density discontinuity makes the mix length and fraction of mixing particle increase, resulting in the lower shock temperatures compared with the results of single-fluid model without mixing. Recent high-compressibility direct-drive spherical implosions on OMEGA are simulated by the interpenetration mix modal. The calculations with atomic mixing between fuel and shell match quite well with the observations. Without considering any mixing, the calculated neutron yields and ion temperatures are overpredicted; while inclusion of the interpenetration mix model with the adjustable parameter α could fit the simulated neutron yields and ion temperatures well with experimental data.展开更多
Hydrogen-bonded organic frameworks(HOFs)are an emerging class of porous materials that hold promise for the adsorptive separation of industrially relevant gas mixtures.However,developing HOFs with high thermal stabili...Hydrogen-bonded organic frameworks(HOFs)are an emerging class of porous materials that hold promise for the adsorptive separation of industrially relevant gas mixtures.However,developing HOFs with high thermal stability and resistance to water remains a daunting challenge.We report here a microporous HOF(HIAM-103)assembled from a hexacarboxylate linker(2,4,6-trimethylbenzene-1,3,5-triylisophthalic acid,H6TMBTI).The compound crystallizes in the trigonal crystal system,and its structure is a four-fold interpenetrated network.Upon thermal activation,the single crystals remain intact,allowing for precise determination of the activated structure.HIAM-103 exhibits remarkable thermal and hydrothermal stability.Its microporous channels demonstrate selective adsorption of C_(2)H_(6)over C_(2)H_(4)and Xe over Kr,and its separation capability toward mixed gases has been validated by column breakthrough experiments under dry and humid conditions.The preferential gas adsorption sites and separation mechanisms have been uncovered through DFT analysis,which suggests that the methyl group decorated 1D channels are the primary reason for the selective adsorption.展开更多
This paper shows a didactic model (PGM), and not only, but representative of the Hadrons described in the Standard Model (SM). In this model, particles are represented by structures corresponding to geometric shapes o...This paper shows a didactic model (PGM), and not only, but representative of the Hadrons described in the Standard Model (SM). In this model, particles are represented by structures corresponding to geometric shapes of coupled quantum oscillators (IQuO). By the properties of IQuO one can define the electric charge and that of color of quarks. Showing the “aurea” (golden) triangular shape of all quarks, we manage to represent the geometric combinations of the nucleons, light mesons, and K-mesons. By the geometric shape of W-bosons, we represent the weak decay of pions and charged Kaons and neutral, highlighting in geometric terms the possibilities of decay in two and three pions of neutral Kaon and the transition to anti-Kaon. In conclusion, from this didactic representation, an in-depth and exhaustive phenomenology of hadrons emerges, which even manages to resolve some problematic aspects of the SM.展开更多
This work shows a didactic model representative of the quarks described in the Standard Model (SM). In the model, particles are represented by structures corresponding to geometric shapes of coupled quantum oscillator...This work shows a didactic model representative of the quarks described in the Standard Model (SM). In the model, particles are represented by structures corresponding to geometric shapes of coupled quantum oscillators (GMP). From these didactic hypotheses emerges an in-depth phenomenology of particles (quarks) fully compatible with that of SM, showing, besides, that the number of possible quarks is six.展开更多
Two new azo-based coordination compounds with a flexible second ligand, crystal 1 （composed with [Zn（adc）（eda）],-1） and crystal 2 （composed with {[Zn（adc）]0.9568（eda）}n-1＇ and {[Zn（adc）]0.0414},） have b...Two new azo-based coordination compounds with a flexible second ligand, crystal 1 （composed with [Zn（adc）（eda）],-1） and crystal 2 （composed with {[Zn（adc）]0.9568（eda）}n-1＇ and {[Zn（adc）]0.0414},） have been synthe- sized as a couple of isomers with different reaction temperature. Adc2- and eda represent azobenzene-4,4＇-dicar- boxylic ion and 1,2-ethanediamine, respectively. Single crystal X-ray diffraction measurement indicates the inter- penetration of the above crystals could be suppressed by simply tuning the reaction temperature, that is, the 5-fold interpenetration which leads to no free volume left in lower temperature synthesized compound [Zn（adc）（eda）]n-1 could be reduced to a 4-fold interpenetration in higher temperature synthesized {[Zn（adc）]o.9568（eda）},-l＇ which re- sults in free volume accounting for 3.6% （3 1.6 A3 per unit cell volume） in crystal 2. The synthesis, crystal structure and fluorescence spectra of crystals 1 and 2 have been discussed, together with the data of elemental analysis and X-ray powder diffraction.展开更多
The architectural design of electrodes offers new opportunities for next-generation electrochemical energy storage devices(EESDs)by increasing surface area,thickness,and active materials mass loading while maintaining...The architectural design of electrodes offers new opportunities for next-generation electrochemical energy storage devices(EESDs)by increasing surface area,thickness,and active materials mass loading while maintaining good ion diffusion through optimized electrode tortuosity.However,conventional thick electrodes increase ion diffusion length and cause larger ion concentration gradients,limiting reaction kinetics.We demonstrate a strategy for building interpenetrated structures that shortens ion diffusion length and reduces ion concentration inhomogeneity.This free-standing device structure also avoids short-circuiting without needing a separator.The feature size and number of interpenetrated units can be adjusted during printing to balance surface area and ion diffusion.Starting with a 3D-printed interpenetrated polymer substrate,we metallize it to make it conductive.This substrate has two individually addressable electrodes,allowing selective electrodeposition of energy storage materials.Using a Zn//MnO_(2) battery as a model system,the interpenetrated device outperforms conventional separate electrode configurations,improving volumetric energy density by 221%and exhibiting a higher capacity retention rate of 49%compared to 35%at temperatures from 20 to 0℃.Our study introduces a new EESD architecture applicable to Li-ion,Na-ion batteries,supercapacitors,etc.展开更多
In this study,acrylic acid was used as a neutralizer to prepare bio-based WPU with an interpenetrating polymer network structure by thermally induced free radical emulsion polymerization.The effects of the content of ...In this study,acrylic acid was used as a neutralizer to prepare bio-based WPU with an interpenetrating polymer network structure by thermally induced free radical emulsion polymerization.The effects of the content of acrylic acid on the properties of the resulting waterborne polyurethane-poly(acrylic acid)(WPU-PAA)dispersion and the films were systematically investigated.The results showed that the cross-linking density of the interpenetrating network polymers was increased and the interlocking structure of the soft and hard phase dislocations in the molecular segments of the double networks was tailored with increasing the content of acrylic acid,leading to enhancement of the mechanical properties and water resistance of WPU-PAA films.Notably,with the increase in content of acrylic acid,the tensile strength,Young’s modulus,and toughness of the WPU-PAA-110 film increased by 3 times,and 8 times,and 2.4 times compared with WPU-PAA-80,respectively.The WPU-PAA-100 film showed the best water resistance,and the water absorption rate at 96 h was only 3.27%.This work provided a new design scheme for constructing bio-based WPU materials with excellent properties.展开更多
The title coordination polymer including two crystallographically independent Co2＋ ions is hydrothermally synthesized, in which the Co（1） 2＋ ion is four-coordinated by two carboxylate oxygen atoms from two differe...The title coordination polymer including two crystallographically independent Co2＋ ions is hydrothermally synthesized, in which the Co（1） 2＋ ion is four-coordinated by two carboxylate oxygen atoms from two different 5-（benzoic acid-4-yldiazenyl）isophthalate （byip3-） anions and two nitrogen atoms from two distinct 1,4-bis（imidazol-1-ylmethyl） benzene （bix） ligands displaying a tetrahedral geometry. The Co（2） 2＋ ion is six-coordinated by two water molecules at the apical positions, and two carboxylate oxygen atoms and two nitrogen atoms at the equatorial positions, affording a slightly distorted octahedron. Two Co（1）2＋ and two Co（2）2＋ ions are linked together by four byip3- anions forming a 44-membered motif and these motifs are further arranged into a three-dimensional framework through bix ligands along the a axis with a larger channel （ca. 22.70×11.01）. Each individual network interpenetrates with the other identical network in a parallel fashion to generate a 2-fold interpenetrating array with the {62.84}{63}2{64.82}2 topology.展开更多
A three-dimensional coordination polymer,[Ni（Hbyip2-）（bix）0.5（H2O）]n,has been hydrothermally synthesized.Each Ni2＋ ion is five-coordinated by three carboxylate O atoms from three different 5-（benzoic acid-4-yl...A three-dimensional coordination polymer,[Ni（Hbyip2-）（bix）0.5（H2O）]n,has been hydrothermally synthesized.Each Ni2＋ ion is five-coordinated by three carboxylate O atoms from three different 5-（benzoic acid-4-yldiazenyl）isophthalate（Hbyip2-） anions,one N atom from one 1,4-bis（imidazol-1-ylmethyl）benzene（bix） ligand and one O atom from an aqua ligand displaying a distorted square-pyramid.Each Ni atom is defined by three Hbyip2-anions and each Hbyip2-anion adopts a tris（mono-dentate） ligand coordinating to three Ni2＋ ions affording a 36-membered inorganic ring.These rings are further arranged into an undulated two-dimensional layer parallel to the（101） plane.Adjacent two-dimensional networks are linked by bix ligands into a three-dimensional {63,83}{63} framework with a large channel（ca.26.3 × 13.6） along the [100] direction.Each individual {63,83}{63} network interpenetrates with two others in a parallel fashion to generate a 3-fold interpenetrating network.展开更多
A new Co（Ⅱ）-based coordination polymer, namely [Co（L）0.5（4,4?-bipy）0.5（H2 O）2]n（1,H4 L = 1,3-di（3?,5?-dicarboxylphenyl）benzene, 4,4?-bipy = 4,4?-bipyridine）, has been hydrothermally synthesized using the ...A new Co（Ⅱ）-based coordination polymer, namely [Co（L）0.5（4,4?-bipy）0.5（H2 O）2]n（1,H4 L = 1,3-di（3?,5?-dicarboxylphenyl）benzene, 4,4?-bipy = 4,4?-bipyridine）, has been hydrothermally synthesized using the mixed-ligands self-assembly strategy and further fully characterized. The crystal structure is of monoclinic, space group C2/c with a = 18.9124（10）, b = 11.6150（5）, c =15.4380（6） ?, β = 110.989（5）°, V = 3166.2（2） ?3, C16 H13 CoNO6, Mr = 374.20, Z = 8, Dc = 1.570 g·cm–3, F（000） = 1496, μ = 1.116 mm–1, R = 0.0461 and wR = 0.1312 for 2328 observed reflections（I > 2s（I））. The crystal structure analysis revealed that 1 is a 4-fold interpenetrated three-dimensional（3D） framework with（3,4）-connected dmd-type topology. Moreover, the thermal stability and magnetic property of 1 were also investigated.展开更多
Highlighting a golden triangular form in <em>u</em> and <em>d </em>quarks (Quark Geometric Model), we build the geometric structures of light meson <em>η</em> and individualize its...Highlighting a golden triangular form in <em>u</em> and <em>d </em>quarks (Quark Geometric Model), we build the geometric structures of light meson <em>η</em> and individualize its decays and spin. By the structure equations describing mesons, we determine a mathematic procedure to calculate the theoretical value of the mass of light mesons <em>η</em>.展开更多
In previous articles (Guido) we demonstrated that Quarks (u, d) are represented by golden geometric structures of coupled quantum oscillators. In this article we show the geometric structure of the pion triplet and, i...In previous articles (Guido) we demonstrated that Quarks (u, d) are represented by golden geometric structures of coupled quantum oscillators. In this article we show the geometric structure of the pion triplet and, in particular, via the structure equation of neutral pion, we identify its decays and we solve the spin question in hadrons thanks also to introduction of algebraic operations [?, ⊕] on geometric structure. Moreover by means of the golden ratio between (u, d), we determine the values of bare masses of quarks (3.51 MeV for u-quark and 5.67 MeV for d-quark) and those ones bounded in a pion (53.31 MeV for u-quark and 85.26 MeV for d-quark). Finally, using algebraic operations [?, ⊕] we point out a new way to represent the processes of pions’ decay.展开更多
Two fascinating Zn（II）entangled coordination polymers,[Zn（eoba）(bbi)];·nH;O（1）and[Zn（boba）(bbi);];（2）,(bbi=1,1?-（1,4-butanediyl）-bis（imidazole）,H;eoba=4,4?-（ethane-1,2-diyldioxy）-dibenzoic acid,H;...Two fascinating Zn（II）entangled coordination polymers,[Zn（eoba）(bbi)];·nH;O（1）and[Zn（boba）(bbi);];（2）,(bbi=1,1?-（1,4-butanediyl）-bis（imidazole）,H;eoba=4,4?-（ethane-1,2-diyldioxy）-dibenzoic acid,H;boba=4,4?-（butane-1,4-diyldioxy）-dibenzoic acid),were obtained by hydrothermal technology and characterized by elemental analysis,infrared spectrum,thermogravimetric analysis and single-crystal X-ray diffraction.1 is a rare 2D→3D example with a 3-fold parallel interpenetration and polycatenaned architecture.2 features a scarce2D→2D example with a 3-fold parallel interpenetrating network which possesses polyrotaxane and polycatenane characters.Moreover,the luminescent properties of 1 and 2 have been discussed.展开更多
In this paper, we show a new theoretical procedure for calculating the nucleonic mass values. We develop this procedure on the geometric representation of (u, d) quarks, these seen as golden structures of coupled quan...In this paper, we show a new theoretical procedure for calculating the nucleonic mass values. We develop this procedure on the geometric representation of (u, d) quarks, these seen as golden structures of coupled quantum oscillators (Aureum Geometric Model or AGM). Using AGM, we also build the geometric structures of nucleons (p, n), determining their structure equations and spins. Thank AGM, coherent to QCD, new aspects of the Quantum Mechanics emerge, opening to anew descriptive paradigm in Particle Physics.展开更多
Using the “Aureum Geometric Model” (AGM) of quarks, we formulate the structure equations describing mesons and, by a mathematic procedure, we calculate the theoretical spectrum of mass values of light mesons without...Using the “Aureum Geometric Model” (AGM) of quarks, we formulate the structure equations describing mesons and, by a mathematic procedure, we calculate the theoretical spectrum of mass values of light mesons without strangeness.展开更多
The gel polymer electrolytes（GPEs）based on poly（vinylidence fluoride）（PVDF）/acrylate interpenetrating polymer network（IPN）are prepared.The micro-phase separation type GPEs are characterized by Fourier transfor...The gel polymer electrolytes（GPEs）based on poly（vinylidence fluoride）（PVDF）/acrylate interpenetrating polymer network（IPN）are prepared.The micro-phase separation type GPEs are characterized by Fourier transform infrared（FTIR）spectroscopy,scanning electron microscope（SEM）,respectively.Moreover,the conductivity and the voltage-current curves of the electrolytes are measured by electrochemical workstation.The higher porosity and electrolyte uptake are observed in the membranes prepared at lower crosslinker concentration.The suitable cross-linking acrylate monomer improves the porosity and the electrochemical behavior of GPE.A dye-sensitized solar cell（DSSC）employing PGE based on PVDF/poly（ethylene glycol dimethacrylate）（PEGDMA）IPN yields an open-circuit voltage of 0.674 V,short-circuit current of 8.476 mA·cm-2and the conversion efficiency of 2.710% under 100 mW·cm-2illumination.展开更多
In this paper, using the AGM model (Aureum Geometric Model), where geometric structures of coupled quantum oscillators represent particles, we formulate a new hypothesis about the origin of the Dark Matter (DM). Highl...In this paper, using the AGM model (Aureum Geometric Model), where geometric structures of coupled quantum oscillators represent particles, we formulate a new hypothesis about the origin of the Dark Matter (DM). Highlighting its hadronic nature, we identify the representative particle’s particular geometric structure, the “dark pion”, and calculate its mass. Finally, we propose an experiment for the detection of this particle.展开更多
基金supported by the Natural Science Foundation of Guizhou Province(20122344)125 program of Guizhou Education Department(2012015)the Doctoral Scientific Fund of Zunyi Normal College(2012BSJJ12)
文摘5-（Hydroxymethyl） isophthalic acid （H2HIA） as a novel organic ligand was prepared from 3,5-bis（methoxycarbonyl）benzoic acid by a two-step method. And then, a 3D helical coor- dination polymer with a 3-fold interpenetration structure, namely [Zn1/2（HIA）1/2（DPEE）1/2]n （1）, was hydrothermally synthesized at 160 ℃, using H2HIA ligands to assemble with DPEE ligands and Zn2＋ ions. Complex 1 crystalizes in orthorhombic system, space group Pnna, with a = 8.2118（5）, b = 17.1698（7）, c =14.9922（7） ？, V = 2113.82（18） ？3, μ = 1.194 mm-1, Z = 4 and S = 0.967. Moreover, some physical characteristics of complex 1, such as powder X-ray diffraction （PXRD）, thermogravimetry analyses （TGA） and photoluminescent properties, were also investigated.
基金Supported by the National Natural Science Foundation of China(No.21371179,21201179)the Fundamental Research Funds for the Central Universities(14CX02213A,16CX05015A)the Foundation of State Key Laboratory of Structural Chemistry(20150026,20160006)
文摘Three indium metal-organic frameworks （In-MOFs）, [In（BTB）（2,2＇-bipy）]？NMP （1）, [In（BTB）（2,2＇-bipy）]？NMP？2H2O （2）, and [In（BTB）（NMP）]·0.5NMP （3）, have been constructed by the solvothermal reaction of In（NO3）3·5H2O and 1,3,5-benzenetribenzoic acid （H3BTB） in similar reaction conditions, and characterized by single-crystal X-ray crystallography, power X-ray diffraction （PXRD）, infrared spectroscopy （IR）, elemental analysis （EA） and thermogravimetry analysis （TGA）. Complex 1 bears a two-dimensional （2D） layered structure of 6,3-connected hcb net topology, and complexes 2 and 3 have 2-fold interpenetrating structures based on 6,3-connected layer, which display the same net topologies with the C3-symmetric H3BTB ligands as 3-connected linkers and the In（Ⅲ） ions as 6-connected nodes. Moreover, the fluorescent properties of 1～3 have also been studied.
文摘The concept of entanglement provides the basis of our current understanding of the flow behavior of polymer melts, Current techniques developed to investigate the degree of interpenetration of polymer chains only provide indirectly the information of the degree of entanglement in a relatively large scale （several to tens of nanometer）. In this article, we report ^1H-NMR spectroscopy with dipolar filters under fast magic angle spinning for probing chain interpenetration of polymer glasses at the molecular level.
基金Supported by the National Basic Research Program of China under Grant No.2007CB815100the National Natural Science Foundation of China under Grant Nos.10775020 and 10935003
文摘The effects of atomic-level rnixing are systemically investigated in a multifluid interpenetration mix model ,and results are compared with the single-fluid model＇s simulations and experimental data. It is shown that increasing the model free parameter α, shock Mach number, and the initial density discontinuity makes the mix length and fraction of mixing particle increase, resulting in the lower shock temperatures compared with the results of single-fluid model without mixing. Recent high-compressibility direct-drive spherical implosions on OMEGA are simulated by the interpenetration mix modal. The calculations with atomic mixing between fuel and shell match quite well with the observations. Without considering any mixing, the calculated neutron yields and ion temperatures are overpredicted; while inclusion of the interpenetration mix model with the adjustable parameter α could fit the simulated neutron yields and ion temperatures well with experimental data.
基金Shenzhen Science and Technology Program(No.RCYX20200714114539243,KCXFZ20211020163818026)the U.S.Department of Energy,Office of Science,Office of Basic Energy Sciences,under Award No.DE-SC0019902.
文摘Hydrogen-bonded organic frameworks(HOFs)are an emerging class of porous materials that hold promise for the adsorptive separation of industrially relevant gas mixtures.However,developing HOFs with high thermal stability and resistance to water remains a daunting challenge.We report here a microporous HOF(HIAM-103)assembled from a hexacarboxylate linker(2,4,6-trimethylbenzene-1,3,5-triylisophthalic acid,H6TMBTI).The compound crystallizes in the trigonal crystal system,and its structure is a four-fold interpenetrated network.Upon thermal activation,the single crystals remain intact,allowing for precise determination of the activated structure.HIAM-103 exhibits remarkable thermal and hydrothermal stability.Its microporous channels demonstrate selective adsorption of C_(2)H_(6)over C_(2)H_(4)and Xe over Kr,and its separation capability toward mixed gases has been validated by column breakthrough experiments under dry and humid conditions.The preferential gas adsorption sites and separation mechanisms have been uncovered through DFT analysis,which suggests that the methyl group decorated 1D channels are the primary reason for the selective adsorption.
文摘This paper shows a didactic model (PGM), and not only, but representative of the Hadrons described in the Standard Model (SM). In this model, particles are represented by structures corresponding to geometric shapes of coupled quantum oscillators (IQuO). By the properties of IQuO one can define the electric charge and that of color of quarks. Showing the “aurea” (golden) triangular shape of all quarks, we manage to represent the geometric combinations of the nucleons, light mesons, and K-mesons. By the geometric shape of W-bosons, we represent the weak decay of pions and charged Kaons and neutral, highlighting in geometric terms the possibilities of decay in two and three pions of neutral Kaon and the transition to anti-Kaon. In conclusion, from this didactic representation, an in-depth and exhaustive phenomenology of hadrons emerges, which even manages to resolve some problematic aspects of the SM.
文摘This work shows a didactic model representative of the quarks described in the Standard Model (SM). In the model, particles are represented by structures corresponding to geometric shapes of coupled quantum oscillators (GMP). From these didactic hypotheses emerges an in-depth phenomenology of particles (quarks) fully compatible with that of SM, showing, besides, that the number of possible quarks is six.
文摘Two new azo-based coordination compounds with a flexible second ligand, crystal 1 （composed with [Zn（adc）（eda）],-1） and crystal 2 （composed with {[Zn（adc）]0.9568（eda）}n-1＇ and {[Zn（adc）]0.0414},） have been synthe- sized as a couple of isomers with different reaction temperature. Adc2- and eda represent azobenzene-4,4＇-dicar- boxylic ion and 1,2-ethanediamine, respectively. Single crystal X-ray diffraction measurement indicates the inter- penetration of the above crystals could be suppressed by simply tuning the reaction temperature, that is, the 5-fold interpenetration which leads to no free volume left in lower temperature synthesized compound [Zn（adc）（eda）]n-1 could be reduced to a 4-fold interpenetration in higher temperature synthesized {[Zn（adc）]o.9568（eda）},-l＇ which re- sults in free volume accounting for 3.6% （3 1.6 A3 per unit cell volume） in crystal 2. The synthesis, crystal structure and fluorescence spectra of crystals 1 and 2 have been discussed, together with the data of elemental analysis and X-ray powder diffraction.
基金financial support from the Center for Coastal Climate Resilience of the University of California,Santa Cruz(UCSC)This work was performed under the auspices of the US Department of Energy by Lawrence Livermore National Laboratory under Contract No.DE-AC52-07NA27344 and supported by Laboratory Directed Research and Development award 23-SI-002.IM release number:LLNL-JRNL-862347。
文摘The architectural design of electrodes offers new opportunities for next-generation electrochemical energy storage devices(EESDs)by increasing surface area,thickness,and active materials mass loading while maintaining good ion diffusion through optimized electrode tortuosity.However,conventional thick electrodes increase ion diffusion length and cause larger ion concentration gradients,limiting reaction kinetics.We demonstrate a strategy for building interpenetrated structures that shortens ion diffusion length and reduces ion concentration inhomogeneity.This free-standing device structure also avoids short-circuiting without needing a separator.The feature size and number of interpenetrated units can be adjusted during printing to balance surface area and ion diffusion.Starting with a 3D-printed interpenetrated polymer substrate,we metallize it to make it conductive.This substrate has two individually addressable electrodes,allowing selective electrodeposition of energy storage materials.Using a Zn//MnO_(2) battery as a model system,the interpenetrated device outperforms conventional separate electrode configurations,improving volumetric energy density by 221%and exhibiting a higher capacity retention rate of 49%compared to 35%at temperatures from 20 to 0℃.Our study introduces a new EESD architecture applicable to Li-ion,Na-ion batteries,supercapacitors,etc.
基金by the Research and Development Program in Key Areas of Guangdong Province(Grant No.2020B0202010008)Guangdong Province Science&Technology Program(2018B030306016)+1 种基金Guangdong Provincial Innovation Team for General Key Technologies in Modern Agricultural Industry(2019KJ133)Key Projects of Basic Research and Applied Basic Research of the Higher Education Institutions of Guangdong Province(2018KZDXM014).
文摘In this study,acrylic acid was used as a neutralizer to prepare bio-based WPU with an interpenetrating polymer network structure by thermally induced free radical emulsion polymerization.The effects of the content of acrylic acid on the properties of the resulting waterborne polyurethane-poly(acrylic acid)(WPU-PAA)dispersion and the films were systematically investigated.The results showed that the cross-linking density of the interpenetrating network polymers was increased and the interlocking structure of the soft and hard phase dislocations in the molecular segments of the double networks was tailored with increasing the content of acrylic acid,leading to enhancement of the mechanical properties and water resistance of WPU-PAA films.Notably,with the increase in content of acrylic acid,the tensile strength,Young’s modulus,and toughness of the WPU-PAA-110 film increased by 3 times,and 8 times,and 2.4 times compared with WPU-PAA-80,respectively.The WPU-PAA-100 film showed the best water resistance,and the water absorption rate at 96 h was only 3.27%.This work provided a new design scheme for constructing bio-based WPU materials with excellent properties.
基金Supported by the Natural Science Foundation of Henan Province (No. 102300410021 and 102300410093)
文摘The title coordination polymer including two crystallographically independent Co2＋ ions is hydrothermally synthesized, in which the Co（1） 2＋ ion is four-coordinated by two carboxylate oxygen atoms from two different 5-（benzoic acid-4-yldiazenyl）isophthalate （byip3-） anions and two nitrogen atoms from two distinct 1,4-bis（imidazol-1-ylmethyl） benzene （bix） ligands displaying a tetrahedral geometry. The Co（2） 2＋ ion is six-coordinated by two water molecules at the apical positions, and two carboxylate oxygen atoms and two nitrogen atoms at the equatorial positions, affording a slightly distorted octahedron. Two Co（1）2＋ and two Co（2）2＋ ions are linked together by four byip3- anions forming a 44-membered motif and these motifs are further arranged into a three-dimensional framework through bix ligands along the a axis with a larger channel （ca. 22.70×11.01）. Each individual network interpenetrates with the other identical network in a parallel fashion to generate a 2-fold interpenetrating array with the {62.84}{63}2{64.82}2 topology.
基金Supported by the Natural Science Foundation of Henan Province(No.092300410119 and 102300410093)
文摘A three-dimensional coordination polymer,[Ni（Hbyip2-）（bix）0.5（H2O）]n,has been hydrothermally synthesized.Each Ni2＋ ion is five-coordinated by three carboxylate O atoms from three different 5-（benzoic acid-4-yldiazenyl）isophthalate（Hbyip2-） anions,one N atom from one 1,4-bis（imidazol-1-ylmethyl）benzene（bix） ligand and one O atom from an aqua ligand displaying a distorted square-pyramid.Each Ni atom is defined by three Hbyip2-anions and each Hbyip2-anion adopts a tris（mono-dentate） ligand coordinating to three Ni2＋ ions affording a 36-membered inorganic ring.These rings are further arranged into an undulated two-dimensional layer parallel to the（101） plane.Adjacent two-dimensional networks are linked by bix ligands into a three-dimensional {63,83}{63} framework with a large channel（ca.26.3 × 13.6） along the [100] direction.Each individual {63,83}{63} network interpenetrates with two others in a parallel fashion to generate a 3-fold interpenetrating network.
基金supported by the grants from Guangdong University of Petrochemical Technology
文摘A new Co（Ⅱ）-based coordination polymer, namely [Co（L）0.5（4,4?-bipy）0.5（H2 O）2]n（1,H4 L = 1,3-di（3?,5?-dicarboxylphenyl）benzene, 4,4?-bipy = 4,4?-bipyridine）, has been hydrothermally synthesized using the mixed-ligands self-assembly strategy and further fully characterized. The crystal structure is of monoclinic, space group C2/c with a = 18.9124（10）, b = 11.6150（5）, c =15.4380（6） ?, β = 110.989（5）°, V = 3166.2（2） ?3, C16 H13 CoNO6, Mr = 374.20, Z = 8, Dc = 1.570 g·cm–3, F（000） = 1496, μ = 1.116 mm–1, R = 0.0461 and wR = 0.1312 for 2328 observed reflections（I > 2s（I））. The crystal structure analysis revealed that 1 is a 4-fold interpenetrated three-dimensional（3D） framework with（3,4）-connected dmd-type topology. Moreover, the thermal stability and magnetic property of 1 were also investigated.
文摘Highlighting a golden triangular form in <em>u</em> and <em>d </em>quarks (Quark Geometric Model), we build the geometric structures of light meson <em>η</em> and individualize its decays and spin. By the structure equations describing mesons, we determine a mathematic procedure to calculate the theoretical value of the mass of light mesons <em>η</em>.
文摘In previous articles (Guido) we demonstrated that Quarks (u, d) are represented by golden geometric structures of coupled quantum oscillators. In this article we show the geometric structure of the pion triplet and, in particular, via the structure equation of neutral pion, we identify its decays and we solve the spin question in hadrons thanks also to introduction of algebraic operations [?, ⊕] on geometric structure. Moreover by means of the golden ratio between (u, d), we determine the values of bare masses of quarks (3.51 MeV for u-quark and 5.67 MeV for d-quark) and those ones bounded in a pion (53.31 MeV for u-quark and 85.26 MeV for d-quark). Finally, using algebraic operations [?, ⊕] we point out a new way to represent the processes of pions’ decay.
基金Supported by the Science and Technology Development plan of Jilin Province(20150520006JH)Science and Technology Research Project of Education Department of Jilin province(2016219,JJKH20180776KJ)Science and Technology Development plan of Siping City(2013055)
文摘Two fascinating Zn（II）entangled coordination polymers,[Zn（eoba）(bbi)];·nH;O（1）and[Zn（boba）(bbi);];（2）,(bbi=1,1?-（1,4-butanediyl）-bis（imidazole）,H;eoba=4,4?-（ethane-1,2-diyldioxy）-dibenzoic acid,H;boba=4,4?-（butane-1,4-diyldioxy）-dibenzoic acid),were obtained by hydrothermal technology and characterized by elemental analysis,infrared spectrum,thermogravimetric analysis and single-crystal X-ray diffraction.1 is a rare 2D→3D example with a 3-fold parallel interpenetration and polycatenaned architecture.2 features a scarce2D→2D example with a 3-fold parallel interpenetrating network which possesses polyrotaxane and polycatenane characters.Moreover,the luminescent properties of 1 and 2 have been discussed.
文摘In this paper, we show a new theoretical procedure for calculating the nucleonic mass values. We develop this procedure on the geometric representation of (u, d) quarks, these seen as golden structures of coupled quantum oscillators (Aureum Geometric Model or AGM). Using AGM, we also build the geometric structures of nucleons (p, n), determining their structure equations and spins. Thank AGM, coherent to QCD, new aspects of the Quantum Mechanics emerge, opening to anew descriptive paradigm in Particle Physics.
文摘Using the “Aureum Geometric Model” (AGM) of quarks, we formulate the structure equations describing mesons and, by a mathematic procedure, we calculate the theoretical spectrum of mass values of light mesons without strangeness.
文摘The gel polymer electrolytes（GPEs）based on poly（vinylidence fluoride）（PVDF）/acrylate interpenetrating polymer network（IPN）are prepared.The micro-phase separation type GPEs are characterized by Fourier transform infrared（FTIR）spectroscopy,scanning electron microscope（SEM）,respectively.Moreover,the conductivity and the voltage-current curves of the electrolytes are measured by electrochemical workstation.The higher porosity and electrolyte uptake are observed in the membranes prepared at lower crosslinker concentration.The suitable cross-linking acrylate monomer improves the porosity and the electrochemical behavior of GPE.A dye-sensitized solar cell（DSSC）employing PGE based on PVDF/poly（ethylene glycol dimethacrylate）（PEGDMA）IPN yields an open-circuit voltage of 0.674 V,short-circuit current of 8.476 mA·cm-2and the conversion efficiency of 2.710% under 100 mW·cm-2illumination.
文摘In this paper, using the AGM model (Aureum Geometric Model), where geometric structures of coupled quantum oscillators represent particles, we formulate a new hypothesis about the origin of the Dark Matter (DM). Highlighting its hadronic nature, we identify the representative particle’s particular geometric structure, the “dark pion”, and calculate its mass. Finally, we propose an experiment for the detection of this particle.
