Non-equilibrium solidification structures of Cu55Ni45 and Cu55Ni43Co2 alloys were prepared by the molten glass purification cycle superheating method.The variation of the recalescence phenomenon with the degree of und...Non-equilibrium solidification structures of Cu55Ni45 and Cu55Ni43Co2 alloys were prepared by the molten glass purification cycle superheating method.The variation of the recalescence phenomenon with the degree of undercooling in the rapid solidification process was investigated using an infrared thermometer.The addition of the Co element affected the evolution of the recalescence phenomenon in Cu-Ni alloys.The images of the solid-liquid interface migration during the rapid solidification of supercooled melts were captured by using a high-speed camera.The solidification rate of Cu-Ni alloys,with the addition of Co elements,was explored.Finally,the grain refinement structure with low supercooling was characterised using electron backscatter diffraction(EBSD).The effect of Co on the microstructural evolution during nonequilibrium solidification of Cu-Ni alloys under conditions of small supercooling is investigated by comparing the microstructures of Cu55Ni45 and Cu55Ni43Co2 alloys.The experimental results show that the addition of a small amount of Co weakens the recalescence behaviour of the Cu55Ni45 alloy and significantly reduces the thermal strain in the rapid solidification phase.In the rapid solidification phase,the thermal strain is greatly reduced,and there is a significant increase in the characteristic undercooling degree.Furthermore,the addition of Co and the reduction of Cu not only result in a lower solidification rate of the alloy,but also contribute to the homogenisation of the grain size.展开更多
The effect of the gradient content of Co element on the solidification process of Cu-based alloy under deep under cooling conditions was explored.The non-equilibrium solidification structure of the under cooled alloy ...The effect of the gradient content of Co element on the solidification process of Cu-based alloy under deep under cooling conditions was explored.The non-equilibrium solidification structure of the under cooled alloy samples were analyzed.It is found that the rapidly solidified alloy has undergone twice grain refinement during the undercooling process.Characterization and significance of the maximum undercooling refinement structure of Cu60Ni35Co5 at T=253 K were analyzed.High-density defects were observed,such as dislocations,stacking faults networks,and twinning structures.The standard FCC diffraction pattern represents that it is still a single-phase structure.Based on the metallographic diagram,EBSD and TEM data analysis,it is illustrated that the occurrence of grain refinement under high undercooling is due to stress induced recrystallization.In addition,the laser cladding technology is used to coat Co-based alloy(Stellite12) coating on 304 stainless steel substrate;the microstructure of the coating cross-section was analyzed.It was found that the microstructure of the cross-section is presented as columnar crystals,planar crystals,and disordered growth direction,so that the coating has better hardness and wear resistance.By electrochemical corrosion of the substrate and coating,it can be seen that the Co and Cr elements present in the coating are more likely to form a dense passivation film,which improved the corrosion resistance of the coating.展开更多
Long-term permeability experiments have indicated that sorption-induced swelling can switch from internal to bulk depending on the evolutive sorption status.However,this sorption swelling switch mechanism has not been...Long-term permeability experiments have indicated that sorption-induced swelling can switch from internal to bulk depending on the evolutive sorption status.However,this sorption swelling switch mechanism has not been considered in current analytical permeability models.This study introduces a normalized sorption non-equilibrium index(SNEI)to characterize the sorption status,quantify the dynamical variations of matrix swelling accumulation and internal swelling partition,and formulate the sorption swelling switch model.The incorporation of this index into the extended total effective stress concept leads to an analytical transient coal permeability model.Model results show that the sorption swelling switch itself results in the permeability switch under stress-constrained conditions,while the confined bulk swelling suppresses the permeability recovery to the continuous reduction under displacement-constrained conditions.Model verifications show that current experimental observations correspond to the early stages of the transient process,and they could be extended to the whole process with these models.This study demonstrates the importance of the sorption swelling switch in determining permeability evolution using simple boundary conditions.It provides new insights into experimentally revealing the sorption swelling switch in the future,and underscores the requirement of a rigorous model for complex coupled processes in large-scale coal seams.展开更多
The heat transfer through a concave permeable fin is analyzed by the local thermal non-equilibrium(LTNE)model.The governing dimensional temperature equations for the solid and fluid phases of the porous extended surfa...The heat transfer through a concave permeable fin is analyzed by the local thermal non-equilibrium(LTNE)model.The governing dimensional temperature equations for the solid and fluid phases of the porous extended surface are modeled,and then are nondimensionalized by suitable dimensionless terms.Further,the obtained nondimensional equations are solved by the clique polynomial method(CPM).The effects of several dimensionless parameters on the fin's thermal profiles are shown by graphical illustrations.Additionally,the current study implements deep neural structures to solve physics-governed coupled equations,and the best-suited hyperparameters are attained by comparison with various network combinations.The results of the CPM and physicsinformed neural network(PINN)exhibit good agreement,signifying that both methods effectively solve the thermal modeling problem.展开更多
Ultrafast transmission electron microscope(UTEM) with the multimodality of time-resolved diffraction, imaging,and spectroscopy provides a unique platform to reveal the fundamental features associated with the interact...Ultrafast transmission electron microscope(UTEM) with the multimodality of time-resolved diffraction, imaging,and spectroscopy provides a unique platform to reveal the fundamental features associated with the interaction between free electrons and matter. In this review, we summarize the principles, instrumentation, and recent developments of the UTEM and its applications in capturing dynamic processes and non-equilibrium transient states. The combination of the transmission electron microscope with a femtosecond laser via the pump–probe method guarantees the high spatiotemporal resolution, allowing the investigation of the transient process in real, reciprocal and energy spaces. Ultrafast structural dynamics can be studied by diffraction and imaging methods, revealing the coherent acoustic phonon generation and photoinduced phase transition process. In the energy dimension, time-resolved electron energy-loss spectroscopy enables the examination of the intrinsic electronic dynamics of materials, while the photon-induced near-field electron microscopy extends the application of the UTEM to the imaging of optical near fields with high real-space resolution. It is noted that light–free-electron interactions have the ability to shape electron wave packets in both longitudinal and transverse directions, showing the potential application in the generation of attosecond electron pulses and vortex electron beams.展开更多
Accurate knowledge of gas flow within the reservoir and related controlling factors will be important for enhancing the production of coal bed methane.At present,most studies focused on the permeability evolution of d...Accurate knowledge of gas flow within the reservoir and related controlling factors will be important for enhancing the production of coal bed methane.At present,most studies focused on the permeability evolution of dry coal under gas adsorption equilibrium,gas flow and gas diffusion within wet coal under the generally non-equilibrium state are often ignored in the process of gas recovery.In this study,an improved apparent permeability model is proposed which accommodates the water and gas adsorption,stress dependence,water film thickness and gas flow regimes.In the process of modeling,the water adsorption is only affected by water content while the gas adsorption is time and water content dependent;based on poroelastic mechanics,the effective fracture aperture and effective pore radius are derived;and then the variation in water film thickness for different pore types under the effect of water content,stress and adsorption swelling are modeled;the flow regimes are considered based on Beskok’s model.Further,after validation with experimental data,the proposed model was applied to numerical simulations to investigate the evolution of permeability-related factors under the effect of different water contents.The gas flow in wet coal under the non-equilibrium state is explicitly revealed.展开更多
Suspended sediment concentrations in the Middle Yangtze River(MYR)reduced greatly after the Three Gorges Project operation,causing the composition of bed material to coarsen continuously.However,little is known about ...Suspended sediment concentrations in the Middle Yangtze River(MYR)reduced greatly after the Three Gorges Project operation,causing the composition of bed material to coarsen continuously.However,little is known about the non-equilibrium transport of graded suspended sediment owing to different bed material compositions(BMCs)along the MYR,and it is necessary to determine the magnitude of recovery factor.Using the Markov stochastic process in conjunction with the hiding-exposure effect of non-uniform bed-material,a new formula is proposed for calculating the recovery factor including the effect of different BMCs,and it is incorporated into the non-equilibrium transport equation to simulate the recovery processes of suspended load in both sand-gravel bed and sand bed reaches of the MYR.The results show that:(i)the recovery rate of graded sediment concentrations at Zhicheng was slower than that at Shashi during the period 2003-2007;(ii)the mean recovery factors of the coarse,medium,and fine sediment fractions in the ZhichengShashi reach were 0.152,0.0012,and 0.0005,respectively,and the coarse sediment recovered up to the maximum sediment concentration of 0.138 kg/m3over a distance of 15 km;and(iii)the results of the new formula that can consider the effect of bed material composition are in general agreement with the field observations,and the spatial and temporal delay effects are inversely related to particle size and BMC.Consequently,the BMC effect on the nonequilibrium sediment transport in different reaches of the MYR needs to be considered for higher simulation accuracy.展开更多
The non-equilibrium between ions and electrons in the hot spot can relax the ignition conditions in inertial confinement fusion[Fan et al.,Phys.Plasmas 23,010703(2016)],and obvious ion-electron non-equilibrium could b...The non-equilibrium between ions and electrons in the hot spot can relax the ignition conditions in inertial confinement fusion[Fan et al.,Phys.Plasmas 23,010703(2016)],and obvious ion-electron non-equilibrium could be observed by our simulations of high-foot implosions when the ion-electron relaxation is enlarged by a factor of 2.On the other hand,in many shots of high-foot implosions on the National Ignition Facility,the observed X-ray enhancement factors due to ablator mixing into the hot spot are less than unity assuming electrons and ions have the same temperature[Meezan et al.,Phys.Plasmas 22,062703(2015)],which is not self-consistent because it can lead to negative ablator mixing into the hot spot.Actually,this non-consistency implies ion-electron non-equilibrium within the hot spot.From our study,we can infer that ion-electron non-equilibrium exists in high-foot implosions and the ion temperature could be~9%larger than the equilibrium temperature in some NIF shots.展开更多
This article summarized systematically the previous investigations on t he dielectric relaxation of wood, the main substances and extractives in wood at oven-dry state, and the dielectric relaxation based on the adso...This article summarized systematically the previous investigations on t he dielectric relaxation of wood, the main substances and extractives in wood at oven-dry state, and the dielectric relaxation based on the adsorbed water in w o od cell wall under equilibrium and non-equilibrium state. Moreover, some expect a tions for future research were proposed on this basis. The purpose of this artic le is to provide other researchers an overall understanding about the research i n this region, and further to promote the research onto a new and higher level.展开更多
The rainstorm weather from July 15,2010 to July 18,2010 is researched by diagnosis analysis method.The results suggest that in the strong and lasting period,the upward air current in the basin is prevail and is above ...The rainstorm weather from July 15,2010 to July 18,2010 is researched by diagnosis analysis method.The results suggest that in the strong and lasting period,the upward air current in the basin is prevail and is above 300 hPa.The convergence layer during strong rainstorm period is not thick.The convergence movement of air current is under 500 hPa.In this rainstorm process,the positive vortex maximum value center of the lower layer of convection layer is perfectly corresponding to rainstorm zone.The air current convergence and divergence intensity is one magnitude larger than the turning intensity.Flux plays a leading role in the system changes process;the non-equilibrium value of the low layer of convection layer during the strong rainstorm period U<0.Strong non-equilibrium is favorable for the movement of convergence.The non-equilibrium value of the high layer of convection layer U>0,and it stimulates the divergence movement of high layer.The divergence of high layer pushes the convergence of the lower layer and thus forms strong upward movement.展开更多
With the integration of ultrafast reflectivity and polarimetry probes,we observed carrier relaxation and spin dynamics induced by ultrafast laser excitation of Ni(111)single crystals.The carrier relaxation time within...With the integration of ultrafast reflectivity and polarimetry probes,we observed carrier relaxation and spin dynamics induced by ultrafast laser excitation of Ni(111)single crystals.The carrier relaxation time within the linear excitation range reveals that electron-phonon coupling and dissipation of photon energy into the bulk of the crystal take tens of picoseconds.On the other hand,the observed spin dynamics indicate a longer time of about 120 ps.To further understand how the lattice degree of freedom is coupled with these dynamics may require the integration of an ultrafast diffraction probe.展开更多
A numerical method is developed based on an unstructured mesh to compute an ionized hypersonic flowfield with radiation in the thermo-chemical nonequilibrium. The flowfield is described by multi-species NavierStocks e...A numerical method is developed based on an unstructured mesh to compute an ionized hypersonic flowfield with radiation in the thermo-chemical nonequilibrium. The flowfield is described by multi-species NavierStocks equations. The chemical model includes 11 species （O2, N2, O, N, NO, NO^＋ , N^＋ , O^＋, N2^＋ , O2^＋, e^- ） and 20 reactions. For simulating the thermal non-equilibrium effect, the two-temperature model is considered. The finite volume method （FVM） used for the spatial and directional discretization of radiative transfer equation（RTE） is described for unstructured grids. The numerical code can handle different kinds of species and radiative bands in a gas thermodynamicly described by two temperatures. In particular, the Delta, Epsilon, Beta prime, and Gamma prime bands of NO are choosen and the distribution of the radiation intensity is obtained.展开更多
Ammonia is gaining increasing attention as a green alternative fuel for achieving large-scale carbon emission reduction. Despite its potential technical prospects, the harsh ignition conditions and slow flame propagat...Ammonia is gaining increasing attention as a green alternative fuel for achieving large-scale carbon emission reduction. Despite its potential technical prospects, the harsh ignition conditions and slow flame propagation speed of ammonia pose significant challenges to its application in engines. Non-equilibrium plasma has been identified as a promising method, but current research on plasma-enhanced ammonia combustion is limited and primarily focuses on ignition characteristics revealed by kinetic models. In this study, low-temperature and low-pressure chemistry in plasma-assisted ammonia oxidative pyrolysis is investigated by integrated studies of steady-state GC measurements and mathematical simulation. The detailed kinetic mechanism of NH_(3) decomposition in plasma-driven Ar/NH_(3) and Ar/NH_(3)/O_(2) mixtures has been developed. The numerical model has good agreements with the experimental measurements in NH_(3)/O_(2) consumption and N_(2)/H_(2) generation, which demonstrates the rationality of modelling. Based on the modelling results, species density profiles, path flux and sensitivity analysis for the key plasmaproduced species such as NH_(2), NH, H_(2), OH, H, O, O(^(1)D), O_(2)(a^(1)△_(g)), O_(2)(b^(1)∑_(g)^(+)), Ar^(*), H^(-), Ar^(+), NH_(3)^(+), O_(2)^(-) in the discharge and afterglow are analyzed in detail to illustrate the effectiveness of the active species on NH_(3) excitation and decomposition at low temperature and relatively higher E/N values. The results revealed that NH_(2), NH, H as well as H_(2) are primarily generated through the electron collision reactions e + NH_(3)→ e + NH_(2)+ H, e + NH_(3)→ e + NH + H_(2) and the excited-argon collision reaction Ar^(*) + NH_(3)+ H → Ar + NH_(2)+ 2H, which will then react with highly reactive oxidative species such as O_(2)^(*), O^(*), O, OH, and O_(2) to produce stable products of NOx and H_(2)O. NH_(3)→ NH is found a specific pathway for NH_(3) consumption with plasma assistance, which further highlights the enhanced kinetic effects.展开更多
In this paper, non-equilibrium ignition conditions for magnetized cylindrical deuterium–tritium plasma in the presence of an axial magnetic field have been investigated. It is expected that temperature imbalance betw...In this paper, non-equilibrium ignition conditions for magnetized cylindrical deuterium–tritium plasma in the presence of an axial magnetic field have been investigated. It is expected that temperature imbalance between ions and electrons as well as the axial magnetic field will relax the threshold of ignition conditions.Therefore, ignition conditions for this model are derived numerically involving the energy balance equation at the stagnation point. It has been derived using parametric space including electron and ion temperature(T_e, T_i), areal density(q R), and seed magnetic field-dependent free parameters of B/q, mB, and BR. For B/ρ < 10~6 G cm^3 g^(-1),mB < 4 × 10~4 G cm g^(-1), and BR <3 × 10~5 G cm, the minimum fuel areal density exceeds between ρR >0.002 g cm^(-2), ρR> 0.25 g cm^(-2), and ρR > 0.02 g cm^(-2),respectively. The practical equilibrium conditions also addressed which is in good agreement with the corresponding one-temperature magnetized mode proposed in previous studies. Moreover, it has been shown that the typical criterion of BR ≥(6.13–4.64) × 10~5 G cm would be expectable. It is also confirmed that the minimum product of areal density times fuel temperature in equilibrium model is located in the range of T = 6–8 keV for all these free parameters, depending on the magnitude of the magnetic field. This is the entry point for the non-equilibrium model consistent with equilibrium model.展开更多
Non-equilibrium morphology has received much attention from both scientific and engineering points of view for its intricate pattern selection mechanisms and useful industrial application. Most study of non-equilibriu...Non-equilibrium morphology has received much attention from both scientific and engineering points of view for its intricate pattern selection mechanisms and useful industrial application. Most study of non-equilibrium is about the metal, alloy and other simple system. The complex silicate system is rarely involved. However, silicate is very important in geosciences and ceramic industry. In this paper, two kinds of non-equilibrium crystal morphologies of silicate: dendrite of diopside and spherulite of plagioclase, were introduced. Combining with the other kinds of non-equilibrium morphologies, the characteristics of micro-macro and anisotropy-isotropy of the non-equilibrium morphologies were discussed. Dendrite of diopside is micro- and macro-anisotropic, spherulite of plagioclase is micro-anisotropic, but macro-isotropic, fractal of NH4Cl is also micro-anisotropic, but macro-isotropic, dense-branching morphology (DBM) formed in non-crystalline system is micro-and macro-isotropic. Based on the micro-macro interplay on the pattern formation, it is proposed that the interplay between micro-anisotropy of crystal structure vs macro-isotropy of undercooling in crystal growth system will control the morphological evolution. The nucleation rate related to the anisotropy for the morphological evolution was also discussed. The fact that diopside develops dendrite and plagioclase develop spherulite in our experiment is due to their structural anisotropy difference.展开更多
Salt-forming regions for a complex salt-water system in non-equilibrium state of evaporation process are usually different from those in solubility diagrams.To understand the solid-forming region of NaCl and improve t...Salt-forming regions for a complex salt-water system in non-equilibrium state of evaporation process are usually different from those in solubility diagrams.To understand the solid-forming region of NaCl and improve the utilization of bittern resources,experiments were carried out to evaporate 20 representative mixture solution samples of Na ^＋,Mg ^2＋ //Cl^-, SO4^2--H2O system with an average evaporation intensity of（1.4±0.4） g·L^-1 ·min^-1（water） at boiling temperature 348 K,and determine the NaCl solid-forming regions in non-equilibrium state.Because of the complexity of salt-forming region,a maximal region and a minimal region were proposed to express the non-equilibrium state salt-forming region with different crystal seed,and a conditional salt-forming region was proposed to present the characteristic region of non-equilibrium salt-forming phase diagram.The areas of the maximal and minimal regions are 2.00 and 1.56 times those in solubility diagram,so it is possible to utilize bittern resources in high efficiency.The recovery rates of NaCl were 99.65%,93.14%,88.57%,72.76%,and 83.68%for six typical bittern sources from Tulantai Salt Lake（China）,Dongtai Salt Lake（China） ,Jilantai Salt Lake（China）,Qarun Salt Lake（Egypt） and seawater,respectively.It is testified that the non-equilibrium state salt-forming phase diagram can be used in industrial processes.展开更多
The development of non-equilibrium segregation of boron at grain boundaries in Fe-4 0%Ni alloy during continuous cooling process was experimentally observed with boron Particle Tracking Autoradiography (PTA) and Trans...The development of non-equilibrium segregation of boron at grain boundaries in Fe-4 0%Ni alloy during continuous cooling process was experimentally observed with boron Particle Tracking Autoradiography (PTA) and Transmission Electron Microscopy (TEM,). The samples with 10ppm boron were cooled at 2℃/s to 1040, 980, 920, 860, 780 and 640℃ respectively after pre-heat treatment of 1150℃ for 15mm with a Gleeble-1500 heat simulating machine, then water quenched to room temperature. The width of segregation layer and boron depletion zone, rich factor and other parameters were measured by a special image analysis system. The experimental results of PTA show that the grain boundary segregation of boron during cooling process is a dynamic process and the development of the non-equilibrium segregation experiences three stages: first increases rapidly from 1150 to 1040℃, then gently from 1040 to 860℃, and rapidly again from 860℃ to 640℃. The width of boron depletion zone increases from about 11μm at 1040℃ to 26μm at 640℃. TEM observation shows that boron precipitates exist at grain boundaries when the samples are cooled to below 860℃. The experimental phenomena are briefly discussed.展开更多
We use non-equilibrium molecular dynamics simulations to calculate the self-diffusion coefficient, D, of a Lennard Jones fluid over a wide density and temperature range. The change in self-diffusion coefficient with t...We use non-equilibrium molecular dynamics simulations to calculate the self-diffusion coefficient, D, of a Lennard Jones fluid over a wide density and temperature range. The change in self-diffusion coefficient with temperature decreases by increasing density. For density ρ＊ = ρσ3 = 0.84 we observe a peak at the value of the self-diffusion coefficient and the critical temperature T＊ = kT/ε = 1.25. The value of the self-diffusion coefficient strongly depends on system size. The data of the self-diffusion coefficient are fitted to a simple analytic relation based on hydrodynamic arguments. This correction scales as N-α, where α is an adjustable parameter and N is the number of particles. It is observed that the values of a 〈 1 provide quite a good correction to the simulation data. The system size dependence is very strong for lower densities, but it is not as strong for higher densities. The self-diffusion coefficient calculated with non-equilibrium molecular dynamic simulations at different temperatures and densities is in good agreement with other calculations fronl the literature.展开更多
In the reaction of methane and carbon dioxide to C2 hydrocarbons under non-equilibrium plasma, methane conversion was decreased, but selectivity of C2 hydrocarbons was increased when using La2O3/?Al2O3 as catalyst. S...In the reaction of methane and carbon dioxide to C2 hydrocarbons under non-equilibrium plasma, methane conversion was decreased, but selectivity of C2 hydrocarbons was increased when using La2O3/?Al2O3 as catalyst. So the yield of C2 hydrocarbons was higher than using plasma alone. The synergism of La2O3/?Al2O3 and plasma gave methane conversion of 24.9% and C2 yield of 18.1%. The distribution of C2 hydrocarbons changed when Pd- La2O3/?Al2O3 was used as catalyst, the major C2 product was ethylene.展开更多
a gliding arc driven by the transverse magnetic field was ignited between the electrodes with a complicated shape at atmospheric pressure and a non-equilibrium plasma was gencrated. Under our experimental conditions, ...a gliding arc driven by the transverse magnetic field was ignited between the electrodes with a complicated shape at atmospheric pressure and a non-equilibrium plasma was gencrated. Under our experimental conditions, a phenomenon was clearly observed where the arc power decreased with the increase in arc voltage. As the arc voltage was higher than 3.375 kV, the are power acquired from the power supply decreased, and the arc plasma began to switch to a non-equilibrium phase. The existence of the non-equilibrium arc plasma was very short, about 10 ms in one gliding arc discharge cycle.展开更多
文摘Non-equilibrium solidification structures of Cu55Ni45 and Cu55Ni43Co2 alloys were prepared by the molten glass purification cycle superheating method.The variation of the recalescence phenomenon with the degree of undercooling in the rapid solidification process was investigated using an infrared thermometer.The addition of the Co element affected the evolution of the recalescence phenomenon in Cu-Ni alloys.The images of the solid-liquid interface migration during the rapid solidification of supercooled melts were captured by using a high-speed camera.The solidification rate of Cu-Ni alloys,with the addition of Co elements,was explored.Finally,the grain refinement structure with low supercooling was characterised using electron backscatter diffraction(EBSD).The effect of Co on the microstructural evolution during nonequilibrium solidification of Cu-Ni alloys under conditions of small supercooling is investigated by comparing the microstructures of Cu55Ni45 and Cu55Ni43Co2 alloys.The experimental results show that the addition of a small amount of Co weakens the recalescence behaviour of the Cu55Ni45 alloy and significantly reduces the thermal strain in the rapid solidification phase.In the rapid solidification phase,the thermal strain is greatly reduced,and there is a significant increase in the characteristic undercooling degree.Furthermore,the addition of Co and the reduction of Cu not only result in a lower solidification rate of the alloy,but also contribute to the homogenisation of the grain size.
基金Funded by the Basic Research Projects in Shanxi Province(No.202103021224183)。
文摘The effect of the gradient content of Co element on the solidification process of Cu-based alloy under deep under cooling conditions was explored.The non-equilibrium solidification structure of the under cooled alloy samples were analyzed.It is found that the rapidly solidified alloy has undergone twice grain refinement during the undercooling process.Characterization and significance of the maximum undercooling refinement structure of Cu60Ni35Co5 at T=253 K were analyzed.High-density defects were observed,such as dislocations,stacking faults networks,and twinning structures.The standard FCC diffraction pattern represents that it is still a single-phase structure.Based on the metallographic diagram,EBSD and TEM data analysis,it is illustrated that the occurrence of grain refinement under high undercooling is due to stress induced recrystallization.In addition,the laser cladding technology is used to coat Co-based alloy(Stellite12) coating on 304 stainless steel substrate;the microstructure of the coating cross-section was analyzed.It was found that the microstructure of the cross-section is presented as columnar crystals,planar crystals,and disordered growth direction,so that the coating has better hardness and wear resistance.By electrochemical corrosion of the substrate and coating,it can be seen that the Co and Cr elements present in the coating are more likely to form a dense passivation film,which improved the corrosion resistance of the coating.
基金supported by the Australian Research Council(Grant No.DP200101293)the National Natural Science Foundation of China(Grant No.42202286)the Zhejiang Collaborative Innovation Center for Prevention and Control of Mountain Geological Hazards(Grant No.PCMGH-2017-Z-02).
文摘Long-term permeability experiments have indicated that sorption-induced swelling can switch from internal to bulk depending on the evolutive sorption status.However,this sorption swelling switch mechanism has not been considered in current analytical permeability models.This study introduces a normalized sorption non-equilibrium index(SNEI)to characterize the sorption status,quantify the dynamical variations of matrix swelling accumulation and internal swelling partition,and formulate the sorption swelling switch model.The incorporation of this index into the extended total effective stress concept leads to an analytical transient coal permeability model.Model results show that the sorption swelling switch itself results in the permeability switch under stress-constrained conditions,while the confined bulk swelling suppresses the permeability recovery to the continuous reduction under displacement-constrained conditions.Model verifications show that current experimental observations correspond to the early stages of the transient process,and they could be extended to the whole process with these models.This study demonstrates the importance of the sorption swelling switch in determining permeability evolution using simple boundary conditions.It provides new insights into experimentally revealing the sorption swelling switch in the future,and underscores the requirement of a rigorous model for complex coupled processes in large-scale coal seams.
基金funding this work through Small Research Project under grant number RGP.1/141/45。
文摘The heat transfer through a concave permeable fin is analyzed by the local thermal non-equilibrium(LTNE)model.The governing dimensional temperature equations for the solid and fluid phases of the porous extended surface are modeled,and then are nondimensionalized by suitable dimensionless terms.Further,the obtained nondimensional equations are solved by the clique polynomial method(CPM).The effects of several dimensionless parameters on the fin's thermal profiles are shown by graphical illustrations.Additionally,the current study implements deep neural structures to solve physics-governed coupled equations,and the best-suited hyperparameters are attained by comparison with various network combinations.The results of the CPM and physicsinformed neural network(PINN)exhibit good agreement,signifying that both methods effectively solve the thermal modeling problem.
基金supported by the National Natural Science Foundation of China (Grant Nos.U22A6005 and 12074408)the National Key Research and Development Program of China (Grant No.2021YFA1301502)+7 种基金Guangdong Major Scientific Research Project (Grant No.2018KZDXM061)Youth Innovation Promotion Association of CAS (Grant No.2021009)Scientific Instrument Developing Project of the Chinese Academy of Sciences (Grant Nos.YJKYYQ20200055,ZDKYYQ2017000,and 22017BA10)Strategic Priority Research Program (B) of the Chinese Academy of Sciences (Grant Nos.XDB25000000 and XDB33010100)Beijing Municipal Science and Technology Major Project (Grant No.Z201100001820006)IOP Hundred Talents Program (Grant No.Y9K5051)Postdoctoral Support Program of China (Grant No.2020M670501)the Synergetic Extreme Condition User Facility (SECUF)。
文摘Ultrafast transmission electron microscope(UTEM) with the multimodality of time-resolved diffraction, imaging,and spectroscopy provides a unique platform to reveal the fundamental features associated with the interaction between free electrons and matter. In this review, we summarize the principles, instrumentation, and recent developments of the UTEM and its applications in capturing dynamic processes and non-equilibrium transient states. The combination of the transmission electron microscope with a femtosecond laser via the pump–probe method guarantees the high spatiotemporal resolution, allowing the investigation of the transient process in real, reciprocal and energy spaces. Ultrafast structural dynamics can be studied by diffraction and imaging methods, revealing the coherent acoustic phonon generation and photoinduced phase transition process. In the energy dimension, time-resolved electron energy-loss spectroscopy enables the examination of the intrinsic electronic dynamics of materials, while the photon-induced near-field electron microscopy extends the application of the UTEM to the imaging of optical near fields with high real-space resolution. It is noted that light–free-electron interactions have the ability to shape electron wave packets in both longitudinal and transverse directions, showing the potential application in the generation of attosecond electron pulses and vortex electron beams.
基金the National Natural Science Foundation of China(No.52079077)the Natural Science Foundation of Shandong Province(No.ZR2021QE069).
文摘Accurate knowledge of gas flow within the reservoir and related controlling factors will be important for enhancing the production of coal bed methane.At present,most studies focused on the permeability evolution of dry coal under gas adsorption equilibrium,gas flow and gas diffusion within wet coal under the generally non-equilibrium state are often ignored in the process of gas recovery.In this study,an improved apparent permeability model is proposed which accommodates the water and gas adsorption,stress dependence,water film thickness and gas flow regimes.In the process of modeling,the water adsorption is only affected by water content while the gas adsorption is time and water content dependent;based on poroelastic mechanics,the effective fracture aperture and effective pore radius are derived;and then the variation in water film thickness for different pore types under the effect of water content,stress and adsorption swelling are modeled;the flow regimes are considered based on Beskok’s model.Further,after validation with experimental data,the proposed model was applied to numerical simulations to investigate the evolution of permeability-related factors under the effect of different water contents.The gas flow in wet coal under the non-equilibrium state is explicitly revealed.
基金the National Natural Science Foundation of China(Grant Nos.51725902,52009095,U2040215,U2240206,and 52109098)supported partly by the Postdoctoral Research Foundation of China(Grant No.BX2021228)Natural Science Foundation of Hubei Province(Grant No.2021CFA029)。
文摘Suspended sediment concentrations in the Middle Yangtze River(MYR)reduced greatly after the Three Gorges Project operation,causing the composition of bed material to coarsen continuously.However,little is known about the non-equilibrium transport of graded suspended sediment owing to different bed material compositions(BMCs)along the MYR,and it is necessary to determine the magnitude of recovery factor.Using the Markov stochastic process in conjunction with the hiding-exposure effect of non-uniform bed-material,a new formula is proposed for calculating the recovery factor including the effect of different BMCs,and it is incorporated into the non-equilibrium transport equation to simulate the recovery processes of suspended load in both sand-gravel bed and sand bed reaches of the MYR.The results show that:(i)the recovery rate of graded sediment concentrations at Zhicheng was slower than that at Shashi during the period 2003-2007;(ii)the mean recovery factors of the coarse,medium,and fine sediment fractions in the ZhichengShashi reach were 0.152,0.0012,and 0.0005,respectively,and the coarse sediment recovered up to the maximum sediment concentration of 0.138 kg/m3over a distance of 15 km;and(iii)the results of the new formula that can consider the effect of bed material composition are in general agreement with the field observations,and the spatial and temporal delay effects are inversely related to particle size and BMC.Consequently,the BMC effect on the nonequilibrium sediment transport in different reaches of the MYR needs to be considered for higher simulation accuracy.
基金This work has been supported by the Foundation of Presi-dent of China Academy of Engineering Physics(Grant Nos.201402037 and 201401040)the CAEP-FESTC(Grant No.R2014-0501-01)the National Basic Research Program of China(Grant No.2013CB34100).
文摘The non-equilibrium between ions and electrons in the hot spot can relax the ignition conditions in inertial confinement fusion[Fan et al.,Phys.Plasmas 23,010703(2016)],and obvious ion-electron non-equilibrium could be observed by our simulations of high-foot implosions when the ion-electron relaxation is enlarged by a factor of 2.On the other hand,in many shots of high-foot implosions on the National Ignition Facility,the observed X-ray enhancement factors due to ablator mixing into the hot spot are less than unity assuming electrons and ions have the same temperature[Meezan et al.,Phys.Plasmas 22,062703(2015)],which is not self-consistent because it can lead to negative ablator mixing into the hot spot.Actually,this non-consistency implies ion-electron non-equilibrium within the hot spot.From our study,we can infer that ion-electron non-equilibrium exists in high-foot implosions and the ion temperature could be~9%larger than the equilibrium temperature in some NIF shots.
文摘This article summarized systematically the previous investigations on t he dielectric relaxation of wood, the main substances and extractives in wood at oven-dry state, and the dielectric relaxation based on the adsorbed water in w o od cell wall under equilibrium and non-equilibrium state. Moreover, some expect a tions for future research were proposed on this basis. The purpose of this artic le is to provide other researchers an overall understanding about the research i n this region, and further to promote the research onto a new and higher level.
基金Supported by Sichuan Meteorology Subject Fund(2010-Youth-02)~~
文摘The rainstorm weather from July 15,2010 to July 18,2010 is researched by diagnosis analysis method.The results suggest that in the strong and lasting period,the upward air current in the basin is prevail and is above 300 hPa.The convergence layer during strong rainstorm period is not thick.The convergence movement of air current is under 500 hPa.In this rainstorm process,the positive vortex maximum value center of the lower layer of convection layer is perfectly corresponding to rainstorm zone.The air current convergence and divergence intensity is one magnitude larger than the turning intensity.Flux plays a leading role in the system changes process;the non-equilibrium value of the low layer of convection layer during the strong rainstorm period U<0.Strong non-equilibrium is favorable for the movement of convergence.The non-equilibrium value of the high layer of convection layer U>0,and it stimulates the divergence movement of high layer.The divergence of high layer pushes the convergence of the lower layer and thus forms strong upward movement.
基金Project supported by the National Key R&D Program of China (Grant Nos. 2022YFA1604402 and 2022YFA1604403)the National Natural Science Foundation of China (NSFC) (Grant No. 11721404)+3 种基金the Shanghai Rising-Star Program (Grant No. 21QA1406100)the Technology Innovation Action Plan of the Science and Technology Commission of Shanghai Municipality (Grant No. 20JC1416000)support by the Air Force Office of Scientific Research (AFOSR) (Grant No. FA9550-20-10139)the Texas A&M Engineering Experimental Station (TEES)
文摘With the integration of ultrafast reflectivity and polarimetry probes,we observed carrier relaxation and spin dynamics induced by ultrafast laser excitation of Ni(111)single crystals.The carrier relaxation time within the linear excitation range reveals that electron-phonon coupling and dissipation of photon energy into the bulk of the crystal take tens of picoseconds.On the other hand,the observed spin dynamics indicate a longer time of about 120 ps.To further understand how the lattice degree of freedom is coupled with these dynamics may require the integration of an ultrafast diffraction probe.
文摘A numerical method is developed based on an unstructured mesh to compute an ionized hypersonic flowfield with radiation in the thermo-chemical nonequilibrium. The flowfield is described by multi-species NavierStocks equations. The chemical model includes 11 species （O2, N2, O, N, NO, NO^＋ , N^＋ , O^＋, N2^＋ , O2^＋, e^- ） and 20 reactions. For simulating the thermal non-equilibrium effect, the two-temperature model is considered. The finite volume method （FVM） used for the spatial and directional discretization of radiative transfer equation（RTE） is described for unstructured grids. The numerical code can handle different kinds of species and radiative bands in a gas thermodynamicly described by two temperatures. In particular, the Delta, Epsilon, Beta prime, and Gamma prime bands of NO are choosen and the distribution of the radiation intensity is obtained.
基金the grant support from the National Natural Science Foundation of China (No. 21975018, 22278032)。
文摘Ammonia is gaining increasing attention as a green alternative fuel for achieving large-scale carbon emission reduction. Despite its potential technical prospects, the harsh ignition conditions and slow flame propagation speed of ammonia pose significant challenges to its application in engines. Non-equilibrium plasma has been identified as a promising method, but current research on plasma-enhanced ammonia combustion is limited and primarily focuses on ignition characteristics revealed by kinetic models. In this study, low-temperature and low-pressure chemistry in plasma-assisted ammonia oxidative pyrolysis is investigated by integrated studies of steady-state GC measurements and mathematical simulation. The detailed kinetic mechanism of NH_(3) decomposition in plasma-driven Ar/NH_(3) and Ar/NH_(3)/O_(2) mixtures has been developed. The numerical model has good agreements with the experimental measurements in NH_(3)/O_(2) consumption and N_(2)/H_(2) generation, which demonstrates the rationality of modelling. Based on the modelling results, species density profiles, path flux and sensitivity analysis for the key plasmaproduced species such as NH_(2), NH, H_(2), OH, H, O, O(^(1)D), O_(2)(a^(1)△_(g)), O_(2)(b^(1)∑_(g)^(+)), Ar^(*), H^(-), Ar^(+), NH_(3)^(+), O_(2)^(-) in the discharge and afterglow are analyzed in detail to illustrate the effectiveness of the active species on NH_(3) excitation and decomposition at low temperature and relatively higher E/N values. The results revealed that NH_(2), NH, H as well as H_(2) are primarily generated through the electron collision reactions e + NH_(3)→ e + NH_(2)+ H, e + NH_(3)→ e + NH + H_(2) and the excited-argon collision reaction Ar^(*) + NH_(3)+ H → Ar + NH_(2)+ 2H, which will then react with highly reactive oxidative species such as O_(2)^(*), O^(*), O, OH, and O_(2) to produce stable products of NOx and H_(2)O. NH_(3)→ NH is found a specific pathway for NH_(3) consumption with plasma assistance, which further highlights the enhanced kinetic effects.
文摘In this paper, non-equilibrium ignition conditions for magnetized cylindrical deuterium–tritium plasma in the presence of an axial magnetic field have been investigated. It is expected that temperature imbalance between ions and electrons as well as the axial magnetic field will relax the threshold of ignition conditions.Therefore, ignition conditions for this model are derived numerically involving the energy balance equation at the stagnation point. It has been derived using parametric space including electron and ion temperature(T_e, T_i), areal density(q R), and seed magnetic field-dependent free parameters of B/q, mB, and BR. For B/ρ < 10~6 G cm^3 g^(-1),mB < 4 × 10~4 G cm g^(-1), and BR <3 × 10~5 G cm, the minimum fuel areal density exceeds between ρR >0.002 g cm^(-2), ρR> 0.25 g cm^(-2), and ρR > 0.02 g cm^(-2),respectively. The practical equilibrium conditions also addressed which is in good agreement with the corresponding one-temperature magnetized mode proposed in previous studies. Moreover, it has been shown that the typical criterion of BR ≥(6.13–4.64) × 10~5 G cm would be expectable. It is also confirmed that the minimum product of areal density times fuel temperature in equilibrium model is located in the range of T = 6–8 keV for all these free parameters, depending on the magnitude of the magnetic field. This is the entry point for the non-equilibrium model consistent with equilibrium model.
基金Project supported by the National of Natural Science Foundation of China (40472023)
文摘Non-equilibrium morphology has received much attention from both scientific and engineering points of view for its intricate pattern selection mechanisms and useful industrial application. Most study of non-equilibrium is about the metal, alloy and other simple system. The complex silicate system is rarely involved. However, silicate is very important in geosciences and ceramic industry. In this paper, two kinds of non-equilibrium crystal morphologies of silicate: dendrite of diopside and spherulite of plagioclase, were introduced. Combining with the other kinds of non-equilibrium morphologies, the characteristics of micro-macro and anisotropy-isotropy of the non-equilibrium morphologies were discussed. Dendrite of diopside is micro- and macro-anisotropic, spherulite of plagioclase is micro-anisotropic, but macro-isotropic, fractal of NH4Cl is also micro-anisotropic, but macro-isotropic, dense-branching morphology (DBM) formed in non-crystalline system is micro-and macro-isotropic. Based on the micro-macro interplay on the pattern formation, it is proposed that the interplay between micro-anisotropy of crystal structure vs macro-isotropy of undercooling in crystal growth system will control the morphological evolution. The nucleation rate related to the anisotropy for the morphological evolution was also discussed. The fact that diopside develops dendrite and plagioclase develop spherulite in our experiment is due to their structural anisotropy difference.
基金Supported by the National Natural Science Foundation of China（20776110） the Natural Science Foundation of Tianjin（06YFJMJC04100）
文摘Salt-forming regions for a complex salt-water system in non-equilibrium state of evaporation process are usually different from those in solubility diagrams.To understand the solid-forming region of NaCl and improve the utilization of bittern resources,experiments were carried out to evaporate 20 representative mixture solution samples of Na ^＋,Mg ^2＋ //Cl^-, SO4^2--H2O system with an average evaporation intensity of（1.4±0.4） g·L^-1 ·min^-1（water） at boiling temperature 348 K,and determine the NaCl solid-forming regions in non-equilibrium state.Because of the complexity of salt-forming region,a maximal region and a minimal region were proposed to express the non-equilibrium state salt-forming region with different crystal seed,and a conditional salt-forming region was proposed to present the characteristic region of non-equilibrium salt-forming phase diagram.The areas of the maximal and minimal regions are 2.00 and 1.56 times those in solubility diagram,so it is possible to utilize bittern resources in high efficiency.The recovery rates of NaCl were 99.65%,93.14%,88.57%,72.76%,and 83.68%for six typical bittern sources from Tulantai Salt Lake（China）,Dongtai Salt Lake（China） ,Jilantai Salt Lake（China）,Qarun Salt Lake（Egypt） and seawater,respectively.It is testified that the non-equilibrium state salt-forming phase diagram can be used in industrial processes.
文摘The development of non-equilibrium segregation of boron at grain boundaries in Fe-4 0%Ni alloy during continuous cooling process was experimentally observed with boron Particle Tracking Autoradiography (PTA) and Transmission Electron Microscopy (TEM,). The samples with 10ppm boron were cooled at 2℃/s to 1040, 980, 920, 860, 780 and 640℃ respectively after pre-heat treatment of 1150℃ for 15mm with a Gleeble-1500 heat simulating machine, then water quenched to room temperature. The width of segregation layer and boron depletion zone, rich factor and other parameters were measured by a special image analysis system. The experimental results of PTA show that the grain boundary segregation of boron during cooling process is a dynamic process and the development of the non-equilibrium segregation experiences three stages: first increases rapidly from 1150 to 1040℃, then gently from 1040 to 860℃, and rapidly again from 860℃ to 640℃. The width of boron depletion zone increases from about 11μm at 1040℃ to 26μm at 640℃. TEM observation shows that boron precipitates exist at grain boundaries when the samples are cooled to below 860℃. The experimental phenomena are briefly discussed.
基金supported by the National Natural Science Foundation of China (Grant No. 51076128)the National High Technology Research and Development Program of China (Grant No. 2009AA05Z107)
文摘We use non-equilibrium molecular dynamics simulations to calculate the self-diffusion coefficient, D, of a Lennard Jones fluid over a wide density and temperature range. The change in self-diffusion coefficient with temperature decreases by increasing density. For density ρ＊ = ρσ3 = 0.84 we observe a peak at the value of the self-diffusion coefficient and the critical temperature T＊ = kT/ε = 1.25. The value of the self-diffusion coefficient strongly depends on system size. The data of the self-diffusion coefficient are fitted to a simple analytic relation based on hydrodynamic arguments. This correction scales as N-α, where α is an adjustable parameter and N is the number of particles. It is observed that the values of a 〈 1 provide quite a good correction to the simulation data. The system size dependence is very strong for lower densities, but it is not as strong for higher densities. The self-diffusion coefficient calculated with non-equilibrium molecular dynamic simulations at different temperatures and densities is in good agreement with other calculations fronl the literature.
文摘In the reaction of methane and carbon dioxide to C2 hydrocarbons under non-equilibrium plasma, methane conversion was decreased, but selectivity of C2 hydrocarbons was increased when using La2O3/?Al2O3 as catalyst. So the yield of C2 hydrocarbons was higher than using plasma alone. The synergism of La2O3/?Al2O3 and plasma gave methane conversion of 24.9% and C2 yield of 18.1%. The distribution of C2 hydrocarbons changed when Pd- La2O3/?Al2O3 was used as catalyst, the major C2 product was ethylene.
文摘a gliding arc driven by the transverse magnetic field was ignited between the electrodes with a complicated shape at atmospheric pressure and a non-equilibrium plasma was gencrated. Under our experimental conditions, a phenomenon was clearly observed where the arc power decreased with the increase in arc voltage. As the arc voltage was higher than 3.375 kV, the are power acquired from the power supply decreased, and the arc plasma began to switch to a non-equilibrium phase. The existence of the non-equilibrium arc plasma was very short, about 10 ms in one gliding arc discharge cycle.
