Various semicokes were obtained from medium-low temperature pyrolysis of Dongrong long flame coal.The proximate analysis,calorific value and Hardgrove grindability index(HGI) of semicokes were determined,and the ignit...Various semicokes were obtained from medium-low temperature pyrolysis of Dongrong long flame coal.The proximate analysis,calorific value and Hardgrove grindability index(HGI) of semicokes were determined,and the ignition temperature,burnout temperature,ignition index,burnout index,burnout ratio,combustion characteristic index of semicokes were measured and analyzed using thermogravimetry analysis(TGA).The effects of pyrolysis temperature,heating rate,and pyrolysis time on yield,composition and calorific value of long flame coal derived semicokes were investigated,especially the influence of pyrolysis temperature on combustion characteristics and grindability of the semicokes was studied combined with X-ray diffraction(XRD) analysis of semicokes.The results show that the volatile content,ash content and calorific value of semicokes pyrolyzed at all process parameters studied meet the technical specifications of the pulverized coal-fired furnaces(PCFF) referring to China Standards GB/T 7562-1998.The pyrolysis temperature is the most influential factor among pyrolysis process parameters.As pyrolysis temperature increases,the yield,ignition index,combustion reactivity and burnout index of semicokes show a decreasing tend,but the ash content increases.In the range of 400 and 450 °C,the grindability of semicokes is rational,especially the grindability of semicokes pyrolyzed at 450 °C is suitable.Except for the decrease of volatile content and increase of ash content,the decrease of combustion performance of semicokes pyrolyzed at higher temperature should be attributed to the improvement of the degree of structural ordering and the increase of aromaticity and average crystallite size of char.It is concluded that the semicokes pyrolyzed at the temperature of 450 °C is the proper fuel for PCFF.展开更多
为揭示长期浸水长焰煤的自燃特性及影响机制,实验研究了长焰煤原始煤样和长期浸水风干煤样的低温氧化特性,分析了长期浸水对煤微观结构、氧化升温过程及活化能等方面的影响规律。研究结果表明:长期被水浸泡煤样的表面孔隙结构更发达,平...为揭示长期浸水长焰煤的自燃特性及影响机制,实验研究了长焰煤原始煤样和长期浸水风干煤样的低温氧化特性,分析了长期浸水对煤微观结构、氧化升温过程及活化能等方面的影响规律。研究结果表明:长期被水浸泡煤样的表面孔隙结构更发达,平均孔径、介孔孔容和微孔孔容都有不同程度的增大;同时,浸水煤样表面的部分有机物和无机物会溶解在水中,煤中自由基浓度增加,基团分布与原煤相比存在明显变化;与原煤样相比,经过90,180 d浸水过程后的煤体,低温氧化过程的气体产生量和产生速率更高,交叉点温度由原煤的160.9℃降低至157,151.5℃,活化能分别降低了3.84,4.18 k J/mol,表现出更高的自燃倾向性。研究结果可为西部浅埋藏近距离煤层群开采上覆采空区长期浸水煤的自燃防治提供借鉴。展开更多
基金support from the Allocated Section of the Basic Fund for the Scientific Research and Operation of Central Universities of China (No.2009KH10)
文摘Various semicokes were obtained from medium-low temperature pyrolysis of Dongrong long flame coal.The proximate analysis,calorific value and Hardgrove grindability index(HGI) of semicokes were determined,and the ignition temperature,burnout temperature,ignition index,burnout index,burnout ratio,combustion characteristic index of semicokes were measured and analyzed using thermogravimetry analysis(TGA).The effects of pyrolysis temperature,heating rate,and pyrolysis time on yield,composition and calorific value of long flame coal derived semicokes were investigated,especially the influence of pyrolysis temperature on combustion characteristics and grindability of the semicokes was studied combined with X-ray diffraction(XRD) analysis of semicokes.The results show that the volatile content,ash content and calorific value of semicokes pyrolyzed at all process parameters studied meet the technical specifications of the pulverized coal-fired furnaces(PCFF) referring to China Standards GB/T 7562-1998.The pyrolysis temperature is the most influential factor among pyrolysis process parameters.As pyrolysis temperature increases,the yield,ignition index,combustion reactivity and burnout index of semicokes show a decreasing tend,but the ash content increases.In the range of 400 and 450 °C,the grindability of semicokes is rational,especially the grindability of semicokes pyrolyzed at 450 °C is suitable.Except for the decrease of volatile content and increase of ash content,the decrease of combustion performance of semicokes pyrolyzed at higher temperature should be attributed to the improvement of the degree of structural ordering and the increase of aromaticity and average crystallite size of char.It is concluded that the semicokes pyrolyzed at the temperature of 450 °C is the proper fuel for PCFF.
文摘为揭示长期浸水长焰煤的自燃特性及影响机制,实验研究了长焰煤原始煤样和长期浸水风干煤样的低温氧化特性,分析了长期浸水对煤微观结构、氧化升温过程及活化能等方面的影响规律。研究结果表明:长期被水浸泡煤样的表面孔隙结构更发达,平均孔径、介孔孔容和微孔孔容都有不同程度的增大;同时,浸水煤样表面的部分有机物和无机物会溶解在水中,煤中自由基浓度增加,基团分布与原煤相比存在明显变化;与原煤样相比,经过90,180 d浸水过程后的煤体,低温氧化过程的气体产生量和产生速率更高,交叉点温度由原煤的160.9℃降低至157,151.5℃,活化能分别降低了3.84,4.18 k J/mol,表现出更高的自燃倾向性。研究结果可为西部浅埋藏近距离煤层群开采上覆采空区长期浸水煤的自燃防治提供借鉴。
