There is an urgent need to develop optimal solutions for deformation control of deep high‐stress roadways,one of the critical problems in underground engineering.The previously proposed four‐dimensional support(here...There is an urgent need to develop optimal solutions for deformation control of deep high‐stress roadways,one of the critical problems in underground engineering.The previously proposed four‐dimensional support(hereinafter 4D support),as a new support technology,can set the roadway surrounding rock under three‐dimensional pressure in the new balanced structure,and prevent instability of surrounding rock in underground engineering.However,the influence of roadway depth and creep deformation on the surrounding rock supported by 4D support is still unknown.This study investigated the influence of roadway depth and creep deformation time on the instability of surrounding rock by analyzing the energy development.The elastic strain energy was analyzed using the program redeveloped in FLAC3D.The numerical simulation results indicate that the combined support mode of 4D roof supports and conventional side supports is highly applicable to the stability control of surrounding rock with a roadway depth exceeding 520 m.With the increase of roadway depth,4D support can effectively restrain the area and depth of plastic deformation in the surrounding rock.Further,4D support limits the accumulation range and rate of elastic strain energy as the creep deformation time increases.4D support can effectively reduce the plastic deformation of roadway surrounding rock and maintain the stability for a long deformation period of 6 months.As confirmed by in situ monitoring results,4D support is more effective for the long‐term stability control of surrounding rock than conventional support.展开更多
Benefiting from the high capacity of Zn metal anodes and intrinsic safety of aqueous electrolytes,rechargeable Zn ion batteries(ZIBs)show promising application in the post‐lithium‐ion period,exhibiting good safety,l...Benefiting from the high capacity of Zn metal anodes and intrinsic safety of aqueous electrolytes,rechargeable Zn ion batteries(ZIBs)show promising application in the post‐lithium‐ion period,exhibiting good safety,low cost,and high energy density.However,its commercialization still faces problems with low Coulombic efficiency and unsatisfied cycling performance due to the poor Zn/Zn2+reversibility that occurred on the Zn anode.To improve the stability of the Zn anode,optimizing the Zn deposition behavior is an efficient way,which can enhance the subsequent striping efficiency and limit the dendrite growth.The Zn deposition is a controlled kinetics‐diffusion joint process that is affected by various factors,such as the interaction between Zn2+ions and Zn anodes,ion concentration gradient,and current distribution.In this review,from an electrochemical perspective,we first overview the factors affecting the Zn deposition behavior and summarize the modification principles.Subsequently,strategies proposed for interfacial modification and 3D structural design as well as the corresponding mechanisms are summarized.Finally,the existing challenges,perspectives on further development direction,and outlook for practical applications of ZIBs are proposed.展开更多
All-inorganic cesium lead halide based perovskite nanocrystals(PNCs)exhibit promising optoelectronic properties,but their poor stability and anion exchange reaction limit their broad commercial applications.Herein,we ...All-inorganic cesium lead halide based perovskite nanocrystals(PNCs)exhibit promising optoelectronic properties,but their poor stability and anion exchange reaction limit their broad commercial applications.Herein,we demonstrated the successful synthesis of blue-green-red emitting CsPbX_(3)(X=Cl/Br,Br,and Br/I)PNCs via hot injection method,followed by silica-coating and embedding in poly(methylmethacrylate)(PMMA)matrix.The photoluminescence(PL)spectra of SiO_(2)/PMMA-coated PNCs can be tuned continuously by regulating precursor composition ratio,from blue(CsPb(Cl_(0.5)/Br_(0.5))_(3);460 nm)to red(CsPb(Br_(0.4)/I_(0.6))_(3)via green(CsPbBr_(3);519 nm).The PNCs composite films exhibit improved stability(thermal-,moisture-,and photo-stability)because of the barrier formed by Si0_(2)/PMMA coating and also displayed exceptional photoluminescent quantum yield(PLQY of blue,green,and red-emitting Si0_(2)/PMMA coated PNCs are 37%,86%,and 71%,respectively)with longer lifetimes inhibiting anion exchange.Eventually,the PNCs-encapsulated Si0_(2)/PMMA composite films were integrated into the UV LED chip as down-converting materials to construct a prototype white-peLED unit.The designed white-peLED unit demonstrated bright white light generating CIE coordinates(0.349,0.350),a luminous efficiency(LE)of 39.2%and a color rendering index(CRI)of 84.7.The wide color gamut of 121.47%of NTSC and 98.56%of Rec.2020 is also achieved with the built w-LED system.Therefore,the results demonstrated that CsPbX_(3)(X=Cl/Br,Br,and Br/I)PNCs@SiO_(2)/PMMA composite films can be employed as efficient UV to visible color conversion materials for white-LEDs and backlighting.展开更多
基金support from the National Key Research and Development Program of China(Nos.2023YFC2907300 and 2019YFE0118500)the National Natural Science Foundation of China(Nos.U22A20598 and 52104107)the Natural Science Foundation of Jiangsu Province(No.BK20200634).
文摘There is an urgent need to develop optimal solutions for deformation control of deep high‐stress roadways,one of the critical problems in underground engineering.The previously proposed four‐dimensional support(hereinafter 4D support),as a new support technology,can set the roadway surrounding rock under three‐dimensional pressure in the new balanced structure,and prevent instability of surrounding rock in underground engineering.However,the influence of roadway depth and creep deformation on the surrounding rock supported by 4D support is still unknown.This study investigated the influence of roadway depth and creep deformation time on the instability of surrounding rock by analyzing the energy development.The elastic strain energy was analyzed using the program redeveloped in FLAC3D.The numerical simulation results indicate that the combined support mode of 4D roof supports and conventional side supports is highly applicable to the stability control of surrounding rock with a roadway depth exceeding 520 m.With the increase of roadway depth,4D support can effectively restrain the area and depth of plastic deformation in the surrounding rock.Further,4D support limits the accumulation range and rate of elastic strain energy as the creep deformation time increases.4D support can effectively reduce the plastic deformation of roadway surrounding rock and maintain the stability for a long deformation period of 6 months.As confirmed by in situ monitoring results,4D support is more effective for the long‐term stability control of surrounding rock than conventional support.
基金The authors acknowledge the National Key Research and Development Program(No.2022YFE0121000)Fundamental Research Funds for the Central Universitiesthe Project for Graduate Innovation Team of the Northwestern Polytechnical University,and the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University(No.CX2021042).
文摘Benefiting from the high capacity of Zn metal anodes and intrinsic safety of aqueous electrolytes,rechargeable Zn ion batteries(ZIBs)show promising application in the post‐lithium‐ion period,exhibiting good safety,low cost,and high energy density.However,its commercialization still faces problems with low Coulombic efficiency and unsatisfied cycling performance due to the poor Zn/Zn2+reversibility that occurred on the Zn anode.To improve the stability of the Zn anode,optimizing the Zn deposition behavior is an efficient way,which can enhance the subsequent striping efficiency and limit the dendrite growth.The Zn deposition is a controlled kinetics‐diffusion joint process that is affected by various factors,such as the interaction between Zn2+ions and Zn anodes,ion concentration gradient,and current distribution.In this review,from an electrochemical perspective,we first overview the factors affecting the Zn deposition behavior and summarize the modification principles.Subsequently,strategies proposed for interfacial modification and 3D structural design as well as the corresponding mechanisms are summarized.Finally,the existing challenges,perspectives on further development direction,and outlook for practical applications of ZIBs are proposed.
基金the Space Core Technology Development Program(No.2017M1A3A3A02016782).
文摘All-inorganic cesium lead halide based perovskite nanocrystals(PNCs)exhibit promising optoelectronic properties,but their poor stability and anion exchange reaction limit their broad commercial applications.Herein,we demonstrated the successful synthesis of blue-green-red emitting CsPbX_(3)(X=Cl/Br,Br,and Br/I)PNCs via hot injection method,followed by silica-coating and embedding in poly(methylmethacrylate)(PMMA)matrix.The photoluminescence(PL)spectra of SiO_(2)/PMMA-coated PNCs can be tuned continuously by regulating precursor composition ratio,from blue(CsPb(Cl_(0.5)/Br_(0.5))_(3);460 nm)to red(CsPb(Br_(0.4)/I_(0.6))_(3)via green(CsPbBr_(3);519 nm).The PNCs composite films exhibit improved stability(thermal-,moisture-,and photo-stability)because of the barrier formed by Si0_(2)/PMMA coating and also displayed exceptional photoluminescent quantum yield(PLQY of blue,green,and red-emitting Si0_(2)/PMMA coated PNCs are 37%,86%,and 71%,respectively)with longer lifetimes inhibiting anion exchange.Eventually,the PNCs-encapsulated Si0_(2)/PMMA composite films were integrated into the UV LED chip as down-converting materials to construct a prototype white-peLED unit.The designed white-peLED unit demonstrated bright white light generating CIE coordinates(0.349,0.350),a luminous efficiency(LE)of 39.2%and a color rendering index(CRI)of 84.7.The wide color gamut of 121.47%of NTSC and 98.56%of Rec.2020 is also achieved with the built w-LED system.Therefore,the results demonstrated that CsPbX_(3)(X=Cl/Br,Br,and Br/I)PNCs@SiO_(2)/PMMA composite films can be employed as efficient UV to visible color conversion materials for white-LEDs and backlighting.
