The low surface energy fluorocarbon polymer from the synthesized fluoro-acrylic resins was developed.Then the molecule orientation principle of nonpolar and polar functional groups in the polymers was analyzed.And the...The low surface energy fluorocarbon polymer from the synthesized fluoro-acrylic resins was developed.Then the molecule orientation principle of nonpolar and polar functional groups in the polymers was analyzed.And the contact angles of pure water drops on the surfaces of various fluoro-monomer homopolymers and interpolymers were measured.So the relation of polymers’fluoro-content with the surface energy was determined.The distribution of fluoric functional groups in the polymers was investigated.And the test results show that though the total fluorine content of the fluorocarbon polymers is relative few,their surface energy is really low due to the enrichment of fluoro-chains on the polymers surface.展开更多
Potential energy surfaces(PESs), vibrational frequencies, and infrared spectra are calculated for NF_(3)^(+) using ab initio calculations, based on UCCSD(T)/cc-p VTZ combined with vibrational configuration interaction...Potential energy surfaces(PESs), vibrational frequencies, and infrared spectra are calculated for NF_(3)^(+) using ab initio calculations, based on UCCSD(T)/cc-p VTZ combined with vibrational configuration interaction(VCI). Based on an iterative algorithm, the surfaces(SURF) program adds automatic points to the lattice representation of the potential function, the one-dimensional and two-dimensional PESs are calculated after reaching a convergence threshold, finally the smooth image of the potential energy surface is fitted. The PESs accurately account for the interaction between the different modes, with the mode q_(6) symmetrical stretching vibrations having the greatest effect on the potential energy change of the whole system throughout the potential energy surface shift. The anharmonic frequencies are obtained when the VCI matrix is diagonalized. Fundamental frequencies, overtones, and combination bands of NF_(3)^(+) are calculated, which generate the degenerate phenomenon between their frequencies. Finally, the calculated anharmonic frequency is used to plot the infrared spectra.Modal antisymmetric stretching ν_(5) and symmetric stretching ν_(6) exhibit a phenomenon of large-intensity borrowing. This study can provide data to support the characterization in the laboratory.展开更多
Accurate initial soil conditions play a crucial role in simulating soil hydrothermal and surface energy fluxes in land surface process modeling.This study emphasized the influence of the initial soil temperature(ST)an...Accurate initial soil conditions play a crucial role in simulating soil hydrothermal and surface energy fluxes in land surface process modeling.This study emphasized the influence of the initial soil temperature(ST)and soil moisture(SM)conditions on a land surface energy and water simulation in the permafrost region in the Tibetan Plateau(TP)using the Community Land Model version 5.0(CLM5.0).The results indicate that the default initial schemes for ST and SM in CLM5.0 were simplistic,and inaccurately represented the soil characteristics of permafrost in the TP which led to underestimating ST during the freezing period while overestimating ST and underestimating SLW during the thawing period at the XDT site.Applying the long-term spin-up method to obtain initial soil conditions has only led to limited improvement in simulating soil hydrothermal and surface energy fluxes.The modified initial soil schemes proposed in this study comprehensively incorporate the characteristics of permafrost,which coexists with soil liquid water(SLW),and soil ice(SI)when the ST is below freezing temperature,effectively enhancing the accuracy of the simulated soil hydrothermal and surface energy fluxes.Consequently,the modified initial soil schemes greatly improved upon the results achieved through the long-term spin-up method.Three modified initial soil schemes experiments resulted in a 64%,88%,and 77%reduction in the average mean bias error(MBE)of ST,and a 13%,21%,and 19%reduction in the average root-mean-square error(RMSE)of SLW compared to the default simulation results.Also,the average MBE of net radiation was reduced by 7%,22%,and 21%.展开更多
Antifouling coatings are used to improve the speed and energy efficiency of ships by preventing or- ganisms, such as barnacles and weed, building up on the underwater hull and helping the ships movement through the wa...Antifouling coatings are used to improve the speed and energy efficiency of ships by preventing or- ganisms, such as barnacles and weed, building up on the underwater hull and helping the ships movement through the water. Typically, marine coatings are tributyltin self-polishing copolymer paints containing toxic molecules called biocides. They have been the most successful in combating bio- fouling on ships, but their widespread use has caused severe pollution in the marine ecosystem. The low surface energy marine coating is an entirely non-toxic alternative, which reduces the adhesion strength of marine organisms, facilitating their hydrodynamic removal at high speeds. In this paper, the novel low surface energy non-toxic marine antifouling coatings were prepared with modified acrylic resin, nano-SiO2, and other pigments. The effects of nano-SiO2 on the surface structure and elastic modulus of coating films have been studied, and the seawater test has been carried out in the Dalian Bay. The results showed that micro-nano layered structures on the coating films and the lowest surface energy and elastic modulus could be obtained when an appropriate mass ratio of resin, nano-SiO2, and other pigments in coatings approached. The seawater exposure test has shown that the lower the sur- face energy and elastic modulus of coatings are, the less the marine biofouling adheres on the coating films.展开更多
Direct exposure of samples to the active species of air generated by a One Atmosphere Uniform Glow Discharge Plasma (OAUGDP) has been used to etch and to increase the surface energy of metallic surfaces, photoresist, ...Direct exposure of samples to the active species of air generated by a One Atmosphere Uniform Glow Discharge Plasma (OAUGDP) has been used to etch and to increase the surface energy of metallic surfaces, photoresist, polymer films, and nonwoven fab- rics. The OAUGDP is a non-thermal plasma with the classical characteristics of a DC normal glow discharge that operates in air (and other gases) at atmospheric pres- sure. Neither a vacuum system nor batch processing is necessary. A wide range of applications to metals, photoresist, films, fabrics, and polymeric webs can be accom- modated by direct exposure of the workpiece to the plasma in parallel-plate reactors. This technolopy is simple, it produces effects that can be obtained in no other way at one atmosphere; it generates minimal pollutants or unwanted by-products; and it is suitable for individual sample or online treatment of metallic surfaces, wafers, films, and fabrics. Early exposures of solid materials to the OAUGDP required minutes to produce rela- tively small increases of surface energy. These durations appeared too long for com- mercial application to fast-moving webs. Recent improvements in OAUGDP gas com- position, power density, plasma quality, recireulating gas flow, and impedance match- ing of the power supply to the parallel plate plasma reactor have made it possible to raise the surface energy of a variety of polymeric webs (PP, PET PE etc.) to levels of 60 to 70 dynes/cm with one second of exposure. In air plasmas, the high surface ener- gies are not durable, and fall to 50 dynes/cm after periods of weeks to months. Here, we report the exposure of metallic surfaces, photoresist, polymeric films, and nonwo- ven fabrics made of PP and PET to an impedance matched parallel plate OAUGDP for durations ranging from one second to several tens of seconds. Data will be re- ported on the surface energy, wettability, wickability, and aging effect of polymeric films and fabrics as functions of time of exposure, and time after exposure; the rate and uniformity of photoresist etching; and the production of sub-micron structures by OAUGDP etching at one atmosphere.展开更多
Laminar flow design is one of the most effective ways to reduce the drag of a commercial aircraft by expanding the laminar flow region on the surface of the aircraft. As material science develops, the emergence of new...Laminar flow design is one of the most effective ways to reduce the drag of a commercial aircraft by expanding the laminar flow region on the surface of the aircraft. As material science develops, the emergence of new materials such as low surface energy materials has offered new choices for laminar flow design of commercial aircraft. Different types of low surface energy micro-nano coatings are prepared to verify the effects on the boundary layer transition position and the drag of the airfoil through wind tunnel tests. The infrared thermal imaging technology is adopted for measuring the boundary layer transition, while the momentum integral approach is employed to measure the drag coefficient through a wake rake. Infrared thermal imaging results indicate that the coatings are capable of moving backward the boundary layer transition position at both a low velocity of Mach number 0.15 and a high velocity of Mach number 0.785. Results of the momentum integral approach demonstrate that the drag coefficients are reduced obviously within the cruising angle of attack range from 1° and 5° by introducing the low surface energy micro-nano coating technology.展开更多
THE response of a compliant coating to pressure fluctuations is known to modify the skin friction in a turbulent boundary layer. It was found that the addition of the dilute solution of polymer additive would reduce d...THE response of a compliant coating to pressure fluctuations is known to modify the skin friction in a turbulent boundary layer. It was found that the addition of the dilute solution of polymer additive would reduce drag, surface pressure fluctuation, and also high frequency radiated flow noise. The results of microbubble show that the drag reduction is near 60%展开更多
As a substitute for toxic cadmium coatings in the aerospace industry,zinc-nickel coatings have excellent application prospects,and their properties can be improved by adding molybdenum.In this study,laser-assisted ele...As a substitute for toxic cadmium coatings in the aerospace industry,zinc-nickel coatings have excellent application prospects,and their properties can be improved by adding molybdenum.In this study,laser-assisted electrodeposition is used to improve the surface quality and properties of Zn–Ni–Mo coatings,with investigation of how laser energy in the range of 0–21.1μJ affects their element content,surface morphology,crystal phase,microhardness,residual internal stress,and corrosion resistance.The laser irradiation accelerates the electrodeposition,refines the grain size,improves the hydrogen adsorption,and reduces the residual tensile stress,and a laser energy of 15.4μJ gives the highest Ni and Mo contents and the lowest Zn content,as well as the optimum surface morphology,microhardness,residual internal stress,and corrosion resistance of the coating.展开更多
Lattice structures have drawn much attention in engineering applications due to their lightweight and multi-functional properties.In this work,a mathematical design approach for functionally graded(FG)and helicoidal l...Lattice structures have drawn much attention in engineering applications due to their lightweight and multi-functional properties.In this work,a mathematical design approach for functionally graded(FG)and helicoidal lattice structures with triply periodic minimal surfaces is proposed.Four types of lattice structures including uniform,helicoidal,FG,and combined FG and helicoidal are fabricated by the additive manufacturing technology.The deformation behaviors,mechanical properties,energy absorption,and acoustic properties of lattice samples are thoroughly investigated.The load-bearing capability of helicoidal lattice samples is gradually improved in the plateau stage,leading to the plateau stress and total energy absorption improved by over 26.9%and 21.2%compared to the uniform sample,respectively.This phenomenon was attributed to the helicoidal design reduces the gap in unit cells and enhances fracture resistance.For acoustic properties,the design of helicoidal reduces the resonance frequency and improves the peak of absorption coefficient,while the FG design mainly influences the peak of absorption coefficient.Across broad range of frequency from 1000 to 6300 Hz,the maximum value of absorption coefficient is improved by18.6%-30%,and the number of points higher than 0.6 increased by 55.2%-61.7%by combining the FG and helicoidal designs.This study provides a novel strategy to simultaneously improve energy absorption and sound absorption properties by controlling the internal architecture of lattice structures.展开更多
The construction of relevant standards for building carbon emission assessment in China has just started,and the quantitative analysis method and evaluation system are still imperfect,which hinders the development of ...The construction of relevant standards for building carbon emission assessment in China has just started,and the quantitative analysis method and evaluation system are still imperfect,which hinders the development of low-carbon building design.Therefore,the use of intelligent energy management system is very necessary.The purpose of this paper is to explore the design optimization of low-carbon buildings based on intelligent energy management systems.Based on the proposed quantitative method of building carbon emission,this paper establishes the quota theoretical system of building carbon emission analysis,and develops the quota based carbon emission calculation software.Smart energy management system is a low-carbon energy-saving system based on the reference of large-scale building energy-saving system and combined with energy consumption.It provides a fast and effective calculation tool for the quantitative evaluation of carbon emission of construction projects,so as to realize the carbon emission control and optimization in the early stage of architectural design and construction.On this basis,the evaluation,analysis and calculation method of building structure based on carbon reduction target is proposed,combined with the carbon emission quota management standard proposed in this paper.Taking small high-rise residential buildings as an example,this paper compares and analyzes different building structural systems from the perspectives of structural performance,economy and carbon emission level.It provides a reference for the design and evaluation of low-carbon building structures.The smart energy management system collects user energy use parameters.It uses time period and time sequence to obtain a large amount of data for analysis and integration,which provides users with intuitive energy consumption data.Compared with the traditional architectural design method,the industrialized construction method can save 589.22 megajoules(MJ)per square meter.Based on 29270 megajoules(MJ)per ton of standard coal,the construction area of the case is about 8000 m2,and the energy saving of residential buildings is 161.04 tons of standard coal.This research is of great significance in reducing the carbon emission intensity of buildings.展开更多
A kinetic model was proposed to predict the seawater fouling process in the seawater heat exchangers.The new model adopted an expression combining depositional and removal behaviors for seawater fouling based on the K...A kinetic model was proposed to predict the seawater fouling process in the seawater heat exchangers.The new model adopted an expression combining depositional and removal behaviors for seawater fouling based on the Kern–Seaton model.The present model parameters include the integrated kinetic rate of deposition(k d)and the integrated kinetic rate of removal(k r),which have clear physical signi ficance.A seawater-fouling monitoring device was established to validate the model.The experimental data were well fitted to the model,and the parameters were obtained in different conditions.SEM and EDX analyses were performed after the experiments,and the results show that the main components of seawater fouling are magnesium hydroxide and aluminum hydroxide.The effects of surface temperature,flow velocity and surface free energy were assessed by the model and the experimental data.The results indicate that the seawater fouling becomes aggravated as the surface temperature increased in a certain range,and the seawater fouling resistance reduced as the flow velocity of seawater increased.Furthermore,the effect of the surface free energy of metals was analyzed,showing that the lower surface free energy mitigates the seawater fouling accumulation.展开更多
Multiphase flow in low permeability porous media is involved in numerous energy and environmental applications.However,a complete description of this process is challenging due to the limited modeling scale and the ef...Multiphase flow in low permeability porous media is involved in numerous energy and environmental applications.However,a complete description of this process is challenging due to the limited modeling scale and the effects of complex pore structures and wettability.To address this issue,based on the digital rock of low permeability sandstone,a direct numerical simulation is performed considering the interphase drag and boundary slip to clarify the microscopic water-oil displacement process.In addition,a dual-porosity pore network model(PNM)is constructed to obtain the water-oil relative permeability of the sample.The displacement efficiency as a recovery process is assessed under different wetting and pore structure properties.Results show that microscopic displacement mechanisms explain the corresponding macroscopic relative permeability.The injected water breaks through the outlet earlier with a large mass flow,while thick oil films exist in rough hydrophobic surfaces and poorly connected pores.The variation of water-oil relative permeability is significant,and residual oil saturation is high in the oil-wet system.The flooding is extensive,and the residual oil is trapped in complex pore networks for hydrophilic pore surfaces;thus,water relative permeability is lower in the water-wet system.While the displacement efficiency is the worst in mixed-wetting systems for poor water connectivity.Microporosity negatively correlates with invading oil volume fraction due to strong capillary resistance,and a large microporosity corresponds to low residual oil saturation.This work provides insights into the water-oil flow from different modeling perspectives and helps to optimize the development plan for enhanced recovery.展开更多
The utilization of mobile edge computing(MEC)for unmanned aerial vehicle(UAV)communication presents a viable solution for achieving high reliability and low latency communication.This study explores the potential of e...The utilization of mobile edge computing(MEC)for unmanned aerial vehicle(UAV)communication presents a viable solution for achieving high reliability and low latency communication.This study explores the potential of employing intelligent reflective surfaces(IRS)andUAVs as relay nodes to efficiently offload user computing tasks to theMEC server system model.Specifically,the user node accesses the primary user spectrum,while adhering to the constraint of satisfying the primary user peak interference power.Furthermore,the UAV acquires energy without interrupting the primary user’s regular communication by employing two energy harvesting schemes,namely time switching(TS)and power splitting(PS).The selection of the optimal UAV is based on the maximization of the instantaneous signal-to-noise ratio.Subsequently,the analytical expression for the outage probability of the system in Rayleigh channels is derived and analyzed.The study investigates the impact of various system parameters,including the number of UAVs,peak interference power,TS,and PS factors,on the system’s outage performance through simulation.The proposed system is also compared to two conventional benchmark schemes:the optimal UAV link transmission and the IRS link transmission.The simulation results validate the theoretical derivation and demonstrate the superiority of the proposed scheme over the benchmark schemes.展开更多
In recent years,switched inductor(SL)technology,switched capacitor(SC)technology,and switched inductor-capacitor(SL-SC)technology have been widely applied to optimize and improve DC-DC boost converters,which can effec...In recent years,switched inductor(SL)technology,switched capacitor(SC)technology,and switched inductor-capacitor(SL-SC)technology have been widely applied to optimize and improve DC-DC boost converters,which can effectively enhance voltage gain and reduce device stress.To address the issue of low output voltage in current renewable energy power generation systems,this study proposes a novel non-isolated cubic high-gain DC-DC converter based on the traditional quadratic DC-DC boost converter by incorporating a SC and a SL-SC unit.Firstly,the proposed converter’s details are elaborated,including its topology structure,operating mode,voltage gain,device stress,and power loss.Subsequently,a comparative analysis is conducted on the voltage gain and device stress between the proposed converter and other high-gain converters.Then,a closed-loop simulation system is constructed to obtain simulation waveforms of various devices and explore the dynamic performance.Finally,an experimental prototype is built,experimental waveforms are obtained,and the experimental dynamic performance and conversion efficiency are analyzed.The theoretical analysis’s correctness is verified through simulation and experimental results.The proposed converter has advantages such as high voltage gain,low device stress,high conversion efficiency,simple control,and wide input voltage range,achieving a good balance between voltage gain,device stress,and power loss.The proposed converter is well-suited for renewable energy systems and holds theoretical significance and practical value in renewable energy applications.It provides an effective solution to the issue of low output voltage in renewable energy power generation systems.展开更多
In this paper,we investigate the energy efficiency maximization for mobile edge computing(MEC)in intelligent reflecting surface(IRS)assisted unmanned aerial vehicle(UAV)communications.In particular,UAVcan collect the ...In this paper,we investigate the energy efficiency maximization for mobile edge computing(MEC)in intelligent reflecting surface(IRS)assisted unmanned aerial vehicle(UAV)communications.In particular,UAVcan collect the computing tasks of the terrestrial users and transmit the results back to them after computing.We jointly optimize the users’transmitted beamforming and uploading ratios,the phase shift matrix of IRS,and the UAV trajectory to improve the energy efficiency.The formulated optimization problem is highly non-convex and difficult to be solved directly.Therefore,we decompose the original problem into three sub-problems.We first propose the successive convex approximation(SCA)based method to design the beamforming of the users and the phase shift matrix of IRS,and apply the Lagrange dual method to obtain a closed-form expression of the uploading ratios.For the trajectory optimization,we propose a block coordinate descent(BCD)based method to obtain a local optimal solution.Finally,we propose the alternating optimization(AO)based overall algorithmand analyzed its complexity to be equivalent or lower than existing algorithms.Simulation results show the superiority of the proposedmethod compared with existing schemes in energy efficiency.展开更多
In order to solve the problem of single arc plasma actuator's failure to suppress the boundary layer separation, the effectiveness of the array surface arc plasma actuator to enhance the excitation intensity is ve...In order to solve the problem of single arc plasma actuator's failure to suppress the boundary layer separation, the effectiveness of the array surface arc plasma actuator to enhance the excitation intensity is verified by experiment. In this study, an electrical parameter measurement system and high-speed schlieren technology were adopted to delve into the electrical, flow field, and excitation characteristics of the high-energy array surface arc plasma actuator under low ambient pressure. The high-energy array surface arc discharge released considerable heat rapidly;as a result, two characteristic structures were generated, i.e., the precursor shock wave and thermal deposition area. The duration increased with the increase in environmental pressure. The lower the pressure, the wider the thermal deposition area's influence range. The precursor shock wave exhibited a higher propagation speed at the initial phase of discharge;it tended to decay over time and finally remained at 340 m/s. The lower the environmental pressure, the higher the speed would be at the initial phase. High-energy array surface arc plasma actuator can be employed to achieve effective high-speed aircraft flow control.展开更多
Wireless sensor networks(WSN)gather information and sense information samples in a certain region and communicate these readings to a base station(BS).Energy efficiency is considered a major design issue in the WSNs,a...Wireless sensor networks(WSN)gather information and sense information samples in a certain region and communicate these readings to a base station(BS).Energy efficiency is considered a major design issue in the WSNs,and can be addressed using clustering and routing techniques.Information is sent from the source to the BS via routing procedures.However,these routing protocols must ensure that packets are delivered securely,guaranteeing that neither adversaries nor unauthentic individuals have access to the sent information.Secure data transfer is intended to protect the data from illegal access,damage,or disruption.Thus,in the proposed model,secure data transmission is developed in an energy-effective manner.A low-energy adaptive clustering hierarchy(LEACH)is developed to efficiently transfer the data.For the intrusion detection systems(IDS),Fuzzy logic and artificial neural networks(ANNs)are proposed.Initially,the nodes were randomly placed in the network and initialized to gather information.To ensure fair energy dissipation between the nodes,LEACH randomly chooses cluster heads(CHs)and allocates this role to the various nodes based on a round-robin management mechanism.The intrusion-detection procedure was then utilized to determine whether intruders were present in the network.Within the WSN,a Fuzzy interference rule was utilized to distinguish the malicious nodes from legal nodes.Subsequently,an ANN was employed to distinguish the harmful nodes from suspicious nodes.The effectiveness of the proposed approach was validated using metrics that attained 97%accuracy,97%specificity,and 97%sensitivity of 95%.Thus,it was proved that the LEACH and Fuzzy-based IDS approaches are the best choices for securing data transmission in an energy-efficient manner.展开更多
Evidence is obtained from the data of an earlier measurement that the effect of ion-surface interaction on the stopping power of highly charged slow ions is not at all tiny rather remarkably large, even it supersedes ...Evidence is obtained from the data of an earlier measurement that the effect of ion-surface interaction on the stopping power of highly charged slow ions is not at all tiny rather remarkably large, even it supersedes the bulk stopping power. The stopping power due to the surface interactions is directly proportional to the charge state of incident ions.展开更多
The inner surface modification process by plasma-based low-energy ion implantation(PBLEII)with an electron cyclotron resonance(ECR)microwave plasma source located at the central axis of a cylindrical tube is modeled t...The inner surface modification process by plasma-based low-energy ion implantation(PBLEII)with an electron cyclotron resonance(ECR)microwave plasma source located at the central axis of a cylindrical tube is modeled to optimize the low-energy ion implantation parameters for industrial applications.In this paper,a magnetized plasma diffusion fluid model has been established to describe the plasma nonuniformity caused by plasma diffusion under an axial magnetic field during the pulse-off time of low pulsed negative bias.Using this plasma density distribution as the initial condition,a sheath collisional fluid model is built up to describe the sheath evolution and ion implantation during the pulse-on time.The plasma nonuniformity at the end of the pulse-off time is more apparent along the radial direction compared with that in the axial direction due to the geometry of the linear plasma source in the center and the difference between perpendicular and parallel plasma diffusion coefficients with respect to the magnetic field.The normalized nitrogen plasma densities on the inner and outer surfaces of the tube are observed to be about 0.39 and 0.24,respectively,of which the value is 1 at the central plasma source.After a 5μs pulse-on time,in the area less than 2 cm from the end of the tube,the nitrogen ion implantation energy decreases from 1.5 keV to 1.3 keV and the ion implantation angle increases from several degrees to more than 40°;both variations reduce the nitrogen ion implantation depth.However,the nitrogen ion implantation dose peaks of about 2×10^(10)-7×10^(10)ions/cm^2 in this area are 2-4 times higher than that of 1.18×10^(10)ions/cm^2 and 1.63×10^(10)ions/cm^2 on the inner and outer surfaces of the tube.The sufficient ion implantation dose ensures an acceptable modification effect near the end of the tube under the low energy and large angle conditions for nitrogen ion implantation,because the modification effect is mainly determined by the ion implantation dose,just as the mass transfer process in PBLEII is dominated by low-energy ion implantation and thermal diffusion.Therefore,a comparatively uniform surface modification by the low-energy nitrogen ion implantation is achieved along the cylindrical tube on both the inner and outer surfaces.展开更多
基金Funded by the National Basic Research Program(973 Program) of China(No.2007CB607603)
文摘The low surface energy fluorocarbon polymer from the synthesized fluoro-acrylic resins was developed.Then the molecule orientation principle of nonpolar and polar functional groups in the polymers was analyzed.And the contact angles of pure water drops on the surfaces of various fluoro-monomer homopolymers and interpolymers were measured.So the relation of polymers’fluoro-content with the surface energy was determined.The distribution of fluoric functional groups in the polymers was investigated.And the test results show that though the total fluorine content of the fluorocarbon polymers is relative few,their surface energy is really low due to the enrichment of fluoro-chains on the polymers surface.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.52002318 and 22103061)。
文摘Potential energy surfaces(PESs), vibrational frequencies, and infrared spectra are calculated for NF_(3)^(+) using ab initio calculations, based on UCCSD(T)/cc-p VTZ combined with vibrational configuration interaction(VCI). Based on an iterative algorithm, the surfaces(SURF) program adds automatic points to the lattice representation of the potential function, the one-dimensional and two-dimensional PESs are calculated after reaching a convergence threshold, finally the smooth image of the potential energy surface is fitted. The PESs accurately account for the interaction between the different modes, with the mode q_(6) symmetrical stretching vibrations having the greatest effect on the potential energy change of the whole system throughout the potential energy surface shift. The anharmonic frequencies are obtained when the VCI matrix is diagonalized. Fundamental frequencies, overtones, and combination bands of NF_(3)^(+) are calculated, which generate the degenerate phenomenon between their frequencies. Finally, the calculated anharmonic frequency is used to plot the infrared spectra.Modal antisymmetric stretching ν_(5) and symmetric stretching ν_(6) exhibit a phenomenon of large-intensity borrowing. This study can provide data to support the characterization in the laboratory.
基金the National Natural Science Foundation of China(Grant No.U20A2081)West Light Foundation of the Chinese Academy of Sciences(Grant No.xbzg-zdsys-202102)the Second Tibetan Plateau Scientific Expedition and Research(STEP)Project(Grant No.2019QZKK0105).
文摘Accurate initial soil conditions play a crucial role in simulating soil hydrothermal and surface energy fluxes in land surface process modeling.This study emphasized the influence of the initial soil temperature(ST)and soil moisture(SM)conditions on a land surface energy and water simulation in the permafrost region in the Tibetan Plateau(TP)using the Community Land Model version 5.0(CLM5.0).The results indicate that the default initial schemes for ST and SM in CLM5.0 were simplistic,and inaccurately represented the soil characteristics of permafrost in the TP which led to underestimating ST during the freezing period while overestimating ST and underestimating SLW during the thawing period at the XDT site.Applying the long-term spin-up method to obtain initial soil conditions has only led to limited improvement in simulating soil hydrothermal and surface energy fluxes.The modified initial soil schemes proposed in this study comprehensively incorporate the characteristics of permafrost,which coexists with soil liquid water(SLW),and soil ice(SI)when the ST is below freezing temperature,effectively enhancing the accuracy of the simulated soil hydrothermal and surface energy fluxes.Consequently,the modified initial soil schemes greatly improved upon the results achieved through the long-term spin-up method.Three modified initial soil schemes experiments resulted in a 64%,88%,and 77%reduction in the average mean bias error(MBE)of ST,and a 13%,21%,and 19%reduction in the average root-mean-square error(RMSE)of SLW compared to the default simulation results.Also,the average MBE of net radiation was reduced by 7%,22%,and 21%.
基金High-Tech Research and Development Program of China (Grant No. 2004AA001520)
文摘Antifouling coatings are used to improve the speed and energy efficiency of ships by preventing or- ganisms, such as barnacles and weed, building up on the underwater hull and helping the ships movement through the water. Typically, marine coatings are tributyltin self-polishing copolymer paints containing toxic molecules called biocides. They have been the most successful in combating bio- fouling on ships, but their widespread use has caused severe pollution in the marine ecosystem. The low surface energy marine coating is an entirely non-toxic alternative, which reduces the adhesion strength of marine organisms, facilitating their hydrodynamic removal at high speeds. In this paper, the novel low surface energy non-toxic marine antifouling coatings were prepared with modified acrylic resin, nano-SiO2, and other pigments. The effects of nano-SiO2 on the surface structure and elastic modulus of coating films have been studied, and the seawater test has been carried out in the Dalian Bay. The results showed that micro-nano layered structures on the coating films and the lowest surface energy and elastic modulus could be obtained when an appropriate mass ratio of resin, nano-SiO2, and other pigments in coatings approached. The seawater exposure test has shown that the lower the sur- face energy and elastic modulus of coatings are, the less the marine biofouling adheres on the coating films.
文摘Direct exposure of samples to the active species of air generated by a One Atmosphere Uniform Glow Discharge Plasma (OAUGDP) has been used to etch and to increase the surface energy of metallic surfaces, photoresist, polymer films, and nonwoven fab- rics. The OAUGDP is a non-thermal plasma with the classical characteristics of a DC normal glow discharge that operates in air (and other gases) at atmospheric pres- sure. Neither a vacuum system nor batch processing is necessary. A wide range of applications to metals, photoresist, films, fabrics, and polymeric webs can be accom- modated by direct exposure of the workpiece to the plasma in parallel-plate reactors. This technolopy is simple, it produces effects that can be obtained in no other way at one atmosphere; it generates minimal pollutants or unwanted by-products; and it is suitable for individual sample or online treatment of metallic surfaces, wafers, films, and fabrics. Early exposures of solid materials to the OAUGDP required minutes to produce rela- tively small increases of surface energy. These durations appeared too long for com- mercial application to fast-moving webs. Recent improvements in OAUGDP gas com- position, power density, plasma quality, recireulating gas flow, and impedance match- ing of the power supply to the parallel plate plasma reactor have made it possible to raise the surface energy of a variety of polymeric webs (PP, PET PE etc.) to levels of 60 to 70 dynes/cm with one second of exposure. In air plasmas, the high surface ener- gies are not durable, and fall to 50 dynes/cm after periods of weeks to months. Here, we report the exposure of metallic surfaces, photoresist, polymeric films, and nonwo- ven fabrics made of PP and PET to an impedance matched parallel plate OAUGDP for durations ranging from one second to several tens of seconds. Data will be re- ported on the surface energy, wettability, wickability, and aging effect of polymeric films and fabrics as functions of time of exposure, and time after exposure; the rate and uniformity of photoresist etching; and the production of sub-micron structures by OAUGDP etching at one atmosphere.
基金support by the United Innovation Program of Shanghai Commercial Aircraft Engine, which was founded by Shanghai Municipal Commission of Economy and Informatization, Shanghai Municipal Education Commission, and AECC Commercial Aircraft Engine Co., Ltd. (No. AR909)the Aeronautical Science Foundation of China (No. 2015ZBP9002)the China Scholarship Council
文摘Laminar flow design is one of the most effective ways to reduce the drag of a commercial aircraft by expanding the laminar flow region on the surface of the aircraft. As material science develops, the emergence of new materials such as low surface energy materials has offered new choices for laminar flow design of commercial aircraft. Different types of low surface energy micro-nano coatings are prepared to verify the effects on the boundary layer transition position and the drag of the airfoil through wind tunnel tests. The infrared thermal imaging technology is adopted for measuring the boundary layer transition, while the momentum integral approach is employed to measure the drag coefficient through a wake rake. Infrared thermal imaging results indicate that the coatings are capable of moving backward the boundary layer transition position at both a low velocity of Mach number 0.15 and a high velocity of Mach number 0.785. Results of the momentum integral approach demonstrate that the drag coefficients are reduced obviously within the cruising angle of attack range from 1° and 5° by introducing the low surface energy micro-nano coating technology.
文摘THE response of a compliant coating to pressure fluctuations is known to modify the skin friction in a turbulent boundary layer. It was found that the addition of the dilute solution of polymer additive would reduce drag, surface pressure fluctuation, and also high frequency radiated flow noise. The results of microbubble show that the drag reduction is near 60%
基金supported by the National Natural Science Foundation of China(Grant Nos.51905226,52075227,and 52105449)the Natural Science Foundation of Jiangsu Province(Grant No.BK20210755)the Postdoctoral Foundation of Jiangsu Province(Grant No.2021K264B).
文摘As a substitute for toxic cadmium coatings in the aerospace industry,zinc-nickel coatings have excellent application prospects,and their properties can be improved by adding molybdenum.In this study,laser-assisted electrodeposition is used to improve the surface quality and properties of Zn–Ni–Mo coatings,with investigation of how laser energy in the range of 0–21.1μJ affects their element content,surface morphology,crystal phase,microhardness,residual internal stress,and corrosion resistance.The laser irradiation accelerates the electrodeposition,refines the grain size,improves the hydrogen adsorption,and reduces the residual tensile stress,and a laser energy of 15.4μJ gives the highest Ni and Mo contents and the lowest Zn content,as well as the optimum surface morphology,microhardness,residual internal stress,and corrosion resistance of the coating.
基金supported by the NUS R&G Postdoc Fellowship Program (No.A-0000065-76-00)the China Scholarship Council (No.202006050088)。
文摘Lattice structures have drawn much attention in engineering applications due to their lightweight and multi-functional properties.In this work,a mathematical design approach for functionally graded(FG)and helicoidal lattice structures with triply periodic minimal surfaces is proposed.Four types of lattice structures including uniform,helicoidal,FG,and combined FG and helicoidal are fabricated by the additive manufacturing technology.The deformation behaviors,mechanical properties,energy absorption,and acoustic properties of lattice samples are thoroughly investigated.The load-bearing capability of helicoidal lattice samples is gradually improved in the plateau stage,leading to the plateau stress and total energy absorption improved by over 26.9%and 21.2%compared to the uniform sample,respectively.This phenomenon was attributed to the helicoidal design reduces the gap in unit cells and enhances fracture resistance.For acoustic properties,the design of helicoidal reduces the resonance frequency and improves the peak of absorption coefficient,while the FG design mainly influences the peak of absorption coefficient.Across broad range of frequency from 1000 to 6300 Hz,the maximum value of absorption coefficient is improved by18.6%-30%,and the number of points higher than 0.6 increased by 55.2%-61.7%by combining the FG and helicoidal designs.This study provides a novel strategy to simultaneously improve energy absorption and sound absorption properties by controlling the internal architecture of lattice structures.
基金supported by“Key Technology Research on Operational Performance Improvement of the Green Building”(2020YFS0060)Key Project of Science and Technology Department of Sichuan Province+2 种基金supported by“Creative VR Teaching and Learning Research Based on‘PBL+’and Multidimensional Collaboration”(JG2021-721)“Reform in the Mode and Practice of Architecture Education with the Characteristics of Geology”(JG2021-672)Education Quality and Teaching Reform Project of Higher Education in Sichuan Province in 2021–2023.
文摘The construction of relevant standards for building carbon emission assessment in China has just started,and the quantitative analysis method and evaluation system are still imperfect,which hinders the development of low-carbon building design.Therefore,the use of intelligent energy management system is very necessary.The purpose of this paper is to explore the design optimization of low-carbon buildings based on intelligent energy management systems.Based on the proposed quantitative method of building carbon emission,this paper establishes the quota theoretical system of building carbon emission analysis,and develops the quota based carbon emission calculation software.Smart energy management system is a low-carbon energy-saving system based on the reference of large-scale building energy-saving system and combined with energy consumption.It provides a fast and effective calculation tool for the quantitative evaluation of carbon emission of construction projects,so as to realize the carbon emission control and optimization in the early stage of architectural design and construction.On this basis,the evaluation,analysis and calculation method of building structure based on carbon reduction target is proposed,combined with the carbon emission quota management standard proposed in this paper.Taking small high-rise residential buildings as an example,this paper compares and analyzes different building structural systems from the perspectives of structural performance,economy and carbon emission level.It provides a reference for the design and evaluation of low-carbon building structures.The smart energy management system collects user energy use parameters.It uses time period and time sequence to obtain a large amount of data for analysis and integration,which provides users with intuitive energy consumption data.Compared with the traditional architectural design method,the industrialized construction method can save 589.22 megajoules(MJ)per square meter.Based on 29270 megajoules(MJ)per ton of standard coal,the construction area of the case is about 8000 m2,and the energy saving of residential buildings is 161.04 tons of standard coal.This research is of great significance in reducing the carbon emission intensity of buildings.
基金Supported by the Leading Academic Discipline Project of Shanghai Municipal Education Commission(J50502)the Construction of Shanghai Science and Technology Commission(13DZ2260900)
文摘A kinetic model was proposed to predict the seawater fouling process in the seawater heat exchangers.The new model adopted an expression combining depositional and removal behaviors for seawater fouling based on the Kern–Seaton model.The present model parameters include the integrated kinetic rate of deposition(k d)and the integrated kinetic rate of removal(k r),which have clear physical signi ficance.A seawater-fouling monitoring device was established to validate the model.The experimental data were well fitted to the model,and the parameters were obtained in different conditions.SEM and EDX analyses were performed after the experiments,and the results show that the main components of seawater fouling are magnesium hydroxide and aluminum hydroxide.The effects of surface temperature,flow velocity and surface free energy were assessed by the model and the experimental data.The results indicate that the seawater fouling becomes aggravated as the surface temperature increased in a certain range,and the seawater fouling resistance reduced as the flow velocity of seawater increased.Furthermore,the effect of the surface free energy of metals was analyzed,showing that the lower surface free energy mitigates the seawater fouling accumulation.
基金supported by National Natural Science Foundation of China(Grant No.42172159)Science Foundation of China University of Petroleum,Beijing(Grant No.2462023XKBH002).
文摘Multiphase flow in low permeability porous media is involved in numerous energy and environmental applications.However,a complete description of this process is challenging due to the limited modeling scale and the effects of complex pore structures and wettability.To address this issue,based on the digital rock of low permeability sandstone,a direct numerical simulation is performed considering the interphase drag and boundary slip to clarify the microscopic water-oil displacement process.In addition,a dual-porosity pore network model(PNM)is constructed to obtain the water-oil relative permeability of the sample.The displacement efficiency as a recovery process is assessed under different wetting and pore structure properties.Results show that microscopic displacement mechanisms explain the corresponding macroscopic relative permeability.The injected water breaks through the outlet earlier with a large mass flow,while thick oil films exist in rough hydrophobic surfaces and poorly connected pores.The variation of water-oil relative permeability is significant,and residual oil saturation is high in the oil-wet system.The flooding is extensive,and the residual oil is trapped in complex pore networks for hydrophilic pore surfaces;thus,water relative permeability is lower in the water-wet system.While the displacement efficiency is the worst in mixed-wetting systems for poor water connectivity.Microporosity negatively correlates with invading oil volume fraction due to strong capillary resistance,and a large microporosity corresponds to low residual oil saturation.This work provides insights into the water-oil flow from different modeling perspectives and helps to optimize the development plan for enhanced recovery.
基金the National Natural Science Foundation of China(62271192)Henan Provincial Scientists Studio(GZS2022015)+10 种基金Central Plains Talents Plan(ZYYCYU202012173)NationalKeyR&DProgramofChina(2020YFB2008400)the Program ofCEMEE(2022Z00202B)LAGEO of Chinese Academy of Sciences(LAGEO-2019-2)Program for Science&Technology Innovation Talents in the University of Henan Province(20HASTIT022)Natural Science Foundation of Henan under Grant 202300410126Program for Innovative Research Team in University of Henan Province(21IRTSTHN015)Equipment Pre-Research Joint Research Program of Ministry of Education(8091B032129)Training Program for Young Scholar of Henan Province for Colleges and Universities(2020GGJS172)Program for Science&Technology Innovation Talents in Universities of Henan Province under Grand(22HASTIT020)Henan Province Science Fund for Distinguished Young Scholars(222300420006).
文摘The utilization of mobile edge computing(MEC)for unmanned aerial vehicle(UAV)communication presents a viable solution for achieving high reliability and low latency communication.This study explores the potential of employing intelligent reflective surfaces(IRS)andUAVs as relay nodes to efficiently offload user computing tasks to theMEC server system model.Specifically,the user node accesses the primary user spectrum,while adhering to the constraint of satisfying the primary user peak interference power.Furthermore,the UAV acquires energy without interrupting the primary user’s regular communication by employing two energy harvesting schemes,namely time switching(TS)and power splitting(PS).The selection of the optimal UAV is based on the maximization of the instantaneous signal-to-noise ratio.Subsequently,the analytical expression for the outage probability of the system in Rayleigh channels is derived and analyzed.The study investigates the impact of various system parameters,including the number of UAVs,peak interference power,TS,and PS factors,on the system’s outage performance through simulation.The proposed system is also compared to two conventional benchmark schemes:the optimal UAV link transmission and the IRS link transmission.The simulation results validate the theoretical derivation and demonstrate the superiority of the proposed scheme over the benchmark schemes.
基金This work was supported by China Railway Corporation Science and Technology Research and Development Project(P2021J038).
文摘In recent years,switched inductor(SL)technology,switched capacitor(SC)technology,and switched inductor-capacitor(SL-SC)technology have been widely applied to optimize and improve DC-DC boost converters,which can effectively enhance voltage gain and reduce device stress.To address the issue of low output voltage in current renewable energy power generation systems,this study proposes a novel non-isolated cubic high-gain DC-DC converter based on the traditional quadratic DC-DC boost converter by incorporating a SC and a SL-SC unit.Firstly,the proposed converter’s details are elaborated,including its topology structure,operating mode,voltage gain,device stress,and power loss.Subsequently,a comparative analysis is conducted on the voltage gain and device stress between the proposed converter and other high-gain converters.Then,a closed-loop simulation system is constructed to obtain simulation waveforms of various devices and explore the dynamic performance.Finally,an experimental prototype is built,experimental waveforms are obtained,and the experimental dynamic performance and conversion efficiency are analyzed.The theoretical analysis’s correctness is verified through simulation and experimental results.The proposed converter has advantages such as high voltage gain,low device stress,high conversion efficiency,simple control,and wide input voltage range,achieving a good balance between voltage gain,device stress,and power loss.The proposed converter is well-suited for renewable energy systems and holds theoretical significance and practical value in renewable energy applications.It provides an effective solution to the issue of low output voltage in renewable energy power generation systems.
基金the Key Scientific and Technological Project of Henan Province(Grant Number 222102210212)Doctoral Research Start Project of Henan Institute of Technology(Grant Number KQ2005)+1 种基金Doctoral Research Start Project of Henan Institute of Technology(Grant Number KQ2110)Key Research Projects of Colleges and Universities in Henan Province(Grant Number 23B510006).
文摘In this paper,we investigate the energy efficiency maximization for mobile edge computing(MEC)in intelligent reflecting surface(IRS)assisted unmanned aerial vehicle(UAV)communications.In particular,UAVcan collect the computing tasks of the terrestrial users and transmit the results back to them after computing.We jointly optimize the users’transmitted beamforming and uploading ratios,the phase shift matrix of IRS,and the UAV trajectory to improve the energy efficiency.The formulated optimization problem is highly non-convex and difficult to be solved directly.Therefore,we decompose the original problem into three sub-problems.We first propose the successive convex approximation(SCA)based method to design the beamforming of the users and the phase shift matrix of IRS,and apply the Lagrange dual method to obtain a closed-form expression of the uploading ratios.For the trajectory optimization,we propose a block coordinate descent(BCD)based method to obtain a local optimal solution.Finally,we propose the alternating optimization(AO)based overall algorithmand analyzed its complexity to be equivalent or lower than existing algorithms.Simulation results show the superiority of the proposedmethod compared with existing schemes in energy efficiency.
文摘In order to solve the problem of single arc plasma actuator's failure to suppress the boundary layer separation, the effectiveness of the array surface arc plasma actuator to enhance the excitation intensity is verified by experiment. In this study, an electrical parameter measurement system and high-speed schlieren technology were adopted to delve into the electrical, flow field, and excitation characteristics of the high-energy array surface arc plasma actuator under low ambient pressure. The high-energy array surface arc discharge released considerable heat rapidly;as a result, two characteristic structures were generated, i.e., the precursor shock wave and thermal deposition area. The duration increased with the increase in environmental pressure. The lower the pressure, the wider the thermal deposition area's influence range. The precursor shock wave exhibited a higher propagation speed at the initial phase of discharge;it tended to decay over time and finally remained at 340 m/s. The lower the environmental pressure, the higher the speed would be at the initial phase. High-energy array surface arc plasma actuator can be employed to achieve effective high-speed aircraft flow control.
文摘Wireless sensor networks(WSN)gather information and sense information samples in a certain region and communicate these readings to a base station(BS).Energy efficiency is considered a major design issue in the WSNs,and can be addressed using clustering and routing techniques.Information is sent from the source to the BS via routing procedures.However,these routing protocols must ensure that packets are delivered securely,guaranteeing that neither adversaries nor unauthentic individuals have access to the sent information.Secure data transfer is intended to protect the data from illegal access,damage,or disruption.Thus,in the proposed model,secure data transmission is developed in an energy-effective manner.A low-energy adaptive clustering hierarchy(LEACH)is developed to efficiently transfer the data.For the intrusion detection systems(IDS),Fuzzy logic and artificial neural networks(ANNs)are proposed.Initially,the nodes were randomly placed in the network and initialized to gather information.To ensure fair energy dissipation between the nodes,LEACH randomly chooses cluster heads(CHs)and allocates this role to the various nodes based on a round-robin management mechanism.The intrusion-detection procedure was then utilized to determine whether intruders were present in the network.Within the WSN,a Fuzzy interference rule was utilized to distinguish the malicious nodes from legal nodes.Subsequently,an ANN was employed to distinguish the harmful nodes from suspicious nodes.The effectiveness of the proposed approach was validated using metrics that attained 97%accuracy,97%specificity,and 97%sensitivity of 95%.Thus,it was proved that the LEACH and Fuzzy-based IDS approaches are the best choices for securing data transmission in an energy-efficient manner.
文摘Evidence is obtained from the data of an earlier measurement that the effect of ion-surface interaction on the stopping power of highly charged slow ions is not at all tiny rather remarkably large, even it supersedes the bulk stopping power. The stopping power due to the surface interactions is directly proportional to the charge state of incident ions.
基金supported by National Natural Science Foundation of China(Nos.50725519,51271048,51321004)
文摘The inner surface modification process by plasma-based low-energy ion implantation(PBLEII)with an electron cyclotron resonance(ECR)microwave plasma source located at the central axis of a cylindrical tube is modeled to optimize the low-energy ion implantation parameters for industrial applications.In this paper,a magnetized plasma diffusion fluid model has been established to describe the plasma nonuniformity caused by plasma diffusion under an axial magnetic field during the pulse-off time of low pulsed negative bias.Using this plasma density distribution as the initial condition,a sheath collisional fluid model is built up to describe the sheath evolution and ion implantation during the pulse-on time.The plasma nonuniformity at the end of the pulse-off time is more apparent along the radial direction compared with that in the axial direction due to the geometry of the linear plasma source in the center and the difference between perpendicular and parallel plasma diffusion coefficients with respect to the magnetic field.The normalized nitrogen plasma densities on the inner and outer surfaces of the tube are observed to be about 0.39 and 0.24,respectively,of which the value is 1 at the central plasma source.After a 5μs pulse-on time,in the area less than 2 cm from the end of the tube,the nitrogen ion implantation energy decreases from 1.5 keV to 1.3 keV and the ion implantation angle increases from several degrees to more than 40°;both variations reduce the nitrogen ion implantation depth.However,the nitrogen ion implantation dose peaks of about 2×10^(10)-7×10^(10)ions/cm^2 in this area are 2-4 times higher than that of 1.18×10^(10)ions/cm^2 and 1.63×10^(10)ions/cm^2 on the inner and outer surfaces of the tube.The sufficient ion implantation dose ensures an acceptable modification effect near the end of the tube under the low energy and large angle conditions for nitrogen ion implantation,because the modification effect is mainly determined by the ion implantation dose,just as the mass transfer process in PBLEII is dominated by low-energy ion implantation and thermal diffusion.Therefore,a comparatively uniform surface modification by the low-energy nitrogen ion implantation is achieved along the cylindrical tube on both the inner and outer surfaces.
