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Performance study of aluminum shielded room for ultra-low-field magnetic resonance imaging based on SQUID: Simulations and experiments
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作者 李波 董慧 +3 位作者 黄小磊 邱阳 陶泉 朱建明 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第2期273-279,共7页
The aluminum shielded room has been an important part of ultra-low-field magnetic resonance imaging(ULF MRI)based on the superconducting quantum interference device(SQUID). The shielded room is effective to attenuate ... The aluminum shielded room has been an important part of ultra-low-field magnetic resonance imaging(ULF MRI)based on the superconducting quantum interference device(SQUID). The shielded room is effective to attenuate the external radio-frequency field and keep the extremely sensitive detector, SQUID, working properly. A high-performance shielded room can increase the signal-to-noise ratio(SNR) and improve image quality. In this study, a circular coil with a diameter of 50 cm and a square coil with a side length of 2.0 m was used to simulate the magnetic fields from the nearby electric apparatuses and the distant environmental noise sources. The shielding effectivenesses(SE) of the shielded room with different thicknesses of aluminum sheets were calculated and simulated. A room using 6-mm-thick aluminum plates with a dimension of 1.5 m×1.5 m×2.0 m was then constructed. The SE was experimentally measured by using three-axis SQUID magnetometers, with tranisent magnetic field induced in the aluminum plates by the strong pre-polarization pulses. The results of the measured SE agreed with that from the simulation. In addition, the introduction of a 0.5-mm gap caused the obvious reduction of SE indicating the importance of door design. The nuclear magnetic resonance(NMR) signals of water at 5.9 kHz were measured in free space and in a shielded room, and the SNR was improved from 3 to 15. The simulation and experimental results will help us design an aluminum shielded room which satisfies the requirements for future ULF human brain imaging. Finally, the cancellation technique of the transient eddy current was tried, the simulation of the cancellation technique will lead us to finding an appropriate way to suppress the eddy current fields. 展开更多
关键词 声成像 防护 模拟 空间 铝板 磁性 学习 表演
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Application of nuclear magnetic resonance technology to carbon capture,utilization and storage:A review 被引量:6
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作者 Liang Xu Qi Li +2 位作者 Matthew Myers Quan Chen Xiaochun Li 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2019年第4期892-908,共17页
Carbon capture,utilization and storage (CCUS) is considered as a very important technology for mitigating global climate change.Carbon dioxide (CO2) injected into an underground reservoir will induce changes in its ph... Carbon capture,utilization and storage (CCUS) is considered as a very important technology for mitigating global climate change.Carbon dioxide (CO2) injected into an underground reservoir will induce changes in its physical properties and the migration of CO2 will be affected by many factors.Accurately understanding these changes and migration characteristics of CO2 is crucial for selecting a CCUS project site,estimating storage capacity and ensuring storage security.In this paper,the basic principles of nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) technologies are briefly introduced in the context of laboratory experiments related to CCUS.The types of NMR apparatus,experimental samples and testing approaches applied worldwide are discussed and analyzed.Then two typical NMR core analysis systems used in CCUS field and a self-developed high-pressure,low-field NMR rock core flooding experimental system are compared.Finally,a summary of the current deficiencies related to NMR applied to CCUS field is given and future research plans are proposed. 展开更多
关键词 GEOLOGIC carbon STORAGE nuclear magnetic resonance (NMR) Core FLOODING Experimental apparatus low-field NMR HIGH-field NMR
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7.0T nuclear magnetic resonance evaluation of the amyloid beta(1–40) animal model of Alzheimer's disease: comparison of cytology verification 被引量:6
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作者 Lei Zhang Shuai Dong +1 位作者 Guixiang Zhao Yu Ma 《Neural Regeneration Research》 SCIE CAS CSCD 2014年第4期430-435,共6页
3.0T magnetic resonance spectroscopic imaging is a commonly used method in the research of brain function in Alzheimer's disease.However,the role of 7.0T high-field magnetic resonance spectroscopic imaging in brai... 3.0T magnetic resonance spectroscopic imaging is a commonly used method in the research of brain function in Alzheimer's disease.However,the role of 7.0T high-field magnetic resonance spectroscopic imaging in brain function of Alzheimer's disease remains unclear.In this study,7.0T magnetic resonance spectroscopy showed that in the hippocampus of Alzheimer's disease rats,the N-acetylaspartate wave crest was reduced,and the creatine and choline wave crest was elevated.This finding was further supported by hematoxylin-eosin staining,which showed a loss of hippocampal neurons and more glial cells.Moreover,electron microscopy showed neuronal shrinkage and mitochondrial rupture,and scanning electron microscopy revealed small size hippocampal synaptic vesicles,incomplete synaptic structure,and reduced number.Overall,the results revealed that 7.0T high-field nuclear magnetic resonance spectroscopy detected the lesions and functional changes in hippocampal neurons of Alzheimer's disease rats in vivo,allowing the possibility for assessing the success rate and grading of the amyloid beta(1–40) animal model of Alzheimer's disease. 展开更多
关键词 阿尔茨海默氏病 Β淀粉样蛋白 核磁共振 动物模型 细胞学 海马神经元 电子显微镜观察 磁共振波谱
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Nuclear magnetic resonance measurement station in SECUF using hybrid superconducting magnets 被引量:1
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作者 李政 郑国庆 《Chinese Physics B》 SCIE EI CAS CSCD 2018年第7期107-111,共5页
Nuclear magnetic resonance(NMR) is one of the most powerful tools to explore new quantum states of condensed matter induced by high magnetic fields at a microscopic level. High magnetic field enhances the intensity of... Nuclear magnetic resonance(NMR) is one of the most powerful tools to explore new quantum states of condensed matter induced by high magnetic fields at a microscopic level. High magnetic field enhances the intensity of the NMR signal, and more importantly, can induce novel phenomena. In this article, examples are given on the field-induced charge density wave(CDW) in high-Tc superconductors and on the studies of quantum spin liquids. We provide a brief introduction to the high magnetic field NMR platform, the station 4 of the Synergetic Extreme Condition User Facility(SECUF), being built at Huairou, Beijing. 展开更多
关键词 超导体 车站 磁性 原子 声测量 磁铁 混合 高磁场
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Heteronuclear intermolecular single-quantum coherences in liquid nuclear magnetic resonance 被引量:1
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作者 陈松 朱小钦 +1 位作者 蔡淑惠 陈忠 《Chinese Physics B》 SCIE EI CAS CSCD 2008年第3期915-920,共6页
This paper analyses the heteronuclear Cosy Revamped by Asymmetric Z-gradient Echo Detection pulse sequence.General theoretical expressions of the pulse sequence with arbitrary flip angles were derived by using dipolar... This paper analyses the heteronuclear Cosy Revamped by Asymmetric Z-gradient Echo Detection pulse sequence.General theoretical expressions of the pulse sequence with arbitrary flip angles were derived by using dipolar field treatment and signals originating from heteronuclear intermolecular single-quantum coherences (iSQCs) in highly-polarized two spin-1/2 systems were mainly discussed in order to find the optimal flip angles.The results show that signals from heteronuclear iSQCs decay slower than those from intermolecular double-quantum coherences or intermolecular zero-quantum coherences.Magical angle experiments validate that the signals are from heteronuclear iSQCs and insensitive to the imperfection of radio-frequency flip angles.All experimental observations are in excellent agreement with theoretical predictions.The quantum-mechanical treatment leads to similar predictions to the dipolar field treatment. 展开更多
关键词 核磁共振 量子相干性 远端偶极领域 高偏振系统
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Observation of intermolecular double-quantum coherence signal dips in nuclear magnetic resonance
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作者 沈桂平 蔡聪波 +1 位作者 蔡淑惠 陈忠 《Chinese Physics B》 SCIE EI CAS CSCD 2011年第10期190-197,共8页
The correlated spectroscopy revamped by asymmetric Z-gradient echo detection (CRAZED) sequence is modified to investigate intermolecular double-quantum coherence nuclear magnetic resonance signal dips in highly polari... The correlated spectroscopy revamped by asymmetric Z-gradient echo detection (CRAZED) sequence is modified to investigate intermolecular double-quantum coherence nuclear magnetic resonance signal dips in highly polarized spin systems. It is found that the occurrence of intermolecular double-quantum coherence signal dips is related to sample geometry, field inhomogeneity and dipolar correlation distance. If the field inhomogeneity is refocused, the signal dip occurs at a fixed position whenever the dipolar correlation distance approaches the sample dimension. However, the position is shifted when the field inhomogeneity exists. Experiments and simulations are performed to validate our theoretic analysis. These signal features may offer a unique way to investigate porous structures and may find applications in biomedicine and material science. 展开更多
关键词 核磁共振信号 量子相干性 分子间 不均匀性 相关距离 自旋系统 回波检测 几何形状
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Advances in high-resolution nuclear magnetic resonance methods in inhomogeneous magnetic fields using intermolecular multiple quantum coherences 被引量:3
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作者 CHEN Zhong LIN MeiJin +1 位作者 CHEN Xi CAI ShuHui 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2009年第1期58-69,共12页
Strong and extremely homogeneous static magnetic field is usually required for high-resolution nu-clear magnetic resonance (NMR). However, in the cases of in vivo and so on, the magnetic field inho-mogeneity owing to ... Strong and extremely homogeneous static magnetic field is usually required for high-resolution nu-clear magnetic resonance (NMR). However, in the cases of in vivo and so on, the magnetic field inho-mogeneity owing to magnetic susceptibility variation in samples is unavoidable and hard to eliminate by conventional methods such as shimming. Recently, intermolecular multiple quantum coherences (iMQCs) have been employed to eliminate inhomogeneous broadening and obtain high-resolution NMR spectra, especially for in vivo samples. Compared to other high-resolution NMR methods, iMQC method exhibits its unique feature and advantage. It simultaneously holds information of chemical shifts, multiplet structures, coupling constants, and relative peak areas. All the information is often used to analyze and characterize molecular structures in conventional one-dimensional NMR spec-troscopy. In this work, recent technical developments including our results in this field are summarized; the high-resolution mechanism is analyzed and comparison with other methods based on interactions between spins is made; comments on the current situation and outlook on the research directions are also made. 展开更多
关键词 nuclear magnetic resonance HIGH-RESOLUTION INHOMOGENEOUS magnetic fieldS INTERMOLECULAR multiple quantum COHERENCE
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Design of Braunbeck Coil for Nuclear Magnetic Resonance Gyro Magnetic Field Excitation 被引量:1
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作者 王昢 刘华 +3 位作者 程翔 赵万良 李绍良 成宇翔 《Journal of Shanghai Jiaotong university(Science)》 EI 2018年第6期740-745,共6页
For generating a uniform and steady magnetic field, Helmholtz coil is extensively used in nuclear magnetic resonance gyro(NMRG). Unfortunately, the volume of Helmholtz coil makes it inconvenient to miniaturize NMRG. T... For generating a uniform and steady magnetic field, Helmholtz coil is extensively used in nuclear magnetic resonance gyro(NMRG). Unfortunately, the volume of Helmholtz coil makes it inconvenient to miniaturize NMRG. This study introduces Braunbeck coil that can be used in magnetic field excitation system. Braunbeck coil can produce homogeneous magnetic field within a limit space, and occupy a small volume. In addition, this study presents mathematical expressions that can be used to calculate the area of uniform magnetic field. Experimental test verifies the effectiveness of the proposed design, and the results accord closely with the actual simulation. 展开更多
关键词 Braunbeck COIL finite element simulation HELMHOLTZ COIL magnetic field EXCITATION magnetic UNIFORM area nuclear magnetic resonance GYRO (NMRG)
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A Novel Model of Predicting Archie's Cementation Factor from Nuclear Magnetic Resonance(NMR) Logs in Low Permeability Reservoirs 被引量:4
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作者 Liang Wang Zhiqiang Mao +3 位作者 Yujiang Shi Qin'e Tao Yumei Cheng Yong Song 《Journal of Earth Science》 SCIE CAS CSCD 2014年第1期183-188,共6页
The resistivity experimental measurements of core samples drilled from low permeability reservoirs of Ordos Basin,Northwest China,illustrate that the cementation factors are not agminate,but vary from 1.335 to 1.749.T... The resistivity experimental measurements of core samples drilled from low permeability reservoirs of Ordos Basin,Northwest China,illustrate that the cementation factors are not agminate,but vary from 1.335 to 1.749.This leads to a challenge for the estimation of water and hydrocarbon saturation.Based on the analysis of Purcell equation and assumption that rock resistivity is determined by the parallel connection of numerous capillary resistances,a theoretical expression of cementation factor in terms of porosity and permeability is established.Then,cementation factor can be calculated if the parameters of porosity and permeability are determined.In the field application,porosity can be easily obtained by conventional logs.However,it is a tough challenge to estimate permeability due to the strong heterogeneity of low permeability reservoirs.Thus,the Schlumberger Doll Research(SDR)model derived from NMR logs has been proposed to estimate permeability.Based on the analysis of the theoretical expressions of cementation factor and SDR model,a novel cementation factor prediction model,which is relevant to porosity and logarithmic mean of NMR T2spectrum(T2lm),is derived.The advantage of this model is that all the input information can be acquired from NMR logs accurately.In order to confirm the credibility of the novel model,the resistivity and corresponding laboratory NMR measurements of 27 core samples are conducted.The credibility of the model is confirmed by comparing the predicted cementation factors with the core analyzed results.The absolute errors for all core samples are lower than 0.071.Once this model is extended to field application,the accuracy of water and hydrocarbon saturation estimation will be significantly improved. 展开更多
关键词 核磁共振T2谱 NMR测井 低渗透储层 预测模型 胶结指数 油藏预测 岩石电阻率 日志
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基于低场核磁共振技术进行黄酒发酵进程监测及品牌的分析
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作者 王欣 郑思宇 +2 位作者 冯龙斐 刘敏 刘宝林 《食品与发酵工业》 CAS CSCD 北大核心 2024年第4期279-285,共7页
该文对不同发酵阶段的黄酒样品进行低场核磁共振(low-field nuclear magnetic resonance,LF-NMR)检测,比较了陈酿时间、酒精度和品牌对黄酒低场核磁弛豫特性的影响,最后对9个品牌黄酒的LF-NMR弛豫信息进行了主成分分析。结果表明,发酵... 该文对不同发酵阶段的黄酒样品进行低场核磁共振(low-field nuclear magnetic resonance,LF-NMR)检测,比较了陈酿时间、酒精度和品牌对黄酒低场核磁弛豫特性的影响,最后对9个品牌黄酒的LF-NMR弛豫信息进行了主成分分析。结果表明,发酵后样品的单组分弛豫时间(T_(2W))显著缩短,而陈酿后黄酒的T_(2W)又相对延长。多组分弛豫图谱(T_(2))表明,对照组和浸米样品均只有1个峰。发酵后样品的T_(2)图谱均出现2个峰。从第一次发酵到煎酒期间,T_(21)和T_(22)不断缩短,而陈酿期间T_(21)和T_(22)相对延长。同一品牌及陈酿时间的黄酒,酒精度越大,体系的T_(2W),T_(21)和T_(22)越短;同一品牌及酒精度下,陈酿时间仅对T_(21)有一定影响。不同品牌黄酒因酿造工艺的区别而使弛豫分布有一定特点。主成分分析表明,不同酒精度、陈酿时间、品牌及种类的黄酒的弛豫特性的PCA分布及间距不同。说明应用LF-NMR技术可实现对不同工艺生产的黄酒的快速辨别。 展开更多
关键词 黄酒 低场核磁共振 发酵 品牌
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基于不同维度低场核磁共振技术的大豆含油率检测与判别
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作者 张宇 赵亚楠 +1 位作者 赵健翔 宋平 《农业工程学报》 EI CAS CSCD 北大核心 2024年第4期337-344,共8页
大豆含油率的高低直接影响榨油与育种结果。为探究大豆含油率的最佳检测方法与构建含油率高低判别模型,该研究基于不同维度低场核磁共振(low field nuclear magnetic resonance,LF-NMR)技术,以国标法为对照,利用LF-NMR波谱和LF-NMR含油... 大豆含油率的高低直接影响榨油与育种结果。为探究大豆含油率的最佳检测方法与构建含油率高低判别模型,该研究基于不同维度低场核磁共振(low field nuclear magnetic resonance,LF-NMR)技术,以国标法为对照,利用LF-NMR波谱和LF-NMR含油含水率软件检测大豆含油率;核磁共振成像(magnetic resonance imaging,MRI)结合深度学习,建立大豆含油率高低判别模型。引入低场二维核磁共振(low field two-dimensional nuclear magnetic resonance,LF-2D-NMR)技术,定性分析一维波谱中信号重叠无法区分组分的问题。试验结果表明,LF-NMR含油含水率软件能快速准确检测大豆含油率,T1-T2二维核磁图谱成功解决了自由水和油信号重叠问题。利用U-net++深度学习模型对MRI成像的矢状面、冠状面、横截面以及三面混合数据集进行训练,其中横截面评价指标与其他数据集相比更优,语义分割部分中平均交并比(mean intersection over union,mIoU)约0.9058,全局准确率0.9980,训练后的模型能够将MRI图像识别并分割,快速判别大豆含油率高低。试验证明,LF-NMR及MRI能够快速无损掌握大豆含油率信息,为大豆的高油育种提供了新思路和技术支持。 展开更多
关键词 低场核磁共振 低场二维核磁共振 磁共振成像 大豆含油率 深度学习
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基于低场核磁共振的预包装即食牛肉保质期预测模型研究
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作者 董海胜 刘恒言 +5 位作者 徐楠 何凯锋 于燕波 兰海云 杜秉健 臧鹏 《食品工业科技》 CAS 北大核心 2024年第8期301-308,共8页
目的:开展预包装即食牛肉保质期快速、准确和无损的预测方法研究,对于保障产品货架期安全具有重要意义。方法:以预包装即食牛肉为分析对象,采集样品低场核磁H质子的T2弛豫时间,建立即食牛肉水分含量定量分析模型,结合样品感官接受性等... 目的:开展预包装即食牛肉保质期快速、准确和无损的预测方法研究,对于保障产品货架期安全具有重要意义。方法:以预包装即食牛肉为分析对象,采集样品低场核磁H质子的T2弛豫时间,建立即食牛肉水分含量定量分析模型,结合样品感官接受性等建立预包装即食牛肉保质期预测模型。结果:预包装即食牛肉低场核磁谱图横向弛豫时间可较好地反映出随着贮存时间的延长航天即食牛肉的品质变化。建立了即食牛肉含水量预测模型,模型的预测误差小于4%;建模集相关系数(r)为0.9405,校正标准差(RMSECV)为34.5,相对分析误差(RPD)为3.1,对10个分别贮存一定时间但未参与建模的样本分别进行距离货架期终点的预测,预测结果与实测值的的相关性达0.99,预测结果的误差范围为0.7%~9.9%,RMSEP为13.6,预测模型的精确度满足货架期预测的精度要求。结论:低场核磁共振技术在预包装即食牛肉产品保质期预测方面具有应用潜力。 展开更多
关键词 低场核磁共振 保质期 预包装即食牛肉 无损预测
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吉林特低渗油藏长岩心CO_(2)驱替微观动用规律研究
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作者 张辉 李忠诚 +4 位作者 祝孝华 李金龙 李海波 姚兰兰 肖前华 《中国科技论文》 CAS 2024年第1期50-56,共7页
针对松辽盆地莫里青油田特低渗储层动用困难的问题,利用物理模拟实验和核磁共振技术相结合的实验方法,开展长岩心CO_(2)驱替研究。结果表明:岩样CO_(2)驱替驱油效率介于72.30%~80.40%。大孔喉(>33 ms)平均赋存占比为33.65%,小孔喉(&l... 针对松辽盆地莫里青油田特低渗储层动用困难的问题,利用物理模拟实验和核磁共振技术相结合的实验方法,开展长岩心CO_(2)驱替研究。结果表明:岩样CO_(2)驱替驱油效率介于72.30%~80.40%。大孔喉(>33 ms)平均赋存占比为33.65%,小孔喉(<33 ms)平均赋存占比为18.01%;1 PV的CO_(2)驱替后,岩样大孔喉平均相对采出程度为80.67%,小孔喉平均相对采出程度为17.45%;5 PV的CO_(2)驱替后,岩样大孔喉平均相对采出程度为95.68%,小孔喉平均相对采出程度为39.82%,大PV驱替可有效动用小孔喉的油。研究成果可为莫里青油田储层CO_(2)驱替提供理论支撑,同时也为同类油藏开展注气先导试验提供科学指导。 展开更多
关键词 特低渗油藏 核磁共振 CO_(2)驱替 采出程度
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复合助剂对低温喷雾干燥蓝靛果粉理化性质的影响
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作者 郑先哲 鲁天麟 +5 位作者 陈启明 张雨涵 沈柳杨 付科森 朱海辉 柏才宇 《农业工程学报》 EI CAS CSCD 北大核心 2024年第2期93-106,共14页
为保证低温喷雾干燥后蓝靛果粉品质,采用黄金分割法研究复合助剂(麦芽糊精、β-环糊精和乳清蛋白)对喷雾干燥蓝靛果粉理化性质的影响,分析低温进风温度(50~90℃)对蓝靛果粉花青素保留率、集粉率和含水率的影响规律。结果表明,在麦芽糊... 为保证低温喷雾干燥后蓝靛果粉品质,采用黄金分割法研究复合助剂(麦芽糊精、β-环糊精和乳清蛋白)对喷雾干燥蓝靛果粉理化性质的影响,分析低温进风温度(50~90℃)对蓝靛果粉花青素保留率、集粉率和含水率的影响规律。结果表明,在麦芽糊精、β-环糊精的质量比例为85.4%、14.6%时,集粉率高达37.96%;随进料溶液中麦芽糊精质量比例增加,蓝靛果粉玻璃化转变温度、水溶性指数、堆积密度、亮度L^(*)值、红度a^(*)值和色差值ΔE呈增加趋势,含水率、花青素含量和黄度b^(*)值呈下降趋势;在麦芽糊精、β-环糊精和乳清蛋白质量比例为72.9%、12.5%、14.6%时,集粉率达到最高(40.11%);随料液中乳清蛋白质量比例增加,蓝靛果粉含水率、花青素含量呈上升趋势,其玻璃化转变温度、水溶性指数、亮度L^(*)值、红度a^(*)值、黄度b^(*)值和色差值ΔE等指标呈下降趋势;复合助剂显著提高蓝靛果粉集粉率(P<0.05),对其中的花青素起到较强保护作用,其含水率、水溶性指数、堆积密度等理化指标均接近于最优水平。低温喷雾干燥研究发现,随进风温度上升,集粉率和含水率呈负相关,在进风温度90℃时,集粉率最高的配方中可实现较高花青素保留率(89.94%)。低频核磁共振波谱以及质子密度图像信息分析表明,加入的助剂与蓝靛果果汁中水分通过氢键、静电结合力和疏水作用等分子间作用力,形成稳定性高水合物、增强液滴聚结抵抗力,提高料液玻璃态转换温度,从而实现高集粉率和高花青素保留率的蓝靛果果粉低温喷雾干燥;红外光谱分析表明,复合助剂可在蓝靛果果粉中形成分子间氢键,并对花青素等活性物质进行固定包埋保护。研究结果可为蓝靛果粉喷雾干燥加工生产提供理论支撑和参考依据。 展开更多
关键词 干燥 理化特性 低温喷雾干燥 复合助剂 蓝靛果 黄金分割法 花青素 核磁共振
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高增塑PEG弹性体网络结构与力学性能关系
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作者 王耀霄 王小英 +2 位作者 陈晨 谭茱匀 周星 《含能材料》 EI CAS CSCD 北大核心 2024年第2期204-210,共7页
为了建立硝酸酯增塑聚醚(NEPE)推进剂中高增塑的聚乙二醇(PEG)基聚氨酯的微观结构与宏观力学性能的相关性,以缩二脲三异氰酸酯(N⁃100)为多官能度固化剂,与硝酸酯增塑的PEG混胶固化,制备了固化参数1.2~1.7的高增塑PEG弹性体。采用单轴拉... 为了建立硝酸酯增塑聚醚(NEPE)推进剂中高增塑的聚乙二醇(PEG)基聚氨酯的微观结构与宏观力学性能的相关性,以缩二脲三异氰酸酯(N⁃100)为多官能度固化剂,与硝酸酯增塑的PEG混胶固化,制备了固化参数1.2~1.7的高增塑PEG弹性体。采用单轴拉伸、X射线衍射、低场核磁共振、平衡溶胀测试方法,对PEG弹性体交联网络微观结构特征进行研究,并基于低场核磁结果,分析了不同网链结构对高增塑PEG弹性体力学性能的影响。结果表明:由于高增塑的特性,PEG弹性体为非晶态,悬尾链与自由链总比例大于85%,交联网络结构完整度低,弹性体呈高伸长率、低抗拉强度和低初始模量的特点。弹性体抗拉强度和初始模量均与交联链网链密度呈正相关;随着物理暂时缠结网链密度的升高,最大伸长率先升高后降低。固化参数为1.6的CU⁃5弹性体交联网络最完整,抗拉强度为0.80 MPa,最大伸长率为1456%,力学性能最优。2种方法测得的网链密度满足低场核磁法交联链密度(νL,A)<溶胀法网链密度(νs)<低场核磁法交联链与悬尾链总网链密度(ν_(L,A+B))的大小关系。 展开更多
关键词 聚乙二醇聚氨酯弹性体 交联网络结构 力学性能 低场核磁
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响应面法优化冷冻鸡血豆腐的制备工艺
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作者 王哲 王灵娟 +6 位作者 杨静 马晶晶 杨彪 秦晓娟 王道营 邹烨 徐为民 《食品工业科技》 CAS 北大核心 2024年第8期247-253,共7页
为使肉鸡副产物之一鸡血高效利用。以新鲜鸡血为主要原料,采用低场核磁不易流动水峰面积为评价标准,通过添加不同品种与浓度的抗冻改良剂对冷冻鸡血豆腐中不易流动水峰面积影响的单因素实验,再结合响应面设计优化冷冻鸡血豆腐的制备工... 为使肉鸡副产物之一鸡血高效利用。以新鲜鸡血为主要原料,采用低场核磁不易流动水峰面积为评价标准,通过添加不同品种与浓度的抗冻改良剂对冷冻鸡血豆腐中不易流动水峰面积影响的单因素实验,再结合响应面设计优化冷冻鸡血豆腐的制备工艺。进一步以失水率、质构、色泽指标对优化的冷冻鸡血豆腐的品质进行分析,为开发冷冻鸡血豆腐产品提供科学依据。结果表明,冷冻鸡血豆腐优化制备工艺为:添加脂酰乳酸钠0.1%,海藻酸钾0.1%,木薯变性淀粉2%。在此工艺条件下,冷冻鸡血豆腐的低场核磁不易流动水峰面积为2143,与空白组和其他优化组相比不易流动水峰面积最大,故保水效果最好。优化制备的冷冻鸡血豆腐的硬度、咀嚼性、凝胶性以及亮度都显著(P<0.05)高于空白组(其中硬度是空白组的17倍,亮度的是空白组的1.13倍)。因此,冷冻鸡血豆腐的制备工艺可显著提高解冻后鸡血豆腐的品质,可促进肉鸡副产物高值化产品的开发。 展开更多
关键词 冷冻鸡血豆腐 抗冻剂 响应面设计 低场核磁 品质
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马蹄脆片微波真空干燥工艺优化及其水分变化
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作者 谭德馨 唐小闲 +4 位作者 张奕涛 李官丽 黎小椿 罗杨合 伍淑婕 《食品研究与开发》 CAS 2024年第3期107-115,共9页
以马蹄为原料,采用微波真空干燥技术干燥马蹄脆片,考察微波功率、干燥温度、真空度、切片厚度对马蹄脆片色差值、总糖含量、脆度的影响,以响应面试验优化干燥工艺,采用低场核磁共振技术研究马蹄脆片干燥过程水分变化情况。结果表明,微... 以马蹄为原料,采用微波真空干燥技术干燥马蹄脆片,考察微波功率、干燥温度、真空度、切片厚度对马蹄脆片色差值、总糖含量、脆度的影响,以响应面试验优化干燥工艺,采用低场核磁共振技术研究马蹄脆片干燥过程水分变化情况。结果表明,微波真空干燥马蹄脆片的最佳工艺为微波功率2.0 kW、干燥温度71℃、真空度-95 kPa、切片厚度3.1 mm,所得产品色差值、总糖含量、脆度分别为3.42、50.51 mg/100 g、464.96 g,产品色泽白亮,酥脆可口,马蹄风味浓厚。低场核磁共振检测结果表明:马蹄片内部主要存在3种状态水,分别是自由水、不易流动水及结合水,其中自由水占比较高、结合水和不易流动水的比例相对较低,在最佳工艺下到达干燥终点时自由水完全除去,只剩少量的不易流动水以及结合水。 展开更多
关键词 马蹄脆片 微波真空干燥 水分变化 工艺优化 低场核磁共振
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高灰煤气化细渣的油类捕收剂浮选与难浮机理
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作者 杨哲 黄根 +4 位作者 赵宇佳 王陆洋 孙小丽 廖寅飞 崔晓珂 《洁净煤技术》 CAS CSCD 北大核心 2024年第1期142-153,共12页
高效分离煤气化细渣中的残碳和矿物是其高值化利用的前提,但气化细渣较差的可浮性成为其浮选分离面临的难题之一。以多喷嘴对置(OMB)水煤浆气化炉的煤气化细渣为对象,研究了油类捕收剂十二烷的浮选效果和气化细渣的难浮机理。通过傅里... 高效分离煤气化细渣中的残碳和矿物是其高值化利用的前提,但气化细渣较差的可浮性成为其浮选分离面临的难题之一。以多喷嘴对置(OMB)水煤浆气化炉的煤气化细渣为对象,研究了油类捕收剂十二烷的浮选效果和气化细渣的难浮机理。通过傅里叶红外光谱测试,发现气化细渣中芳香结构和侧链的含量相比煤炭样品的含量较少,且气化细渣表面存在较多含氧基团;X射线光电子能谱结果表明气化细渣矿物中包含多种亲水的氧化矿物。通过低温氮气吸附和压汞试验测量了气化细渣的孔隙特性,结果表明其孔隙在纳米到微米尺寸内均有大量分布;计算得到原矿样品的BET比表面积为62.03 m^(2)/g。通过粉末润湿试验和改进的Lucas-Washburn方程表征了水和十二烷对气化细渣粉末的润湿过程,试验发现气化细渣残碳相比水更易被十二烷润湿,而气化细渣尾矿更易被水润湿,但残碳和尾矿对水的润湿性差异较小;通过低场-H^(1)核磁共振的T_(2)反演图谱证明了油类捕收剂在孔隙中的吸附行为;油类捕收剂用量的增加和油滴粒径的减小导致孔隙药剂吸附量增加。油类捕收剂在气化细渣的浮选过程中大量进入孔隙而难以有效在残碳表面吸附,导致油类捕收剂的浮选作用效果差。 展开更多
关键词 气化细渣 浮选 油类捕收剂 低场核磁 Lucas-Washburn方程
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一种核磁共振陀螺横向磁场线圈耦合标定方法
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作者 张昊 岳亚洲 +1 位作者 雷兴 马圣杰 《压电与声光》 CAS 北大核心 2024年第1期97-102,共6页
磁场线圈是核磁共振陀螺磁场系统的核心部件,是惰性气体磁共振激励维持、主动磁补偿的核心部件。横向磁场线圈的耦合对磁补偿精度与磁共振激励都有较大影响。因此,横向磁场线圈的耦合标定尤为重要。为解决上述问题,提出了一种基于核磁... 磁场线圈是核磁共振陀螺磁场系统的核心部件,是惰性气体磁共振激励维持、主动磁补偿的核心部件。横向磁场线圈的耦合对磁补偿精度与磁共振激励都有较大影响。因此,横向磁场线圈的耦合标定尤为重要。为解决上述问题,提出了一种基于核磁共振陀螺内置磁力仪的横向磁场线圈耦合标定方法,通过理论仿真和实验设计,验证了其正确性与可行性。实验结果表明,采用所提出的耦合标定方法对X轴对Y轴耦合和Y轴对X轴耦合进行标定,分别为1.86%和3.11%。通过旋转线圈改变装配角度,表明此方法在较小旋转角度时,测量结果不受装配误差的影响。通过标定同一批次的5只线圈,根据结果从中选取耦合较小的线圈进行装配,为核磁共振陀螺线圈的筛选奠定了基础。 展开更多
关键词 核磁共振陀螺仪 碱金属磁力仪 磁场线圈 磁场线圈耦合 横向磁场线圈耦合标定
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基于熵权法、灰色关联度法和低场核磁共振检测的苹果品质评价
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作者 沈海军 徐子昂 +2 位作者 王文琪 宇庭 曹仲文 《食品工业科技》 CAS 北大核心 2024年第1期231-238,共8页
研究不同品种苹果的品质特性,建立苹果品质综合评价模型。以5个品种的苹果(天水花牛、阿克苏糖心、黄元帅、奶油富士、洛川红富士)作为研究对象,对其硬度、黏着性、咀嚼性、内聚性等4项质构特性和含水量、可滴定酸(Titratable acid,TA)... 研究不同品种苹果的品质特性,建立苹果品质综合评价模型。以5个品种的苹果(天水花牛、阿克苏糖心、黄元帅、奶油富士、洛川红富士)作为研究对象,对其硬度、黏着性、咀嚼性、内聚性等4项质构特性和含水量、可滴定酸(Titratable acid,TA)、可溶性糖含量(Soluble sugar,SS)、可溶性固体含量(Soluble solid content,SSC)等4项理化指标进行检测,结合低场核磁共振检测技术,探究苹果水分分布与理化及质构特性间的关联性,通过主成分分析法确立可评价苹果品质的主要指标。基于熵权法对各核心指标赋予权重,并建立灰色关联度评价模型。结果表明,不同品种苹果的各指标存在显著性差异(P<0.05),其水分分布与质构特性和理化指标存在高度的相关性,确立了自旋-自旋弛豫时间T_(22)(不易流动水)、T_(21)(结合水)及TA、SS、SSC为核心指标。熵权法计算权重结果得出T_(22)、T_(21)之和为35.31%,占比最大,表明水分分布对苹果品质影响最大,由灰色关联度分析得出天水花牛和阿克苏糖心的品质较好。本研究所采用的方法,能够快速准确地建立苹果的品质评价模型,为包括苹果在内的果蔬品质评价提供新方法。 展开更多
关键词 苹果 熵权法 灰色关联度法 低场核磁共振 主成分分析 品质评价
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