Pyrolysis of benzene at 30 Torr was studied from 1360 K to 1820 K in this work. Synchrotron vacuum ultraviolet photoionization mass spectrometry was employed to detect the pyroly- sis products such as radicals, isomer...Pyrolysis of benzene at 30 Torr was studied from 1360 K to 1820 K in this work. Synchrotron vacuum ultraviolet photoionization mass spectrometry was employed to detect the pyroly- sis products such as radicals, isomers and polycyclic aromatic hydrocarbons, and measure their mole fraction profiles versus temperature. A low-pressure pyrolysis model of benzene was developed and validated by the experimental results. Rate of production analysis was performed to reveal the major reaction networks in both fuel decomposition and aromatic growth processes. It is concluded that benzene is mainly decomposed via H-abstraction reaction to produce phenyl and partly decomposed via unimolecular decomposition reac- tions to produce propargyl or phenyl. The decomposition process stops at the formation of acetylene and polyyne species like diacetylene and 1,3,5-hexatriyne due to their high thermal stabilities. Besides, the aromatic growth process in the low-pressure pyrolysis of benzene is concluded to initiate from benzene and phenyl, and is controlled by the even carbon growth mechanism due to the inhibited formation of C5 and C7 species which play important roles in the odd carbon growth mechanism.展开更多
AIM To evaluate the safety and feasibility of a new technology combining low-pressure pneumoperitoneum(LPP) and abdominal wall lift(AWL) in laparoscopic total mesorectal excision(TME) for rectal cancer.METHODS From No...AIM To evaluate the safety and feasibility of a new technology combining low-pressure pneumoperitoneum(LPP) and abdominal wall lift(AWL) in laparoscopic total mesorectal excision(TME) for rectal cancer.METHODS From November 2015 to July 2017,26 patients underwent laparoscopic TME for rectal cancer using LPP(6-8 mm Hg) with subcutaneous AWL in Qilu Hospital of Shandong University,Jinan,China.Clinical data regarding patients' demographics,intraoperative monitoring indices,operation-related indices andpathological outcomes were prospectively collected.RESULTS Laparoscopic TME was performed in 26 cases(14 anterior resection and 12 abdominoperineal resection) successfully,without conversion to open or laparoscopic surgery with standard-pressure pneumoperitoneum.Intraoperative monitoring showed stable heart rate,blood pressure and paw airway pressure.The mean operative time was 194.29 ± 41.27 min(range:125-270 min) and 200.41 ± 20.56 min(range:170-230 min) for anterior resection and abdominoperineal resection,respectively.The mean number of lymph nodes harvested was 16.71 ± 5.06(range:7-27).There was no positive circumferential or distal resection margin.No local recurrence was observed during a median follow-up period of 11.96 ± 5.55 mo(range:5-23 mo).CONCLUSION LPP combined with AWL is safe and feasible for laparoscopic TME.The technique can provide satisfactory exposure of the operative field and stable operative monitoring indices.展开更多
The influence of a key process variable on the mold filling characteristics of AZ91 Mg-alloy was studied in the low pressure EPC process.The applied flow quantity of insert gas from 1 to 5 m~3/h associated with the pr...The influence of a key process variable on the mold filling characteristics of AZ91 Mg-alloy was studied in the low pressure EPC process.The applied flow quantity of insert gas from 1 to 5 m~3/h associated with the pressurizing rate in the low pressure EPC casting process was considered for rectangle and L-shape plate casting. The experimental results show that there is an optimal flow quantity of insert gas for good mold filling characteristics in AZ91 Mg-alloy low-pressure EPC process. The optimal flow quantity of insert gas for the specimens is 3 to 4 m~3/h. Either less or higher than the optimal flow quantity of insert gas would lead to misrun defects or folds, blisters and porosity defects. The practice of hub casting confirmed that the low-pressure EPC process with an optimal processing variable exemplified as 4 m~3/h gas flow quantity was capable of producing complicated magnesium castings without misrun defects.展开更多
Alkali metal DC arc discharge has the characteristics of easy ionization,low power consumption,high plasma temperature and ionization degree,etc,which can be applied in aerospace vehicles in various ways.In this paper...Alkali metal DC arc discharge has the characteristics of easy ionization,low power consumption,high plasma temperature and ionization degree,etc,which can be applied in aerospace vehicles in various ways.In this paper,we calculate the physical property parameters of lithium vapor,one of the major alkali metals,and analyze the discharge characteristics of lithium plasma with the magnetohydrodynamic(MHD)model.The discharge effects between constant current and voltage sources are also compared.It is shown that the lithium plasma of DC arc discharge has relatively high temperature and current density.The peak temperature can reach tens of thousands of K,and the current density reaches 6 x 107 A m 2.Under the same rated power,the plasma parameters of the constant voltage source discharge are much higher than those of the constant current source discharge,which can be used as the preferred discharge mode for aerospace applications.展开更多
Pulsed-jet cleaning is recognized as the most efficient method to regenerate bag dust collectors traditionally used in industrial processes to control the emission of particulates.In this study,non-woven needle felt f...Pulsed-jet cleaning is recognized as the most efficient method to regenerate bag dust collectors traditionally used in industrial processes to control the emission of particulates.In this study,non-woven needle felt filter bags with and without a film coating material have been analyzed considering different geometries(different number N of pairs of pleated filter bag sides)in the frame of dedicated low-pressure pulsed-jet cleaning experiments.The flow structure inside the bag and the response characteristics of its wall have also been analyzed numerically through a computational fluid-dynamics/structural-dynamics(CFD-CSD)unidirectional fluid-solid coupling method.As shown by the experiments,the peak pressure(P_(0))on the wall of the filter bag with N=8 and 12 is higher,which indicates dust can be removed more effectively in these cases.The peak pressure on the wall increases first and then decreases along the direction of the bag length,while the peak pressure of the pleated filter bag with nonwoven needled felt film coating is greater than that without film coating.A comprehensive analysis of the time variation of acceleration,deformation,strain,stress and other factors,has led to the conclusion that the pleated filter bag with N=12 would be the optimal choice.展开更多
Low-pressure air plasma cleaning is an effective method for removing organic contaminants on large-aperture optical components in situ in the inertial confinement fusion facility.Chemical reactions play a significant ...Low-pressure air plasma cleaning is an effective method for removing organic contaminants on large-aperture optical components in situ in the inertial confinement fusion facility.Chemical reactions play a significant role in plasma cleaning,which is a complex process involving abundant bond cleavage and species generation.In this work,experiments and reactive molecular dynamics simulations were carried out to unravel the reaction mechanism between the benchmark organic contaminants of dibutyl phthalate and air plasma.The optical emission spectroscopy was used to study the overall evolution behaviors of excited molecular species and radical signals from air plasma as a reference to simulations.Detailed reaction pathways were revealed and characterized,and specific intermediate radicals and products were analyzed during experiments and simulation.The reactive species in the air plasma,such as O,HO_(2)and O_(3)radicals,played a crucial role in cleaving organic molecular structures.Together,our findings provide an atomic-level understanding of complex reaction processes of low-pressure air plasma cleaning mechanisms and are essential for its application in industrial plasma cleaning.展开更多
Effect of low-pressure carbonation （LPC） on heat inactivation of Saccharomyces cerevisiae was investigated. The cell suspension was carbonated at 1 MPa and 4℃ for 15 min and subsequently heated from 51 to 61 ℃ and...Effect of low-pressure carbonation （LPC） on heat inactivation of Saccharomyces cerevisiae was investigated. The cell suspension was carbonated at 1 MPa and 4℃ for 15 min and subsequently heated from 51 to 61 ℃ and 5 s to 5 min （heating with LPC）. As a control experiment, cell suspension was heat-treated under atmospheric pressure without LPC （heating）. The inactivation ratio of heating at 53℃ and 55℃ for l rain with LPC was approximately 1 log order higher than heating alone. Extending heating time to 5 min did not widen the difference in the inactivation ratio between heating with LPC and heating alone at both heating temperatures. At 57℃, the difference in inactivation ratio increased from 1 to 2.5 log order with extending treatment time from 5 to 15 s. The results suggested that the enhanced inactivation effect by LPC was obtained at the higher temperature with short time treatment than the lower temperature with longer time treatment. Under fluorescence microscope observation of LPC-treated cell stained with LysoSensor probe, it seemed that LPC was hardly able to acidify the cytoplasm ofS. cerevisiae. It is considered that the ability orS. cerevisiae ceils to keep their cytoplasmic pH during LPC resulted in the inferior increase in heat inactivation ratio by LPC as compared with bacteria in the previous studies.展开更多
Stable neutron generation with a yield of ~1.2×10^(4) neutrons per pulse was obtained during d(d,n)^(3)He reaction initiated by the high-voltage nanosecond discharge in a gap with a potential tungsten cylinder(an...Stable neutron generation with a yield of ~1.2×10^(4) neutrons per pulse was obtained during d(d,n)^(3)He reaction initiated by the high-voltage nanosecond discharge in a gap with a potential tungsten cylinder(anode)and a grounded deuterated zirconium plate(cathode)filled with deuterium at a pressure of ~10^(2) Pa.Estimated duration of the neutron pulse was ~1.5 ns.Less intensive neutron emission was registered without deuterated plate.Splashing of material of the tungsten electrode was observed during the high-voltage nanosecond discharge in the deuterium,hydrogen,helium and argon at pressures of 10^(2)-10^(4) Pa.展开更多
Metal clusters RCCo_3(CO)_9(R-H,C1,Br,CH_3,Ph) were prepared in 18.8-57.3% yields from the reaction of cobalt(Ⅱ)salt and RCX_a under mild PTC conditions(latm CO,25℃).The cobalt salt was reduced to Co(CO)_4 in the pr...Metal clusters RCCo_3(CO)_9(R-H,C1,Br,CH_3,Ph) were prepared in 18.8-57.3% yields from the reaction of cobalt(Ⅱ)salt and RCX_a under mild PTC conditions(latm CO,25℃).The cobalt salt was reduced to Co(CO)_4 in the presence of Na_3S_2O_4.展开更多
The propagation of the high-power microwave（HPM） with a frequency of 6 GHz in the lowpressure argon plasma was studied by the method of fluid approximation.The two-dimensional transmission model was built based on t...The propagation of the high-power microwave（HPM） with a frequency of 6 GHz in the lowpressure argon plasma was studied by the method of fluid approximation.The two-dimensional transmission model was built based on the wave equation,the electron drift-diffusion equations and the heavy species transport equations,which were solved by means of COMSOL Multiphysics software.The simulation results showed that the propagation characteristic of the HPM was closely related to the average electron density of the plasma.The attenuation of the transmitted wave increased nonlinearly with the electron density.Specifically,the growth of the attenuation slowed down as the electron density increased uniformly.In addition,the concrete transmission process of the HPM wave in the low-pressure argon plasma was given.展开更多
Pure Al and Al-30%Al_(2)O_(3)composite coatings are prepared on the surface of AZ31B magnesium alloy by low-pressure cold spraying.The morphology and structure of the coatings are analyzed by scanning electron microsc...Pure Al and Al-30%Al_(2)O_(3)composite coatings are prepared on the surface of AZ31B magnesium alloy by low-pressure cold spraying.The morphology and structure of the coatings are analyzed by scanning electron microscope (SEM),energy dispersive spectroscopy (EDS),and X-ray diffraction (XRD),and the effects of the addition of Al_(2)O_(3)on the microstructure of the Al-based coatings are discussed.The mechanical properties and corrosion resistance of the coatings are fully evaluated by the micro-hardness tester,electronic tensile machine,and electrochemical workstation.The results show that the coating structure is more uniform and denser,and the porosity is significantly reduced after the addition of Al_(2)O_(3).The interfaces between the coatings and the magnesium alloy substrate are distinct,and the coatings and the substrate are mechanically combined.Compared with the pure Al coating,the microhardness of the Al-Al_(2)O_(3)composite coating is increased to 61.1 HV_(0.2),and the bonding strength reaches above 53.1 MPa.The self-corrosion potential of the two coatings is higher than that of the magnesium alloy,and the self-corrosion current density is significantly lower than that of the magnesium alloy substrate.The Al-based coatings prepared by low-pressure cold spraying have high hardness,good bonding strength,and good corrosion resistance,which can be used for the repair and protection of magnesium alloy structural parts.展开更多
The design of high-lift Low-Pressure Turbines(LPTs)causes the separation of the boundary layer on the suction side of the blade and leads to a strong secondary flow.This present study aims to minimize secondary losses...The design of high-lift Low-Pressure Turbines(LPTs)causes the separation of the boundary layer on the suction side of the blade and leads to a strong secondary flow.This present study aims to minimize secondary losses through endwall slot suction and incoming wakes in a front-loaded high-lift LPT cascade with Zweifel of 1.58 under low Reynolds number of 25000.Two slotted schemes for the boundary layer of the endwall were designed(Plan A and Plan B),and the effects of suction mass flow on secondary flow were studied.The underlying physics of the endwall boundary layer of the suction and secondary flow under unsteady wakes was discussed.The results show that slot suction at the endwall boundary layer can significantly suppress the secondary flow by removing low-momentum fluids.Plans A and B significantly reduced the secondary kinetic energy by 44.2%and 36.9%,respectively,compared with the baseline cascade at the suction mass flow ratios of 1%.With an increase in the mass flow ratio of suction,the secondary flow was gradually reduced in both Plans A and B.It is more beneficial to control the secondary flow to destroy the intersection of the pressure side and suction side of the horseshoe vortex before it develops into a passage vortex.Under unsteady wakes,the combined effects of incoming wakes and endwall boundary layer suction can further suppress the secondary flow at the suction mass flow ratios of 2%for Plan A,because the positive and negative vorticity inside upstream wakes accelerated the mixing of the main flow and secondary flow and thus increased the energy of secondary vortices.展开更多
The double-layer NiCr-Cr_(3)C_(2)/Ni-Zn-Al_(2)O_(3) coatings with sufficient corrosion and wear resistance were prepared on low carbon steel substrates.The intermediate layers Ni-Zn-Al_(2)O_(3) were fabricated by usin...The double-layer NiCr-Cr_(3)C_(2)/Ni-Zn-Al_(2)O_(3) coatings with sufficient corrosion and wear resistance were prepared on low carbon steel substrates.The intermediate layers Ni-Zn-Al_(2)O_(3) were fabricated by using low-pressure cold spray (LPCS) method to improve the salt fog corrosion resistance properties of the supersonic plasma spray (SPS) NiCr-Cr_(3)C_(2) coatings.The friction and wear performance for the double-layer and single-layer NiCr-Cr_(3)C_(2) coatings were carried out by line-contact reciprocating sliding,respectively.Combined with the coating surface analysis techniques,the effect of the salt fog corrosion on the tribological properties of the double-layer coatings was studied.The results showed that the double-layer coatings exhibited better wear resistance than that of the single-layer coatings,due to the better corrosion resistance of the intermediate layer;the wear mass losses of the double-layer coatings was reduced by 70%than that of the single layer coatings and the wear mechanism of coatings after salt fog corrosion conditions is mainly corrosion wear.展开更多
On August 7,2023,Mangshi City,Dehong Prefecture experienced a local heavy rainstorm,and the geological disaster caused by the heavy rainfall caused casualties and property losses.Based on the real-time observation dat...On August 7,2023,Mangshi City,Dehong Prefecture experienced a local heavy rainstorm,and the geological disaster caused by the heavy rainfall caused casualties and property losses.Based on the real-time observation data of automatic stations,Doppler weather radar detection and meteorological risk warning products,the disaster situation,social impact,forecast and early warning service,causes of heavy precipitation and forecast and early warning inspection were summarized and analyzed.The results show that the heavy rainfall was prominent locally,lasted for a long time and accumulated a large amount of rainfall.There were biases in model products,and it was difficult for forecasters to make subjective corrections in complex terrain.The analysis ideas and focus points of heavy rainfall forecast,the improvement ideas and technical schemes of forecast deviation,and the improvement ideas and suggestions of services were summarized.It provides a reference for the forecast and early warning of severe weather in the future.展开更多
Non-metallic inclusions and zyglo indications frequently occur in the superalloy castings produced through the traditional vacuum gravity investment casting process,particularly in components with thin-walled and comp...Non-metallic inclusions and zyglo indications frequently occur in the superalloy castings produced through the traditional vacuum gravity investment casting process,particularly in components with thin-walled and complex structural features.The vacuum-assisted low-pressure casting(VLC),a type of counter-gravity casting(CGC)method,has been developed to minimize non-metallic inclusions and zyglo indications in superalloy castings.Rectifying frames for gas turbines made from K446 alloy were produced semi-continuously using the VLC process and subsequently evaluated through tensile testing,chemical composition analysis,X-ray diffraction,and zyglo penetrant inspection.The results indicate a roughly 10%improvement in tensile strength at 800℃ compared to gravity casting.Moreover,no significant changes are observed in the chemical composition of the alloys from the beginning to the end of a casting campaign,indicating that the developed VLC process is viable for the engineering-scale production of superalloy castings.Compared to traditional vacuum gravity casting(GC)method,the application of VLC can reduce the numbers of non-metallic inclusions and Zyglo indications in the castings by over 80%.At the same time,it significantly shortens the production time by 3 to 5 days.展开更多
During the low-pressure casting of extra-large size C95800 copper alloy components,traditional linear pressurization technique leads to a rapid surge of liquid metal inlet velocity at the regions where the mold cavity...During the low-pressure casting of extra-large size C95800 copper alloy components,traditional linear pressurization technique leads to a rapid surge of liquid metal inlet velocity at the regions where the mold cavity cross-section enlarges.This rapid increasement of liquid metal inlet velocity causes serious entrapment of gas and oxide films,and results in various casting defects such as the bifilm defects.These defects detrimentally deteriorate mechanical properties of the castings.To address this issue,an innovative nonlinear pressurization strategy timely matching to the casting structure was proposed.The pressurization rate decreases at sections where the cross-section widens,but it gradually increases as the liquid metal level rises.By this way,the inlet velocity remains below a critical threshold to prevent the entrapment of gas and oxide films.Comparative analyses involving numerical simulations and casting verification illustrate that the nonlinear pressurization technique,compared to the linear pressurization,effectively diminishes both the size and number of bifilm defects.Furthermore,the nonlinear pressurization method enhances the casting yield strength by 10%,tensile strength by 14%,and elongation by 10%.Examination through scanning electron microscopy highlights that the bifilm defects arising from the linear pressurization process result in the reduction of the castings’mechanical properties.These observations underscore the efficacy of nonlinear pressurization in enhancing the quality and reliability of gigantic castings,as exemplified by a 5.4-ton extra-large sized C95800 copper alloy propeller hub with complex structures in the current study.展开更多
Drying paddy with low-pressure superheated steam(LPSS)can effectively increase theγ-aminobutyric acid content in paddy.This study aimed to investigate the characteristics and mathematical models(MMs)of thin-layer dry...Drying paddy with low-pressure superheated steam(LPSS)can effectively increase theγ-aminobutyric acid content in paddy.This study aimed to investigate the characteristics and mathematical models(MMs)of thin-layer drying of paddy with LPSS.The experimentally obtained data werefitted by nonlinear regression with 5 MMs commonly used for thin-layer drying to calculate the goodness of fit of the MMs.Then,the thin-layer drying of paddy with LPSS was modeled with two machine learning methods as a Bayesian regularization back propagation(BRBP)neural network and a support vector machine(SVM).The results showed that paddy drying with LPSS is a reduced-rate drying process.The drying temperature and operating pressure have a significant impact on the drying process.Under the same pressure,increasing the drying temperature can accelerate the drying rate.Under the same temperature,increasing the operating pressure can accelerate the drying rate.The comparison of the model evaluation indexes showed that 5 common empirical MMs(Hederson and Pabis,Page,Midilli,Logarithmic,and Lewis)for thin-layer drying can achieve excellent fitting effects for a single experimental condition.However,the regression fitting of the indexes by calculating the coefficient(s)of each model showed that the empirical MMs produce poor fitting effects.The BRBP neural network-based model was slightly better than the SVM-based model,and both were significantly better than the empirical MM(the Henderson and Pabis model),as evidenced by a comparison of the training root mean square error(RMSE),testing RMSE,training mean absolute error(MAE),testing MAE,training R2,and testing R2 of the Henderson and Pabis model,the BRBP neural network model,and the SVM-based model.This results indicate that the MMs established by the two machine learning methods can better predict the moisture content changes in the paddy samples dried by LPSS.展开更多
The Scientific Experimental system in Near SpacE(SENSE)consists of different types of instruments that will be installed on a balloon-based platform to characterize near-space environmental parameters.As one of the ma...The Scientific Experimental system in Near SpacE(SENSE)consists of different types of instruments that will be installed on a balloon-based platform to characterize near-space environmental parameters.As one of the main scientific payloads,the middle and near ultraviolet spectrograph(MN-UVS)will provide full spectra coverage from middle ultraviolet(MUV,200−300 nm)to near ultraviolet(NUV,300−400 nm)with a spectral resolution of 2 nm.Its primary mission is to acquire data regarding the UV radiation background of the upper atmosphere.The MN-UVS is made up of six primary components:a fore-optical module,an imaging grating module,a UV intensified focal plane module,a titanium alloy frame,a spectrometer control module,and a data processing module.This paper presents in detail the engineering design of each functional unit of the MN-UVS,as well as the instrument’s radiometric calibration,wavelength calibration,impact test,and low-pressure discharge test.Furthermore,we are able to report ground test and flight test results of high quality,showing that the MN-UVS has a promising future in upcoming near-space applications.展开更多
The spatiotemporal evolutions of a one-dimensional collisionless decaying plasma bounded by two electrodes with an externally applied electrostatic field are studied by theoretical analyses and particle-in-cell(PIC)si...The spatiotemporal evolutions of a one-dimensional collisionless decaying plasma bounded by two electrodes with an externally applied electrostatic field are studied by theoretical analyses and particle-in-cell(PIC)simulations with the ion extraction process in a laser-induced plasma as the major research background.Based on the theoretical analyses,the transport process of the charged particles including electrons and ions can be divided into three stages:electron oscillation and ion matrix sheath extraction stage,sheath expansion and ion rarefaction wave propagation stage and the plasma collapse stage,and the corresponding criterion for each stage is also presented.Consequently,a complete analytical model is established for describing the ion extraction flux at each stage during the decaying of the laser-induced plasmas under an electrostatic field,which is also validated by the PIC modeling results.Based on this analytical model,influences of the key physical parameters,including the initial electron temperature and number density,plasma width and the externally applied electric voltage,on the ratio of the extracted ions are predicted.The calculated results show that a higher applied electric potential,smaller initial plasma number density and plasma width lead to a higher ratio of the extracted ions during the first stage;while in this stage,the initial electron temperature shows little effect on it.Meanwhile,more ions will be extracted before the plasma collapse once a higher electric potential is applied.The theoretical model presented in this paper is helpful not only for a deep understanding to the charged particle transport mechanisms for a bounded decaying plasma under an applied electrostatic field,but also for an optimization of the ion extraction process in practical applications.展开更多
The interlayer bonding properties are normally unsatisfying for 3D printed composites owing to the layer-by-layer formation process.In this study,low-pressure annealing was performed on 3D printed carbon fiber reinfor...The interlayer bonding properties are normally unsatisfying for 3D printed composites owing to the layer-by-layer formation process.In this study,low-pressure annealing was performed on 3D printed carbon fiber reinforced polyether ether ketone(CF/PEEK)to improve the interlayer bonding strength.The effects of annealing parameters on the mechanical properties and microstructure were studied.The results showed that the interlaminar shear strength(ILSS)of CF/PEEK improved by up to 55.4%after annealing.SEM and𝜇-CT were also applied to reveal the reinforcing mechanism.This improvement could mainly be attributed to the increased crystallinity of the CF/PEEK after annealing.Additionally,annealing reduced the porosity of the printed CF/PEEK and improved the fiber-resin interface.This resulted in a reduction in the stress concentration areas during loading,thereby enhancing the interlayer bonding strength of CF/PEEK.展开更多
基金This work is supported by the National Natu- ral Science Foundation of China （No.51106146 and No.51036007）, China Postdoctoral Science Foundation （No.20100480047 and No.201104326）, Chinese Univer- sities Scientific Fund （No.WK2310000010）, and Chinese Academy of Sciences.
文摘Pyrolysis of benzene at 30 Torr was studied from 1360 K to 1820 K in this work. Synchrotron vacuum ultraviolet photoionization mass spectrometry was employed to detect the pyroly- sis products such as radicals, isomers and polycyclic aromatic hydrocarbons, and measure their mole fraction profiles versus temperature. A low-pressure pyrolysis model of benzene was developed and validated by the experimental results. Rate of production analysis was performed to reveal the major reaction networks in both fuel decomposition and aromatic growth processes. It is concluded that benzene is mainly decomposed via H-abstraction reaction to produce phenyl and partly decomposed via unimolecular decomposition reac- tions to produce propargyl or phenyl. The decomposition process stops at the formation of acetylene and polyyne species like diacetylene and 1,3,5-hexatriyne due to their high thermal stabilities. Besides, the aromatic growth process in the low-pressure pyrolysis of benzene is concluded to initiate from benzene and phenyl, and is controlled by the even carbon growth mechanism due to the inhibited formation of C5 and C7 species which play important roles in the odd carbon growth mechanism.
基金Supported by the Special Found for Taishan Scholar Project of Shandong Province,China
文摘AIM To evaluate the safety and feasibility of a new technology combining low-pressure pneumoperitoneum(LPP) and abdominal wall lift(AWL) in laparoscopic total mesorectal excision(TME) for rectal cancer.METHODS From November 2015 to July 2017,26 patients underwent laparoscopic TME for rectal cancer using LPP(6-8 mm Hg) with subcutaneous AWL in Qilu Hospital of Shandong University,Jinan,China.Clinical data regarding patients' demographics,intraoperative monitoring indices,operation-related indices andpathological outcomes were prospectively collected.RESULTS Laparoscopic TME was performed in 26 cases(14 anterior resection and 12 abdominoperineal resection) successfully,without conversion to open or laparoscopic surgery with standard-pressure pneumoperitoneum.Intraoperative monitoring showed stable heart rate,blood pressure and paw airway pressure.The mean operative time was 194.29 ± 41.27 min(range:125-270 min) and 200.41 ± 20.56 min(range:170-230 min) for anterior resection and abdominoperineal resection,respectively.The mean number of lymph nodes harvested was 16.71 ± 5.06(range:7-27).There was no positive circumferential or distal resection margin.No local recurrence was observed during a median follow-up period of 11.96 ± 5.55 mo(range:5-23 mo).CONCLUSION LPP combined with AWL is safe and feasible for laparoscopic TME.The technique can provide satisfactory exposure of the operative field and stable operative monitoring indices.
文摘The influence of a key process variable on the mold filling characteristics of AZ91 Mg-alloy was studied in the low pressure EPC process.The applied flow quantity of insert gas from 1 to 5 m~3/h associated with the pressurizing rate in the low pressure EPC casting process was considered for rectangle and L-shape plate casting. The experimental results show that there is an optimal flow quantity of insert gas for good mold filling characteristics in AZ91 Mg-alloy low-pressure EPC process. The optimal flow quantity of insert gas for the specimens is 3 to 4 m~3/h. Either less or higher than the optimal flow quantity of insert gas would lead to misrun defects or folds, blisters and porosity defects. The practice of hub casting confirmed that the low-pressure EPC process with an optimal processing variable exemplified as 4 m~3/h gas flow quantity was capable of producing complicated magnesium castings without misrun defects.
文摘Alkali metal DC arc discharge has the characteristics of easy ionization,low power consumption,high plasma temperature and ionization degree,etc,which can be applied in aerospace vehicles in various ways.In this paper,we calculate the physical property parameters of lithium vapor,one of the major alkali metals,and analyze the discharge characteristics of lithium plasma with the magnetohydrodynamic(MHD)model.The discharge effects between constant current and voltage sources are also compared.It is shown that the lithium plasma of DC arc discharge has relatively high temperature and current density.The peak temperature can reach tens of thousands of K,and the current density reaches 6 x 107 A m 2.Under the same rated power,the plasma parameters of the constant voltage source discharge are much higher than those of the constant current source discharge,which can be used as the preferred discharge mode for aerospace applications.
基金This study was financially supported by Anhui Provincial Scientific and Technological Major Project(Grant No.18030801109).
文摘Pulsed-jet cleaning is recognized as the most efficient method to regenerate bag dust collectors traditionally used in industrial processes to control the emission of particulates.In this study,non-woven needle felt filter bags with and without a film coating material have been analyzed considering different geometries(different number N of pairs of pleated filter bag sides)in the frame of dedicated low-pressure pulsed-jet cleaning experiments.The flow structure inside the bag and the response characteristics of its wall have also been analyzed numerically through a computational fluid-dynamics/structural-dynamics(CFD-CSD)unidirectional fluid-solid coupling method.As shown by the experiments,the peak pressure(P_(0))on the wall of the filter bag with N=8 and 12 is higher,which indicates dust can be removed more effectively in these cases.The peak pressure on the wall increases first and then decreases along the direction of the bag length,while the peak pressure of the pleated filter bag with nonwoven needled felt film coating is greater than that without film coating.A comprehensive analysis of the time variation of acceleration,deformation,strain,stress and other factors,has led to the conclusion that the pleated filter bag with N=12 would be the optimal choice.
基金the Joint Funds of National Natural Science Foundation of China and China Academy of Engineering Physics(NSAF)(No.U2030109)National Natural Science Foundation of China(No.52075129)。
文摘Low-pressure air plasma cleaning is an effective method for removing organic contaminants on large-aperture optical components in situ in the inertial confinement fusion facility.Chemical reactions play a significant role in plasma cleaning,which is a complex process involving abundant bond cleavage and species generation.In this work,experiments and reactive molecular dynamics simulations were carried out to unravel the reaction mechanism between the benchmark organic contaminants of dibutyl phthalate and air plasma.The optical emission spectroscopy was used to study the overall evolution behaviors of excited molecular species and radical signals from air plasma as a reference to simulations.Detailed reaction pathways were revealed and characterized,and specific intermediate radicals and products were analyzed during experiments and simulation.The reactive species in the air plasma,such as O,HO_(2)and O_(3)radicals,played a crucial role in cleaving organic molecular structures.Together,our findings provide an atomic-level understanding of complex reaction processes of low-pressure air plasma cleaning mechanisms and are essential for its application in industrial plasma cleaning.
文摘Effect of low-pressure carbonation （LPC） on heat inactivation of Saccharomyces cerevisiae was investigated. The cell suspension was carbonated at 1 MPa and 4℃ for 15 min and subsequently heated from 51 to 61 ℃ and 5 s to 5 min （heating with LPC）. As a control experiment, cell suspension was heat-treated under atmospheric pressure without LPC （heating）. The inactivation ratio of heating at 53℃ and 55℃ for l rain with LPC was approximately 1 log order higher than heating alone. Extending heating time to 5 min did not widen the difference in the inactivation ratio between heating with LPC and heating alone at both heating temperatures. At 57℃, the difference in inactivation ratio increased from 1 to 2.5 log order with extending treatment time from 5 to 15 s. The results suggested that the enhanced inactivation effect by LPC was obtained at the higher temperature with short time treatment than the lower temperature with longer time treatment. Under fluorescence microscope observation of LPC-treated cell stained with LysoSensor probe, it seemed that LPC was hardly able to acidify the cytoplasm ofS. cerevisiae. It is considered that the ability orS. cerevisiae ceils to keep their cytoplasmic pH during LPC resulted in the inferior increase in heat inactivation ratio by LPC as compared with bacteria in the previous studies.
文摘Stable neutron generation with a yield of ~1.2×10^(4) neutrons per pulse was obtained during d(d,n)^(3)He reaction initiated by the high-voltage nanosecond discharge in a gap with a potential tungsten cylinder(anode)and a grounded deuterated zirconium plate(cathode)filled with deuterium at a pressure of ~10^(2) Pa.Estimated duration of the neutron pulse was ~1.5 ns.Less intensive neutron emission was registered without deuterated plate.Splashing of material of the tungsten electrode was observed during the high-voltage nanosecond discharge in the deuterium,hydrogen,helium and argon at pressures of 10^(2)-10^(4) Pa.
文摘Metal clusters RCCo_3(CO)_9(R-H,C1,Br,CH_3,Ph) were prepared in 18.8-57.3% yields from the reaction of cobalt(Ⅱ)salt and RCX_a under mild PTC conditions(latm CO,25℃).The cobalt salt was reduced to Co(CO)_4 in the presence of Na_3S_2O_4.
基金supported by National High Technology Research and Development Program of China(Grant No.2015AA8016029A)
文摘The propagation of the high-power microwave（HPM） with a frequency of 6 GHz in the lowpressure argon plasma was studied by the method of fluid approximation.The two-dimensional transmission model was built based on the wave equation,the electron drift-diffusion equations and the heavy species transport equations,which were solved by means of COMSOL Multiphysics software.The simulation results showed that the propagation characteristic of the HPM was closely related to the average electron density of the plasma.The attenuation of the transmitted wave increased nonlinearly with the electron density.Specifically,the growth of the attenuation slowed down as the electron density increased uniformly.In addition,the concrete transmission process of the HPM wave in the low-pressure argon plasma was given.
文摘Pure Al and Al-30%Al_(2)O_(3)composite coatings are prepared on the surface of AZ31B magnesium alloy by low-pressure cold spraying.The morphology and structure of the coatings are analyzed by scanning electron microscope (SEM),energy dispersive spectroscopy (EDS),and X-ray diffraction (XRD),and the effects of the addition of Al_(2)O_(3)on the microstructure of the Al-based coatings are discussed.The mechanical properties and corrosion resistance of the coatings are fully evaluated by the micro-hardness tester,electronic tensile machine,and electrochemical workstation.The results show that the coating structure is more uniform and denser,and the porosity is significantly reduced after the addition of Al_(2)O_(3).The interfaces between the coatings and the magnesium alloy substrate are distinct,and the coatings and the substrate are mechanically combined.Compared with the pure Al coating,the microhardness of the Al-Al_(2)O_(3)composite coating is increased to 61.1 HV_(0.2),and the bonding strength reaches above 53.1 MPa.The self-corrosion potential of the two coatings is higher than that of the magnesium alloy,and the self-corrosion current density is significantly lower than that of the magnesium alloy substrate.The Al-based coatings prepared by low-pressure cold spraying have high hardness,good bonding strength,and good corrosion resistance,which can be used for the repair and protection of magnesium alloy structural parts.
基金support for this work was provided by the National Natural Science Foundation of China(No.52206060)the National Science and Technology Major Project of China(Nos.J2019-Ⅱ-0021-0042 and J2019-Ⅱ-0002-0022).
文摘The design of high-lift Low-Pressure Turbines(LPTs)causes the separation of the boundary layer on the suction side of the blade and leads to a strong secondary flow.This present study aims to minimize secondary losses through endwall slot suction and incoming wakes in a front-loaded high-lift LPT cascade with Zweifel of 1.58 under low Reynolds number of 25000.Two slotted schemes for the boundary layer of the endwall were designed(Plan A and Plan B),and the effects of suction mass flow on secondary flow were studied.The underlying physics of the endwall boundary layer of the suction and secondary flow under unsteady wakes was discussed.The results show that slot suction at the endwall boundary layer can significantly suppress the secondary flow by removing low-momentum fluids.Plans A and B significantly reduced the secondary kinetic energy by 44.2%and 36.9%,respectively,compared with the baseline cascade at the suction mass flow ratios of 1%.With an increase in the mass flow ratio of suction,the secondary flow was gradually reduced in both Plans A and B.It is more beneficial to control the secondary flow to destroy the intersection of the pressure side and suction side of the horseshoe vortex before it develops into a passage vortex.Under unsteady wakes,the combined effects of incoming wakes and endwall boundary layer suction can further suppress the secondary flow at the suction mass flow ratios of 2%for Plan A,because the positive and negative vorticity inside upstream wakes accelerated the mixing of the main flow and secondary flow and thus increased the energy of secondary vortices.
基金Fundamental Research Funds for Central Universities Project (No. 1CX05021A)Shandong Provincial Key R&D Plan Project (No. 2GHY15108)Shandong Postdoctoral Innovation Project and Qingdao Postdoctoral Applied Research Project。
文摘The double-layer NiCr-Cr_(3)C_(2)/Ni-Zn-Al_(2)O_(3) coatings with sufficient corrosion and wear resistance were prepared on low carbon steel substrates.The intermediate layers Ni-Zn-Al_(2)O_(3) were fabricated by using low-pressure cold spray (LPCS) method to improve the salt fog corrosion resistance properties of the supersonic plasma spray (SPS) NiCr-Cr_(3)C_(2) coatings.The friction and wear performance for the double-layer and single-layer NiCr-Cr_(3)C_(2) coatings were carried out by line-contact reciprocating sliding,respectively.Combined with the coating surface analysis techniques,the effect of the salt fog corrosion on the tribological properties of the double-layer coatings was studied.The results showed that the double-layer coatings exhibited better wear resistance than that of the single-layer coatings,due to the better corrosion resistance of the intermediate layer;the wear mass losses of the double-layer coatings was reduced by 70%than that of the single layer coatings and the wear mechanism of coatings after salt fog corrosion conditions is mainly corrosion wear.
基金Supported by the Research on the Spatial and Temporal Characteristics and Occurrence Mechanism of Rainstorm in Dehong (STIAP202244)Key Laboratory of Heavy Rainfall in River Basins,China Meteorological Administration (2023BHR-Y09)+1 种基金Project of Key Laboratory of Hydrometeorology,China Meteorological Administration (23SWQXZ009)National Natural Science Foundation of China (42075013,41765003,41665005).
文摘On August 7,2023,Mangshi City,Dehong Prefecture experienced a local heavy rainstorm,and the geological disaster caused by the heavy rainfall caused casualties and property losses.Based on the real-time observation data of automatic stations,Doppler weather radar detection and meteorological risk warning products,the disaster situation,social impact,forecast and early warning service,causes of heavy precipitation and forecast and early warning inspection were summarized and analyzed.The results show that the heavy rainfall was prominent locally,lasted for a long time and accumulated a large amount of rainfall.There were biases in model products,and it was difficult for forecasters to make subjective corrections in complex terrain.The analysis ideas and focus points of heavy rainfall forecast,the improvement ideas and technical schemes of forecast deviation,and the improvement ideas and suggestions of services were summarized.It provides a reference for the forecast and early warning of severe weather in the future.
基金financially supported by the National Key Research and Development Plan Project of the Ministry of Science and Technology:Intelligent Liquid Precision Casting Technology and Application of Large Complex Thin-Wall High-End Metal Components(No.2022YFB3706800).
文摘Non-metallic inclusions and zyglo indications frequently occur in the superalloy castings produced through the traditional vacuum gravity investment casting process,particularly in components with thin-walled and complex structural features.The vacuum-assisted low-pressure casting(VLC),a type of counter-gravity casting(CGC)method,has been developed to minimize non-metallic inclusions and zyglo indications in superalloy castings.Rectifying frames for gas turbines made from K446 alloy were produced semi-continuously using the VLC process and subsequently evaluated through tensile testing,chemical composition analysis,X-ray diffraction,and zyglo penetrant inspection.The results indicate a roughly 10%improvement in tensile strength at 800℃ compared to gravity casting.Moreover,no significant changes are observed in the chemical composition of the alloys from the beginning to the end of a casting campaign,indicating that the developed VLC process is viable for the engineering-scale production of superalloy castings.Compared to traditional vacuum gravity casting(GC)method,the application of VLC can reduce the numbers of non-metallic inclusions and Zyglo indications in the castings by over 80%.At the same time,it significantly shortens the production time by 3 to 5 days.
基金supported by the National Natural Science Foundation of China(Granted Nos.51827801,52371152)the Foundation of National Key Laboratory of Precision Hot Processing of Metals(Granted No.DCQQ2790100724).
文摘During the low-pressure casting of extra-large size C95800 copper alloy components,traditional linear pressurization technique leads to a rapid surge of liquid metal inlet velocity at the regions where the mold cavity cross-section enlarges.This rapid increasement of liquid metal inlet velocity causes serious entrapment of gas and oxide films,and results in various casting defects such as the bifilm defects.These defects detrimentally deteriorate mechanical properties of the castings.To address this issue,an innovative nonlinear pressurization strategy timely matching to the casting structure was proposed.The pressurization rate decreases at sections where the cross-section widens,but it gradually increases as the liquid metal level rises.By this way,the inlet velocity remains below a critical threshold to prevent the entrapment of gas and oxide films.Comparative analyses involving numerical simulations and casting verification illustrate that the nonlinear pressurization technique,compared to the linear pressurization,effectively diminishes both the size and number of bifilm defects.Furthermore,the nonlinear pressurization method enhances the casting yield strength by 10%,tensile strength by 14%,and elongation by 10%.Examination through scanning electron microscopy highlights that the bifilm defects arising from the linear pressurization process result in the reduction of the castings’mechanical properties.These observations underscore the efficacy of nonlinear pressurization in enhancing the quality and reliability of gigantic castings,as exemplified by a 5.4-ton extra-large sized C95800 copper alloy propeller hub with complex structures in the current study.
文摘Drying paddy with low-pressure superheated steam(LPSS)can effectively increase theγ-aminobutyric acid content in paddy.This study aimed to investigate the characteristics and mathematical models(MMs)of thin-layer drying of paddy with LPSS.The experimentally obtained data werefitted by nonlinear regression with 5 MMs commonly used for thin-layer drying to calculate the goodness of fit of the MMs.Then,the thin-layer drying of paddy with LPSS was modeled with two machine learning methods as a Bayesian regularization back propagation(BRBP)neural network and a support vector machine(SVM).The results showed that paddy drying with LPSS is a reduced-rate drying process.The drying temperature and operating pressure have a significant impact on the drying process.Under the same pressure,increasing the drying temperature can accelerate the drying rate.Under the same temperature,increasing the operating pressure can accelerate the drying rate.The comparison of the model evaluation indexes showed that 5 common empirical MMs(Hederson and Pabis,Page,Midilli,Logarithmic,and Lewis)for thin-layer drying can achieve excellent fitting effects for a single experimental condition.However,the regression fitting of the indexes by calculating the coefficient(s)of each model showed that the empirical MMs produce poor fitting effects.The BRBP neural network-based model was slightly better than the SVM-based model,and both were significantly better than the empirical MM(the Henderson and Pabis model),as evidenced by a comparison of the training root mean square error(RMSE),testing RMSE,training mean absolute error(MAE),testing MAE,training R2,and testing R2 of the Henderson and Pabis model,the BRBP neural network model,and the SVM-based model.This results indicate that the MMs established by the two machine learning methods can better predict the moisture content changes in the paddy samples dried by LPSS.
基金This work was supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(grant XDA17010203,XDA17010201).
文摘The Scientific Experimental system in Near SpacE(SENSE)consists of different types of instruments that will be installed on a balloon-based platform to characterize near-space environmental parameters.As one of the main scientific payloads,the middle and near ultraviolet spectrograph(MN-UVS)will provide full spectra coverage from middle ultraviolet(MUV,200−300 nm)to near ultraviolet(NUV,300−400 nm)with a spectral resolution of 2 nm.Its primary mission is to acquire data regarding the UV radiation background of the upper atmosphere.The MN-UVS is made up of six primary components:a fore-optical module,an imaging grating module,a UV intensified focal plane module,a titanium alloy frame,a spectrometer control module,and a data processing module.This paper presents in detail the engineering design of each functional unit of the MN-UVS,as well as the instrument’s radiometric calibration,wavelength calibration,impact test,and low-pressure discharge test.Furthermore,we are able to report ground test and flight test results of high quality,showing that the MN-UVS has a promising future in upcoming near-space applications.
基金the National Natural Science Foundation of China(Grant No.11775128)。
文摘The spatiotemporal evolutions of a one-dimensional collisionless decaying plasma bounded by two electrodes with an externally applied electrostatic field are studied by theoretical analyses and particle-in-cell(PIC)simulations with the ion extraction process in a laser-induced plasma as the major research background.Based on the theoretical analyses,the transport process of the charged particles including electrons and ions can be divided into three stages:electron oscillation and ion matrix sheath extraction stage,sheath expansion and ion rarefaction wave propagation stage and the plasma collapse stage,and the corresponding criterion for each stage is also presented.Consequently,a complete analytical model is established for describing the ion extraction flux at each stage during the decaying of the laser-induced plasmas under an electrostatic field,which is also validated by the PIC modeling results.Based on this analytical model,influences of the key physical parameters,including the initial electron temperature and number density,plasma width and the externally applied electric voltage,on the ratio of the extracted ions are predicted.The calculated results show that a higher applied electric potential,smaller initial plasma number density and plasma width lead to a higher ratio of the extracted ions during the first stage;while in this stage,the initial electron temperature shows little effect on it.Meanwhile,more ions will be extracted before the plasma collapse once a higher electric potential is applied.The theoretical model presented in this paper is helpful not only for a deep understanding to the charged particle transport mechanisms for a bounded decaying plasma under an applied electrostatic field,but also for an optimization of the ion extraction process in practical applications.
基金This work was supported by Basic Strengthening Program of China(Grant No.2021-JCJQ-JJ-0186)National Natural Science Foundation of China(Grant No.52205383)+1 种基金Natural Science Foundation of Jiangsu(Grant Nos.BK20220895&BK20210314)Postdoctoral Science Foundation of China(Grant No.2021M691568).
文摘The interlayer bonding properties are normally unsatisfying for 3D printed composites owing to the layer-by-layer formation process.In this study,low-pressure annealing was performed on 3D printed carbon fiber reinforced polyether ether ketone(CF/PEEK)to improve the interlayer bonding strength.The effects of annealing parameters on the mechanical properties and microstructure were studied.The results showed that the interlaminar shear strength(ILSS)of CF/PEEK improved by up to 55.4%after annealing.SEM and𝜇-CT were also applied to reveal the reinforcing mechanism.This improvement could mainly be attributed to the increased crystallinity of the CF/PEEK after annealing.Additionally,annealing reduced the porosity of the printed CF/PEEK and improved the fiber-resin interface.This resulted in a reduction in the stress concentration areas during loading,thereby enhancing the interlayer bonding strength of CF/PEEK.
