Mineral contents and fractures of shale from well Yuye-1 and outcrops were examined mainly based on systematic description of the cores and outcrops, and data from experimental analyses. The data enabled us to thoroug...Mineral contents and fractures of shale from well Yuye-1 and outcrops were examined mainly based on systematic description of the cores and outcrops, and data from experimental analyses. The data enabled us to thoroughly explore the mineralogy and developmental features of shale of the Lower Silurian Longmaxi Formation in the study area. The results show that,the Lower Silurian Longmaxi Shale(SLS) in the southeastern margin of Sichuan Basin, China, is primarily characterized by a high content of brittle minerals and a relatively low content of clay minerals. The total content of brittle minerals is approximately 57%,including 27% quartz, 12.2% feldspar, 11.2% carbonate and 2.4% pyrite. The total content of clay minerals reaches 41.6%,composed of illite(23.8%), mixed-layer of illite and smectite(I/S)(10.8%) and chlorite(7.0%). The SLS accommodates the widespread development of various types of fractures, including tectonic fractures, diagenetic fractures, inter-layer fractures and slip fractures. The developmental level of the fracture in the SLS is mainly influenced by faults, lithology, mineral contents and total organic carbon content(TOC) in study area.展开更多
Based on anatomy of key areas and data points and analysis of typical features of shell layer in Guanyinqiao Member, basic characteristics of key interfaces, mainly bentonite layers, in the Upper Ordovician Wufeng For...Based on anatomy of key areas and data points and analysis of typical features of shell layer in Guanyinqiao Member, basic characteristics of key interfaces, mainly bentonite layers, in the Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation in the Sichuan Basin and its surrounding areas and the relationship between these key interfaces with the deposition of organic-rich shale have been examined systematically. The Wufeng Formation-Longmaxi Formation has four types of marker beds with interface attributes, namely, the characteristic graptolite belt, Guanyinqiao Member shell layer, section with dense bentonite layers, and concretion section, which can be taken as key interfaces for stratigraphic division and correlation of the graptolite shale. The shell layer in Guanyinqiao Member is the most standard key interface in Wufeng Formation-Longmaxi Formation, and can also be regarded as an important indicator for judging the depositional scale of organic-rich shale in key areas. There are 8 dense bentonite sections of two types mainly occurring in 7 graptolite belts in these formations. They have similar interface characteristics with the shell layer in Guanyinqiao Member in thickness and natural gamma response, and belong to tectonic interfaces(i.e., event deposits). They have three kinds of distribution scales: whole region, large part of the region, and local part, and can be the third, fourth and fifth order sequence interfaces, and have a differential control effect on organic-rich shale deposits. The horizon the characteristic graptolite belt occurs first is the isochronous interface, which is not directly related to the deposition of organic-rich shale. Concretions only appear in local areas, and show poor stability in vertical and horizontal directions, and have no obvious relationship with the deposition of the organic-rich shale.展开更多
Based on thin-section,argon-ion polished large-area imaging and nano-CT scanning data,the reservoir characteristics and genetic mechanisms of the Lower Silurian Longmaxi shale layers with different laminae and laminae...Based on thin-section,argon-ion polished large-area imaging and nano-CT scanning data,the reservoir characteristics and genetic mechanisms of the Lower Silurian Longmaxi shale layers with different laminae and laminae combinations in the Sichuan Basin were examined.It is found that the shale has two kinds of laminae,clayey lamina and silty lamina,which are different in single lamina thickness,composition,pore type and structure,plane porosity and pore size distribution.The clayey laminae are about 100μm thick each,over 15%in organic matter content,over 70%in quartz content,and higher in organic pore ratio and plane porosity.They have abundant bedding fractures and organic matter and organic pores connecting with each other to form a network.In contrast,the silty laminae are about 50μm thick each,5%to 15%in organic matter content,over 50%in carbonate content,higher in inorganic pore ratio,undeveloped in bedding fracture,and have organic matter and organic pores disconnected from each other.The formation of mud lamina and silt lamina may be related to the flourish of silicon-rich organisms.The mud lamina is formed during the intermittent period,and silt lamina is formed during the bloom period of silicon-rich organisms.The mud laminae and silt laminae can combine into three types of assemblages:strip-shaped silt,gradating sand-mud and sand-mud thin interlayers.The strip-shaped silt assemblage has the highest porosity and horizontal/vertical permeability ratio,followed by the gradating sand-mud assemblage and sand-mud thin interlayer assemblage.The difference in the content ratio of the mud laminae to silt laminae results in the difference in the horizontal/vertical permeability ratio.展开更多
The pores in shales are mainly of nanometer-scale,and their pore size distribution is very important for the preservation and exploitation of shale gas.This study focused on the organic-rich Lower Silurian black shale...The pores in shales are mainly of nanometer-scale,and their pore size distribution is very important for the preservation and exploitation of shale gas.This study focused on the organic-rich Lower Silurian black shale from four wells in the Upper Yangtze Platform,and their TOC,mineralogical composition and pore characterization were investigated.Low pressure N_2 and CO_2 adsorption were conducted at 77.35 K and 273.15 K,respectively,and the pore structures were characterized by modified Brunauer-Emmett-Teller(BET),Dubinin-Radushkevich(DR),t-plot,BarrettJoyner-Halenda(BJH) and density functional theory(DFT) methods and then the relationship between pore structure and shale gas sorption capacity was discussed.The results indicate that(1) The Lower Silurian shale has high TOC content of 0.92%-4.96%,high quartz content of 30.6%-69.5%,and high clays content of 24.1%-51.2%.The total specific surface area varies from 7.56 m^2/g to 25.86 m^2/g.Both the total specific surface area and quartz content are positively associated with the TOC content.(2)Shale samples with higher TOC content have more micropores,which results in more complex nanopore structure.Micropore volumes/surface areas and non-micropore surface areas all increase with the increasing TOC content.(3) A combination of N_2 and CO_2 adsorption provides the most suitable detection range(~0.3-60 nm) and has high reliability and accuracy for nanopore structure characterization.(4) The TOC content is the key factor to control the gas sorption capacity of the Lower Silurian shale in the Upper Yangtze Platform.展开更多
Sweet spots in the shale reservoirs of the Lower Silurian Longmaxi Formation in Weiyuan 201 Block of Sichuan Basin were predicted quantitatively using seismic data and fuzzy optimization method. First, based on seismi...Sweet spots in the shale reservoirs of the Lower Silurian Longmaxi Formation in Weiyuan 201 Block of Sichuan Basin were predicted quantitatively using seismic data and fuzzy optimization method. First, based on seismic and rock physics analysis, the rock physics characteristics of the reservoirs were determined, and elastic parameters sensitive to shale reservoirs with high gas content were selected. Second, data volumes with high precision of the elastic parameters were obtained from pre-stack simultaneous inversion. The horizontal distribution of key parameters for shale gas evaluation were calculated based on the results of rock physics analysis. Then, the fuzzy evaluation equation was established by fuzzy optimization method with test and logging data of horizontal wells with similar operation conditions. key parameters affecting the productivity of horizontal wells were sorted out and the weights of them in the sweet spots quantitative prediction were worked out by fuzzy optimization to set up a sweet spots evaluation system. Three classes of shale gas reservoirs which including two kinds of sweet spots were predicted with the above procedure, and the sweet spots have been predicted quantitatively by combining the above prediction results with the testing production. The testing results of 7 verification wells proved the reliability of the prediction results.展开更多
This paper presents a set of bulk geochemical and mineralogical data from a paleoweathering profile located in Zunyi District, Northern Guizhou, China. It was formed at the top of the Hanjiadian Formation of the Lower...This paper presents a set of bulk geochemical and mineralogical data from a paleoweathering profile located in Zunyi District, Northern Guizhou, China. It was formed at the top of the Hanjiadian Formation of the Lower Silurian. A truncated, argillic, gleyed, kryptic paleospodosol is recognized in the paleoweathering profile. Ratios of immobile elements(Ti/Zr, Ti/Al) and their binary(e.g., Nb vs. Zr/TiO_2 and Th/Sc vs. Zr/Sc), triangular diagrams(La-Th-Sc, Th-ScZr/10, Zr-Cr-Ga) reflect that the Gaojiayan paleosol is the product of in-situ weathering of gray-green silty mudstone of the underlying Hanjiadian Formation. Mass balance calculations indicate K enrichment and Na enrichment in the upper and lower portions of paleosol, respectively. These findings both are the results of transgression, which brings substantial concentrations of such elements as K, Na, and Sr. In particular, K enrichment is achieved by the illitization of kaolinite. The biological processes of terrestrial vascular plants also enhance K concentration, especially at the top of the paleosol. Na enrichment is a consequence of albitization and/or adsorption by clay minerals through cation exchange. The mass distributions and relative mass changes of rare earth elements(REEs) in the studied profile display characteristics of vertical zonation. Three peaks in total REEs content are observed, indicating two paleoclimatic or paleoenvironmental changes. Mineralogical characteristics indicate that the paleoclimate changed first from warm and humid to cold and dry and later, to dry and lightly warmer. The corresponding soil environment varies from weakly acidic to strongly alkaline and later, to weakly acidic. Mass translocation characteristics of REEs and several transition metals suggest that the Gaojiayan paleosol may have undergone top erosion.展开更多
The distribution of Lower Silurian conodonts from the sections on the Kozhym River was studied first by S.V. Melnikov.After additional studies of the Upper Ordovician-Lower Silurian strata,Oulodus? aff.nathani, Wallis...The distribution of Lower Silurian conodonts from the sections on the Kozhym River was studied first by S.V. Melnikov.After additional studies of the Upper Ordovician-Lower Silurian strata,Oulodus? aff.nathani, Walliserodus cf.curvatus,Panderodus sp.and Ozarkodina sp.were identified by P.M(a|¨)nnik in the Subpolar Urals.Studies of conodonts from the展开更多
Based on the Qiliao section of the Upper Ordovician Wufeng Formation – Lower Silurian Longmaxi Formation in Shizhu, Chongqing city, the development characteristics of bentonite in eastern Sichuan Basin was examined s...Based on the Qiliao section of the Upper Ordovician Wufeng Formation – Lower Silurian Longmaxi Formation in Shizhu, Chongqing city, the development characteristics of bentonite in eastern Sichuan Basin was examined systematically, and its geological significance and scientific value were analyzed. The main understandings are as follows:(1) Six bentonite dense layers were found in the Qiliao section, mainly occurring in 6 graptolitic belts of the Katian, Rhuddanian and Aeronian. Most of the bentonite dense layers showed obvious increase in clay, peak response of GR curve, and indistinct relationship between volcanic ash and total organic carbon(TOC).(2) The bentonite dense layers of Longmaxi Formation were widely distributed in eastern Sichuan Basin and its periphery, and generally showed GR peak, which can be an important reference interface for dividing the bottom boundary of the Coronograptus cyphus belt and the top boundary of the Rhuddanian in eastern Sichuan Basin and western Hubei province.(3) Taking the bentonite dense layers as the stratification basis of the Rhuddanian and Aeronian, it was determined that the sediment thickness of the Rhuddanian in the eastern Sichuan depression was generally 10–40 m, but only the upper part of the Coronograptus cyphus belt was deposited in the hinderland of Yichang Uplift, and the sedimentary thickness was only 3–7 m.(4) In the hinderland of the Yichang Uplift, at least five and a half graptolitic belts were missing in Wufeng Formation – Rhuddanian, and the deposition time of Rhuddanian was less than 0.4 Ma.(5) The bentonite dense layers were important sedimentary responses to the strong deflection of the Yangtze basin at the turn of the Ordovician–Silurian, which suggested that four tectonic activity periods existed in the eastern Sichuan depression, including the early stage of the depression, the middle-late stage of the depression, the early stage of the foreland flexure and the development stage of the foreland flexure. The high-quality shale was mainly developed from the early stage to the middle-late stage in the depression.展开更多
Marine shale gas resources have great potential in the south of the Sichuan Basin in China.At present,the high-quality shale gas resources at depth of 2000–3500 m are under effective development,and strategic breakth...Marine shale gas resources have great potential in the south of the Sichuan Basin in China.At present,the high-quality shale gas resources at depth of 2000–3500 m are under effective development,and strategic breakthroughs have been made in deeper shale gas resources at depth of 3500–4500 m.To promote the effective production of shale gas in this area,this study examines key factors controlling high shale gas production and presents the next exploration direction in the southern Sichuan Basin based on summarizing the geological understandings from the Lower Silurian Longmaxi Formation shale gas exploration combined with the latest results of geological evaluation.The results show that:(1)The relative sea depth in marine shelf sedimentary environment controls the development and distribution of reservoirs.In the relatively deep water area in deep-water shelf,grade-I reservoirs with a larger continuous thickness develop.The relative depth of sea in marine shelf sedimentary environment can be determined by redox conditions.The research shows that the uranium to thorium mass ratio greater than 1.25 indicates relatively deep water in anoxic reduction environment,and the uranium to thorium mass ratio of 0.75–1.25 indicates semi-deep water in weak reduction and weak oxidation environment,and the uranium to thorium mass ratio less than 0.75 indicates relatively shallow water in strong oxidation environment.(2)The propped fractures in shale reservoirs subject to fracturing treatment are generally 10–12 m high,if grade-I reservoirs are more than 10 m in continuous thickness,then all the propped section would be high-quality reserves;in this case,the longer the continuous thickness of penetrated grade-I reservoirs,the higher the production will be.(3)The shale gas reservoirs at 3500–4500 m depth in southern Sichuan are characterized by high formation pressure,high pressure coefficient,well preserved pores,good pore structure and high proportion of free gas,making them the most favorable new field for shale gas exploration;and the pressure coefficient greater than 1.2 is a necessary condition for shale gas wells to obtain high production.(4)High production wells in the deep shale gas reservoirs are those in areas where Long11-Long13 sub-beds are more than 10 m thick,with 1500 m long horizontal section,grade-I reservoirs penetration rate of over 90%,and fractured by dense cutting+high intensity sand injection+large displacement+large liquid volume.(5)The relatively deep-water area in the deep-water shelf and the area at depth of 3500–4500 m well overlap in the southern Sichuan,and the overlapping area is the most favorable shale gas exploration and development zones in the southern Sichuan in the future.With advancement in theory and technology,annual shale gas production in the southern Sichuan is expected to reach 450×108 m3.展开更多
Based on field outcrop data,the effects of cyclic change of astronomical orbit and volcanic activity on organic carbon accumulation during the Late Ordovician-Early Silurian in the Upper Yangtze area were studied usin...Based on field outcrop data,the effects of cyclic change of astronomical orbit and volcanic activity on organic carbon accumulation during the Late Ordovician-Early Silurian in the Upper Yangtze area were studied using cyclostratigraphic and geochemical methods.d13 C and chemical index of alteration(CIA)were used to filter the astronomical orbit parameters recorded in sediments.It is found that the climate change driven by orbital cycle controls the fluctuations of sea level at different scales,obliquity forcing climate changes drive thermohaline circulation(THC)of the ocean,and THC-induced bottom currents transport nutrient-laden water from high latitude regions to the surface water of low-latitude area.Hence,THC is the main dynamic mechanism of organic-carbon supply.The marine productivity indexes of Ba/Al and Ni/Al indicate that volcanic activities had limited effect on marine productivity but had great influences on organic carbon preservation efficiency in late Hirnantian(E4).Paleo-ocean redox environmental indicators Th/U,V/Cr and V/(V+Ni)show that there is a significant correlation between volcanism and oxygen content in Paleo-ocean,so it is inferred that volcanisms controlled the organic carbon preservation efficiency by regulating oxygen content in Paleo-ocean,and the difference in volcanism intensity in different areas is an important factor for the differential preservation efficiency of organic carbon.The organic carbon input driven by orbital cycle and the preservation efficiency affected by volcanisms worked together to control the enrichment of organic carbon in the Middle–Upper Yangtze region.展开更多
As the hydrocarbon generation and storage mechanisms of high quality shales of Upper Ordovician Wufeng Formation– Lower Silurian Longmaxi Formation remain unclear, based on geological conditions and experimental mode...As the hydrocarbon generation and storage mechanisms of high quality shales of Upper Ordovician Wufeng Formation– Lower Silurian Longmaxi Formation remain unclear, based on geological conditions and experimental modelling of shale gas formation, the shale gas generation and accumulation mechanisms as well as their coupling relationships of deep-water shelf shales in Wufeng–Longmaxi Formation of Sichuan Basin were analyzed from petrology, mineralogy, and geochemistry. The high quality shales of Wufeng–Longmaxi Formation in Sichuan Basin are characterized by high thermal evolution, high hydrocarbon generation intensity, good material base, and good roof and floor conditions;the high quality deep-water shelf shale not only has high biogenic silicon content and organic carbon content, but also high porosity coupling. It is concluded that:(1) The shales had good preservation conditions and high retainment of crude oil in the early times, and the shale gas was mainly from cracking of crude oil.(2) The biogenic silicon(opal A) turned into crystal quartz in early times of burial diagenesis, lots of micro-size intergranular pores were produced in the same time;moreover, the biogenic silicon frame had high resistance to compaction, thus it provided the conditions not only for oil charge in the early stage, but also for formation and preservation of nanometer cellular-like pores, and was the key factor enabling the preservation of organic pores.(3) The high quality shale of Wufeng–Longmaxi Formation had high brittleness, strong homogeneity, siliceous intergranular micro-pores and nanometer organic pores, which were conducive to the formation of complicated fissure network connecting the siliceous intergranular nano-pores, and thus high and stable production of shale gas.展开更多
Based on the drilling data of the Silurian Longmaxi Formation in the Sichuan Basin and periphery, SW China, the Ro lower limits and essential features of the carbonization of organic matter in over-high maturity marin...Based on the drilling data of the Silurian Longmaxi Formation in the Sichuan Basin and periphery, SW China, the Ro lower limits and essential features of the carbonization of organic matter in over-high maturity marine shale were examined using laser Raman, electrical and physical property characterization techniques. Three preliminary conclusions are drawn:(1) The lower limit of Ro for the carbonization of Type I-II1 organic matter in marine shale is 3.5%; when the Ro is less than 3.4%, carbonization of organic matter won't happen in general; when the Ro ranges from 3.4% to 3.5%, non-carbonization and weak carbonization of organic matter may coexist; when the Ro is higher than 3.5%, the carbonization of organic matter is highly likely to take place.(2) Organic-rich shale entering carbonization phase have three basic characteristics: log resistivity curve showing a general "slender neck" with low-ultralow resistance response, Raman spectra showing a higher graphite peak, and poor physical property(with matrix porosity of only less than 1/2 of the normal level).(3) The quality damage of shale reservoir caused by the carbonization of organic matter is almost fatal, which primarily manifests in depletion of hydrocarbon generation capacity, reduction or disappearance of organic pores and intercrystalline pores of clay minerals, and drop of adsorption capacity to natural gas. Therefore, the lower limit of Ro for the carbonization of Type I-II1 organic matter should be regarded as the theoretically impassable red line of shale gas exploration in the ancient marine shale formations. The organic-rich shale with low-ultralow resistance should be evaluated effectively in area selection to exclude the high risk areas caused by the carbonization of organic matter. The target organic-rich shale layers with low-ultralow resistance drilled during exploration and development should be evaluated on carbonization level of organic matter, and the deployment plan should be adjusted according to the evaluation results in time.展开更多
Acoustic wave velocity has been commonly utilized to predict subsurface geopressure using empirical relations.Acoustic wave velocity is, however, affected by many factors. To estimate pore pressure accurately, we here...Acoustic wave velocity has been commonly utilized to predict subsurface geopressure using empirical relations.Acoustic wave velocity is, however, affected by many factors. To estimate pore pressure accurately, we here propose to use elastic rock physics models to understand and analyze quantitatively the various contributions from these different factors affecting wave velocity. We report a closed-form relationship between the frame flexibility factor(γ) in a rock physics model and differential pressure, which presents the major control of pressure on elastic properties such as bulk modulus and compressional wave velocity. For a gas-bearing shale with abundant micro-cracks and fractures, its bulk modulus is much lower at abnormally high pore pressure(high γ values) where thin cracks and flat pores are open than that at normal hydrostatic pressure(low γ values) where pores are more rounded on average. The developed relations between bulk modulus and differential pressure have been successfully applied to the Upper Ordovician Wufeng and Lower Silurian Longmaxi formations in the Dingshan area of the Sichuan Basin to map the three-dimensional spatial distribution of pore pressure in the shale, integrating core, log and seismic data. The estimated results agree well with field measurements. Pressure coefficient is positively correlated to gas content. The relations and methods reported here could be useful for hydrocarbon exploration, production, and drilling safety in both unconventional and conventional fields.展开更多
基金Project(41302076)supported by the National Natural Science Foundation of ChinaProject(BJ14266)supported by Special Fund of Ministry of Science and Technology from the State Key Laboratory of Continental Dynamics(Northwest University),China
文摘Mineral contents and fractures of shale from well Yuye-1 and outcrops were examined mainly based on systematic description of the cores and outcrops, and data from experimental analyses. The data enabled us to thoroughly explore the mineralogy and developmental features of shale of the Lower Silurian Longmaxi Formation in the study area. The results show that,the Lower Silurian Longmaxi Shale(SLS) in the southeastern margin of Sichuan Basin, China, is primarily characterized by a high content of brittle minerals and a relatively low content of clay minerals. The total content of brittle minerals is approximately 57%,including 27% quartz, 12.2% feldspar, 11.2% carbonate and 2.4% pyrite. The total content of clay minerals reaches 41.6%,composed of illite(23.8%), mixed-layer of illite and smectite(I/S)(10.8%) and chlorite(7.0%). The SLS accommodates the widespread development of various types of fractures, including tectonic fractures, diagenetic fractures, inter-layer fractures and slip fractures. The developmental level of the fracture in the SLS is mainly influenced by faults, lithology, mineral contents and total organic carbon content(TOC) in study area.
基金Supported by the PetroChina Science and Technology Project(2021DJ1904)PetroChina Exploration and Production Company Marine Shale Gas Selection Project(kt2018-01-06)。
文摘Based on anatomy of key areas and data points and analysis of typical features of shell layer in Guanyinqiao Member, basic characteristics of key interfaces, mainly bentonite layers, in the Upper Ordovician Wufeng Formation-Lower Silurian Longmaxi Formation in the Sichuan Basin and its surrounding areas and the relationship between these key interfaces with the deposition of organic-rich shale have been examined systematically. The Wufeng Formation-Longmaxi Formation has four types of marker beds with interface attributes, namely, the characteristic graptolite belt, Guanyinqiao Member shell layer, section with dense bentonite layers, and concretion section, which can be taken as key interfaces for stratigraphic division and correlation of the graptolite shale. The shell layer in Guanyinqiao Member is the most standard key interface in Wufeng Formation-Longmaxi Formation, and can also be regarded as an important indicator for judging the depositional scale of organic-rich shale in key areas. There are 8 dense bentonite sections of two types mainly occurring in 7 graptolite belts in these formations. They have similar interface characteristics with the shell layer in Guanyinqiao Member in thickness and natural gamma response, and belong to tectonic interfaces(i.e., event deposits). They have three kinds of distribution scales: whole region, large part of the region, and local part, and can be the third, fourth and fifth order sequence interfaces, and have a differential control effect on organic-rich shale deposits. The horizon the characteristic graptolite belt occurs first is the isochronous interface, which is not directly related to the deposition of organic-rich shale. Concretions only appear in local areas, and show poor stability in vertical and horizontal directions, and have no obvious relationship with the deposition of the organic-rich shale.
基金Supported by China National Science and Technology Major Project(2017ZX05035-001)National Natural Science Fund Project(41572079)
文摘Based on thin-section,argon-ion polished large-area imaging and nano-CT scanning data,the reservoir characteristics and genetic mechanisms of the Lower Silurian Longmaxi shale layers with different laminae and laminae combinations in the Sichuan Basin were examined.It is found that the shale has two kinds of laminae,clayey lamina and silty lamina,which are different in single lamina thickness,composition,pore type and structure,plane porosity and pore size distribution.The clayey laminae are about 100μm thick each,over 15%in organic matter content,over 70%in quartz content,and higher in organic pore ratio and plane porosity.They have abundant bedding fractures and organic matter and organic pores connecting with each other to form a network.In contrast,the silty laminae are about 50μm thick each,5%to 15%in organic matter content,over 50%in carbonate content,higher in inorganic pore ratio,undeveloped in bedding fracture,and have organic matter and organic pores disconnected from each other.The formation of mud lamina and silt lamina may be related to the flourish of silicon-rich organisms.The mud lamina is formed during the intermittent period,and silt lamina is formed during the bloom period of silicon-rich organisms.The mud laminae and silt laminae can combine into three types of assemblages:strip-shaped silt,gradating sand-mud and sand-mud thin interlayers.The strip-shaped silt assemblage has the highest porosity and horizontal/vertical permeability ratio,followed by the gradating sand-mud assemblage and sand-mud thin interlayer assemblage.The difference in the content ratio of the mud laminae to silt laminae results in the difference in the horizontal/vertical permeability ratio.
基金the financial support of the National Science and Technology Major Project(No.2016ZX05034-001)National Natural Science Foundation of China(No.41472112)
文摘The pores in shales are mainly of nanometer-scale,and their pore size distribution is very important for the preservation and exploitation of shale gas.This study focused on the organic-rich Lower Silurian black shale from four wells in the Upper Yangtze Platform,and their TOC,mineralogical composition and pore characterization were investigated.Low pressure N_2 and CO_2 adsorption were conducted at 77.35 K and 273.15 K,respectively,and the pore structures were characterized by modified Brunauer-Emmett-Teller(BET),Dubinin-Radushkevich(DR),t-plot,BarrettJoyner-Halenda(BJH) and density functional theory(DFT) methods and then the relationship between pore structure and shale gas sorption capacity was discussed.The results indicate that(1) The Lower Silurian shale has high TOC content of 0.92%-4.96%,high quartz content of 30.6%-69.5%,and high clays content of 24.1%-51.2%.The total specific surface area varies from 7.56 m^2/g to 25.86 m^2/g.Both the total specific surface area and quartz content are positively associated with the TOC content.(2)Shale samples with higher TOC content have more micropores,which results in more complex nanopore structure.Micropore volumes/surface areas and non-micropore surface areas all increase with the increasing TOC content.(3) A combination of N_2 and CO_2 adsorption provides the most suitable detection range(~0.3-60 nm) and has high reliability and accuracy for nanopore structure characterization.(4) The TOC content is the key factor to control the gas sorption capacity of the Lower Silurian shale in the Upper Yangtze Platform.
基金Supported by the China National Science and Technology Major Project(2017ZX05035-02)
文摘Sweet spots in the shale reservoirs of the Lower Silurian Longmaxi Formation in Weiyuan 201 Block of Sichuan Basin were predicted quantitatively using seismic data and fuzzy optimization method. First, based on seismic and rock physics analysis, the rock physics characteristics of the reservoirs were determined, and elastic parameters sensitive to shale reservoirs with high gas content were selected. Second, data volumes with high precision of the elastic parameters were obtained from pre-stack simultaneous inversion. The horizontal distribution of key parameters for shale gas evaluation were calculated based on the results of rock physics analysis. Then, the fuzzy evaluation equation was established by fuzzy optimization method with test and logging data of horizontal wells with similar operation conditions. key parameters affecting the productivity of horizontal wells were sorted out and the weights of them in the sweet spots quantitative prediction were worked out by fuzzy optimization to set up a sweet spots evaluation system. Three classes of shale gas reservoirs which including two kinds of sweet spots were predicted with the above procedure, and the sweet spots have been predicted quantitatively by combining the above prediction results with the testing production. The testing results of 7 verification wells proved the reliability of the prediction results.
基金supported by 12th Five-Year Plan Project of State Key Laboratory Of Ore Deposit Geochemistry Chinese Academy of Sciences(SKLODGZY125-08)funds from State Key Laboratory of Palaeobiology and Stratigraphy Chinese Academy of SciencesChinese National Program on Key Basic Research and Development(2007CB411408)
文摘This paper presents a set of bulk geochemical and mineralogical data from a paleoweathering profile located in Zunyi District, Northern Guizhou, China. It was formed at the top of the Hanjiadian Formation of the Lower Silurian. A truncated, argillic, gleyed, kryptic paleospodosol is recognized in the paleoweathering profile. Ratios of immobile elements(Ti/Zr, Ti/Al) and their binary(e.g., Nb vs. Zr/TiO_2 and Th/Sc vs. Zr/Sc), triangular diagrams(La-Th-Sc, Th-ScZr/10, Zr-Cr-Ga) reflect that the Gaojiayan paleosol is the product of in-situ weathering of gray-green silty mudstone of the underlying Hanjiadian Formation. Mass balance calculations indicate K enrichment and Na enrichment in the upper and lower portions of paleosol, respectively. These findings both are the results of transgression, which brings substantial concentrations of such elements as K, Na, and Sr. In particular, K enrichment is achieved by the illitization of kaolinite. The biological processes of terrestrial vascular plants also enhance K concentration, especially at the top of the paleosol. Na enrichment is a consequence of albitization and/or adsorption by clay minerals through cation exchange. The mass distributions and relative mass changes of rare earth elements(REEs) in the studied profile display characteristics of vertical zonation. Three peaks in total REEs content are observed, indicating two paleoclimatic or paleoenvironmental changes. Mineralogical characteristics indicate that the paleoclimate changed first from warm and humid to cold and dry and later, to dry and lightly warmer. The corresponding soil environment varies from weakly acidic to strongly alkaline and later, to weakly acidic. Mass translocation characteristics of REEs and several transition metals suggest that the Gaojiayan paleosol may have undergone top erosion.
文摘The distribution of Lower Silurian conodonts from the sections on the Kozhym River was studied first by S.V. Melnikov.After additional studies of the Upper Ordovician-Lower Silurian strata,Oulodus? aff.nathani, Walliserodus cf.curvatus,Panderodus sp.and Ozarkodina sp.were identified by P.M(a|¨)nnik in the Subpolar Urals.Studies of conodonts from the
基金Supported by the China National Science and Technology Major Project(2017ZX05035001)
文摘Based on the Qiliao section of the Upper Ordovician Wufeng Formation – Lower Silurian Longmaxi Formation in Shizhu, Chongqing city, the development characteristics of bentonite in eastern Sichuan Basin was examined systematically, and its geological significance and scientific value were analyzed. The main understandings are as follows:(1) Six bentonite dense layers were found in the Qiliao section, mainly occurring in 6 graptolitic belts of the Katian, Rhuddanian and Aeronian. Most of the bentonite dense layers showed obvious increase in clay, peak response of GR curve, and indistinct relationship between volcanic ash and total organic carbon(TOC).(2) The bentonite dense layers of Longmaxi Formation were widely distributed in eastern Sichuan Basin and its periphery, and generally showed GR peak, which can be an important reference interface for dividing the bottom boundary of the Coronograptus cyphus belt and the top boundary of the Rhuddanian in eastern Sichuan Basin and western Hubei province.(3) Taking the bentonite dense layers as the stratification basis of the Rhuddanian and Aeronian, it was determined that the sediment thickness of the Rhuddanian in the eastern Sichuan depression was generally 10–40 m, but only the upper part of the Coronograptus cyphus belt was deposited in the hinderland of Yichang Uplift, and the sedimentary thickness was only 3–7 m.(4) In the hinderland of the Yichang Uplift, at least five and a half graptolitic belts were missing in Wufeng Formation – Rhuddanian, and the deposition time of Rhuddanian was less than 0.4 Ma.(5) The bentonite dense layers were important sedimentary responses to the strong deflection of the Yangtze basin at the turn of the Ordovician–Silurian, which suggested that four tectonic activity periods existed in the eastern Sichuan depression, including the early stage of the depression, the middle-late stage of the depression, the early stage of the foreland flexure and the development stage of the foreland flexure. The high-quality shale was mainly developed from the early stage to the middle-late stage in the depression.
基金Supported by the China National Science and Technology Major Project(2016ZX05062)the PetroChina Science and Technology Major Project(2016E-0611)
文摘Marine shale gas resources have great potential in the south of the Sichuan Basin in China.At present,the high-quality shale gas resources at depth of 2000–3500 m are under effective development,and strategic breakthroughs have been made in deeper shale gas resources at depth of 3500–4500 m.To promote the effective production of shale gas in this area,this study examines key factors controlling high shale gas production and presents the next exploration direction in the southern Sichuan Basin based on summarizing the geological understandings from the Lower Silurian Longmaxi Formation shale gas exploration combined with the latest results of geological evaluation.The results show that:(1)The relative sea depth in marine shelf sedimentary environment controls the development and distribution of reservoirs.In the relatively deep water area in deep-water shelf,grade-I reservoirs with a larger continuous thickness develop.The relative depth of sea in marine shelf sedimentary environment can be determined by redox conditions.The research shows that the uranium to thorium mass ratio greater than 1.25 indicates relatively deep water in anoxic reduction environment,and the uranium to thorium mass ratio of 0.75–1.25 indicates semi-deep water in weak reduction and weak oxidation environment,and the uranium to thorium mass ratio less than 0.75 indicates relatively shallow water in strong oxidation environment.(2)The propped fractures in shale reservoirs subject to fracturing treatment are generally 10–12 m high,if grade-I reservoirs are more than 10 m in continuous thickness,then all the propped section would be high-quality reserves;in this case,the longer the continuous thickness of penetrated grade-I reservoirs,the higher the production will be.(3)The shale gas reservoirs at 3500–4500 m depth in southern Sichuan are characterized by high formation pressure,high pressure coefficient,well preserved pores,good pore structure and high proportion of free gas,making them the most favorable new field for shale gas exploration;and the pressure coefficient greater than 1.2 is a necessary condition for shale gas wells to obtain high production.(4)High production wells in the deep shale gas reservoirs are those in areas where Long11-Long13 sub-beds are more than 10 m thick,with 1500 m long horizontal section,grade-I reservoirs penetration rate of over 90%,and fractured by dense cutting+high intensity sand injection+large displacement+large liquid volume.(5)The relatively deep-water area in the deep-water shelf and the area at depth of 3500–4500 m well overlap in the southern Sichuan,and the overlapping area is the most favorable shale gas exploration and development zones in the southern Sichuan in the future.With advancement in theory and technology,annual shale gas production in the southern Sichuan is expected to reach 450×108 m3.
基金Supported by the China National Science and Technology Major Project(2017ZX05063002-009)National Natural Science Foundation of China(4177021173,41972120)CNPC-Southwest Petroleum University Innovation Consortium Science and Technology Cooperation Project(2020CX020000)。
文摘Based on field outcrop data,the effects of cyclic change of astronomical orbit and volcanic activity on organic carbon accumulation during the Late Ordovician-Early Silurian in the Upper Yangtze area were studied using cyclostratigraphic and geochemical methods.d13 C and chemical index of alteration(CIA)were used to filter the astronomical orbit parameters recorded in sediments.It is found that the climate change driven by orbital cycle controls the fluctuations of sea level at different scales,obliquity forcing climate changes drive thermohaline circulation(THC)of the ocean,and THC-induced bottom currents transport nutrient-laden water from high latitude regions to the surface water of low-latitude area.Hence,THC is the main dynamic mechanism of organic-carbon supply.The marine productivity indexes of Ba/Al and Ni/Al indicate that volcanic activities had limited effect on marine productivity but had great influences on organic carbon preservation efficiency in late Hirnantian(E4).Paleo-ocean redox environmental indicators Th/U,V/Cr and V/(V+Ni)show that there is a significant correlation between volcanism and oxygen content in Paleo-ocean,so it is inferred that volcanisms controlled the organic carbon preservation efficiency by regulating oxygen content in Paleo-ocean,and the difference in volcanism intensity in different areas is an important factor for the differential preservation efficiency of organic carbon.The organic carbon input driven by orbital cycle and the preservation efficiency affected by volcanisms worked together to control the enrichment of organic carbon in the Middle–Upper Yangtze region.
基金Supported by the China National Science and Technology Major Project(2017ZX05036,2017ZX05036001).
文摘As the hydrocarbon generation and storage mechanisms of high quality shales of Upper Ordovician Wufeng Formation– Lower Silurian Longmaxi Formation remain unclear, based on geological conditions and experimental modelling of shale gas formation, the shale gas generation and accumulation mechanisms as well as their coupling relationships of deep-water shelf shales in Wufeng–Longmaxi Formation of Sichuan Basin were analyzed from petrology, mineralogy, and geochemistry. The high quality shales of Wufeng–Longmaxi Formation in Sichuan Basin are characterized by high thermal evolution, high hydrocarbon generation intensity, good material base, and good roof and floor conditions;the high quality deep-water shelf shale not only has high biogenic silicon content and organic carbon content, but also high porosity coupling. It is concluded that:(1) The shales had good preservation conditions and high retainment of crude oil in the early times, and the shale gas was mainly from cracking of crude oil.(2) The biogenic silicon(opal A) turned into crystal quartz in early times of burial diagenesis, lots of micro-size intergranular pores were produced in the same time;moreover, the biogenic silicon frame had high resistance to compaction, thus it provided the conditions not only for oil charge in the early stage, but also for formation and preservation of nanometer cellular-like pores, and was the key factor enabling the preservation of organic pores.(3) The high quality shale of Wufeng–Longmaxi Formation had high brittleness, strong homogeneity, siliceous intergranular micro-pores and nanometer organic pores, which were conducive to the formation of complicated fissure network connecting the siliceous intergranular nano-pores, and thus high and stable production of shale gas.
基金Supported by the CAS Strategic Pilot Project(XDA14010101)National Science and Technology Major Project(2017ZX05035001)PetroChina Exploration&Production Shale Gas Resource Evaluation and Strategic Selection Project(kt2017-10-02)
文摘Based on the drilling data of the Silurian Longmaxi Formation in the Sichuan Basin and periphery, SW China, the Ro lower limits and essential features of the carbonization of organic matter in over-high maturity marine shale were examined using laser Raman, electrical and physical property characterization techniques. Three preliminary conclusions are drawn:(1) The lower limit of Ro for the carbonization of Type I-II1 organic matter in marine shale is 3.5%; when the Ro is less than 3.4%, carbonization of organic matter won't happen in general; when the Ro ranges from 3.4% to 3.5%, non-carbonization and weak carbonization of organic matter may coexist; when the Ro is higher than 3.5%, the carbonization of organic matter is highly likely to take place.(2) Organic-rich shale entering carbonization phase have three basic characteristics: log resistivity curve showing a general "slender neck" with low-ultralow resistance response, Raman spectra showing a higher graphite peak, and poor physical property(with matrix porosity of only less than 1/2 of the normal level).(3) The quality damage of shale reservoir caused by the carbonization of organic matter is almost fatal, which primarily manifests in depletion of hydrocarbon generation capacity, reduction or disappearance of organic pores and intercrystalline pores of clay minerals, and drop of adsorption capacity to natural gas. Therefore, the lower limit of Ro for the carbonization of Type I-II1 organic matter should be regarded as the theoretically impassable red line of shale gas exploration in the ancient marine shale formations. The organic-rich shale with low-ultralow resistance should be evaluated effectively in area selection to exclude the high risk areas caused by the carbonization of organic matter. The target organic-rich shale layers with low-ultralow resistance drilled during exploration and development should be evaluated on carbonization level of organic matter, and the deployment plan should be adjusted according to the evaluation results in time.
文摘Acoustic wave velocity has been commonly utilized to predict subsurface geopressure using empirical relations.Acoustic wave velocity is, however, affected by many factors. To estimate pore pressure accurately, we here propose to use elastic rock physics models to understand and analyze quantitatively the various contributions from these different factors affecting wave velocity. We report a closed-form relationship between the frame flexibility factor(γ) in a rock physics model and differential pressure, which presents the major control of pressure on elastic properties such as bulk modulus and compressional wave velocity. For a gas-bearing shale with abundant micro-cracks and fractures, its bulk modulus is much lower at abnormally high pore pressure(high γ values) where thin cracks and flat pores are open than that at normal hydrostatic pressure(low γ values) where pores are more rounded on average. The developed relations between bulk modulus and differential pressure have been successfully applied to the Upper Ordovician Wufeng and Lower Silurian Longmaxi formations in the Dingshan area of the Sichuan Basin to map the three-dimensional spatial distribution of pore pressure in the shale, integrating core, log and seismic data. The estimated results agree well with field measurements. Pressure coefficient is positively correlated to gas content. The relations and methods reported here could be useful for hydrocarbon exploration, production, and drilling safety in both unconventional and conventional fields.
