Carrying out green energy transformation,implementing clean energy power replacement and supply,and developing a new power system are some primary driving forces needed to fulfill China’s carbon-peak and carbon-neutr...Carrying out green energy transformation,implementing clean energy power replacement and supply,and developing a new power system are some primary driving forces needed to fulfill China’s carbon-peak and carbon-neutral strategic goals.The construction of new power systems in China’s provinces and cities is developing rapidly,and the lack of a typical model promotes the application.The new power system path design should be based on the actual development of the power grid in different regions,energy use characteristics,and other actual needs to carry out the differentiated path design.In this context,this study analyzes the characteristics of the new domestic power system based on the policy background of the new domestic power system,constructs a new model for power system development stage identification,and proposes the overall design of the new power system development path from the power supply,transmission and distribution,and load sides.It also uses the Hebei South Network as an example to explore the development stage of the Hebei South Grid based on actual development needs.Finally,this study designs a novel power system development path for the entire supply and demand chain for the Hebei South Grid to propose ideas for constructing a new power system in China and to help green energy transformation.展开更多
A new spherical mobile robot BHQ-1 is designed. The spherical robot is driven by two internally mounted motors that induce the ball to move straight and turn around on a flat surface. A dynamic model of the robot is d...A new spherical mobile robot BHQ-1 is designed. The spherical robot is driven by two internally mounted motors that induce the ball to move straight and turn around on a flat surface. A dynamic model of the robot is developed with Lagrange method and factors affecting the driving torque of two motors are analyzed. The relationship between the turning radius of the robot and the length of two links is discussed in order to optimize its mechanism design. Simulation and experimental results demonstrate the good controllability and motion performance of BHQ-1.展开更多
Evidences indicate that,due to the limited caching capacity or inaccurate estimation on users’preferences,the requested files may not be fully cached in the network edge.The transmissions of the un-cached files will ...Evidences indicate that,due to the limited caching capacity or inaccurate estimation on users’preferences,the requested files may not be fully cached in the network edge.The transmissions of the un-cached files will also lead to duplicated transmissions on backhaul channels.Buffer-aided relay has been proposed to improve the transmission performance of the un-cached files.Because of the limited buffer capacity and the information asymmetric environment,how to allocate the limited buffer capacity and how to incentivize users in participating buffer-aided relay have become critical issues.In this work,an incentive scheme based on the contract theory is proposed.Specifically,the backlog violation probability,i.e.,the buffer overflow probability,is provided based on the martingale theory.Next,based on the backlog violation probability,the utility functions of the relay node and users are constructed.With the purpose to maximize the utility of the relay node,the optimal contract problem is formulated.Then,the feasibility of the contract is also demonstrated,and the optimal solution can be obtained by the interior point method.Finally,numerical results are presented to demonstrate effectiveness of the proposed contract theory scheme.展开更多
A general methodology for developing intelligent CAE systems is presented, which is based on a so-called Model Based Reasoning Approach (MBRA) in knowledge engineering. Generic features of CAE systems are described, a...A general methodology for developing intelligent CAE systems is presented, which is based on a so-called Model Based Reasoning Approach (MBRA) in knowledge engineering. Generic features of CAE systems are described, and a generic model for the architecture of CAE systems with these generic features is then presented. A model-based reasoning approach is modified for implementing the generic model. A case for developing a computer system for the mechanism design based on a specific finite element theory is used to explain the methodology.展开更多
The corporate entrepreneurship has become an important part in the business mana gement as well as a worldwide fashion. Traditional management idealism, organiza tion structure, management technology and enterprise cu...The corporate entrepreneurship has become an important part in the business mana gement as well as a worldwide fashion. Traditional management idealism, organiza tion structure, management technology and enterprise culture have influenced the further step of the whole process to some extent. Therefore, manager should sea rch for the plausible management mechanism with an aim to support the corporate entrepreneurship. It includes strengthening the corporate risk-taking, setting up motivation mechanism for corporate entrepreneurship, rebuilding the pioneerin g group, formulating an evaluation method, establishing and perfecting monitor a nd restraining mechanism, encouraging creativity and building favorable culture to provide a profitable outer environment for corporate entrepreneurship.展开更多
Drawing the ecological protection red line is to maintain the integrity and benign operation of the ecosystem within the area,and to ensure that the ecological environment is within the boundary of controllable ecolog...Drawing the ecological protection red line is to maintain the integrity and benign operation of the ecosystem within the area,and to ensure that the ecological environment is within the boundary of controllable ecological security.Taking the ecologically vulnerable areas in western China as the research object and using the game theory and literature analysis,this paper studied the game behavior of ecological protection red line in these areas.In addition,this paper also analyzed the stakeholders such as government,enterprises and the masses in the drawing of the ecological protection red line,and comprehensively analyzed the game strategies between the government and the masses,the government and enterprises,and the central and local governments and enterprises.On the basis of the analysis,it came up with a safeguard mechanism for the coordination of the interests of the ecological protection red line.展开更多
New type professional farmers are farmers who possess certain resources and capitals,have certain extent of spirit of entrepreneurship,and are fully capable of obtaining and allocating resources related to agricultura...New type professional farmers are farmers who possess certain resources and capitals,have certain extent of spirit of entrepreneurship,and are fully capable of obtaining and allocating resources related to agricultural production and management,and engaged in agricultural production and management for obtaining average profit.Cultivation of new type professional farmers should be promoted in the process and at the background of"coordinated development of industrialization,informationization,urbanization and agricultural modernization".It should establish a proper cultivation subject system consisting of government,enterprises,rural communities and nonprofit organizations.Relying on multiple motive forces,efforts should be concentrated on cultivating those farmers with enterprising,highly innovative and learning ability,to guide traditional farmers to change into learning,enterprising and innovative ones.In addition,cultivation of new type professional farmers must rely on farmer education and training,modern agricultural development,increase in agricultural comparative advantage,innovation of rural management system and mechanism,multiple types of agricultural operation on a fairly large scale,as well as construction and regulation of new rural communities.Finally,it is recommended to provide system guarantee from long-term input mechanism of new type professional farmer education and training,incentive and restrictive mechanism of new type professional farmer cultivation,and construction of favorable environment for agricultural entrepreneurship.展开更多
This paper studies the mechanism design that induces firms to provide public goods under two regulatory means: price cap regulation and optimal regulation, respectively. We first outline two models of monopoly regulat...This paper studies the mechanism design that induces firms to provide public goods under two regulatory means: price cap regulation and optimal regulation, respectively. We first outline two models of monopoly regulation with unobservable marginal costs and effort, which can be regard as an optimal problem with dual restrictions. By solving this problem, we get the two optimal regulatory mechanisms to induce the provision of public goods. Further, by comparative statics, the conclusion is drawn that the welfare loss associated with price cap regulation, with respective to optimal regulation, increases more with increase of the expense of public goods.展开更多
A novel method of realizing the optimal transmission of the crank-and-rocker mechanism is presented,The optimal combination design is made by finding the related optimal transmission parameters ,The diagram of the opt...A novel method of realizing the optimal transmission of the crank-and-rocker mechanism is presented,The optimal combination design is made by finding the related optimal transmission parameters ,The diagram of the optimal transmission is drawn ,In the diagram,the relation among minimum transmission angle,the coeffcient oftravel speed variation,the oscillating angle of the rocker and the length of the bars is shown,concisely,conveniently and directly,The method possesses the main characteristic,That is is to achieve the optimal transmission parameters under the transmission angle by directly choosing in the diagram,according to the given requirements ,The characteristics of the mechanical transmission can be improved to gain the optimal transmission effect by the method,Especially,the method is simple and convenient in practical use.展开更多
Palletizing robot technology has been applied more and more extensively in logistics automation field.But there are some limitations in the current single-arm palletizing robot that it cannot do effective work in the ...Palletizing robot technology has been applied more and more extensively in logistics automation field.But there are some limitations in the current single-arm palletizing robot that it cannot do effective work in the process of moving back to the taking-end and the mechanical arm has so many freedoms that its control system is relatively complex.Based on the translating cam principle,a novel palletizing robot is designed.The horizontal movement of the palletizing mechanical arm is controlled by changeable outer slides,and the vertical movement is controlled by partitioned up-and-down spindles.To improve palletizing efficiency,the single palletizing mechanical arm is changed into multi-arm.Moreover,to improve its kinematic properties,the acceleration operating performance,joint driving force and palletizing trajectory are optimized through the multi-objective delaminating sequence method.According to the optimization results,the 3D model of the multi-arm palletizing robot is built in Pro/E,and the kinematic simulation is made.The simulation results show that the novel mechanism and optimization parameters are rational and feasible.This novel palletizing robot has the advantages of cam mechanism,so it simplifies the driving mode of palletizing movement and can lower the requirements for controlling system.At the same time,it can increase palletizing efficiency further by adding mechanical arms.展开更多
The present research on moulded case circuit breaker(MCCB) focuses on the enhancement of current-limiting interrupting performance during short circuit, overload, under voltage and phase failure, involving electrics, ...The present research on moulded case circuit breaker(MCCB) focuses on the enhancement of current-limiting interrupting performance during short circuit, overload, under voltage and phase failure, involving electrics, magnetic, mechanics, thermal, material, friction, arc extinguishing, impact vibration, skin effect, etc. The rigid-flexible coupling of the parts and components of the metamorphic manipulating mechanism in multi-fields leads to the non-rigid, high frequency, high damping, singularity of the Euler-Lagrange equations which represents the multi-body dynamics. The small step iteration which is used for obtaining the instantaneous and short time critical interrupting performance of metamorphic mechanism appears inaccuracy. It is difficult to realize top-down design by existing CAD systems. Therefore, a metamorphic manipulating mechanism design method for MCCB using index reduced iteration(IRI) is put forward. The metamorphic manipulating mechanism of MCCB is decomposed into three mechanisms: main switch connector mechanism, electromagnet-drawbar-jump buckle mechanism, and bimetallic strip-drawbar mechanism, which is respectively described by electro-dynamic force, electromagnet force, and bimetallic strip force. The dummy part(virtual rigid) without moment of inertia and mass is employed as intermediate to join the flexible body and rigid body. The model of rigid-flexible coupling metamorphic mechanism multi-body dynamics is built. The differential algebraic equations(DAEs) of the multibody dynamics model are converted to pure ordinary differential equations(ODEs) by coordinate partition. Order reduced integration with multi-step and variable step-size is preceded based on IRI. The non-linear algebraic equations are solved in each integration step by Newton-Rapson iteration. There is no ill-condition and singularity of Jacobian matrix when step size reduces to zero. The independent prototype design system using ACIS R13, HOOPS V11.0 and Visual C++.NET 2003 has been developed, which verifies the effectiveness of the proposed method. The proposed method enhances the current-limiting interrupting performance of MCCB, and has reference significance for multi-body dynamics design for similar flexible metamorphic mechanisms in multi-fields.展开更多
Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction...Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction conditions,good stability,and suitable for large-scale production.Recently,with the cross fusion of nanomedicine and nanocatalysis,nanozyme-based theranostic strategies attract great attention,since the enzymatic reactions can be triggered in the tumor microenvironment to achieve good curative effect with substrate specificity and low side effects.Thus,various nanozymes have been developed and used for tumor therapy.In this review,more than 270 research articles are discussed systematically to present progress in the past five years.First,the discovery and development of nanozymes are summarized.Second,classification and catalytic mechanism of nanozymes are discussed.Third,activity prediction and rational design of nanozymes are focused by highlighting the methods of density functional theory,machine learning,biomimetic and chemical design.Then,synergistic theranostic strategy of nanozymes are introduced.Finally,current challenges and future prospects of nanozymes used for tumor theranostic are outlined,including selectivity,biosafety,repeatability and stability,in-depth catalytic mechanism,predicting and evaluating activities.展开更多
Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely comme...Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely commercial application and development of LSB is mainly hindered by serious“shuttle effect”of lithium polysulfides(Li PSs),slow reaction kinetics,notorious lithium dendrites,etc.In various structures of LSB materials,array structured materials,possessing the composition of ordered micro units with the same or similar characteristics of each unit,present excellent application potential for various secondary cells due to some merits such as immobilization of active substances,high specific surface area,appropriate pore sizes,easy modification of functional material surface,accommodated huge volume change,enough facilitated transportation for electrons/lithium ions,and special functional groups strongly adsorbing Li PSs.Thus many novel array structured materials are applied to battery for tackling thorny problems mentioned above.In this review,recent progresses and developments on array structured materials applied in LSBs including preparation ways,collaborative structural designs based on array structures,and action mechanism analyses in improving electrochemical performance and safety are summarized.Meanwhile,we also have detailed discussion for array structured materials in LSBs and constructed the structure-function relationships between array structured materials and battery performances.Lastly,some directions and prospects about preparation ways,functional modifications,and practical applications of array structured materials in LSBs are generalized.We hope the review can attract more researchers'attention and bring more studying on array structured materials for other secondary batteries including LSB.展开更多
Different bilayer structures of HfO_(x)/Ti(TiO_(x)) are designed for hafnium-based memory to investigate the switching characteristics. The chemical states in the films and near the interface are characterized by x-ra...Different bilayer structures of HfO_(x)/Ti(TiO_(x)) are designed for hafnium-based memory to investigate the switching characteristics. The chemical states in the films and near the interface are characterized by x-ray photoelectron spectroscopy,and the oxygen vacancies are analyzed. Highly improved on/off ratio(~104) and much uniform switching parameters are observed for bilayer structures compared to single layer HfO_(x) sample, which can be attributed to the modulation of oxygen vacancies at the interface and better control of the growth of filaments. Furthermore, the reliability of the prepared samples is investigated. The carrier conduction behaviors of HfO_(x)-based samples can be attributed to the trapping and de-trapping process of oxygen vacancies and a filamentary model is proposed. In addition, the rupture of filaments during the reset process for the bilayer structures occur at the weak points near the interface by the recovery of oxygen vacancies accompanied by the variation of barrier height. The re-formation of fixed filaments due to the residual filaments as lightning rods results in the better switching performance of the bilayer structure.展开更多
Lithium-sulfur batteries(LSBs)have been regarded as one of the promising candidates for the next-generation“lithium-ion battery beyond”owing to their high energy density and due to the low cost of sulfur.However,the...Lithium-sulfur batteries(LSBs)have been regarded as one of the promising candidates for the next-generation“lithium-ion battery beyond”owing to their high energy density and due to the low cost of sulfur.However,the main obstacles encountered in the commercial implementation of LSBs are the notorious shuttle effect,retarded sulfur redox kinetics,and uncontrolled dendrite growth.Accordingly,single-atom catalysts(SACs),which have ultrahigh catalytic efficiency,tunable coordination configuration,and light weight,have shown huge potential in the field of LSBs to date.This review summarizes the recent research progress of SACs applied as multifunctional components in LSBs.The design principles and typical synthetic strategies of SACs toward effective Li–S chemistry as well as the working mechanism promoting sulfur conversion reactions,inhibiting the lithium polysulfide shuttle effect,and regulating Li+nucleation are comprehensively illustrated.Potential future directions in terms of research on SACs for the realization of commercially viable LSBs are also outlined.展开更多
Non-renewable fossil fuels have led to serious problems such as global warming,environmental pollution,etc.Oxygen electrocatalysis including oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)plays a cent...Non-renewable fossil fuels have led to serious problems such as global warming,environmental pollution,etc.Oxygen electrocatalysis including oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)plays a central role in clean energy conversion,enabling a number of sustainable processes for future air battery technologies.Fluorine,as the most electronegative element(4.0)not only can induce more efficient regulation for the electronic structure,but also can bring more abundant defects and other novel effects in materials selection and preparation for favorable catalysis with respect to the other nonmetal elements.However,an individual and comprehensive overview of fluorine-containing functional materials for oxygen electrocatalysis field is still blank.Therefore,it is very meaningful to review the recent progresses of fluorine-containing oxygen electrocatalysts.In this review,we first systematically summarize the controllable preparation methods and their possible development directions based on fluorine-containing materials from four preparation methods.Due to the strong electron-withdrawing properties of fluorine,its control of the electronic structure can effectively enhance the oxygen electrocatalytic activity of the materials.In addition,the catalytic enhancement effect of fluorine on carbonbased materials also includes the prevent oxidation and the layer peeling,and realizes the precise atomic control.And the catalytic improvement mechanism of fluorine containing metal-based compounds also includes the hydration of metal site,the crystal transformation,and the oxygen vacancy induction.Then,based on their various dimensions(0D–3D),we also have summarized the advantages of different morphologies on oxygen electrocatalytic performances.Finally,the prospects and possible future researching direction of F-containing oxygen electrocatalysts are presented(e.g.,novel pathways,advanced methods for measurement and simulation,field assistance and multi-functions).The review is considered valuable and helpful in exploring the novel designs and mechanism analyses of advanced fluorine-containing electrocatalysts.展开更多
基金funded by the State Grid Hebei Electric Power Co.,Ltd projectthe National Natural Science Foundation of China’s major project,“Research on the Construction of China’s Economic Transformation Mode for Carbon Neutrality(72140001)This study is titled“Research on Novel Power System Development Path”。
文摘Carrying out green energy transformation,implementing clean energy power replacement and supply,and developing a new power system are some primary driving forces needed to fulfill China’s carbon-peak and carbon-neutral strategic goals.The construction of new power systems in China’s provinces and cities is developing rapidly,and the lack of a typical model promotes the application.The new power system path design should be based on the actual development of the power grid in different regions,energy use characteristics,and other actual needs to carry out the differentiated path design.In this context,this study analyzes the characteristics of the new domestic power system based on the policy background of the new domestic power system,constructs a new model for power system development stage identification,and proposes the overall design of the new power system development path from the power supply,transmission and distribution,and load sides.It also uses the Hebei South Network as an example to explore the development stage of the Hebei South Grid based on actual development needs.Finally,this study designs a novel power system development path for the entire supply and demand chain for the Hebei South Grid to propose ideas for constructing a new power system in China and to help green energy transformation.
基金This project is supported by National Hi-tech Research and Development Program of China(863 Program, No.2003AA404190).
文摘A new spherical mobile robot BHQ-1 is designed. The spherical robot is driven by two internally mounted motors that induce the ball to move straight and turn around on a flat surface. A dynamic model of the robot is developed with Lagrange method and factors affecting the driving torque of two motors are analyzed. The relationship between the turning radius of the robot and the length of two links is discussed in order to optimize its mechanism design. Simulation and experimental results demonstrate the good controllability and motion performance of BHQ-1.
基金the National Natural Science Foundation of China(No.61702258)the Key Projects of Natural Science Research in Colleges and Universities of Jiangsu Province(No.19KJA410001)the Foundation of Jiangsu Advanced Numerical Control Technology Key Laboratory(No.SYKJ201901).
文摘Evidences indicate that,due to the limited caching capacity or inaccurate estimation on users’preferences,the requested files may not be fully cached in the network edge.The transmissions of the un-cached files will also lead to duplicated transmissions on backhaul channels.Buffer-aided relay has been proposed to improve the transmission performance of the un-cached files.Because of the limited buffer capacity and the information asymmetric environment,how to allocate the limited buffer capacity and how to incentivize users in participating buffer-aided relay have become critical issues.In this work,an incentive scheme based on the contract theory is proposed.Specifically,the backlog violation probability,i.e.,the buffer overflow probability,is provided based on the martingale theory.Next,based on the backlog violation probability,the utility functions of the relay node and users are constructed.With the purpose to maximize the utility of the relay node,the optimal contract problem is formulated.Then,the feasibility of the contract is also demonstrated,and the optimal solution can be obtained by the interior point method.Finally,numerical results are presented to demonstrate effectiveness of the proposed contract theory scheme.
文摘A general methodology for developing intelligent CAE systems is presented, which is based on a so-called Model Based Reasoning Approach (MBRA) in knowledge engineering. Generic features of CAE systems are described, and a generic model for the architecture of CAE systems with these generic features is then presented. A model-based reasoning approach is modified for implementing the generic model. A case for developing a computer system for the mechanism design based on a specific finite element theory is used to explain the methodology.
文摘The corporate entrepreneurship has become an important part in the business mana gement as well as a worldwide fashion. Traditional management idealism, organiza tion structure, management technology and enterprise culture have influenced the further step of the whole process to some extent. Therefore, manager should sea rch for the plausible management mechanism with an aim to support the corporate entrepreneurship. It includes strengthening the corporate risk-taking, setting up motivation mechanism for corporate entrepreneurship, rebuilding the pioneerin g group, formulating an evaluation method, establishing and perfecting monitor a nd restraining mechanism, encouraging creativity and building favorable culture to provide a profitable outer environment for corporate entrepreneurship.
基金Sponsored by Social Science Foundation Project of Hunan Province(16YBX008)Major Program of Hunan Provincial Social Science Evaluation Committee(XSP18YBC143)
文摘Drawing the ecological protection red line is to maintain the integrity and benign operation of the ecosystem within the area,and to ensure that the ecological environment is within the boundary of controllable ecological security.Taking the ecologically vulnerable areas in western China as the research object and using the game theory and literature analysis,this paper studied the game behavior of ecological protection red line in these areas.In addition,this paper also analyzed the stakeholders such as government,enterprises and the masses in the drawing of the ecological protection red line,and comprehensively analyzed the game strategies between the government and the masses,the government and enterprises,and the central and local governments and enterprises.On the basis of the analysis,it came up with a safeguard mechanism for the coordination of the interests of the ecological protection red line.
基金Supported by Key Project of National Social Science Foundation(10AGL007&12ASH004)Key Project of Ministry of Education(DFA100209)+2 种基金Ph.D.Foundation Project of Southwest University(SWU1209338)Fundamental Research Funds for the Central Universities in 2013(SWU1309315)Fundamental Research Funds for the Central Universities in 2009(SWU0909629)
文摘New type professional farmers are farmers who possess certain resources and capitals,have certain extent of spirit of entrepreneurship,and are fully capable of obtaining and allocating resources related to agricultural production and management,and engaged in agricultural production and management for obtaining average profit.Cultivation of new type professional farmers should be promoted in the process and at the background of"coordinated development of industrialization,informationization,urbanization and agricultural modernization".It should establish a proper cultivation subject system consisting of government,enterprises,rural communities and nonprofit organizations.Relying on multiple motive forces,efforts should be concentrated on cultivating those farmers with enterprising,highly innovative and learning ability,to guide traditional farmers to change into learning,enterprising and innovative ones.In addition,cultivation of new type professional farmers must rely on farmer education and training,modern agricultural development,increase in agricultural comparative advantage,innovation of rural management system and mechanism,multiple types of agricultural operation on a fairly large scale,as well as construction and regulation of new rural communities.Finally,it is recommended to provide system guarantee from long-term input mechanism of new type professional farmer education and training,incentive and restrictive mechanism of new type professional farmer cultivation,and construction of favorable environment for agricultural entrepreneurship.
文摘This paper studies the mechanism design that induces firms to provide public goods under two regulatory means: price cap regulation and optimal regulation, respectively. We first outline two models of monopoly regulation with unobservable marginal costs and effort, which can be regard as an optimal problem with dual restrictions. By solving this problem, we get the two optimal regulatory mechanisms to induce the provision of public goods. Further, by comparative statics, the conclusion is drawn that the welfare loss associated with price cap regulation, with respective to optimal regulation, increases more with increase of the expense of public goods.
文摘A novel method of realizing the optimal transmission of the crank-and-rocker mechanism is presented,The optimal combination design is made by finding the related optimal transmission parameters ,The diagram of the optimal transmission is drawn ,In the diagram,the relation among minimum transmission angle,the coeffcient oftravel speed variation,the oscillating angle of the rocker and the length of the bars is shown,concisely,conveniently and directly,The method possesses the main characteristic,That is is to achieve the optimal transmission parameters under the transmission angle by directly choosing in the diagram,according to the given requirements ,The characteristics of the mechanical transmission can be improved to gain the optimal transmission effect by the method,Especially,the method is simple and convenient in practical use.
基金Supported by Natural Science Foundation of Shandong Province,China(No.ZR2010EM007)Shandong Province Science and Technology Development Plan(No.2010GGX10402)
文摘Palletizing robot technology has been applied more and more extensively in logistics automation field.But there are some limitations in the current single-arm palletizing robot that it cannot do effective work in the process of moving back to the taking-end and the mechanical arm has so many freedoms that its control system is relatively complex.Based on the translating cam principle,a novel palletizing robot is designed.The horizontal movement of the palletizing mechanical arm is controlled by changeable outer slides,and the vertical movement is controlled by partitioned up-and-down spindles.To improve palletizing efficiency,the single palletizing mechanical arm is changed into multi-arm.Moreover,to improve its kinematic properties,the acceleration operating performance,joint driving force and palletizing trajectory are optimized through the multi-objective delaminating sequence method.According to the optimization results,the 3D model of the multi-arm palletizing robot is built in Pro/E,and the kinematic simulation is made.The simulation results show that the novel mechanism and optimization parameters are rational and feasible.This novel palletizing robot has the advantages of cam mechanism,so it simplifies the driving mode of palletizing movement and can lower the requirements for controlling system.At the same time,it can increase palletizing efficiency further by adding mechanical arms.
基金supported by National Basic Research Program of China(973 Program, Grant No. 2011CB706506)National S&T Great Special of China(Grant Nos. 2012ZX04010011, 2011ZX04014-131)+1 种基金National Science Foundation for Young Scholars of China(Grant No. 51005204)Postdoctoral Fund of China(Grant No. 20100471000)
文摘The present research on moulded case circuit breaker(MCCB) focuses on the enhancement of current-limiting interrupting performance during short circuit, overload, under voltage and phase failure, involving electrics, magnetic, mechanics, thermal, material, friction, arc extinguishing, impact vibration, skin effect, etc. The rigid-flexible coupling of the parts and components of the metamorphic manipulating mechanism in multi-fields leads to the non-rigid, high frequency, high damping, singularity of the Euler-Lagrange equations which represents the multi-body dynamics. The small step iteration which is used for obtaining the instantaneous and short time critical interrupting performance of metamorphic mechanism appears inaccuracy. It is difficult to realize top-down design by existing CAD systems. Therefore, a metamorphic manipulating mechanism design method for MCCB using index reduced iteration(IRI) is put forward. The metamorphic manipulating mechanism of MCCB is decomposed into three mechanisms: main switch connector mechanism, electromagnet-drawbar-jump buckle mechanism, and bimetallic strip-drawbar mechanism, which is respectively described by electro-dynamic force, electromagnet force, and bimetallic strip force. The dummy part(virtual rigid) without moment of inertia and mass is employed as intermediate to join the flexible body and rigid body. The model of rigid-flexible coupling metamorphic mechanism multi-body dynamics is built. The differential algebraic equations(DAEs) of the multibody dynamics model are converted to pure ordinary differential equations(ODEs) by coordinate partition. Order reduced integration with multi-step and variable step-size is preceded based on IRI. The non-linear algebraic equations are solved in each integration step by Newton-Rapson iteration. There is no ill-condition and singularity of Jacobian matrix when step size reduces to zero. The independent prototype design system using ACIS R13, HOOPS V11.0 and Visual C++.NET 2003 has been developed, which verifies the effectiveness of the proposed method. The proposed method enhances the current-limiting interrupting performance of MCCB, and has reference significance for multi-body dynamics design for similar flexible metamorphic mechanisms in multi-fields.
基金S.G.acknowledges the financial support from the National Natural Science Foundation of China(NSFC 52272144,51972076)the Heilongjiang Provincial Natural Science Foundation of China(JQ2022E001)+4 种基金the Natural Science Foundation of Shandong Province(ZR2020ZD42)the Fundamental Research Funds for the Central Universities.H.D.acknowledges the financial support from the National Natural Science Foundation of China(NSFC 22205048)China Postdoctoral Science Foundation(2022M710931 and 2023T160154)Heilongjiang Postdoctoral Science Foundation(LBH-Z22010)G.Y.acknowledges the financial support from the National Science Foundation of Heilongjiang Education Department(324022075).
文摘Since the discovery of enzyme-like activity of Fe3O4 nanoparticles in 2007,nanozymes are becoming the promising substitutes for natural enzymes due to their advantages of high catalytic activity,low cost,mild reaction conditions,good stability,and suitable for large-scale production.Recently,with the cross fusion of nanomedicine and nanocatalysis,nanozyme-based theranostic strategies attract great attention,since the enzymatic reactions can be triggered in the tumor microenvironment to achieve good curative effect with substrate specificity and low side effects.Thus,various nanozymes have been developed and used for tumor therapy.In this review,more than 270 research articles are discussed systematically to present progress in the past five years.First,the discovery and development of nanozymes are summarized.Second,classification and catalytic mechanism of nanozymes are discussed.Third,activity prediction and rational design of nanozymes are focused by highlighting the methods of density functional theory,machine learning,biomimetic and chemical design.Then,synergistic theranostic strategy of nanozymes are introduced.Finally,current challenges and future prospects of nanozymes used for tumor theranostic are outlined,including selectivity,biosafety,repeatability and stability,in-depth catalytic mechanism,predicting and evaluating activities.
基金This work was supported by the National Natural Science Foundation of China(52203066,51973157,61904123)the Tianjin Natural Science Foundation(18JCQNJC02900)+3 种基金the National innovation and entrepreneurship training program for college students(202310058007)the Tianjin Municipal college students’innovation and entrepreneurship training program(202310058088)the Science&Technology Development Fund of Tianjin Education Commission for Higher Education(Grant No.2018KJ196)the State Key Laboratory of Membrane and Membrane Separation,Tiangong University.
文摘Lithium-sulfur battery(LSB)has brought much attention and concern because of high theoretical specific capacity and energy density as one of main competitors for next-generation energy storage systems.The widely commercial application and development of LSB is mainly hindered by serious“shuttle effect”of lithium polysulfides(Li PSs),slow reaction kinetics,notorious lithium dendrites,etc.In various structures of LSB materials,array structured materials,possessing the composition of ordered micro units with the same or similar characteristics of each unit,present excellent application potential for various secondary cells due to some merits such as immobilization of active substances,high specific surface area,appropriate pore sizes,easy modification of functional material surface,accommodated huge volume change,enough facilitated transportation for electrons/lithium ions,and special functional groups strongly adsorbing Li PSs.Thus many novel array structured materials are applied to battery for tackling thorny problems mentioned above.In this review,recent progresses and developments on array structured materials applied in LSBs including preparation ways,collaborative structural designs based on array structures,and action mechanism analyses in improving electrochemical performance and safety are summarized.Meanwhile,we also have detailed discussion for array structured materials in LSBs and constructed the structure-function relationships between array structured materials and battery performances.Lastly,some directions and prospects about preparation ways,functional modifications,and practical applications of array structured materials in LSBs are generalized.We hope the review can attract more researchers'attention and bring more studying on array structured materials for other secondary batteries including LSB.
基金financially supported by the National Natural Science Foundation of China (Grant No.51802025)the Natural Science Basic Research Plan in Shaanxi Province of China (Grant No.2020JQ-384)。
文摘Different bilayer structures of HfO_(x)/Ti(TiO_(x)) are designed for hafnium-based memory to investigate the switching characteristics. The chemical states in the films and near the interface are characterized by x-ray photoelectron spectroscopy,and the oxygen vacancies are analyzed. Highly improved on/off ratio(~104) and much uniform switching parameters are observed for bilayer structures compared to single layer HfO_(x) sample, which can be attributed to the modulation of oxygen vacancies at the interface and better control of the growth of filaments. Furthermore, the reliability of the prepared samples is investigated. The carrier conduction behaviors of HfO_(x)-based samples can be attributed to the trapping and de-trapping process of oxygen vacancies and a filamentary model is proposed. In addition, the rupture of filaments during the reset process for the bilayer structures occur at the weak points near the interface by the recovery of oxygen vacancies accompanied by the variation of barrier height. The re-formation of fixed filaments due to the residual filaments as lightning rods results in the better switching performance of the bilayer structure.
基金Science and Technology Innovation Program of Hunan Province,Grant/Award Number:2021RC3021Project of State Key Laboratory of Environment‐Friendly Energy Materials,Grant/Award Numbers:18ZD320304,21fksy24+2 种基金Natural Science Foundation of Hunan Province,Grant/Award Number:2021JJ40780National Natural Science Foundation of China,Grant/Award Numbers:51902346,52172239Start‐up Funding of Yangtze Region Institute(Huzhou),University of Electronic Science and Technology,Grant/Award Number:U03220102。
文摘Lithium-sulfur batteries(LSBs)have been regarded as one of the promising candidates for the next-generation“lithium-ion battery beyond”owing to their high energy density and due to the low cost of sulfur.However,the main obstacles encountered in the commercial implementation of LSBs are the notorious shuttle effect,retarded sulfur redox kinetics,and uncontrolled dendrite growth.Accordingly,single-atom catalysts(SACs),which have ultrahigh catalytic efficiency,tunable coordination configuration,and light weight,have shown huge potential in the field of LSBs to date.This review summarizes the recent research progress of SACs applied as multifunctional components in LSBs.The design principles and typical synthetic strategies of SACs toward effective Li–S chemistry as well as the working mechanism promoting sulfur conversion reactions,inhibiting the lithium polysulfide shuttle effect,and regulating Li+nucleation are comprehensively illustrated.Potential future directions in terms of research on SACs for the realization of commercially viable LSBs are also outlined.
基金supported by the National Natural Science Foundation of China,China(52203066,51973157,51673148 and 51678411)the Science and Technology Plans of Tianjin,China(19PTSYJC00010)+3 种基金China Postdoctoral Science Foundation Grant,China(2019M651047)the Tianjin Research Innovation Project for Postgraduate Students,China(2020YJSB062)the Tianjin Municipal College Student’Innovation And Entrepreneurship Training Program,China(202110058052)the National Innovation and Entrepreneurship Training Program for College Students,China(202110058017)。
文摘Non-renewable fossil fuels have led to serious problems such as global warming,environmental pollution,etc.Oxygen electrocatalysis including oxygen reduction reaction(ORR)and oxygen evolution reaction(OER)plays a central role in clean energy conversion,enabling a number of sustainable processes for future air battery technologies.Fluorine,as the most electronegative element(4.0)not only can induce more efficient regulation for the electronic structure,but also can bring more abundant defects and other novel effects in materials selection and preparation for favorable catalysis with respect to the other nonmetal elements.However,an individual and comprehensive overview of fluorine-containing functional materials for oxygen electrocatalysis field is still blank.Therefore,it is very meaningful to review the recent progresses of fluorine-containing oxygen electrocatalysts.In this review,we first systematically summarize the controllable preparation methods and their possible development directions based on fluorine-containing materials from four preparation methods.Due to the strong electron-withdrawing properties of fluorine,its control of the electronic structure can effectively enhance the oxygen electrocatalytic activity of the materials.In addition,the catalytic enhancement effect of fluorine on carbonbased materials also includes the prevent oxidation and the layer peeling,and realizes the precise atomic control.And the catalytic improvement mechanism of fluorine containing metal-based compounds also includes the hydration of metal site,the crystal transformation,and the oxygen vacancy induction.Then,based on their various dimensions(0D–3D),we also have summarized the advantages of different morphologies on oxygen electrocatalytic performances.Finally,the prospects and possible future researching direction of F-containing oxygen electrocatalysts are presented(e.g.,novel pathways,advanced methods for measurement and simulation,field assistance and multi-functions).The review is considered valuable and helpful in exploring the novel designs and mechanism analyses of advanced fluorine-containing electrocatalysts.
