Boron phosphide(BP)has gained significant research attention due to its unique photoelectric and mechanical properties.In this work,we investigated the stability of BP under high pressure using x-ray diffraction and s...Boron phosphide(BP)has gained significant research attention due to its unique photoelectric and mechanical properties.In this work,we investigated the stability of BP under high pressure using x-ray diffraction and scanning electron microscope.The phase diagram of BP was explored in both B-rich and P-rich environments,revealing crucial insight into its behavior at 5.0 GPa.Additionally,we measured the melting curve of BP from 8.0 GPa to 15.0 GPa.Our findings indicate that the stability of BP under high pressure is improved within B-rich and P-rich environments.Furthermore,we report a remarkable observation of melting curve frustration at 10.0 GPa.This study will enhance our understanding of stability of BP under high pressure,shedding light on its potential application in semiconductor,thermal,and light-transmitting devices.展开更多
The effects of projectile/target impedance matching and projectile shape on energy,momentum transfer and projectile melting during collisions are investigated by numerical simulation.By comparing the computation resul...The effects of projectile/target impedance matching and projectile shape on energy,momentum transfer and projectile melting during collisions are investigated by numerical simulation.By comparing the computation results with the experimental results,the correctness of the calculation and the statistical method of momentum transfer coefficient is verified.Different shapes of aluminum,copper and heavy tungsten alloy projectiles striking aluminum,basalt,and pumice target for impacts up to 10 km/s are simulated.The influence mechanism of the shape of the projectile and projectile/target density on the momentum transfer was obtained.With an increase in projectile density and length-diameter ratio,the energy transfer time between the projectile and targets is prolonged.The projectile decelerates slowly,resulting in a larger cratering depth.The energy consumed by the projectile in the excavation stage increased,resulting in lower mass-velocity of ejecta and momentum transfer coefficient.The numerical simulation results demonstrated that for different projectile/target combinations,the higher the wave impedance of the projectile,the higher the initial phase transition velocity and the smaller the mass of phase transition.The results can provide theoretical guidance for kinetic impactor design and material selection.展开更多
The aerospace and military sectors have widely used AA7075, a type of 7075 aluminum alloy, due to its exceptional mechanical performance. Selective laser melting (SLM) is a highly effective method for producing intric...The aerospace and military sectors have widely used AA7075, a type of 7075 aluminum alloy, due to its exceptional mechanical performance. Selective laser melting (SLM) is a highly effective method for producing intricate metallic components, particularly in the case of aluminum alloys like Al-Si-Mg. Nevertheless, the production of high-strength AA7075 by SLM is challenging because of its susceptibility to heat cracking and elemental vaporization. In this study, AA7075 powders were mechanically mixed with SiC and TiC particles. Subsequently, this new type of AA7075 powder was effectively utilized in green laser printing to create solid components with fine-grain strengthening microstructures consisting of equiaxial grains. These as-printed parts exhibit a tensile strength of up to 350 MPa and a ductility exceeding 2.1%. Hardness also increases with the increasing content of mixed powder, highlighting the essential role of SiC and TiC in SLM for improved hardness and tensile strength performance. .展开更多
Cenozoic potassic-ultrapotassic igneous rocks are widespread in the southeastern Tibetan Plateau.Their petrogenesis and magmatic processes remain subject to debate in spite of numerous publications.Almost all of the C...Cenozoic potassic-ultrapotassic igneous rocks are widespread in the southeastern Tibetan Plateau.Their petrogenesis and magmatic processes remain subject to debate in spite of numerous publications.Almost all of the Cenozoic extrusive and intrusive rocks in the Yao’an area,western Yunnan Province,SW China,are geochemically shoshonitic,collectively termed here the Yao’an Shoshonitic Complex(YSC).The YSC is located in the(south)easternmost part of the ENE-WSW-trending,~550 km-long and~250 km-wide Cenozoic magmatic zone;the latter separates the orthogonal and oblique collision belts of the India-Eurasia collision orogen.Previously published geochronological and thermochronological data revealed that the rocks of the YSC were emplaced over a short timespan of 34-32 Ma.This and our new data suggest that the primary magma of the YSC likely was formed by partial melting of ancient continental lithospheric mantle beneath the Yangtze Block.This part of the continental lithospheric mantle had likely not been modified by any oceanic subduction.Fractionation crystallization of an Mg-and Ca-bearing mineral and TiFe oxides during the magmatic evolution probably account for the variable lithologies of the YSC.展开更多
The Cenozoic Himalayan leucogranite-pegmatite belt has been a hotspot for rare metal exploration in recent years.To determine the genesis of the pegmatite in the Himalayan region and its relationship with the Greater ...The Cenozoic Himalayan leucogranite-pegmatite belt has been a hotspot for rare metal exploration in recent years.To determine the genesis of the pegmatite in the Himalayan region and its relationship with the Greater Himalayan Crystalline Complex(GHC),the Gyirong pegmatite in southern Tibet was chosen for geochronological and geochemical studies.The dating analyses indicate that the U-Th-Pb ages of zircon,monazite,and xenotime exhibit large variations(38.6‒16.1 Ma),with the weighted average value of the four youngest points is 16.5±0.3 Ma,which indicates that the final stage of crystallization of the melt occurred in the Miocene.The age of the muscovite Ar-Ar inverse isochron is 15.2±0.4 Ma,which is slightly later than the intrusion age,showing that a cooling process associated with rapid denudation occurred at 16‒15 Ma.TheεHf(t)values of the Cenozoic anatectic zircons cluster between−12 and−9 with an average of−11.4.The Gyirong pegmatite shows high contents of Si,Al,and K,a high Al saturation index,and low contents of Na,Ca,Fe,Mn,P,Mg,and Ti.Overall,the Gyirong pegmatite is enriched in Rb,Cs,U,K,Th and Pb and depleted in Nb,Ta,Zr,Ti,Eu,Sr,and Ba.The samples show a high 87Sr/86Sr(16 Ma)ratio of ca.0.762 and a lowεNd(16 Ma)value of−16.0.The calculated average initial values of 208Pb/204Pb(16 Ma),207Pb/204Pb(16 Ma)and 206Pb/204Pb(16 Ma)of the whole rock are 39.72,15.79 and 19.56,respectively.The Sr-Nd-Pb-Hf isotopic characteristics of the Gyirong pegmatite are consistent with those of the GHC.This study concludes that the Gyirong pegmatite represents a typical crustal‒derived anatectic pegmatite with low metallogenic potential for rare metals.The Gyirong pegmatite records the long‒term metamorphism and partial melting process of the GHC,and reflects the crustal thickening caused by thrust compression at 39‒29 Ma and the crustal thinning induced by extensional decompression during 28‒15 Ma.展开更多
To enrich material types applied to additive manufacturing and enlarge application scope of additive manufacturing in conformal cooling tools,M2 high-speed steel specimens were fabricated by selective laser melting(SL...To enrich material types applied to additive manufacturing and enlarge application scope of additive manufacturing in conformal cooling tools,M2 high-speed steel specimens were fabricated by selective laser melting(SLM).Effects of SLM parameters on the microstructure and mechanical properties of M2 high-speed steel were investigated.The results showed that substrate temperature and energy density had significant influence on the densification process of materials and defects control.Models to evaluate the effect of substrate temperature and energy density on hardness were studied.The optimized process parameters,laser power,scan speed,scan distance,and substrate temperature,for fabricated M2 are 220 W,960 mm/s,0.06 mm,and 200℃,respectively.Based on this,the hardness and tensile strength reached 60 HRC and 1000 MPa,respectively.Interlaminar crack formation and suppression mechanism and the relationship between temperature gradient and thermal stress were illustrated.The inhibition effect of substrate temperature on the cracks generated by residual stresses was also explained.AM showed great application potential in the field of special conformal cooling cutting tool preparation.展开更多
The metallurgical properties of the CaO–SiO_(2)–Al_(2)O_(3)–4.6wt%Mg O–Fe_(2)O_(3)slag system,formed by the co-treatment process of spent automotive catalyst(SAC)and copper-bearing electroplating sludge(CBES),were...The metallurgical properties of the CaO–SiO_(2)–Al_(2)O_(3)–4.6wt%Mg O–Fe_(2)O_(3)slag system,formed by the co-treatment process of spent automotive catalyst(SAC)and copper-bearing electroplating sludge(CBES),were studied systematically in this paper.The slag structure,melting temperature,and viscous characteristics were investigated by Fourier transform infrared(FTIR)spectroscopy,Raman spectroscopy,Fact Sage calculation,and viscosity measurements.Experimental results show that the increase of Fe_(2)O_(3)content(3.8wt%–16.6wt%),the mass ratio of CaO/SiO_(2)(m(CaO)/m(SiO_(2)),0.5–1.3),and the mass ratio of SiO_(2)/Al_(2)O_(3)(m(SiO_(2))/m(Al_(2)O_(3)),1.0–5.0)can promote the depolymerization of silicate network,and the presence of a large amount of Fe_(2)O_(3)in form of tetrahedral and octahedral units ensures the charge compensation of Al^(3+)ions and makes Al_(2)O_(3)only behave as an acid oxide.Thermodynamic calculation and viscosity measurements show that with the increase of Fe_(2)O_(3)content,m(Ca O)/m(SiO_(2)),and m(SiO_(2))/m(Al_(2)O_(3)),the depolymerization of silicate network structure and low-melting-point phase transformation first occur within the slag,leading to the decrease in melting point and viscosity of the slag,while further increase causes the formation of high-melting-point phase and a resultant re-increase in viscosity and melting point.Based on experimental analysis,the preferred slag composition with low polymerization degree,viscosity,and melting point is as follows:Fe_(2)O_(3)content of 10.2wt%–13.4wt%,m(CaO)/m(SiO_(2))of 0.7–0.9 and m(SiO_(2))/m(Al_(2)O_(3))of 3.0–4.0.This work provides a theoretical support for slag design in co-smelting process of SAC and CBES.展开更多
The evolution of microstructure and formation mechanism of incipient melting microstructure of DD5 single crystal superalloy during solution heat treatment were studied by scanning electron microscopy(SEM),electron pr...The evolution of microstructure and formation mechanism of incipient melting microstructure of DD5 single crystal superalloy during solution heat treatment were studied by scanning electron microscopy(SEM),electron probe microanalysis(EPMA),and energy dispersive spectroscopy(EDS).The solidus and liquidus of single crystal alloy were obtained by differential scanning calorimetry(DSC).Results show that the mosaic-like eutectic and fan-like eutectic are dissolved at first,and the coarseγ'phase is dissolved later during the solution heat treatment of 1,390°C/2 h+1,310°C/4 h+1,320°C/10 h+air cooling(AC).The composition segregations of Al,Ta,W and Re are 0.99,0.96,1.04 and 1.16,respectively,which close to 1.The incipient melting is caused by the low local temperature of the alloy,and the micropore region with a lower melting point is the preferred position for incipient melting.展开更多
This study is concerned with the surface integrity of Inconel 738LC parts manufactured by selective laser melting(SLM)followed by high-speed milling(HSM).In the investigation process of surface integrity,the study emp...This study is concerned with the surface integrity of Inconel 738LC parts manufactured by selective laser melting(SLM)followed by high-speed milling(HSM).In the investigation process of surface integrity,the study employs ultradepth three-dimensional microscopy,laser scanning confocal microscopy,scanning electron microscopy,electron backscatter diffractometry,and energy dispersive spectroscopy to characterize the evolution of material microstructure,work hardening,residual stress coupling,and anisotropic effect of the building direction on surface integrity of the samples.The results show that SLM/HSM hybrid manufacturing can be an effective method to obtain better surface quality with a thinner machining metamorphic layer.High-speed machining is adopted to reduce cutting force and suppress machining heat,which is an effective way to produce better surface mechanical properties during the SLM/HSM hybrid manufacturing process.In general,high-speed milling of the SLM-built Inconel 738LC samples offers better surface integrity,compared to simplex additive manufacturing or casting.展开更多
The Ross-Amundsen sector is experiencing an accelerating warming trend and a more intensive advective influx of marine air streams.As a result,massive surface melting events of the ice shelf are occurring more frequen...The Ross-Amundsen sector is experiencing an accelerating warming trend and a more intensive advective influx of marine air streams.As a result,massive surface melting events of the ice shelf are occurring more frequently,which puts the West Antarctica Ice Sheet at greater risk of degradation.This study shows the connection between surface melting and the prominent intrusion of warm and humid air flows from lower latitudes.By applying the Climate Feedback-Response Analysis Method(CFRAM),the temporal surge of the downward longwave(LW)fluxes over the surface of the Ross Ice Shelf(RIS)and adjacent regions are identified for four historically massive RIS surface melting events.The melting events are decomposed to identify which physical mechanisms are the main contributors.We found that intrusions of warm and humid airflow from lower latitudes are conducive to warm air temperature and water vapor anomalies,as well as cloud development.These changes exert a combined impact on the abnormal enhancement of the downward LW surface radiative fluxes,significantly contributing to surface warming and the resultant massive melting of ice.展开更多
The use of carbon-fiber heating cables(CFHC)to achieve effective melting of snow and ice deposited on roads is a method used worldwide.In this study,tensile and compressive tests have been conducted to analyze the mech...The use of carbon-fiber heating cables(CFHC)to achieve effective melting of snow and ice deposited on roads is a method used worldwide.In this study,tensile and compressive tests have been conducted to analyze the mechan-ical properties of the CFHC and assess whether the maximum tensile and compressive strengths can meet the pavement design specifications.In order to study the aging produced by multiple cycles of heating and cooling,in particular,the CFHC was repeatedly heated in a cold chamber with an ambient temperature ranging between-20℃ and+40℃.Moreover,to evaluate how the strength of the pavement is affected by its presence,the CFHC was embedded at different depths and concrete blocks with different curing ages were subjected to relevant com-pression and splitting tensile tests.Numerical simulations based on the ANSYS software have also been performed and compared with the outcomes of the static loading tests.The results show that the CFHC embedded in the concrete does not affect the compressive splitting tensile strengths of the pavement.Overall,the CFHC meets the conditions required for continued use in road ice melting applications.展开更多
Due to the layer-by-layer manufacturing characteristics,metallurgical process of selective laser melting(SLM)is inherently dif-ferent in the building direction because of varying conditions,thereby resulting inter-lay...Due to the layer-by-layer manufacturing characteristics,metallurgical process of selective laser melting(SLM)is inherently dif-ferent in the building direction because of varying conditions,thereby resulting inter-layer heterogeneity.To mitigate such anisotropy,it is of great significance to understand the effects of processing parameters on the property evolution and thus metallurgy of fabrication process.This research proposes one-factor-at-a-time experiment to investigate the influences of laser power and scanning speed on the surface qual-ity,microstructures and mechanical properties of selective laser melted Ti-6Al-4V parts.Surface quality is assessed by roughness around the printings while mechanical properties are evaluated through microhardness and tensile strengths.Phases in microstructure are quantified by XRD to correlate with mechanical properties.Fracture morphology is analyzed to understand the effect of defects and microstructure on mechanical performance.The optimized parameter corresponding to best surface quality and mechanical properties has been found respect-ively in laser power of 190 W and scanning speed of 800 mm/s.After optimization,surface roughness has decreased by 44.47%for upper surface.Yielding strength,tensile strength and elongation rate have improved by 13.17%,43.34%and 64.51%,respectively,with similar hardness and Young’s modulus.In addition,heterogeneity of mechanical properties has great improvement by a range of 31.63%-92.68%.展开更多
The objective of this work is to examine how temperature-dependent thermal conductivity and concentration-dependent molecular diffusion affect Reiner-Philippoff nanofluid flow past a nonlinear stretching sheet. At the...The objective of this work is to examine how temperature-dependent thermal conductivity and concentration-dependent molecular diffusion affect Reiner-Philippoff nanofluid flow past a nonlinear stretching sheet. At the interface of the elongated surface zero-mass flux and melting heat condition are incorporated. The formulated mathematical problem is simplified by implementing suitable similarity transformations. For the numerical solution bvp4c is utilized. The parameters emerging in the model are discussed versus allied profiles through graphical illustrations. It is perceived that the velocity of the fluid decays on incrementing the Bingham number. The gyrotactic microorganism profile declines on amplifying the Peclet number. The validation of the proposed model is also added to this study. .展开更多
A study on the melting and viscosity properties of the chromium-containing high-titanium melting slag(CaO–SiO2–MgO–Al2O3–TiO2–Cr2O3) with TiO2 contents ranging from 38.63 wt% to 42.63 wt% was conducted. The melti...A study on the melting and viscosity properties of the chromium-containing high-titanium melting slag(CaO–SiO2–MgO–Al2O3–TiO2–Cr2O3) with TiO2 contents ranging from 38.63 wt% to 42.63 wt% was conducted. The melting properties were investigated with a meltingpoint apparatus, and viscosity was measured using the rotating cylinder method. The FactSage 7.1 software and X-ray diffraction, in combination with scanning electron microscopy–energy-dispersive spectroscopy(SEM–EDS), were used to characterize the phase equilibrium and microstructure of chromium-containing high-titanium melting slags. The results indicated that an increase in the TiO2 content led to a decrease in the viscosity of the chromium-containing high-titanium melting slag. In addition, the softening temperature, hemispheric temperature, and flowing temperature decreased with increasing TiO2 content. The amount of crystallized anosovite and sphene phases gradually increased with increasing TiO2 content, whereas the amount of perovskite phase decreased. SEM observations revealed that the distribution of the anosovite phase was dominantly influenced by TiO2.展开更多
Large-size primary MC carbides can significantly reduce the performance of M2 high-speed steel.To better control the morphology and size of primary MC carbides,the effect of melting rate on microsegregation and primar...Large-size primary MC carbides can significantly reduce the performance of M2 high-speed steel.To better control the morphology and size of primary MC carbides,the effect of melting rate on microsegregation and primary MC carbides of M2 steel during electroslag remelting was investigated.When the melting rate is decreased from 2 kg·min^(-1) to 0.8 kg·min^(-1),the columnar dendrites are gradually coarsened,and the extent of segregation of Mo and V is alleviated,while the segregation of Cr becomes severe.At 2 kg·min^(-1),the number of primary MC carbides per unit area with the sizes in the range of 2 μm to 6 μm accounts for about 75% of all MC carbides,while the carbides are mainly concentrated on the size larger than 8 μm at 0.8 kg·min^(-1).Thermodynamic calculations based on the Clyne-Kurz (simplified to C-K) model shows that MC carbide can be precipitated in the final solidification stage and a smaller secondary dendrite arm spacing caused by higher melting rate (2 kg·min^(-1) in this experiment) facilitates the refinement of primary MC carbides.展开更多
Electron beam selective melting(EBM)and selective laser melting(SLM)are regarded as significant manufacturing processes for near-net-shaped Ti6Al4V components.Generally,in the conventional EBM process,preheating is ne...Electron beam selective melting(EBM)and selective laser melting(SLM)are regarded as significant manufacturing processes for near-net-shaped Ti6Al4V components.Generally,in the conventional EBM process,preheating is necessitated to avoid"smoke"caused by the charging of electrons.In the conventional SLM process,laser as an energy source without the risk of"smoke"can be employed to melt metal powder at low temperatures.However,because of the low absorption rate of laser,the powder bed temperature cannot reach a high level.It is difficult to obtain as-built TiAl4V with favorable comprehensive properties via conventional EBM or SLM.Hence,two types of electron beam and laser hybrid preheating(EB-LHP)combined with selective melting strategies are proposed.Using laser to preheat powder allows EBM to be performed at a low powder bed temperature(EBM-LT),whereas using an electron beam to preheat powder allows SLM to be performed at a high powder bed temperature(SLM-HT).Ti6Al4V samples are fabricated using two different manufacturing strategies(i.e.,EBM-LT and SLM-HT)and two conventional processes,i.e.,EBM at a high powder bed temperature(EBM-HT)and SLM at a low powder bed temperature(SLM-LT).The temperature-dependent surface quality,microstructure,density,and mechanical properties of the as-built Ti6Al4V samples are characterized and compared.Results show that EBM-LT Ti6Al4V exhibits a higher ultimate tensile strength(981±43 MPa)and a lower elongation(12.2%±2.3%)than EBM-HT Ti6Al4V owing to the presence ofα′martensite.The SLM-HT Ti6Al4V possesses the highest ultimate tensile strength(1,059±62 MPa)and an elongation(14.8%±4.0%)comparable to that of the EBM-HT Ti6Al4V(16.6%±1.2%).展开更多
Re-melting process has been utilized to mitigate the residual stress level in the selective laser melting(SLM)process in recent years.However,the complex consolidation mechanism of powder and the different material be...Re-melting process has been utilized to mitigate the residual stress level in the selective laser melting(SLM)process in recent years.However,the complex consolidation mechanism of powder and the different material behavior after the first laser melting hinder the direct implementation of the re-melting process.In this work,the effects of re-melting on the temperature and residual stress evolution in the SLM process are investigated using a thermo-mechanically coupled finite element model.The degree of consolidation is incorporated in the energy balance equation based on the thermodynamically-consistent phase-field approach.The drastic change of material properties due to the variation of temperature and material state is also considered.Using the proposed simulation framework,the single-track scanning is simulated first to predict the melt pool dimension and validate the proposed model with the existing experimental data.The obtained thermal histories reveal that the highest cooling rate is observed at the end of the local solidification time which acts as an important indicator for the alleviation of temperature gradient.Then,the scanning of a whole single layer that consists of multiple tracks is simulated to observe the stress evolution with several re-melting processes.After the full melting of powder material in the first scanning process,the increase of residual stress level is observed with one remelting cycle.Moreover,the predicted stress level with the re-melting process shows the variation trend attributable to the accumulated heat in the tracks.The numerical issues and the detailed implementation process are also introduced in this paper.展开更多
Two-dimensional(2D)melting is a fundamental research topic in condensed matter physics,which can also provide guidance on fabricating new functional materials.Nevertheless,our understanding of 2D melting is still far ...Two-dimensional(2D)melting is a fundamental research topic in condensed matter physics,which can also provide guidance on fabricating new functional materials.Nevertheless,our understanding of 2D melting is still far from being complete due to existence of possible complicate transition mechanisms and absence of effective analysis methods.Here,using Monte Carlo simulations,we investigate 2D melting of 60°rhombs which melt from two different surface-fullycoverable crystals,a complex hexagonal crystal(cHX)whose primitive cell contains three rhombs,and a simple rhombic crystal(RB)whose primitive cell contains one rhomb.The melting of both crystals shows a sequence of solid,hexatic in molecular orientation(Hmo),and isotropic phases which obey the Berezinskii-Kosterlitz-Thouless-Halperin-Nelson-Young(BKTHNY)theory.However,local polymorphic configuration(LPC)based analysis reveals different melting mechanisms:the cHX-Hmotransition is driven by the proliferation of point-like defects during which defect-associated LPCs are generated sequentially,whereas the RB-Hmotransition is driven by line defects where defect-associated LPCs are generated simultaneously.These differences result in the observed different solid-Hmotransition points which areφA=0.812 for the cHX-HmoandφA=0.828 for the RB-Hmo.Our work will shed light on the initial-crystal-dependence of 2D melting behavior.展开更多
In the electroslag remelting process, the electrode molten state is a critical factor determining the ingot quality, while the electrode immersion depth and melting rate are key factors for the stability of the electr...In the electroslag remelting process, the electrode molten state is a critical factor determining the ingot quality, while the electrode immersion depth and melting rate are key factors for the stability of the electroslag re-melting process. Studies were carried out to investigate the microscopic and macroscopic effects of electrode immersion depth and melting rate on the potential distribution and heat density in the slag bath, and on the depth and shape of the molten bath. Based on the finite element method and the numerical solution method, the effect of the electrode immersion depth on the slag bath heat density was researched; the relationship between the electrode immersion depth and the slag resistance was obtained; and the unsteady-state model of the solidification process of the re-melting ingot was solved using the finite difference method. The mathematical model and physical model of the electrode melting process were established and solved; and the corresponding curves between the electrode molten-state and slag-bath physical parameters were obtained. The experimental results verified the simulated results studied in this paper.展开更多
New monazite U\|Pb geochronological data from the Everest region suggest that 20～25Ma elapsed between the initial India—Asia collision and kyanite\|sillimanite grade metamorphism. Our results indicate a two\|phase m...New monazite U\|Pb geochronological data from the Everest region suggest that 20～25Ma elapsed between the initial India—Asia collision and kyanite\|sillimanite grade metamorphism. Our results indicate a two\|phase metamorphic history, with peak Barrovian metamorphism at (32 2±0 4)Ma and a later high\|temperature, low\|pressure event (620℃, 400MPa) at (22 7±0 2)Ma.. Emplacement and crystallization of the Everest granite subsequently occurred at 20 5～21 3Ma. The monazite crystallization ages that differ by 10Ma are recorded in two structurally adjacent rocks of different lithology, which have the same post collisional p—T history.. Scanning electron microscopy reveals that the younger monazite is elaborately shaped and grew in close association with apatite at grain boundaries and triple junctions, suggesting that growth was stimulated by a change in the fluid regime. The older monazite is euhedral, is not associated with apatite, and is commonly armoured within silicate minerals. During the low\|pressure metamorphic event, the armouring protected the older monazites, and a lack of excess apatite in this sample prevented new growth. Textural relationships suggest that apatite is one of the necessary monazite\|producing reactants, and spots within monazite that are rich in Ca, Fe, Al and Si suggest that allanite acted as a preexisting rare earth element host. We propose a simplified reaction for monazite crystallization based on this evidence.展开更多
基金Project supported by the National Natural Science Foundation of China (Grant No.12074273)the Sichuan Science and Technology Program (Grant No.2022NSFSC1810)。
文摘Boron phosphide(BP)has gained significant research attention due to its unique photoelectric and mechanical properties.In this work,we investigated the stability of BP under high pressure using x-ray diffraction and scanning electron microscope.The phase diagram of BP was explored in both B-rich and P-rich environments,revealing crucial insight into its behavior at 5.0 GPa.Additionally,we measured the melting curve of BP from 8.0 GPa to 15.0 GPa.Our findings indicate that the stability of BP under high pressure is improved within B-rich and P-rich environments.Furthermore,we report a remarkable observation of melting curve frustration at 10.0 GPa.This study will enhance our understanding of stability of BP under high pressure,shedding light on its potential application in semiconductor,thermal,and light-transmitting devices.
基金the National Natural Science Foundation of China(Grant Nos.62227901,12202068)the Civil Aerospace Pre-research Project(Grant No.D020304).
文摘The effects of projectile/target impedance matching and projectile shape on energy,momentum transfer and projectile melting during collisions are investigated by numerical simulation.By comparing the computation results with the experimental results,the correctness of the calculation and the statistical method of momentum transfer coefficient is verified.Different shapes of aluminum,copper and heavy tungsten alloy projectiles striking aluminum,basalt,and pumice target for impacts up to 10 km/s are simulated.The influence mechanism of the shape of the projectile and projectile/target density on the momentum transfer was obtained.With an increase in projectile density and length-diameter ratio,the energy transfer time between the projectile and targets is prolonged.The projectile decelerates slowly,resulting in a larger cratering depth.The energy consumed by the projectile in the excavation stage increased,resulting in lower mass-velocity of ejecta and momentum transfer coefficient.The numerical simulation results demonstrated that for different projectile/target combinations,the higher the wave impedance of the projectile,the higher the initial phase transition velocity and the smaller the mass of phase transition.The results can provide theoretical guidance for kinetic impactor design and material selection.
文摘The aerospace and military sectors have widely used AA7075, a type of 7075 aluminum alloy, due to its exceptional mechanical performance. Selective laser melting (SLM) is a highly effective method for producing intricate metallic components, particularly in the case of aluminum alloys like Al-Si-Mg. Nevertheless, the production of high-strength AA7075 by SLM is challenging because of its susceptibility to heat cracking and elemental vaporization. In this study, AA7075 powders were mechanically mixed with SiC and TiC particles. Subsequently, this new type of AA7075 powder was effectively utilized in green laser printing to create solid components with fine-grain strengthening microstructures consisting of equiaxial grains. These as-printed parts exhibit a tensile strength of up to 350 MPa and a ductility exceeding 2.1%. Hardness also increases with the increasing content of mixed powder, highlighting the essential role of SiC and TiC in SLM for improved hardness and tensile strength performance. .
基金financially supported by the Ministry of Sciences and Technology of China(Grant No.2022YFF0800901)the Natural Science Foundation of China(Grant Nos.92055206 and 42163007)。
文摘Cenozoic potassic-ultrapotassic igneous rocks are widespread in the southeastern Tibetan Plateau.Their petrogenesis and magmatic processes remain subject to debate in spite of numerous publications.Almost all of the Cenozoic extrusive and intrusive rocks in the Yao’an area,western Yunnan Province,SW China,are geochemically shoshonitic,collectively termed here the Yao’an Shoshonitic Complex(YSC).The YSC is located in the(south)easternmost part of the ENE-WSW-trending,~550 km-long and~250 km-wide Cenozoic magmatic zone;the latter separates the orthogonal and oblique collision belts of the India-Eurasia collision orogen.Previously published geochronological and thermochronological data revealed that the rocks of the YSC were emplaced over a short timespan of 34-32 Ma.This and our new data suggest that the primary magma of the YSC likely was formed by partial melting of ancient continental lithospheric mantle beneath the Yangtze Block.This part of the continental lithospheric mantle had likely not been modified by any oceanic subduction.Fractionation crystallization of an Mg-and Ca-bearing mineral and TiFe oxides during the magmatic evolution probably account for the variable lithologies of the YSC.
基金sponsored by the National Key R&D Programme of China(2021YFC2901803)National Natural Science Foundation of China(92055314 and 41802095)+2 种基金the China Geological Survey(DD20230049 and DD20220983)is a contribution to the International Geoscience Programme(IGCP-741)Academician Bao-jun Liu Foundation of Southwest Geological Science and Technology Innovation Center.
文摘The Cenozoic Himalayan leucogranite-pegmatite belt has been a hotspot for rare metal exploration in recent years.To determine the genesis of the pegmatite in the Himalayan region and its relationship with the Greater Himalayan Crystalline Complex(GHC),the Gyirong pegmatite in southern Tibet was chosen for geochronological and geochemical studies.The dating analyses indicate that the U-Th-Pb ages of zircon,monazite,and xenotime exhibit large variations(38.6‒16.1 Ma),with the weighted average value of the four youngest points is 16.5±0.3 Ma,which indicates that the final stage of crystallization of the melt occurred in the Miocene.The age of the muscovite Ar-Ar inverse isochron is 15.2±0.4 Ma,which is slightly later than the intrusion age,showing that a cooling process associated with rapid denudation occurred at 16‒15 Ma.TheεHf(t)values of the Cenozoic anatectic zircons cluster between−12 and−9 with an average of−11.4.The Gyirong pegmatite shows high contents of Si,Al,and K,a high Al saturation index,and low contents of Na,Ca,Fe,Mn,P,Mg,and Ti.Overall,the Gyirong pegmatite is enriched in Rb,Cs,U,K,Th and Pb and depleted in Nb,Ta,Zr,Ti,Eu,Sr,and Ba.The samples show a high 87Sr/86Sr(16 Ma)ratio of ca.0.762 and a lowεNd(16 Ma)value of−16.0.The calculated average initial values of 208Pb/204Pb(16 Ma),207Pb/204Pb(16 Ma)and 206Pb/204Pb(16 Ma)of the whole rock are 39.72,15.79 and 19.56,respectively.The Sr-Nd-Pb-Hf isotopic characteristics of the Gyirong pegmatite are consistent with those of the GHC.This study concludes that the Gyirong pegmatite represents a typical crustal‒derived anatectic pegmatite with low metallogenic potential for rare metals.The Gyirong pegmatite records the long‒term metamorphism and partial melting process of the GHC,and reflects the crustal thickening caused by thrust compression at 39‒29 Ma and the crustal thinning induced by extensional decompression during 28‒15 Ma.
基金Supported by National Natural Science Foundation of China (Grant No.52005154)Hebei Provincial Natural Science Foundation (Grant No.E2020202035)。
文摘To enrich material types applied to additive manufacturing and enlarge application scope of additive manufacturing in conformal cooling tools,M2 high-speed steel specimens were fabricated by selective laser melting(SLM).Effects of SLM parameters on the microstructure and mechanical properties of M2 high-speed steel were investigated.The results showed that substrate temperature and energy density had significant influence on the densification process of materials and defects control.Models to evaluate the effect of substrate temperature and energy density on hardness were studied.The optimized process parameters,laser power,scan speed,scan distance,and substrate temperature,for fabricated M2 are 220 W,960 mm/s,0.06 mm,and 200℃,respectively.Based on this,the hardness and tensile strength reached 60 HRC and 1000 MPa,respectively.Interlaminar crack formation and suppression mechanism and the relationship between temperature gradient and thermal stress were illustrated.The inhibition effect of substrate temperature on the cracks generated by residual stresses was also explained.AM showed great application potential in the field of special conformal cooling cutting tool preparation.
基金financially supported by the Guangzhou Basic and Applied Basic Research Project,China(No.202102020623)the Guangdong Academy of Sciences’Project of Science and Technology Development,China(No.2020 GDASYL-20200103101)+1 种基金the National Key Research and Development Program of China(No.2020YFC1908902)the Natural Science Foundation of Guangdong Province Project,China(No.2020A1515010729)。
文摘The metallurgical properties of the CaO–SiO_(2)–Al_(2)O_(3)–4.6wt%Mg O–Fe_(2)O_(3)slag system,formed by the co-treatment process of spent automotive catalyst(SAC)and copper-bearing electroplating sludge(CBES),were studied systematically in this paper.The slag structure,melting temperature,and viscous characteristics were investigated by Fourier transform infrared(FTIR)spectroscopy,Raman spectroscopy,Fact Sage calculation,and viscosity measurements.Experimental results show that the increase of Fe_(2)O_(3)content(3.8wt%–16.6wt%),the mass ratio of CaO/SiO_(2)(m(CaO)/m(SiO_(2)),0.5–1.3),and the mass ratio of SiO_(2)/Al_(2)O_(3)(m(SiO_(2))/m(Al_(2)O_(3)),1.0–5.0)can promote the depolymerization of silicate network,and the presence of a large amount of Fe_(2)O_(3)in form of tetrahedral and octahedral units ensures the charge compensation of Al^(3+)ions and makes Al_(2)O_(3)only behave as an acid oxide.Thermodynamic calculation and viscosity measurements show that with the increase of Fe_(2)O_(3)content,m(Ca O)/m(SiO_(2)),and m(SiO_(2))/m(Al_(2)O_(3)),the depolymerization of silicate network structure and low-melting-point phase transformation first occur within the slag,leading to the decrease in melting point and viscosity of the slag,while further increase causes the formation of high-melting-point phase and a resultant re-increase in viscosity and melting point.Based on experimental analysis,the preferred slag composition with low polymerization degree,viscosity,and melting point is as follows:Fe_(2)O_(3)content of 10.2wt%–13.4wt%,m(CaO)/m(SiO_(2))of 0.7–0.9 and m(SiO_(2))/m(Al_(2)O_(3))of 3.0–4.0.This work provides a theoretical support for slag design in co-smelting process of SAC and CBES.
基金The authors would like to express their sincere thanks to the financial support from the Key Project of National Natural Science Foundation of China(No.U16642548).
文摘The evolution of microstructure and formation mechanism of incipient melting microstructure of DD5 single crystal superalloy during solution heat treatment were studied by scanning electron microscopy(SEM),electron probe microanalysis(EPMA),and energy dispersive spectroscopy(EDS).The solidus and liquidus of single crystal alloy were obtained by differential scanning calorimetry(DSC).Results show that the mosaic-like eutectic and fan-like eutectic are dissolved at first,and the coarseγ'phase is dissolved later during the solution heat treatment of 1,390°C/2 h+1,310°C/4 h+1,320°C/10 h+air cooling(AC).The composition segregations of Al,Ta,W and Re are 0.99,0.96,1.04 and 1.16,respectively,which close to 1.The incipient melting is caused by the low local temperature of the alloy,and the micropore region with a lower melting point is the preferred position for incipient melting.
基金Shenzhen Municipal Science and Technology Innovation Commission Projects(Grant Nos.Y01336107,JCYJ20180504165824643,GJHZ20180411143506667,JC YJ20170817111811303 and KQTD20190929172505711)。
文摘This study is concerned with the surface integrity of Inconel 738LC parts manufactured by selective laser melting(SLM)followed by high-speed milling(HSM).In the investigation process of surface integrity,the study employs ultradepth three-dimensional microscopy,laser scanning confocal microscopy,scanning electron microscopy,electron backscatter diffractometry,and energy dispersive spectroscopy to characterize the evolution of material microstructure,work hardening,residual stress coupling,and anisotropic effect of the building direction on surface integrity of the samples.The results show that SLM/HSM hybrid manufacturing can be an effective method to obtain better surface quality with a thinner machining metamorphic layer.High-speed machining is adopted to reduce cutting force and suppress machining heat,which is an effective way to produce better surface mechanical properties during the SLM/HSM hybrid manufacturing process.In general,high-speed milling of the SLM-built Inconel 738LC samples offers better surface integrity,compared to simplex additive manufacturing or casting.
基金supported by the National Natural Science Foundation of China (Grant Nos. 42075028 and 42222502)the Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai) (Grant SML2021SP302)
文摘The Ross-Amundsen sector is experiencing an accelerating warming trend and a more intensive advective influx of marine air streams.As a result,massive surface melting events of the ice shelf are occurring more frequently,which puts the West Antarctica Ice Sheet at greater risk of degradation.This study shows the connection between surface melting and the prominent intrusion of warm and humid air flows from lower latitudes.By applying the Climate Feedback-Response Analysis Method(CFRAM),the temporal surge of the downward longwave(LW)fluxes over the surface of the Ross Ice Shelf(RIS)and adjacent regions are identified for four historically massive RIS surface melting events.The melting events are decomposed to identify which physical mechanisms are the main contributors.We found that intrusions of warm and humid airflow from lower latitudes are conducive to warm air temperature and water vapor anomalies,as well as cloud development.These changes exert a combined impact on the abnormal enhancement of the downward LW surface radiative fluxes,significantly contributing to surface warming and the resultant massive melting of ice.
基金The authors have received financial support from the National Natural Science Foundation of China(No.52078194)the Key Research and Development Program of Hubei Province(No.2021BGD015)the Knowledge Innovation Project of Wuhan(No.2022010801010259).
文摘The use of carbon-fiber heating cables(CFHC)to achieve effective melting of snow and ice deposited on roads is a method used worldwide.In this study,tensile and compressive tests have been conducted to analyze the mechan-ical properties of the CFHC and assess whether the maximum tensile and compressive strengths can meet the pavement design specifications.In order to study the aging produced by multiple cycles of heating and cooling,in particular,the CFHC was repeatedly heated in a cold chamber with an ambient temperature ranging between-20℃ and+40℃.Moreover,to evaluate how the strength of the pavement is affected by its presence,the CFHC was embedded at different depths and concrete blocks with different curing ages were subjected to relevant com-pression and splitting tensile tests.Numerical simulations based on the ANSYS software have also been performed and compared with the outcomes of the static loading tests.The results show that the CFHC embedded in the concrete does not affect the compressive splitting tensile strengths of the pavement.Overall,the CFHC meets the conditions required for continued use in road ice melting applications.
基金Project was supported by the Natural Science Foundation of Fujian Province(Grant No.2020J01873)Science and Technology Major Project of Fujian Province(Grant No.2020HZ03018)+1 种基金Fujian Provincial Foreign Cooperation Project of Science and Technology(Grant No.2020I1003)Fujian Provincial Special Project for Marine Economy Development(Grant No.2021-517).
文摘Due to the layer-by-layer manufacturing characteristics,metallurgical process of selective laser melting(SLM)is inherently dif-ferent in the building direction because of varying conditions,thereby resulting inter-layer heterogeneity.To mitigate such anisotropy,it is of great significance to understand the effects of processing parameters on the property evolution and thus metallurgy of fabrication process.This research proposes one-factor-at-a-time experiment to investigate the influences of laser power and scanning speed on the surface qual-ity,microstructures and mechanical properties of selective laser melted Ti-6Al-4V parts.Surface quality is assessed by roughness around the printings while mechanical properties are evaluated through microhardness and tensile strengths.Phases in microstructure are quantified by XRD to correlate with mechanical properties.Fracture morphology is analyzed to understand the effect of defects and microstructure on mechanical performance.The optimized parameter corresponding to best surface quality and mechanical properties has been found respect-ively in laser power of 190 W and scanning speed of 800 mm/s.After optimization,surface roughness has decreased by 44.47%for upper surface.Yielding strength,tensile strength and elongation rate have improved by 13.17%,43.34%and 64.51%,respectively,with similar hardness and Young’s modulus.In addition,heterogeneity of mechanical properties has great improvement by a range of 31.63%-92.68%.
文摘The objective of this work is to examine how temperature-dependent thermal conductivity and concentration-dependent molecular diffusion affect Reiner-Philippoff nanofluid flow past a nonlinear stretching sheet. At the interface of the elongated surface zero-mass flux and melting heat condition are incorporated. The formulated mathematical problem is simplified by implementing suitable similarity transformations. For the numerical solution bvp4c is utilized. The parameters emerging in the model are discussed versus allied profiles through graphical illustrations. It is perceived that the velocity of the fluid decays on incrementing the Bingham number. The gyrotactic microorganism profile declines on amplifying the Peclet number. The validation of the proposed model is also added to this study. .
基金financially supported by the National Natural Science Foundation of China(No.51904066)the Fundamental Research Funds for the Central Universities,China(No.N182503032)+1 种基金the Postdoctoral Foundation of Northeastern University,China(No.20190201)the Postdoctoral International Exchange Program,China(Dispatch Project,20190075)
文摘A study on the melting and viscosity properties of the chromium-containing high-titanium melting slag(CaO–SiO2–MgO–Al2O3–TiO2–Cr2O3) with TiO2 contents ranging from 38.63 wt% to 42.63 wt% was conducted. The melting properties were investigated with a meltingpoint apparatus, and viscosity was measured using the rotating cylinder method. The FactSage 7.1 software and X-ray diffraction, in combination with scanning electron microscopy–energy-dispersive spectroscopy(SEM–EDS), were used to characterize the phase equilibrium and microstructure of chromium-containing high-titanium melting slags. The results indicated that an increase in the TiO2 content led to a decrease in the viscosity of the chromium-containing high-titanium melting slag. In addition, the softening temperature, hemispheric temperature, and flowing temperature decreased with increasing TiO2 content. The amount of crystallized anosovite and sphene phases gradually increased with increasing TiO2 content, whereas the amount of perovskite phase decreased. SEM observations revealed that the distribution of the anosovite phase was dominantly influenced by TiO2.
基金financially supported by the National Natural Science Foundation of China(No.51904087)the Open Project of State Key Laboratory of Advanced Special Steel,Shanghai Key Laboratory of Advanced Ferrometallurgy,Shanghai University(SKLASS 2019-20)+2 种基金the Science and Technology Commission of Shanghai Municipality(No.19DZ2270200)the Natural Science Foundation-Steel and Iron Foundation of Hebei Province(No.E2019202482)Tianjin Science and Technology Project(No.18YFZCGX00220)。
文摘Large-size primary MC carbides can significantly reduce the performance of M2 high-speed steel.To better control the morphology and size of primary MC carbides,the effect of melting rate on microsegregation and primary MC carbides of M2 steel during electroslag remelting was investigated.When the melting rate is decreased from 2 kg·min^(-1) to 0.8 kg·min^(-1),the columnar dendrites are gradually coarsened,and the extent of segregation of Mo and V is alleviated,while the segregation of Cr becomes severe.At 2 kg·min^(-1),the number of primary MC carbides per unit area with the sizes in the range of 2 μm to 6 μm accounts for about 75% of all MC carbides,while the carbides are mainly concentrated on the size larger than 8 μm at 0.8 kg·min^(-1).Thermodynamic calculations based on the Clyne-Kurz (simplified to C-K) model shows that MC carbide can be precipitated in the final solidification stage and a smaller secondary dendrite arm spacing caused by higher melting rate (2 kg·min^(-1) in this experiment) facilitates the refinement of primary MC carbides.
基金the National Key R&D Program(2018YFB1105200)111 Project(B17026)Open Fund of State Key Laboratory of Advanced Forming Technology and Equipment(SKL2019006)。
文摘Electron beam selective melting(EBM)and selective laser melting(SLM)are regarded as significant manufacturing processes for near-net-shaped Ti6Al4V components.Generally,in the conventional EBM process,preheating is necessitated to avoid"smoke"caused by the charging of electrons.In the conventional SLM process,laser as an energy source without the risk of"smoke"can be employed to melt metal powder at low temperatures.However,because of the low absorption rate of laser,the powder bed temperature cannot reach a high level.It is difficult to obtain as-built TiAl4V with favorable comprehensive properties via conventional EBM or SLM.Hence,two types of electron beam and laser hybrid preheating(EB-LHP)combined with selective melting strategies are proposed.Using laser to preheat powder allows EBM to be performed at a low powder bed temperature(EBM-LT),whereas using an electron beam to preheat powder allows SLM to be performed at a high powder bed temperature(SLM-HT).Ti6Al4V samples are fabricated using two different manufacturing strategies(i.e.,EBM-LT and SLM-HT)and two conventional processes,i.e.,EBM at a high powder bed temperature(EBM-HT)and SLM at a low powder bed temperature(SLM-LT).The temperature-dependent surface quality,microstructure,density,and mechanical properties of the as-built Ti6Al4V samples are characterized and compared.Results show that EBM-LT Ti6Al4V exhibits a higher ultimate tensile strength(981±43 MPa)and a lower elongation(12.2%±2.3%)than EBM-HT Ti6Al4V owing to the presence ofα′martensite.The SLM-HT Ti6Al4V possesses the highest ultimate tensile strength(1,059±62 MPa)and an elongation(14.8%±4.0%)comparable to that of the EBM-HT Ti6Al4V(16.6%±1.2%).
基金the Korea Evaluation Institute of Industrial Technology(KEIT)grant funded by the Korea government(MOTIE,https://itech.keit.re.kr/index.do#00010000)(No.20004662,Industrial Technology Innovation Program,Grantee:GJY)Institute of Engineering Research(Grantee:GJY)at Seoul National University(https://www.snu.ac.kr/).The authors are grateful for their supports.
文摘Re-melting process has been utilized to mitigate the residual stress level in the selective laser melting(SLM)process in recent years.However,the complex consolidation mechanism of powder and the different material behavior after the first laser melting hinder the direct implementation of the re-melting process.In this work,the effects of re-melting on the temperature and residual stress evolution in the SLM process are investigated using a thermo-mechanically coupled finite element model.The degree of consolidation is incorporated in the energy balance equation based on the thermodynamically-consistent phase-field approach.The drastic change of material properties due to the variation of temperature and material state is also considered.Using the proposed simulation framework,the single-track scanning is simulated first to predict the melt pool dimension and validate the proposed model with the existing experimental data.The obtained thermal histories reveal that the highest cooling rate is observed at the end of the local solidification time which acts as an important indicator for the alleviation of temperature gradient.Then,the scanning of a whole single layer that consists of multiple tracks is simulated to observe the stress evolution with several re-melting processes.After the full melting of powder material in the first scanning process,the increase of residual stress level is observed with one remelting cycle.Moreover,the predicted stress level with the re-melting process shows the variation trend attributable to the accumulated heat in the tracks.The numerical issues and the detailed implementation process are also introduced in this paper.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11874277,21621004,12104453,and 12090054)the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB33030300)
文摘Two-dimensional(2D)melting is a fundamental research topic in condensed matter physics,which can also provide guidance on fabricating new functional materials.Nevertheless,our understanding of 2D melting is still far from being complete due to existence of possible complicate transition mechanisms and absence of effective analysis methods.Here,using Monte Carlo simulations,we investigate 2D melting of 60°rhombs which melt from two different surface-fullycoverable crystals,a complex hexagonal crystal(cHX)whose primitive cell contains three rhombs,and a simple rhombic crystal(RB)whose primitive cell contains one rhomb.The melting of both crystals shows a sequence of solid,hexatic in molecular orientation(Hmo),and isotropic phases which obey the Berezinskii-Kosterlitz-Thouless-Halperin-Nelson-Young(BKTHNY)theory.However,local polymorphic configuration(LPC)based analysis reveals different melting mechanisms:the cHX-Hmotransition is driven by the proliferation of point-like defects during which defect-associated LPCs are generated sequentially,whereas the RB-Hmotransition is driven by line defects where defect-associated LPCs are generated simultaneously.These differences result in the observed different solid-Hmotransition points which areφA=0.812 for the cHX-HmoandφA=0.828 for the RB-Hmo.Our work will shed light on the initial-crystal-dependence of 2D melting behavior.
基金financially supported by the Machine Tools Major Project of the Eleventh Five-Year Plan of China(grant No.2009ZX04006-032)
文摘In the electroslag remelting process, the electrode molten state is a critical factor determining the ingot quality, while the electrode immersion depth and melting rate are key factors for the stability of the electroslag re-melting process. Studies were carried out to investigate the microscopic and macroscopic effects of electrode immersion depth and melting rate on the potential distribution and heat density in the slag bath, and on the depth and shape of the molten bath. Based on the finite element method and the numerical solution method, the effect of the electrode immersion depth on the slag bath heat density was researched; the relationship between the electrode immersion depth and the slag resistance was obtained; and the unsteady-state model of the solidification process of the re-melting ingot was solved using the finite difference method. The mathematical model and physical model of the electrode melting process were established and solved; and the corresponding curves between the electrode molten-state and slag-bath physical parameters were obtained. The experimental results verified the simulated results studied in this paper.
文摘New monazite U\|Pb geochronological data from the Everest region suggest that 20～25Ma elapsed between the initial India—Asia collision and kyanite\|sillimanite grade metamorphism. Our results indicate a two\|phase metamorphic history, with peak Barrovian metamorphism at (32 2±0 4)Ma and a later high\|temperature, low\|pressure event (620℃, 400MPa) at (22 7±0 2)Ma.. Emplacement and crystallization of the Everest granite subsequently occurred at 20 5～21 3Ma. The monazite crystallization ages that differ by 10Ma are recorded in two structurally adjacent rocks of different lithology, which have the same post collisional p—T history.. Scanning electron microscopy reveals that the younger monazite is elaborately shaped and grew in close association with apatite at grain boundaries and triple junctions, suggesting that growth was stimulated by a change in the fluid regime. The older monazite is euhedral, is not associated with apatite, and is commonly armoured within silicate minerals. During the low\|pressure metamorphic event, the armouring protected the older monazites, and a lack of excess apatite in this sample prevented new growth. Textural relationships suggest that apatite is one of the necessary monazite\|producing reactants, and spots within monazite that are rich in Ca, Fe, Al and Si suggest that allanite acted as a preexisting rare earth element host. We propose a simplified reaction for monazite crystallization based on this evidence.
