We present data pertaining to mineral assemblages and composition of the Central Indian Ocean Basin(CIOB)pumices.Eight groups of pumices were identified considering the presence of phenocrysts of plagioclase,clinopyro...We present data pertaining to mineral assemblages and composition of the Central Indian Ocean Basin(CIOB)pumices.Eight groups of pumices were identified considering the presence of phenocrysts of plagioclase,clinopyroxene,orthopyroxene,hornblende and biotite together with the occurrence of quartz and glass.Pigeonite,fayalite and ulvospinelare reported for the first time from these pumices.In the eight groups,the modal percentage of the constituents are phenocrysts 3%to 19%(avg 9.6%),silicic glass 33%to 54%(avg 43%)and the rest is vesicles.Based on the above factors we have identified the possible sources of the CIOB pumices.The mineral compositions of plagioclase,pyroxenes,and biotite of the CIOB pumices were compared with those of Krakatau and Toba.Most of the plagioclase and pyroxene compositions resemble the Haranggoal Dacite Tuff of Toba and Krakatau.Considering the mineral assemblages and compositions,there are pumices which do not correlate to any of the above eruptions and are probably from yet unidentified source/sources.These sources could either be from nearby terrestrial volcanoes or intraplate seamounts present in the CIOB.In a global context,it is viable that petrological characteristics could be used as initial criteria to determine the source of pumices that occur at abyssal depths in the world ocean.展开更多
Biotite is an important hydrated ferromagnesian silicate mineral in igneous rocks and porphyry deposits.The determination of chemical compositions of biotite plays an important role in both igneous petrology and ore f...Biotite is an important hydrated ferromagnesian silicate mineral in igneous rocks and porphyry deposits.The determination of chemical compositions of biotite plays an important role in both igneous petrology and ore forming processes.This paper summarizes research results of magmatic and hydrothermal biotites exemplified by the Lakange porphyry Cu–Mo deposit and the Qulong porphyry Cu deposit in the Gangdese porphyry–skarn metallogenic belt,Tibet.Biotite mineral chemistry can provide critical insights into classification,geothermometer,geothermobarometry,oxygen fugacity,petrogenesis and tectonic setting,evaluating magmatic-hydrothermal process by halogen and halogen fugacity ratios,and distinguishing between barren and mineralized rocks.Biotite provides the latest mineralogical evidence on metallogenic prognosis and prospecting evaluation for porphyry Cu polymetallic deposits or magmatic hydrothermal deposits.展开更多
Wehrlite samples (size: ~4 cm) hosted in basaltic lavas from the SW of Hosséré Dammougalré are located in the western Adamawa Plateau. Porphyritic and allotriomorphic texture characterize respectively h...Wehrlite samples (size: ~4 cm) hosted in basaltic lavas from the SW of Hosséré Dammougalré are located in the western Adamawa Plateau. Porphyritic and allotriomorphic texture characterize respectively host Basalt and wehrlite xenoliths. The phenocrysts of olivine (Fo68−74), and Ti-magnetite are scattered in host basalt. Wehrlite xenoliths (~4 cm size) contain Cr-rich clinopyroxene (diopise-augite), olivine (Fo76−88) and chromiferous spinel. Equilibrium temperatures calculated from Fe/Mg exchange reaction for olivine/spinel vary between 944°C and 1102°C. The wehrlite olivine crystals with low Fo (<90) indicate a re-equilibration of Fe-Mg in the host basalt at low temperatures. All the analyzed wehrlite clinopyroxenes have crystallized at high pressures as evidenced by the Alvi and Aliv contents. The studied spinel-bearing wehrlite xenoliths represent probably the residual portions of the upper mantle, which are an important source of information about lithospheric composition and thermal evolution beneath the Adamawa Plateau.展开更多
Mount Cameroon volcano has erupted several times in the 20 th Century with documented eruptions in 1909,1922,1954,1959,1982,1999 and 2000.Evidence of historic volcanism is represented by several older lava flows and l...Mount Cameroon volcano has erupted several times in the 20 th Century with documented eruptions in 1909,1922,1954,1959,1982,1999 and 2000.Evidence of historic volcanism is represented by several older lava flows and lahar deposits around the flanks of the volcano.This study aims to assess the evolution of Mount Cameroon volcanism through its eruptive history via interpretation of mineralogical,whole rock geochemical and Pb,Sr,Nd isotope data generated from historic and recent lava flows.In this study,samples were collected from the 1959,1982,1999 and 2000 eruptions and from several historic eruption sites with unknown eruption dates.Evaluation of major and trace element data demonstrates that Mount Cameroon is geotectonically associated with within-plate Ocean Island Basalt Settings.More than 90%of the studied historic lavas(n=29)classify as tephrites and basanites whereas the modern lavas(n=38)are predominantly trachybasalts,demonstrating evolution from primitive to evolved lavas over time typically in response to fractional crystallization.Petrographically,the lavas are porphyritic with main mineral phases being olivine,clinopyroxene,plagioclase feldspars and Fe-Ti-Cr oxides.The 1982 lavas are predominantly aphyric and dominated by lath-shaped flow-aligned plagioclase in the groundmass.Olivine chemistry shows variable forsterite compositions from Fo60-89.Clinopyroxenes vary from diopside through augite to titanaugite with chemical composition ranges from Wo45En32Fs7 to Wo51En47Fs17.Plagioclase feldspars vary from labradorite(An567 O)to bytownite(An80-87).For the Fe-Ti-Cr oxides,calculated ulvospinel component shows a wide variation from ulv38-87.CIPW-normative classification on the Di-Ol-Hy-Qz-Ne system shows that all Mount Cameroon lavas are nepheline-normative(Ne ranges from4.20 wt.%to 11.45 wt.%).Radiogenic isotope data demonstrate that Mount Cameroon lavas are HIMU(or high μ=238U/204Pb),characterized by 206Pb/204Pb=20.19-20.46,207Pb/204Pb=15.63-15.69,208Pb/204Pb=40.01-40.30,87Sr/86Sr=0.70322-0.70339(εsr=-21.37 to-18.96)and 143 Nd/144 Nd=0.51276-0.51285(εNd=+2.29 to+4.05).The historic lavas show stronger HIMU signature relative to the modern lavas,suggesting evolution towards less HIMU signatures over time.This study has revealed that Mount Cameroon volcanism has evolved from primitive magmas characterized by stronger HIMU signatures with high 206/204Pb and 208/204Pb isotopes,low SiO2 and high Mg,Ni,Cr content towards lower HIMU signatures with relatively higher SiO2,lower Mg,Cr and Ni compositions.The geochemical and isotopic changes,which account for the evolution of magmatism on Mount Cameroon occur over long periods of time because all the modern lavas erupted within the last 100 years are isotopically homogeneous,with very limited variation in SiO2 compositions.展开更多
Chromitites associated with intensely altered dunites and harzburgites from fourteen dif ferent localities in the Islahiye ophiolites(SE Anatolia)is reported here for the first time.These chromitites were observed as ...Chromitites associated with intensely altered dunites and harzburgites from fourteen dif ferent localities in the Islahiye ophiolites(SE Anatolia)is reported here for the first time.These chromitites were observed as lenticular and banded bodies with disseminated and massive textures and containing magnesiochromite grains with the following composition:CrO=58.91–59.74 wt%,Al_(2)O_(3)=10.85–11.20 wt%,and TiO=0.09–0.13 wt%.The Mg#[Mg/(Mg+Fe)]values of magnesiochromite from the Islahiye ophiolite range between 0.52 and 0.60 and their Cr#[Cr/(Cr+Al)]values vary from 0.7802 to 0.7844.These contents vary with a constant pattern,coincident with the estimated parental liquids that have originated from the derivative of a single bulk of boninitic magma together with Al,Ti-poor,and Cr-rich initial contents.The chromitites are serpentinised in almost all parts of the study area,and harzburgite and dunite can be observed in different locations.Although the overall composition of platinum group elements(PGE)in most examined chromitites varies between 97 and 191 ppb,three chromitites from the Islahiye region present enrichments in overall PGE(up to 214 ppb).The mineralogical and geochemical features of chromitites from the Islahiye region exhibit a robust similarity to podiform chromitites in the mantle fragment of supra–subduction zone type ophiolitic bodies.The estimated parental magmas of the investigated chromites are consistent with the diff erentiation of arcrelated melts and do not suggest an oceanic spreading centre tectonic environment.The Islahiye chromites are enriched in IPGE(Ir,Os,Ru),with the occasional presence of Ru and Ir and higher Os contents in chromite.Furthermore,we did not find any platinum group minerals(PGM)associated with the serpentine silicate sample matrix,which would have stated a secondary enrichment in PGEs.All chromitites in the investigated region have high Cr and low Ti values,are defined as magnesiochromite and were crystallised from a characteristic boninitic magma.展开更多
Major and accessory minerals from the Ibity granite, Tsarasaotra monzonitic and granite dykes, and Antsahakely granite of the Itremo domain in the Precambrian basement of Madagascar were characterized by using microsc...Major and accessory minerals from the Ibity granite, Tsarasaotra monzonitic and granite dykes, and Antsahakely granite of the Itremo domain in the Precambrian basement of Madagascar were characterized by using microscopic observations and chemical analyses with the aim of understanding their chemical characteristics and estimating the crystallization pressure and oxygen fugacity of their host rocks. Plagioclases in these rocks are albite and oligoclase, while alkali feldspars are orthoclase. For the phlogopite-micas, Fe-biotite and Li-phengite are common for the Ibity and Antsahakely granites, Mg-biotite is common for the Ibity granite and the Tsarasaotra monzonitic and granite dykes, and siderophyllite and Zinnwaldite are specific to the Ibity granite. Phlogopite-micas in the studied rocks are mainly primary, accessorily re-equilibrated, and rarely secondary. Calcic amphiboles distributed in the Magnesio-and Ferro-hornblende are identified in the Tsarasaotra monzonitic, whereas amphibole is rare and absent in the other rocks. Igneous titanite is observed in the Ibity granite and in the Tsarasaotra monzonitic rocks, which have similar compositions to some REE oxide-rich titanites. Concerning the Fe-Ti oxide phases, the rhombohedral and spinel/trifer tetroxide phases are found in both the Tsarasaotra monzonitic and the Tsarasaotra granite dyke, the trifer tetroxide and spinel + wüstite phases are found only in the Ibity granite, and the pseudobrookite + rhombohedral phase is found only in the Tsarasaotra granite dyke. The epidote mineral, rarely found in the Antsahakely granite, could be an indicator of metamorphism or hydrothermal activity involved during the emplacement of this rock. Aluminum in hornblende geobarometer gave pressure ranges of around 5 kbar for the Tsarasaotra monzonitic rocks. The Titanite geobarometer gave pressures of 2.5 - 3.2 kbar for the Ibity granite, 2.9 kbar for the Tsarasaotra monzonitic, and 7.1 kbar for the Antsahakely granite. Both amphibole and Fe-Ti oxide-base oxygen fugacity reveal high oxygen fugacity conditions for the Tsarasaotra monzonitic and granite dyke emplacements, which might have a relationship with a porphyritic environment.展开更多
The Gelmandeh Massive is located in the Central part of Iranian Microcontinent. Amphibolitic rocks occupy the main portion of Gelmandeh complex, which consists of hornblendite, garnet amphibolites, and gneiss. Geochem...The Gelmandeh Massive is located in the Central part of Iranian Microcontinent. Amphibolitic rocks occupy the main portion of Gelmandeh complex, which consists of hornblendite, garnet amphibolites, and gneiss. Geochemical investigations indicate that the ratio of Eu/Eu* separates samples into two categories: first category with ratio of Eu/Eu* > 1 and the second with ratio of Eu/Eu* < 1, which the former indicates an enriched mantle origin while the latter points to crustal contamination. Generally, amphibolites can be differentiated into two separate series. First series is characterized with calc-alkaline to alkaline composition with enriched mantle origin, and the second one has calc-alkaline to tholeiitic nature and it is of continental type that underwent crustal contamination within subduction zone. The microprobe electron analysis shows that the amphiboles were a member of the calcic group and hastingsite-tschermakite series. Geo-barometric studied and mineral paragenesis show that the metamorphism is of Barovian type with PT condition upto 7 K bar and 580°C.展开更多
Petrography and chemistry of minerals show that rocks of Upper Eocene in northeast of Tafresh are composed mostly of andesitic basalt, basaltic andesite and andesite volcanic rocks. Mineralogically these rocks are com...Petrography and chemistry of minerals show that rocks of Upper Eocene in northeast of Tafresh are composed mostly of andesitic basalt, basaltic andesite and andesite volcanic rocks. Mineralogically these rocks are composed of phenocrystals of olivine, clinopyroxene and plagioclase and main texture of them is porphyry with cryptocrystalline or microcrystalline matrix. In addition, aphyric and pitted textures (amygdala) are also observed. According to the results of EPMA, phenocrystals of plagioclase in mentioned rocks include a range of anorthite to albite minerals. Alkali feldspars also contain a range of sodic to potassic minerals. Pyroxene crystals include hedenbergite, augite and hypersthene. Olivine minerals are often of the ferrohornblendite type. Based on thermobarometry it is estimated that to form clinopyroxene crystals of basaltic andesite rocks, temperature between 750°C to 1000°C is needed. Andesitic basalt rocks at higher temperature (1100°C) and andesite rocks at lower temperature (below 750°C) are formed. According to the distribution of aluminum in clinopyroxenes, these minerals at pressures less than 5 kbar and water content between 5% to 10% are crystallized. The mineral composition indicates that these rocks are formed in a tensional environment.展开更多
Metabasite refers to metamorphosed basalts and other mafic igneous rocks (rich in iron and magnesium). When a mafic igneous rock is subjected to new pressure and temperature conditions during metamorphism, these chemi...Metabasite refers to metamorphosed basalts and other mafic igneous rocks (rich in iron and magnesium). When a mafic igneous rock is subjected to new pressure and temperature conditions during metamorphism, these chemical components will rearrange themselves to form new minerals. Metabasites can be found in many metamorphic belts including Sanandaj-Sirjan metamorphic belt of Iran. The study area is a Tanbour metamorphic complex in Eastern of Sirjan city, which is geologically located at the Sanandaj-Sirjan metamorphic belt in Southern Iran. Metabasite in this complex consists of greenschist, epidote amphibolite and amphibolite. Amphibole and plagioclase are the main minerals in the greenschist and amphibolite, and the a secondary mineral in some micaschist seen in the study area. The electron microprobe analysis was done on this mineralization in greenschist, epidote amphibolite and amphibolite, which showed that the amphiboles in greenschist was a member of the calcic group and Actinolite type, and the amphiboles in epidote amphibolite was a member of the calcic group and these amphiboles were tschermakite up to Ferro-Tschermakite + Ferro-Hornblende type. The amphibole in amphibolite is a member of the calcic group and this amphibole is Magnesio-Hornblende type. The plagioclases in the greenschist is pure albite (An 3.29 - 3.6), and in the epidote amphibolite is oligoclase (An 19.5 - 24.2), while in the amphibolites is oligoclase (An 16.9 - 26.6). The estimated P–T conditions are in favor of their metamorphism under epidote amphibolite (550°C and 8 kbar) and amphibolite (611°C - 652° Cand 10.5 kbar) facies.展开更多
The glass and mineral chemistry of basalts examined from the northern central Indian ridge (NCIR) provides an insight into magma genesis around the vicinity of two transform faults: Vityaz (VT) and Vema (VM). The stud...The glass and mineral chemistry of basalts examined from the northern central Indian ridge (NCIR) provides an insight into magma genesis around the vicinity of two transform faults: Vityaz (VT) and Vema (VM). The studied mid-ocean ridge basalts (MORBs) from the outer ridge flank (VT area) and a near-ridge seamount (VM area) reveal that they are moderately phyric plagioclase basalts composed of plagioclase (phenocryst [An60-90] and groundmass [An35-79]), olivine (Fo81-88), diopside (Wo45-51, En25-37, Fs14-24), and titanomagnetite (FeOt～63.75 wt% and TiO2～22.69 wt%). The whole-rock composition of these basalts has similar Mg# [mole Mg/mole(Mg+Fe2+)] (VT basalt:～0.56-0.58; VM basalt:～0.57), but differ in their total alkali content (VT basalt:～2.65; VM basalt:～3.24). The bulk composition of the magma was gradually depleted in MgO and enriched in FeOt, TiO2, P2O5, and Na2O with progressive fractionation, the basalts were gradually enriched in Y and Zr and depleted in Ni and Cr. In addition, the ΣREE of magma also increased with fractionation, without any change in the (La/ Yb)N value. Glass from the VM seamount shows more fractionated characters (Mg#: 0.56-0.57) compared to the outer ridge flank lava of the VT area (Mg#: 0.63-0.65). This study concludes that present basalts experienced low-pressure crystallization at a relatively shallow depth. The geochemical changes in the NCIR magmas resulted from fractional crystallization at a shallow depth. As a consequence, spinel was the first mineral to crystallize at a pressure >10 kbar, followed by Fe-rich olivine at <10 kbar pressure.展开更多
The Mirge-Naqshineh gold district is situated at northwest of Iran with a NW-trending brittleductile shear zone. It is hosted by Precambrian meta-sedimentary and meta-volcanic units traversed by mineralized quartz vei...The Mirge-Naqshineh gold district is situated at northwest of Iran with a NW-trending brittleductile shear zone. It is hosted by Precambrian meta-sedimentary and meta-volcanic units traversed by mineralized quartz veins. In terms of cross-cutting relationships and sulfide content three types of quartz veins are identified in the region. Among those, parallel to bedding quartz vein(type Ⅰ) is the main host for gold mineralization. Gold is found in three different forms: 1) submicrometer-size inclusions of gold in arsenian pyrite, 2) as electrum and 3) in the crystal lattice of sulfides(pyrite, galena and chalcopyrite). Six types of pyrite(Py1-Py6) were identified in this ore reserve. Py3 coexists with arsenopyrite and contains the greatest As-Au concentrations. There is a negative correlation between the As and S contents in Py2 and Py3, implying the substitution of sulfur by arsenic. Pyrites and mineralized quartz veins were formed via metamorphic-hydrothermal fluid and reflect the gold-transportation as Au(HS)_2^- under reducing and acidic conditions. The gold precipitation mainly controlled by crystallization of arsenian pyrite during fluid/rock interactions and variation of fO_2. The volcanic host rock has played an important role in gold concentration, as Py3 in this rock contains inclusion of gold particles, but gold is within the lattice of pyrite in phyllite or other units.展开更多
Petrography and mineral chemistry of four carbonaceous chondrites(GRV 020017,GRV 020025,GRV 021579,GRV 022459)collected from the Grove Mountains(GRV),Antarctica,were reported here.All four chondrites are unequilibrate...Petrography and mineral chemistry of four carbonaceous chondrites(GRV 020017,GRV 020025,GRV 021579,GRV 022459)collected from the Grove Mountains(GRV),Antarctica,were reported here.All four chondrites are unequilibrated,as indicated by well shaped chondrules and the chemical variations of olivine and low-Ca pyroxene.The modal abundance ratio of matrix/chondrule are 2(GRV 020017),2.8(GRV 020025),1.2(GRV 021579),1(GRV 022459).GRV 022459 has the largest chondrules(0.6-2.0 mm).A total of 30 Ca-Al-rich inclusions were found in the four meteorites.Most inclusions were highly altered,with abundant phyllosilicates in the inclusions of GRV 020017 and GRV 020025.On the base of petrography and mineral chemistry,these chondrites are classified as CM2(GRV 020017 and 020025),CO3(GRV 021579)and CV3(GRV 022459).展开更多
This paper elucidates the compositional studies on clinopyroxene, plagioclase of basalts to andesitic rocks of Torud area to understand the geotectonic and geothermobarometry conditions.?Early?Eocene-Oligocene calc-al...This paper elucidates the compositional studies on clinopyroxene, plagioclase of basalts to andesitic rocks of Torud area to understand the geotectonic and geothermobarometry conditions.?Early?Eocene-Oligocene calc-alkaline volcanic rocks are exposed around Torud in the Central Iranian zone. Volcanic rocks consist of basaltic, andesite basalt, Tracyandesite, and andesite. Minerals in the volcanic rocks exhibit degrees of disequilibrium features. Plagioclase as dominant mineral in these rocks generally displays oscillatory zoning. Mineral chemistry studies show that clinopyroxenes in the volcanic rocks are diopside, augite and plotted in medium pressure field. The clinopyroxene composition yields the crystallization temperatures 900°C?- 1000°C. The mineral composition indicates that these rocks are formed in a tensional environment.展开更多
Neshveh intrusion which is located in the NW of Saveh City is a part of Sahand-Bazman magmatic arc within the Central Iranian zone. This intrusion consists of quartz-monzogabbro, quartz-monzodiorite, granodiorite and ...Neshveh intrusion which is located in the NW of Saveh City is a part of Sahand-Bazman magmatic arc within the Central Iranian zone. This intrusion consists of quartz-monzogabbro, quartz-monzodiorite, granodiorite and granite that have intruded into the Eocene volcano-sedimentary rocks. This intrusion is medium to high-K calc alkaline, metaluminous, and I-type granitoid. All phases of the Neshveh granitoid are characterized by LREE-rich patterns with high LREE/HREE ratio and negative Eu anomalies. Similarity of patterns suggests a comagmatic source for these rocks and demonstrates the role of magmatic differentiation in their evolution. Clinopyroxene classified as calcic type with varying from clinoenstatite-clinofferosillite to diopside and augite from quartz-monzogabbros to quartz-monzodiorite and granodiorite. Plagioclase composition varies from bytownite and labradorite in quartz-monzogabbros to andesine in quartz-monzodiorites and oligoclase in granodiorites and granites. Core of some plagioclases in granodiorites and granites shows the calcic composition which is labradorite and andesine in granodiorite and andesine in granites. Field investigations along with petrographic and geochemical studies indicate that all phases of the Neshveh intrusion derived from a common magma source as a result of mineral differentiation. Geochemical evidences show smooth differentiation trends in which most of major elements (except Al2O3, K2O and Na2O) are negatively correlated with SiO2?and K2O, Ba, Rb, Ce, Nb, and Zr are positively correlated with SiO2. Some elements such as Na2O, Sr, Eu and Y follow curves that reflect crystal fractionation of clinopyroxene, plagioc1ase and hornblende. Furthermore, large volumes of quartz-monzogabbros compared to granites, as well as the lack of mafic enclaves in more evolved rocks, are also indicative of crystal fractionation. Clinopyroxene fractionation was the main control in the evolution of the magmas up to 55 wt% SiO2. Hornblende took over from 55 wt% SiO2, resulting in decreasing Dy/Yb with increasing silica content in the most siliceous rocks. Fractionation of opaque minerals and apatite throughout the sequence, and the continuous increase in K2O and Ba vs. SiO2?reflect the absence of significant fractionation of biotite and K-feldspar.展开更多
The garnet muscovite granitic pegmatite of Um Solimate,in southern Egypt,represents a promising asset for strategic and economic metals,especially Bi-Ni-Ag-Nb-Ta as well as U and Th.The ore bodies occur as large masse...The garnet muscovite granitic pegmatite of Um Solimate,in southern Egypt,represents a promising asset for strategic and economic metals,especially Bi-Ni-Ag-Nb-Ta as well as U and Th.The ore bodies occur as large masses,pockets and/or veins of very coarse-grained pegmatites,which consist mainly of K-feldspar,quartz and albite with subordinate muscovite,garnet,and biotite.Radiometric data revealed that e U-and e Th-contents of the pegmatites reach up to 39 ppm and 82 ppm,respectively.The studied pegmatites are enriched in primary U and Th minerals(uraninite,coffinite,thorianite and uranothorite)as well as Hf-rich zircon and monazite,which give rise to anomalous radioactive zones.Niobium-tantalium-bearing minerals(i.e.ferrocolumbite,microlite and uranopyrochlore),xenotime,barite,galena,fluorite,and apatite are ubiquitous,and,consequently,the studied pegmatites belong tothe Niobium-Yttrium-Fluorine-type(NYF)family.The noble metal mineralization includes argentite(Ag_(2)S),native Ni and Bi as well as bismite and bismoclite.In addition,beryl and tourmaline are observed in pegmatites near the contact with metasediments and ultramafic bodies.The observed compositional variations of Ta/(Ta+Nb)and Mn/(Mn+Fe)ratios in columbite(0.08-0.45 and 0.11-0.57,respectively)and Hf contents in zircon(3.54-6.46 wt%)may reflectan extreme degree of magmatic fractionation leading to formation of the pegmatite orebody.展开更多
Amphiboles are frequently observed in the medium to high grade metamorphic rocks of garnet bearing amphibolites from Thana.In present work,authors have discussed the mineral chemistry and nomenclature of amphiboles.On...Amphiboles are frequently observed in the medium to high grade metamorphic rocks of garnet bearing amphibolites from Thana.In present work,authors have discussed the mineral chemistry and nomenclature of amphiboles.On the basis of mineral chemistry,the amphibole from garnet bearing amphibolite are normally varies from Hastingsite,Ferropargasite to Tschermakite variety.展开更多
Tourmaline is widespread in the host strata of strata-bound base metal sulphide de-posits in the Devonian metallogenic district around Shanyang-Zhashui in eastern Qinling. As amember of the schorl-dravite series, the ...Tourmaline is widespread in the host strata of strata-bound base metal sulphide de-posits in the Devonian metallogenic district around Shanyang-Zhashui in eastern Qinling. As amember of the schorl-dravite series, the tourmaline is characterized by Mg>Fe and Na > Ca,showing apparent chemical zonation which records the geochemistry during its formation andsubsequent regi0nal metamorphism and hydrothermal overprint. The close similarity in chemi-cal and isotopic constitutions between the tourmaline of the main metallogenic epoch in this district [FeO/(FeO+MgO) = 0. 34 - 0. 39 andδ 11B = - 7. 6‰. - - 8. 8‰] and those related tomassive sulphide deposits typical of submarine (exhalative) hydrothermal sedimentation mayadd further support to a similar mechanism of mineralization for the strata-bound deposits in thedistrict.展开更多
In the Wadi Feiran area, amphibolites occur as inclusions, bands, linear bodies of variable thickness and irregular lenses in para-geneisses. Chemical evidence indicates that these amphibolites display an igneous orig...In the Wadi Feiran area, amphibolites occur as inclusions, bands, linear bodies of variable thickness and irregular lenses in para-geneisses. Chemical evidence indicates that these amphibolites display an igneous origin and were derived from magma essentially of tholelitic rather than alkaline composition; transitional in character between continental and island-arc. The chemistry of amphiboles, related to pressure and temperature conditions of metamorphism, showed that they were formed under low pressure and high temperature conditions.展开更多
Petrochemical studies indicate that the Yanghou metamorphic ultramafic rocks are composed of metamorphosed harzburgite and ultramafic cumulate. Trace element geochemistry and mineral chemistry of the metamorphic harzb...Petrochemical studies indicate that the Yanghou metamorphic ultramafic rocks are composed of metamorphosed harzburgite and ultramafic cumulate. Trace element geochemistry and mineral chemistry of the metamorphic harzburgite indicate that they are relicts of depleted mantle. Systematic petrochemical, mineral chemical and geochronological studies led to such a conclusion that the Yanghou metamorphic ultramafic rocks may be the components of Late Sinian Early Paleozoic ophiolites in South China.展开更多
Paleoproterozoic Bijawars of the Sonrai basin consists of(a) Sonrai(mostly carbonate carbonaceous shale and phosphatic breccia) and(b) Solda Formations(commonly chloritic and ferruginous shale) with well-developed cla...Paleoproterozoic Bijawars of the Sonrai basin consists of(a) Sonrai(mostly carbonate carbonaceous shale and phosphatic breccia) and(b) Solda Formations(commonly chloritic and ferruginous shale) with well-developed clay-organo-rich facies,often marked with hydrothermal activities.Previous studies revealed abundance order of kaolinite> chlorite> illite> smectite;and kaolinite> illite> chlorite in clay(0.2-2.0 μm) fractions separated from the Sonrai and Solda Formations,respectively.To understand atomic substitutions and trace elemental concentrations,clay minerals were analyzed by fusion ICPMS and SEM-EDS.PAAS normalized data plots show U,Th,Rb,Ba,Pb Sr,and large-ion lithophiles enrichment,whereas,Bandai sandstone and Rohini carbonate clays show HREE enrichment with asymmetrical patterns,similar to those reported from the well-established McArthur River,Cigar Lake,and Sue UTUD of Canada.For Rohni carbonate,chondrite-normalized REE data plots revealed M shape REE patterns,ascribed to Gd-Tb-Dy-Ho tetrad effect and anomalous Y,Zr,and Hf concentrations.Owing to HREE incorporation in the clay inter-layers,linear and flattened REE trends were noticed.Flat REE patterns associated with the highly altered chlorite and illite represent negative Eu anomaly related to the dilational nature of the uraninite structure and is suggestive of anoxic conditions.展开更多
基金Part of the research was supported under Endeavour Fellowship awarded to Niyati G.Kalangutkar by Government of Australia and the work was conducted at Queensland University of Technology Laboratory, Brisbane, Queensland
文摘We present data pertaining to mineral assemblages and composition of the Central Indian Ocean Basin(CIOB)pumices.Eight groups of pumices were identified considering the presence of phenocrysts of plagioclase,clinopyroxene,orthopyroxene,hornblende and biotite together with the occurrence of quartz and glass.Pigeonite,fayalite and ulvospinelare reported for the first time from these pumices.In the eight groups,the modal percentage of the constituents are phenocrysts 3%to 19%(avg 9.6%),silicic glass 33%to 54%(avg 43%)and the rest is vesicles.Based on the above factors we have identified the possible sources of the CIOB pumices.The mineral compositions of plagioclase,pyroxenes,and biotite of the CIOB pumices were compared with those of Krakatau and Toba.Most of the plagioclase and pyroxene compositions resemble the Haranggoal Dacite Tuff of Toba and Krakatau.Considering the mineral assemblages and compositions,there are pumices which do not correlate to any of the above eruptions and are probably from yet unidentified source/sources.These sources could either be from nearby terrestrial volcanoes or intraplate seamounts present in the CIOB.In a global context,it is viable that petrological characteristics could be used as initial criteria to determine the source of pumices that occur at abyssal depths in the world ocean.
基金supported by the National Key R&D Program of China (grant number 2018YFC0604101)the Public Science and Technology Research Funds Projects, Ministry of Land Resources of the People’s Republic of China (project nos. 201511017 and 201511022-05)+2 种基金the Basic Research Fund of the Chinese Academy of Geological Sciences (grant no. YYWF201608)the National Natural Science Foundation of China (grant no. 41402178)the Geological Survey project (grant no. DD20160026)
文摘Biotite is an important hydrated ferromagnesian silicate mineral in igneous rocks and porphyry deposits.The determination of chemical compositions of biotite plays an important role in both igneous petrology and ore forming processes.This paper summarizes research results of magmatic and hydrothermal biotites exemplified by the Lakange porphyry Cu–Mo deposit and the Qulong porphyry Cu deposit in the Gangdese porphyry–skarn metallogenic belt,Tibet.Biotite mineral chemistry can provide critical insights into classification,geothermometer,geothermobarometry,oxygen fugacity,petrogenesis and tectonic setting,evaluating magmatic-hydrothermal process by halogen and halogen fugacity ratios,and distinguishing between barren and mineralized rocks.Biotite provides the latest mineralogical evidence on metallogenic prognosis and prospecting evaluation for porphyry Cu polymetallic deposits or magmatic hydrothermal deposits.
文摘Wehrlite samples (size: ~4 cm) hosted in basaltic lavas from the SW of Hosséré Dammougalré are located in the western Adamawa Plateau. Porphyritic and allotriomorphic texture characterize respectively host Basalt and wehrlite xenoliths. The phenocrysts of olivine (Fo68−74), and Ti-magnetite are scattered in host basalt. Wehrlite xenoliths (~4 cm size) contain Cr-rich clinopyroxene (diopise-augite), olivine (Fo76−88) and chromiferous spinel. Equilibrium temperatures calculated from Fe/Mg exchange reaction for olivine/spinel vary between 944°C and 1102°C. The wehrlite olivine crystals with low Fo (<90) indicate a re-equilibration of Fe-Mg in the host basalt at low temperatures. All the analyzed wehrlite clinopyroxenes have crystallized at high pressures as evidenced by the Alvi and Aliv contents. The studied spinel-bearing wehrlite xenoliths represent probably the residual portions of the upper mantle, which are an important source of information about lithospheric composition and thermal evolution beneath the Adamawa Plateau.
文摘Mount Cameroon volcano has erupted several times in the 20 th Century with documented eruptions in 1909,1922,1954,1959,1982,1999 and 2000.Evidence of historic volcanism is represented by several older lava flows and lahar deposits around the flanks of the volcano.This study aims to assess the evolution of Mount Cameroon volcanism through its eruptive history via interpretation of mineralogical,whole rock geochemical and Pb,Sr,Nd isotope data generated from historic and recent lava flows.In this study,samples were collected from the 1959,1982,1999 and 2000 eruptions and from several historic eruption sites with unknown eruption dates.Evaluation of major and trace element data demonstrates that Mount Cameroon is geotectonically associated with within-plate Ocean Island Basalt Settings.More than 90%of the studied historic lavas(n=29)classify as tephrites and basanites whereas the modern lavas(n=38)are predominantly trachybasalts,demonstrating evolution from primitive to evolved lavas over time typically in response to fractional crystallization.Petrographically,the lavas are porphyritic with main mineral phases being olivine,clinopyroxene,plagioclase feldspars and Fe-Ti-Cr oxides.The 1982 lavas are predominantly aphyric and dominated by lath-shaped flow-aligned plagioclase in the groundmass.Olivine chemistry shows variable forsterite compositions from Fo60-89.Clinopyroxenes vary from diopside through augite to titanaugite with chemical composition ranges from Wo45En32Fs7 to Wo51En47Fs17.Plagioclase feldspars vary from labradorite(An567 O)to bytownite(An80-87).For the Fe-Ti-Cr oxides,calculated ulvospinel component shows a wide variation from ulv38-87.CIPW-normative classification on the Di-Ol-Hy-Qz-Ne system shows that all Mount Cameroon lavas are nepheline-normative(Ne ranges from4.20 wt.%to 11.45 wt.%).Radiogenic isotope data demonstrate that Mount Cameroon lavas are HIMU(or high μ=238U/204Pb),characterized by 206Pb/204Pb=20.19-20.46,207Pb/204Pb=15.63-15.69,208Pb/204Pb=40.01-40.30,87Sr/86Sr=0.70322-0.70339(εsr=-21.37 to-18.96)and 143 Nd/144 Nd=0.51276-0.51285(εNd=+2.29 to+4.05).The historic lavas show stronger HIMU signature relative to the modern lavas,suggesting evolution towards less HIMU signatures over time.This study has revealed that Mount Cameroon volcanism has evolved from primitive magmas characterized by stronger HIMU signatures with high 206/204Pb and 208/204Pb isotopes,low SiO2 and high Mg,Ni,Cr content towards lower HIMU signatures with relatively higher SiO2,lower Mg,Cr and Ni compositions.The geochemical and isotopic changes,which account for the evolution of magmatism on Mount Cameroon occur over long periods of time because all the modern lavas erupted within the last 100 years are isotopically homogeneous,with very limited variation in SiO2 compositions.
基金Cukurova University Research Foundation for their support(Project No:FYL-2018-10437,FBA-2021-13093)。
文摘Chromitites associated with intensely altered dunites and harzburgites from fourteen dif ferent localities in the Islahiye ophiolites(SE Anatolia)is reported here for the first time.These chromitites were observed as lenticular and banded bodies with disseminated and massive textures and containing magnesiochromite grains with the following composition:CrO=58.91–59.74 wt%,Al_(2)O_(3)=10.85–11.20 wt%,and TiO=0.09–0.13 wt%.The Mg#[Mg/(Mg+Fe)]values of magnesiochromite from the Islahiye ophiolite range between 0.52 and 0.60 and their Cr#[Cr/(Cr+Al)]values vary from 0.7802 to 0.7844.These contents vary with a constant pattern,coincident with the estimated parental liquids that have originated from the derivative of a single bulk of boninitic magma together with Al,Ti-poor,and Cr-rich initial contents.The chromitites are serpentinised in almost all parts of the study area,and harzburgite and dunite can be observed in different locations.Although the overall composition of platinum group elements(PGE)in most examined chromitites varies between 97 and 191 ppb,three chromitites from the Islahiye region present enrichments in overall PGE(up to 214 ppb).The mineralogical and geochemical features of chromitites from the Islahiye region exhibit a robust similarity to podiform chromitites in the mantle fragment of supra–subduction zone type ophiolitic bodies.The estimated parental magmas of the investigated chromites are consistent with the diff erentiation of arcrelated melts and do not suggest an oceanic spreading centre tectonic environment.The Islahiye chromites are enriched in IPGE(Ir,Os,Ru),with the occasional presence of Ru and Ir and higher Os contents in chromite.Furthermore,we did not find any platinum group minerals(PGM)associated with the serpentine silicate sample matrix,which would have stated a secondary enrichment in PGEs.All chromitites in the investigated region have high Cr and low Ti values,are defined as magnesiochromite and were crystallised from a characteristic boninitic magma.
文摘Major and accessory minerals from the Ibity granite, Tsarasaotra monzonitic and granite dykes, and Antsahakely granite of the Itremo domain in the Precambrian basement of Madagascar were characterized by using microscopic observations and chemical analyses with the aim of understanding their chemical characteristics and estimating the crystallization pressure and oxygen fugacity of their host rocks. Plagioclases in these rocks are albite and oligoclase, while alkali feldspars are orthoclase. For the phlogopite-micas, Fe-biotite and Li-phengite are common for the Ibity and Antsahakely granites, Mg-biotite is common for the Ibity granite and the Tsarasaotra monzonitic and granite dykes, and siderophyllite and Zinnwaldite are specific to the Ibity granite. Phlogopite-micas in the studied rocks are mainly primary, accessorily re-equilibrated, and rarely secondary. Calcic amphiboles distributed in the Magnesio-and Ferro-hornblende are identified in the Tsarasaotra monzonitic, whereas amphibole is rare and absent in the other rocks. Igneous titanite is observed in the Ibity granite and in the Tsarasaotra monzonitic rocks, which have similar compositions to some REE oxide-rich titanites. Concerning the Fe-Ti oxide phases, the rhombohedral and spinel/trifer tetroxide phases are found in both the Tsarasaotra monzonitic and the Tsarasaotra granite dyke, the trifer tetroxide and spinel + wüstite phases are found only in the Ibity granite, and the pseudobrookite + rhombohedral phase is found only in the Tsarasaotra granite dyke. The epidote mineral, rarely found in the Antsahakely granite, could be an indicator of metamorphism or hydrothermal activity involved during the emplacement of this rock. Aluminum in hornblende geobarometer gave pressure ranges of around 5 kbar for the Tsarasaotra monzonitic rocks. The Titanite geobarometer gave pressures of 2.5 - 3.2 kbar for the Ibity granite, 2.9 kbar for the Tsarasaotra monzonitic, and 7.1 kbar for the Antsahakely granite. Both amphibole and Fe-Ti oxide-base oxygen fugacity reveal high oxygen fugacity conditions for the Tsarasaotra monzonitic and granite dyke emplacements, which might have a relationship with a porphyritic environment.
文摘The Gelmandeh Massive is located in the Central part of Iranian Microcontinent. Amphibolitic rocks occupy the main portion of Gelmandeh complex, which consists of hornblendite, garnet amphibolites, and gneiss. Geochemical investigations indicate that the ratio of Eu/Eu* separates samples into two categories: first category with ratio of Eu/Eu* > 1 and the second with ratio of Eu/Eu* < 1, which the former indicates an enriched mantle origin while the latter points to crustal contamination. Generally, amphibolites can be differentiated into two separate series. First series is characterized with calc-alkaline to alkaline composition with enriched mantle origin, and the second one has calc-alkaline to tholeiitic nature and it is of continental type that underwent crustal contamination within subduction zone. The microprobe electron analysis shows that the amphiboles were a member of the calcic group and hastingsite-tschermakite series. Geo-barometric studied and mineral paragenesis show that the metamorphism is of Barovian type with PT condition upto 7 K bar and 580°C.
文摘Petrography and chemistry of minerals show that rocks of Upper Eocene in northeast of Tafresh are composed mostly of andesitic basalt, basaltic andesite and andesite volcanic rocks. Mineralogically these rocks are composed of phenocrystals of olivine, clinopyroxene and plagioclase and main texture of them is porphyry with cryptocrystalline or microcrystalline matrix. In addition, aphyric and pitted textures (amygdala) are also observed. According to the results of EPMA, phenocrystals of plagioclase in mentioned rocks include a range of anorthite to albite minerals. Alkali feldspars also contain a range of sodic to potassic minerals. Pyroxene crystals include hedenbergite, augite and hypersthene. Olivine minerals are often of the ferrohornblendite type. Based on thermobarometry it is estimated that to form clinopyroxene crystals of basaltic andesite rocks, temperature between 750°C to 1000°C is needed. Andesitic basalt rocks at higher temperature (1100°C) and andesite rocks at lower temperature (below 750°C) are formed. According to the distribution of aluminum in clinopyroxenes, these minerals at pressures less than 5 kbar and water content between 5% to 10% are crystallized. The mineral composition indicates that these rocks are formed in a tensional environment.
文摘Metabasite refers to metamorphosed basalts and other mafic igneous rocks (rich in iron and magnesium). When a mafic igneous rock is subjected to new pressure and temperature conditions during metamorphism, these chemical components will rearrange themselves to form new minerals. Metabasites can be found in many metamorphic belts including Sanandaj-Sirjan metamorphic belt of Iran. The study area is a Tanbour metamorphic complex in Eastern of Sirjan city, which is geologically located at the Sanandaj-Sirjan metamorphic belt in Southern Iran. Metabasite in this complex consists of greenschist, epidote amphibolite and amphibolite. Amphibole and plagioclase are the main minerals in the greenschist and amphibolite, and the a secondary mineral in some micaschist seen in the study area. The electron microprobe analysis was done on this mineralization in greenschist, epidote amphibolite and amphibolite, which showed that the amphiboles in greenschist was a member of the calcic group and Actinolite type, and the amphiboles in epidote amphibolite was a member of the calcic group and these amphiboles were tschermakite up to Ferro-Tschermakite + Ferro-Hornblende type. The amphibole in amphibolite is a member of the calcic group and this amphibole is Magnesio-Hornblende type. The plagioclases in the greenschist is pure albite (An 3.29 - 3.6), and in the epidote amphibolite is oligoclase (An 19.5 - 24.2), while in the amphibolites is oligoclase (An 16.9 - 26.6). The estimated P–T conditions are in favor of their metamorphism under epidote amphibolite (550°C and 8 kbar) and amphibolite (611°C - 652° Cand 10.5 kbar) facies.
基金supported largely by the Office of Naval Research,USA (grant no.:00144-97-1-0925,CLP 0886).This is NIO's contribution # 4362
文摘The glass and mineral chemistry of basalts examined from the northern central Indian ridge (NCIR) provides an insight into magma genesis around the vicinity of two transform faults: Vityaz (VT) and Vema (VM). The studied mid-ocean ridge basalts (MORBs) from the outer ridge flank (VT area) and a near-ridge seamount (VM area) reveal that they are moderately phyric plagioclase basalts composed of plagioclase (phenocryst [An60-90] and groundmass [An35-79]), olivine (Fo81-88), diopside (Wo45-51, En25-37, Fs14-24), and titanomagnetite (FeOt～63.75 wt% and TiO2～22.69 wt%). The whole-rock composition of these basalts has similar Mg# [mole Mg/mole(Mg+Fe2+)] (VT basalt:～0.56-0.58; VM basalt:～0.57), but differ in their total alkali content (VT basalt:～2.65; VM basalt:～3.24). The bulk composition of the magma was gradually depleted in MgO and enriched in FeOt, TiO2, P2O5, and Na2O with progressive fractionation, the basalts were gradually enriched in Y and Zr and depleted in Ni and Cr. In addition, the ΣREE of magma also increased with fractionation, without any change in the (La/ Yb)N value. Glass from the VM seamount shows more fractionated characters (Mg#: 0.56-0.57) compared to the outer ridge flank lava of the VT area (Mg#: 0.63-0.65). This study concludes that present basalts experienced low-pressure crystallization at a relatively shallow depth. The geochemical changes in the NCIR magmas resulted from fractional crystallization at a shallow depth. As a consequence, spinel was the first mineral to crystallize at a pressure >10 kbar, followed by Fe-rich olivine at <10 kbar pressure.
基金supported by Urmia UniversityIMIDRO(Iranian Mines and Mining Industries Development and Renovation Organization)
文摘The Mirge-Naqshineh gold district is situated at northwest of Iran with a NW-trending brittleductile shear zone. It is hosted by Precambrian meta-sedimentary and meta-volcanic units traversed by mineralized quartz veins. In terms of cross-cutting relationships and sulfide content three types of quartz veins are identified in the region. Among those, parallel to bedding quartz vein(type Ⅰ) is the main host for gold mineralization. Gold is found in three different forms: 1) submicrometer-size inclusions of gold in arsenian pyrite, 2) as electrum and 3) in the crystal lattice of sulfides(pyrite, galena and chalcopyrite). Six types of pyrite(Py1-Py6) were identified in this ore reserve. Py3 coexists with arsenopyrite and contains the greatest As-Au concentrations. There is a negative correlation between the As and S contents in Py2 and Py3, implying the substitution of sulfur by arsenic. Pyrites and mineralized quartz veins were formed via metamorphic-hydrothermal fluid and reflect the gold-transportation as Au(HS)_2^- under reducing and acidic conditions. The gold precipitation mainly controlled by crystallization of arsenian pyrite during fluid/rock interactions and variation of fO_2. The volcanic host rock has played an important role in gold concentration, as Py3 in this rock contains inclusion of gold particles, but gold is within the lattice of pyrite in phyllite or other units.
基金supported by the Doctor's Foundation of Hunan University of Science and Technology(Grant No.E50806)
文摘Petrography and mineral chemistry of four carbonaceous chondrites(GRV 020017,GRV 020025,GRV 021579,GRV 022459)collected from the Grove Mountains(GRV),Antarctica,were reported here.All four chondrites are unequilibrated,as indicated by well shaped chondrules and the chemical variations of olivine and low-Ca pyroxene.The modal abundance ratio of matrix/chondrule are 2(GRV 020017),2.8(GRV 020025),1.2(GRV 021579),1(GRV 022459).GRV 022459 has the largest chondrules(0.6-2.0 mm).A total of 30 Ca-Al-rich inclusions were found in the four meteorites.Most inclusions were highly altered,with abundant phyllosilicates in the inclusions of GRV 020017 and GRV 020025.On the base of petrography and mineral chemistry,these chondrites are classified as CM2(GRV 020017 and 020025),CO3(GRV 021579)and CV3(GRV 022459).
文摘This paper elucidates the compositional studies on clinopyroxene, plagioclase of basalts to andesitic rocks of Torud area to understand the geotectonic and geothermobarometry conditions.?Early?Eocene-Oligocene calc-alkaline volcanic rocks are exposed around Torud in the Central Iranian zone. Volcanic rocks consist of basaltic, andesite basalt, Tracyandesite, and andesite. Minerals in the volcanic rocks exhibit degrees of disequilibrium features. Plagioclase as dominant mineral in these rocks generally displays oscillatory zoning. Mineral chemistry studies show that clinopyroxenes in the volcanic rocks are diopside, augite and plotted in medium pressure field. The clinopyroxene composition yields the crystallization temperatures 900°C?- 1000°C. The mineral composition indicates that these rocks are formed in a tensional environment.
文摘Neshveh intrusion which is located in the NW of Saveh City is a part of Sahand-Bazman magmatic arc within the Central Iranian zone. This intrusion consists of quartz-monzogabbro, quartz-monzodiorite, granodiorite and granite that have intruded into the Eocene volcano-sedimentary rocks. This intrusion is medium to high-K calc alkaline, metaluminous, and I-type granitoid. All phases of the Neshveh granitoid are characterized by LREE-rich patterns with high LREE/HREE ratio and negative Eu anomalies. Similarity of patterns suggests a comagmatic source for these rocks and demonstrates the role of magmatic differentiation in their evolution. Clinopyroxene classified as calcic type with varying from clinoenstatite-clinofferosillite to diopside and augite from quartz-monzogabbros to quartz-monzodiorite and granodiorite. Plagioclase composition varies from bytownite and labradorite in quartz-monzogabbros to andesine in quartz-monzodiorites and oligoclase in granodiorites and granites. Core of some plagioclases in granodiorites and granites shows the calcic composition which is labradorite and andesine in granodiorite and andesine in granites. Field investigations along with petrographic and geochemical studies indicate that all phases of the Neshveh intrusion derived from a common magma source as a result of mineral differentiation. Geochemical evidences show smooth differentiation trends in which most of major elements (except Al2O3, K2O and Na2O) are negatively correlated with SiO2?and K2O, Ba, Rb, Ce, Nb, and Zr are positively correlated with SiO2. Some elements such as Na2O, Sr, Eu and Y follow curves that reflect crystal fractionation of clinopyroxene, plagioc1ase and hornblende. Furthermore, large volumes of quartz-monzogabbros compared to granites, as well as the lack of mafic enclaves in more evolved rocks, are also indicative of crystal fractionation. Clinopyroxene fractionation was the main control in the evolution of the magmas up to 55 wt% SiO2. Hornblende took over from 55 wt% SiO2, resulting in decreasing Dy/Yb with increasing silica content in the most siliceous rocks. Fractionation of opaque minerals and apatite throughout the sequence, and the continuous increase in K2O and Ba vs. SiO2?reflect the absence of significant fractionation of biotite and K-feldspar.
文摘The garnet muscovite granitic pegmatite of Um Solimate,in southern Egypt,represents a promising asset for strategic and economic metals,especially Bi-Ni-Ag-Nb-Ta as well as U and Th.The ore bodies occur as large masses,pockets and/or veins of very coarse-grained pegmatites,which consist mainly of K-feldspar,quartz and albite with subordinate muscovite,garnet,and biotite.Radiometric data revealed that e U-and e Th-contents of the pegmatites reach up to 39 ppm and 82 ppm,respectively.The studied pegmatites are enriched in primary U and Th minerals(uraninite,coffinite,thorianite and uranothorite)as well as Hf-rich zircon and monazite,which give rise to anomalous radioactive zones.Niobium-tantalium-bearing minerals(i.e.ferrocolumbite,microlite and uranopyrochlore),xenotime,barite,galena,fluorite,and apatite are ubiquitous,and,consequently,the studied pegmatites belong tothe Niobium-Yttrium-Fluorine-type(NYF)family.The noble metal mineralization includes argentite(Ag_(2)S),native Ni and Bi as well as bismite and bismoclite.In addition,beryl and tourmaline are observed in pegmatites near the contact with metasediments and ultramafic bodies.The observed compositional variations of Ta/(Ta+Nb)and Mn/(Mn+Fe)ratios in columbite(0.08-0.45 and 0.11-0.57,respectively)and Hf contents in zircon(3.54-6.46 wt%)may reflectan extreme degree of magmatic fractionation leading to formation of the pegmatite orebody.
文摘Amphiboles are frequently observed in the medium to high grade metamorphic rocks of garnet bearing amphibolites from Thana.In present work,authors have discussed the mineral chemistry and nomenclature of amphiboles.On the basis of mineral chemistry,the amphibole from garnet bearing amphibolite are normally varies from Hastingsite,Ferropargasite to Tschermakite variety.
文摘Tourmaline is widespread in the host strata of strata-bound base metal sulphide de-posits in the Devonian metallogenic district around Shanyang-Zhashui in eastern Qinling. As amember of the schorl-dravite series, the tourmaline is characterized by Mg>Fe and Na > Ca,showing apparent chemical zonation which records the geochemistry during its formation andsubsequent regi0nal metamorphism and hydrothermal overprint. The close similarity in chemi-cal and isotopic constitutions between the tourmaline of the main metallogenic epoch in this district [FeO/(FeO+MgO) = 0. 34 - 0. 39 andδ 11B = - 7. 6‰. - - 8. 8‰] and those related tomassive sulphide deposits typical of submarine (exhalative) hydrothermal sedimentation mayadd further support to a similar mechanism of mineralization for the strata-bound deposits in thedistrict.
文摘In the Wadi Feiran area, amphibolites occur as inclusions, bands, linear bodies of variable thickness and irregular lenses in para-geneisses. Chemical evidence indicates that these amphibolites display an igneous origin and were derived from magma essentially of tholelitic rather than alkaline composition; transitional in character between continental and island-arc. The chemistry of amphiboles, related to pressure and temperature conditions of metamorphism, showed that they were formed under low pressure and high temperature conditions.
文摘Petrochemical studies indicate that the Yanghou metamorphic ultramafic rocks are composed of metamorphosed harzburgite and ultramafic cumulate. Trace element geochemistry and mineral chemistry of the metamorphic harzburgite indicate that they are relicts of depleted mantle. Systematic petrochemical, mineral chemical and geochronological studies led to such a conclusion that the Yanghou metamorphic ultramafic rocks may be the components of Late Sinian Early Paleozoic ophiolites in South China.
基金JPS acknowledges Delhi University for financial support towards this work in the form of R&D Project Grant(No.DRCH/R&D/2012-2013/4155).
文摘Paleoproterozoic Bijawars of the Sonrai basin consists of(a) Sonrai(mostly carbonate carbonaceous shale and phosphatic breccia) and(b) Solda Formations(commonly chloritic and ferruginous shale) with well-developed clay-organo-rich facies,often marked with hydrothermal activities.Previous studies revealed abundance order of kaolinite> chlorite> illite> smectite;and kaolinite> illite> chlorite in clay(0.2-2.0 μm) fractions separated from the Sonrai and Solda Formations,respectively.To understand atomic substitutions and trace elemental concentrations,clay minerals were analyzed by fusion ICPMS and SEM-EDS.PAAS normalized data plots show U,Th,Rb,Ba,Pb Sr,and large-ion lithophiles enrichment,whereas,Bandai sandstone and Rohini carbonate clays show HREE enrichment with asymmetrical patterns,similar to those reported from the well-established McArthur River,Cigar Lake,and Sue UTUD of Canada.For Rohni carbonate,chondrite-normalized REE data plots revealed M shape REE patterns,ascribed to Gd-Tb-Dy-Ho tetrad effect and anomalous Y,Zr,and Hf concentrations.Owing to HREE incorporation in the clay inter-layers,linear and flattened REE trends were noticed.Flat REE patterns associated with the highly altered chlorite and illite represent negative Eu anomaly related to the dilational nature of the uraninite structure and is suggestive of anoxic conditions.
