A stacked Si/SiO_(x)/C composite anode material with carbon-coated structure was prepared by sol-gel method combined with carbothermal reduction using organic silicon.The results of X-ray diffractometry, scanning elec...A stacked Si/SiO_(x)/C composite anode material with carbon-coated structure was prepared by sol-gel method combined with carbothermal reduction using organic silicon.The results of X-ray diffractometry, scanning electron microscopy, and elemental analysis show that the Si/SiO_(x)/C material is a secondary particle with a porous micronanostructure, and the presence of nanometer silicon does not affect the carbothermal reduction and carbon coating.Electrochemical test results indicate that the specific capacity and first coulombic efficiency of SiO_(x)/C composite with nanometer silicon can be increased to 1 946.05 mAh/g and 76.49%,respectively.The reversible specific capacity of Si/SiO_(x)/C material blended with graphite is 749.69 mAh/g after 100 cycles at a current density of 0.1 C,and the capacity retention rate is up to 89.03%.Therefore, the composite has excellent electrochemical cycle stability.展开更多
A series of photocatalysts of un-doped, single-doped and co-doped nanometer titanium diox- ide （TiO2） have been successfully prepared by template method using Fe（NO3）3.9H2O, La（NO3）3.6H2O, and tetrabutyl titanat...A series of photocatalysts of un-doped, single-doped and co-doped nanometer titanium diox- ide （TiO2） have been successfully prepared by template method using Fe（NO3）3.9H2O, La（NO3）3.6H2O, and tetrabutyl titanate as precursors and glucan as template. Scanning electron microscopy, X-ray diffraction, and N2 adsorption-desorption measurement were employed to characterize the morphology, crystal structure and surface structure of the samples. The photo-absorbance of the obtained catalysts was measured by UV-Vis absorption spectroscopy, and the photocatalytic activities of the prepared samples under UV and visible light were estimated by measuring the degradation rate of methyl orange in an aqueous solution. The characterizations indicated that the prepared photocatalysts consisted of anatase phase and possessed high surface area of ca. 163-176 m2/g. It was shown that the Fe and La co-doped nano-TiO2 could be activated by visible light and could thus be used as an effective catalyst in photo-oxidation reactions. The synergistic effect of Fe and La co-doping played an important role in improving the photocatalytic activity. In addition, the possibility of cyclic usage of co-doped nano-TiO2 was also confirmed, the photocatalytic activity of codoped nano-TiO2 remained above 89.6% of the fresh sample after being used four times.展开更多
Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structu...Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structure. Annealed at 500 ℃, nanometer TiO 2 with a specific surface area of 101.39 m 2 ·g -1 and a grain size about 10 nm were obtained(pH=5); and with a specific surface area of 95.48 m 2 ·g -1 and a grain size about 30 nm were obtained(pH=10). The research indicated that crystal phase transformation of rutile at 750 ℃made great promotion in grain size growth.展开更多
In the electric field and layer-to-layer interaction energy, the law of split-level of high-level Stark effect of spherical nanometer system is explored as well as the frequency of spectrum, intensity and size effect ...In the electric field and layer-to-layer interaction energy, the law of split-level of high-level Stark effect of spherical nanometer system is explored as well as the frequency of spectrum, intensity and size effect of coefficient of spontaneous radiation. Taking three layers CdS/HgS spherical nanometer system as an example, the influence of the electric field and layer-to- layer interaction energy is explored on Stark effect and spectrum. The results show that in the Stark effect system, the energy level is split based on 1, 3, ..., （2n-1）, when it is in the electric field only, similar to the hydrogen atoms; and in the electric field and layer-to-layer interaction, it is split based on 1, 4, ~ -., n2; with the quantum transition, the frequency of the spectrum decreases with the increasing size of the system; apart from a few spectral lines, the intensity of most spectral lines will decreased as the size increases; while the coefficient of spontaneous radiation will increase with the increasing size; the electric field will cause the changes of spectrum frequency; its spectrum frequency shift is proportional to the square of the electric field intensity; apart from a few spectral lines, the frequency shift of spectral lines that is caused by the electric field and layer-to-layer interaction will decrease as the size increases; the interaction will make the level of electronic energy level lower slightly （the order of magnitude is between 10-7-10-9 eV）, the slightly increased spectrum intensity and the slightly increased value of coefficient of spontaneous radiation, but it will not influence the frequency of spectrum, intensity, and the trend that coefficient of spontaneous radiation changes with the size; when the size is smaller, the layer-to-layer interaction effect will be significant.展开更多
The relation of mass, stiffness and rate of damping is obtained by using the mechanical analysis of the obstructive vibration system of two dimensions for the design of the obstructive vibration system of more freedom...The relation of mass, stiffness and rate of damping is obtained by using the mechanical analysis of the obstructive vibration system of two dimensions for the design of the obstructive vibration system of more freedom and the micro vibration test bed. The result of stimulational experiment indicates that the isolation of vibration of this system is satisfactory. The design method of vibration can be used as the reference to ultra precision machine tool, super micro orientation machanism and so on.展开更多
The nanometer cobalt blue pigments were prepared by microemulsion method. Using dynamic light scattering(DLS) test method, the influences of water content on the size of liquid drop of microemulsion and the liquid dro...The nanometer cobalt blue pigments were prepared by microemulsion method. Using dynamic light scattering(DLS) test method, the influences of water content on the size of liquid drop of microemulsion and the liquid drop of microemulsion on the final diameter of nanometer particle were studied in the course of preparation. Accordingly, the method to control the diameter of nanometer particle by changing water content was established. The nanometer cobalt blue particles were confirmed by XRD and TEM. Color parameters of pigments were determined. The quantum size effect of the pigments was discussed.展开更多
Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structu...Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structure. Annealed at 500 ℃, nanometer TiO 2 with a specific surface area of 101.39 m 2 ·g -1 and a grain size about 10 nm were obtained(pH=5); and with a specific surface area of 95.48 m 2 ·g -1 and a grain size about 30 nm were obtained(pH=10). The research indicated that crystal phase transformation of rutile at 750 ℃made great promotion in grain size growth.展开更多
The quantum phenomenological model has been proposed to investigate the magnetic property of nanometer magnetic granular film in an applied magnetic field.The magnetoresistance of the granular films with two distinct ...The quantum phenomenological model has been proposed to investigate the magnetic property of nanometer magnetic granular film in an applied magnetic field.The magnetoresistance of the granular films with two distinct magnetic phases has been calculated by using Born approximation.The results show that the average scattering cross section of the magnetic cluster decreases with the increasing number n of the atom.The origin of the giant magnetoresistance comes from the spin dependent scattering between conduction electrons and magnetic granules and the field dependence of magnetoresistance and the quadratic relation of magnetoresistance on the rate of magnetic moment are in good agreement with the experiments reported.展开更多
Nanometer crystal samarium borate with a particle size of 20～40?nm was prepared using replacing solvent drying technique. The wear resistance and load carrying capacity of 500SN base oil could be improved and the fri...Nanometer crystal samarium borate with a particle size of 20～40?nm was prepared using replacing solvent drying technique. The wear resistance and load carrying capacity of 500SN base oil could be improved and the friction coefficient could be decreased by the addition of nanometer samarium borate. But the dosage of samarium borate nanoparticles had to be controlled at a relatively low level, a higher concentration of nanoparticles was not of beneficial to the tribological performance of the oil. The optimal dosage of nanometer samarium borate is 1.0%. Tribochemical reactions took place in the tribological process, which resulted in the formation of deposition products including diboron trioxide and disamarium trioxide. Fe 2B and FeB were also found on the wear scar. The improvement of tribological properties of the oil comes from the formation of deposition layer and permeating layer. [展开更多
Nanometer powders of Al Fe alloy were prepared by gas evaporation. The formation regularity of the phases in the as prepared powders and the morphology of the particles were examined. The experimental results show tha...Nanometer powders of Al Fe alloy were prepared by gas evaporation. The formation regularity of the phases in the as prepared powders and the morphology of the particles were examined. The experimental results show that chemical composition of the master alloy is the key factor which controls the chemical composition of the compound phases in nanometer powders at given evaporating temperature, the compound phases with high Fe mole fraction will form with increasing of Fe content in master alloy. Only Al 13 Fe 4, FeAl 2 and Al 2Fe compound phases form in nanometer powders in present experiment, changing of the pressure of Ar can only alter relative amounts of the compound phases in the powders. Nanometer particles with inhomogeneous tissue were obtained, which is very different from that of pure Al and Fe nanometer particles. When mole fraction of Fe in particles increases, the inhomogeneity is enhanced. [展开更多
Two kinds of TiO_2 nanometer thin films were prepared on stainless steel bythe reverse micellar and sol-gel methods, respectively. The calcined TiO_ 2 thin films werecharacterized by X-ray diffraction (XRD), atomic fo...Two kinds of TiO_2 nanometer thin films were prepared on stainless steel bythe reverse micellar and sol-gel methods, respectively. The calcined TiO_ 2 thin films werecharacterized by X-ray diffraction (XRD), atomic force microscopy (AFM), BET surface area and X-rayphotoelectron spectroscopy (XPS). Photocatalytic activity was evaluated by photocatalyticdecoloration of methyl orange aqueous solution. The results showed that the TiO_2 thin filmsprepared by reverse micellar method (designated as RM-TiO_2 films) showed higher photocatalyticactivity than those by sol-gel method (designated as SG-TiO_2 films). This is attributed to the factthat the former is composed of smaller monodispersed spherical particles with a size of about 15 nmand possesses higher surface areas.展开更多
Nanometer α-Fe2O3 catalysts were prepared by hydrolyzation in high temperature. Three kinds of precipitators, NaOH, （NH4）2CO3 and urea were used to compare the effect in the process of hydrolyzation. Nanometer size...Nanometer α-Fe2O3 catalysts were prepared by hydrolyzation in high temperature. Three kinds of precipitators, NaOH, （NH4）2CO3 and urea were used to compare the effect in the process of hydrolyzation. Nanometer sizer, transmission electron microscopy （TEM） and X-ray diffraction （XRD） were employed to test the profiles and diameters of the product particles. The test results indicate that the production is nanometer α-Fe2O3 with narrow particle size distribution （PSD） and good dispersibility. The catalysts are mixed with ammonia perchlorate （AP） in 1.0 wt.%. And the composite particles of catalysts with AP are prepared using a new solvent-nonsolvent method. Differential thermal analyzer （DTA） is employed to analysis the thermal decomposition of the composite particles and pure AP sample. The results imply that the thermal decomposition curve peaks of the samples in which nanometer α-Fe2O3 catalysts are added appear comparatively more ahead than that of pure AP sample. Among these mixtures added nanometer material, the smaller the particle diameter of catalyst is, the more ahead the thermal decomposition curve peaks of AP appear. The high and low temperature thermal decomposition curve peaks of AP mixed with the catalyst deposed by urea are more ahead of 77.8?℃ and 9.7?℃ than that of pure AP, respectively. The mechanism of the catalyst deposed by urea with smaller diameter and the distinct catalysis of the particles on the thermal decomposition of AP are discussed.展开更多
Nanometer ZnO particles were synthesized by evaporating of zinc powders of averageparticle size of 370μm studied by XRD, TEM and electron diffraction. The particleswere formed by the oxidation of evaporated zinc vapo...Nanometer ZnO particles were synthesized by evaporating of zinc powders of averageparticle size of 370μm studied by XRD, TEM and electron diffraction. The particleswere formed by the oxidation of evaporated zinc vapor in the air. It was found that the particles range from 70 to 100nm in average particle size. The effect of experimental parameters was investigated, the increase of the air flow-rates reduced the average particle size, while increasing the evaporation temperature and the amount of metal charged increased the average particle size. TEM of the particles collected showed that the crystal habits of particles have a tetrapod-like of wurtzite structure consists of four needle crystals. It was found by electron diffraction that all particles were single crystal.展开更多
The nanometer and ordinary anatase titanium dioxide(TiO_2) powders were adopted as the sonocatalysts for the degradation of methyl orange used as a model compound for the first time. It was found that the sonocatalyti...The nanometer and ordinary anatase titanium dioxide(TiO_2) powders were adopted as the sonocatalysts for the degradation of methyl orange used as a model compound for the first time. It was found that the sonocatalytic degradation effect of methyl orange in the presence of TiO_2 powder were much better than that without TiO_2, but the sonocatalytic activity of the nanometer anatase TiO_2 particle was obviously higher than that of ordinary anatase TiO_2 particle. Although there are many factors influencing sonocatalytic degradation of methyl orange, the experimental results showed that the best degradation ratio of methyl orange could be obtained when the experimental conditions were: initial concentration 15 mg/L, nanometer anatase TiO_2 adding amount 750 mg/L, ultrasonic frequency 40 kHz, output power 50 W, pH = 3.0 and temperature 40℃ within 150 min. In addition, the catalytic activity of reused nanometer anatase TiO_2 catalyst was also studied and found to decline gradually comparing with initial nanometer anatase TiO_2 catalyst. All experiments indicated that the method of the sonocatalytic degradation of organic pollutants in the presence of TiO_2 powder was an advisable choice for non- or low-transparent organic wastewaters.展开更多
A new method of using nanometer TiO 2 as solid phase extractant coupled with ICP AES was proposed for speciation of rare earth elements. The adsorption behavior of rare earth complexes on nanometer TiO 2 was inves...A new method of using nanometer TiO 2 as solid phase extractant coupled with ICP AES was proposed for speciation of rare earth elements. The adsorption behavior of rare earth complexes on nanometer TiO 2 was investigated. Effect of pH value, contact time, elution solution and interfering ions on the recovery of the rare earth complexes were studied. A quantitative recovery (>90%) was found in the pH range of 4～9.0 for Eu citric, 4.5～9.0 for Eu oxine and Eu HIBA, and 6.5～9.0 for Eu 3+ . Eu EDTA can not be adsorbed in the pH range studied. There is large difference in the adsorption behavior on nanometer TiO 2 between rare earth element and its complexes. The possibility of application of nanometer TiO 2 on the speciation of rare earth element was explored.展开更多
Nanometer Al_2O_3 is one of new types of functional materials with broad application and development prospects in the future. The basic principle and ways of nanometer Al_2O_3 fabricated using sol-gel technique were i...Nanometer Al_2O_3 is one of new types of functional materials with broad application and development prospects in the future. The basic principle and ways of nanometer Al_2O_3 fabricated using sol-gel technique were introduced, and the factors affecting nanometer Al_2O_3 fabricated using sol-gel method were analyzed. The progress in research on nanometer Al_2O_3 and the application fields of nanometer Al_2O_3 were reviewed. The existing problems and the problems prospect for nanometer Al_2O_3 were pointed out.展开更多
By loading nanometer anatase onto exfoliated graphite with the sol-gel method, exfoliated graphite-TiO2 composite （EG-TiO2） can be prepared, which can adsorb oil and can also degrade oil. In a technologic condition ...By loading nanometer anatase onto exfoliated graphite with the sol-gel method, exfoliated graphite-TiO2 composite （EG-TiO2） can be prepared, which can adsorb oil and can also degrade oil. In a technologic condition for preparing EG-TiO2, the impregnated number of times is the most important factor to influence oil-adsorbing capability, that is, when the impregnated number of times increases, the amount of saturation-adsorbed oil decreases. The study of EG-TiO2 photocatalytic degradation of machine oil based on the weight-loss method and infrared spectrum method indicates that EG-TiO2 has obvious effect of photocatalytic degradation for machine oil. Its performance is superior to pure nanometer TiO2 powder because nanometer TiO2 in EG-TiO2 has three-dimension laminar structure and comparatively high adsorption capability.展开更多
The effects of nanometer realgar uterine cervix cancer cell line SiHa cells and suspension on proliferation and apoptosis of human oncogenic genes HPV16E6/E7 were investigated. A ＂micro-jet effiux＂ strategy was used...The effects of nanometer realgar uterine cervix cancer cell line SiHa cells and suspension on proliferation and apoptosis of human oncogenic genes HPV16E6/E7 were investigated. A ＂micro-jet effiux＂ strategy was used for the preparation of nanometer realgar suspension. SiHa cells were treated with nanometer Realgar suspension in various concentrations （6.25, 12.5, 25 and 50 mg/L） for different durations （12, 24, 48 and 72 h）. The inhibitive effect of nanometer realgar suspension on growth of SiHa cells was detected by MTT method. Special morphological changes of apoptosis were observed by transmission electron microscopy （TEM） and DNA fragments electrophoresis. The apoptotic rate was quantified by flow cytometry （FCM）. The expression of HPV 16E6/E7 mRNA and protein was assayed by RT-PCR and Western blot respectively. The results showed after being treated with 25--50 mg/L nanometer realgar suspension for 48 h, the survival rate of SiHa cells was decreased, and apoptotic rate markedly increased in a time- and concentration-dependent manner. TEM and DNA electrophoresis revealed the special morphological changes of apoptosis. The apoptotic rate of SiHa cells treated with nanometer realgar suspension was significantly higher than in the control group （P〈0.01）, and G0/G1 phase arrest appeared following treatment with nanometer realgar suspension in 25 and 50 mg/L for 48 h. RT-PCR and Western blot assay indicated that nanometer realgar suspension reduced the HPV16E6/E7 gene expression. Nanometer realgar suspension could inhibit the proliferation and induce apoptosis of SiHa cells. The mechanism may be related to the down-regulation of the HPV16E6/E7 gene expression.展开更多
In view of the inadequate cementing quality in the cementation for long isolation intervals ofoil and gas wells, and considering the field practice in Tarim Oilfield, a nanometer material LC-212 was introduced as the ...In view of the inadequate cementing quality in the cementation for long isolation intervals ofoil and gas wells, and considering the field practice in Tarim Oilfield, a nanometer material LC-212 was introduced as the base stock to experimentally develop a new spacer system NMS-I, in combination with other materials, including a chemical gel plugging agent, carboxymethyl cellulose and barite. Experimental results indicated that the system had a wide adjustable range of density, good rheological property, static stability and compatibility with cement slurry. It also showed no flocculating or thickening effect on the water-base drilling fluid and low-density cement system. Meanwhile, the capacity of lost circulation control and the influence of the spacer on the second interfacial cementing strength were evaluated by a self-made lost circulation simulator and shearing test facility. The results showed that the spacer had favorable plugging and flushing effect, and the second interfacial cementing strength can be greatly improved. Moreover, based on the experiments, the mechanisms of spacer function were analyzed. The results obtained from the investigation offer a novel approach to resolving some practical problems in cementing jobs.展开更多
文摘A stacked Si/SiO_(x)/C composite anode material with carbon-coated structure was prepared by sol-gel method combined with carbothermal reduction using organic silicon.The results of X-ray diffractometry, scanning electron microscopy, and elemental analysis show that the Si/SiO_(x)/C material is a secondary particle with a porous micronanostructure, and the presence of nanometer silicon does not affect the carbothermal reduction and carbon coating.Electrochemical test results indicate that the specific capacity and first coulombic efficiency of SiO_(x)/C composite with nanometer silicon can be increased to 1 946.05 mAh/g and 76.49%,respectively.The reversible specific capacity of Si/SiO_(x)/C material blended with graphite is 749.69 mAh/g after 100 cycles at a current density of 0.1 C,and the capacity retention rate is up to 89.03%.Therefore, the composite has excellent electrochemical cycle stability.
文摘A series of photocatalysts of un-doped, single-doped and co-doped nanometer titanium diox- ide （TiO2） have been successfully prepared by template method using Fe（NO3）3.9H2O, La（NO3）3.6H2O, and tetrabutyl titanate as precursors and glucan as template. Scanning electron microscopy, X-ray diffraction, and N2 adsorption-desorption measurement were employed to characterize the morphology, crystal structure and surface structure of the samples. The photo-absorbance of the obtained catalysts was measured by UV-Vis absorption spectroscopy, and the photocatalytic activities of the prepared samples under UV and visible light were estimated by measuring the degradation rate of methyl orange in an aqueous solution. The characterizations indicated that the prepared photocatalysts consisted of anatase phase and possessed high surface area of ca. 163-176 m2/g. It was shown that the Fe and La co-doped nano-TiO2 could be activated by visible light and could thus be used as an effective catalyst in photo-oxidation reactions. The synergistic effect of Fe and La co-doping played an important role in improving the photocatalytic activity. In addition, the possibility of cyclic usage of co-doped nano-TiO2 was also confirmed, the photocatalytic activity of codoped nano-TiO2 remained above 89.6% of the fresh sample after being used four times.
文摘Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structure. Annealed at 500 ℃, nanometer TiO 2 with a specific surface area of 101.39 m 2 ·g -1 and a grain size about 10 nm were obtained(pH=5); and with a specific surface area of 95.48 m 2 ·g -1 and a grain size about 30 nm were obtained(pH=10). The research indicated that crystal phase transformation of rutile at 750 ℃made great promotion in grain size growth.
文摘In the electric field and layer-to-layer interaction energy, the law of split-level of high-level Stark effect of spherical nanometer system is explored as well as the frequency of spectrum, intensity and size effect of coefficient of spontaneous radiation. Taking three layers CdS/HgS spherical nanometer system as an example, the influence of the electric field and layer-to- layer interaction energy is explored on Stark effect and spectrum. The results show that in the Stark effect system, the energy level is split based on 1, 3, ..., （2n-1）, when it is in the electric field only, similar to the hydrogen atoms; and in the electric field and layer-to-layer interaction, it is split based on 1, 4, ~ -., n2; with the quantum transition, the frequency of the spectrum decreases with the increasing size of the system; apart from a few spectral lines, the intensity of most spectral lines will decreased as the size increases; while the coefficient of spontaneous radiation will increase with the increasing size; the electric field will cause the changes of spectrum frequency; its spectrum frequency shift is proportional to the square of the electric field intensity; apart from a few spectral lines, the frequency shift of spectral lines that is caused by the electric field and layer-to-layer interaction will decrease as the size increases; the interaction will make the level of electronic energy level lower slightly （the order of magnitude is between 10-7-10-9 eV）, the slightly increased spectrum intensity and the slightly increased value of coefficient of spontaneous radiation, but it will not influence the frequency of spectrum, intensity, and the trend that coefficient of spontaneous radiation changes with the size; when the size is smaller, the layer-to-layer interaction effect will be significant.
文摘The relation of mass, stiffness and rate of damping is obtained by using the mechanical analysis of the obstructive vibration system of two dimensions for the design of the obstructive vibration system of more freedom and the micro vibration test bed. The result of stimulational experiment indicates that the isolation of vibration of this system is satisfactory. The design method of vibration can be used as the reference to ultra precision machine tool, super micro orientation machanism and so on.
文摘The nanometer cobalt blue pigments were prepared by microemulsion method. Using dynamic light scattering(DLS) test method, the influences of water content on the size of liquid drop of microemulsion and the liquid drop of microemulsion on the final diameter of nanometer particle were studied in the course of preparation. Accordingly, the method to control the diameter of nanometer particle by changing water content was established. The nanometer cobalt blue particles were confirmed by XRD and TEM. Color parameters of pigments were determined. The quantum size effect of the pigments was discussed.
文摘Nanometer TiO 2 powders were obtained from TiOSO 4 and studied by XRD, TEM and BET. The result indicated that pH and heat treatment temperature have great effects on their grain size and crystal phase structure. Annealed at 500 ℃, nanometer TiO 2 with a specific surface area of 101.39 m 2 ·g -1 and a grain size about 10 nm were obtained(pH=5); and with a specific surface area of 95.48 m 2 ·g -1 and a grain size about 30 nm were obtained(pH=10). The research indicated that crystal phase transformation of rutile at 750 ℃made great promotion in grain size growth.
基金Supported by National Natural Science Foundation of China!(No.194 7710 5)
文摘The quantum phenomenological model has been proposed to investigate the magnetic property of nanometer magnetic granular film in an applied magnetic field.The magnetoresistance of the granular films with two distinct magnetic phases has been calculated by using Born approximation.The results show that the average scattering cross section of the magnetic cluster decreases with the increasing number n of the atom.The origin of the giant magnetoresistance comes from the spin dependent scattering between conduction electrons and magnetic granules and the field dependence of magnetoresistance and the quadratic relation of magnetoresistance on the rate of magnetic moment are in good agreement with the experiments reported.
文摘Nanometer crystal samarium borate with a particle size of 20～40?nm was prepared using replacing solvent drying technique. The wear resistance and load carrying capacity of 500SN base oil could be improved and the friction coefficient could be decreased by the addition of nanometer samarium borate. But the dosage of samarium borate nanoparticles had to be controlled at a relatively low level, a higher concentration of nanoparticles was not of beneficial to the tribological performance of the oil. The optimal dosage of nanometer samarium borate is 1.0%. Tribochemical reactions took place in the tribological process, which resulted in the formation of deposition products including diboron trioxide and disamarium trioxide. Fe 2B and FeB were also found on the wear scar. The improvement of tribological properties of the oil comes from the formation of deposition layer and permeating layer. [
文摘Nanometer powders of Al Fe alloy were prepared by gas evaporation. The formation regularity of the phases in the as prepared powders and the morphology of the particles were examined. The experimental results show that chemical composition of the master alloy is the key factor which controls the chemical composition of the compound phases in nanometer powders at given evaporating temperature, the compound phases with high Fe mole fraction will form with increasing of Fe content in master alloy. Only Al 13 Fe 4, FeAl 2 and Al 2Fe compound phases form in nanometer powders in present experiment, changing of the pressure of Ar can only alter relative amounts of the compound phases in the powders. Nanometer particles with inhomogeneous tissue were obtained, which is very different from that of pure Al and Fe nanometer particles. When mole fraction of Fe in particles increases, the inhomogeneity is enhanced. [
基金This project is financially supported by the National Natural Science Foundation of China (No.s 50272049, 50072016) The Excellent Young Teachers Program of MOE, China (No. (2002)350)
文摘Two kinds of TiO_2 nanometer thin films were prepared on stainless steel bythe reverse micellar and sol-gel methods, respectively. The calcined TiO_ 2 thin films werecharacterized by X-ray diffraction (XRD), atomic force microscopy (AFM), BET surface area and X-rayphotoelectron spectroscopy (XPS). Photocatalytic activity was evaluated by photocatalyticdecoloration of methyl orange aqueous solution. The results showed that the TiO_2 thin filmsprepared by reverse micellar method (designated as RM-TiO_2 films) showed higher photocatalyticactivity than those by sol-gel method (designated as SG-TiO_2 films). This is attributed to the factthat the former is composed of smaller monodispersed spherical particles with a size of about 15 nmand possesses higher surface areas.
文摘Nanometer α-Fe2O3 catalysts were prepared by hydrolyzation in high temperature. Three kinds of precipitators, NaOH, （NH4）2CO3 and urea were used to compare the effect in the process of hydrolyzation. Nanometer sizer, transmission electron microscopy （TEM） and X-ray diffraction （XRD） were employed to test the profiles and diameters of the product particles. The test results indicate that the production is nanometer α-Fe2O3 with narrow particle size distribution （PSD） and good dispersibility. The catalysts are mixed with ammonia perchlorate （AP） in 1.0 wt.%. And the composite particles of catalysts with AP are prepared using a new solvent-nonsolvent method. Differential thermal analyzer （DTA） is employed to analysis the thermal decomposition of the composite particles and pure AP sample. The results imply that the thermal decomposition curve peaks of the samples in which nanometer α-Fe2O3 catalysts are added appear comparatively more ahead than that of pure AP sample. Among these mixtures added nanometer material, the smaller the particle diameter of catalyst is, the more ahead the thermal decomposition curve peaks of AP appear. The high and low temperature thermal decomposition curve peaks of AP mixed with the catalyst deposed by urea are more ahead of 77.8?℃ and 9.7?℃ than that of pure AP, respectively. The mechanism of the catalyst deposed by urea with smaller diameter and the distinct catalysis of the particles on the thermal decomposition of AP are discussed.
文摘Nanometer ZnO particles were synthesized by evaporating of zinc powders of averageparticle size of 370μm studied by XRD, TEM and electron diffraction. The particleswere formed by the oxidation of evaporated zinc vapor in the air. It was found that the particles range from 70 to 100nm in average particle size. The effect of experimental parameters was investigated, the increase of the air flow-rates reduced the average particle size, while increasing the evaporation temperature and the amount of metal charged increased the average particle size. TEM of the particles collected showed that the crystal habits of particles have a tetrapod-like of wurtzite structure consists of four needle crystals. It was found by electron diffraction that all particles were single crystal.
基金Foundation item: The National Natural Science Foundation of China(No. 20371023)
文摘The nanometer and ordinary anatase titanium dioxide(TiO_2) powders were adopted as the sonocatalysts for the degradation of methyl orange used as a model compound for the first time. It was found that the sonocatalytic degradation effect of methyl orange in the presence of TiO_2 powder were much better than that without TiO_2, but the sonocatalytic activity of the nanometer anatase TiO_2 particle was obviously higher than that of ordinary anatase TiO_2 particle. Although there are many factors influencing sonocatalytic degradation of methyl orange, the experimental results showed that the best degradation ratio of methyl orange could be obtained when the experimental conditions were: initial concentration 15 mg/L, nanometer anatase TiO_2 adding amount 750 mg/L, ultrasonic frequency 40 kHz, output power 50 W, pH = 3.0 and temperature 40℃ within 150 min. In addition, the catalytic activity of reused nanometer anatase TiO_2 catalyst was also studied and found to decline gradually comparing with initial nanometer anatase TiO_2 catalyst. All experiments indicated that the method of the sonocatalytic degradation of organic pollutants in the presence of TiO_2 powder was an advisable choice for non- or low-transparent organic wastewaters.
文摘A new method of using nanometer TiO 2 as solid phase extractant coupled with ICP AES was proposed for speciation of rare earth elements. The adsorption behavior of rare earth complexes on nanometer TiO 2 was investigated. Effect of pH value, contact time, elution solution and interfering ions on the recovery of the rare earth complexes were studied. A quantitative recovery (>90%) was found in the pH range of 4～9.0 for Eu citric, 4.5～9.0 for Eu oxine and Eu HIBA, and 6.5～9.0 for Eu 3+ . Eu EDTA can not be adsorbed in the pH range studied. There is large difference in the adsorption behavior on nanometer TiO 2 between rare earth element and its complexes. The possibility of application of nanometer TiO 2 on the speciation of rare earth element was explored.
文摘Nanometer Al_2O_3 is one of new types of functional materials with broad application and development prospects in the future. The basic principle and ways of nanometer Al_2O_3 fabricated using sol-gel technique were introduced, and the factors affecting nanometer Al_2O_3 fabricated using sol-gel method were analyzed. The progress in research on nanometer Al_2O_3 and the application fields of nanometer Al_2O_3 were reviewed. The existing problems and the problems prospect for nanometer Al_2O_3 were pointed out.
文摘By loading nanometer anatase onto exfoliated graphite with the sol-gel method, exfoliated graphite-TiO2 composite （EG-TiO2） can be prepared, which can adsorb oil and can also degrade oil. In a technologic condition for preparing EG-TiO2, the impregnated number of times is the most important factor to influence oil-adsorbing capability, that is, when the impregnated number of times increases, the amount of saturation-adsorbed oil decreases. The study of EG-TiO2 photocatalytic degradation of machine oil based on the weight-loss method and infrared spectrum method indicates that EG-TiO2 has obvious effect of photocatalytic degradation for machine oil. Its performance is superior to pure nanometer TiO2 powder because nanometer TiO2 in EG-TiO2 has three-dimension laminar structure and comparatively high adsorption capability.
基金a grant from Hubei Chal-lenging Program of Science and Technology,China(No.2007AA301B38-3)
文摘The effects of nanometer realgar uterine cervix cancer cell line SiHa cells and suspension on proliferation and apoptosis of human oncogenic genes HPV16E6/E7 were investigated. A ＂micro-jet effiux＂ strategy was used for the preparation of nanometer realgar suspension. SiHa cells were treated with nanometer Realgar suspension in various concentrations （6.25, 12.5, 25 and 50 mg/L） for different durations （12, 24, 48 and 72 h）. The inhibitive effect of nanometer realgar suspension on growth of SiHa cells was detected by MTT method. Special morphological changes of apoptosis were observed by transmission electron microscopy （TEM） and DNA fragments electrophoresis. The apoptotic rate was quantified by flow cytometry （FCM）. The expression of HPV 16E6/E7 mRNA and protein was assayed by RT-PCR and Western blot respectively. The results showed after being treated with 25--50 mg/L nanometer realgar suspension for 48 h, the survival rate of SiHa cells was decreased, and apoptotic rate markedly increased in a time- and concentration-dependent manner. TEM and DNA electrophoresis revealed the special morphological changes of apoptosis. The apoptotic rate of SiHa cells treated with nanometer realgar suspension was significantly higher than in the control group （P〈0.01）, and G0/G1 phase arrest appeared following treatment with nanometer realgar suspension in 25 and 50 mg/L for 48 h. RT-PCR and Western blot assay indicated that nanometer realgar suspension reduced the HPV16E6/E7 gene expression. Nanometer realgar suspension could inhibit the proliferation and induce apoptosis of SiHa cells. The mechanism may be related to the down-regulation of the HPV16E6/E7 gene expression.
文摘In view of the inadequate cementing quality in the cementation for long isolation intervals ofoil and gas wells, and considering the field practice in Tarim Oilfield, a nanometer material LC-212 was introduced as the base stock to experimentally develop a new spacer system NMS-I, in combination with other materials, including a chemical gel plugging agent, carboxymethyl cellulose and barite. Experimental results indicated that the system had a wide adjustable range of density, good rheological property, static stability and compatibility with cement slurry. It also showed no flocculating or thickening effect on the water-base drilling fluid and low-density cement system. Meanwhile, the capacity of lost circulation control and the influence of the spacer on the second interfacial cementing strength were evaluated by a self-made lost circulation simulator and shearing test facility. The results showed that the spacer had favorable plugging and flushing effect, and the second interfacial cementing strength can be greatly improved. Moreover, based on the experiments, the mechanisms of spacer function were analyzed. The results obtained from the investigation offer a novel approach to resolving some practical problems in cementing jobs.
