Brazil and Colombia have large reserves of coal. Those reserves in Brazil are located predominantly in the south and the main reserves in Colombia are located in the north. Despite the relative ease of exploitation, t...Brazil and Colombia have large reserves of coal. Those reserves in Brazil are located predominantly in the south and the main reserves in Colombia are located in the north. Despite the relative ease of exploitation, these resources have been underestimated as a source of energy. Currently, these countries are developing projects and partnerships aiming to qualify this mineral resource, adding quality to the final product of the processing plants. In this scenario, the processing of Brazilian and Colombian coal in flotation columns appears as a promising alternative, having been successful in mineral systems containing fine particles. The paper aims to study the overall process of column flotation for a specific Brazilian coal and a specific Colombian coal. The material used in this study consists of fine coal from Brazil （Copelmi） and Colombia （Cerrejon）. The objective is to recover carbonaceous matter and reduce the ash and contaminants grade. The two coals were floated using a negative bias in a 5 cm diameter conventional flotation column of 5 m high. Flotation parameter investigated included air velocity in the range 0.6 to 1.5 cm/s. For all runs, a constant negative bias of-0.25 cm/s and a pulp concentration of 8% w/w were used. For Cerrej6n coal, 300 g/ton of frother and 907 g/ton of collector was used, whereas for Copelmi coal, 600 g/ton of frother and 1,815 g/ton of collector was employed. The frother was a commercial Aerofroth 65 （AF65）, whereas the collector was Kerosene. For the Colombian coal, in general, yield, organic recovery, ash recovery and water recovery decreased with the increasing air rate. However, for Brazilian coal the air rate had no significant effect. For Colombian coal, the highest yield （60% w/w） and organic recovery （69% w/w） were obtained at the lowest air rate （0.6 cm/s）.展开更多
MoS2/Zr composite films were deposited on the cemented carbide YT14 （WC＋14%TiC＋6%Co） by medium-frequency magnetron sputtered and coupled with multi-arc ion plated techniques.The influence of negative bias voltage ...MoS2/Zr composite films were deposited on the cemented carbide YT14 （WC＋14%TiC＋6%Co） by medium-frequency magnetron sputtered and coupled with multi-arc ion plated techniques.The influence of negative bias voltage on the composite film properties,including adhesion strength,micro-hardness,thickness and tribological properties were investigated.The results showed that proper negative bias voltage could significantly improve the mechanical and tribological properties of composite films.The effects of negative bias voltage on film properties were also put forward.The optimal negative bias voltage was -200 V under this experiment conditions.The obtained composite films were dense,the adhesion strength was about 60 N,the thickness was about 2.4 μm,and the micro-hardness was about 9.0 GPa.The friction coefficient and wear rate was 0.12 and 2.1×10-7 cm3/N·m respectively after 60 m sliding operation against hardened steel under a load of 20 N and a sliding speed of 200 rev·min-1.展开更多
The NBTI degradation phenomenon and the role of hydrogen during NBT stress are presented in this paper. It is found that PBT stress can recover a fraction of Vth shift induced by NBT1. However, this recovery is unstab...The NBTI degradation phenomenon and the role of hydrogen during NBT stress are presented in this paper. It is found that PBT stress can recover a fraction of Vth shift induced by NBT1. However, this recovery is unstable. The original degradation reappears soon after reapplication of the NBT stress condition. Hydrogen-related species play a key role during a device＇s NBT degradation. Experimental results show that the diffusion species are neutral, they repassivate Si dangling bond which is independent of the gate voltage polaxity. In addition to the diffusion towards gate oxide, hydrogen diffusion to Si-substrate must be taken into account for it also has important influence on device degradation during NBT stress.展开更多
This paper studies the effect of drain bias on ultra-short p-channel metal-oxide-semiconductor field-effect transistor （PMOSFET） degradation during negative bias temperature （NBT） stress. When a relatively large g...This paper studies the effect of drain bias on ultra-short p-channel metal-oxide-semiconductor field-effect transistor （PMOSFET） degradation during negative bias temperature （NBT） stress. When a relatively large gate voltage is applied, the degradation magnitude is much more than the drain voltage which is the same as the gate voltage supplied, and the time exponent gets larger than that of the NBT instability （NBTI）. With decreasing drain voltage, the degradation magnitude and the time exponent all get smaller. At some values of the drain voltage, the degradation magnitude is even smaller than that of NBTI, and when the drain voltage gets small enough, the exhibition of degradation becomes very similar to the NBTI degradation. When a relatively large drain voltage is applied, with decreasing gate voltage, the degradation magnitude gets smaller. However, the time exponent becomes larger. With the help of electric field simulation, this paper concludes that the degradation magnitude is determined by the vertical electric field of the oxide, the amount of hot holes generated by the strong channel lateral electric field at the gate/drain overlap region, and the time exponent is mainly controlled by localized damage caused by the lateral electric field of the oxide in the gate/drain overlap region where hot carriers are produced.展开更多
The effect of the static negative bias temperature （NBT） stress on a p-channel power metal-oxide-semiconductor field-effect transistor （MOSFET） is investigated by experiment and simulation. The time evolution of t...The effect of the static negative bias temperature （NBT） stress on a p-channel power metal-oxide-semiconductor field-effect transistor （MOSFET） is investigated by experiment and simulation. The time evolution of the negative bias temperature instability （NBTI） degradation has the trend predicted by the reaction-diffusion （R-D） model but with an exaggerated time scale. The phenomena of the flat-roof section are observed under various stress conditions, which can be considered as the dynamic equilibrium phase in the R-D process. Based on the simulated results, the variation of the flat-roof section with the stress condition can be explained.展开更多
The effect of substrate bias on the degradation during applying a negative bias temperature （NBT） stress is studied in this paper. With a smaller gate voltage stress applied, the degradation of negative bias tempera...The effect of substrate bias on the degradation during applying a negative bias temperature （NBT） stress is studied in this paper. With a smaller gate voltage stress applied, the degradation of negative bias temperature instability （NBTI） is enhanced, and there comes forth an inflexion point. The degradation pace turns larger when the substrate bias is higher than the inflexion point. The substrate hot holes can be injected into oxide and generate additional oxide traps, inducing an inflexion phenomenon. When a constant substrate bias stress is applied, as the gate voltage stress increases, an inflexion comes into being also. The higher gate voltage causes the electrons to tunnel into the substrate from the poly, thereby generating the electro,hole pairs by impact ionization. The holes generated by impact ionization and the holes from the substrate all can be accelerated to high energies by the substrate bias. More additional oxide traps can be produced, and correspondingly, the degradation is strengthened by the substrate bias. The results of the alternate stress experiment show that the interface traps generated by the hot holes cannot be annealed, which is different from those generated by common holes.展开更多
Hot carrier injection （HCI） at high temperatures and different values of gate bias Vg has been performed in order to study the actions of negative bias temperature instability （NBTI） and hot carriers. Hot-carrier-...Hot carrier injection （HCI） at high temperatures and different values of gate bias Vg has been performed in order to study the actions of negative bias temperature instability （NBTI） and hot carriers. Hot-carrier-stress-induced damage at Vg = Vd, where Vd is the voltage of the transistor drain, increases as temperature rises, contrary to conventional hot carrier behaviour, which is identified as being related to the NBTI. A comparison between the actions of NBTI and hot carriers at low and high gate voltages shows that the damage behaviours are quite different： the low gate voltage stress results in an increase in transconductance, while the NBTI-dominated high gate voltage and high temperature stress causes a decrease in transconductance. It is concluded that this can be a major source of hot carrier damage at elevated temperatures and high gate voltage stressing of p-channel metal-oxide-semiconductor field-effect transistors （PMOSFETs）. We demonstrate a novel mode of NBTI-enhanced hot carrier degradation in PMOSFETs. A novel method to decouple the actions of NBTI from that of hot carriers is also presented.展开更多
A new on-line methodology is used to characterize the negative bias temperature instability （NBTI） without inherent recovery. Saturation drain voltage shift and mobility shift are extracted by ID-VD characterization...A new on-line methodology is used to characterize the negative bias temperature instability （NBTI） without inherent recovery. Saturation drain voltage shift and mobility shift are extracted by ID-VD characterizations, which were measured before stress, and after every certain stress phase, using the proportional differential operator （PDO） method. The new on-line methodology avoids the mobility linearity assumption as compared with the previous onthe-fly method. It is found that both reaction-diffusion and charge-injection processes are important in NBTI effect under either DC or AC stress. A similar activation energy, 0.15 eV, occurred in both DC and AC NBTI processes. Also degradation rate factor is independent of temperature below 90℃ and sharply increases above it. The frequency dependence of NBTI degradation shows that NBTI degradation is independent of frequencies. The carrier tunnelling and reaction-diffusion mechanisms exist simultaneously in NBTI degradation of sub-micron pMOSFETs, and the carrier tunnelling dominates the earlier NBTI stage and the reaction-diffusion mechanism follows when the generation rate of traps caused by carrier tunnelling reaches its maximum.展开更多
This paper studies negative bias temperature instability （NBTI） under alternant and alternating current （AC） stress. Under alternant stress, the degradation smaller than that of single negative stress is obtained....This paper studies negative bias temperature instability （NBTI） under alternant and alternating current （AC） stress. Under alternant stress, the degradation smaller than that of single negative stress is obtained. The smaller degradation is resulted from the recovery of positive stress. There are two reasons for the recovery. One is the passivation of H dangling bonds, and another is the detrapping of charges trapped in the oxide. Under different frequencies of AC stress, the parameters all show regular degradation, and also smaller than that of the direct current stress. The higher the frequency is, the smaller the degradation becomes. As the negative stress time is too small under higher frequency, the deeper defects are hard to be filled in. Therefore, the detrapping of oxide charges is easy to occur under positive bias and the degradation is smaller with higher frequency.展开更多
The exponent n of the generation of an interface trap （Nit）, which contributes to the power-law negative bias temperature instability （NBTI） degradation, and the exponent’s time evolution are investigated by simu...The exponent n of the generation of an interface trap （Nit）, which contributes to the power-law negative bias temperature instability （NBTI） degradation, and the exponent’s time evolution are investigated by simulations with varying the stress voltage Vg and temperature T. It is found that the exponent n in the diffusion-limited phase of the degradation process is irrelevant to both Vg and T. The time evolution of the exponent n is affected by the stress conditions, which is reflected in the shift of the onset of the diffusion-limited phase. According to the diffusion profiles, the generation of the atomic hydrogen species, which is equal to the buildup of Nit, is strongly correlated with the stress conditions, whereas the diffusion of the hydrogen species shows Vg-unaffected but T-affected relations through the normalized results.展开更多
The effect of negative bias temperature instability （NBTI） on a single event transient （SET） has been studied in a 130 nm bulk silicon CMOS process based on 3D TCAD device simulations. The investigation shows that...The effect of negative bias temperature instability （NBTI） on a single event transient （SET） has been studied in a 130 nm bulk silicon CMOS process based on 3D TCAD device simulations. The investigation shows that NBTI can result in the pulse width and amplitude of SET narrowing when the heavy ion hits the PMOS in the high-input inverter; but NBTI can result in the pulse width and amplitude of SET broadening when the heavy ion hits the NMOS in the low-input inverter. Based on this study, for the first time we propose that the impact of NBTI on a SET produced by the heavy ion hitting the NMOS has already been a significant reliability issue and should be of wide concern, and the radiation hardened design must consider the impact of NBTI on a SET.展开更多
A new type of degradation phenomena featured with increased subthreshold swing and threshold voltage after negative gate bias stress(NBS)is observed for amorphous InGaZnO(a-IGZO)thin-film transistors(TFTs),which can r...A new type of degradation phenomena featured with increased subthreshold swing and threshold voltage after negative gate bias stress(NBS)is observed for amorphous InGaZnO(a-IGZO)thin-film transistors(TFTs),which can recover in a short time.After comparing with the degradation phenomena under negative bias illumination stress(NBIS),positive bias stress(PBS),and positive bias illumination stress(PBIS),degradation mechanisms under NBS is proposed to be the generation of singly charged oxygen vacancies(V_(o)^(+))in addition to the commonly reported doubly charged oxygen vacancies(V_(o)^(2+)).Furthermore,the NBS degradation phenomena can only be observed when the transfer curves after NBS are measured from the negative gate bias to the positive gate bias direction due to the fast recovery of V_(o)^(+)under positive gate bias.The proposed degradation mechanisms are verified by TCAD simulation.展开更多
The negative gate bias stress(NBS)reliability of n-type polycrystalline silicon(poly-Si)thin-film transistors(TFTs)with a distinct defective grain boundary(GB)in the channel is investigated.Results show that conventio...The negative gate bias stress(NBS)reliability of n-type polycrystalline silicon(poly-Si)thin-film transistors(TFTs)with a distinct defective grain boundary(GB)in the channel is investigated.Results show that conventional NBS degradation with negative shift of the transfer curves is absent.The on-state current is decreased,but the subthreshold characteristics are not affected.The gate bias dependence of the drain leakage current at V_(ds)of 5.0 V is suppressed,whereas the drain leakage current at V_(ds)of 0.1 V exhibits obvious gate bias dependence.As confirmed via TCAD simulation,the corresponding mechanisms are proposed to be trap state generation in the GB region,positive-charge local formation in the gate oxide near the source and drain,and trap state introduction in the gate oxide.展开更多
An analytical model is proposed to calculate single event transient (SET) pulse width with bulk complementary metal oxide semiconductor (CMOS) technology based on the physics of semiconductor devices. Combining with t...An analytical model is proposed to calculate single event transient (SET) pulse width with bulk complementary metal oxide semiconductor (CMOS) technology based on the physics of semiconductor devices. Combining with the most prevalent negative bias temperature instability (NBTI) degradation model, a novel analytical model is developed to predict the time evolution of the NBTI induced SET broadening in the production, and NBTI experiments and three-dimensional numerical device simulations are used to verify the model. At the same time, an analytical model to predict the time evolution of the NBTI induced SET broadening in the propagation is also proposed, and NBTI experiments and the simulation program with integrated circuit emphasis (SPICE) are used to verify the proposed model.展开更多
NiCu films about 60nm thick were deposited on MgO (001) substrates at 230℃ by DC plasma-sputtering at 2.7kV and 8mA in pure Ar gas using a Ni90Cu10 target. A DC bias voltage of 0, 60, 110 or 140V was applied to the ...NiCu films about 60nm thick were deposited on MgO (001) substrates at 230℃ by DC plasma-sputtering at 2.7kV and 8mA in pure Ar gas using a Ni90Cu10 target. A DC bias voltage of 0, 60, 110 or 140V was applied to the substrate during deposition. The adhesion of the film to the substrate was studied using a scratch test as a function of . The application of is very effective in increasing the adhesion of the film to the substrate. In conclusion, the adhesion increases with cleaning the substrate surface by sputtering off impurity admolecules during the film initial formation due to the energetic Ar ion particle bombardment.展开更多
Amorphous carbon films were deposited on single-crystalline silicon and K9glass by pulse laser ablation using different negative substrate bias. Scanning electron microscope(SEM) was used to observe morphology of the ...Amorphous carbon films were deposited on single-crystalline silicon and K9glass by pulse laser ablation using different negative substrate bias. Scanning electron microscope(SEM) was used to observe morphology of the surface. Thickness and refractive index of the filmdeposited on K9 glass were measured by ellipsometry. Micro-hardness of films was measured relativelyto single crystal silicon. All films deposited on silicon were analyzed by Raman spectra. Allspectra were deconvoluted to three peaks. Line-width ratios varied similarly with bias voltage whenthe laser energy was kept invariant.展开更多
Degradation induced by the negative bias temperature instability(NBTI)can be attributed to three mutually uncoupled physical mechanisms,i.e.,the generation of interface traps(ΔV_(IT)),hole trapping in pre-existing ga...Degradation induced by the negative bias temperature instability(NBTI)can be attributed to three mutually uncoupled physical mechanisms,i.e.,the generation of interface traps(ΔV_(IT)),hole trapping in pre-existing gate oxide defects(ΔV_(HT)),and the generation of gate oxide defects(ΔV_(OT)).In this work,the characteristic of NBTI for p-type MOSFET fabricated by using a 28-nm high-k metal gate(HKMG)process is thoroughly studied.The experimental results show that the degradation is enhanced at a larger stress bias and higher temperature.The effects of the three underlying subcomponents are evaluated by using the comprehensive models.It is found that the generation of interface traps dominates the NBTI degradation during long-time NBTI stress.Moreover,the NBTI parameters of the power-law time exponent and temperature activation energy as well as the gate oxide field acceleration are extracted.The dependence of operating lifetime on stress bias and temperature is also discussed.It is observed that NBTI lifetime significantly decreases as the stress increases.Furthermore,the decrease of charges related to interface traps and hole detrapping in pre-existing gate oxide defects are used to explain the recovery mechanism after stress.展开更多
In this study we investigate the dynamic recovery effects in IRF9520 commercial p-channel power vertical double diffused metal-oxide semiconductor field-effect transistors（VDMOSFETs） subjected to negative bias tempe...In this study we investigate the dynamic recovery effects in IRF9520 commercial p-channel power vertical double diffused metal-oxide semiconductor field-effect transistors（VDMOSFETs） subjected to negative bias temperature（NBT）stressing under the particular pulsed bias. Particular values of the pulsed stress voltage frequency and duty cycle are chosen in order to analyze the recoverable and permanent components of stress-induced threshold voltage shift in detail. The results are discussed in terms of the mechanisms responsible for buildup of oxide charge and interface traps. The partial recovery during the low level of pulsed gate voltage is ascribed to the removal of recoverable component of degradation, i.e., to passivation/neutralization of shallow oxide traps that are not transformed into the deeper traps（permanent component）.Considering the value of characteristic time constant associated with complete removal of the recoverable component of degradation, it is shown that by selecting an appropriate combination of the frequency and duty cycle, the threshold voltage shifts induced under the pulsed negative bias temperature stress conditions can be significantly reduced, which may be utilized for improving the device lifetime in real application circuits.展开更多
Negative bias temperature instability（NBTI） has become a serious reliability issue, and the interface traps and oxide charges play an important role in the degradation process. In this paper, we study the recovery o...Negative bias temperature instability（NBTI） has become a serious reliability issue, and the interface traps and oxide charges play an important role in the degradation process. In this paper, we study the recovery of NBTI systemically under different conditions in the P-type metal–oxide–semiconductor field effect transistor（PMOSFET）, explain the various recovery phenomena, and find the possible processes of the recovery.展开更多
The impact of negative bias temperature instability （NBTI） can be ascribed to three mutually uncorrelated factors, including hole trapping by pre-existing traps （△ VHT） in gate insulator, generated traps （△ VOT...The impact of negative bias temperature instability （NBTI） can be ascribed to three mutually uncorrelated factors, including hole trapping by pre-existing traps （△ VHT） in gate insulator, generated traps （△ VOT） in bulk insulator, and interface trap generation （△ VIT）. In this paper, we have experimentally investigated the NBTI characteristic for a 40-nm complementary metal-oxide semiconductor （CMOS） process. The power-law time dependence, temperature activation, and field acceleration have also been explored based on the physical reaction-diffusion model. Moreover, the end-of-life of stressed device dependent on the variation of stress field and temperature have been evaluated. With the consideration of locking effect, the recovery characteristics have been modelled and discussed.展开更多
文摘Brazil and Colombia have large reserves of coal. Those reserves in Brazil are located predominantly in the south and the main reserves in Colombia are located in the north. Despite the relative ease of exploitation, these resources have been underestimated as a source of energy. Currently, these countries are developing projects and partnerships aiming to qualify this mineral resource, adding quality to the final product of the processing plants. In this scenario, the processing of Brazilian and Colombian coal in flotation columns appears as a promising alternative, having been successful in mineral systems containing fine particles. The paper aims to study the overall process of column flotation for a specific Brazilian coal and a specific Colombian coal. The material used in this study consists of fine coal from Brazil （Copelmi） and Colombia （Cerrejon）. The objective is to recover carbonaceous matter and reduce the ash and contaminants grade. The two coals were floated using a negative bias in a 5 cm diameter conventional flotation column of 5 m high. Flotation parameter investigated included air velocity in the range 0.6 to 1.5 cm/s. For all runs, a constant negative bias of-0.25 cm/s and a pulp concentration of 8% w/w were used. For Cerrej6n coal, 300 g/ton of frother and 907 g/ton of collector was used, whereas for Copelmi coal, 600 g/ton of frother and 1,815 g/ton of collector was employed. The frother was a commercial Aerofroth 65 （AF65）, whereas the collector was Kerosene. For the Colombian coal, in general, yield, organic recovery, ash recovery and water recovery decreased with the increasing air rate. However, for Brazilian coal the air rate had no significant effect. For Colombian coal, the highest yield （60% w/w） and organic recovery （69% w/w） were obtained at the lowest air rate （0.6 cm/s）.
基金Funded by the National Natural Science Foundation of China (No.51075237)the National Basic Research Program of China (No.2009CB724402)+3 种基金the Taishan Scholar Program of Shandong Provincethe Outstanding Young Scholar Science Foundation of Shandong (No.JQ200917)the National Natural Science Foundation of Shandong (No.ZR2010EZ002)National High Technology Research and Development Program (No.2009AA044303)
文摘MoS2/Zr composite films were deposited on the cemented carbide YT14 （WC＋14%TiC＋6%Co） by medium-frequency magnetron sputtered and coupled with multi-arc ion plated techniques.The influence of negative bias voltage on the composite film properties,including adhesion strength,micro-hardness,thickness and tribological properties were investigated.The results showed that proper negative bias voltage could significantly improve the mechanical and tribological properties of composite films.The effects of negative bias voltage on film properties were also put forward.The optimal negative bias voltage was -200 V under this experiment conditions.The obtained composite films were dense,the adhesion strength was about 60 N,the thickness was about 2.4 μm,and the micro-hardness was about 9.0 GPa.The friction coefficient and wear rate was 0.12 and 2.1×10-7 cm3/N·m respectively after 60 m sliding operation against hardened steel under a load of 20 N and a sliding speed of 200 rev·min-1.
基金Project supported by the National Natural Science Foundation of China （Grant No 60206006）, the Hi-Tech Research ＆ Development Program of China （Grant No 2004AA1Z1070） and the Key Project of Chinese Ministry of Education （Grant No 104172）.
文摘The NBTI degradation phenomenon and the role of hydrogen during NBT stress are presented in this paper. It is found that PBT stress can recover a fraction of Vth shift induced by NBT1. However, this recovery is unstable. The original degradation reappears soon after reapplication of the NBT stress condition. Hydrogen-related species play a key role during a device＇s NBT degradation. Experimental results show that the diffusion species are neutral, they repassivate Si dangling bond which is independent of the gate voltage polaxity. In addition to the diffusion towards gate oxide, hydrogen diffusion to Si-substrate must be taken into account for it also has important influence on device degradation during NBT stress.
基金Project supported by the National Natural Science Foundation of China (Grant Nos. 60736033 and 60376024)the National Key Technology Research and Development Program of the Ministry of Science and Technology of China (Grant No. 2007BAK25B03)
文摘This paper studies the effect of drain bias on ultra-short p-channel metal-oxide-semiconductor field-effect transistor （PMOSFET） degradation during negative bias temperature （NBT） stress. When a relatively large gate voltage is applied, the degradation magnitude is much more than the drain voltage which is the same as the gate voltage supplied, and the time exponent gets larger than that of the NBT instability （NBTI）. With decreasing drain voltage, the degradation magnitude and the time exponent all get smaller. At some values of the drain voltage, the degradation magnitude is even smaller than that of NBTI, and when the drain voltage gets small enough, the exhibition of degradation becomes very similar to the NBTI degradation. When a relatively large drain voltage is applied, with decreasing gate voltage, the degradation magnitude gets smaller. However, the time exponent becomes larger. With the help of electric field simulation, this paper concludes that the degradation magnitude is determined by the vertical electric field of the oxide, the amount of hot holes generated by the strong channel lateral electric field at the gate/drain overlap region, and the time exponent is mainly controlled by localized damage caused by the lateral electric field of the oxide in the gate/drain overlap region where hot carriers are produced.
基金Project supported by the National Basic Research Program of China(Grant No.2011CBA00606)the National Natural Science Foundation of China(Grant No.61106106)
文摘The effect of the static negative bias temperature （NBT） stress on a p-channel power metal-oxide-semiconductor field-effect transistor （MOSFET） is investigated by experiment and simulation. The time evolution of the negative bias temperature instability （NBTI） degradation has the trend predicted by the reaction-diffusion （R-D） model but with an exaggerated time scale. The phenomena of the flat-roof section are observed under various stress conditions, which can be considered as the dynamic equilibrium phase in the R-D process. Based on the simulated results, the variation of the flat-roof section with the stress condition can be explained.
基金Project supported by the National Natural Science Foundation of China (Grant Nos 60376024,60736033 and 60506020)the National High Technology Research and Development Program of China (Grant No 2003AA1Z1630)
文摘The effect of substrate bias on the degradation during applying a negative bias temperature （NBT） stress is studied in this paper. With a smaller gate voltage stress applied, the degradation of negative bias temperature instability （NBTI） is enhanced, and there comes forth an inflexion point. The degradation pace turns larger when the substrate bias is higher than the inflexion point. The substrate hot holes can be injected into oxide and generate additional oxide traps, inducing an inflexion phenomenon. When a constant substrate bias stress is applied, as the gate voltage stress increases, an inflexion comes into being also. The higher gate voltage causes the electrons to tunnel into the substrate from the poly, thereby generating the electro,hole pairs by impact ionization. The holes generated by impact ionization and the holes from the substrate all can be accelerated to high energies by the substrate bias. More additional oxide traps can be produced, and correspondingly, the degradation is strengthened by the substrate bias. The results of the alternate stress experiment show that the interface traps generated by the hot holes cannot be annealed, which is different from those generated by common holes.
基金Project supported by the National Natural Science Foundation of China （Grant No 60206006）. the Program for New Century Excellent Talents of Ministry of Education of China （Grant No 681231366）. the National Defense Pre-Research Foundation of China （Grant No 51408010305DZ0168） and the Key Project of Chinese Ministry of Education （Grant No 104172）.
文摘Hot carrier injection （HCI） at high temperatures and different values of gate bias Vg has been performed in order to study the actions of negative bias temperature instability （NBTI） and hot carriers. Hot-carrier-stress-induced damage at Vg = Vd, where Vd is the voltage of the transistor drain, increases as temperature rises, contrary to conventional hot carrier behaviour, which is identified as being related to the NBTI. A comparison between the actions of NBTI and hot carriers at low and high gate voltages shows that the damage behaviours are quite different： the low gate voltage stress results in an increase in transconductance, while the NBTI-dominated high gate voltage and high temperature stress causes a decrease in transconductance. It is concluded that this can be a major source of hot carrier damage at elevated temperatures and high gate voltage stressing of p-channel metal-oxide-semiconductor field-effect transistors （PMOSFETs）. We demonstrate a novel mode of NBTI-enhanced hot carrier degradation in PMOSFETs. A novel method to decouple the actions of NBTI from that of hot carriers is also presented.
文摘A new on-line methodology is used to characterize the negative bias temperature instability （NBTI） without inherent recovery. Saturation drain voltage shift and mobility shift are extracted by ID-VD characterizations, which were measured before stress, and after every certain stress phase, using the proportional differential operator （PDO） method. The new on-line methodology avoids the mobility linearity assumption as compared with the previous onthe-fly method. It is found that both reaction-diffusion and charge-injection processes are important in NBTI effect under either DC or AC stress. A similar activation energy, 0.15 eV, occurred in both DC and AC NBTI processes. Also degradation rate factor is independent of temperature below 90℃ and sharply increases above it. The frequency dependence of NBTI degradation shows that NBTI degradation is independent of frequencies. The carrier tunnelling and reaction-diffusion mechanisms exist simultaneously in NBTI degradation of sub-micron pMOSFETs, and the carrier tunnelling dominates the earlier NBTI stage and the reaction-diffusion mechanism follows when the generation rate of traps caused by carrier tunnelling reaches its maximum.
基金Project supported by the National Key Science and Technology Special Project,China (Grant No. 2008ZX01002-002)the Fundamental Research Funds for the Central Universities,China (Grant No. JY10000904009)the Major Program and State Key Program of the National Natural Science Foundation of China (Grant Nos. 60890191 and 60736033)
文摘This paper studies negative bias temperature instability （NBTI） under alternant and alternating current （AC） stress. Under alternant stress, the degradation smaller than that of single negative stress is obtained. The smaller degradation is resulted from the recovery of positive stress. There are two reasons for the recovery. One is the passivation of H dangling bonds, and another is the detrapping of charges trapped in the oxide. Under different frequencies of AC stress, the parameters all show regular degradation, and also smaller than that of the direct current stress. The higher the frequency is, the smaller the degradation becomes. As the negative stress time is too small under higher frequency, the deeper defects are hard to be filled in. Therefore, the detrapping of oxide charges is easy to occur under positive bias and the degradation is smaller with higher frequency.
基金Project supported by the National Basic Research Program of China(Grant No.2011CBA00606)the National Natural Science Foundation of China(Grant No.61106106)the Fundamental Research Funds for the Central Universities,China(Grant No.K50511250008)
文摘The exponent n of the generation of an interface trap （Nit）, which contributes to the power-law negative bias temperature instability （NBTI） degradation, and the exponent’s time evolution are investigated by simulations with varying the stress voltage Vg and temperature T. It is found that the exponent n in the diffusion-limited phase of the degradation process is irrelevant to both Vg and T. The time evolution of the exponent n is affected by the stress conditions, which is reflected in the shift of the onset of the diffusion-limited phase. According to the diffusion profiles, the generation of the atomic hydrogen species, which is equal to the buildup of Nit, is strongly correlated with the stress conditions, whereas the diffusion of the hydrogen species shows Vg-unaffected but T-affected relations through the normalized results.
基金Project supported by the Key Program of the National Natural Science Foundation of China(No.60836004)the National Natural Science Foundation of China(Nos.61006070,61076025)
文摘The effect of negative bias temperature instability （NBTI） on a single event transient （SET） has been studied in a 130 nm bulk silicon CMOS process based on 3D TCAD device simulations. The investigation shows that NBTI can result in the pulse width and amplitude of SET narrowing when the heavy ion hits the PMOS in the high-input inverter; but NBTI can result in the pulse width and amplitude of SET broadening when the heavy ion hits the NMOS in the low-input inverter. Based on this study, for the first time we propose that the impact of NBTI on a SET produced by the heavy ion hitting the NMOS has already been a significant reliability issue and should be of wide concern, and the radiation hardened design must consider the impact of NBTI on a SET.
基金Project supported in part by the National Natural Science Foundation of China(Grant Nos.61971299 and 61974101)the Natural Science Foundation of Jiangsu Province,China(Grant No.SBK2020021406)+2 种基金the Fund from the State Key Laboratory of ASIC and System,Fudan University(Grant No.2019KF007)the Fund from the Suzhou Science and Technology Bureau(Grant No.SYG201933)the Fund from the Jiangsu Higher Education Institute of China(Grant No.19KJB510058).
文摘A new type of degradation phenomena featured with increased subthreshold swing and threshold voltage after negative gate bias stress(NBS)is observed for amorphous InGaZnO(a-IGZO)thin-film transistors(TFTs),which can recover in a short time.After comparing with the degradation phenomena under negative bias illumination stress(NBIS),positive bias stress(PBS),and positive bias illumination stress(PBIS),degradation mechanisms under NBS is proposed to be the generation of singly charged oxygen vacancies(V_(o)^(+))in addition to the commonly reported doubly charged oxygen vacancies(V_(o)^(2+)).Furthermore,the NBS degradation phenomena can only be observed when the transfer curves after NBS are measured from the negative gate bias to the positive gate bias direction due to the fast recovery of V_(o)^(+)under positive gate bias.The proposed degradation mechanisms are verified by TCAD simulation.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61971299 and 61974101)the Natural Science Foundation of Jiangsu Province of China(Grant No.BK20201201)+1 种基金the Fund from Suzhou Science and Technology Bureau(Grant No.SYG201933)the Fund from the State Key Laboratory of ASIC and System,Fudan University(Grant No.2021KF005)
文摘The negative gate bias stress(NBS)reliability of n-type polycrystalline silicon(poly-Si)thin-film transistors(TFTs)with a distinct defective grain boundary(GB)in the channel is investigated.Results show that conventional NBS degradation with negative shift of the transfer curves is absent.The on-state current is decreased,but the subthreshold characteristics are not affected.The gate bias dependence of the drain leakage current at V_(ds)of 5.0 V is suppressed,whereas the drain leakage current at V_(ds)of 0.1 V exhibits obvious gate bias dependence.As confirmed via TCAD simulation,the corresponding mechanisms are proposed to be trap state generation in the GB region,positive-charge local formation in the gate oxide near the source and drain,and trap state introduction in the gate oxide.
基金supported by the Key Program of the National Natural Science Foundation of China (Grant No. 60836004)the National Natural Science Foundation of China (Grant Nos. 61006070, 61076025)
文摘An analytical model is proposed to calculate single event transient (SET) pulse width with bulk complementary metal oxide semiconductor (CMOS) technology based on the physics of semiconductor devices. Combining with the most prevalent negative bias temperature instability (NBTI) degradation model, a novel analytical model is developed to predict the time evolution of the NBTI induced SET broadening in the production, and NBTI experiments and three-dimensional numerical device simulations are used to verify the model. At the same time, an analytical model to predict the time evolution of the NBTI induced SET broadening in the propagation is also proposed, and NBTI experiments and the simulation program with integrated circuit emphasis (SPICE) are used to verify the proposed model.
文摘NiCu films about 60nm thick were deposited on MgO (001) substrates at 230℃ by DC plasma-sputtering at 2.7kV and 8mA in pure Ar gas using a Ni90Cu10 target. A DC bias voltage of 0, 60, 110 or 140V was applied to the substrate during deposition. The adhesion of the film to the substrate was studied using a scratch test as a function of . The application of is very effective in increasing the adhesion of the film to the substrate. In conclusion, the adhesion increases with cleaning the substrate surface by sputtering off impurity admolecules during the film initial formation due to the energetic Ar ion particle bombardment.
基金This project is financially supported by the Foundation of Educational Council of Hunan Province (No.98B004)
文摘Amorphous carbon films were deposited on single-crystalline silicon and K9glass by pulse laser ablation using different negative substrate bias. Scanning electron microscope(SEM) was used to observe morphology of the surface. Thickness and refractive index of the filmdeposited on K9 glass were measured by ellipsometry. Micro-hardness of films was measured relativelyto single crystal silicon. All films deposited on silicon were analyzed by Raman spectra. Allspectra were deconvoluted to three peaks. Line-width ratios varied similarly with bias voltage whenthe laser energy was kept invariant.
文摘Degradation induced by the negative bias temperature instability(NBTI)can be attributed to three mutually uncoupled physical mechanisms,i.e.,the generation of interface traps(ΔV_(IT)),hole trapping in pre-existing gate oxide defects(ΔV_(HT)),and the generation of gate oxide defects(ΔV_(OT)).In this work,the characteristic of NBTI for p-type MOSFET fabricated by using a 28-nm high-k metal gate(HKMG)process is thoroughly studied.The experimental results show that the degradation is enhanced at a larger stress bias and higher temperature.The effects of the three underlying subcomponents are evaluated by using the comprehensive models.It is found that the generation of interface traps dominates the NBTI degradation during long-time NBTI stress.Moreover,the NBTI parameters of the power-law time exponent and temperature activation energy as well as the gate oxide field acceleration are extracted.The dependence of operating lifetime on stress bias and temperature is also discussed.It is observed that NBTI lifetime significantly decreases as the stress increases.Furthermore,the decrease of charges related to interface traps and hole detrapping in pre-existing gate oxide defects are used to explain the recovery mechanism after stress.
基金Project supported by the Fund from the Ministry of Education,Science and Technological Development of the Republic of Serbia(Grant Nos.OI-171026 and TR-32026)the Ei PCB Factory,Ni
文摘In this study we investigate the dynamic recovery effects in IRF9520 commercial p-channel power vertical double diffused metal-oxide semiconductor field-effect transistors（VDMOSFETs） subjected to negative bias temperature（NBT）stressing under the particular pulsed bias. Particular values of the pulsed stress voltage frequency and duty cycle are chosen in order to analyze the recoverable and permanent components of stress-induced threshold voltage shift in detail. The results are discussed in terms of the mechanisms responsible for buildup of oxide charge and interface traps. The partial recovery during the low level of pulsed gate voltage is ascribed to the removal of recoverable component of degradation, i.e., to passivation/neutralization of shallow oxide traps that are not transformed into the deeper traps（permanent component）.Considering the value of characteristic time constant associated with complete removal of the recoverable component of degradation, it is shown that by selecting an appropriate combination of the frequency and duty cycle, the threshold voltage shifts induced under the pulsed negative bias temperature stress conditions can be significantly reduced, which may be utilized for improving the device lifetime in real application circuits.
基金Project supported by the National Basic Research Program of China(Grant No.2011CBA00606)the National Natural Science Foundation of China(Grant Nos.61404097,61334002,61106106,and 61176130)the Fundamental Research Funds for the Central Universities,China(Grant No.JB140415)
文摘Negative bias temperature instability（NBTI） has become a serious reliability issue, and the interface traps and oxide charges play an important role in the degradation process. In this paper, we study the recovery of NBTI systemically under different conditions in the P-type metal–oxide–semiconductor field effect transistor（PMOSFET）, explain the various recovery phenomena, and find the possible processes of the recovery.
基金supported by the National Natural Science Foundation of China(Grant Nos.61574056 and 61204038)the Natural Science Funds of Shanghai,China(Grant No.14ZR1412000)+1 种基金the Fund from the Science and Technology Commission of Shanghai Municipality(Grant No.14DZ2260800)Shanghai Sailing Program(Grant No.17YF1404700)
文摘The impact of negative bias temperature instability （NBTI） can be ascribed to three mutually uncorrelated factors, including hole trapping by pre-existing traps （△ VHT） in gate insulator, generated traps （△ VOT） in bulk insulator, and interface trap generation （△ VIT）. In this paper, we have experimentally investigated the NBTI characteristic for a 40-nm complementary metal-oxide semiconductor （CMOS） process. The power-law time dependence, temperature activation, and field acceleration have also been explored based on the physical reaction-diffusion model. Moreover, the end-of-life of stressed device dependent on the variation of stress field and temperature have been evaluated. With the consideration of locking effect, the recovery characteristics have been modelled and discussed.
