For the control of surface defects in interstitial-free(IF) steel, quantitative metallographic analyses of near-surface inclusions and surface liquid flow detection via the nail-board tipping method were conducted. Th...For the control of surface defects in interstitial-free(IF) steel, quantitative metallographic analyses of near-surface inclusions and surface liquid flow detection via the nail-board tipping method were conducted. The results show that, at casting speeds of 0.8 and 1.0 m/min, a thin liquid mold flux layer forms and non-uniform floating of argon bubbles occurs, inducing the entrainment and subsequent entrapment of the liquid flux; fine inclusion particles of Al_2O_3 can also aggregate at the solidification front. At higher casting speeds of 1.4 and 1.6 m/min, the liquid mold flux can be entrained and carried deeper into the liquid steel pool because of strong level fluctuations of the liquid steel and the flux. The optimal casting speed is approximately 1.2 m/min, with the most favorable surface flow status and, correspondingly, the lowest number of inclusions near the slab surface.展开更多
Laboratory and industrial studies were carried out to investigate non-metallic inclusions in high strength alloy steel refined by high basicity and high Al_2O_3 slag.It was found that the steel/slag reaction time larg...Laboratory and industrial studies were carried out to investigate non-metallic inclusions in high strength alloy steel refined by high basicity and high Al_2O_3 slag.It was found that the steel/slag reaction time largely affected non-metallic inclusions.With the reaction time increased from 30 min to 90 min in laboratory study,MgO-Al_2O_3 spinels were gradually changed into CaO-MgO-Al_2O_3 system inclusions surrounded by softer CaO-Al_2O_3 surface layers.By using high basicity slag which contained as much as 41%Al_2O_3 in the laboratory study,ratio of low melting temperature CaO-MgO-Al_2O_3 system inclusions was remarkably increased to above 80%.In the industrial experiment,during the secondary refining,the inclusions changed in order of 'Al_2O_3→MgO-Al_2O_3→CaO-MgO-Al_2O_3'.Through the LF and RH refining,most inclusions could be transferred to lower melting temperature CaO-Al_2O_3 and CaO-MgO-Al_2O_3 system inclusions.展开更多
Buried pipelines are an essential component of the urban infrastructure of modern cities.Traditional buried pipes are mainly made of metal materials.With the development of material science and technology in recent ye...Buried pipelines are an essential component of the urban infrastructure of modern cities.Traditional buried pipes are mainly made of metal materials.With the development of material science and technology in recent years,non-metallic pipes,such as plastic pipes,ceramic pipes,and concrete pipes,are increasingly taking the place of pipes made from metal in various pipeline networks such as water supply,drainage,heat,industry,oil,and gas.The location technologies for the location of the buried metal pipeline have become mature,but detection and location technologies for the non-metallic pipelines are still developing.In this paper,current trends and future perspectives of detection and location of buried non-metallic pipelines are summarized.Initially,this paper reviews and analyzes electromagnetic induction technologies,electromagnetic wave technologies,and other physics-based technologies.It then focuses on acoustic detection and location technologies,and finally introduces emerging technologies.Then the technical characteristics of each detection and location method have been compared,with their strengths and weaknesses identified.The current trends and future perspectives of each buried non-metallic pipeline detection and location technology have also been defined.Finally,some suggestions for the future development of buried non-metallic pipeline detection and location technologies are provided.展开更多
Dear Editor,I write to present one case report of a patient suffered the panophthalmitis caused by non-metallic foreign body with no etiologic agent and recovered quickly by phacoemulsification and vitrectomy with sil...Dear Editor,I write to present one case report of a patient suffered the panophthalmitis caused by non-metallic foreign body with no etiologic agent and recovered quickly by phacoemulsification and vitrectomy with silicone oil tamponade.Ocular trauma remains a major cause of blindness, particularly in the working-age population.展开更多
In this paper, a kind of three-dimensional analysis technology for characterizing non-metallic inclusions in steel was clearly elaborated. It is an electron microscopy observation, namely the non-aqueous electrolysis ...In this paper, a kind of three-dimensional analysis technology for characterizing non-metallic inclusions in steel was clearly elaborated. It is an electron microscopy observation, namely the non-aqueous electrolysis extraction method with a settled coulometer. In the research,the extraction effects of non-metallic inclusions in different electrolysis systems were studied, and it was concluded that alkalescent 2% TEA non-aqueous electrolyte was applicable for extracting most of non-metallic inclusion particles in steel. And then, in order to ensure the microscopic characterization and statistical calculation of inclusion particles, some electrolysis parameters should be confirmed, such as the size of the sample, control of the electrolysis mass, electric current, etc. Furthermore, for preventing the disturbance of carbides and presenting clear three-dimensional appearance by microscopic characterization, magnetic separation was utilized to separate the inclusion particles from carbides, which was useful for getting more veracious types, particle sizes and chemical composition of inclusions. Moreover, through calculation of quantity and particle size of inclusions in continuous determinate fields, the total quantity per unit volume or area and the particle size distribution of inclusions could be acquired by conversion with electrolysis loss. Besides, the comparison between this method and traditional quantitative metallography was also discussed, and finally, a conclusion was drawn that both of them have respectively applications in characterizing inclusions.展开更多
In order to know the behavior of non-metallic inclusions in centrifugal induction electroslag castings (CIESC), non-metallic inclusions in 5CrMnMo and 4Cr5MoSiV1 were qualitatively and quantitatively analyzed. The lar...In order to know the behavior of non-metallic inclusions in centrifugal induction electroslag castings (CIESC), non-metallic inclusions in 5CrMnMo and 4Cr5MoSiV1 were qualitatively and quantitatively analyzed. The largest size of inclusions in the casting and the thermodynamic possibility of TiN precipitation in steel were also calculated. The results show that sulfide inclusions are evenly distributed and the content is low. The amount of oxide inclusions in CIESC: 4Cr5MoSiV1 steel is close to the ESR steel and lower than that in the EAF steel, and there are some differences along radial direction. Nitride inclusions are fine and the diameter of the largest one is 3-1 mum. With the increase of the centrifugal machine's rotational speed, the ratio of round inclusions increases and the ratio of sharp inclusions decreases. According to the experiment and the calculation results, it is pointed out that the largest diameter of non-metallic inclusions in the CIESC 4Cr5MoSiV1 casting is only 6.6 mum, and [N%][Ti%] in 4Cr5MoSiV1 steel should be controlled less than 4.4x 10(-5) in order to further reduce the amount and size of TiN inclusions.展开更多
In aluminum killed steels, the size, shape, quantity and formation of non-metallic inclusions in ladle steel (before and after RH vacuum treatment) and in tundish as well as in slabs were studied by EPMA (Electron Pro...In aluminum killed steels, the size, shape, quantity and formation of non-metallic inclusions in ladle steel (before and after RH vacuum treatment) and in tundish as well as in slabs were studied by EPMA (Electron Probe Microanalysis) and by analyzing the total oxygen. The results showed that in the slabs the total oxygen was quite low and the inclusions discovered were mainly small-sized angular alumina inclusions. This indicates that most inclusions have been removed by floating out during the continuous casting process. In addition, the countermeasures were discussed to decrease the alumina inclusions in the slabs further.展开更多
Focusing on the extending length restriction of the completion screen pipe resistance running into ultra-short radius horizontal well,this paper proposed technology of hydraulic drive completion tubular string running...Focusing on the extending length restriction of the completion screen pipe resistance running into ultra-short radius horizontal well,this paper proposed technology of hydraulic drive completion tubular string running into ultra-short radius horizontal well.Innovative hydraulic drive tools and string structure are designed,which are composed of guide tubing,hydraulic drive tubing and non-metallic completion screen pipe from inside to outside.A novel mechanical-hydraulic coupling model is established.Based on the wellbore structure of an ultra-short radius horizontal well for deep coalbed methane,the numerical calculations of force and hydraulic load on tubular strings were accomplished by the mechanical-hydraulic coupling model.The results show that the extending length of completion tubular string with the hydraulic drive is 17 times that of conventional completion technology under the same conditions.The multi-factor orthogonal design is adopted to analyze the numerical calculations,and the results show that the extending length of the completion tubular string is mainly affected by the completion tubular string structure and the friction coefficient between the non-metallic composite continuous screen pipe and the wellbore.Two series of hydraulic drive completion tubular string structures suitable for ultra-short radius horizontal wells under different conditions are optimized,with the extending limits of 381 m and 655 m,respectively.These researches will provide theoretical guidance for design and control of hydraulic drive non-metallic composite continuous completion screen pipe running into ultra-short radius horizontal wells.展开更多
Six different kinds of non-metallic or organic disinfectants were obtained in this research study including “Neutral Electrolyzed Water”, “M22” organic disinfectant solution, Superoxy Food Wash disinfectant, Hydro...Six different kinds of non-metallic or organic disinfectants were obtained in this research study including “Neutral Electrolyzed Water”, “M22” organic disinfectant solution, Superoxy Food Wash disinfectant, Hydrogen Peroxide, Clorox Germicidal Bleach and Clidox-S. The effectiveness of these disinfectants was studied against various subtypes of avian influenza virus (AIV). The virus-disinfectant mixtures were prepared in serial dilutions of each disinfectant with a constant virus titer and incubated at ambient temperature in different time intervals for virus inactivation. The virus inactivation results were determined by virus recovery in embryonating chicken eggs. Among the six different kinds of nonmetallic disinfectants obtained for this research project, Neutral Electrolyzed Water, “M22” solution, Clorox Germicidal Bleach and Clidox-S were effectively inactivated AIV with appropriate working dilutions and reaction times. Superoxy Food Wash disinfectant and Hydrogen Peroxide were found having limited effect on virus inactivation with extended exposure times of more than 2 hours. These research findings provide scientific data to poultry industry with guidelines to select and use non-metallic organic disinfectants for poultry flock sanitation and disinfection to effectively prevent and control of avian influenza outbreaks.展开更多
Non-metallic inclusions,especially the large ones,within P/M Ni-base superalloy have a major influence on fatigue characteristics,but are not directly measurable by routine inspection.In this paper,a method,automatic ...Non-metallic inclusions,especially the large ones,within P/M Ni-base superalloy have a major influence on fatigue characteristics,but are not directly measurable by routine inspection.In this paper,a method,automatic image analysis,is proposed for estimation of the content,size and amount of non-metallic inclusions in superalloy.The methodology for the practical application of this method is described and the factors affecting the precision of the estimation are discussed.In the experiment,the characteristics of the non-metallic inclusions in Ni-base P/M superalloy are analyzed.展开更多
The expansion parts and components of non-metallic in devices have become a fait accompli. In the case parts, components of non-metallic are used in atmospheres explosive and may be a potential source of ignition [1]....The expansion parts and components of non-metallic in devices have become a fait accompli. In the case parts, components of non-metallic are used in atmospheres explosive and may be a potential source of ignition [1]. Ignition hazards due to static electricity from the charged non-conductive non-metallic materials are well known [2]. The prevalence protection metal parts and components of anti-corrosion exist in any device equipped with a metal casing. Inherent risks associated services are caused by static electricity. Electrostatic phenomena arise in many situations, in a variety of environments and industries. The occurrence of charge static in many cases unexpected is unwanted and requires the use of expensive preventive measures. Brush discharge and propagating brush discharge (e.g. composite coating about non-conductive electrostatic properties of an isolated base conductive) create explosion hazard in underground endangered by firedamp and/or coal dust [3].展开更多
Investigations were made both in laboratorial and industrial scales on formation of non-metallic inclusions with relatively lower melting temperatures to improve the fatigue property of the special steels which contai...Investigations were made both in laboratorial and industrial scales on formation of non-metallic inclusions with relatively lower melting temperatures to improve the fatigue property of the special steels which contained extra low oxygen.It was found in laboratory studies that steel/slag reaction time largely affected non-metallic inclusions in steel.With the slag/steel reaction time increasing from 30 to 90 min,inclusions of MgO-Al2O3 spinel were gradually changed into CaO-MgO-Al2O3 system inclusions which were surrounded by lower melting temperature softer CaO-Al2O3 surface layers.By using high basicity and as much as 41 mass% Al2O3 refining slag,the ratio of the lower melting temperature CaO-MgO-Al2O3 system inclusions was remarkably increased to above 80%.In the industrial experiments,it was found that the inclusions changed in the order of "Al2O3 →MgO-Al2O3 system→CaO-MgO-Al2O3 system" in the secondary refining,and the change from MgO-Al2O3 system to CaO-MgO-Al2O3 system took place from the outside to the inside.The diffusion of CaO and MgO inside the layer of CaO-MgO-Al2O3 was considered as the controlling step of the inclusion transfer.Through LF and RH refining,most inclusions could be transferred to lower melting temperature CaO-Al2O3 and CaO-MgO-Al2O3 system inclusions.展开更多
Non-metallic inclusion distribution in the surface layer of IF steel slabs during unsteady casting was investigated using the original position statistic distribution analysis（OPA）method.It was found that most non-m...Non-metallic inclusion distribution in the surface layer of IF steel slabs during unsteady casting was investigated using the original position statistic distribution analysis（OPA）method.It was found that most non-metallic inclusions larger than 10 μm existed in the subsurface layers of 0.5-3.5 mm from the slab surfaces and very few large non-metallic inclusions were found in the inner regions（≥4.5 mm from slab surfaces）.In addition,it was found that at high casting speed level（1.4 m/min）,even a slight change of casting speed could result in a remarkable increase of the non-metallic inclusions.Thus,at high casting speed,changing the casting speed should be avoided or considerably lower speed changing rate must be used.展开更多
Non-metallic inclusion in electroslag remelting is a constant topic that has been studied for decades.Different results and conclusions are obtained on some of the subjects from these previous investigations.These dif...Non-metallic inclusion in electroslag remelting is a constant topic that has been studied for decades.Different results and conclusions are obtained on some of the subjects from these previous investigations.These differences originate in part from different experimental conditions,including original inclusion chemistries in consumable electrode,slag composition,oxygen level,liquid metal compositions,deoxidation schemes,and melting rates of electroslag remelting.The advances in the operating practices of inclusion control in electroslag remelting production are reviewed.Inclusion evolution during the electroslag remelting and related processing parameters are also reviewed and assessed.The role of the reoxidation of liquid steel during electroslag remelting on oxide inclusion composition is discussed.The generation of inclusions in remelted ingot is critically assessed.Perspective and remaining issues are noted.展开更多
The behavior of non-metallic inclusions in LCAK （low carbon aluminum killed） steel produced by BOF （basic oxygen furnace）-LF （ladle furnace） refining-FTSC （flexible thin slab continuous caster） production rout...The behavior of non-metallic inclusions in LCAK （low carbon aluminum killed） steel produced by BOF （basic oxygen furnace）-LF （ladle furnace） refining-FTSC （flexible thin slab continuous caster） production route was investigated. The results showed that, LF refining for LCAK steel could decrease the wT[o] significantly, and the inclusions were modified by Ca treatment, which prevented nozzle clogging efficiently. However, owing to the unstable casting condition in the earlier stage of casting, a severe reoxidation occurred, accompanied with mold slag entrapment. The transformation of non-metallic inclusions during the steelmaking process was Al2O3→MgO→Al2O3 type inclusion→MgO-Al2O3 O3-CaO type inclusion with a CaS ring, and the mechanism of the transformation was pro posed and discussed via thermodynamic and kinetic analysis. Besides, to avoid CaS precipitation, the product of W[Al] ×w3[S] in steel should be less than 2.0 × 10 10 at 1873 K, which remands higher desulfurization ratio during LF refining.展开更多
Recent results on conversion from graphite to diamond by aid of non-metallic catalysts are reviewed. The current status of experimental advances is presented and typical examples from relevant literature are provided ...Recent results on conversion from graphite to diamond by aid of non-metallic catalysts are reviewed. The current status of experimental advances is presented and typical examples from relevant literature are provided for understanding the mechanism of the graphite-diamond conversion by aid of these non-metallic catalysts. Furthermore, a tendency of graphite-diamond transformation assisted by carbonates, sulfates or phosphorus under high pressure and high temperature has been investigated by calculating the activation energy and transformation probability of the carbon atoms over a potential barrier. It was found that the activation energy is highly sensitive to the catalyst chosen. The probability sequence of graphite-diamond transformation with these catalysts was put forward.展开更多
Effects of prior austenite deformation and non-metallic inclusions on the ferrite nucleation and grain refine- ment of two kinds of low-carbon steels have been studied. The ferrite nucleation on MnS and V（C, N） is o...Effects of prior austenite deformation and non-metallic inclusions on the ferrite nucleation and grain refine- ment of two kinds of low-carbon steels have been studied. The ferrite nucleation on MnS and V（C, N） is observed. The combination of thermomeehanical processes with adequate amounts of non-metallic inclusions formed in low-car- bon steels could effectively refine the grain size and the microstructure. Ferrite nucleated on the single MnS or V（C, N） inclusions and complex MnS＋V（C,N） inclusion. The proper addition of elements S and V could effectively promote the formation of ferrite and further refinement of ferrite grains.展开更多
Silicene, the silicon counterpart of graphene, has been successfully grown on metallic substrates such as Ag（111）, ZrB2（0001）, and Ir（111） surfaces. However, characterization of its electronic structure is hampe...Silicene, the silicon counterpart of graphene, has been successfully grown on metallic substrates such as Ag（111）, ZrB2（0001）, and Ir（111） surfaces. However, characterization of its electronic structure is hampered by the metallic substrate. In addition, potential applications of silicene in nanoelectronic devices will require its growth on or integration with semiconducting and insulating substrates. We herein present a review of recent theoretical works regarding the interaction of silicene with non-metallic templates, distinguishing between the weak van-der-Waals-like interactions of silicene with, for example, layered metal （di）chalcogenides, and the stronger covalent bonding between silicene and, for example, ZnS surfaces. We then present a methodology to effectively compare the stability of diverse silicene structures using thermodynamics and molecular dynamics density functional theory calculations. Recent experimental results on the growth of silicene on MoS2 are also reported and compared to the theoretical predictions.展开更多
There is a close relation between the characteristics of products and the chemical composition control of inclusions in steelmaking process. Therefore, it is very important for a warranty of product’s characteristics...There is a close relation between the characteristics of products and the chemical composition control of inclusions in steelmaking process. Therefore, it is very important for a warranty of product’s characteristics to improve inclusion quality resulting in defective products. In the present work, the control technique of inclusions’ chemical composition is discussed thermodynamically based on the Redlich-Kister type polynomial to metallic solution and regular solution model to molten oxide solution. It is very effective for the precise chemical composition control of oxides to determine the concentration of deoxidizers based on the thermodynamic relation among dissolved deoxidizers and oxygen, because it is known that oxide inclusions are equilibrated with them in molten steel in the steel making process. High alloy steel production process was focused in the present work.展开更多
In this paper,the electronic structure and stability of the intrinsic,B-,N-,Si-,S-doped graphene are studied based on first-principles calculations of density functional theory.Firstly,the intrinsic,B-,N-,Si-,S-doped ...In this paper,the electronic structure and stability of the intrinsic,B-,N-,Si-,S-doped graphene are studied based on first-principles calculations of density functional theory.Firstly,the intrinsic,B-,N-,Si-,S-doped graphene structures are optimized,and then the forming energy,band structure,density of states,differential charge density are analyzed and calculated.The results show that Band Si-doped systems are p-type doping,while N is n-type doping.By comparing the forming energy,it is found that N atoms are more easily doped in graphene.In addition,for B-,N-,Si-doped systems,it is found that the doping atoms will open the band gap,leading to a great change in the band structure of the doping system.Finally,we systematically study the optical properties of the different configurations.By comparison,it is found that the order of light sensitivity in the visible region is as follows:S-doped>Si-doped>pure>B-doped>N-doped.Our results will provide theoretical guidance for the stability and electronic structure of non-metallic doped graphene.展开更多
基金financially supported by the National Natural Science Foundation of China (No. 51674069)the National Key R & D Program of China (No. 2017YFC0805100)
文摘For the control of surface defects in interstitial-free(IF) steel, quantitative metallographic analyses of near-surface inclusions and surface liquid flow detection via the nail-board tipping method were conducted. The results show that, at casting speeds of 0.8 and 1.0 m/min, a thin liquid mold flux layer forms and non-uniform floating of argon bubbles occurs, inducing the entrainment and subsequent entrapment of the liquid flux; fine inclusion particles of Al_2O_3 can also aggregate at the solidification front. At higher casting speeds of 1.4 and 1.6 m/min, the liquid mold flux can be entrained and carried deeper into the liquid steel pool because of strong level fluctuations of the liquid steel and the flux. The optimal casting speed is approximately 1.2 m/min, with the most favorable surface flow status and, correspondingly, the lowest number of inclusions near the slab surface.
文摘Laboratory and industrial studies were carried out to investigate non-metallic inclusions in high strength alloy steel refined by high basicity and high Al_2O_3 slag.It was found that the steel/slag reaction time largely affected non-metallic inclusions.With the reaction time increased from 30 min to 90 min in laboratory study,MgO-Al_2O_3 spinels were gradually changed into CaO-MgO-Al_2O_3 system inclusions surrounded by softer CaO-Al_2O_3 surface layers.By using high basicity slag which contained as much as 41%Al_2O_3 in the laboratory study,ratio of low melting temperature CaO-MgO-Al_2O_3 system inclusions was remarkably increased to above 80%.In the industrial experiment,during the secondary refining,the inclusions changed in order of 'Al_2O_3→MgO-Al_2O_3→CaO-MgO-Al_2O_3'.Through the LF and RH refining,most inclusions could be transferred to lower melting temperature CaO-Al_2O_3 and CaO-MgO-Al_2O_3 system inclusions.
基金Supported by Downhole Intelligent Measurement and Control Science and Technology Innovation Team of Southwest Petroleum University(Grant No.2018CXTD04)National Natural Science Foundation of China(Grant Nos.61701085,51974273)+1 种基金Chengdu Municipal international science and technology cooperation project of China(Grant Nos.2020-GH02-00016-HZ)2020 National Mountain Highway Engineering Technology Research Center Open Fund Project(Grant No.GSGZJ-2020-01).
文摘Buried pipelines are an essential component of the urban infrastructure of modern cities.Traditional buried pipes are mainly made of metal materials.With the development of material science and technology in recent years,non-metallic pipes,such as plastic pipes,ceramic pipes,and concrete pipes,are increasingly taking the place of pipes made from metal in various pipeline networks such as water supply,drainage,heat,industry,oil,and gas.The location technologies for the location of the buried metal pipeline have become mature,but detection and location technologies for the non-metallic pipelines are still developing.In this paper,current trends and future perspectives of detection and location of buried non-metallic pipelines are summarized.Initially,this paper reviews and analyzes electromagnetic induction technologies,electromagnetic wave technologies,and other physics-based technologies.It then focuses on acoustic detection and location technologies,and finally introduces emerging technologies.Then the technical characteristics of each detection and location method have been compared,with their strengths and weaknesses identified.The current trends and future perspectives of each buried non-metallic pipeline detection and location technology have also been defined.Finally,some suggestions for the future development of buried non-metallic pipeline detection and location technologies are provided.
基金Supported by Natural Science Foundation of China (No.81571819 No.81500766)the Natural Science Foundation of Zhejiang Province, China (No.LY14H120004)
文摘Dear Editor,I write to present one case report of a patient suffered the panophthalmitis caused by non-metallic foreign body with no etiologic agent and recovered quickly by phacoemulsification and vitrectomy with silicone oil tamponade.Ocular trauma remains a major cause of blindness, particularly in the working-age population.
文摘In this paper, a kind of three-dimensional analysis technology for characterizing non-metallic inclusions in steel was clearly elaborated. It is an electron microscopy observation, namely the non-aqueous electrolysis extraction method with a settled coulometer. In the research,the extraction effects of non-metallic inclusions in different electrolysis systems were studied, and it was concluded that alkalescent 2% TEA non-aqueous electrolyte was applicable for extracting most of non-metallic inclusion particles in steel. And then, in order to ensure the microscopic characterization and statistical calculation of inclusion particles, some electrolysis parameters should be confirmed, such as the size of the sample, control of the electrolysis mass, electric current, etc. Furthermore, for preventing the disturbance of carbides and presenting clear three-dimensional appearance by microscopic characterization, magnetic separation was utilized to separate the inclusion particles from carbides, which was useful for getting more veracious types, particle sizes and chemical composition of inclusions. Moreover, through calculation of quantity and particle size of inclusions in continuous determinate fields, the total quantity per unit volume or area and the particle size distribution of inclusions could be acquired by conversion with electrolysis loss. Besides, the comparison between this method and traditional quantitative metallography was also discussed, and finally, a conclusion was drawn that both of them have respectively applications in characterizing inclusions.
文摘In order to know the behavior of non-metallic inclusions in centrifugal induction electroslag castings (CIESC), non-metallic inclusions in 5CrMnMo and 4Cr5MoSiV1 were qualitatively and quantitatively analyzed. The largest size of inclusions in the casting and the thermodynamic possibility of TiN precipitation in steel were also calculated. The results show that sulfide inclusions are evenly distributed and the content is low. The amount of oxide inclusions in CIESC: 4Cr5MoSiV1 steel is close to the ESR steel and lower than that in the EAF steel, and there are some differences along radial direction. Nitride inclusions are fine and the diameter of the largest one is 3-1 mum. With the increase of the centrifugal machine's rotational speed, the ratio of round inclusions increases and the ratio of sharp inclusions decreases. According to the experiment and the calculation results, it is pointed out that the largest diameter of non-metallic inclusions in the CIESC 4Cr5MoSiV1 casting is only 6.6 mum, and [N%][Ti%] in 4Cr5MoSiV1 steel should be controlled less than 4.4x 10(-5) in order to further reduce the amount and size of TiN inclusions.
文摘In aluminum killed steels, the size, shape, quantity and formation of non-metallic inclusions in ladle steel (before and after RH vacuum treatment) and in tundish as well as in slabs were studied by EPMA (Electron Probe Microanalysis) and by analyzing the total oxygen. The results showed that in the slabs the total oxygen was quite low and the inclusions discovered were mainly small-sized angular alumina inclusions. This indicates that most inclusions have been removed by floating out during the continuous casting process. In addition, the countermeasures were discussed to decrease the alumina inclusions in the slabs further.
基金Supported by the Innovative Research Group Project of China National Natural Science Foundation(51821092)Key Project of China National Natural Science Foundation(U1762214).
文摘Focusing on the extending length restriction of the completion screen pipe resistance running into ultra-short radius horizontal well,this paper proposed technology of hydraulic drive completion tubular string running into ultra-short radius horizontal well.Innovative hydraulic drive tools and string structure are designed,which are composed of guide tubing,hydraulic drive tubing and non-metallic completion screen pipe from inside to outside.A novel mechanical-hydraulic coupling model is established.Based on the wellbore structure of an ultra-short radius horizontal well for deep coalbed methane,the numerical calculations of force and hydraulic load on tubular strings were accomplished by the mechanical-hydraulic coupling model.The results show that the extending length of completion tubular string with the hydraulic drive is 17 times that of conventional completion technology under the same conditions.The multi-factor orthogonal design is adopted to analyze the numerical calculations,and the results show that the extending length of the completion tubular string is mainly affected by the completion tubular string structure and the friction coefficient between the non-metallic composite continuous screen pipe and the wellbore.Two series of hydraulic drive completion tubular string structures suitable for ultra-short radius horizontal wells under different conditions are optimized,with the extending limits of 381 m and 655 m,respectively.These researches will provide theoretical guidance for design and control of hydraulic drive non-metallic composite continuous completion screen pipe running into ultra-short radius horizontal wells.
文摘Six different kinds of non-metallic or organic disinfectants were obtained in this research study including “Neutral Electrolyzed Water”, “M22” organic disinfectant solution, Superoxy Food Wash disinfectant, Hydrogen Peroxide, Clorox Germicidal Bleach and Clidox-S. The effectiveness of these disinfectants was studied against various subtypes of avian influenza virus (AIV). The virus-disinfectant mixtures were prepared in serial dilutions of each disinfectant with a constant virus titer and incubated at ambient temperature in different time intervals for virus inactivation. The virus inactivation results were determined by virus recovery in embryonating chicken eggs. Among the six different kinds of nonmetallic disinfectants obtained for this research project, Neutral Electrolyzed Water, “M22” solution, Clorox Germicidal Bleach and Clidox-S were effectively inactivated AIV with appropriate working dilutions and reaction times. Superoxy Food Wash disinfectant and Hydrogen Peroxide were found having limited effect on virus inactivation with extended exposure times of more than 2 hours. These research findings provide scientific data to poultry industry with guidelines to select and use non-metallic organic disinfectants for poultry flock sanitation and disinfection to effectively prevent and control of avian influenza outbreaks.
文摘Non-metallic inclusions,especially the large ones,within P/M Ni-base superalloy have a major influence on fatigue characteristics,but are not directly measurable by routine inspection.In this paper,a method,automatic image analysis,is proposed for estimation of the content,size and amount of non-metallic inclusions in superalloy.The methodology for the practical application of this method is described and the factors affecting the precision of the estimation are discussed.In the experiment,the characteristics of the non-metallic inclusions in Ni-base P/M superalloy are analyzed.
文摘The expansion parts and components of non-metallic in devices have become a fait accompli. In the case parts, components of non-metallic are used in atmospheres explosive and may be a potential source of ignition [1]. Ignition hazards due to static electricity from the charged non-conductive non-metallic materials are well known [2]. The prevalence protection metal parts and components of anti-corrosion exist in any device equipped with a metal casing. Inherent risks associated services are caused by static electricity. Electrostatic phenomena arise in many situations, in a variety of environments and industries. The occurrence of charge static in many cases unexpected is unwanted and requires the use of expensive preventive measures. Brush discharge and propagating brush discharge (e.g. composite coating about non-conductive electrostatic properties of an isolated base conductive) create explosion hazard in underground endangered by firedamp and/or coal dust [3].
基金supported by the National Basic Research Program of China (Grant No. 2010CB630806)
文摘Investigations were made both in laboratorial and industrial scales on formation of non-metallic inclusions with relatively lower melting temperatures to improve the fatigue property of the special steels which contained extra low oxygen.It was found in laboratory studies that steel/slag reaction time largely affected non-metallic inclusions in steel.With the slag/steel reaction time increasing from 30 to 90 min,inclusions of MgO-Al2O3 spinel were gradually changed into CaO-MgO-Al2O3 system inclusions which were surrounded by lower melting temperature softer CaO-Al2O3 surface layers.By using high basicity and as much as 41 mass% Al2O3 refining slag,the ratio of the lower melting temperature CaO-MgO-Al2O3 system inclusions was remarkably increased to above 80%.In the industrial experiments,it was found that the inclusions changed in the order of "Al2O3 →MgO-Al2O3 system→CaO-MgO-Al2O3 system" in the secondary refining,and the change from MgO-Al2O3 system to CaO-MgO-Al2O3 system took place from the outside to the inside.The diffusion of CaO and MgO inside the layer of CaO-MgO-Al2O3 was considered as the controlling step of the inclusion transfer.Through LF and RH refining,most inclusions could be transferred to lower melting temperature CaO-Al2O3 and CaO-MgO-Al2O3 system inclusions.
文摘Non-metallic inclusion distribution in the surface layer of IF steel slabs during unsteady casting was investigated using the original position statistic distribution analysis（OPA）method.It was found that most non-metallic inclusions larger than 10 μm existed in the subsurface layers of 0.5-3.5 mm from the slab surfaces and very few large non-metallic inclusions were found in the inner regions（≥4.5 mm from slab surfaces）.In addition,it was found that at high casting speed level（1.4 m/min）,even a slight change of casting speed could result in a remarkable increase of the non-metallic inclusions.Thus,at high casting speed,changing the casting speed should be avoided or considerably lower speed changing rate must be used.
基金The financial support by the National Natural Science Foundation of China(Grant Nos.51874026 and 52074027)the Fundamental Research Funds for the Central Universities(Grant No.FRF-AT-20-13)is greatly acknowledgedThe authors are also thankful to the financial support from the State Key Laboratory of Advanced Metallurgy(Grant No.41621024).
文摘Non-metallic inclusion in electroslag remelting is a constant topic that has been studied for decades.Different results and conclusions are obtained on some of the subjects from these previous investigations.These differences originate in part from different experimental conditions,including original inclusion chemistries in consumable electrode,slag composition,oxygen level,liquid metal compositions,deoxidation schemes,and melting rates of electroslag remelting.The advances in the operating practices of inclusion control in electroslag remelting production are reviewed.Inclusion evolution during the electroslag remelting and related processing parameters are also reviewed and assessed.The role of the reoxidation of liquid steel during electroslag remelting on oxide inclusion composition is discussed.The generation of inclusions in remelted ingot is critically assessed.Perspective and remaining issues are noted.
基金Item Sponsored by National Key Technology Research and Development Programin 11th Five-Year Plan of China(2006BAE03A13)
文摘The behavior of non-metallic inclusions in LCAK （low carbon aluminum killed） steel produced by BOF （basic oxygen furnace）-LF （ladle furnace） refining-FTSC （flexible thin slab continuous caster） production route was investigated. The results showed that, LF refining for LCAK steel could decrease the wT[o] significantly, and the inclusions were modified by Ca treatment, which prevented nozzle clogging efficiently. However, owing to the unstable casting condition in the earlier stage of casting, a severe reoxidation occurred, accompanied with mold slag entrapment. The transformation of non-metallic inclusions during the steelmaking process was Al2O3→MgO→Al2O3 type inclusion→MgO-Al2O3 O3-CaO type inclusion with a CaS ring, and the mechanism of the transformation was pro posed and discussed via thermodynamic and kinetic analysis. Besides, to avoid CaS precipitation, the product of W[Al] ×w3[S] in steel should be less than 2.0 × 10 10 at 1873 K, which remands higher desulfurization ratio during LF refining.
基金Project supported by the National Natural Science Foundation of China (Grant No. 19674970).
文摘Recent results on conversion from graphite to diamond by aid of non-metallic catalysts are reviewed. The current status of experimental advances is presented and typical examples from relevant literature are provided for understanding the mechanism of the graphite-diamond conversion by aid of these non-metallic catalysts. Furthermore, a tendency of graphite-diamond transformation assisted by carbonates, sulfates or phosphorus under high pressure and high temperature has been investigated by calculating the activation energy and transformation probability of the carbon atoms over a potential barrier. It was found that the activation energy is highly sensitive to the catalyst chosen. The probability sequence of graphite-diamond transformation with these catalysts was put forward.
基金Item Supported by National Natural Science Foundation of China (50871059)Specialized Research Foundation for Doctoral Program of Higher Education (20070003006)
文摘Effects of prior austenite deformation and non-metallic inclusions on the ferrite nucleation and grain refine- ment of two kinds of low-carbon steels have been studied. The ferrite nucleation on MnS and V（C, N） is observed. The combination of thermomeehanical processes with adequate amounts of non-metallic inclusions formed in low-car- bon steels could effectively refine the grain size and the microstructure. Ferrite nucleated on the single MnS or V（C, N） inclusions and complex MnS＋V（C,N） inclusion. The proper addition of elements S and V could effectively promote the formation of ferrite and further refinement of ferrite grains.
文摘Silicene, the silicon counterpart of graphene, has been successfully grown on metallic substrates such as Ag（111）, ZrB2（0001）, and Ir（111） surfaces. However, characterization of its electronic structure is hampered by the metallic substrate. In addition, potential applications of silicene in nanoelectronic devices will require its growth on or integration with semiconducting and insulating substrates. We herein present a review of recent theoretical works regarding the interaction of silicene with non-metallic templates, distinguishing between the weak van-der-Waals-like interactions of silicene with, for example, layered metal （di）chalcogenides, and the stronger covalent bonding between silicene and, for example, ZnS surfaces. We then present a methodology to effectively compare the stability of diverse silicene structures using thermodynamics and molecular dynamics density functional theory calculations. Recent experimental results on the growth of silicene on MoS2 are also reported and compared to the theoretical predictions.
文摘There is a close relation between the characteristics of products and the chemical composition control of inclusions in steelmaking process. Therefore, it is very important for a warranty of product’s characteristics to improve inclusion quality resulting in defective products. In the present work, the control technique of inclusions’ chemical composition is discussed thermodynamically based on the Redlich-Kister type polynomial to metallic solution and regular solution model to molten oxide solution. It is very effective for the precise chemical composition control of oxides to determine the concentration of deoxidizers based on the thermodynamic relation among dissolved deoxidizers and oxygen, because it is known that oxide inclusions are equilibrated with them in molten steel in the steel making process. High alloy steel production process was focused in the present work.
基金supported by the China Postdoctoral Science Foundation(No.2019M651281)。
文摘In this paper,the electronic structure and stability of the intrinsic,B-,N-,Si-,S-doped graphene are studied based on first-principles calculations of density functional theory.Firstly,the intrinsic,B-,N-,Si-,S-doped graphene structures are optimized,and then the forming energy,band structure,density of states,differential charge density are analyzed and calculated.The results show that Band Si-doped systems are p-type doping,while N is n-type doping.By comparing the forming energy,it is found that N atoms are more easily doped in graphene.In addition,for B-,N-,Si-doped systems,it is found that the doping atoms will open the band gap,leading to a great change in the band structure of the doping system.Finally,we systematically study the optical properties of the different configurations.By comparison,it is found that the order of light sensitivity in the visible region is as follows:S-doped>Si-doped>pure>B-doped>N-doped.Our results will provide theoretical guidance for the stability and electronic structure of non-metallic doped graphene.
