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A Sterically Hindered Zirconocene Complex (1,2-Ph_2C_5H_3)_2ZrCl_2:Synthesis,Structure and Properties as Olefin Polymerization Catalyst 被引量:1
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作者 Fan ZHANG Ying MU +3 位作者 Yue Tao ZHANG Cong Xi CHEN Hui Min ZHAI Han HONG(Department of Chemistry, Jilin University, Changchun 130023Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080) 《Chinese Chemical Letters》 SCIE CAS CSCD 2000年第7期641-644,共4页
An unbridged zirconocene complex bis(1,2-diphenylcyclopentadienyl)zirconium dichloride [(1,2-Ph2-C5H3)2ZrCl2] 1 has been synthesized and structurally characterized. When activated by MAO, 1 produces ultra-high molecul... An unbridged zirconocene complex bis(1,2-diphenylcyclopentadienyl)zirconium dichloride [(1,2-Ph2-C5H3)2ZrCl2] 1 has been synthesized and structurally characterized. When activated by MAO, 1 produces ultra-high molecular weight polyethylene with high melting transition temperature, as well as atactic oligopropylene with average molecular weight of ~1150 g mol-1. 展开更多
关键词 Zirconium complex metallocene catalyst olefin polymerization
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NdCl_3/MgCl_2 BISUPPORTED CATALYST FOR OLEFIN POLYMERIZATION
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作者 王海 肖士镜 蔡世绵 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1993年第4期64-67,共4页
The NdCl_3/MgCl_2 bisupported catalyst was prepared by using NdCl_3 ,MgCl_2, (CH_3)_2(CH_2)_2 OH and TiCl_4. It is shown that the structure of bisupported catalyst was different from those of either NdCl_3 or MgCl_2 s... The NdCl_3/MgCl_2 bisupported catalyst was prepared by using NdCl_3 ,MgCl_2, (CH_3)_2(CH_2)_2 OH and TiCl_4. It is shown that the structure of bisupported catalyst was different from those of either NdCl_3 or MgCl_2 single supported catalyst. A peculiar type of kinetic curve for ethylene polymerization was found. 展开更多
关键词 NdCl_3 MgCl_2 Bisupported catalyst olefin polymerization
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STUDY ON HIGHLY ACTIVE ZIEGLERNATTA CATALYSTS FOR POLYMERIZATION OF OLEFINS
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作者 王立 封麟先 +1 位作者 徐君庭 杨士林 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 1995年第1期41-50,共10页
In this paper, highly active Ziegler-Natta catalysts of MgCl_2 supported TiCl_4 for synthesis ofpolyolefins, using di-n-butyl phthalate (DNBP) as internal donor and diphenyl dimethoxyl silane(DPDMS) as external donor,... In this paper, highly active Ziegler-Natta catalysts of MgCl_2 supported TiCl_4 for synthesis ofpolyolefins, using di-n-butyl phthalate (DNBP) as internal donor and diphenyl dimethoxyl silane(DPDMS) as external donor, have been prepared. The conditions controlling the treatment ofsupport were studied. The interactions of various components present in the catalysts and theirinfluences on catalytic performance were investigated. It is found that by using DNBP and DPDMSas internal and external donors together the polymer products with higher isotactic index can beobtained. Plausible structure model and mechanism were proposed. 展开更多
关键词 Ziegler-Natta catalyst polymerization of olefins ESR Internal and external donors
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Development of Olefin Polymerization Catalysts and Their Commercialization
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作者 Mao Bingquan, Yang Yuanyi (Beijing Research Institute of Chemical Industry, SINOPEC, Beijing\ 100013) 《工程科学(英文版)》 2003年第2期75-79,共5页
As one of the most important products in petrochemical industry, polyolefin, including mainly polyethylene, polypropylene and α\|olefin polymers, is also a major raw material for plastics industry. The market demand ... As one of the most important products in petrochemical industry, polyolefin, including mainly polyethylene, polypropylene and α\|olefin polymers, is also a major raw material for plastics industry. The market demand for polyolefin in 2002 reached 88 Mt, making two thirds of the demand for thermoplastics. The growth rate of demand will be 5%-7 % in the next five years\+\{\\}. Because of its close relation to nations economy and its peoples daily life, the output of polyolefin becomes an important index of the nations industria lization and modernization level. 展开更多
关键词 olefin polymerization catalystS DEVELOPMENT COMMERCIALIZATION
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Polymerization Mechanism of α-Linear Olefin 被引量:3
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作者 邢文国 张长桥 +2 位作者 于萍 刘成卜 魏云鹤 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2010年第1期39-44,I0001,共7页
The density functional theory on the level of B3LYP/6-31G was empolyed to study the chain growth mechanism in polymerization process of α-linear olefin in TiCl3/AlEt2Cl catalytic system to synthesize drag reduction a... The density functional theory on the level of B3LYP/6-31G was empolyed to study the chain growth mechanism in polymerization process of α-linear olefin in TiCl3/AlEt2Cl catalytic system to synthesize drag reduction agent. Full parameter optimization without symmetry restrictions for reactants, products, the possible transition states, and intermediates was calculated. Vibration frequency was analyzed for all of stagnation points on the potential energy surface at the same theoretical level. The internal reaction coordinate was calculated from the transition states to reactants and products respectively. The results showed as flloes: (i) Coordination compounds were formed on the optimum configuration of TiCl3/AlEt2Cl.(ii) The transition states were formed. The energy di?erence between transition states and the coordination compounds was 40.687 kJ/mol. (iii) Double bond opened and Ti-C(4) bond fractured, and the polymerization was completed. The calculation results also showed that the chain growth mechanism did not essentially change with the increase of carbon atom number of α-linear olefin. From the relationship between polymerization activation energy and carbon atom number of the α-linear olefin, it can be seen that the α-linear olefin monomers with 6-10 carbon atoms had low activation energy and wide range. It was optimum to synthesize drag reduction agent by polymerization. 展开更多
关键词 Density functional theory polymerization mechanism α-Linear olefin Drag reduction agent Ziegler-Natta catalyst
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Oligomerization and Polymerization of Ethylene Initiated by a Novel Ni(Ⅱ)-Based Acetyliminopyridine Complexes as Single-Site Catalysts 被引量:1
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作者 Baojun Zhang Yanji Wang +5 位作者 Gang Wang Jun Cao Shukun Sun Lihua Xing Yongcheng Sun Yunguang Han 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2007年第1期64-69,共6页
Novel Ni(II)-based acetyliminopyridine complexes 1b, 2b, 3b (1-3b), which are synthesized from ligands 1a, 2a, 3a (1-3a) and [NiCl2(DME)], are suitable precursors for the catalysts that are necessary for ethyl... Novel Ni(II)-based acetyliminopyridine complexes 1b, 2b, 3b (1-3b), which are synthesized from ligands 1a, 2a, 3a (1-3a) and [NiCl2(DME)], are suitable precursors for the catalysts that are necessary for ethylene oligomerization and polymerization reactions, activated by methylaluminoxane (MAO). The MAO-treated 1-3b presents an active catalytic center, which may oligomerize and polymerize ethylene to produce linear α-olefins and polyethylene, respectively. The molecular weight distributions of oligomers that are obtained are in good agreement with the Schulz-Flory rules for oligomers〉C4. The activity of 3b-MAO complex is 6.3×10^7 g/(molNi.h) at 50 ℃. The activities and molecular weight distributions of oligomers show significant reliance on the structures of catalyst precursors. 展开更多
关键词 OLIGOMERIZATION polymerization ETHYLENE Ni(II)-based catalyst α -olefin
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Simple Preparation of Halogen-Substituted <i>α</i>-Diimine Nickel Complexes Immobilized into Clay Interlayer as Catalysts for Ethylene Oligo-/Polymerization
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作者 Miru Yoshida-Hirahara Shiori Fujiwara Hideki Kurokawa 《Modern Research in Catalysis》 2017年第2期100-120,共21页
In the practical use for the production of the α-olefins, it is highly desired to develop a novel heterogeneous catalyst system. The metal complexes immobilized into the clay interlayers show a great potential as het... In the practical use for the production of the α-olefins, it is highly desired to develop a novel heterogeneous catalyst system. The metal complexes immobilized into the clay interlayers show a great potential as heterogeneous catalysts due to their excellent processability. In this study, nine types of heterogeneous procatalyst Ln/Ni2+-micas were synthesized via a one-pot preparation method, which includes both the condensation reaction of the ligand derivatives and the intercalation of the ligands into the Ni2+ ion-exchanged fluorotetrasilicic mica interlayer. The ligand structures of the prepared procatalysts were [Ln: R-N = C(Nap)-C(Nap) = N-R] [(Nap = 1,8-naphthdiyl) (L1, R = 2-MePh;L2, R = 2-FPh;L3, R = 2-BrPh;L4, R = 4-MePh;L5, R = 4-FPh;L6, R = 4-BrPh;L7, R = 2,4-F2Ph;L8, R = 2,4-Br2Ph;L9, R = 2,6-F2Ph). At 50℃ and 0.7 MPaethylene pressure, the triisobutylaluminum-activated L1-L6/Ni2+-mica showed a catalytic activity for the ethylene oligo-/polymerization in the range of 334 - 549 g-ethylene&bull;g-cat–1&bull;h–1. A high catalyst activity was obtained when the substituent having a larger steric bulk than that of a methyl substituent was introduced at the ortho-position of the aryl rings. The introduction of the fluorine substituent as a strong electron-withdrawing group to the para-position also increased the catalytic activity. The L2, L4, L5, and L6/Ni2+-micas showed moderate selectivities to oligomers consisting of C4-C20 in the range of 19.9 - 41.6 wt% at 50℃. The calculated Schulz-Flory constants α based on the mole fraction of C12 and C14 were within 0.61 - 0.78. 展开更多
关键词 ETHYLENE Oligo-/polymerization Heterogeneous catalyst HALOGEN SUBSTITUTED α-Diimine Nickel Complex α-olefin Oligomer Layered CLAY Mineral
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Potentially Practical Catalytic Systems for Olefin-Polar Monomer Coordination Copolymerization 被引量:1
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作者 Chen Tan Min Chen +1 位作者 Chen Zou Changle Chen 《CCS Chemistry》 CSCD 2024年第4期882-897,共16页
Studies on transition-metal catalyzed olefin-polar monomer coordination copolymerization and their resulting polar-functionalized polyolefin materials have attracted attention from both academia and industry.After dec... Studies on transition-metal catalyzed olefin-polar monomer coordination copolymerization and their resulting polar-functionalized polyolefin materials have attracted attention from both academia and industry.After decades of research,recent developments in a variety of high-performance catalytic systems have shown that this field is on the brink of industrialization.This review summarizes representative olefin-polar monomer coordination copolymerization catalyst systems that may be suitable for industrial polyolefin production via homogeneous solution-phase processes or heterogeneous gas-phase/slurry-phase processes. 展开更多
关键词 olefin copolymerization polar monomer catalyst solution polymerization heterogeneous
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HOMO- AND COPOLYMERIZATION OF ETHYLENE CATALYZED BY ANSA-METALLOCENES WITH DOUBLY HETERO-BRIDGES
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作者 闫卫东 王佰全 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2008年第4期415-423,共9页
Three ansa-metallocenes(Me_2C)(Me_2Si)Cp_2TiCl_2(1),[(CH_2)_5C](Me_2Si)Cp_2TiCl_2 (2)and (Me_2C)(Me_2Si)Cp_2ZrCl_2 (3)with larger dihedral angles and longer distance from metal to the center of Cp planes were synthesi... Three ansa-metallocenes(Me_2C)(Me_2Si)Cp_2TiCl_2(1),[(CH_2)_5C](Me_2Si)Cp_2TiCl_2 (2)and (Me_2C)(Me_2Si)Cp_2ZrCl_2 (3)with larger dihedral angles and longer distance from metal to the center of Cp planes were synthesized and used as catalysts for ethylene polymerization in the presence of methylaluminoxane (MAO).In the case of ethylene polymerization,compared the feature structures of unbridged metallocenes, singly bridged metallocenes and doubly bridged metallocenes 1,2,3,there exhibit the relationship bet... 展开更多
关键词 Ansa-metallocene catalyst Doubly hetero-bridged metallocene polymerization ETHYLENE α-olefins
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烯烃聚合用二亚胺催化剂的研究进展
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作者 王琪 宋昊 刘振宇 《合成树脂及塑料》 CAS 北大核心 2024年第2期72-77,共6页
综述了近几年烯烃聚合用α-二亚胺催化剂的研究进展,聚焦于配体结构的修饰,包括空间效应和电子效应的调控策略,以及配体结构变化对催化剂活性和热稳定性的影响。调控α-二亚胺配体的轴向位阻可达到提高催化剂活性、热稳定性,聚合物相对... 综述了近几年烯烃聚合用α-二亚胺催化剂的研究进展,聚焦于配体结构的修饰,包括空间效应和电子效应的调控策略,以及配体结构变化对催化剂活性和热稳定性的影响。调控α-二亚胺配体的轴向位阻可达到提高催化剂活性、热稳定性,聚合物相对分子质量,以及调节支化度的目的。在适当的空间位阻下,引入不同电子效应的取代基对配体进行结构修饰同样也可提高α-二亚胺催化剂的性能。 展开更多
关键词 烯烃聚合 α-二亚胺催化剂 “链行走”机理 催化剂活性 热稳定性
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α-二亚胺镍/钯催化剂体系用于乙烯聚合研究进展
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作者 刘真 《石油化工》 CAS CSCD 北大核心 2024年第6期903-911,共9页
带有大位阻基团的二亚胺催化体系在烯烃聚合中已经有着非常广泛的应用,它的结构中具有的诸多调控位点可实现催化剂性能及所制备聚合物性能的调整。介绍了近年来Brookhart催化体系的研究进展,综述了该催化体系的改进方法,主要包括改变配... 带有大位阻基团的二亚胺催化体系在烯烃聚合中已经有着非常广泛的应用,它的结构中具有的诸多调控位点可实现催化剂性能及所制备聚合物性能的调整。介绍了近年来Brookhart催化体系的研究进展,综述了该催化体系的改进方法,主要包括改变配体骨架、N-芳基对位基团修饰、N-芳基取代基修饰及其他类型的修饰等,并分析了催化体系的改进对催化剂活性以及聚合物性能的影响。 展开更多
关键词 Brookhart催化剂 烯烃聚合 活性 支化度
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烯烃聚合用茂金属催化剂研究进展
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作者 梁晓宇 岳晓菲 +1 位作者 韦依 潘世光 《合成树脂及塑料》 CAS 北大核心 2024年第5期58-62,共5页
综述了主流的非桥联型、桥联型、限定几何构型和吡啶氨基型中典型的6个茂金属催化剂在乙烯与α-烯烃高温溶液聚合方面的应用。为了探究桥联型茂金属催化剂微观结构与烯烃聚合活性的内在关系,着重分析了4个茂金属催化剂的几何结构参数,... 综述了主流的非桥联型、桥联型、限定几何构型和吡啶氨基型中典型的6个茂金属催化剂在乙烯与α-烯烃高温溶液聚合方面的应用。为了探究桥联型茂金属催化剂微观结构与烯烃聚合活性的内在关系,着重分析了4个茂金属催化剂的几何结构参数,揭示了该类催化剂通过改变配位空间以提高聚合性能的方向。 展开更多
关键词 茂金属催化剂 聚烯烃弹性体 烯烃聚合 乙烯 Α-烯烃
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链穿梭聚合制备烯烃多嵌段共聚物的研究进展
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作者 张然荻 高榕 +3 位作者 苟清强 郑刚 赖菁菁 王莹 《石油化工》 CAS CSCD 北大核心 2024年第9期1352-1361,共10页
通过链穿梭聚合技术可制备烯烃多嵌段共聚物(OBC),极大地提高了催化剂的使用效率。OBC的链结构可以集每一个链段的各自优势于一体,表现出区别于均聚物、无规共聚物或共混物的独特性质。通过调控催化剂和链穿梭剂的结构、配比及反应条件... 通过链穿梭聚合技术可制备烯烃多嵌段共聚物(OBC),极大地提高了催化剂的使用效率。OBC的链结构可以集每一个链段的各自优势于一体,表现出区别于均聚物、无规共聚物或共混物的独特性质。通过调控催化剂和链穿梭剂的结构、配比及反应条件,可以调控OBC的链结构和性能。介绍了链穿梭聚合的原理,综述了链穿梭聚合用于制备OBC的最新研究进展,包括不同单体的共聚、新型链穿梭剂的开发、OBC结构与性能的表征研究,提出了目前链穿梭聚合的问题与挑战,对未来的发展进行了展望。 展开更多
关键词 链穿梭聚合 烯烃多嵌段共聚物 催化剂 聚合物结构
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链穿梭聚合制备的烯烃多嵌段共聚物
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作者 高海洋 高恒 +1 位作者 涂广水 郑涵斗 《炼油与化工》 CAS 2024年第5期1-6,共6页
烯烃多嵌段共聚物因其独特的分子结构和优异的物理性能,在材料科学中展现出重要的应用前景。链穿梭聚合技术有效地实现了烯烃多嵌段共聚物的合成,简化了工业化生产并显著提升了聚合物的性能。文中介绍了烯烃多嵌段共聚物的结构,性能和应... 烯烃多嵌段共聚物因其独特的分子结构和优异的物理性能,在材料科学中展现出重要的应用前景。链穿梭聚合技术有效地实现了烯烃多嵌段共聚物的合成,简化了工业化生产并显著提升了聚合物的性能。文中介绍了烯烃多嵌段共聚物的结构,性能和应用,综述了烯烃多嵌段共聚物的链穿梭聚合制备技术和其它新型单体烯烃多嵌段共聚物的研究进展。 展开更多
关键词 烯烃多嵌段共聚物 链穿梭聚合 催化剂 链转移剂
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(Arylimido)vanadium(V)-Alkylidene Complexes as Catalysts for Ring-opening Metathesis Polymerization(ROMP) of Cyclic Olefins: Ligand Design for Exhibiting the High Activity 被引量:2
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作者 Kotohiro Nomura Sapanna Chaimongkolkunasin 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2019年第10期943-950,I0002,共9页
(Imido)vanadium(V)-alkylidene complexes of type V(CHSiMe3)(NR)(OR?)(PMe3)2 [R = Ad, C6H5, 2,6-Me2C6H3, 2,6-Cl2C6H3;R?= 2,6-Me2C6H3, 2,6-i Pr2C6H3, 2,6-F2C6H3, C6F5, C6Cl5] exhibited from moderate to remarkable catalyt... (Imido)vanadium(V)-alkylidene complexes of type V(CHSiMe3)(NR)(OR?)(PMe3)2 [R = Ad, C6H5, 2,6-Me2C6H3, 2,6-Cl2C6H3;R?= 2,6-Me2C6H3, 2,6-i Pr2C6H3, 2,6-F2C6H3, C6F5, C6Cl5] exhibited from moderate to remarkable catalytic activities for ringopening metathesis polymerization(ROMP) of norbornene(NBE). The catalytic activities were affected by the ligand substituents, and V(CHSiMe3)(N-2,6-Cl2C6H3)(OC6X5)(PMe3)2(X = F, Cl) demonstrated the exceptionally high catalytic activities for ROMP of NBE.The complexes polymerized cycloheptene(CHPE) and cis-cyclooctene(COE), and ROMP of COE by the OC6 Cl5 analogue proceeded in a living manner even at 80℃, and the activity increased with increasing the temperature up to 120 ℃. Highly active catalysts for ROMP of cyclic olefins(NBE, cyclopentene, and CHPE) can be generated in situ by premixing isolated V(CHSiMe3)(NC6F5)(O-2,6-iPr2C6H3)(PMe3)2 with 1.0 equiv. of C6F5OH or C6Cl5OH via immediate phenoxy exchange;the activity was affected by the kind of phenol added [TOF in the ROMPs of NBE: 4.62 × 10^4 min^–1(upon addition of C6F5OH) versus 37.3 min^–1(none)]. 展开更多
关键词 olefin METATHESIS Molecular catalyst RING-OPENING METATHESIS polymerization Cyclic olefin VANADIUM catalyst
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Regioselective Polymerizations of α-Olefins with an α-Diamine Nickel Catalyst 被引量:4
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作者 Heng Liao Jie Gao +2 位作者 Liu Zhong Hai-Yang Gao Qing Wu 《Chinese Journal of Polymer Science》 SCIE CAS CSCD 2019年第10期959-965,I0003,共8页
Polymerizations of linear α-olefins(CnH2n, CH2=CH―R, R = Cn-2) catalyzed by early transition metals typically afford amorphous polymers with alkyl chains(Cn-2), while chain-straightening polymerizations of α-olefin... Polymerizations of linear α-olefins(CnH2n, CH2=CH―R, R = Cn-2) catalyzed by early transition metals typically afford amorphous polymers with alkyl chains(Cn-2), while chain-straightening polymerizations of α-olefins with nickel-based catalysts produce semicrystalline polyolefins. Polymerizations of various α-olefins were carried out using an α-diamine nickel catalyst with a significantly distorted chelating ring. The influences of temperature, monomer concentration, and chain length of α-olefins on polyolefin microstructure were examined in detail. The α-diamine nickel catalyst realized highly regioselective 2,1-insertion of α-olefins regardless of reaction temperature and monomer concentration. Increased chain length of α-olefins led to the formation of more linear polyolefin.Semicrystalline polyolefins with high melting temperatures(Tm) were made from α-olefins through highly regioselective 2,1-insertion and precise chain-straightening. 展开更多
关键词 Nickel catalyst Α-olefin polymerization Regioselectivity Chain WALKING
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Polar comonomer incorporation using cationic Ni α-diimine olefin polymerization catalysts
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作者 Jordan M.Kaiser Brian K.Long 《Science China Chemistry》 SCIE EI CAS CSCD 2019年第2期153-154,共2页
Polyolefins are an indispensable class of materials that have become the most widely produced and utilized polymers today.They are readily synthesized from cheap and abundant monomer feedstocks,such as ethylene and pr... Polyolefins are an indispensable class of materials that have become the most widely produced and utilized polymers today.They are readily synthesized from cheap and abundant monomer feedstocks,such as ethylene and propylene,and are capable of achieving a vast array of thermal and mechanical properties based upon their composition and topology.However,despite their numerous advantages, polyolefins are typically devoid of functional groups which can limit their applicability to many product families,such as coatings,adhesives,and cross-linked polyolefins. 展开更多
关键词 NI Α-DIIMINE olefin polymerization catalysts
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烯烃聚合非茂金属催化剂的研究进展 被引量:2
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作者 倪双阳 任鹤 +3 位作者 王玉如 季荣磊 李琛 崔宇超 《弹性体》 CAS 北大核心 2023年第1期75-80,共6页
综述了近年来用于烯烃聚合的非茂金属催化剂的研究进展,分别介绍了非茂前过渡金属类催化剂和非茂后过渡金属类催化剂在烯烃聚合中的应用及催化性能。非茂前过渡金属催化剂具有催化活性高、聚合物结构可控和分散性好的特点,二十世纪九十... 综述了近年来用于烯烃聚合的非茂金属催化剂的研究进展,分别介绍了非茂前过渡金属类催化剂和非茂后过渡金属类催化剂在烯烃聚合中的应用及催化性能。非茂前过渡金属催化剂具有催化活性高、聚合物结构可控和分散性好的特点,二十世纪九十年代之后已得到了快速的发展。后过渡金属催化剂(特别是Ni和Pd)由于具有独特的性能和较弱的亲氧性,能够合成高支化、具有拓扑结构的聚乙烯并且能催化烯烃与极性单体共聚。简述了α-二亚胺镍和钯催化剂在高支化聚乙烯和催化烯烃与极性单体直接共聚方面的应用,最后对非茂金属催化剂的未来发展进行了展望。 展开更多
关键词 烯烃聚合 前过渡金属催化剂 后过渡金属催化剂 α-二亚胺镍 钯催化剂
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Dual roles of trifluoroborate in nickel-catalyzed ethylene polymerization:Electronic perturbation and anchoring for heterogenization 被引量:1
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作者 Changwen Hong Zihao Wang +3 位作者 Hui Jiang Guifu Si Maoping Song Changle Chen 《Chinese Chemical Letters》 SCIE CAS CSCD 2023年第8期352-355,共4页
Brookhart-typeα-diimine nickel and palladium catalysts have been extensively studied over the past several decades;however,the heterogenization of these metal complexes has received much less attention.In this contri... Brookhart-typeα-diimine nickel and palladium catalysts have been extensively studied over the past several decades;however,the heterogenization of these metal complexes has received much less attention.In this contribution,we installed a trifluoroborate potassium substituent on anα-diimine framework.The ionic nature of trifluoroborate potassium endowed theα-diimine nickel complex with a strong affinity for the SiO_(2)support,while its electron-donating nature enhanced the catalyst stability and polyethylene molecular weight.In the presence of only 100 equiv.of Et2AlCl cocatalyst,the SiO_(2)-supported catalyst demonstrated significantly better performance than its homogeneous analog during ethylene polymerization,with extremely high activity(1.42–6.53×10^(7)g mol^(−1)h^(−1))and high thermal stability.The heterogeneous system led to the formation of high-molecular-weight polyethylenes(Mn 142,500–732,800 g/mol),narrow polydispersities(2.18–3.00),tunable branching densities(21–64 per 1000 carbon atoms),and great mechanical properties.Moreover,the efficient copolymerization of ethylene with comonomers such as methyl 10-undecenoate,6-chloro-1-hexene or 5-hexenylacetate was achieved.These superior properties enabled by the trifluoroborate potassium moiety may inspire its applications in other polymerization catalyst systems. 展开更多
关键词 Nickel catalysts Heterogeneous catalysts olefin polymerization Polar monomer COpolymerization
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电子顺磁共振在Ziegler-Natta催化剂研究中的应用进展
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作者 唐树轩 刘海涛 李昌秀 《石油化工》 CAS CSCD 北大核心 2023年第6期855-861,共7页
Ziegler-Natta催化剂的相关研究是聚烯烃领域的关键。电子顺磁共振(EPR)是表征Ziegler-Natta催化剂中顺磁性Ti组分的有效手段。介绍了EPR的相关原理,综述了应用EPR探究给电子体、聚合单体、无机小分子、烷基铝、格氏试剂、氧化物、L酸... Ziegler-Natta催化剂的相关研究是聚烯烃领域的关键。电子顺磁共振(EPR)是表征Ziegler-Natta催化剂中顺磁性Ti组分的有效手段。介绍了EPR的相关原理,综述了应用EPR探究给电子体、聚合单体、无机小分子、烷基铝、格氏试剂、氧化物、L酸和钛含量等因素对Ziegler-Natta催化剂的影响,以及脉冲EPR技术在Ziegler-Natta催化剂科研前沿的应用,并对EPR应用于Ziegler-Natta催化剂研究进行了展望。 展开更多
关键词 ZIEGLER-NATTA催化剂 电子顺磁共振 电子自旋共振 烯烃聚合
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