In combination with theoretical calculations,experiments were conducted to investigate the evolution behavior of nonmetallic inclusions(NMIs)during the manufacture of large-scale heat-resistant steel ingots using 9CrM...In combination with theoretical calculations,experiments were conducted to investigate the evolution behavior of nonmetallic inclusions(NMIs)during the manufacture of large-scale heat-resistant steel ingots using 9CrMoCoB heat-resistant steel and CaF_(2)–CaO–Al_(2)O_(3)–SiO_(2)–B_(2)O_(3)electroslag remelting(ESR)-type slag in an 80-t industrial ESR furnace.The main types of NMI in the consumable electrode comprised pure alumina,a multiphase oxide consisting of an Al_(2)O_(3)core and liquid CaO–Al_(2)O_(3)–SiO_(2)–MnO shell,and M_(23)C_(6)carbides with an MnS core.The Al_(2)O_(3)and MnS inclusions had higher precipitation temperatures than the M_(23)C_(6)-type carbide under equilibrium and nonequilibrium solidification processes.Therefore,inclusions can act as nucleation sites for carbide layer precipitation.The ESR process completely removed the liquid CaO–Al_(2)O_(3)–SiO_(2)–MnO oxide and MnS inclusion with a carbide shell,and only the Al_(2)O_(3)inclusions and Al_(2)O_(3)core with a carbide shell occupied the remelted ingot.The M_(23)C_(6)-type carbides in steel were determined as Cr_(23)C_(6)based on the analysis of transmission electron microscopy results.The substitution of Cr with W,Fe,or/and Mo in the Cr_(23)C_(6)lattice caused slight changes in the lattice parameter of the Cr_(23)C_(6)carbide.Therefore,Cr_(21.34)Fe_(1.66)C_(6),(Cr_(19)W_(4)C_(6),Cr_(18.4)Mo_(4.6)C_(6),and Cr_(16)Fe_(5)Mo_(2)C_(6)can match the fraction pattern of Cr_(23)C_(6)carbide.The Al_(2)O_(3)inclusions in the remelted ingot formed due to the reduction of CaO,SiO_(2),and MnO components in the liquid inclusion.The increased Al content in liquid steel or the higher supersaturation degree of Al_(2)O_(3)precipitation in the remelted ingot than that in the electrode can be attributed to the evaporation of CaF_(2)and the increase in CaO content in the ESR-type slag.展开更多
AIM:To provide comprehensive data on nonmetallic intraorbital foreign bodies(IOFBs)by summarizing and analyzing material types,clinical manifestations,imaging features,and treatment strategies.METHODS:Totally 28 nonme...AIM:To provide comprehensive data on nonmetallic intraorbital foreign bodies(IOFBs)by summarizing and analyzing material types,clinical manifestations,imaging features,and treatment strategies.METHODS:Totally 28 nonmetallic IOFB cases treated at Shengjing Hospital of China Medical University from 2012 to 2020 were retrospectively reviewed.The types of foreign bodies,clinical features,imaging manifestations,and treatment outcomes were analyzed.RESULTS:Among all cases,67.8%(19/28)of the foreign bodies were organic.The top three entrances were the upper eyelid skin(7/28),lower fornix conjunctiva(6/28),and lower eyelid skin(4/28).In most cases(11/28,39.3%),foreign bodies remained in the medial orbits.The major clinical manifestations included eyelid redness and swelling(20/28,71.4%),conjunctival congestion and edema(17/28,60.7%),and ophthalmoptosis(15/28,53.6%).Infection was the main complication,which occurred in 57.1%(16/28)of all cases.Computerized tomography(CT)values differed for different foreign bodies and varied in the different periods after injury.The plant-and grease-derived foreign bodies and the surrounding pus cysts showed different signals on magnetic resonance imaging(MRI).The prognosis varied with different foreign body types,surgery timing,and intraoperative management.CONCLUSION:The majority of nonmetallic IOFBs are organic and often remain in the superior,medial,and inferior areas of the orbit.Clinical manifestations vary owing to their different textures.CT and MRI facilitate the identification of foreign body materials.Plant-derived foreign bodies should be completely removed,and surgical treatment is a complicated process.展开更多
In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, ...In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, magnesite, talc, Xiuyan jade etc. occur. The formation of these magnesian nonmetallic deposits was related to early Proterozoic evaporates; then these deposits underwent reworking of regional metamorphism and hydrothermal metasomatism during the Lüliang orogeny and tectono-magmatism during the Indosinian-Yanshanian. Among other things, the Mg-rich carbonates formations, minerogenetic structures and ore-forming fluids played a controlling role in the formation of the mineral deposits. Therefore, it can be concluded that the mineral deposits are products of combined processes of the coupling of ore source field, fluid field, thermal field (energy field) and stress field under certain time-space conditions in the early Proterozoic and the late-stage superimposed reworking of tectono-magmatism.展开更多
The mass transfer among the multiphase interactions among the steel, slag, lining refractory, and nonmetallic inclusions during the refining process of a bearing steel was studied using laboratory experiments and nume...The mass transfer among the multiphase interactions among the steel, slag, lining refractory, and nonmetallic inclusions during the refining process of a bearing steel was studied using laboratory experiments and numerical kinetic prediction. Experiments on the system with and without the slag phase were carried out to evaluate the influence of the refractory and the slag on the mass transfer. A mathematical model coupled the ion and molecule coexistence theory, coupled-reaction model, and the surface renewal theory was established to predict the dynamic mass transfer and composition transformation of the steel, the slag, and nonmetallic inclusions in the steel. During the refining process,Al_(2)O_(3) inclusions transformed into Mg O inclusions owing to the mass transfer of [Mg] at the steel/refractory interface and(Mg O) at the slag/refractory interface. Most of the aluminum involved in the transport entered the slag and a small part of the aluminum transferred to lining refractory, forming the Al_(2)O_(3) or Mg O·Al_(2)O_(3). The slag had a significant acceleration effect on the mass transfer. The mass transfer rate(or the reaction rate) of the system with the slag was approximately 5 times larger than that of the system without the slag. In the first 20 min of the refining, rates of magnesium mass transfer at the steel/inclusion interface, steel/refractory interface, and steel/slag interface were x, 1.1 x, and 2.2 x,respectively. The composition transformation of inclusions and the mass transfer of magnesium and aluminum in the steel were predicted with an acceptable accuracy using the established kinetic model.展开更多
Based on the industrial production of non-oriented silicon steel, the rare earth （RE） treatment during the Ruhrstahl Heraeus （RH） refining process was studied. The morphology and the size distribution were observe...Based on the industrial production of non-oriented silicon steel, the rare earth （RE） treatment during the Ruhrstahl Heraeus （RH） refining process was studied. The morphology and the size distribution were observed for the steel specimens treated with different RE treatment conditions. Furthermore, the formation and change of the nonmetallic inclusion characteristics of finished steel sheets after the RE treatment were discussed. The results have shown that in the present work,the suitable RE metal additions are 0.6 -0.9 kg/t steel. After the suitable RE treatment,the formation of AIN and MnS inclusions were restrained, and the aggregation, flotation and removal of nonmetallic inclusions were efficiently promoted and the cleanliness of liquid steel was significantly increased. Meanwhile, the total oxygen concentration reached the minimum value and thle desulfurization efficiency was optimal ,and the type of main inclusions was approximately spherical or elliptical spherical RE radicle inclusions whose size was relatively large.展开更多
The monomer agglomeration of nonmetallic inclusions was simulated with a diffusion limited aggregation （DLA） model of the fractal theory. The simulation study with a random two-dimensional diffusion was carried out....The monomer agglomeration of nonmetallic inclusions was simulated with a diffusion limited aggregation （DLA） model of the fractal theory. The simulation study with a random two-dimensional diffusion was carried out. The results indicate that the DLA model can be used for the simulation of agglomeration behavior of the cluster-type inclusions. The morphology of clusters was observed with SEM and compared with the simulated agglomerates. The modelling procedure of the DLA model is applicable for the agglomeration process. The uncertainty of agglomeration process and the persuasive average agglomerative ratio was analyzed. The factors about the agglomerative ratio with the collision path distance and the size of particles or seed were discussed. The adherence of the nonmetallic inclusions on the dam, the weir and the walls of a tundish, and the absorption of inclusions by stopper or nozzle were also discussed.展开更多
The properties of MnO–Al2O3–SiO2-based plasticized inclusion are likely to change during soaking process due to its low melting point. In this study, the evolution of the MnO–Al2O3–SiO2-based inclusion of 18 wt%Cr...The properties of MnO–Al2O3–SiO2-based plasticized inclusion are likely to change during soaking process due to its low melting point. In this study, the evolution of the MnO–Al2O3–SiO2-based inclusion of 18 wt%Cr-8 wt%Ni stainless steel under isothermal soaking process at 1250°C for different times was investigated by laboratory-scale experiments and thermodynamic analysis. The results showed that the inclusion population density increased at the first stage and then decreased while their average size first decreased and then increased. In addition, almost no Cr2O3-concentrated regions existed within the inclusion before soaking, but more and more Cr2O3 precipitates were formed during soaking. Furthermore, the plasticity of the inclusion deteriorated due to a decrease in the amount of liquid phase and an increase in the high-melting-pointphase MnO–Cr2O3 spinel after the soaking process. In-situ observations by high-temperature confocal laser scanning microscopy(CLSM) confirmed that liquid phases were produced in the inclusions and the inclusions grew rather quickly during the soaking process. Both the experimental results and thermodynamic analysis conclude that there are three routes for inclusion evolution during the soaking process. In particular, Ostwald ripening plays an important role in the inclusion evolution, i.e., MnO–Al2O3–SiO2-based inclusions grow by absorbing the newly precipitated smaller-size MnO–Cr2O3 inclusions.展开更多
This study deals with Nd：YAG laser cutting nonmetallic materials, which is one of the most important and popular industrial applications of laser. The main theme is to evaluate the effects of Nd：YAG laser beam power...This study deals with Nd：YAG laser cutting nonmetallic materials, which is one of the most important and popular industrial applications of laser. The main theme is to evaluate the effects of Nd：YAG laser beam power besides work piece scanning speed. For approximate cutting depth, a theoretical study is conducted in terms of material property and cutting speed. Results show a nonlinear relation between the cutting depth and input energy. There is no significant effect of speed on cutting depth with the speed being larger than 30 mm/s. An extra energy is utilized in the deep cutting. It is inferred that as the laser power increases, cutting depth increases. The experimental outcomes are in good agreement with theoretical results. This analysis will provide a guideline for laser-based industry to select a suitable laser for cutting, scribing, trimming, engraving, and marking nonmetallic materials.展开更多
The distribution and characteristics of nonmetallic micro-inclusions of GCr15 bearing steel were explored through metallographic area method in virtue of tracer method and electronic microscope.The results show that t...The distribution and characteristics of nonmetallic micro-inclusions of GCr15 bearing steel were explored through metallographic area method in virtue of tracer method and electronic microscope.The results show that the micro-inclusions,of which the average value is 0.032%,are mainly the compounds formed via the adsorption/aggregation of multielement deoxidized compounds and secondarily deoxidized products on tundish liquid level.The micro-inclusions of diameters from 0 to 5 μm are 92.5% in total,which basically determines the characteristics of inclusions distribution in casting slab.The inclusions of diameters more than 10 μm only account for less than 1% in total,which have little influence on steel quality.The relationship between equilibrium compositions of the first deoxidation products and molten steel compositions was also calculated based on thermodynamic theory.展开更多
There is a close relationship between occurrence of nonmetallic minerals and tectonic evolution of geosyncline, platform and diwa (geodepression) on the western margin of the Dongting diwa. Some results that (1) diwa ...There is a close relationship between occurrence of nonmetallic minerals and tectonic evolution of geosyncline, platform and diwa (geodepression) on the western margin of the Dongting diwa. Some results that (1) diwa tectonics is berfeficial for formation and preservation of nonmetallic minerals and (2) volcano-sedimentary altered ore deposits, saline deposits and organo-sedimentary ore deposits can be often found in diwa basins are gained.展开更多
The structures, infrared spectra and cation stability of seven 5,5′-azotetrazolate nonmetallic salts are investigated by using B3LYP method with 6-311+G (d) basis set. The salts are guanidinium (GZT), aminoguanidiniu...The structures, infrared spectra and cation stability of seven 5,5′-azotetrazolate nonmetallic salts are investigated by using B3LYP method with 6-311+G (d) basis set. The salts are guanidinium (GZT), aminoguanidinium (AGZT), diaminoguanidinium (DAGZT), triaminoguanidinium (TAGZT), azidoformamidinium (AFZT), ammonium (AZT), and hydrazinium (HZT), respectively. The calculated results indicate that the carbon and nitrogen atoms of the cations in seven nonmetallic salts are characterized to be sp2 hybrid atoms, and the ranges of characteristic absorption peaks in IR spectra of the seven nonmetallic salts are approximative consistent. All their cations are stable and their stabilities decrease with the increase in their nitrogen contents.展开更多
This review summarized the recent advances in the utilization of nonmetallic minerals and their applications for fabrication of unfired refractories.The preparation of refractory powder utilizing cheap nonmetallic min...This review summarized the recent advances in the utilization of nonmetallic minerals and their applications for fabrication of unfired refractories.The preparation of refractory powder utilizing cheap nonmetallic minerals of zircon,low-grade bauxite and quartz was discussed,respectively.The preparation of three unfired SiC-based refractories：SiC-SiAlON-ZrN,Al2O3-SiC/β-SiAlON/Ti（C,N）-C,and Al2O3-SiC-Si3N4 using the as-prepared refractory powders was introduced.展开更多
The shape, type, content, and dimension of nonmetallic inclusions in SUS304 strip produced by twin-roll strip casting were studied using scanning electron microscopy （SEM）. The results show that the inclusions are m...The shape, type, content, and dimension of nonmetallic inclusions in SUS304 strip produced by twin-roll strip casting were studied using scanning electron microscopy （SEM）. The results show that the inclusions are mainly spherical Al2O3 and complex oxides composed of MnO, Al2O3 , and SiO2. The percentage of fine oxides smaller than 3 μm reaches up to 51.8%. The theoretical calculations show that fine oxides have precipitated during solidification. Therefore, it is concluded that during twin-roll strip casting, because of high cooling rate, the size of inclusions precipitated during solidification decreases, and the amount increases.展开更多
Although electrohydraulic discharge is effective for wastewater treatment,its application is restricted by water conductivity and limited to the treatment of low conductivity water. For high conductivity water treatme...Although electrohydraulic discharge is effective for wastewater treatment,its application is restricted by water conductivity and limited to the treatment of low conductivity water. For high conductivity water treatment,water-surface discharge is the preferred choice.However. the metallic electrodes are easily corroded because of the high temperature and strong oxidative environment caused by gas phase discharge and the electrochemical reaction in water.As a result. the efficiency of the water treatment might be affected and the service life of the reactor might be shortened.In order to avoid the corrosion problem,nonmetallic electrode water-surface discharge is introduced into high conductivity water treatment in the present study.Carbon-felt and water were used as the high voltage electrode and ground electrode,respectively.A comparison of the electrical and chemical characteristics showed that nonmetallic electrode discharge maintained the discharge characteristics and enhanced the energy efficiency,and furthermore,the corrosion of metal electrodes was avoided.展开更多
Physical simulation is used to study the movement of nonmetallic particles in Al melt in electro- magnetic field. It is found that the terminal velocity of particles in different Reynolds number range has different fu...Physical simulation is used to study the movement of nonmetallic particles in Al melt in electro- magnetic field. It is found that the terminal velocity of particles in different Reynolds number range has different functions. By confirming drag force coefficient of nonmetallic particles with Reynolds number in the range of 0.2-10 and 10-25 respectively, two functions of terminal ve- locity for spherical nonmetallic particles have been got accordingly, which provide a theoretical basis for separating nonmetallic inclusions from Al melt in electromagnetic field.展开更多
The flotation results of a phosphate ore are improved by replacing the conventional collectors of fatty acids with composite collectors. The synergistic effect on the froth characteristics in systems using composite c...The flotation results of a phosphate ore are improved by replacing the conventional collectors of fatty acids with composite collectors. The synergistic effect on the froth characteristics in systems using composite collectors has then been studied, and the concept of 'mixed hemimicellae' has been proposed in the adsorption of composite collectors at the air/solution interfaces.展开更多
Owing to the internal relationship between material sources or mineralization ways and the difference ofmineralization micro-environments or the change of constraints. certain types of nonmetallic mineral depositsare ...Owing to the internal relationship between material sources or mineralization ways and the difference ofmineralization micro-environments or the change of constraints. certain types of nonmetallic mineral depositsare regularly formed either simultaneously or in successive order under the control of certain association ofmineralization processes in a certain geotectonic environment, thus forming a minerogenetic series ofnonmetallic mineral deposits. The geological setting that controls the formation of minerogenetic series is mosttruly recorded in ore-bearing formations. while the mineralization processes which are associated or surely suc-cessive are the indispensable prerequisite for the formation of the various mineral deposits of a minerogeneticseries. Therefore, the minerogenetic series of nonmetallic mineral deposits can be classified according tomineral-bearing formations and mineralization processes. Based on available data. 13 minerogenetic series aredistinguished in China. The study of minerogenetic series may not only result in the enrichment of the theory ofmineral deposits but also help direct mineral prospecting and give guidance in the integrated development andutillization of mineral resources.展开更多
Zero-valent iron(ZVI),an ideal reductant treating persistent pollutants,is hampered by issues like corrosion,passivation,and suboptimal utilization.Recent advancements in nonmetallic modified ZVI(NM-ZVI)show promising...Zero-valent iron(ZVI),an ideal reductant treating persistent pollutants,is hampered by issues like corrosion,passivation,and suboptimal utilization.Recent advancements in nonmetallic modified ZVI(NM-ZVI)show promising potential in circumventing these challenges by modifying ZVI's surface and internal physicochemical properties.Despite its promise,a thorough synthesis of research advancements in this domain remains elusive.Here we review the innovative methodologies,regulatory principles,and reduction-centric mechanisms underpinning NM-ZVI's effectiveness against two prevalent persistent pollutants:halogenated organic compounds and heavy metals.We start by evaluating different nonmetallic modification techniques,such as liquid-phase reduction,mechanical ball milling,and pyrolysis,and their respective advantages.The discussion progresses towards a critical analysis of current strategies and mechanisms used for NM-ZVI to enhance its reactivity,electron selectivity,and electron utilization efficiency.This is achieved by optimizing the elemental compositions,content ratios,lattice constants,hydrophobicity,and conductivity.Furthermore,we propose novel approaches for augmenting NM-ZVI's capability to address complex pollution challenges.This review highlights NM-ZVI's potential as an alternative to remediate water environments contaminated with halogenated organic compounds or heavy metals,contributing to the broader discourse on green remediation technologies.展开更多
Organic electrode materials(OEMs),withmerits of structural diversity,molecular-level controllability,resource abundance,and environmental friendliness,have become a promising electrode candidate for low-carbon renewab...Organic electrode materials(OEMs),withmerits of structural diversity,molecular-level controllability,resource abundance,and environmental friendliness,have become a promising electrode candidate for low-carbon renewable batteries.Safer,environmentally benign,and sustainable aqueous rechargeable batteries are particularly appealing for large-scale energy storage applications.This review aims to provide an insightful discussion of OEMs in nonmetallic charge carrier-based batteries,especially for the application in aqueous rechargeable systems.The emerging application of OEMs in versatile aqueous batteries will be analyzed emphatically,including aqueous proton batteries,aqueous ammonium-ion batteries,and air self-charging batteries.We expect that this review can serve as a guide for the future development of OEMs in nonmetallic charge carrier-based batteries and provide inspiration for unmet challenges.展开更多
To control the distribution of nonmetallic inclusions in molten developed method, hot-top pulsed magneto-oscillation （HPMO）, steel is of highly commercial importance. A newly was employed to control nonmetallic incl...To control the distribution of nonmetallic inclusions in molten developed method, hot-top pulsed magneto-oscillation （HPMO）, steel is of highly commercial importance. A newly was employed to control nonmetallic inclusions in a medium-carbon steel ingot. The experimental results present that the position of nonmetallic inclusions of spinel （Al-Mg-O） and Mn-S inclusions is significantly influenced by HPMO. The number of nonmetallic inclusions gradually increased from the lateral wall to the center of ingot along the radial direction under the impact of HPMO treatment, whereas this distribution trend cannot be observed in the reference sample without HPMO treatment. In addition, the number of inclusions along vertical direction is proportional to the height of ingot, especially for the inclusions with the size of larger than 10 pro. It indicates that the application of HPMO can push away inclusions from lateral to center, and then the expelled inclusions aggregate and rise up to the top of ingot.展开更多
基金the Korea Evaluation Institute of Industrial Technology(KEIT,No.20009956)the Korea Institute for Advancement of Technology(KIAT,No.P0023676,HRD Program for Industrial Innovation)+1 种基金funded by the Ministry of Trade,Industry and Energy(MOTIE),Koreathe Swedish Foundation for International Cooperation in Research and Higher Education(STINT)for supporting the collaboration between KTH(Sweden)and Hanyang University(Korea)。
文摘In combination with theoretical calculations,experiments were conducted to investigate the evolution behavior of nonmetallic inclusions(NMIs)during the manufacture of large-scale heat-resistant steel ingots using 9CrMoCoB heat-resistant steel and CaF_(2)–CaO–Al_(2)O_(3)–SiO_(2)–B_(2)O_(3)electroslag remelting(ESR)-type slag in an 80-t industrial ESR furnace.The main types of NMI in the consumable electrode comprised pure alumina,a multiphase oxide consisting of an Al_(2)O_(3)core and liquid CaO–Al_(2)O_(3)–SiO_(2)–MnO shell,and M_(23)C_(6)carbides with an MnS core.The Al_(2)O_(3)and MnS inclusions had higher precipitation temperatures than the M_(23)C_(6)-type carbide under equilibrium and nonequilibrium solidification processes.Therefore,inclusions can act as nucleation sites for carbide layer precipitation.The ESR process completely removed the liquid CaO–Al_(2)O_(3)–SiO_(2)–MnO oxide and MnS inclusion with a carbide shell,and only the Al_(2)O_(3)inclusions and Al_(2)O_(3)core with a carbide shell occupied the remelted ingot.The M_(23)C_(6)-type carbides in steel were determined as Cr_(23)C_(6)based on the analysis of transmission electron microscopy results.The substitution of Cr with W,Fe,or/and Mo in the Cr_(23)C_(6)lattice caused slight changes in the lattice parameter of the Cr_(23)C_(6)carbide.Therefore,Cr_(21.34)Fe_(1.66)C_(6),(Cr_(19)W_(4)C_(6),Cr_(18.4)Mo_(4.6)C_(6),and Cr_(16)Fe_(5)Mo_(2)C_(6)can match the fraction pattern of Cr_(23)C_(6)carbide.The Al_(2)O_(3)inclusions in the remelted ingot formed due to the reduction of CaO,SiO_(2),and MnO components in the liquid inclusion.The increased Al content in liquid steel or the higher supersaturation degree of Al_(2)O_(3)precipitation in the remelted ingot than that in the electrode can be attributed to the evaporation of CaF_(2)and the increase in CaO content in the ESR-type slag.
文摘AIM:To provide comprehensive data on nonmetallic intraorbital foreign bodies(IOFBs)by summarizing and analyzing material types,clinical manifestations,imaging features,and treatment strategies.METHODS:Totally 28 nonmetallic IOFB cases treated at Shengjing Hospital of China Medical University from 2012 to 2020 were retrospectively reviewed.The types of foreign bodies,clinical features,imaging manifestations,and treatment outcomes were analyzed.RESULTS:Among all cases,67.8%(19/28)of the foreign bodies were organic.The top three entrances were the upper eyelid skin(7/28),lower fornix conjunctiva(6/28),and lower eyelid skin(4/28).In most cases(11/28,39.3%),foreign bodies remained in the medial orbits.The major clinical manifestations included eyelid redness and swelling(20/28,71.4%),conjunctival congestion and edema(17/28,60.7%),and ophthalmoptosis(15/28,53.6%).Infection was the main complication,which occurred in 57.1%(16/28)of all cases.Computerized tomography(CT)values differed for different foreign bodies and varied in the different periods after injury.The plant-and grease-derived foreign bodies and the surrounding pus cysts showed different signals on magnetic resonance imaging(MRI).The prognosis varied with different foreign body types,surgery timing,and intraoperative management.CONCLUSION:The majority of nonmetallic IOFBs are organic and often remain in the superior,medial,and inferior areas of the orbit.Clinical manifestations vary owing to their different textures.CT and MRI facilitate the identification of foreign body materials.Plant-derived foreign bodies should be completely removed,and surgical treatment is a complicated process.
基金supported by the Foundation for Development of Geological Science and Technology of the former Ministry of Geology and Mineral Resources of China grant HY979830
文摘In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, magnesite, talc, Xiuyan jade etc. occur. The formation of these magnesian nonmetallic deposits was related to early Proterozoic evaporates; then these deposits underwent reworking of regional metamorphism and hydrothermal metasomatism during the Lüliang orogeny and tectono-magmatism during the Indosinian-Yanshanian. Among other things, the Mg-rich carbonates formations, minerogenetic structures and ore-forming fluids played a controlling role in the formation of the mineral deposits. Therefore, it can be concluded that the mineral deposits are products of combined processes of the coupling of ore source field, fluid field, thermal field (energy field) and stress field under certain time-space conditions in the early Proterozoic and the late-stage superimposed reworking of tectono-magmatism.
基金financially supported by the National Natural Science Foundation China(Nos.U1860206,51725402,and 51874032)the Fundamental Research Funds for the Central Universities(Nos.FRF-TP-19-037A2Z and FRFBD-20-04A)+2 种基金the S&T Program of Hebei,China(No.20311006D)the High Steel Center(HSC)at Yanshan University,Chinathe High Quality Steel Consortium(HQSC)at University of Science and Technology Beijing,China。
文摘The mass transfer among the multiphase interactions among the steel, slag, lining refractory, and nonmetallic inclusions during the refining process of a bearing steel was studied using laboratory experiments and numerical kinetic prediction. Experiments on the system with and without the slag phase were carried out to evaluate the influence of the refractory and the slag on the mass transfer. A mathematical model coupled the ion and molecule coexistence theory, coupled-reaction model, and the surface renewal theory was established to predict the dynamic mass transfer and composition transformation of the steel, the slag, and nonmetallic inclusions in the steel. During the refining process,Al_(2)O_(3) inclusions transformed into Mg O inclusions owing to the mass transfer of [Mg] at the steel/refractory interface and(Mg O) at the slag/refractory interface. Most of the aluminum involved in the transport entered the slag and a small part of the aluminum transferred to lining refractory, forming the Al_(2)O_(3) or Mg O·Al_(2)O_(3). The slag had a significant acceleration effect on the mass transfer. The mass transfer rate(or the reaction rate) of the system with the slag was approximately 5 times larger than that of the system without the slag. In the first 20 min of the refining, rates of magnesium mass transfer at the steel/inclusion interface, steel/refractory interface, and steel/slag interface were x, 1.1 x, and 2.2 x,respectively. The composition transformation of inclusions and the mass transfer of magnesium and aluminum in the steel were predicted with an acceptable accuracy using the established kinetic model.
文摘Based on the industrial production of non-oriented silicon steel, the rare earth （RE） treatment during the Ruhrstahl Heraeus （RH） refining process was studied. The morphology and the size distribution were observed for the steel specimens treated with different RE treatment conditions. Furthermore, the formation and change of the nonmetallic inclusion characteristics of finished steel sheets after the RE treatment were discussed. The results have shown that in the present work,the suitable RE metal additions are 0.6 -0.9 kg/t steel. After the suitable RE treatment,the formation of AIN and MnS inclusions were restrained, and the aggregation, flotation and removal of nonmetallic inclusions were efficiently promoted and the cleanliness of liquid steel was significantly increased. Meanwhile, the total oxygen concentration reached the minimum value and thle desulfurization efficiency was optimal ,and the type of main inclusions was approximately spherical or elliptical spherical RE radicle inclusions whose size was relatively large.
文摘The monomer agglomeration of nonmetallic inclusions was simulated with a diffusion limited aggregation （DLA） model of the fractal theory. The simulation study with a random two-dimensional diffusion was carried out. The results indicate that the DLA model can be used for the simulation of agglomeration behavior of the cluster-type inclusions. The morphology of clusters was observed with SEM and compared with the simulated agglomerates. The modelling procedure of the DLA model is applicable for the agglomeration process. The uncertainty of agglomeration process and the persuasive average agglomerative ratio was analyzed. The factors about the agglomerative ratio with the collision path distance and the size of particles or seed were discussed. The adherence of the nonmetallic inclusions on the dam, the weir and the walls of a tundish, and the absorption of inclusions by stopper or nozzle were also discussed.
基金financially supported by the National Science Foundation for Young Scientists of China(No.5170402)the China Postdoctoral Fund(No.2018M630071)+1 种基金the Fundamental Research Funds for the Central Universities(No.RF-TP-19-030A2)the Joint Funds of the National Natural Science Foundation of China(No.U1560203)
文摘The properties of MnO–Al2O3–SiO2-based plasticized inclusion are likely to change during soaking process due to its low melting point. In this study, the evolution of the MnO–Al2O3–SiO2-based inclusion of 18 wt%Cr-8 wt%Ni stainless steel under isothermal soaking process at 1250°C for different times was investigated by laboratory-scale experiments and thermodynamic analysis. The results showed that the inclusion population density increased at the first stage and then decreased while their average size first decreased and then increased. In addition, almost no Cr2O3-concentrated regions existed within the inclusion before soaking, but more and more Cr2O3 precipitates were formed during soaking. Furthermore, the plasticity of the inclusion deteriorated due to a decrease in the amount of liquid phase and an increase in the high-melting-pointphase MnO–Cr2O3 spinel after the soaking process. In-situ observations by high-temperature confocal laser scanning microscopy(CLSM) confirmed that liquid phases were produced in the inclusions and the inclusions grew rather quickly during the soaking process. Both the experimental results and thermodynamic analysis conclude that there are three routes for inclusion evolution during the soaking process. In particular, Ostwald ripening plays an important role in the inclusion evolution, i.e., MnO–Al2O3–SiO2-based inclusions grow by absorbing the newly precipitated smaller-size MnO–Cr2O3 inclusions.
基金supported by the Science Foundation of the Ministry of Science and Technology Malaysiathe Islamic Development Bank Jeddahsupport of the Universiti Teknologi Malaysia for this research work
文摘This study deals with Nd：YAG laser cutting nonmetallic materials, which is one of the most important and popular industrial applications of laser. The main theme is to evaluate the effects of Nd：YAG laser beam power besides work piece scanning speed. For approximate cutting depth, a theoretical study is conducted in terms of material property and cutting speed. Results show a nonlinear relation between the cutting depth and input energy. There is no significant effect of speed on cutting depth with the speed being larger than 30 mm/s. An extra energy is utilized in the deep cutting. It is inferred that as the laser power increases, cutting depth increases. The experimental outcomes are in good agreement with theoretical results. This analysis will provide a guideline for laser-based industry to select a suitable laser for cutting, scribing, trimming, engraving, and marking nonmetallic materials.
基金Supported by Natural Science Foundation of Hebei Province (No.502265)
文摘The distribution and characteristics of nonmetallic micro-inclusions of GCr15 bearing steel were explored through metallographic area method in virtue of tracer method and electronic microscope.The results show that the micro-inclusions,of which the average value is 0.032%,are mainly the compounds formed via the adsorption/aggregation of multielement deoxidized compounds and secondarily deoxidized products on tundish liquid level.The micro-inclusions of diameters from 0 to 5 μm are 92.5% in total,which basically determines the characteristics of inclusions distribution in casting slab.The inclusions of diameters more than 10 μm only account for less than 1% in total,which have little influence on steel quality.The relationship between equilibrium compositions of the first deoxidation products and molten steel compositions was also calculated based on thermodynamic theory.
文摘There is a close relationship between occurrence of nonmetallic minerals and tectonic evolution of geosyncline, platform and diwa (geodepression) on the western margin of the Dongting diwa. Some results that (1) diwa tectonics is berfeficial for formation and preservation of nonmetallic minerals and (2) volcano-sedimentary altered ore deposits, saline deposits and organo-sedimentary ore deposits can be often found in diwa basins are gained.
文摘The structures, infrared spectra and cation stability of seven 5,5′-azotetrazolate nonmetallic salts are investigated by using B3LYP method with 6-311+G (d) basis set. The salts are guanidinium (GZT), aminoguanidinium (AGZT), diaminoguanidinium (DAGZT), triaminoguanidinium (TAGZT), azidoformamidinium (AFZT), ammonium (AZT), and hydrazinium (HZT), respectively. The calculated results indicate that the carbon and nitrogen atoms of the cations in seven nonmetallic salts are characterized to be sp2 hybrid atoms, and the ranges of characteristic absorption peaks in IR spectra of the seven nonmetallic salts are approximative consistent. All their cations are stable and their stabilities decrease with the increase in their nitrogen contents.
基金supported by the National Natural Science Foundations of China ( 51032007,51372232,and 51472222 )the Research Fund for the Doctoral Program of Higher Education of China ( 20130022110006 )the Beijing Higher Education Young Elite Teacher Project ( YETP0636)
文摘This review summarized the recent advances in the utilization of nonmetallic minerals and their applications for fabrication of unfired refractories.The preparation of refractory powder utilizing cheap nonmetallic minerals of zircon,low-grade bauxite and quartz was discussed,respectively.The preparation of three unfired SiC-based refractories：SiC-SiAlON-ZrN,Al2O3-SiC/β-SiAlON/Ti（C,N）-C,and Al2O3-SiC-Si3N4 using the as-prepared refractory powders was introduced.
基金This work was financially supported by the National Natural Science Foundation of China (No.50434040).
文摘The shape, type, content, and dimension of nonmetallic inclusions in SUS304 strip produced by twin-roll strip casting were studied using scanning electron microscopy （SEM）. The results show that the inclusions are mainly spherical Al2O3 and complex oxides composed of MnO, Al2O3 , and SiO2. The percentage of fine oxides smaller than 3 μm reaches up to 51.8%. The theoretical calculations show that fine oxides have precipitated during solidification. Therefore, it is concluded that during twin-roll strip casting, because of high cooling rate, the size of inclusions precipitated during solidification decreases, and the amount increases.
基金supported by National Natural Science Foundation of China(Nos.20836008 and 21076189)
文摘Although electrohydraulic discharge is effective for wastewater treatment,its application is restricted by water conductivity and limited to the treatment of low conductivity water. For high conductivity water treatment,water-surface discharge is the preferred choice.However. the metallic electrodes are easily corroded because of the high temperature and strong oxidative environment caused by gas phase discharge and the electrochemical reaction in water.As a result. the efficiency of the water treatment might be affected and the service life of the reactor might be shortened.In order to avoid the corrosion problem,nonmetallic electrode water-surface discharge is introduced into high conductivity water treatment in the present study.Carbon-felt and water were used as the high voltage electrode and ground electrode,respectively.A comparison of the electrical and chemical characteristics showed that nonmetallic electrode discharge maintained the discharge characteristics and enhanced the energy efficiency,and furthermore,the corrosion of metal electrodes was avoided.
基金supported by the National Natural Science Foundation of China(No.59871029)the China Postdoctoral Science Foundation.
文摘Physical simulation is used to study the movement of nonmetallic particles in Al melt in electro- magnetic field. It is found that the terminal velocity of particles in different Reynolds number range has different functions. By confirming drag force coefficient of nonmetallic particles with Reynolds number in the range of 0.2-10 and 10-25 respectively, two functions of terminal ve- locity for spherical nonmetallic particles have been got accordingly, which provide a theoretical basis for separating nonmetallic inclusions from Al melt in electromagnetic field.
文摘The flotation results of a phosphate ore are improved by replacing the conventional collectors of fatty acids with composite collectors. The synergistic effect on the froth characteristics in systems using composite collectors has then been studied, and the concept of 'mixed hemimicellae' has been proposed in the adsorption of composite collectors at the air/solution interfaces.
文摘Owing to the internal relationship between material sources or mineralization ways and the difference ofmineralization micro-environments or the change of constraints. certain types of nonmetallic mineral depositsare regularly formed either simultaneously or in successive order under the control of certain association ofmineralization processes in a certain geotectonic environment, thus forming a minerogenetic series ofnonmetallic mineral deposits. The geological setting that controls the formation of minerogenetic series is mosttruly recorded in ore-bearing formations. while the mineralization processes which are associated or surely suc-cessive are the indispensable prerequisite for the formation of the various mineral deposits of a minerogeneticseries. Therefore, the minerogenetic series of nonmetallic mineral deposits can be classified according tomineral-bearing formations and mineralization processes. Based on available data. 13 minerogenetic series aredistinguished in China. The study of minerogenetic series may not only result in the enrichment of the theory ofmineral deposits but also help direct mineral prospecting and give guidance in the integrated development andutillization of mineral resources.
基金supported by the NSFC-JSPS joint research program(No.51961145202)the National Natural Science Foundation of China(No.52370163,52321005,and 52293443)the State Key Laboratory of Urban Water Resource and Environment(Harbin Institute of Technology)(No.2022TS42).
文摘Zero-valent iron(ZVI),an ideal reductant treating persistent pollutants,is hampered by issues like corrosion,passivation,and suboptimal utilization.Recent advancements in nonmetallic modified ZVI(NM-ZVI)show promising potential in circumventing these challenges by modifying ZVI's surface and internal physicochemical properties.Despite its promise,a thorough synthesis of research advancements in this domain remains elusive.Here we review the innovative methodologies,regulatory principles,and reduction-centric mechanisms underpinning NM-ZVI's effectiveness against two prevalent persistent pollutants:halogenated organic compounds and heavy metals.We start by evaluating different nonmetallic modification techniques,such as liquid-phase reduction,mechanical ball milling,and pyrolysis,and their respective advantages.The discussion progresses towards a critical analysis of current strategies and mechanisms used for NM-ZVI to enhance its reactivity,electron selectivity,and electron utilization efficiency.This is achieved by optimizing the elemental compositions,content ratios,lattice constants,hydrophobicity,and conductivity.Furthermore,we propose novel approaches for augmenting NM-ZVI's capability to address complex pollution challenges.This review highlights NM-ZVI's potential as an alternative to remediate water environments contaminated with halogenated organic compounds or heavy metals,contributing to the broader discourse on green remediation technologies.
基金All authors would like to acknowledge the support from the National Natural Science Foundation of China(NSFC no.51872128)the Ministry of Science and Technology of China(grant nos.G2021014005L and G2022014098L)+1 种基金the Natural Science Foundation of Jiangsu Province(grant no.BK20210744)the Young Talent Support Fund from Jiangsu University(grant no.5501310023).
文摘Organic electrode materials(OEMs),withmerits of structural diversity,molecular-level controllability,resource abundance,and environmental friendliness,have become a promising electrode candidate for low-carbon renewable batteries.Safer,environmentally benign,and sustainable aqueous rechargeable batteries are particularly appealing for large-scale energy storage applications.This review aims to provide an insightful discussion of OEMs in nonmetallic charge carrier-based batteries,especially for the application in aqueous rechargeable systems.The emerging application of OEMs in versatile aqueous batteries will be analyzed emphatically,including aqueous proton batteries,aqueous ammonium-ion batteries,and air self-charging batteries.We expect that this review can serve as a guide for the future development of OEMs in nonmetallic charge carrier-based batteries and provide inspiration for unmet challenges.
基金Acknowledgements The authors acknowledge the financial supports from the National Natural Science Foundation of China （Grant Nos. U1760204 and 51504048）, the National Key Research Program of China （Grant No. 2017YFB0701800） and the Science and Technology Commission of Shanghai Municipality （Grant No. 15520710800）.
文摘To control the distribution of nonmetallic inclusions in molten developed method, hot-top pulsed magneto-oscillation （HPMO）, steel is of highly commercial importance. A newly was employed to control nonmetallic inclusions in a medium-carbon steel ingot. The experimental results present that the position of nonmetallic inclusions of spinel （Al-Mg-O） and Mn-S inclusions is significantly influenced by HPMO. The number of nonmetallic inclusions gradually increased from the lateral wall to the center of ingot along the radial direction under the impact of HPMO treatment, whereas this distribution trend cannot be observed in the reference sample without HPMO treatment. In addition, the number of inclusions along vertical direction is proportional to the height of ingot, especially for the inclusions with the size of larger than 10 pro. It indicates that the application of HPMO can push away inclusions from lateral to center, and then the expelled inclusions aggregate and rise up to the top of ingot.
