将基于最优插值（OI）的同化并行模块植入全谱空间的第三代海浪模式 WAVEWATCH III ver-sion3.14,建立数据同化的海浪模式预报系统,并通过实际的预报个例对同化系统进行检验。个例实验是以5°S以北的印度洋海域为目标计算区域,海面...将基于最优插值（OI）的同化并行模块植入全谱空间的第三代海浪模式 WAVEWATCH III ver-sion3.14,建立数据同化的海浪模式预报系统,并通过实际的预报个例对同化系统进行检验。个例实验是以5°S以北的印度洋海域为目标计算区域,海面风场强迫采用业务单位的中尺度天气预报模式WRF （weather research and forecast）提供的逐时海面风场预报产品。模式积分过程中连续同化2010年12月15日、16日和17日过境北印度洋的Jason-2卫星高度计沿轨有效波高（SWH）数据（需要指出的是,每次同化得到新的SWH分析场后需重构相应的二维海浪谱用于谱模式）。SWH同化分析值和无同化的对照组分别与高度计沿轨观测数据比较发现,就日平均统计来看,同化较无同化使SWH分析值的均方根误差减小约25%-50%。以 SWH同化分析场作为初始场的预报表明,同化对预报影响的时效性可延长至48-60 h。本研究目的是通过将高度计测量的SWH数据同化到海浪模式进一步提升海浪数值预报的准确度。展开更多
While argyrodite sulfides are getting more and more attention as highly promising solid-state electrolytes(SSEs)for solid batteries,they also suffer from the typical sulfide setbacks such as poor electrochemical compa...While argyrodite sulfides are getting more and more attention as highly promising solid-state electrolytes(SSEs)for solid batteries,they also suffer from the typical sulfide setbacks such as poor electrochemical compatibility with Li anode and high-voltage cathodes and serious sensitivity to humid air,which hinders their practical applications.Herein,we have devised an effective strategy to overcome these challenging shortcomings through modification of chalcogen chemistry under the guidance of theoretical modeling.The resultant Li_(6.25)PS_(4)O_(1.25)Cl_(0.75)delivered excellent electrochemical compatibility with both pure Li anode and high-voltage LiCoO_(2)cathode,without compromising the superb ionic conductivity of the pristine sulfide.Furthermore,the current SSE also exhibited highly improved stability to oxygen and humidity,with further advantage being more insulating to electrons.The remarkably enhanced compatibility with electrodes is attributed to in situ formation of helpful electrolyte–electrode interphases.The formation of in situ anode–electrolyte interphase(AEI)enabled stable Li plating/stripping in the Li|Li_(6.25)PS_(4)O_(1.25)Cl_(0.75)|Li symmetric cells at a high current density up to 1 mA cm^(-2)over 200 h and 2 mA cm^(-2)for another 100 h.The in situ amorphous nano-film cathode–electrolyte interphase(CEI)facilitated protection of the SSE from decomposition at elevated voltage.Consequently,the synergistic effect of AEI and CEI helped the LiCoO_(2)|Li_(6.25)PS_(4)O_(1.25)Cl_(0.75)|Li full-battery cell to achieve markedly better cycling stability than that using the pristine Li_(6)PS_(5)Cl as SSE,at a high area loading of the active cathode material(4 mg cm^(-2))in type-2032 coin cells.This work is to add a desirable SSE in the argyrodite sulfide family,so that high-performance solid battery cells could be fabricated without the usual need of strict control of the ambient atmosphere.展开更多
文摘将基于最优插值（OI）的同化并行模块植入全谱空间的第三代海浪模式 WAVEWATCH III ver-sion3.14,建立数据同化的海浪模式预报系统,并通过实际的预报个例对同化系统进行检验。个例实验是以5°S以北的印度洋海域为目标计算区域,海面风场强迫采用业务单位的中尺度天气预报模式WRF （weather research and forecast）提供的逐时海面风场预报产品。模式积分过程中连续同化2010年12月15日、16日和17日过境北印度洋的Jason-2卫星高度计沿轨有效波高（SWH）数据（需要指出的是,每次同化得到新的SWH分析场后需重构相应的二维海浪谱用于谱模式）。SWH同化分析值和无同化的对照组分别与高度计沿轨观测数据比较发现,就日平均统计来看,同化较无同化使SWH分析值的均方根误差减小约25%-50%。以 SWH同化分析场作为初始场的预报表明,同化对预报影响的时效性可延长至48-60 h。本研究目的是通过将高度计测量的SWH数据同化到海浪模式进一步提升海浪数值预报的准确度。
基金supported in part by the Zhengzhou Materials Genome Institutethe National Natural Science Foundation of China(No.52171082,51001091,51571182,111174256,91233101,51602094,11274100)the Program for Science&Technology Innovation Talents in the Universities of Henan Province(18HASTIT009)。
文摘While argyrodite sulfides are getting more and more attention as highly promising solid-state electrolytes(SSEs)for solid batteries,they also suffer from the typical sulfide setbacks such as poor electrochemical compatibility with Li anode and high-voltage cathodes and serious sensitivity to humid air,which hinders their practical applications.Herein,we have devised an effective strategy to overcome these challenging shortcomings through modification of chalcogen chemistry under the guidance of theoretical modeling.The resultant Li_(6.25)PS_(4)O_(1.25)Cl_(0.75)delivered excellent electrochemical compatibility with both pure Li anode and high-voltage LiCoO_(2)cathode,without compromising the superb ionic conductivity of the pristine sulfide.Furthermore,the current SSE also exhibited highly improved stability to oxygen and humidity,with further advantage being more insulating to electrons.The remarkably enhanced compatibility with electrodes is attributed to in situ formation of helpful electrolyte–electrode interphases.The formation of in situ anode–electrolyte interphase(AEI)enabled stable Li plating/stripping in the Li|Li_(6.25)PS_(4)O_(1.25)Cl_(0.75)|Li symmetric cells at a high current density up to 1 mA cm^(-2)over 200 h and 2 mA cm^(-2)for another 100 h.The in situ amorphous nano-film cathode–electrolyte interphase(CEI)facilitated protection of the SSE from decomposition at elevated voltage.Consequently,the synergistic effect of AEI and CEI helped the LiCoO_(2)|Li_(6.25)PS_(4)O_(1.25)Cl_(0.75)|Li full-battery cell to achieve markedly better cycling stability than that using the pristine Li_(6)PS_(5)Cl as SSE,at a high area loading of the active cathode material(4 mg cm^(-2))in type-2032 coin cells.This work is to add a desirable SSE in the argyrodite sulfide family,so that high-performance solid battery cells could be fabricated without the usual need of strict control of the ambient atmosphere.
