With the application of HIGEE process intensification technology, petroleum sulfonate surfactant used for enhanced oil recovery was synthesized from petroleum fraction of Shengli crude oil with three sulfonating agent...With the application of HIGEE process intensification technology, petroleum sulfonate surfactant used for enhanced oil recovery was synthesized from petroleum fraction of Shengli crude oil with three sulfonating agents, including diluted liquid sulfur trioxide, diluted gaseous sulfur trioxide and fuming sulfuric acid. For each sulfonating agent, different operation modes (liquid-liquid or gas-liquid reaction with semi-continuous or continuous operation) were applied. The effects of various experimental conditions, such as solvent/oil mass ratio, sulfonating agent/oil mass ratio, gas/liquid ratio, gas concentration, reaction temperature, rotating speed, circulation ratio, reaction time and aging time, on the content of active matter and unsulfonated oil were investigated. Under relatively optimal reaction conditions, the target product was prepared with high mass content of active matter (up to 45.3%) and extremely low oil/water interfacial tension (4.5×10 –3 mN·m –1 ). The product quality and process efficiency are higher compared with traditional sulfonation technology.展开更多
An innovative idea was proposed to prepare the overbased nano-sized calcium carbonate-calcium petroleum sulfonate in-situ the HIGEE reactor. The test sample prepared by this technology could meet the requirement of th...An innovative idea was proposed to prepare the overbased nano-sized calcium carbonate-calcium petroleum sulfonate in-situ the HIGEE reactor. The test sample prepared by this technology could meet the requirement of the industry standard SH0042-91 for the first-grade product on a par with similar overseas product. The test results obtained upon observation under microscope after freezing etching of specimen revealed that the crystal size of colloidal calcium sulfonate was in the range of 10-30 nm with an average size of 20 nm. The size of the detergent additive was uniform with good transmittance and fluidity. The HIGEE technology possesses five specific features as shown below: Firstly, the carbonation reaction is completed in one step with the reaction time reduced by more than 50% as compared to traditional batch reactor process along with enhanced reaction efficiency, good operability of the process and stabilized product quality. Secondly, ammonia emitted from the reaction is used as the co- promoter without the need for adding ammonia and water as promoters to simplify the promoter system along with effective and strong coupling of reactions. Thirdly, the utilization rate of Ca(OH)2 and CO2 is increased by 15% and 30%, respectively, with product yield increased by 15%, and calcium residue decreased by 65%. Fourthly, the HIGEE technology is environmental benign because of gasoline is used in this technology instead of toxic toluene and xylene. Fifthly, the dimension of HIGEE reactor is reduced by above two-thirds. The success in development of this new technology will offer new ideas and technology platform for the synthesis of metal detergent additive to lubricating oils in China.展开更多
A column-switching anion-exchange chromatography method was described for the separation and determination of petroleum monosulfonates (PMS) and petroleum disulfonates (PDS) in crude oil that was simply diluted with t...A column-switching anion-exchange chromatography method was described for the separation and determination of petroleum monosulfonates (PMS) and petroleum disulfonates (PDS) in crude oil that was simply diluted with the dichloromethane/methanol (60/40). The high performance liquid chromatography (HPLC) system consisted of a clean-up column and an analytical column, which were connected with two six-port switching valves. Detection of petroleum sulfonates was available and repeatable. This method has been successfully applied to determine PMS and PDS in crude oil samples from Shengli oil field.展开更多
Petroleum sulfonate is one of the most important surfactants used in surfactant flooding for enhanced oil recovery, which is mainly obtained by treating high-boiling petroleum fractions in a stirred tank reactor(STR) ...Petroleum sulfonate is one of the most important surfactants used in surfactant flooding for enhanced oil recovery, which is mainly obtained by treating high-boiling petroleum fractions in a stirred tank reactor(STR) or in a fallingfilm reactor(FFR). The synthesis of petroleum sulfonate with ultra-low interfacial tension from viscous petroleum fractions was carried out in a rotating packed bed(RPB) reactor using dilute liquid sulfur trioxide as the sulfonating agent in this study. The effects of various experimental conditions on components content and oil-water interfacial tension(IFT) were investigated. Under the optimum conditions, the active matter content could reach up to 50.3% and the IFT could be equal to 4.7×10-3 m N/m. Compared with the traditional reactor, the active matter content is by 14.12% higher in the RPB as compared to that obtained in the STR. The uneven change of the test oil droplets during the IFT measurement was also discussed. The increase of heavy components content not only can eliminate the contraction phenomenon, but also can reduce the IFT to a minimum. This can be conducive to explaining the reason for producing IFT and the preparation of proper formulations for practical application.展开更多
As the New Year kicks off,it's also time to celebrate the 5ot Anniversary of Petroleum Exploration and Development.In the past 50 years,Petroleum Exploration and Development has been endeavoring to disseminating t...As the New Year kicks off,it's also time to celebrate the 5ot Anniversary of Petroleum Exploration and Development.In the past 50 years,Petroleum Exploration and Development has been endeavoring to disseminating technology,witnessing and recording the glorious history of China's oil industry developing from weak to strong.In the new era,we have been focusing on theoretical innovation and technology advancement in oil and gas exploration and development,taking an edge on the latest development of the industry,continuously improving the quality of our journal,and leading the journal in a way of high quality and with special features.展开更多
The purpose of this study was to identify and compare the degradation efficiencies of free and entrapped bacterial consortia(Staphylococcus capitis CP053957.1 and Achromobacter marplatensis MT078618.1)to different pol...The purpose of this study was to identify and compare the degradation efficiencies of free and entrapped bacterial consortia(Staphylococcus capitis CP053957.1 and Achromobacter marplatensis MT078618.1)to different polymers such as Sodium Alginate(SA),Sodium Alginate/Poly(Vinyl Alcohol)(SA/PVA),and Bushnell Haas Agar(BHA).In addition to SA and SA/PVA,which are cost-effective,non-toxic and have different functional groups,BHA,which is frequently encountered in laboratory-scale studies but has not been used as an entrapment material until now.Based on these,the polymers with different surface morphologies and chemical compositions were analyzed by SEM and FT-IR.While the petroleum removal efficiency was higher with the entrapped bacterial consortia than with the free one,BHA-entrapped bacterial consortium enhanced the petroleum removal more than SA and SA/PVA.Accordingly,the degradation rate of bacterial consortia entrapped with BHA was 2.039 day^(-1),SA/PVA was 1.560,SA was 0.993,the half-life period of BHA-entrapped bacterial consortia is quite low(t_(1/2)=0.339)compared with SA(t_(1/2)=0.444)and SA/PVA(t_(1/2)=0.697).The effects of the four main factors such as:amount of BHA(0.5,1,1.5,2,2.5,3 g),disc size(4,5,6,7,8 mm),inoculum concentration(1,2.5,5,7.5,10 mL),and incubation period on petroleum removal were also investigated.The maximum petroleum removal(94.5%)was obtained at≥2.5 mL of bacterial consortium entrapped in 2 g BHA with a 7 mm disc size at 168 h and the results were also confirmed by statistical analysis.Although a decrease was observed during the reuse of bacterial consortium entrapped in BHA,the petroleum removal was still above 50%at 10th cycle.Based on GC-MS analysis,the removal capacity of BHA-entrapped consortium was over 90%for short-chain n-alkanes and 80%for medium-chain n-alkanes.Overall,the obtained data are expected to provide a potential guideline in cleaning up the large-scale oil pollution in the future.Since there has been no similar study investigating petroleum removal with the bacterial consortia entrapped with BHA,this novel entrapment material can potentially be used in the treatment of petroleum pollution in advanced remediation studies.展开更多
The classical source-to-trap petroleum system concept only considers the migration and accumulation of conventional oil and gas in traps driven dominantly by buoyance in a basin,although revised and improved,even some...The classical source-to-trap petroleum system concept only considers the migration and accumulation of conventional oil and gas in traps driven dominantly by buoyance in a basin,although revised and improved,even some new concepts as composite petroleum system,total petroleum system,total composite petroleum system,were proposed,but they do not account for the vast unconventional oil and gas reservoirs within the system,which is not formed and distributed in traps dominantly by buoyancedriven.Therefore,the petroleum system concept is no longer adequate in dealing with all the oil and gas accumulations in a basin where significant amount of the unconventional oil and gas resources are present in addition to the conventional oil and gas accumulations.This paper looked into and analyzed the distribution characteristics of conventional and unconventional oil/gas reservoirs and their differences and correlations in petroliferous basins in China and North America,and then proposed whole petroleum system(WPS)concept,the WPS is defined as a natural system that encompasses all the conventional and unconventional oil and gas,reservoirs and resources originated from organic matter in source rocks,the geological elements and processes involving the formation,evolution,and distribution of these oil and gas,reservoirs and resources.It is found in the WPS that there are three kinds of hydrocarbons dynamic fields,three kinds of original hydrocarbons,three kinds of reservoir rocks,and the coupling of these three essential elements lead to the basic ordered distribution model of shale oil/gas reservoirs contacting or interbeded with tight oil/gas reservoirs and separated conventional oil/gas reservoirs from source rocks upward,which is expressed as“S\T-C”.Abnormal conditions lead to other three special ordered distribution models:The first is that with shale oil/gas reservoirs separated from tight oil/gas reservoirs.The second is that with two direction ordered distributions from source upward and downward.The third is with lateral distribution from source outside.展开更多
Based on the analysis of Upper Paleozoic source rocks, source-reservoir-caprock assemblage, and gas accumulation characteristics in the Ordos Basin, the gas accumulation geological model of total petroleum system is d...Based on the analysis of Upper Paleozoic source rocks, source-reservoir-caprock assemblage, and gas accumulation characteristics in the Ordos Basin, the gas accumulation geological model of total petroleum system is determined. Then, taking the Carboniferous Benxi Formation and the Permian Taiyuan Formation and Shanxi Formation as examples, the main controlling factors of gas accumulation and enrichment are discussed, and the gas enrichment models of total petroleum system are established. The results show that the source rocks, faults and tight reservoirs and their mutual coupling relations control the distribution and enrichment of gas. Specifically, the distribution and hydrocarbon generation capacity of source rocks control the enrichment degree and distribution range of retained shale gas and tight gas in the source. The coupling between the hydrocarbon generation capacity of source rocks and the physical properties of tight reservoirs controls the distribution and sweet spot development of near-source tight gas in the basin center. The far-source tight gas in the basin margin is mainly controlled by the distribution of faults, and the distribution of inner-source, near-source and far-source gas is adjusted and reformed by faults. Generally, the Upper Paleozoic gas in the Ordos Basin is recognized in four enrichment models: inner-source coalbed gas and shale gas, inner-source tight sandstone gas, near-source tight gas, and far-source fault-transported gas. In the Ordos Basin, inner-source tight gas and near-source tight gas are the current focuses of exploration, and inner-source coalbed gas and shale gas and far-source gas will be important potential targets in the future.展开更多
The development of globally distributed Phanerozoic petroleum source rocks is concentrated on time intervals, which correlate convincingly with climatic driven glaciation epochs of Earth’s history, repeated every 150...The development of globally distributed Phanerozoic petroleum source rocks is concentrated on time intervals, which correlate convincingly with climatic driven glaciation epochs of Earth’s history, repeated every 150 million years, and during sea level high stands and maxima of global magmatism with a period of 300 million years. The 150 million year periodicity appears to be related to the path of the solar system through the spiral arms of the Milky Way and the 300 million year periodicity to changes of the spiral system. The spiral arms are preferred birth places of new stars, of which the larger ones have only smaller lifespans. Their preliminary deaths ended with explosions and selectively with the development of so-called white dwarfs, neutron stars or black holes. The times of the explosions of intermediate (sun-like) stars can be determined by measuring the present brightness of the dwarfs. Not surprisingly the last two maxima of recordable near solar system star explosions took place during the presumably spiral arms driven glacial epochs in Eocene to present and Upper Jurassic times. Such near solar system star explosions may have been the source of intense neutrino showers, cosmic rays and star dust. This dust contained all kinds of chemical elements, including phosphorus and uranium. Such cosmic phosphorus may have supported, through fertilizing, the distribution of life on Earth additionally to local phosphorus resources via bloom of biota in lakes and oceans and the enhanced growth of plants on land across all climatic zones. Subsequently it maintained the development of petroleum source rocks of all organic matter types within black shales and coals. Via the distribution of remnants of exploding stars—mainly white dwarfs, but neutron stars and black holes have to be counted as well—a cosmic contribution can therefore casually linked to the deposition of petroleum source rocks on Earth, not only purely correlatively by their contemporaneous appearances.展开更多
The zinc oxide nano-particles have been used in this research. In this work, zinc oxide nanoparticles have been added to light and heavy crude oil. In this research, thermoelectric and physical properties of light and...The zinc oxide nano-particles have been used in this research. In this work, zinc oxide nanoparticles have been added to light and heavy crude oil. In this research, thermoelectric and physical properties of light and heavy crude petroleum have been measured, experimentally. In addition, dimensionless groups in hydrodynamics and heat transfer calculations are presented. This research illustrates that heat capacity of light and heavy crude petroleum varies from 4256 J/kg·°C to 4457 J/kg·°C and 4476 J/kg·°C to 5002 J/kg·°C, respectively. Moreover, heat capacity of light and heavy nano-crude petroleum is changing from about 4285 J/kg·°C to 4496 J/kg·°C and 4494 J/kg·°C to 5021 J/kg·°C, respectively.展开更多
On the 49th anniversary of the founding of Petroleum Exploration and Development,the 9th Editorial Committee is officially established,with Academician Zhao Wenzhi of the Chinese Academy of Engineering serving as the ...On the 49th anniversary of the founding of Petroleum Exploration and Development,the 9th Editorial Committee is officially established,with Academician Zhao Wenzhi of the Chinese Academy of Engineering serving as the Director and Professor Dou Lirong,President of PetroChina Research Institute of Petroleum Exploration and Development,serving as the Executive Deputy Director.展开更多
On June 28^(th),2023,Clarivate Analytics released the Journal Citation Reports of 2022.The impact factor of Petroleum Exploration and Development has reached 7.5,a 44%increase against 5.194 as of 2021,seting a new his...On June 28^(th),2023,Clarivate Analytics released the Journal Citation Reports of 2022.The impact factor of Petroleum Exploration and Development has reached 7.5,a 44%increase against 5.194 as of 2021,seting a new historical record in world petroleum engineering journals.展开更多
Direct methanol fuel cells(DMFCs) have attracted extensive attention as promising next-generation energy conversion devices. However, commercialized proton exchange membranes(PEMs) hardly fulfill the demand of methano...Direct methanol fuel cells(DMFCs) have attracted extensive attention as promising next-generation energy conversion devices. However, commercialized proton exchange membranes(PEMs) hardly fulfill the demand of methanol tolerance for DMFCs employing high-concentration methanol solutions.Herein, we report a series of semi-crystalline poly(arylene ether ketone) PEMs with ultra-densely sulfonic-acid-functionalized pendants linked by flexible alkyl chains, namely, SL-SPEK-x(where x represents the molar ratio of the novel monomer containing multiple phenyl side chain to the bisfluoride monomers). The delicate structural design rendered SL-SPEK-x membranes with high crystallinity and well-defined nanoscale phase separation between hydrophilic and hydrophobic phases. The reinforcement from poly(ether ketone) crystals enabled membranes with inhibited dimensional variation and methanol penetration. Furthermore, microphase separation significantly enhanced proton conductivity. The SL-SPEK-12.5 membrane achieved the optimum trade-off between proton conductivity(0.182 S cm^(-1), 80 ℃), water swelling(13.6%, 80 ℃), and methanol permeability(1.6 × 10^(-7)cm~2 s^(-1)). The DMFC assembled by the SL-SPEK-12.5 membrane operated smoothly with a 10 M methanol solution, outputting a maximum power density of 158.3 mW cm^(-2), nearly twice that of Nafion 117(94.2 mW cm^(-2)). Overall, the novel structural optimization strategy provides the possibility of PEMs surviving in high-concentration methanol solutions, thus facilitating the miniaturization and portability of DMFC devices.展开更多
The application of high-sulfur petroleum coke after desulfurization in aluminum electrolysis anodes is an important development trend. However, removing sulfur from high-sulfur petroleum coke is still a significant ch...The application of high-sulfur petroleum coke after desulfurization in aluminum electrolysis anodes is an important development trend. However, removing sulfur from high-sulfur petroleum coke is still a significant challenge.This study proposes alkali calcining and reflux washing to examine the impacts of temperature, particle size, the mass ratio of Na_(2)CO_(3) to NaOH, and total sodium addition on the desulfurization efficiency and mechanism. The results show that the desulfurization rate increases with increasing temperature, increasing total sodium content, and decreasing particle size. The addition of alkali can significantly reduce the opening-ring reaction temperature of thiophene and convert organic sulfur into inorganic sulfur(Na_(2)S). Three washing methods were compared, and reflux washing was selected to separate inorganic sulfur(Na_(2)S) from calcined petroleum coke. The sulfur content in petroleum coke decreased from 7.29% to 1.90%, with a desulfurization rate of 80.13% under optimal conditions. The petroleum coke was analyzed before and after desulfurization using X-Ray diffraction(XRD), Scanning Electron Microscopy(SEM), Infrared Spectroscopy(IR), Thermogravimetric Analysis and Differential Scanning Calorimetry(TG-DSC), Gaschromatography-mass Spectrometry(GC-MS). The results show that thiophene and benzothiophene in petroleum coke are decomposed and converted into octane and ethyl cyclohexane. These new observations are expected to provide further understanding and guidance for the utilization of highsulfur petroleum coke.展开更多
Rod milling sand(RMS)—a coarse sand aggregate—was recycled for cemented paste backfill(CPB)for the underground mined area at the Jinchuan nickel deposit,named rod milling sand-based cemented paste backfill(RCPB).The...Rod milling sand(RMS)—a coarse sand aggregate—was recycled for cemented paste backfill(CPB)for the underground mined area at the Jinchuan nickel deposit,named rod milling sand-based cemented paste backfill(RCPB).The adverse effects of coarse particles on the transportation of CPB slurry through pipelines to underground stopes resulting in weakening of the stability of the backfill system are well known.Therefore,sulfonated naphthalene formaldehyde(SNF)condensate was used for the performance improvement of RCPB.The synergistic effect of solid content(SC),lime-to-sand ratio,and SNF dosage on the rheological and physicomechanical properties,including slump,yield stress,bleeding rate,uniaxial compressive strength(UCS),as well as mechanism analysis of RCPB,have been explored.The results indicate that the effect of SNF on RCPB performance is related to the SNF dosage,lime-to-sand ratio,and SC.The slump of fresh RCPB with 0.1wt%-0.5wt%SNF increased by 2.6%-26.2%,whereas the yield stress reduced by 4.1%-50.3%,indicating better workability and improved cohesiveness of the mix.The bleeding rate of fresh RCPB decreased first and then rose with the increase of SNF dosage,and the peak decrease was 67.67%.UCS of RCPB first increased and then decreased with the increase of SNF dosage.At the optimal SNF addition ratio of 0.3wt%,the UCS of RCPB curing for 7,14 and,28 d ages increased by 31.5%,28.4%,and 29.5%,respectively.The beneficial effects of SNF in enhancing the early UCS of RCPB have been corroborated.However,the later UCS increases at a slower rate.The research findings may guide the design and preparation of RCPB with adequate performance for practical applications.展开更多
The remediation of crude oil-impacted soil has always been a challenge in different soil environments and climatic conditions. Bioremediation technology has offered a breakthrough in restoring crude oil-impacted soil/...The remediation of crude oil-impacted soil has always been a challenge in different soil environments and climatic conditions. Bioremediation technology has offered a breakthrough in restoring crude oil-impacted soil/sediment in muddy, dry soil and wetlands. Though, there have been varied environmental conditions that have hampered the success of the bioremediation process. This study has evaluated the effectiveness of a biostimulated bioremediation of crude oil-impacted soil using some design criteria—nutrient amendment (NPK fertilizer) and moisture content. Soil sample sets—A, B, C, D, E, F, and G were impacted with crude oil at a ratio of 10 g/kg and amended with varying amounts of nutrient 30, 60, and 80 g of N.P.K fertilizer. The medium for the inoculation of the nutrient was water and the volume of water applied varied from 30% to 80% saturation. The soil sample sets were harvested at an interval of 3 months for 180 days to determine the concentration of total petroleum hydrocarbon left in the soil. The analysis of the total petroleum hydrocarbon was achieved using a GC-FID with a capillary column and autosampler. Soil samples were extracted with mixed solvent dichloromethane and acetone at a 1:1 ratio. The total petroleum hydrocarbon results show that biostimulated bioremediation achieved better results in soil sample sets with low moisture content (30% water saturation) and moderate nutrient amendment. The biodegradation of the sample sets with high water saturation and a high nutrient amendment was slow with a higher amount of total hydrocarbon content at the end of the 180 days. The variability in the hydrocarbon degradation pattern of contaminated soil shows that biostimulated bioremediation achieved better results in soils with low moisture content than in soil environments with high water content (saturation). More so, nutrient overdosing of the substrate hampered the effectiveness of the remediation process.展开更多
The process of transporting crude oil across pipelines is one of the most critical aspects of the midstream petroleum industry.In the present experimental work,the effect of temperature,pressure drop,and pipe diameter...The process of transporting crude oil across pipelines is one of the most critical aspects of the midstream petroleum industry.In the present experimental work,the effect of temperature,pressure drop,and pipe diameter on the flow rate of heavy crude oil have been assessed.Moreover,the total discharge and energy losses have been evaluated in order to demonstrate the improvements potentially achievable by using solar heating method replacing pipe,and adjusting the value of the initial pressure difference.Crude oil of API=20 has been used for the experiments,with the studied pipelines sections connecting the separator unit to the storage tank operating at a temperature of 25℃-100℃,pressure drop of 3,4,5,and 6 kg/cm^(2),and with pipe diameter of 4,6,and 8 in.The results show that on increasing the temperature and/or the pressure drop,the flow rate through the pipeline becomes higher,thus raising the total pumping energy(as the pipe diameter increase),while energy losses increase from the last separator to the storage tank in the field.A pipe diameter increase can also produce a growth of the total pumping energy(i.e.,energy losses increase).The results of the present analysis suggest that employing an optimal temperature(50℃)is needed to ensure good performance.展开更多
A cross-sectional exploratory assessment of the needs and challenges of petroleum industry in Nigeria, in assessing process safety cumulative risk for major accidents prevention was investigated. A purposive cum rando...A cross-sectional exploratory assessment of the needs and challenges of petroleum industry in Nigeria, in assessing process safety cumulative risk for major accidents prevention was investigated. A purposive cum random sampling technique was used in this study, among selected petroleum companies operating in Nigeria. Survey questionnaires were received from 216 participants made up of asset integrity engineers/operators, process safety experts, production safety professionals in the petroleum industry in Nigeria. Data analyses were carried out to cover descriptive and inferential statistics. Overall, the study recognized that assessing process safety cumulative risk is not a simple process due largely to the changing nature of safety critical barriers degradation data. The study result showed four main challenges faced by petroleum industries in Nigeria, in assessing process safety cumulative risk: 1) the study showed that 94% of the respondents agreed that there is limited accessibility to safety critical barriers degradation data (little automation). Also 2) 94% of the respondents accounted for poor knowledge of process safety cumulative risk is and agreed it to be of low rating. The result further showed that 3) 90% of the respondents demonstrated that there are no guidance and procedures in assessing process safety cumulative risk and finally 4) 92% of the respondents reported that there is no real-time risk visualization model/ tool. Addressing these issues and challenges by the petroleum industries in the study area, will lead to successful assessment of process safety cumulative risk, thereby reducing the risk of major accidents.展开更多
The petroleum industry has a complex,inflexible and challenging supply chain(SC)that impacts both the national economy as well as people’s daily lives with a range of services,including transportation,heating,electri...The petroleum industry has a complex,inflexible and challenging supply chain(SC)that impacts both the national economy as well as people’s daily lives with a range of services,including transportation,heating,electricity,lubricants,as well as chemicals and petrochemicals.In the petroleum industry,supply chain management presents several challenges,especially in the logistics sector,that are not found in other industries.In addition,logistical challenges contribute significantly to the cost of oil.Uncertainty regarding customer demand and supply significantly affects SC networks.Hence,SC flexibility can be maintained by addressing uncertainty.On the other hand,in the real world,decision-making challenges are often ambiguous or vague.In some cases,measurements are incorrect owing to measurement errors,instrument faults,etc.,which lead to a pentagonal fuzzy number(PFN)which is the extension of a fuzzy number.Therefore,it is necessary to develop quantitative models to optimize logistics operations and supply chain networks.This study proposed a linear programming model under an uncertain environment.The model minimizes the cost along the refineries,depots,multimode transport and demand nodes.Further developed pentagonal fuzzy optimization,an alternative approach is developed to solve the downstream supply chain using themixed-integer linear programming(MILP)model to obtain a feasible solution to the fuzzy transportation cost problem.In this model,the coefficient of the transportation costs and parameters is assumed to be a pentagonal fuzzy number.Furthermore,defuzzification is performed using an accuracy function.To validate the model and technique and feasibility solution,an illustrative example of the oil and gas SC is considered,providing improved results compared with existing techniques and demonstrating its ability to benefit petroleum companies is the objective of this study.展开更多
Recently, significant oil discoveries have been made in the shallower pay zones of the Jurassic Badaowan Formation (J_(1)b) in the Mahu Sag, Junggar Basin, Northwest China. However, little work has been done on the ge...Recently, significant oil discoveries have been made in the shallower pay zones of the Jurassic Badaowan Formation (J_(1)b) in the Mahu Sag, Junggar Basin, Northwest China. However, little work has been done on the geochemical characteristics and origins of the oil in the J_(1)b reservoir. This study analyzes 44 oil and 14 source rock samples from the area in order to reveal their organic geochemical characteristics and the origins of the oils. The J_(1)b oils are characterized by a low Pr/Ph ratio and high β-carotene and gammacerane indices, which indicate that they were mainly generated from source rocks deposited in a hypersaline environment. The oils are also extremely enhanced in C_(29) regular steranes, possibly derived from halophilic algae. Oil-source correlation shows that the oils were derived from the Lower Permian Fengcheng Formation (P_(1)f) source rocks, which were deposited in a strongly stratified and highly saline water column with a predominance of algal/bacterial input in the organic matter. The source rocks of the Middle Permian lower-Wuerhe Formation (P_(2)w), which were deposited in fresh to slightly saline water conditions with a greater input of terrigenous organic matter, make only a minor contribution to the J_(1)b oils. The reconstruction of the oil accumulation process shows that the J_(1)b oil reservoir may have been twice charged during Late Jurassic–Early Cretaceous and the Paleogene–Neogene, respectively. A large amount volume of hydrocarbons generated in the P_(1)f source rock and leaked from T_(1)b oil reservoirs migrated along faults connecting source beds and shallow-buried secondary faults into Jurassic traps, resulting in large-scale accumulations in J_(1)b. These results are crucial for understanding the petroleum system of the Mahu Sag and will provide valuable guidance for petroleum exploration in the shallower formations in the slope area of the sag.展开更多
基金Supported by the National Natural Science Foundation of China （20821004 20990221） the National High Technology Research and Development Program of China （2006AA030202）
文摘With the application of HIGEE process intensification technology, petroleum sulfonate surfactant used for enhanced oil recovery was synthesized from petroleum fraction of Shengli crude oil with three sulfonating agents, including diluted liquid sulfur trioxide, diluted gaseous sulfur trioxide and fuming sulfuric acid. For each sulfonating agent, different operation modes (liquid-liquid or gas-liquid reaction with semi-continuous or continuous operation) were applied. The effects of various experimental conditions, such as solvent/oil mass ratio, sulfonating agent/oil mass ratio, gas/liquid ratio, gas concentration, reaction temperature, rotating speed, circulation ratio, reaction time and aging time, on the content of active matter and unsulfonated oil were investigated. Under relatively optimal reaction conditions, the target product was prepared with high mass content of active matter (up to 45.3%) and extremely low oil/water interfacial tension (4.5×10 –3 mN·m –1 ). The product quality and process efficiency are higher compared with traditional sulfonation technology.
文摘An innovative idea was proposed to prepare the overbased nano-sized calcium carbonate-calcium petroleum sulfonate in-situ the HIGEE reactor. The test sample prepared by this technology could meet the requirement of the industry standard SH0042-91 for the first-grade product on a par with similar overseas product. The test results obtained upon observation under microscope after freezing etching of specimen revealed that the crystal size of colloidal calcium sulfonate was in the range of 10-30 nm with an average size of 20 nm. The size of the detergent additive was uniform with good transmittance and fluidity. The HIGEE technology possesses five specific features as shown below: Firstly, the carbonation reaction is completed in one step with the reaction time reduced by more than 50% as compared to traditional batch reactor process along with enhanced reaction efficiency, good operability of the process and stabilized product quality. Secondly, ammonia emitted from the reaction is used as the co- promoter without the need for adding ammonia and water as promoters to simplify the promoter system along with effective and strong coupling of reactions. Thirdly, the utilization rate of Ca(OH)2 and CO2 is increased by 15% and 30%, respectively, with product yield increased by 15%, and calcium residue decreased by 65%. Fourthly, the HIGEE technology is environmental benign because of gasoline is used in this technology instead of toxic toluene and xylene. Fifthly, the dimension of HIGEE reactor is reduced by above two-thirds. The success in development of this new technology will offer new ideas and technology platform for the synthesis of metal detergent additive to lubricating oils in China.
基金the National Nature Science Foundation of China(No.20675085)the support from the Program of the Light in China's Western Region(2003)the Province Nature Science Foundation of Gansu(No.3ZS041-A25-23).
文摘A column-switching anion-exchange chromatography method was described for the separation and determination of petroleum monosulfonates (PMS) and petroleum disulfonates (PDS) in crude oil that was simply diluted with the dichloromethane/methanol (60/40). The high performance liquid chromatography (HPLC) system consisted of a clean-up column and an analytical column, which were connected with two six-port switching valves. Detection of petroleum sulfonates was available and repeatable. This method has been successfully applied to determine PMS and PDS in crude oil samples from Shengli oil field.
基金supported by Project of the National Twelfth Five-Year Research Program of China (Grants. 2014BAE03B02)
文摘Petroleum sulfonate is one of the most important surfactants used in surfactant flooding for enhanced oil recovery, which is mainly obtained by treating high-boiling petroleum fractions in a stirred tank reactor(STR) or in a fallingfilm reactor(FFR). The synthesis of petroleum sulfonate with ultra-low interfacial tension from viscous petroleum fractions was carried out in a rotating packed bed(RPB) reactor using dilute liquid sulfur trioxide as the sulfonating agent in this study. The effects of various experimental conditions on components content and oil-water interfacial tension(IFT) were investigated. Under the optimum conditions, the active matter content could reach up to 50.3% and the IFT could be equal to 4.7×10-3 m N/m. Compared with the traditional reactor, the active matter content is by 14.12% higher in the RPB as compared to that obtained in the STR. The uneven change of the test oil droplets during the IFT measurement was also discussed. The increase of heavy components content not only can eliminate the contraction phenomenon, but also can reduce the IFT to a minimum. This can be conducive to explaining the reason for producing IFT and the preparation of proper formulations for practical application.
文摘As the New Year kicks off,it's also time to celebrate the 5ot Anniversary of Petroleum Exploration and Development.In the past 50 years,Petroleum Exploration and Development has been endeavoring to disseminating technology,witnessing and recording the glorious history of China's oil industry developing from weak to strong.In the new era,we have been focusing on theoretical innovation and technology advancement in oil and gas exploration and development,taking an edge on the latest development of the industry,continuously improving the quality of our journal,and leading the journal in a way of high quality and with special features.
文摘The purpose of this study was to identify and compare the degradation efficiencies of free and entrapped bacterial consortia(Staphylococcus capitis CP053957.1 and Achromobacter marplatensis MT078618.1)to different polymers such as Sodium Alginate(SA),Sodium Alginate/Poly(Vinyl Alcohol)(SA/PVA),and Bushnell Haas Agar(BHA).In addition to SA and SA/PVA,which are cost-effective,non-toxic and have different functional groups,BHA,which is frequently encountered in laboratory-scale studies but has not been used as an entrapment material until now.Based on these,the polymers with different surface morphologies and chemical compositions were analyzed by SEM and FT-IR.While the petroleum removal efficiency was higher with the entrapped bacterial consortia than with the free one,BHA-entrapped bacterial consortium enhanced the petroleum removal more than SA and SA/PVA.Accordingly,the degradation rate of bacterial consortia entrapped with BHA was 2.039 day^(-1),SA/PVA was 1.560,SA was 0.993,the half-life period of BHA-entrapped bacterial consortia is quite low(t_(1/2)=0.339)compared with SA(t_(1/2)=0.444)and SA/PVA(t_(1/2)=0.697).The effects of the four main factors such as:amount of BHA(0.5,1,1.5,2,2.5,3 g),disc size(4,5,6,7,8 mm),inoculum concentration(1,2.5,5,7.5,10 mL),and incubation period on petroleum removal were also investigated.The maximum petroleum removal(94.5%)was obtained at≥2.5 mL of bacterial consortium entrapped in 2 g BHA with a 7 mm disc size at 168 h and the results were also confirmed by statistical analysis.Although a decrease was observed during the reuse of bacterial consortium entrapped in BHA,the petroleum removal was still above 50%at 10th cycle.Based on GC-MS analysis,the removal capacity of BHA-entrapped consortium was over 90%for short-chain n-alkanes and 80%for medium-chain n-alkanes.Overall,the obtained data are expected to provide a potential guideline in cleaning up the large-scale oil pollution in the future.Since there has been no similar study investigating petroleum removal with the bacterial consortia entrapped with BHA,this novel entrapment material can potentially be used in the treatment of petroleum pollution in advanced remediation studies.
基金This work was supported by the major science and technology projects of CNPC during the“14th five-year plan”(Grant number 2021DJ0101)。
文摘The classical source-to-trap petroleum system concept only considers the migration and accumulation of conventional oil and gas in traps driven dominantly by buoyance in a basin,although revised and improved,even some new concepts as composite petroleum system,total petroleum system,total composite petroleum system,were proposed,but they do not account for the vast unconventional oil and gas reservoirs within the system,which is not formed and distributed in traps dominantly by buoyancedriven.Therefore,the petroleum system concept is no longer adequate in dealing with all the oil and gas accumulations in a basin where significant amount of the unconventional oil and gas resources are present in addition to the conventional oil and gas accumulations.This paper looked into and analyzed the distribution characteristics of conventional and unconventional oil/gas reservoirs and their differences and correlations in petroliferous basins in China and North America,and then proposed whole petroleum system(WPS)concept,the WPS is defined as a natural system that encompasses all the conventional and unconventional oil and gas,reservoirs and resources originated from organic matter in source rocks,the geological elements and processes involving the formation,evolution,and distribution of these oil and gas,reservoirs and resources.It is found in the WPS that there are three kinds of hydrocarbons dynamic fields,three kinds of original hydrocarbons,three kinds of reservoir rocks,and the coupling of these three essential elements lead to the basic ordered distribution model of shale oil/gas reservoirs contacting or interbeded with tight oil/gas reservoirs and separated conventional oil/gas reservoirs from source rocks upward,which is expressed as“S\T-C”.Abnormal conditions lead to other three special ordered distribution models:The first is that with shale oil/gas reservoirs separated from tight oil/gas reservoirs.The second is that with two direction ordered distributions from source upward and downward.The third is with lateral distribution from source outside.
基金Supported by the National Natural Science Foundation of China (41872128)the CNPC Major Science and Technology Project (2021DJ0101)。
文摘Based on the analysis of Upper Paleozoic source rocks, source-reservoir-caprock assemblage, and gas accumulation characteristics in the Ordos Basin, the gas accumulation geological model of total petroleum system is determined. Then, taking the Carboniferous Benxi Formation and the Permian Taiyuan Formation and Shanxi Formation as examples, the main controlling factors of gas accumulation and enrichment are discussed, and the gas enrichment models of total petroleum system are established. The results show that the source rocks, faults and tight reservoirs and their mutual coupling relations control the distribution and enrichment of gas. Specifically, the distribution and hydrocarbon generation capacity of source rocks control the enrichment degree and distribution range of retained shale gas and tight gas in the source. The coupling between the hydrocarbon generation capacity of source rocks and the physical properties of tight reservoirs controls the distribution and sweet spot development of near-source tight gas in the basin center. The far-source tight gas in the basin margin is mainly controlled by the distribution of faults, and the distribution of inner-source, near-source and far-source gas is adjusted and reformed by faults. Generally, the Upper Paleozoic gas in the Ordos Basin is recognized in four enrichment models: inner-source coalbed gas and shale gas, inner-source tight sandstone gas, near-source tight gas, and far-source fault-transported gas. In the Ordos Basin, inner-source tight gas and near-source tight gas are the current focuses of exploration, and inner-source coalbed gas and shale gas and far-source gas will be important potential targets in the future.
文摘The development of globally distributed Phanerozoic petroleum source rocks is concentrated on time intervals, which correlate convincingly with climatic driven glaciation epochs of Earth’s history, repeated every 150 million years, and during sea level high stands and maxima of global magmatism with a period of 300 million years. The 150 million year periodicity appears to be related to the path of the solar system through the spiral arms of the Milky Way and the 300 million year periodicity to changes of the spiral system. The spiral arms are preferred birth places of new stars, of which the larger ones have only smaller lifespans. Their preliminary deaths ended with explosions and selectively with the development of so-called white dwarfs, neutron stars or black holes. The times of the explosions of intermediate (sun-like) stars can be determined by measuring the present brightness of the dwarfs. Not surprisingly the last two maxima of recordable near solar system star explosions took place during the presumably spiral arms driven glacial epochs in Eocene to present and Upper Jurassic times. Such near solar system star explosions may have been the source of intense neutrino showers, cosmic rays and star dust. This dust contained all kinds of chemical elements, including phosphorus and uranium. Such cosmic phosphorus may have supported, through fertilizing, the distribution of life on Earth additionally to local phosphorus resources via bloom of biota in lakes and oceans and the enhanced growth of plants on land across all climatic zones. Subsequently it maintained the development of petroleum source rocks of all organic matter types within black shales and coals. Via the distribution of remnants of exploding stars—mainly white dwarfs, but neutron stars and black holes have to be counted as well—a cosmic contribution can therefore casually linked to the deposition of petroleum source rocks on Earth, not only purely correlatively by their contemporaneous appearances.
文摘The zinc oxide nano-particles have been used in this research. In this work, zinc oxide nanoparticles have been added to light and heavy crude oil. In this research, thermoelectric and physical properties of light and heavy crude petroleum have been measured, experimentally. In addition, dimensionless groups in hydrodynamics and heat transfer calculations are presented. This research illustrates that heat capacity of light and heavy crude petroleum varies from 4256 J/kg·°C to 4457 J/kg·°C and 4476 J/kg·°C to 5002 J/kg·°C, respectively. Moreover, heat capacity of light and heavy nano-crude petroleum is changing from about 4285 J/kg·°C to 4496 J/kg·°C and 4494 J/kg·°C to 5021 J/kg·°C, respectively.
文摘On the 49th anniversary of the founding of Petroleum Exploration and Development,the 9th Editorial Committee is officially established,with Academician Zhao Wenzhi of the Chinese Academy of Engineering serving as the Director and Professor Dou Lirong,President of PetroChina Research Institute of Petroleum Exploration and Development,serving as the Executive Deputy Director.
文摘On June 28^(th),2023,Clarivate Analytics released the Journal Citation Reports of 2022.The impact factor of Petroleum Exploration and Development has reached 7.5,a 44%increase against 5.194 as of 2021,seting a new historical record in world petroleum engineering journals.
基金supported by the program of Jilin Provincial Department of Science and Technology (YDZJ202301ZYTS320)。
文摘Direct methanol fuel cells(DMFCs) have attracted extensive attention as promising next-generation energy conversion devices. However, commercialized proton exchange membranes(PEMs) hardly fulfill the demand of methanol tolerance for DMFCs employing high-concentration methanol solutions.Herein, we report a series of semi-crystalline poly(arylene ether ketone) PEMs with ultra-densely sulfonic-acid-functionalized pendants linked by flexible alkyl chains, namely, SL-SPEK-x(where x represents the molar ratio of the novel monomer containing multiple phenyl side chain to the bisfluoride monomers). The delicate structural design rendered SL-SPEK-x membranes with high crystallinity and well-defined nanoscale phase separation between hydrophilic and hydrophobic phases. The reinforcement from poly(ether ketone) crystals enabled membranes with inhibited dimensional variation and methanol penetration. Furthermore, microphase separation significantly enhanced proton conductivity. The SL-SPEK-12.5 membrane achieved the optimum trade-off between proton conductivity(0.182 S cm^(-1), 80 ℃), water swelling(13.6%, 80 ℃), and methanol permeability(1.6 × 10^(-7)cm~2 s^(-1)). The DMFC assembled by the SL-SPEK-12.5 membrane operated smoothly with a 10 M methanol solution, outputting a maximum power density of 158.3 mW cm^(-2), nearly twice that of Nafion 117(94.2 mW cm^(-2)). Overall, the novel structural optimization strategy provides the possibility of PEMs surviving in high-concentration methanol solutions, thus facilitating the miniaturization and portability of DMFC devices.
基金financially supported by the National Natural Science Foundation of China (Grant Nos. 51964031 and 52164039)。
文摘The application of high-sulfur petroleum coke after desulfurization in aluminum electrolysis anodes is an important development trend. However, removing sulfur from high-sulfur petroleum coke is still a significant challenge.This study proposes alkali calcining and reflux washing to examine the impacts of temperature, particle size, the mass ratio of Na_(2)CO_(3) to NaOH, and total sodium addition on the desulfurization efficiency and mechanism. The results show that the desulfurization rate increases with increasing temperature, increasing total sodium content, and decreasing particle size. The addition of alkali can significantly reduce the opening-ring reaction temperature of thiophene and convert organic sulfur into inorganic sulfur(Na_(2)S). Three washing methods were compared, and reflux washing was selected to separate inorganic sulfur(Na_(2)S) from calcined petroleum coke. The sulfur content in petroleum coke decreased from 7.29% to 1.90%, with a desulfurization rate of 80.13% under optimal conditions. The petroleum coke was analyzed before and after desulfurization using X-Ray diffraction(XRD), Scanning Electron Microscopy(SEM), Infrared Spectroscopy(IR), Thermogravimetric Analysis and Differential Scanning Calorimetry(TG-DSC), Gaschromatography-mass Spectrometry(GC-MS). The results show that thiophene and benzothiophene in petroleum coke are decomposed and converted into octane and ethyl cyclohexane. These new observations are expected to provide further understanding and guidance for the utilization of highsulfur petroleum coke.
基金financially supported by the National Natural Science Foundation of China(Nos.52104156,52074351,52004330)the Science and Technology Innovation Program of Hunan Province,China(No.2021RC3125)the Natural Science Foundation of Hunan Province,China(No.2022JJ30714)。
文摘Rod milling sand(RMS)—a coarse sand aggregate—was recycled for cemented paste backfill(CPB)for the underground mined area at the Jinchuan nickel deposit,named rod milling sand-based cemented paste backfill(RCPB).The adverse effects of coarse particles on the transportation of CPB slurry through pipelines to underground stopes resulting in weakening of the stability of the backfill system are well known.Therefore,sulfonated naphthalene formaldehyde(SNF)condensate was used for the performance improvement of RCPB.The synergistic effect of solid content(SC),lime-to-sand ratio,and SNF dosage on the rheological and physicomechanical properties,including slump,yield stress,bleeding rate,uniaxial compressive strength(UCS),as well as mechanism analysis of RCPB,have been explored.The results indicate that the effect of SNF on RCPB performance is related to the SNF dosage,lime-to-sand ratio,and SC.The slump of fresh RCPB with 0.1wt%-0.5wt%SNF increased by 2.6%-26.2%,whereas the yield stress reduced by 4.1%-50.3%,indicating better workability and improved cohesiveness of the mix.The bleeding rate of fresh RCPB decreased first and then rose with the increase of SNF dosage,and the peak decrease was 67.67%.UCS of RCPB first increased and then decreased with the increase of SNF dosage.At the optimal SNF addition ratio of 0.3wt%,the UCS of RCPB curing for 7,14 and,28 d ages increased by 31.5%,28.4%,and 29.5%,respectively.The beneficial effects of SNF in enhancing the early UCS of RCPB have been corroborated.However,the later UCS increases at a slower rate.The research findings may guide the design and preparation of RCPB with adequate performance for practical applications.
文摘The remediation of crude oil-impacted soil has always been a challenge in different soil environments and climatic conditions. Bioremediation technology has offered a breakthrough in restoring crude oil-impacted soil/sediment in muddy, dry soil and wetlands. Though, there have been varied environmental conditions that have hampered the success of the bioremediation process. This study has evaluated the effectiveness of a biostimulated bioremediation of crude oil-impacted soil using some design criteria—nutrient amendment (NPK fertilizer) and moisture content. Soil sample sets—A, B, C, D, E, F, and G were impacted with crude oil at a ratio of 10 g/kg and amended with varying amounts of nutrient 30, 60, and 80 g of N.P.K fertilizer. The medium for the inoculation of the nutrient was water and the volume of water applied varied from 30% to 80% saturation. The soil sample sets were harvested at an interval of 3 months for 180 days to determine the concentration of total petroleum hydrocarbon left in the soil. The analysis of the total petroleum hydrocarbon was achieved using a GC-FID with a capillary column and autosampler. Soil samples were extracted with mixed solvent dichloromethane and acetone at a 1:1 ratio. The total petroleum hydrocarbon results show that biostimulated bioremediation achieved better results in soil sample sets with low moisture content (30% water saturation) and moderate nutrient amendment. The biodegradation of the sample sets with high water saturation and a high nutrient amendment was slow with a higher amount of total hydrocarbon content at the end of the 180 days. The variability in the hydrocarbon degradation pattern of contaminated soil shows that biostimulated bioremediation achieved better results in soils with low moisture content than in soil environments with high water content (saturation). More so, nutrient overdosing of the substrate hampered the effectiveness of the remediation process.
文摘The process of transporting crude oil across pipelines is one of the most critical aspects of the midstream petroleum industry.In the present experimental work,the effect of temperature,pressure drop,and pipe diameter on the flow rate of heavy crude oil have been assessed.Moreover,the total discharge and energy losses have been evaluated in order to demonstrate the improvements potentially achievable by using solar heating method replacing pipe,and adjusting the value of the initial pressure difference.Crude oil of API=20 has been used for the experiments,with the studied pipelines sections connecting the separator unit to the storage tank operating at a temperature of 25℃-100℃,pressure drop of 3,4,5,and 6 kg/cm^(2),and with pipe diameter of 4,6,and 8 in.The results show that on increasing the temperature and/or the pressure drop,the flow rate through the pipeline becomes higher,thus raising the total pumping energy(as the pipe diameter increase),while energy losses increase from the last separator to the storage tank in the field.A pipe diameter increase can also produce a growth of the total pumping energy(i.e.,energy losses increase).The results of the present analysis suggest that employing an optimal temperature(50℃)is needed to ensure good performance.
文摘A cross-sectional exploratory assessment of the needs and challenges of petroleum industry in Nigeria, in assessing process safety cumulative risk for major accidents prevention was investigated. A purposive cum random sampling technique was used in this study, among selected petroleum companies operating in Nigeria. Survey questionnaires were received from 216 participants made up of asset integrity engineers/operators, process safety experts, production safety professionals in the petroleum industry in Nigeria. Data analyses were carried out to cover descriptive and inferential statistics. Overall, the study recognized that assessing process safety cumulative risk is not a simple process due largely to the changing nature of safety critical barriers degradation data. The study result showed four main challenges faced by petroleum industries in Nigeria, in assessing process safety cumulative risk: 1) the study showed that 94% of the respondents agreed that there is limited accessibility to safety critical barriers degradation data (little automation). Also 2) 94% of the respondents accounted for poor knowledge of process safety cumulative risk is and agreed it to be of low rating. The result further showed that 3) 90% of the respondents demonstrated that there are no guidance and procedures in assessing process safety cumulative risk and finally 4) 92% of the respondents reported that there is no real-time risk visualization model/ tool. Addressing these issues and challenges by the petroleum industries in the study area, will lead to successful assessment of process safety cumulative risk, thereby reducing the risk of major accidents.
文摘The petroleum industry has a complex,inflexible and challenging supply chain(SC)that impacts both the national economy as well as people’s daily lives with a range of services,including transportation,heating,electricity,lubricants,as well as chemicals and petrochemicals.In the petroleum industry,supply chain management presents several challenges,especially in the logistics sector,that are not found in other industries.In addition,logistical challenges contribute significantly to the cost of oil.Uncertainty regarding customer demand and supply significantly affects SC networks.Hence,SC flexibility can be maintained by addressing uncertainty.On the other hand,in the real world,decision-making challenges are often ambiguous or vague.In some cases,measurements are incorrect owing to measurement errors,instrument faults,etc.,which lead to a pentagonal fuzzy number(PFN)which is the extension of a fuzzy number.Therefore,it is necessary to develop quantitative models to optimize logistics operations and supply chain networks.This study proposed a linear programming model under an uncertain environment.The model minimizes the cost along the refineries,depots,multimode transport and demand nodes.Further developed pentagonal fuzzy optimization,an alternative approach is developed to solve the downstream supply chain using themixed-integer linear programming(MILP)model to obtain a feasible solution to the fuzzy transportation cost problem.In this model,the coefficient of the transportation costs and parameters is assumed to be a pentagonal fuzzy number.Furthermore,defuzzification is performed using an accuracy function.To validate the model and technique and feasibility solution,an illustrative example of the oil and gas SC is considered,providing improved results compared with existing techniques and demonstrating its ability to benefit petroleum companies is the objective of this study.
基金supported by the National Natural Science Foundation of China(No.41802179)Sichuan Science and Technology Program(No.2019YFH0037)the Foundation of the State Key Laboratory of Petroleum Resources and Prospecting,China University of Petroleum,Beijing(No.PRP/open-1906).
文摘Recently, significant oil discoveries have been made in the shallower pay zones of the Jurassic Badaowan Formation (J_(1)b) in the Mahu Sag, Junggar Basin, Northwest China. However, little work has been done on the geochemical characteristics and origins of the oil in the J_(1)b reservoir. This study analyzes 44 oil and 14 source rock samples from the area in order to reveal their organic geochemical characteristics and the origins of the oils. The J_(1)b oils are characterized by a low Pr/Ph ratio and high β-carotene and gammacerane indices, which indicate that they were mainly generated from source rocks deposited in a hypersaline environment. The oils are also extremely enhanced in C_(29) regular steranes, possibly derived from halophilic algae. Oil-source correlation shows that the oils were derived from the Lower Permian Fengcheng Formation (P_(1)f) source rocks, which were deposited in a strongly stratified and highly saline water column with a predominance of algal/bacterial input in the organic matter. The source rocks of the Middle Permian lower-Wuerhe Formation (P_(2)w), which were deposited in fresh to slightly saline water conditions with a greater input of terrigenous organic matter, make only a minor contribution to the J_(1)b oils. The reconstruction of the oil accumulation process shows that the J_(1)b oil reservoir may have been twice charged during Late Jurassic–Early Cretaceous and the Paleogene–Neogene, respectively. A large amount volume of hydrocarbons generated in the P_(1)f source rock and leaked from T_(1)b oil reservoirs migrated along faults connecting source beds and shallow-buried secondary faults into Jurassic traps, resulting in large-scale accumulations in J_(1)b. These results are crucial for understanding the petroleum system of the Mahu Sag and will provide valuable guidance for petroleum exploration in the shallower formations in the slope area of the sag.
