Monitoring minuscule mechanical signals,both in magnitude and direction,is imperative in many application scenarios,e.g.,structural health monitoring and robotic sensing systems.However,the piezoelectric sensor strugg...Monitoring minuscule mechanical signals,both in magnitude and direction,is imperative in many application scenarios,e.g.,structural health monitoring and robotic sensing systems.However,the piezoelectric sensor struggles to satisfy the requirements for directional recognition due to the limited piezoelectric coefficient matrix,and achieving sensitivity for detecting micrometer-scale deformations is also challenging.Herein,we develop a vector sensor composed of lead zirconate titanate-electronic grade glass fiber composite filaments with oriented arrangement,capable of detecting minute anisotropic deformations.The as-prepared vector sensor can identify the deformation directions even when subjected to an unprecedented nominal strain of 0.06%,thereby enabling its utility in accurately discerning the 5μm-height wrinkles in thin films and in monitoring human pulse waves.The ultra-high sensitivity is attributed to the formation of porous ferroelectret and the efficient load transfer efficiency of continuous lead zirconate titanate phase.Additionally,when integrated with machine learning techniques,the sensor’s capability to recognize multi-signals enables it to differentiate between 10 types of fine textures with 100%accuracy.The structural design in piezoelectric devices enables a more comprehensive perception of mechanical stimuli,offering a novel perspective for enhancing recognition accuracy.展开更多
Piezoelectric and triboelectric effects are of growing interest for facilitating high-sensitivity and self-powered tactile sensor applications.The working principles of piezoelectric and triboelectric nanogenerators p...Piezoelectric and triboelectric effects are of growing interest for facilitating high-sensitivity and self-powered tactile sensor applications.The working principles of piezoelectric and triboelectric nanogenerators provide strategies for enhancing output voltage signals to achieve high sensitivity.Increasing the piezoelectric constant and surface triboelectric charge density are key factors in this enhancement.Methods such as annealing processes,doping techniques,grain orientation controls,crystallinity controls,and composite structures can effectively enhance the piezoelectric constant.For increasing triboelectric output,surface plasma treatment,charge injection,microstructuring,control of dielectric constant,and structural modification are effective methods.The fabrication methods present significant opportunities in tactile sensor applications.This review article summarizes the overall piezoelectric and triboelectric fabrication processes from materials to device aspects.It highlights applications in pressure,touch,bending,texture,distance,and material recognition sensors.The conclusion section addresses challenges and research opportunities,such as limited flexibility,stretchability,decoupling from multi-stimuli,multifunctional sensors,and data processing.展开更多
Zinc oxide(ZnO),as a broadband gap semiconductor material,exhibits unique physical and chemical properties that make it highly suitable for optoelectronics,piezoelectric devices,and gas-sensitive sensors,showing signi...Zinc oxide(ZnO),as a broadband gap semiconductor material,exhibits unique physical and chemical properties that make it highly suitable for optoelectronics,piezoelectric devices,and gas-sensitive sensors,showing significant potential for various applications.This paper focuses on the regulation and application of ZnO-based p-n junctions and piezoelectric devices.It discusses in detail the preparation of ZnO materials,the construction of p-n junctions,the optimization of piezoelectric device performance,and its application in various fields.By employing different preparation methods and strategies,high-quality ZnO thin films can be grown,and effective control of p-type conductivity achieved.This study provides both a theoretical foundation and technical support for controlling the performance of ZnO-based piezoelectric devices,as well as paving new pathways for the broader application of ZnO materials.展开更多
Benefiting from the widespread potential applications in the era of the Internet of Thing and metaverse,triboelectric and piezoelectric nanogenerators(TENG&PENG)have attracted considerably increasing attention.The...Benefiting from the widespread potential applications in the era of the Internet of Thing and metaverse,triboelectric and piezoelectric nanogenerators(TENG&PENG)have attracted considerably increasing attention.Their outstanding characteristics,such as self-powered ability,high output performance,integration compatibility,cost-effectiveness,simple configurations,and versatile operation modes,could effectively expand the lifetime of vastly distributed wearable,implantable,and environmental devices,eventually achieving self-sustainable,maintenance-free,and reliable systems.However,current triboelectric/piezoelectric based active(i.e.self-powered)sensors still encounter serious bottlenecks in continuous monitoring and multimodal applications due to their intrinsic limitations of monomodal kinetic response and discontinuous transient output.This work systematically summarizes and evaluates the recent research endeavors to address the above challenges,with detailed discussions on the challenge origins,designing strategies,device performance,and corresponding diverse applications.Finally,conclusions and outlook regarding the research gap in self-powered continuous multimodal monitoring systems are provided,proposing the necessity of future research development in this field.展开更多
The research,fabrication and development of piezoelectric nanofibrous materials offer effective solutions to the challenges related to energy consumption and non-renewable resources.However,enhancing their electrical ...The research,fabrication and development of piezoelectric nanofibrous materials offer effective solutions to the challenges related to energy consumption and non-renewable resources.However,enhancing their electrical output still remains a significant challenge.Here,a strategy of inducing constrained phase separation on single nanofibers via shear force was proposed.Employing electrospinning technology,a polyacrylonitrile/polyvinylidene difluoride(PAN/PVDF)nanofibrous membrane was fabricated in one step,which enabled simultaneous piezoelectric and triboelectric conversion within a single-layer membrane.Each nanofiber contained independent components of PAN and PVDF and exhibited a rough surface.The abundant frictional contact points formed between these heterogeneous components contributed to an enhanced endogenous triboelectric output,showcasing an excellent synergistic effect of piezoelectric and triboelectric response in the nanofibrous membrane.Additionally,the component mass ratio influenced the microstructure,piezoelectric conformation and piezoelectric performance of the PAN/PVDF nanofibrous membranes.Through comprehensive performance comparison,the optimal mass ratio of PAN to PVDF was determined to be 9∶1.The piezoelectric devices made of the optimal PAN/PVDF nanofibrous membranes with rough nanofiber surfaces generated an output voltage of 20 V,which was about 1.8 times that of the smooth one at the same component mass ratio.The strategy of constrained phase separation on the surface of individual nanofibers provides a new approach to enhance the output performance of single-layer piezoelectric nanofibrous materials.展开更多
As an emerging multifunctional metal with the lowest melting point except for mercury,gallium combines a wide range of metallic and non-metallic elements to form advanced semiconductors critically important in cutting...As an emerging multifunctional metal with the lowest melting point except for mercury,gallium combines a wide range of metallic and non-metallic elements to form advanced semiconductors critically important in cutting-edge technologies.However,due to its low melting point and poor machinability,it is quite difficult to simultaneously characterize gallium’s elastic properties and damping characteristics using conventional methods,which is es-sential in designing and evaluating gallium-based structures.Therefore,developing effective methods to achieve accurate and efficient measurements of Young’s modulus and corresponding internal friction of gallium is of great significance.This letter studies simultaneous measurements of the variations in Young’s modulus and internal friction of gallium at varying temperatures by employing the modified piezoelectric ultrasonic composite oscil-lator technique.Combining the explicit theoretical formulas with the measured resonance and anti-resonance frequencies,it has been discovered that Young’s modulus undergoes an approximately linear decrease as the temperature rises,declining from 83.84 GPa at -70℃ to 79.37 GPa at 20℃.Moreover,like aluminum in the same Group ⅢA of the Periodic Table of Elements and exhibits a grain-boundary internal friction peak,gallium displays a longitudinal internal friction peak at approximately-12°C,with the peak value reaching 1.77×10^(-3).This basic research on gallium’s elastic properties and damping characteristics under low-temperature condi-tions will inspire further explorations of the mechanical properties of a diverse spectrum of low-melting-point functional materials and facilitate applications of gallium-based structures under complex conditions.展开更多
Piezoelectric ceramic materials are important components of piezoelectric buzzers,where the parameter of inverse piezoelectric coefficient(d_(33)^(*))plays a decisive role in the performance of the buzzer.Here,we repo...Piezoelectric ceramic materials are important components of piezoelectric buzzers,where the parameter of inverse piezoelectric coefficient(d_(33)^(*))plays a decisive role in the performance of the buzzer.Here,we report the manufacture and performance of a lead-free ceramic-based(0.96(K_(0.5)Na_(0.5))(Nb_(0.96)Sb_(0.04))O_(3)-0.04(Bi_(0.5)Na_(0.5))ZrO_(3)-1 mol%Al_(2)O_(3),abbreviated as KNNS-BNZ-1 mol%Al_(2)O_(3))piezoelectric buzzer and compare it with commercial(PbZr_(0.5)Ti_(0.5)O_(3),abbreviated as PZT)ceramics.Briefly,KNN-based ceramics have a typical perovskite structure and piezoelectric properties of d_(33)=480 pC/N,k_(p)=0.62 and d_(33)^(*)=830 pm/V,compared to d_(33)=500 pC/N,k_(p)=0.6 and d_(33)^(*)=918 pm/V of the commercial PZT-4 ceramics.Our results show that the KNNS-BNZ-1 mol%Al_(2)O_(3)ceramics have a similar sound pressure level performance over the testing frequency range to commercial PZT ceramics(which is even better in the 3-4 kHz range).These findings highlight the great application potential of KNN-based piezoelectric ceramics.展开更多
Graphene platelets(GPLs)-reinforced metal foam structures enhance the mechanical properties while maintaining the lightweight characteristics of metal foams.Further bonding piezoelectric actuator and sensor layers on ...Graphene platelets(GPLs)-reinforced metal foam structures enhance the mechanical properties while maintaining the lightweight characteristics of metal foams.Further bonding piezoelectric actuator and sensor layers on the surfaces of GPLs-reinforced metal foam beams enables active vibration control,greatly expanding their applications in the aerospace industry.For the first time,this paper investigates the vibration characteristics and active vibration control of GPLs-reinforced metal foam beams with surfacebonded piezoelectric layers.The constant velocity feedback scheme is used to design the closed-loop controller including piezoelectric actuators and sensors.The effects of the GPLs on the linear and nonlinear free vibrations of the beams are numerically studied.The Newmark-βmethod combined with Newton's iteration technique is used to calculate the nonlinear responses of the beams under different load forms including harmonic loads,impact loads,and moving loads.Additionally,special attention is given to the vibration reduction performance of the velocity feedback control on the responses of the beam.展开更多
This paper employs the Direct Finite Element Squared(DFE2)method to develop Sparse Polynomial Chaos Expansions(SPCE)models for analyzing the electromechanical properties of multiscale piezoelectric structures.By incor...This paper employs the Direct Finite Element Squared(DFE2)method to develop Sparse Polynomial Chaos Expansions(SPCE)models for analyzing the electromechanical properties of multiscale piezoelectric structures.By incorporating variations in piezoelectric and elastic constants,the DFE2 method is utilized to simulate the statistical characteristics—such as expected values and standard deviations—of electromechanical properties,including Mises stress,maximum in-plane principal strain,electric potential gradient,and electric potential,under varying parameters.This approach achieves a balance between computational efficiency and accuracy.Different SPCE models are used to investigate the influence of piezoelectric and elastic constants on multiscale piezoelectric materials.Additionally,the multiscale parameterization study investigates how microscale material properties affect the macroscopic response of these structures and materials.展开更多
In this paper,the dispersion,attenuation,and bandgap characteristics of in-plane coupled Bloch waves in one-dimensional piezoelectric semiconductor(PSC)phononic crystals are investigated,emphasizing the influence of p...In this paper,the dispersion,attenuation,and bandgap characteristics of in-plane coupled Bloch waves in one-dimensional piezoelectric semiconductor(PSC)phononic crystals are investigated,emphasizing the influence of positive-negative(PN)junctions.Unlike piezoelectric phononic crystals,the coupled Bloch waves in PSC phononic crystals are attenuated due to their semiconductor properties,and thus the solution of Bloch waves becomes more complicated.The transfer matrix of the phononic crystal unit cell is obtained using the state transfer equation.By applying the Bloch theorem for periodic structures,the dispersion relation of the coupled Bloch waves is derived,and the dispersion,attenuation,and bandgap are obtained in the complex wave number domain.It is found that the influence of the PN junction cannot be neglected.Moreover,the effects of the PN junction under different apparent wave numbers and steady-state carrier concentrations are provided.This indicates the feasibility of adjusting the propagation characteristics of Bloch waves through the regulation of the PN heterojunction.展开更多
In this paper,the mechanical response of a one-dimensional(1D)hexagonal piezoelectric quasicrystal(PQC)thin film is analyzed under electric and temperature loads.Based on the Euler-Bernoulli beam theory,a theoretical ...In this paper,the mechanical response of a one-dimensional(1D)hexagonal piezoelectric quasicrystal(PQC)thin film is analyzed under electric and temperature loads.Based on the Euler-Bernoulli beam theory,a theoretical model is proposed,resulting in coupled governing integral equations that account for interfacial normal and shear stresses.To numerically solve these integral equations,an expansion method using orthogonal Chebyshev polynomials is employed.The results provide insights into the interfacial stresses,axial force,as well as axial and vertical deformations of the PQC film.Additionally,fracture criteria,including stress intensity factors,mode angles,and the J-integral,are evaluated.The solution is compared with the membrane theory,neglecting the normal stress and bending deformation.Finally,the effects of stiffness and aspect ratio on the PQC film are thoroughly discussed.This study serves as a valuable guide for controlling the mechanical response and conducting safety assessments of PQC film systems.展开更多
Organic contaminants have posed a direct and substantial risk to human wellness and the environment.In recent years,piezo-electric catalysis has evolved as a novel and effective method for decomposing these contaminan...Organic contaminants have posed a direct and substantial risk to human wellness and the environment.In recent years,piezo-electric catalysis has evolved as a novel and effective method for decomposing these contaminants.Although piezoelectric materials offer a wide range of options,most related studies thus far have focused on inorganic materials and have paid little attention to organic materi-als.Organic materials have advantages,such as being lightweight,inexpensive,and easy to process,over inorganic materials.Therefore,this paper provides a comprehensive review of the progress made in the research on piezoelectric catalysis using organic materials,high-lighting their catalytic efficiency in addressing various pollutants.In addition,the applications of organic materials in piezoelectric cata-lysis for water decomposition to produce hydrogen,disinfect bacteria,treat tumors,and reduce carbon dioxide are presented.Finally,fu-ture developmental trends regarding the piezoelectric catalytic potential of organic materials are explored.展开更多
The dynamic responses and generated voltage in a curved sandwich beam with glass reinforced laminate(GRL)layers and a pliable core in the presence of a piezoelectric layer under low-velocity impact(LVI)are investigate...The dynamic responses and generated voltage in a curved sandwich beam with glass reinforced laminate(GRL)layers and a pliable core in the presence of a piezoelectric layer under low-velocity impact(LVI)are investigated.The current study aims to carry out a dynamic analysis on the sandwich beam when the impactor hits the top face sheet with an initial velocity.For the layer analysis,the high-order shear deformation theory(HSDT)and Frostig's second model for the displacement fields of the core layer are used.The classical non-adhesive elastic contact theory and Hunter's principle are used to calculate the dynamic responses in terms of time.In order to validate the analytical method,the outcomes of the current investigation are compared with those gained by the experimental tests carried out by other researchers for a rectangular composite plate subject to the LVI.Finite element(FE)simulations are conducted by means of the ABAQUS software.The effects of the parameters such as foam modulus,layer material,fiber angle,impactor mass,and its velocity on the generated voltage are reviewed.展开更多
Piezoelectric semiconductors(PSs)possess both semiconducting properties and piezoelectric coupling effects,making them optimal building blocks for semiconductor devices.PS fiber-like structures have wide applications ...Piezoelectric semiconductors(PSs)possess both semiconducting properties and piezoelectric coupling effects,making them optimal building blocks for semiconductor devices.PS fiber-like structures have wide applications in multi-functional semiconductor devices.In this paper,a one-dimensional(1D)theoretical model is established to describe the piezotronic responses of a PS fiber under gradient temperature changes.The theoretical model aims to explain the mechanism behind the resistance change caused by such gradient temperature changes.Numerical results demonstrate that a gradient temperature change significantly affects the physical fields within the PS fiber,and can induce changes in its surface resistance.It provides important theoretical guidance on the development of piezotronic devices that are sensitive to temperature effects.展开更多
Background:Most bone-related injuries to grassroots troops are caused by training or accidental injuries.To establish preventive measures to reduce all kinds of trauma and improve the combat effectiveness of grassroot...Background:Most bone-related injuries to grassroots troops are caused by training or accidental injuries.To establish preventive measures to reduce all kinds of trauma and improve the combat effectiveness of grassroots troops,it is imperative to develop new strategies and scafolds to promote bone regeneration.Methods:In this study,a porous piezoelectric hydrogel bone scafold was fabricated by incorporating polydopamine(PDA)-modified ceramic hydroxyapatite(PDA-hydroxyapatite,PHA)and PDA-modified barium titanate(PDABaTiO_(3),PBT)nanoparticles into a chitosan/gelatin(Cs/Gel)matrix.The physical and chemical properties of the Cs/Gel/PHA scafold with 0–10 wt%PBT were analyzed.Cell and animal experiments were performed to characterize the immunomodulatory,angiogenic,and osteogenic capabilities of the piezoelectric hydrogel scafold in vitro and in vivo.Results:The incorporation of BaTiO_(3) into the scafold improved its mechanical properties and increased self-generated electricity.Due to their endogenous piezoelectric stimulation and bioactive constituents,the prepared Cs/Gel/PHA/PBT hydrogels exhibited cytocompatibility as well as immunomodulatory,angiogenic,and osteogenic capabilities;they not only effectively induced macrophage polarization to M2 phenotype but also promoted the migration,tube formation,and angiogenic differentiation of human umbilical vein endothelial cells(HUVECs)and facilitated the migration,osteodifferentiation,and extracellular matrix(ECM)mineralization of MC3T3-E1 cells.The in vivo evaluations showed that these piezoelectric hydrogels with versatile capabilities significantly facilitated new bone formation in a rat large-sized cranial injury model.The underlying molecular mechanism can be partly attributed to the immunomodulation of the Cs/Gel/PHA/PBT hydrogels as shown via transcriptome sequencing analysis,and the PI3K/Akt signaling axis plays an important role in regulating macrophage M2 polarization.Conclusion:The piezoelectric Cs/Gel/PHA/PBT hydrogels developed here with favorable immunomodulation,angiogenesis,and osteogenesis functions may be used as a substitute in periosteum injuries,thereby offering the novel strategy of applying piezoelectric stimulation in bone tissue engineering for the enhancement of combat efectiveness in grassroots troops.展开更多
Piezoelectric devices exhibit unique properties that vary with different vibration modes,closely influenced by their polarization direction.This paper presents an analysis on the free vibration of laminated piezoelect...Piezoelectric devices exhibit unique properties that vary with different vibration modes,closely influenced by their polarization direction.This paper presents an analysis on the free vibration of laminated piezoelectric beams with varying polarization directions,using a state-space-based differential quadrature method.First,based on the electro-elasticity theory,the state-space method is extended to anisotropic piezoelectric materials,establishing state-space equations for arbitrary polarized piezoelectric beams.A semi-analytical solution for the natural frequency is then obtained via the differential quadrature method.The study commences by examining the impact of a uniform polarization direction,and then proceeds to analyze six polarization schemes relevant to the current research and applications.Additionally,the effects of geometric dimensions and gradient index on the natural frequencies are explored.The numerical results demonstrate that varying the polarization direction can significantly influence the natural frequencies,offering distinct advantages for piezoelectric elements with different polarizations.This research provides both theoretical insights and numerical methods for the structural design of piezoelectric devices.展开更多
Charge separation is critical for achieving efficient solar-to-hydrogen conversion,whereas piezoelectric-enhanced photoelectrochemical(PEC)systems can effectively modulate band bending and charge migration.Herein,we d...Charge separation is critical for achieving efficient solar-to-hydrogen conversion,whereas piezoelectric-enhanced photoelectrochemical(PEC)systems can effectively modulate band bending and charge migration.Herein,we design an n-TiO_(2)/Ba TiO_(3)/p-TiO_(2)(TBTm)heterojunction in which the piezoelectric Ba TiO_(3) layer is sandwiched between n-TiO_(2)and p-TiO_(2).The built-in electric field of TBTm can provide a strong driving force to accelerate carrier separation and prolong carrier lifetime.Consequently,the TBT3 achieves a prominent photocurrent density,as high as 2.13 m A cm^(-2)at 1.23 V versus reversible hydrogen electrode(RHE),which is 2.4-and 1.5-times higher than TiO_(2) and TiO_(2)–Ba TiO_(3) heterojunction,respectively.Driven by mechanical deformation,the induced dipole polarization can further regulate built-in electric fields,and the piezoelectric photocurrent density of TBT3-800 is 2.84 times higher than TiO_(2) at 1.23 V vs.RHE due to the construction of piezoelectric-heterostructures.This work provides a piezoelectric polarization strategy for modulating the built-in electric field of heterojunction for PEC system.展开更多
The self-powered tissue engineering scaffold with good biocompatibility is of great significance for stimulating nerve cell growth.In this study,silk fibroin(SF)-based fibers with regulatable structure and piezoelectr...The self-powered tissue engineering scaffold with good biocompatibility is of great significance for stimulating nerve cell growth.In this study,silk fibroin(SF)-based fibers with regulatable structure and piezoelectric performance are fabricated by dry-spinning and post-treatment.The concentration of SF and calcium ion in spinning dope and the post-treatment affect the conformation transition and crystallinity of SF.As a result,the SF fibers exhibit high piezoelectric coefficient d_(33)(3.24 pm/V)and output voltage(~27 V).Furthermore,these piezoelectric fibers promote the growth of PC-12 cells,demonstrating the promising potential for nerve repair and other energy harvester.展开更多
Broadband vibration attenuation is a challenging task in engineering since it is difficult to achieve low-frequency and broadband vibration control simultaneously.To solve this problem,this paper designs a piezoelectr...Broadband vibration attenuation is a challenging task in engineering since it is difficult to achieve low-frequency and broadband vibration control simultaneously.To solve this problem,this paper designs a piezoelectric meta-beam with unidirectional electric circuits,exhibiting promising broadband attenuation capabilities.An analytical model in a closed form for achieving the solution of unidirectional vibration transmission of the designed meta-beam is developed based on the state-space transfer function method.The method can analyze the forward and backward vibration transmission of the piezoelectric meta-beam in a unified manner,providing reliable dynamics solutions of the beam.The analytical results indicate that the meta-beam effectively reduces the unidirectional vibration across a broad low-frequency range,which is also verified by the solutions obtained from finite element analyses.The designed meta-beam and the proposed analytical method facilitate a comprehensive investigation into the distinctive unidirectional transmission behavior and superb broadband vibration attenuation performance.展开更多
This paper theoretically studies the axisymmetric frictionless indentation of a transversely isotropic piezoelectric semiconductor(PSC)half-space subject to a rigid flatended cylindrical indenter.The contact area and ...This paper theoretically studies the axisymmetric frictionless indentation of a transversely isotropic piezoelectric semiconductor(PSC)half-space subject to a rigid flatended cylindrical indenter.The contact area and other surface of the PSC half-space are assumed to be electrically insulating.By the Hankel integral transformation,the problem is reduced to the Fredholm integral equation of the second kind.This equation is solved numerically to obtain the indentation behaviors of the PSC half-space,mainly including the indentation force-depth relation and the electric potential-depth relation.The results show that the effect of the semiconductor property on the indentation responses is limited within a certain range of variation of the steady carrier concentration.The dependence of indentation behavior on material properties is also analyzed by two different kinds of PSCs.Finite element simulations are conducted to verify the results calculated by the integral equation technique,and good agreement is demonstrated.展开更多
基金financially supported by the National Key Research and Development Program of China(No.2022YFA1205300 and No.2022YFA1205304)the Oceanic Interdisciplinary Program of Shanghai Jiao Tong University(SL2022ZD103).
文摘Monitoring minuscule mechanical signals,both in magnitude and direction,is imperative in many application scenarios,e.g.,structural health monitoring and robotic sensing systems.However,the piezoelectric sensor struggles to satisfy the requirements for directional recognition due to the limited piezoelectric coefficient matrix,and achieving sensitivity for detecting micrometer-scale deformations is also challenging.Herein,we develop a vector sensor composed of lead zirconate titanate-electronic grade glass fiber composite filaments with oriented arrangement,capable of detecting minute anisotropic deformations.The as-prepared vector sensor can identify the deformation directions even when subjected to an unprecedented nominal strain of 0.06%,thereby enabling its utility in accurately discerning the 5μm-height wrinkles in thin films and in monitoring human pulse waves.The ultra-high sensitivity is attributed to the formation of porous ferroelectret and the efficient load transfer efficiency of continuous lead zirconate titanate phase.Additionally,when integrated with machine learning techniques,the sensor’s capability to recognize multi-signals enables it to differentiate between 10 types of fine textures with 100%accuracy.The structural design in piezoelectric devices enables a more comprehensive perception of mechanical stimuli,offering a novel perspective for enhancing recognition accuracy.
基金supported by National Research Foundation of Korea(2022M3D1A2054488)Technology Innovation Program(20025736,Development of MICS SoC and platform for in-vivo implantable electroceutical device)funded by the Ministry of Trade,Industry&Energy(MOTIE,Korea)。
文摘Piezoelectric and triboelectric effects are of growing interest for facilitating high-sensitivity and self-powered tactile sensor applications.The working principles of piezoelectric and triboelectric nanogenerators provide strategies for enhancing output voltage signals to achieve high sensitivity.Increasing the piezoelectric constant and surface triboelectric charge density are key factors in this enhancement.Methods such as annealing processes,doping techniques,grain orientation controls,crystallinity controls,and composite structures can effectively enhance the piezoelectric constant.For increasing triboelectric output,surface plasma treatment,charge injection,microstructuring,control of dielectric constant,and structural modification are effective methods.The fabrication methods present significant opportunities in tactile sensor applications.This review article summarizes the overall piezoelectric and triboelectric fabrication processes from materials to device aspects.It highlights applications in pressure,touch,bending,texture,distance,and material recognition sensors.The conclusion section addresses challenges and research opportunities,such as limited flexibility,stretchability,decoupling from multi-stimuli,multifunctional sensors,and data processing.
基金The Natural Science Foundation of Guangdong Province(Project No.2023A1515012352)。
文摘Zinc oxide(ZnO),as a broadband gap semiconductor material,exhibits unique physical and chemical properties that make it highly suitable for optoelectronics,piezoelectric devices,and gas-sensitive sensors,showing significant potential for various applications.This paper focuses on the regulation and application of ZnO-based p-n junctions and piezoelectric devices.It discusses in detail the preparation of ZnO materials,the construction of p-n junctions,the optimization of piezoelectric device performance,and its application in various fields.By employing different preparation methods and strategies,high-quality ZnO thin films can be grown,and effective control of p-type conductivity achieved.This study provides both a theoretical foundation and technical support for controlling the performance of ZnO-based piezoelectric devices,as well as paving new pathways for the broader application of ZnO materials.
基金supported by the National Key R&D Program of China(Grant Nos.2022YFB3603403,2021YFB3600502)the National Natural Science Foundation of China(Grant Nos.62075040,62301150)+3 种基金the Southeast University Interdisciplinary Research Program for Young Scholars(2024FGC1007)the Start-up Research Fund of Southeast University(RF1028623164)the Nanjing Science and Technology Innovation Project for Returned Overseas Talent(4206002302)the Fundamental Research Funds for the Central Universities(2242024K40015).
文摘Benefiting from the widespread potential applications in the era of the Internet of Thing and metaverse,triboelectric and piezoelectric nanogenerators(TENG&PENG)have attracted considerably increasing attention.Their outstanding characteristics,such as self-powered ability,high output performance,integration compatibility,cost-effectiveness,simple configurations,and versatile operation modes,could effectively expand the lifetime of vastly distributed wearable,implantable,and environmental devices,eventually achieving self-sustainable,maintenance-free,and reliable systems.However,current triboelectric/piezoelectric based active(i.e.self-powered)sensors still encounter serious bottlenecks in continuous monitoring and multimodal applications due to their intrinsic limitations of monomodal kinetic response and discontinuous transient output.This work systematically summarizes and evaluates the recent research endeavors to address the above challenges,with detailed discussions on the challenge origins,designing strategies,device performance,and corresponding diverse applications.Finally,conclusions and outlook regarding the research gap in self-powered continuous multimodal monitoring systems are provided,proposing the necessity of future research development in this field.
基金National Natural Science Foundation of China(No.52373281)National Energy-Saving and Low-Carbon Materials Production and Application Demonstration Platform Program,China(No.TC220H06N)。
文摘The research,fabrication and development of piezoelectric nanofibrous materials offer effective solutions to the challenges related to energy consumption and non-renewable resources.However,enhancing their electrical output still remains a significant challenge.Here,a strategy of inducing constrained phase separation on single nanofibers via shear force was proposed.Employing electrospinning technology,a polyacrylonitrile/polyvinylidene difluoride(PAN/PVDF)nanofibrous membrane was fabricated in one step,which enabled simultaneous piezoelectric and triboelectric conversion within a single-layer membrane.Each nanofiber contained independent components of PAN and PVDF and exhibited a rough surface.The abundant frictional contact points formed between these heterogeneous components contributed to an enhanced endogenous triboelectric output,showcasing an excellent synergistic effect of piezoelectric and triboelectric response in the nanofibrous membrane.Additionally,the component mass ratio influenced the microstructure,piezoelectric conformation and piezoelectric performance of the PAN/PVDF nanofibrous membranes.Through comprehensive performance comparison,the optimal mass ratio of PAN to PVDF was determined to be 9∶1.The piezoelectric devices made of the optimal PAN/PVDF nanofibrous membranes with rough nanofiber surfaces generated an output voltage of 20 V,which was about 1.8 times that of the smooth one at the same component mass ratio.The strategy of constrained phase separation on the surface of individual nanofibers provides a new approach to enhance the output performance of single-layer piezoelectric nanofibrous materials.
基金financially supported by the National Key R&D Program of China(Grant No.2023YFF0716800)the National Natural Science Foundation of China(Grant No.12074160)the Natural Science Foundation of Liaoning Province of China(Grant No.2024-MS-181).
文摘As an emerging multifunctional metal with the lowest melting point except for mercury,gallium combines a wide range of metallic and non-metallic elements to form advanced semiconductors critically important in cutting-edge technologies.However,due to its low melting point and poor machinability,it is quite difficult to simultaneously characterize gallium’s elastic properties and damping characteristics using conventional methods,which is es-sential in designing and evaluating gallium-based structures.Therefore,developing effective methods to achieve accurate and efficient measurements of Young’s modulus and corresponding internal friction of gallium is of great significance.This letter studies simultaneous measurements of the variations in Young’s modulus and internal friction of gallium at varying temperatures by employing the modified piezoelectric ultrasonic composite oscil-lator technique.Combining the explicit theoretical formulas with the measured resonance and anti-resonance frequencies,it has been discovered that Young’s modulus undergoes an approximately linear decrease as the temperature rises,declining from 83.84 GPa at -70℃ to 79.37 GPa at 20℃.Moreover,like aluminum in the same Group ⅢA of the Periodic Table of Elements and exhibits a grain-boundary internal friction peak,gallium displays a longitudinal internal friction peak at approximately-12°C,with the peak value reaching 1.77×10^(-3).This basic research on gallium’s elastic properties and damping characteristics under low-temperature condi-tions will inspire further explorations of the mechanical properties of a diverse spectrum of low-melting-point functional materials and facilitate applications of gallium-based structures under complex conditions.
基金Project supported by the Key Research and Develop Projects in Gansu Province(Grant No.23YFGA0002)the project funding of Audiowell Electronics(Guangdong)Co.,Ltd.
文摘Piezoelectric ceramic materials are important components of piezoelectric buzzers,where the parameter of inverse piezoelectric coefficient(d_(33)^(*))plays a decisive role in the performance of the buzzer.Here,we report the manufacture and performance of a lead-free ceramic-based(0.96(K_(0.5)Na_(0.5))(Nb_(0.96)Sb_(0.04))O_(3)-0.04(Bi_(0.5)Na_(0.5))ZrO_(3)-1 mol%Al_(2)O_(3),abbreviated as KNNS-BNZ-1 mol%Al_(2)O_(3))piezoelectric buzzer and compare it with commercial(PbZr_(0.5)Ti_(0.5)O_(3),abbreviated as PZT)ceramics.Briefly,KNN-based ceramics have a typical perovskite structure and piezoelectric properties of d_(33)=480 pC/N,k_(p)=0.62 and d_(33)^(*)=830 pm/V,compared to d_(33)=500 pC/N,k_(p)=0.6 and d_(33)^(*)=918 pm/V of the commercial PZT-4 ceramics.Our results show that the KNNS-BNZ-1 mol%Al_(2)O_(3)ceramics have a similar sound pressure level performance over the testing frequency range to commercial PZT ceramics(which is even better in the 3-4 kHz range).These findings highlight the great application potential of KNN-based piezoelectric ceramics.
基金Project supported by the National Natural Science Foundation of China(Nos.12102015 and 12472003)the R&D Program of Beijing Municipal Education Commission of China(No.KM202110005030)。
文摘Graphene platelets(GPLs)-reinforced metal foam structures enhance the mechanical properties while maintaining the lightweight characteristics of metal foams.Further bonding piezoelectric actuator and sensor layers on the surfaces of GPLs-reinforced metal foam beams enables active vibration control,greatly expanding their applications in the aerospace industry.For the first time,this paper investigates the vibration characteristics and active vibration control of GPLs-reinforced metal foam beams with surfacebonded piezoelectric layers.The constant velocity feedback scheme is used to design the closed-loop controller including piezoelectric actuators and sensors.The effects of the GPLs on the linear and nonlinear free vibrations of the beams are numerically studied.The Newmark-βmethod combined with Newton's iteration technique is used to calculate the nonlinear responses of the beams under different load forms including harmonic loads,impact loads,and moving loads.Additionally,special attention is given to the vibration reduction performance of the velocity feedback control on the responses of the beam.
基金supported by the Zhumadian 2023 Major Science and Technology Special Project(Grant No.ZMDSZDZX2023002)the Postgraduate Education Reform and Quality Improvement Project of Henan Province(Grant No.YJS2023JD52).
文摘This paper employs the Direct Finite Element Squared(DFE2)method to develop Sparse Polynomial Chaos Expansions(SPCE)models for analyzing the electromechanical properties of multiscale piezoelectric structures.By incorporating variations in piezoelectric and elastic constants,the DFE2 method is utilized to simulate the statistical characteristics—such as expected values and standard deviations—of electromechanical properties,including Mises stress,maximum in-plane principal strain,electric potential gradient,and electric potential,under varying parameters.This approach achieves a balance between computational efficiency and accuracy.Different SPCE models are used to investigate the influence of piezoelectric and elastic constants on multiscale piezoelectric materials.Additionally,the multiscale parameterization study investigates how microscale material properties affect the macroscopic response of these structures and materials.
基金Project supported by the National Natural Science Foundation of China(Nos.11872105,12072022,11911530176,and 12202039)。
文摘In this paper,the dispersion,attenuation,and bandgap characteristics of in-plane coupled Bloch waves in one-dimensional piezoelectric semiconductor(PSC)phononic crystals are investigated,emphasizing the influence of positive-negative(PN)junctions.Unlike piezoelectric phononic crystals,the coupled Bloch waves in PSC phononic crystals are attenuated due to their semiconductor properties,and thus the solution of Bloch waves becomes more complicated.The transfer matrix of the phononic crystal unit cell is obtained using the state transfer equation.By applying the Bloch theorem for periodic structures,the dispersion relation of the coupled Bloch waves is derived,and the dispersion,attenuation,and bandgap are obtained in the complex wave number domain.It is found that the influence of the PN junction cannot be neglected.Moreover,the effects of the PN junction under different apparent wave numbers and steady-state carrier concentrations are provided.This indicates the feasibility of adjusting the propagation characteristics of Bloch waves through the regulation of the PN heterojunction.
基金Supported by the National Natural Science Foundation of China (Nos. 11902293 and 12272353)。
文摘In this paper,the mechanical response of a one-dimensional(1D)hexagonal piezoelectric quasicrystal(PQC)thin film is analyzed under electric and temperature loads.Based on the Euler-Bernoulli beam theory,a theoretical model is proposed,resulting in coupled governing integral equations that account for interfacial normal and shear stresses.To numerically solve these integral equations,an expansion method using orthogonal Chebyshev polynomials is employed.The results provide insights into the interfacial stresses,axial force,as well as axial and vertical deformations of the PQC film.Additionally,fracture criteria,including stress intensity factors,mode angles,and the J-integral,are evaluated.The solution is compared with the membrane theory,neglecting the normal stress and bending deformation.Finally,the effects of stiffness and aspect ratio on the PQC film are thoroughly discussed.This study serves as a valuable guide for controlling the mechanical response and conducting safety assessments of PQC film systems.
基金the National Natural Science Foundation of China(No.22179108)the Key Research and Development Projects of Shaanxi Province,China(No.2020GXLH-Z-032)+2 种基金the Doctoral Re-search Start-up Fund project of Xi’an Polytechnic University(No.107020589)the Shaanxi Provincial High-Level Talents Introduction Project(Youth Talent Fund)the Performance subsidy fund for Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province,China(No.22567627H).
文摘Organic contaminants have posed a direct and substantial risk to human wellness and the environment.In recent years,piezo-electric catalysis has evolved as a novel and effective method for decomposing these contaminants.Although piezoelectric materials offer a wide range of options,most related studies thus far have focused on inorganic materials and have paid little attention to organic materi-als.Organic materials have advantages,such as being lightweight,inexpensive,and easy to process,over inorganic materials.Therefore,this paper provides a comprehensive review of the progress made in the research on piezoelectric catalysis using organic materials,high-lighting their catalytic efficiency in addressing various pollutants.In addition,the applications of organic materials in piezoelectric cata-lysis for water decomposition to produce hydrogen,disinfect bacteria,treat tumors,and reduce carbon dioxide are presented.Finally,fu-ture developmental trends regarding the piezoelectric catalytic potential of organic materials are explored.
文摘The dynamic responses and generated voltage in a curved sandwich beam with glass reinforced laminate(GRL)layers and a pliable core in the presence of a piezoelectric layer under low-velocity impact(LVI)are investigated.The current study aims to carry out a dynamic analysis on the sandwich beam when the impactor hits the top face sheet with an initial velocity.For the layer analysis,the high-order shear deformation theory(HSDT)and Frostig's second model for the displacement fields of the core layer are used.The classical non-adhesive elastic contact theory and Hunter's principle are used to calculate the dynamic responses in terms of time.In order to validate the analytical method,the outcomes of the current investigation are compared with those gained by the experimental tests carried out by other researchers for a rectangular composite plate subject to the LVI.Finite element(FE)simulations are conducted by means of the ABAQUS software.The effects of the parameters such as foam modulus,layer material,fiber angle,impactor mass,and its velocity on the generated voltage are reviewed.
基金Project supported by the National Natural Science Foundation of China (Nos.12172326 and 11972319)the National Key Research and Development Program of China (No.2020YFA0711700)the Natural Science Foundation of Zhejiang Province of China (No.LR21A020002)。
文摘Piezoelectric semiconductors(PSs)possess both semiconducting properties and piezoelectric coupling effects,making them optimal building blocks for semiconductor devices.PS fiber-like structures have wide applications in multi-functional semiconductor devices.In this paper,a one-dimensional(1D)theoretical model is established to describe the piezotronic responses of a PS fiber under gradient temperature changes.The theoretical model aims to explain the mechanism behind the resistance change caused by such gradient temperature changes.Numerical results demonstrate that a gradient temperature change significantly affects the physical fields within the PS fiber,and can induce changes in its surface resistance.It provides important theoretical guidance on the development of piezotronic devices that are sensitive to temperature effects.
基金supported by the National Natural Science Foundation of China(82202352,82271629)the Translational Medicine and Interdisciplinary Research Joint Fund of Zhongnan Hospital of Wuhan University(ZNLH202202)+1 种基金the China Postdoctoral Science Foundation Funded Project(2023M732711)the Wenzhou Medical University grant(QTJ23004)。
文摘Background:Most bone-related injuries to grassroots troops are caused by training or accidental injuries.To establish preventive measures to reduce all kinds of trauma and improve the combat effectiveness of grassroots troops,it is imperative to develop new strategies and scafolds to promote bone regeneration.Methods:In this study,a porous piezoelectric hydrogel bone scafold was fabricated by incorporating polydopamine(PDA)-modified ceramic hydroxyapatite(PDA-hydroxyapatite,PHA)and PDA-modified barium titanate(PDABaTiO_(3),PBT)nanoparticles into a chitosan/gelatin(Cs/Gel)matrix.The physical and chemical properties of the Cs/Gel/PHA scafold with 0–10 wt%PBT were analyzed.Cell and animal experiments were performed to characterize the immunomodulatory,angiogenic,and osteogenic capabilities of the piezoelectric hydrogel scafold in vitro and in vivo.Results:The incorporation of BaTiO_(3) into the scafold improved its mechanical properties and increased self-generated electricity.Due to their endogenous piezoelectric stimulation and bioactive constituents,the prepared Cs/Gel/PHA/PBT hydrogels exhibited cytocompatibility as well as immunomodulatory,angiogenic,and osteogenic capabilities;they not only effectively induced macrophage polarization to M2 phenotype but also promoted the migration,tube formation,and angiogenic differentiation of human umbilical vein endothelial cells(HUVECs)and facilitated the migration,osteodifferentiation,and extracellular matrix(ECM)mineralization of MC3T3-E1 cells.The in vivo evaluations showed that these piezoelectric hydrogels with versatile capabilities significantly facilitated new bone formation in a rat large-sized cranial injury model.The underlying molecular mechanism can be partly attributed to the immunomodulation of the Cs/Gel/PHA/PBT hydrogels as shown via transcriptome sequencing analysis,and the PI3K/Akt signaling axis plays an important role in regulating macrophage M2 polarization.Conclusion:The piezoelectric Cs/Gel/PHA/PBT hydrogels developed here with favorable immunomodulation,angiogenesis,and osteogenesis functions may be used as a substitute in periosteum injuries,thereby offering the novel strategy of applying piezoelectric stimulation in bone tissue engineering for the enhancement of combat efectiveness in grassroots troops.
基金Project supported by the National Natural Science Foundation of China(Nos.12272353 and 12002316)the Key Scientific and Technological Research Projects in Henan Province of China(No.232102211075)。
文摘Piezoelectric devices exhibit unique properties that vary with different vibration modes,closely influenced by their polarization direction.This paper presents an analysis on the free vibration of laminated piezoelectric beams with varying polarization directions,using a state-space-based differential quadrature method.First,based on the electro-elasticity theory,the state-space method is extended to anisotropic piezoelectric materials,establishing state-space equations for arbitrary polarized piezoelectric beams.A semi-analytical solution for the natural frequency is then obtained via the differential quadrature method.The study commences by examining the impact of a uniform polarization direction,and then proceeds to analyze six polarization schemes relevant to the current research and applications.Additionally,the effects of geometric dimensions and gradient index on the natural frequencies are explored.The numerical results demonstrate that varying the polarization direction can significantly influence the natural frequencies,offering distinct advantages for piezoelectric elements with different polarizations.This research provides both theoretical insights and numerical methods for the structural design of piezoelectric devices.
基金the support from the National Natural Science Foundation of China(22222808,21978200,22161142002)the Joint Research Programs of National Natural Science Foundation of China and Pakistan Science Foundation(PSF-NSFC-IV/Phy/P-PU(31))the Haihe Laboratory of Sustainable Chemical Transformations for financial support。
文摘Charge separation is critical for achieving efficient solar-to-hydrogen conversion,whereas piezoelectric-enhanced photoelectrochemical(PEC)systems can effectively modulate band bending and charge migration.Herein,we design an n-TiO_(2)/Ba TiO_(3)/p-TiO_(2)(TBTm)heterojunction in which the piezoelectric Ba TiO_(3) layer is sandwiched between n-TiO_(2)and p-TiO_(2).The built-in electric field of TBTm can provide a strong driving force to accelerate carrier separation and prolong carrier lifetime.Consequently,the TBT3 achieves a prominent photocurrent density,as high as 2.13 m A cm^(-2)at 1.23 V versus reversible hydrogen electrode(RHE),which is 2.4-and 1.5-times higher than TiO_(2) and TiO_(2)–Ba TiO_(3) heterojunction,respectively.Driven by mechanical deformation,the induced dipole polarization can further regulate built-in electric fields,and the piezoelectric photocurrent density of TBT3-800 is 2.84 times higher than TiO_(2) at 1.23 V vs.RHE due to the construction of piezoelectric-heterostructures.This work provides a piezoelectric polarization strategy for modulating the built-in electric field of heterojunction for PEC system.
基金Project sponsored by the Basic Research Project of the Science and Technology Commission of Shanghai Municipality (Grant No.21JC1400100)the Shanghai Rising-Star Program (Grant No.22QA1400400)+1 种基金the National Natural Science Foundation of China (Grant No.52173031)the Oriental Talent Plan (Leading Talent Program,No.152)。
文摘The self-powered tissue engineering scaffold with good biocompatibility is of great significance for stimulating nerve cell growth.In this study,silk fibroin(SF)-based fibers with regulatable structure and piezoelectric performance are fabricated by dry-spinning and post-treatment.The concentration of SF and calcium ion in spinning dope and the post-treatment affect the conformation transition and crystallinity of SF.As a result,the SF fibers exhibit high piezoelectric coefficient d_(33)(3.24 pm/V)and output voltage(~27 V).Furthermore,these piezoelectric fibers promote the growth of PC-12 cells,demonstrating the promising potential for nerve repair and other energy harvester.
基金Project supported by the National Natural Science Foundation of China (Nos. U2141244, 11932011,12393781, 12121002, and 12202267)supported by the Oceanic Interdisciplinary Program of Shanghai Jiao Tong University(No.SL2021ZD104)+4 种基金the Science and Technology Cooperation Project of Shanghai Jiao Tong University&Inner Mongolia Autonomous Region-Action Plan of Shanghai Jiao Tong University for“Science and Technology Prosperity”(No.2022XYJG0001-01-08)the Industryuniversity-research Cooperation Fund of Shanghai Academy of Spaceflight Technology(No.USCAST2021-11)Shanghai Pujiang Program(No.22PJ1405300)Young Talent Reservoir of CSTAM(No.CSTAM2022-XSC-QN1)the Starting Grant of Shanghai Jiao Tong University(No.WH220402014).
文摘Broadband vibration attenuation is a challenging task in engineering since it is difficult to achieve low-frequency and broadband vibration control simultaneously.To solve this problem,this paper designs a piezoelectric meta-beam with unidirectional electric circuits,exhibiting promising broadband attenuation capabilities.An analytical model in a closed form for achieving the solution of unidirectional vibration transmission of the designed meta-beam is developed based on the state-space transfer function method.The method can analyze the forward and backward vibration transmission of the piezoelectric meta-beam in a unified manner,providing reliable dynamics solutions of the beam.The analytical results indicate that the meta-beam effectively reduces the unidirectional vibration across a broad low-frequency range,which is also verified by the solutions obtained from finite element analyses.The designed meta-beam and the proposed analytical method facilitate a comprehensive investigation into the distinctive unidirectional transmission behavior and superb broadband vibration attenuation performance.
基金Project supported by the National Natural Science Foundation of China(Nos.12072209,U21A2043012192211)+1 种基金the Natural Science Foundation of Hebei Province of China(No.A2020210009)the S&T Program of Hebei Province of China(No.225676162GH)。
文摘This paper theoretically studies the axisymmetric frictionless indentation of a transversely isotropic piezoelectric semiconductor(PSC)half-space subject to a rigid flatended cylindrical indenter.The contact area and other surface of the PSC half-space are assumed to be electrically insulating.By the Hankel integral transformation,the problem is reduced to the Fredholm integral equation of the second kind.This equation is solved numerically to obtain the indentation behaviors of the PSC half-space,mainly including the indentation force-depth relation and the electric potential-depth relation.The results show that the effect of the semiconductor property on the indentation responses is limited within a certain range of variation of the steady carrier concentration.The dependence of indentation behavior on material properties is also analyzed by two different kinds of PSCs.Finite element simulations are conducted to verify the results calculated by the integral equation technique,and good agreement is demonstrated.
