The polyacrylamide which is directly added into concrete shows strong water absorption property.Thus the construction of underwater constructure would demand high amount of water,resulting in poor workability of concr...The polyacrylamide which is directly added into concrete shows strong water absorption property.Thus the construction of underwater constructure would demand high amount of water,resulting in poor workability of concrete and strength shrinkage after hardening.Herein,a kind of anionic polyacrylamide(APAM)grafted with water reducing functional group(-COOH)was synthesized at low temperatures by partial factor design and response surface design.The structure and morphology of APAM were characterized by UV,FTIR and SEM methods.The experimental results show that the molecular weight of the synthesized APAM could reach 11 million,under the condition that the temperature was 35℃,the pH value was 8,the monomer concentration was 27wt%,the initiator dosage was 0.6wt%,and the monomer ratio(n(AM):n(AA))was 3.When the APAM was applied into the underwater slurry,it presented good flocculation and low water demand.When the dosage was 1%of the mass of the cement,the water demand increased by 12%,which could meet the self-leveling and anti-dispersity of the underwater slurry at the same time.This technology provides technical guidance for the large-scale industrial production of polyacrylamide for underwater concrete construction while achieving environmental protection during production.展开更多
The degradation of partially hydrolyzed polyacrylamide(HPAM) found in alkaline/surfactant/polymer flooding sewage was investigated using Fenton-type reagents. Different Fenton reagent treatments for HPAM degradation w...The degradation of partially hydrolyzed polyacrylamide(HPAM) found in alkaline/surfactant/polymer flooding sewage was investigated using Fenton-type reagents. Different Fenton reagent treatments for HPAM degradation were compared. The effects of pH, hydrogen peroxide(H_(2)O_(2)), ferrous ion(Fe^(2+)), and tartaric ion(C_(4)H_(4)O_(6)^(2-)) concentrations were studied. The degradation reaction occurred within a wide range of pH(3–9). The HPAM degradation performance of photo-Fenton processes using solar light and UV were compared with that of the Fenton process. The degradation rate was found to be strongly dependent on the H_(2)O_(2)/Fe^(2+)/C_(4)H_(4)O_(6)^(2-)molar ratio. The HPAM degradation efficiency was 90%, and the chemical oxygen demand removal efficiency was 85%. HPAM could be degraded into a compound with a lower molecular weight, but it was difficult to achieve complete mineralization to CO_(2). The presence of intermediate products hindered further oxidation in the Fenton process.展开更多
Once a popular injectable filler,polyacrylamide hydrogel(PAAG)has been banned in China since 2006 due to its unclear safety and long-term complications.However,it is still being used worldwide because of its huge comm...Once a popular injectable filler,polyacrylamide hydrogel(PAAG)has been banned in China since 2006 due to its unclear safety and long-term complications.However,it is still being used worldwide because of its huge commercial profit,leading to emerging complications and an urgent need for standardized clinical management.This review aimed to assess the properties,safety,and complications of PAAG and treatment strategies for its removal.展开更多
In this work,non-thermal plasma has been applied to treat polyacrylamide(PAM)wastewater.We have investigated the in fluence of the rule of PAM wastewater initial pH,solution concentration and discharge time,discharge ...In this work,non-thermal plasma has been applied to treat polyacrylamide(PAM)wastewater.We have investigated the in fluence of the rule of PAM wastewater initial pH,solution concentration and discharge time,discharge voltage on chemical oxygen demand(COD)degradation rate.At the same time,the effect of pH and discharge time on the viscosity removal rate of PAM solution was also studied.Then,the effect of pH on the viscosity removal rate of 1.0g 1^-1 PAM solution was studied separately.Through orthogonal test,the factors affecting the COD degradation rate of PAM wastewater were determined as follows:discharge time>discharge voltage>solution concentration>wastewater initial pH.1'he COD highest removal rate of PAM wastewater reached 85.74%,when the optimal conditions are as follows:discharge voltage 40 kV,discharge time 5 h,solution concentration 1.0 g 1^-1,pH 1.5.This research provides some basic data and new theoretical basis for PAM wastewater purification.展开更多
1 INTRODUCTIONIn recent years,colloidal dispersion gel(CDG)have been attracting more and more in thefield of enhanced oil recovery on account of the cost-effectiveness and high efficiency ofblocking formation.Compared...1 INTRODUCTIONIn recent years,colloidal dispersion gel(CDG)have been attracting more and more in thefield of enhanced oil recovery on account of the cost-effectiveness and high efficiency ofblocking formation.Compared with bulk gel(BG),CDG exhibits lower polymer concentra-tion,undefined shape and selective blocking formation characteristics.The characteris-tics of CDG and BG are related to structure.In the bulk gel a continuous network of polymermolecules is formed predominant through intermolecular cross-linkages.The展开更多
A new kind of polyacrylamide derivate, hydroximic polyacrylamide (HPAM), was prepared from polyacrylamide (PAM) with hydroxylamine hydrochloride in KOH/alcohol solution. Based on colorimetric method in the measurement...A new kind of polyacrylamide derivate, hydroximic polyacrylamide (HPAM), was prepared from polyacrylamide (PAM) with hydroxylamine hydrochloride in KOH/alcohol solution. Based on colorimetric method in the measurement of C 7 9 alkyl hydroximic acid, the substitution degree of HPAM was determined by selecting octyl hydroximic acid as a primary standard substance. The effects of temperature, the amount of hydroxylamine and potassium hydroxide, and the reaction time on the reaction are discussed. HPAM with 5.78% substitution of degree was acquired by optimizing the reaction conditions. IR spectra revealed that tautomerism appears in the HPAM, and that HPAM exists in both the forms of hydroxamic type and hydroximic type, and the latter type can easily lead to the forming of intramolecular hydrogen bond.展开更多
This laboratory study examines the potential use of an anionic polyacrylamide(PAM)-based material as an environmentally sustainable additive for the stabilization of an expansive soil from South Australia.The experime...This laboratory study examines the potential use of an anionic polyacrylamide(PAM)-based material as an environmentally sustainable additive for the stabilization of an expansive soil from South Australia.The experimental program consisted of consistency limits,sediment volume,compaction and oedometer cyclic swell-shrink tests,performed using distilled water and four different PAM-to-water solutions of P_(D)=0.1 g/L,0.2 g/L,0.4 g/L and 0.6 g/L as the mixing liquids.Overall,the relative swelling and shrinkage strains were found to decrease with increasing number of applied swell-shrink cycles,with an‘elastic equilibrium’condition achieved on the conclusion of four cycles.The propensity for swelling/shrinkage potential reduction(for any given cycle)was found to be in favor of increasing the PAM dosage up to P_(D)=0.2 g/L,beyond which the excess PAM molecules self-associate as aggregates,thereby functioning as a lubricant instead of a flocculant;this critical dosage was termed‘maximum flocculation dosage’(MFD).The MFD assertion was discussed and validated using the consistency limits and sediment volume properties,both exhibiting only marginal variations beyond the identified MFD of P_(D)=0.2 g/L.The accumulated axial strain progressively transitioned from‘expansive’for the unamended soil to an ideal‘neutral’state at the MFD,while higher dosages demonstrated undesirable‘contractive’states.展开更多
Tetragonal zirconia (T-ZrO2) ceramic nanopowders stabilized with 3 mol% Y2O3 were synthesized via polyacrylamide gel method, using ZrOCl2?8H2O and Y(NO3)3?6H2O as raw materials. The effect of temperature on phase comp...Tetragonal zirconia (T-ZrO2) ceramic nanopowders stabilized with 3 mol% Y2O3 were synthesized via polyacrylamide gel method, using ZrOCl2?8H2O and Y(NO3)3?6H2O as raw materials. The effect of temperature on phase composition and morphology of YSZ nanopowders and sintering behavior of YSZ ceramics was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Vickers hardness tester. The aging-resistance of YSZ ceramics was measured by means of aging experiments. The results demonstrated that the phase composition of YSZ ceramic nanopowders had no obvious change and it was composed of T-ZrO2. Particle size of well-dispersed YSZ ceramic nanopowders increased from 17 to 35 nm with increasing calcining temperature from 600 to 800 ℃. There was noticeable negative correlation between calcining temperature and the relative density of YSZ ceramic at the same sintering temperature. The aging experiments showed that water vapor facilitated tetragonal to monoclinic phase transformation, and the sample that had smaller grain size exhibited better aging-resistance. It can be concluded that when the calcining temperature is 600 ℃ and sintering temperature is 1550 ℃, the relative density and hardness of YSZ ceramic arrive at the peak of 96.64% and 11.135 GPa respectively, and it has less microcracks and excellent aging-resistance.展开更多
Flocculation studies between dual polymers on pulp and paper mill wastewater are reported in this paper. The effects of different molecular weights of polyDADMAC and different dosages of Polyacrylamide (PAM) were stud...Flocculation studies between dual polymers on pulp and paper mill wastewater are reported in this paper. The effects of different molecular weights of polyDADMAC and different dosages of Polyacrylamide (PAM) were studied. The molecular weights of polyDADMAC used were 8.8×104, 10.5×104 and 15.7×104 g/mol. The flocculation performance was analyzed in jar tests with PolyDADMAC and Polyacrylamide dosages ranging from 0.4-2.0 mg/L﹣1 and 0.4-8.0 mg/L﹣1 respectively. A higher molecular weight and a 6.0 mg/L﹣1 dosagepolyDADMAC gave the highest level of flocculation based on turbidity and TSS removal. In addition, increasing the molecular weight of PolyDADMAC increased ζ potential values approaching zero. This indicated that polyDADMAC acts as a destabilizer. Based on TSS, the addition of PAM will improve the size of microflocs created by polyDADMAC. It demonstrates that PAM acts as a bridger between microflocs.展开更多
An understanding of nutrient movement in soil is important for developing management strategies to minimize nutrient leaching and surface movement, thus improving nutrient uptake by plants, maintaining a sustainable s...An understanding of nutrient movement in soil is important for developing management strategies to minimize nutrient leaching and surface movement, thus improving nutrient uptake by plants, maintaining a sustainable soil system, and even protecting groundwater quality. Polyacrylamide (PAM) is known as one of soil conditioner that functions to stabilize soil structure, increase infiltration, and reduce surface runoff. This study assesses the effects of PAM on the vertical movement of soil-water and major/minor nutrients (NO3-N, NH3-N, T-N, PO4-P, T-P, K, Ca, Mg, and Fe) in soils. Saturated hydraulic conductivity (Ksat) increases with increasing PAM concen- trations up to 10 mg·L-1 for sand and 20 mg·L-1 for a mixture of sand and clay. Decreases in the loss of soluble nutrients, particularly NH3-N, PO4-P and T-P, are observed as PAM concentrations increase. In contrast, PAM concentration has no effect on nitrate and minor nutrient levels. These results indicate that the application of PAM may be a viable method for protecting water bodies from excessive nutrients and improving nutrient availability for plants.展开更多
Surfactant-grafted Polyacrylamide (S-PAM) serves as a novel oil displacement agent in oilfield. Its toxicity and the impact on the occupational safety are unclear. The analysis on composition and chemical structure of...Surfactant-grafted Polyacrylamide (S-PAM) serves as a novel oil displacement agent in oilfield. Its toxicity and the impact on the occupational safety are unclear. The analysis on composition and chemical structure of S-PAM shows that due to its instability the harmful ammonia gas may be generated during the operation of S-PAM or high temperature. The toxicity and safety evaluation of the S-PAM were analyzed, and suggestions on the protection were proposed. It can provide a safe and healthy working environment for the operators with enormous social and economic benefits.展开更多
The selective water plugging agent was prepared by heating the blends of the polyacry-lamide inverse latex, modified urea formaldehyde resin, crosslinking agent and catalysts.The results show that using different type...The selective water plugging agent was prepared by heating the blends of the polyacry-lamide inverse latex, modified urea formaldehyde resin, crosslinking agent and catalysts.The results show that using different types of polymers and additives or changing in theirproportion of the blends, the gelling viscosity, starting point of gelling and other propertiesof the IPN can be controlled.展开更多
The effect of salt solutions(NaCl,Na2SO4 and CaCl2) on the conformational properties of partially hydrolyzed polyacrylamide(HPAM) was investigated by using static laser light scattering(SLLS).The special interaction b...The effect of salt solutions(NaCl,Na2SO4 and CaCl2) on the conformational properties of partially hydrolyzed polyacrylamide(HPAM) was investigated by using static laser light scattering(SLLS).The special interaction between CaCl2 solution and HPAM was also researched.Experimental results show that the chain structure of HPAM is interrelated with the charge density,the kind and the concentration of salt solutions.The mean-square radius of gyration(Rz) and the second virial coefficient(A2) of HPAM decrease with increasing concentration of salt solutions,and the salt effect tends towards the maximum when the concentration of salt solution is increased to some amount.展开更多
A new series of MR-IPN polyacrylamide—poly(vinyl-ethylenediamine)chelatesorbents were prepared by the reaction of ethylenediamine with MR-IPN matrixes.The newchelate sorbent showed good sorption properties for auric ...A new series of MR-IPN polyacrylamide—poly(vinyl-ethylenediamine)chelatesorbents were prepared by the reaction of ethylenediamine with MR-IPN matrixes.The newchelate sorbent showed good sorption properties for auric and platinic ions.展开更多
The viscoelastic behavior of polyacrylamide solution is crucial for its application in various industries.The mixed polyacrylamide solution was prepared by mixing polyacrylamide with different relative molecular masse...The viscoelastic behavior of polyacrylamide solution is crucial for its application in various industries.The mixed polyacrylamide solution was prepared by mixing polyacrylamide with different relative molecular masses according to the defined mass fraction.The viscosity and elasticity of mixed polyacrylamide solution were separately tested with RS150 rheometer and capillary breakup extensional rheometer and compared with those of the single polyacrylamide solution which is directly provided by manufacturer without any mixing.The results indicate that the mixed and single polyacrylamide solutions have the same shear viscosity and intrinsic viscosity.However,some mixed polyacrylamide solutions have higher elasticity than single polyacrylamide solution.The flow resistance of mixed polyacrylamide with higher elasticity is also greater than that of single polyacrylamide solution in porous medium.This paper presents an effective method of mixing polyacrylamides with different relative molecular masses,which can enhance the elasticity of polyacrylamide solution and flowing resistance through porous medium.展开更多
The effects of thermal history on the rheological properties of partially hydrolyzed polyacrylamide/ sodium dodecyl sulfate complex aqueous solutions have been studied using both steady shear and dynamic temperature s...The effects of thermal history on the rheological properties of partially hydrolyzed polyacrylamide/ sodium dodecyl sulfate complex aqueous solutions have been studied using both steady shear and dynamic temperature sweep characterizations. An abnormal rheological behavior was found that dynamic moduli of the aqueous solutions increased, while the viscosity decreased after thermal treatment, which could help to gain insight into the micro-phase evolution of the polymer/surfactant complex aqueous solutions and its dependence on temperature.展开更多
The characteristics of soil treated with cationic polyacrylamide(CPAM)mass content of 0%,0.2%,0.4%,0.6%,0.8%,and 1%were investigated through a series of laboratory tests to explore the practical engineering effect of ...The characteristics of soil treated with cationic polyacrylamide(CPAM)mass content of 0%,0.2%,0.4%,0.6%,0.8%,and 1%were investigated through a series of laboratory tests to explore the practical engineering effect of an expansive soil amended with environmental protection material CPAM.The results indicate that with the increasing CPAM content,the liquid limit and plasticity index of soil decrease,the plastic limit increases,and the free swelling ratio and loaded swelling ratio decrease.Besides,the improved soil has less disintegrating property and better water stability.The shear strength increases as the content increases,and the optimal content is 0.6%.Meanwhile,the cohesion of the soil first increases and then decreases,and the internal friction angle increases.Additionally,the unconfined compressive strength first increases and then decreases.The improved soil presents the characteristics of brittle failure and reaches the peak value(410.1 kPa)at the content of 0.8%after curing for 14 days.Scanning electron microscope(SEM)exhibits that the number of curved and wrinkled sections of the expansive soil is reduced after CPAM improvement.Simultaneously,the arrangement of the superimposed polymer changes from face-face to side-angle or side-face-angle,and the reticular structure formed improves the strength and spatial stability of the soil.Therefore,adding appropriate cationic polyacrylamide could improve expansive soil in engineering.展开更多
The kinetics of ultrasonic degradation of aqueous solution of polyacrylamide（PAM）and poly（ethyleneoxide）（PEO）as well as ultrasonic block copolymerization of aqueous solution of the mixture of PAM/PEOwere studied...The kinetics of ultrasonic degradation of aqueous solution of polyacrylamide（PAM）and poly（ethyleneoxide）（PEO）as well as ultrasonic block copolymerization of aqueous solution of the mixture of PAM/PEOwere studied respectively.The degradation reaction of PEO follows a linear relationship between（P1-P∞）-1and irradiation time,while that of PAM follows a linear relationship between（P1-P∞）-1/2and irradiation time.The structure of the copolymer was identified by IR,NMR and DTA,and the copolymer prepared is a blockone.The copolymer formed by irradiating 1% aqueous solution of PEO/PAM mixture（1:1）for a period of40min.at 18.2 kHz with a sonic intensity corresponding to 2.OA input current on the reversed main circuitamounts to 61.8%.展开更多
In this study, Nitrogen leaching following surface application of biosolid with and without polyacrylamide (PAM) coating was investigated using soil column experiments. Three treatments including bare soil (C), a comm...In this study, Nitrogen leaching following surface application of biosolid with and without polyacrylamide (PAM) coating was investigated using soil column experiments. Three treatments including bare soil (C), a commercially available biosolid (BS) and PAM coated biosolid (PAM + BS), were applied to manually packed (bulk density: 1.3 g·cm-3) growth chamber soil columns (GC columns: 5 cm diameter by 40 cm long) and greenhouse soil columns (GH columns: 15 cm diameter by 40 cm long). The application rates for BS and PAM + BS were 729 and 740 kg/ha, respectively. The GC columns were incubated for 60 days in a dark chamber at 25℃ and no crop was grown in the columns. The GH columns were incubated for 60 days in a greenhouse and Ryegrass (seed rate: 252 kg/ha) was grown in these columns under 16 h daylight and at about 25℃. The columns were irrigated weekly using 270 mL DI-water for GC columns and 850 mL for GH columns and leachate was analyzed for Ammonium (NH4-N), Nitrate (NO3-N) and total Nitrogen (TN). The GH column experiments were repeated with three times greater biosolid application rate (2187 kg/ha) while keeping the PAM and Ryegrass seed rate constant. The leachate volume and NH4-N, NO3-N and TN concentration/load were not significantly different among the treatments for the GH columns but were significantly different during the incubation period. The same was true for GC columns with the exception of NO3-N and TN concentration/load which, overall, were higher for the BS and PAM + BS treatments than for the C treatment. In the beginning of the incubation, the leachate from all treatments (GC and GH) contained the highest NH4-N concentrations (>USEPA target level: 0.1 mg/L) and decreased, in some cases rapidly, to near zero. The NO3-N concentrations were highest in the middle of the incubation and greater than the USEPA target level (10 mg/L). The NO3-N concentrations were lower for cropped GH columns compared to GC columns due to NO3-N uptake by plants. The three fold increase in biosolid application rate did not increase NH4-N concentrations in leachate but did increase NO3-N and TN concentrations/loads in leachate on average 2.5 to 2.7 times. The non-significant differences among treatment means for NH4-N, NO3-N and TN concentrations/loads for the GH columns suggest that land application of biosolid (with or without PAM) to cropped silt loam landscapes at the rates considered may be safe within the context of groundwater pollution.展开更多
基金Funded by the National Natural Science Foundation of China(No.51778378)the Natural Science Foundation of Hebei Province(No.E2022210103)。
文摘The polyacrylamide which is directly added into concrete shows strong water absorption property.Thus the construction of underwater constructure would demand high amount of water,resulting in poor workability of concrete and strength shrinkage after hardening.Herein,a kind of anionic polyacrylamide(APAM)grafted with water reducing functional group(-COOH)was synthesized at low temperatures by partial factor design and response surface design.The structure and morphology of APAM were characterized by UV,FTIR and SEM methods.The experimental results show that the molecular weight of the synthesized APAM could reach 11 million,under the condition that the temperature was 35℃,the pH value was 8,the monomer concentration was 27wt%,the initiator dosage was 0.6wt%,and the monomer ratio(n(AM):n(AA))was 3.When the APAM was applied into the underwater slurry,it presented good flocculation and low water demand.When the dosage was 1%of the mass of the cement,the water demand increased by 12%,which could meet the self-leveling and anti-dispersity of the underwater slurry at the same time.This technology provides technical guidance for the large-scale industrial production of polyacrylamide for underwater concrete construction while achieving environmental protection during production.
基金the Northeast Petroleum University Youth Science Foundation (No. 2019QNL-35)Guiding Science and Technology Plan Project of Daqing (No. zd-2021-39)。
文摘The degradation of partially hydrolyzed polyacrylamide(HPAM) found in alkaline/surfactant/polymer flooding sewage was investigated using Fenton-type reagents. Different Fenton reagent treatments for HPAM degradation were compared. The effects of pH, hydrogen peroxide(H_(2)O_(2)), ferrous ion(Fe^(2+)), and tartaric ion(C_(4)H_(4)O_(6)^(2-)) concentrations were studied. The degradation reaction occurred within a wide range of pH(3–9). The HPAM degradation performance of photo-Fenton processes using solar light and UV were compared with that of the Fenton process. The degradation rate was found to be strongly dependent on the H_(2)O_(2)/Fe^(2+)/C_(4)H_(4)O_(6)^(2-)molar ratio. The HPAM degradation efficiency was 90%, and the chemical oxygen demand removal efficiency was 85%. HPAM could be degraded into a compound with a lower molecular weight, but it was difficult to achieve complete mineralization to CO_(2). The presence of intermediate products hindered further oxidation in the Fenton process.
文摘Once a popular injectable filler,polyacrylamide hydrogel(PAAG)has been banned in China since 2006 due to its unclear safety and long-term complications.However,it is still being used worldwide because of its huge commercial profit,leading to emerging complications and an urgent need for standardized clinical management.This review aimed to assess the properties,safety,and complications of PAAG and treatment strategies for its removal.
基金supported by Anhui University of Science and Technology Youth Fund(No.QN201415)Anhui Province Science and Technology Key Project(No.1301042130)College Students’ Innovation and Entrepreneurship Training Program(No.201810361079)
文摘In this work,non-thermal plasma has been applied to treat polyacrylamide(PAM)wastewater.We have investigated the in fluence of the rule of PAM wastewater initial pH,solution concentration and discharge time,discharge voltage on chemical oxygen demand(COD)degradation rate.At the same time,the effect of pH and discharge time on the viscosity removal rate of PAM solution was also studied.Then,the effect of pH on the viscosity removal rate of 1.0g 1^-1 PAM solution was studied separately.Through orthogonal test,the factors affecting the COD degradation rate of PAM wastewater were determined as follows:discharge time>discharge voltage>solution concentration>wastewater initial pH.1'he COD highest removal rate of PAM wastewater reached 85.74%,when the optimal conditions are as follows:discharge voltage 40 kV,discharge time 5 h,solution concentration 1.0 g 1^-1,pH 1.5.This research provides some basic data and new theoretical basis for PAM wastewater purification.
文摘1 INTRODUCTIONIn recent years,colloidal dispersion gel(CDG)have been attracting more and more in thefield of enhanced oil recovery on account of the cost-effectiveness and high efficiency ofblocking formation.Compared with bulk gel(BG),CDG exhibits lower polymer concentra-tion,undefined shape and selective blocking formation characteristics.The characteris-tics of CDG and BG are related to structure.In the bulk gel a continuous network of polymermolecules is formed predominant through intermolecular cross-linkages.The
文摘A new kind of polyacrylamide derivate, hydroximic polyacrylamide (HPAM), was prepared from polyacrylamide (PAM) with hydroxylamine hydrochloride in KOH/alcohol solution. Based on colorimetric method in the measurement of C 7 9 alkyl hydroximic acid, the substitution degree of HPAM was determined by selecting octyl hydroximic acid as a primary standard substance. The effects of temperature, the amount of hydroxylamine and potassium hydroxide, and the reaction time on the reaction are discussed. HPAM with 5.78% substitution of degree was acquired by optimizing the reaction conditions. IR spectra revealed that tautomerism appears in the HPAM, and that HPAM exists in both the forms of hydroxamic type and hydroximic type, and the latter type can easily lead to the forming of intramolecular hydrogen bond.
基金funded by the Australian Research Council(ARC),Project No.DP140103004。
文摘This laboratory study examines the potential use of an anionic polyacrylamide(PAM)-based material as an environmentally sustainable additive for the stabilization of an expansive soil from South Australia.The experimental program consisted of consistency limits,sediment volume,compaction and oedometer cyclic swell-shrink tests,performed using distilled water and four different PAM-to-water solutions of P_(D)=0.1 g/L,0.2 g/L,0.4 g/L and 0.6 g/L as the mixing liquids.Overall,the relative swelling and shrinkage strains were found to decrease with increasing number of applied swell-shrink cycles,with an‘elastic equilibrium’condition achieved on the conclusion of four cycles.The propensity for swelling/shrinkage potential reduction(for any given cycle)was found to be in favor of increasing the PAM dosage up to P_(D)=0.2 g/L,beyond which the excess PAM molecules self-associate as aggregates,thereby functioning as a lubricant instead of a flocculant;this critical dosage was termed‘maximum flocculation dosage’(MFD).The MFD assertion was discussed and validated using the consistency limits and sediment volume properties,both exhibiting only marginal variations beyond the identified MFD of P_(D)=0.2 g/L.The accumulated axial strain progressively transitioned from‘expansive’for the unamended soil to an ideal‘neutral’state at the MFD,while higher dosages demonstrated undesirable‘contractive’states.
基金Funded by the National Natural Science Foundation of China(No.51964035)the Natural Science Foundation of Inner Mongolia Autonomous Region(No.2019MS0520)。
文摘Tetragonal zirconia (T-ZrO2) ceramic nanopowders stabilized with 3 mol% Y2O3 were synthesized via polyacrylamide gel method, using ZrOCl2?8H2O and Y(NO3)3?6H2O as raw materials. The effect of temperature on phase composition and morphology of YSZ nanopowders and sintering behavior of YSZ ceramics was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and Vickers hardness tester. The aging-resistance of YSZ ceramics was measured by means of aging experiments. The results demonstrated that the phase composition of YSZ ceramic nanopowders had no obvious change and it was composed of T-ZrO2. Particle size of well-dispersed YSZ ceramic nanopowders increased from 17 to 35 nm with increasing calcining temperature from 600 to 800 ℃. There was noticeable negative correlation between calcining temperature and the relative density of YSZ ceramic at the same sintering temperature. The aging experiments showed that water vapor facilitated tetragonal to monoclinic phase transformation, and the sample that had smaller grain size exhibited better aging-resistance. It can be concluded that when the calcining temperature is 600 ℃ and sintering temperature is 1550 ℃, the relative density and hardness of YSZ ceramic arrive at the peak of 96.64% and 11.135 GPa respectively, and it has less microcracks and excellent aging-resistance.
文摘Flocculation studies between dual polymers on pulp and paper mill wastewater are reported in this paper. The effects of different molecular weights of polyDADMAC and different dosages of Polyacrylamide (PAM) were studied. The molecular weights of polyDADMAC used were 8.8×104, 10.5×104 and 15.7×104 g/mol. The flocculation performance was analyzed in jar tests with PolyDADMAC and Polyacrylamide dosages ranging from 0.4-2.0 mg/L﹣1 and 0.4-8.0 mg/L﹣1 respectively. A higher molecular weight and a 6.0 mg/L﹣1 dosagepolyDADMAC gave the highest level of flocculation based on turbidity and TSS removal. In addition, increasing the molecular weight of PolyDADMAC increased ζ potential values approaching zero. This indicated that polyDADMAC acts as a destabilizer. Based on TSS, the addition of PAM will improve the size of microflocs created by polyDADMAC. It demonstrates that PAM acts as a bridger between microflocs.
文摘An understanding of nutrient movement in soil is important for developing management strategies to minimize nutrient leaching and surface movement, thus improving nutrient uptake by plants, maintaining a sustainable soil system, and even protecting groundwater quality. Polyacrylamide (PAM) is known as one of soil conditioner that functions to stabilize soil structure, increase infiltration, and reduce surface runoff. This study assesses the effects of PAM on the vertical movement of soil-water and major/minor nutrients (NO3-N, NH3-N, T-N, PO4-P, T-P, K, Ca, Mg, and Fe) in soils. Saturated hydraulic conductivity (Ksat) increases with increasing PAM concen- trations up to 10 mg·L-1 for sand and 20 mg·L-1 for a mixture of sand and clay. Decreases in the loss of soluble nutrients, particularly NH3-N, PO4-P and T-P, are observed as PAM concentrations increase. In contrast, PAM concentration has no effect on nitrate and minor nutrient levels. These results indicate that the application of PAM may be a viable method for protecting water bodies from excessive nutrients and improving nutrient availability for plants.
文摘Surfactant-grafted Polyacrylamide (S-PAM) serves as a novel oil displacement agent in oilfield. Its toxicity and the impact on the occupational safety are unclear. The analysis on composition and chemical structure of S-PAM shows that due to its instability the harmful ammonia gas may be generated during the operation of S-PAM or high temperature. The toxicity and safety evaluation of the S-PAM were analyzed, and suggestions on the protection were proposed. It can provide a safe and healthy working environment for the operators with enormous social and economic benefits.
文摘The selective water plugging agent was prepared by heating the blends of the polyacry-lamide inverse latex, modified urea formaldehyde resin, crosslinking agent and catalysts.The results show that using different types of polymers and additives or changing in theirproportion of the blends, the gelling viscosity, starting point of gelling and other propertiesof the IPN can be controlled.
基金Project(50673033) supported by the National Natural Science Foundation of China
文摘The effect of salt solutions(NaCl,Na2SO4 and CaCl2) on the conformational properties of partially hydrolyzed polyacrylamide(HPAM) was investigated by using static laser light scattering(SLLS).The special interaction between CaCl2 solution and HPAM was also researched.Experimental results show that the chain structure of HPAM is interrelated with the charge density,the kind and the concentration of salt solutions.The mean-square radius of gyration(Rz) and the second virial coefficient(A2) of HPAM decrease with increasing concentration of salt solutions,and the salt effect tends towards the maximum when the concentration of salt solution is increased to some amount.
文摘A new series of MR-IPN polyacrylamide—poly(vinyl-ethylenediamine)chelatesorbents were prepared by the reaction of ethylenediamine with MR-IPN matrixes.The newchelate sorbent showed good sorption properties for auric and platinic ions.
文摘The viscoelastic behavior of polyacrylamide solution is crucial for its application in various industries.The mixed polyacrylamide solution was prepared by mixing polyacrylamide with different relative molecular masses according to the defined mass fraction.The viscosity and elasticity of mixed polyacrylamide solution were separately tested with RS150 rheometer and capillary breakup extensional rheometer and compared with those of the single polyacrylamide solution which is directly provided by manufacturer without any mixing.The results indicate that the mixed and single polyacrylamide solutions have the same shear viscosity and intrinsic viscosity.However,some mixed polyacrylamide solutions have higher elasticity than single polyacrylamide solution.The flow resistance of mixed polyacrylamide with higher elasticity is also greater than that of single polyacrylamide solution in porous medium.This paper presents an effective method of mixing polyacrylamides with different relative molecular masses,which can enhance the elasticity of polyacrylamide solution and flowing resistance through porous medium.
基金This work was supported by 973 Project "Fundamental Study on Enhanced Oil Recovery"(G1999022500).
文摘The effects of thermal history on the rheological properties of partially hydrolyzed polyacrylamide/ sodium dodecyl sulfate complex aqueous solutions have been studied using both steady shear and dynamic temperature sweep characterizations. An abnormal rheological behavior was found that dynamic moduli of the aqueous solutions increased, while the viscosity decreased after thermal treatment, which could help to gain insight into the micro-phase evolution of the polymer/surfactant complex aqueous solutions and its dependence on temperature.
基金funded by the National Natural Science Foundation of China(41977236,41672278,41271071)the Science and Technology Planning Project of Housing and Urban-Rural Development of Anhui Province(2019-YF023)+1 种基金the Major Universities Natural Science Research Project in Anhui Province(KJ2016SD19)the Natural Science Foundation of Jiangxi Province(2019ACBL20002).
文摘The characteristics of soil treated with cationic polyacrylamide(CPAM)mass content of 0%,0.2%,0.4%,0.6%,0.8%,and 1%were investigated through a series of laboratory tests to explore the practical engineering effect of an expansive soil amended with environmental protection material CPAM.The results indicate that with the increasing CPAM content,the liquid limit and plasticity index of soil decrease,the plastic limit increases,and the free swelling ratio and loaded swelling ratio decrease.Besides,the improved soil has less disintegrating property and better water stability.The shear strength increases as the content increases,and the optimal content is 0.6%.Meanwhile,the cohesion of the soil first increases and then decreases,and the internal friction angle increases.Additionally,the unconfined compressive strength first increases and then decreases.The improved soil presents the characteristics of brittle failure and reaches the peak value(410.1 kPa)at the content of 0.8%after curing for 14 days.Scanning electron microscope(SEM)exhibits that the number of curved and wrinkled sections of the expansive soil is reduced after CPAM improvement.Simultaneously,the arrangement of the superimposed polymer changes from face-face to side-angle or side-face-angle,and the reticular structure formed improves the strength and spatial stability of the soil.Therefore,adding appropriate cationic polyacrylamide could improve expansive soil in engineering.
文摘The kinetics of ultrasonic degradation of aqueous solution of polyacrylamide（PAM）and poly（ethyleneoxide）（PEO）as well as ultrasonic block copolymerization of aqueous solution of the mixture of PAM/PEOwere studied respectively.The degradation reaction of PEO follows a linear relationship between（P1-P∞）-1and irradiation time,while that of PAM follows a linear relationship between（P1-P∞）-1/2and irradiation time.The structure of the copolymer was identified by IR,NMR and DTA,and the copolymer prepared is a blockone.The copolymer formed by irradiating 1% aqueous solution of PEO/PAM mixture（1:1）for a period of40min.at 18.2 kHz with a sonic intensity corresponding to 2.OA input current on the reversed main circuitamounts to 61.8%.
文摘In this study, Nitrogen leaching following surface application of biosolid with and without polyacrylamide (PAM) coating was investigated using soil column experiments. Three treatments including bare soil (C), a commercially available biosolid (BS) and PAM coated biosolid (PAM + BS), were applied to manually packed (bulk density: 1.3 g·cm-3) growth chamber soil columns (GC columns: 5 cm diameter by 40 cm long) and greenhouse soil columns (GH columns: 15 cm diameter by 40 cm long). The application rates for BS and PAM + BS were 729 and 740 kg/ha, respectively. The GC columns were incubated for 60 days in a dark chamber at 25℃ and no crop was grown in the columns. The GH columns were incubated for 60 days in a greenhouse and Ryegrass (seed rate: 252 kg/ha) was grown in these columns under 16 h daylight and at about 25℃. The columns were irrigated weekly using 270 mL DI-water for GC columns and 850 mL for GH columns and leachate was analyzed for Ammonium (NH4-N), Nitrate (NO3-N) and total Nitrogen (TN). The GH column experiments were repeated with three times greater biosolid application rate (2187 kg/ha) while keeping the PAM and Ryegrass seed rate constant. The leachate volume and NH4-N, NO3-N and TN concentration/load were not significantly different among the treatments for the GH columns but were significantly different during the incubation period. The same was true for GC columns with the exception of NO3-N and TN concentration/load which, overall, were higher for the BS and PAM + BS treatments than for the C treatment. In the beginning of the incubation, the leachate from all treatments (GC and GH) contained the highest NH4-N concentrations (>USEPA target level: 0.1 mg/L) and decreased, in some cases rapidly, to near zero. The NO3-N concentrations were highest in the middle of the incubation and greater than the USEPA target level (10 mg/L). The NO3-N concentrations were lower for cropped GH columns compared to GC columns due to NO3-N uptake by plants. The three fold increase in biosolid application rate did not increase NH4-N concentrations in leachate but did increase NO3-N and TN concentrations/loads in leachate on average 2.5 to 2.7 times. The non-significant differences among treatment means for NH4-N, NO3-N and TN concentrations/loads for the GH columns suggest that land application of biosolid (with or without PAM) to cropped silt loam landscapes at the rates considered may be safe within the context of groundwater pollution.
