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Synthetic polymers:A review of applications in drilling fluids 被引量:2
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作者 Shadfar Davoodi Mohammed Al-Shargabi +2 位作者 David A.Wood Valeriy S.Rukavishnikov Konstantin M.Minaev 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期475-518,共44页
With the growth of deep drilling and the complexity of the well profile,the requirements for a more complete and efficient exploitation of productive formations increase,which increases the risk of various complicatio... With the growth of deep drilling and the complexity of the well profile,the requirements for a more complete and efficient exploitation of productive formations increase,which increases the risk of various complications.Currently,reagents based on modified natural polymers(which are naturally occurring compounds)and synthetic polymers(SPs)which are polymeric compounds created industrially,are widely used to prevent emerging complications in the drilling process.However,compared to modified natural polymers,SPs form a family of high-molecular-weight compounds that are fully synthesized by undergoing chemical polymerization reactions.SPs provide substantial flexibility in their design.Moreover,their size and chemical composition can be adjusted to provide properties for nearly all the functional objectives of drilling fluids.They can be classified based on chemical ingredients,type of reaction,and their responses to heating.However,some of SPs,due to their structural characteristics,have a high cost,a poor temperature and salt resistance in drilling fluids,and degradation begins when the temperature reaches 130℃.These drawbacks prevent SP use in some medium and deep wells.Thus,this review addresses the historical development,the characteristics,manufacturing methods,classification,and the applications of SPs in drilling fluids.The contributions of SPs as additives to drilling fluids to enhance rheology,filtrate generation,carrying of cuttings,fluid lubricity,and clay/shale stability are explained in detail.The mechanisms,impacts,and advances achieved when SPs are added to drilling fluids are also described.The typical challenges encountered by SPs when deployed in drilling fluids and their advantages and drawbacks are also discussed.Economic issues also impact the applications of SPs in drilling fluids.Consequently,the cost of the most relevant SPs,and the monomers used in their synthesis,are assessed.Environmental impacts of SPs when deployed in drilling fluids,and their manufacturing processes are identified,together with advances in SP-treatment methods aimed at reducing those impacts.Recommendations for required future research addressing SP property and performance gaps are provided. 展开更多
关键词 Synthetic versus natural polymers Nanopolymers drilling fluid additives LUBRICITY Clay swelling Hole cleaning
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The Conversion of Non-Dispersed Polymers into Low-Potassium Anti-Collapse Drilling Fluids
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作者 Hao Hu Jian Guan +2 位作者 Shanfa Tang Jialuo Rong Yuanpeng Cheng 《Fluid Dynamics & Materials Processing》 EI 2024年第2期325-335,共11页
Different drillingfluid systems are designed according to mineral composition,lithology and wellbore stability of different strata.In the present study,the conversion of a non-dispersed polymer drillingfluid into a low ... Different drillingfluid systems are designed according to mineral composition,lithology and wellbore stability of different strata.In the present study,the conversion of a non-dispersed polymer drillingfluid into a low potas-sium anti-collapsing drillingfluid is investigated.Since the two drillingfluids belong to completely different types,the key to this conversion is represented by new inhibitors,dispersants and water-loss agents by which a non-dispersed drillingfluid can be turned into a dispersed drillingfluid while ensuring wellbore stability and reason-able rheology(carrying sand—inhibiting cuttings dispersion).In particular,the(QYZ-1)inhibitors and(FSJSS-2)dispersants are used.The former can inhibit the hydration expansion capacity of clay,reduce the dynamic shear force and weaken the viscosity;the latter can improve the sealing effect and reduce thefiltrate loss.The results have shown that after adding a reasonable proportion of these substances(QYZ-1:FSJSS-2)to the non-dispersed polymer drillingfluid,while the apparent viscosity,plastic viscosity,structural viscosity andfluidity index under-went almost negligible changes,the dynamic plastic ratio increased,and thefiltration loss decreased significantly,thereby indicating good compatibility.According to the tests(conducted in the Leijia area),the density was 1.293 g/cm3,and after standing for 24 h,the SF(static settlement factor)was 0.51.Moreover,thefiltration loss was reduced to 4.0 mL,the rolling recovery rate reached 96.92%,with excellent plugging and anti-collapse performances. 展开更多
关键词 Non-dispersed polymer drilling fluid low potassium anti-collapsing drilling fluid drilling fluid conversion drilling fluid reuse filter vector
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Research progress and development of deep and ultra-deep drilling fluid technology
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作者 SUN Jinsheng YANG Jingbin +2 位作者 BAI Yingrui LYU Kaihe LIU Fengbao 《Petroleum Exploration and Development》 SCIE 2024年第4期1022-1034,共13页
The research progress of deep and ultra-deep drilling fluid technology systematically reviewed,the key problems existing are analyzed,and the future development direction is proposed.In view of the high temperature,hi... The research progress of deep and ultra-deep drilling fluid technology systematically reviewed,the key problems existing are analyzed,and the future development direction is proposed.In view of the high temperature,high pressure and high stress,fracture development,wellbore instability,drilling fluid lost circulation and other problems faced in the process of deep and ultra-deep complex oil and gas drilling,scholars have developed deep and ultra-deep high-temperature and high-salt resistant water-based drilling fluid technology,high-temperature resistant oil-based/synthetic drilling fluid technology,drilling fluid technology for reservoir protection and drilling fluid lost circulation control technology.However,there are still some key problems such as insufficient resistance to high temperature,high pressure and high stress,wellbore instability and serious lost circulation.Therefore,the development direction of deep and ultra-deep drilling fluid technology in the future is proposed:(1)The technology of high-temperature and high-salt resistant water-based drilling fluid should focus on improving high temperature stability,improving rheological properties,strengthening filtration control and improving compatibility with formation.(2)The technology of oil-based/synthetic drilling fluid resistant to high temperature should further study in the aspects of easily degradable environmental protection additives with low toxicity such as high temperature stabilizer,rheological regulator and related supporting technologies.(3)The drilling fluid technology for reservoir protection should be devoted to the development of new high-performance additives and materials,and further improve the real-time monitoring technology by introducing advanced sensor networks and artificial intelligence algorithms.(4)The lost circulation control of drilling fluid should pay more attention to the integration and application of intelligent technology,the research and application of high-performance plugging materials,the exploration of diversified plugging techniques and methods,and the improvement of environmental protection and production safety awareness. 展开更多
关键词 deep and ultra-deep drilling high temperature resistant drilling fluid reservoir protection drilling fluid lost circulation control safety and environmental protection technical prospects
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Formation damage mechanism and control strategy of the compound function of drilling fluid and fracturing fluid in shale reservoirs
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作者 SUN Jinsheng XU Chengyuan +6 位作者 KANG Yili JING Haoran ZHANG Jie YANG Bin YOU Lijun ZHANG Hanshi LONG Yifu 《Petroleum Exploration and Development》 SCIE 2024年第2期430-439,共10页
For the analysis of the formation damage caused by the compound function of drilling fluid and fracturing fluid,the prediction method for dynamic invasion depth of drilling fluid is developed considering the fracture ... For the analysis of the formation damage caused by the compound function of drilling fluid and fracturing fluid,the prediction method for dynamic invasion depth of drilling fluid is developed considering the fracture extension due to shale minerals erosion by oil-based drilling fluid.With the evaluation for the damage of natural and hydraulic fractures caused by mechanical properties weakening of shale fracture surface,fracture closure and rock powder blocking,the formation damage pattern is proposed with consideration of the compound effect of drilling fluid and fracturing fluid.The formation damage mechanism during drilling and completion process in shale reservoir is revealed,and the protection measures are raised.The drilling fluid can deeply invade into the shale formation through natural and induced fractures,erode shale minerals and weaken the mechanical properties of shale during the drilling process.In the process of hydraulic fracturing,the compound effect of drilling fluid and fracturing fluid further weakens the mechanical properties of shale,results in fracture closure and rock powder shedding,and thus induces stress-sensitive damage and solid blocking damage of natural/hydraulic fractures.The damage can yield significant conductivity decrease of fractures,and restrict the high and stable production of shale oil and gas wells.The measures of anti-collapse and anti-blocking to accelerate the drilling of reservoir section,forming chemical membrane to prevent the weakening of the mechanical properties of shale fracture surface,strengthening the plugging of shale fracture and reducing the invasion range of drilling fluid,optimizing fracturing fluid system to protect fracture conductivity are put forward for reservoir protection. 展开更多
关键词 shale oil and gas drilling fluid fracturing fluid stress-sensitive solid blocking formation damage reservoir protection
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Chemical modification of barite for improving the performance of weighting materials for water-based drilling fluids
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作者 Li-Li Yang Ze-Yu Liu +3 位作者 Shi-bo Wang Xian-Bo He Guan-Cheng Jiang Jie Zhang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第1期551-566,共16页
With increasing drilling depth and large dosage of weighting materials,drilling fluids with high solid content are characterized by poor stability,high viscosity,large water loss,and thick mud cake,easier leading to r... With increasing drilling depth and large dosage of weighting materials,drilling fluids with high solid content are characterized by poor stability,high viscosity,large water loss,and thick mud cake,easier leading to reservoir damage and wellbore instability.In this paper,micronized barite(MB)was modified(mMB)by grafting with hydrophilic polymer onto the surface through the free radical polymerization to displace conventional API barite partly.The suspension stability of water-based drilling fluids(WBDFs)weighted with API barite:mMB=2:1 in 600 g was significantly enhanced compared with that with API barite/WBDFs,exhibiting the static sag factor within 0.54 and the whole stability index of 2.The viscosity and yield point reached the minimum,with a reduction of more than 40%compared with API barite only at the same density.Through multi-stage filling and dense accumulation of weighting materials and clays,filtration loss was decreased,mud cake quality was improved,and simultaneously it had great reservoir protection performance,and the permeability recovery rate reached 87%.In addition,it also effectively improved the lubricity of WBDFs.The sticking coefficient of mud cake was reduced by 53.4%,and the friction coefficient was 0.2603.Therefore,mMB can serve as a versatile additive to control the density,rheology,filtration,and stability of WBDFs weighted with API barite,thus regulating comprehensive performance and achieving reservoir protection capacity.This work opened up a new path for the productive drilling of extremely deep and intricate wells by providing an efficient method for managing the performance of high-density WBDFs. 展开更多
关键词 drilling fluids Weighting materials Filtration control Reservoir protection Stability property
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A novel responsive stabilizing Janus nanosilica as a nanoplugging agent in water-based drilling fluids for exploiting hostile shale environments
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作者 Alain Pierre Tchameni Lv-Yan Zhuo +5 位作者 Lesly Dasilva Wandji Djouonkep Robert Dery Nagre Lu-Xin Chen Lin Zhao Chao Ma Bin-Qiang Xie 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1190-1210,共21页
Thermo-responsive nanocomposites have recently emerged as potential nanoplugging agents for shale stabilization in high-temperature water-based drilling fluids(WBDFs). However, their inhibitory properties have not bee... Thermo-responsive nanocomposites have recently emerged as potential nanoplugging agents for shale stabilization in high-temperature water-based drilling fluids(WBDFs). However, their inhibitory properties have not been very effective in high-temperature drilling operations. Thermo-responsive Janus nanocomposites are expected to strongly interact with clay particles from the inward hemisphere of nanomaterials, which drive the establishment of a tighter hydrophobic membrane over the shale surface at the outward hemisphere under geothermal conditions for shale stabilization. This work combines the synergistic benefits of thermo-responsive and zwitterionic nanomaterials to synchronously enhance the chemical inhibitions and plugging performances in shale under harsh conditions. A novel thermoresponsive Janus nanosilica(TRJS) exhibiting zwitterionic character was synthesized, characterized,and assessed as shale stabilizer for WBDFs at high temperatures. Compared to pristine nanosilica(Si NP)and symmetrical thermo-responsive nanosilica(TRS), TRJS exhibited anti-polyelectrolyte behaviour, in which electrolyte ions screened the electrostatic attraction between the charged particles, potentially stabilizing nanomaterial in hostile shaly environments(i.e., up to saturated brine or API brine). Macroscopically, TRJS exhibited higher chemical inhibition than Si NP and TRS in brine, prompting a better capability to control pressure penetration. TRJS adsorbed onto the clay surface via chemisorption and hydrogen bonding, and the interactions became substantial in brine, according to the results of electrophoretic mobility, surface wettability, and X-ray diffraction. Thus, contributing to the firm trapping of TRJS into the nanopore structure of the shale, triggering the formation of a tight hydrophobic membrane over the shale surface from the outward hemisphere. The addition of TRJS into WBDF had no deleterious effect on fluid properties after hot-treatment at 190℃, implying that TRJS could find potential use as a shale stabilizer in WBDFs in hostile environments. 展开更多
关键词 Janus nanosilica Thermo-responsive copolymer Anti-polyelectrolyte effect Shale stabilizer Inhibition Plugging drilling fluid
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Natural rubber latex as a potential additive for water-based drilling fluids
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作者 Jun Yang Guan-Cheng Jiang +4 位作者 Jing-Tian Yi Yin-Bo He Li-Li Yang Teng-Fei Dong Guo-Shuai Wang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第4期2677-2687,共11页
The environmental hazards and"carbon footprint"of oil and gas drilling can be significantly reduced by replacing traditional petroleum-based chemical additives with natural materials derived from plants and ... The environmental hazards and"carbon footprint"of oil and gas drilling can be significantly reduced by replacing traditional petroleum-based chemical additives with natural materials derived from plants and animals.This paper explored for the first time the interaction mechanism between natural rubber latex(NRL)and bentonite suspensions(BTs)through a series of characterization experiments,as well as the potential applications in water-based drilling fluids(WBDF).The gel viscoelasticity experiments showed that NRL could decrease the consistency coefficient(k)and flow index(n)of BTs,and enhance the shear thinning performance of BTs as pseudo-plastic fluids.In addition,0.5 w/v%NRL not only increased the critical yield stress and strengthened the structural strength between the bentonite particles,but also facilitated the compatibility of pressure loss and flow efficiency.The evaluation of colloidal stability and WBDF performance indicated that NRL particles could promote the hydration and charge stability on the surface of BTs particles,and optimize the particle size distribution and flow resistance of WBDF under the"intercalation-exfoliation-encapsulation"synergistic interaction.Moreover,NRL can improve the rheological properties of WBDF at high temperatures(<150.C),and form a dense blocking layer by bridging and sealing the pores and cracks of the filter cake,which ultimately reduces the permeability of the cake and the filtration loss of WBDF. 展开更多
关键词 Natural materials Water-based drilling fluids Natural rubber latex Bentonite suspensions Filtration loss
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Research on the Method of Heat Preservation and Heating for the Drilling System of Polar Offshore Drilling Platform
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作者 Yingkai Dong Chaohe Chen +2 位作者 Guangyan Jia Lidai Wang Jian Bai 《Energy Engineering》 EI 2024年第5期1173-1193,共21页
This study investigates the heat dissipation mechanism of the insulation layer and other plane insulation layers in the polar drilling rig system.Combining the basic theory of heat transfer with the environmental requ... This study investigates the heat dissipation mechanism of the insulation layer and other plane insulation layers in the polar drilling rig system.Combining the basic theory of heat transfer with the environmental requirements of polar drilling operations and the characteristics of polar drilling processes,we analyze the factors that affect the insulation effect of the drilling rig system.These factors include the thermal conductivity of the insulation material,the thickness of the insulation layer,ambient temperature,and wind speed.We optimize the thermal insulation material of the polar drilling rig system using a steady-state method to measure solid thermal conductivity.By analyzing the distribution of temperature in space after heating,we optimize the distribution and air outlet angle of the heater using Fluent hydrodynamics software.The results demonstrate that under polar conditions,polyisocyanurate with stable thermodynamic properties is selected as the thermal insulation material.The selection of thermal insulation material and thickness significantly affects the thermal insulation effect of the system but has little effect on its heating effect.Moreover,when the air outlet angle of the heater is set to 32.5°,the heating efficiency of the system can be effectively improved.According to heat transfer equations and heat balance theory,we determine that the heating power required for the system to reach 5°C is close to numerical simulation. 展开更多
关键词 Polar drilling drilling system fluid dynamics heat preservation and heating numerical simulation
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Improving the anti-collapse performance of water-based drilling fluids of Xinjiang Oilfield using hydrophobically modified silica nanoparticles with cationic surfactants 被引量:2
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作者 He Li Xian-Bin Huang +3 位作者 Jin-Sheng Sun Kai-He Lv Xu Meng Zhen Zhang 《Petroleum Science》 SCIE EI CAS CSCD 2023年第3期1768-1778,共11页
Wellbore instability,especially drilling with water-based drilling fluids(WBDFs)in complex shale for-mations,is a critical challenge for oil and gas development.The purpose of this paper is to study the feasibility of... Wellbore instability,especially drilling with water-based drilling fluids(WBDFs)in complex shale for-mations,is a critical challenge for oil and gas development.The purpose of this paper is to study the feasibility of using hydrophobically modified silica nanoparticle(HMN)to enhance the comprehensive performance of WBDFs in the Xinjiang Oilfield,especially the anti-collapse performance.The effect of HMN on the overall performance of WBDFs in the Xinjiang Oilfield,including inhibition,plugging,lu-bricity,rheology,and filtration loss,was studied with a series of experiments.The mechanism of HMN action was studied by analyzing the changes of shale surface structure and chemical groups,wettability,and capillary force.The experimental results showed that HMN could improve the performance of WBDFs in the Xinjiang Oilfeld to inhibit the hydration swelling and dispersion of shale.The plugging and lubrication performance of the WBDFs in the Xinjiang Oilfield were also enhanced with HMN based on the experimental results.HMN had less impact on the rheological and filtration performance of the WBDFs in the Xinjiang Oilfield.In addition,HMN significantly prevented the decrease of shale strength.The potential mechanism of HMN was as follows.The chemical composition and structure of the shale surface were altered due to the adsorption of HMN driven by electrostatic attraction.Changes of the shale surface resulted in significant wettability transition.The capillary force of the shale was converted from a driving force of water into the interior to a resistance.In summary,hydrophobic nanoparticles presented afavorable application potential for WBDFs. 展开更多
关键词 Hydrophobic nanoparticle Wetting alteration Wellbore stability Water-based drilling fluids SHALE
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A high-temperature resistant and high-density polymeric saturated brine-based drilling fluid 被引量:1
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作者 HUANG Xianbin SUN Jinsheng +3 位作者 LYU Kaihe DONG Xiaodong LIU Fengbao GAO Chongyang 《Petroleum Exploration and Development》 SCIE 2023年第5期1215-1224,共10页
Three high-temperature resistant polymeric additives for water-based drilling fluids are designed and developed:weakly cross-linked zwitterionic polymer fluid loss reducer(WCZ),flexible polymer microsphere nano-pluggi... Three high-temperature resistant polymeric additives for water-based drilling fluids are designed and developed:weakly cross-linked zwitterionic polymer fluid loss reducer(WCZ),flexible polymer microsphere nano-plugging agent(FPM)and comb-structure polymeric lubricant(CSP).A high-temperature resistant and high-density polymeric saturated brine-based drilling fluid was developed for deep drilling.The WCZ has a good anti-polyelectrolyte effect and exhibits the API fluid loss less than 8 mL after aging in saturated salt environment at 200°C.The FPM can reduce the fluid loss by improving the quality of the mud cake and has a good plugging effect on nano-scale pores/fractures.The CSP,with a weight average molecular weight of 4804,has multiple polar adsorption sites and exhibits excellent lubricating performance under high temperature and high salt conditions.The developed drilling fluid system with a density of 2.0 g/cm^(3)has good rheological properties.It shows a fluid loss less than 15 mL at 200°C and high pressure,a sedimentation factor(SF)smaller than 0.52 after standing at high temperature for 5 d,and a rolling recovery of hydratable drill cuttings similar to oil-based drilling fluid.Besides,it has good plugging and lubricating performance. 展开更多
关键词 deep drilling saturated brine-based drilling fluid high-temperature resistant additive water-based drilling fluid rheological property plugging performance lubricating performance
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Performance Analysis of a Profile Control Agent for Waste Drilling Fluid Treatment
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作者 Xueyu Zhao 《Fluid Dynamics & Materials Processing》 EI 2023年第7期1897-1905,共9页
A method for the treatment of hazardous waste drilling fluids,potentially leading to environmental pollution,is considered.The waste drilling fluid is treated with an inorganic flocculant,an organic flocculant,and a p... A method for the treatment of hazardous waste drilling fluids,potentially leading to environmental pollution,is considered.The waste drilling fluid is treated with an inorganic flocculant,an organic flocculant,and a pH regulator.The profile control agent consists of partially hydrolyzed polyacrylamide,formaldehyde,hexamethylenetetramine,resorcinol,phenol,and the treated waste drilling fluid itself.For a waste drilling fluid concentration of 2500 mg/L,the gelling time of the profile control agent is 25 h,and the gelling strength is 32,000 mPa.s.Compared with the profile control agent prepared by recirculated water under the same conditions,the present profile control agent displays better stability,salt-resistance,and performance. 展开更多
关键词 Waste drilling fluid profile control agent cross-linking system GEL environmental protection
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Hydrophobic Small-Molecule Polymers as High-Temperature-Resistant Inhibitors in Water-Based Drilling Fluids
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作者 Xuyang Yao Kecheng Liu +5 位作者 Zenan Zhou Jun Zhou Xianbin Huang Tiemei Lu Yongsheng Yu He Li 《Fluid Dynamics & Materials Processing》 EI 2023年第7期1775-1787,共13页
Water-based drilling fluids can cause hydration of the wellbore rocks,thereby leading to instability.This study aimed to synthesize a hydrophobic small-molecule polymer(HLMP)as an inhibitor to suppress mud shale hydra... Water-based drilling fluids can cause hydration of the wellbore rocks,thereby leading to instability.This study aimed to synthesize a hydrophobic small-molecule polymer(HLMP)as an inhibitor to suppress mud shale hydration.An infrared spectral method and a thermogravimetric technique were used to characterize the chemical composition of the HLMP and evaluate its heat stability.Experiments were conducted to measure the linear swelling,rolling recovery rate,and bentonite inhibition rate and evaluate accordingly the inhibition performance of the HLMP.Moreover,the HLMP was characterized through measurements of the zeta potential,particle size distribution,contact angles,and interlayer space testing.As confirmed by the results,the HLMP could successfully be synthesized with a favorable heat stability.Furthermore,favorable results were found for the inhibitory processes of the HLMP on swelling and dispersed hydration during mud shale hydration.The positively charged HLMP could be electrically neutralized with clay particles,thereby inhibiting diffusion in the double electron clay layers.The hydrophobic group in the HLMP molecular structure resulted in the formation of a hydrophobic membrane on the rock surface,enhancing the hydrophobicity of the rock.In addition,the small molecules of the HLMP could plug the spaces between the layers of bentonite crystals,thereby reducing the entry of water molecules and inhibiting shale hydration. 展开更多
关键词 Water-based drilling fluids hydrophobic polymers shale inhibitor temperature resistance
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Optimization of Anti-Collapse Drilling Fluid Systems with High Potassium Content
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作者 Yu Xia Jian Guan +2 位作者 Yong Gao Shanfa Tang Jialuo Rong 《Fluid Dynamics & Materials Processing》 EI 2023年第6期1609-1622,共14页
The ash mudstone in some oil formations is highly water-sensitive.The oil formation is fractured,and the risk of well leakage and collapse is not negligible.This study presents a countermeasure for well collapse preve... The ash mudstone in some oil formations is highly water-sensitive.The oil formation is fractured,and the risk of well leakage and collapse is not negligible.This study presents a countermeasure for well collapse prevention,based on a“force-chemistry synergistic balance”approach and the utilization of environmentally friendly and efficient hydration inhibitors.The relevance of this approach is demonstrated considering a drilling fluid system with the high potassium content.The analysis shows that the system can maintain good rheological properties,filtration loss and suspension stability even after aging at 130℃ for 16 h.The primary roll recovery of rock chips is better than 98%.The secondary rolling recovery rate is 89%.The rapid water loss is close to zero.The effects of carrying rock,sand,hydration inhibition and dispersion of drill chips are all noticeable. 展开更多
关键词 Mudstone hydration force-chemistry synergistic balance environmental protection high potassium content potent inhibition anti-collapse drilling fluid
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A study of the properties of hydrophobically associating water-soluble polymers used in drilling fluids
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作者 舒福昌 史茂勇 +4 位作者 张岩 张峰 黄红玺 向兴金 王建华 《Petroleum Science》 SCIE CAS CSCD 2004年第4期57-61,共5页
Hydrophobically associating water-soluble polymers (HPAP) have been synthesized from acrylamide(AM), acrylate (AA), 2-acrylamido-2-methyl propane sulfonic acid (AMPS) and hydrophobic monomer (AP) in aqueous solution... Hydrophobically associating water-soluble polymers (HPAP) have been synthesized from acrylamide(AM), acrylate (AA), 2-acrylamido-2-methyl propane sulfonic acid (AMPS) and hydrophobic monomer (AP) in aqueous solution by radical polymerization. New polymer drilling fluids are made up of HPAP, which is used as viscosifiers and encapsulation agents. Properties of this system are reported in this paper. Results indicate that this system has a high value of yield point to plastic viscosity (YP/PV≥0.7), high viscosity at a low-shear rate (LSRV≥30000mPa·s), excellent shear thinning behavior, good solid-carrying behavior, resistance to shear, good thermal stability (as high as 140℃) and salt resistance. The system has excellent behavior in high-density solution of NaCl and in calcium and magnesium rich saline solutions. Hence, HPAP also can be used in saltwater polymer drilling fluids. 展开更多
关键词 Hydrophobically associating water-soluble polymers drilling fluids VISCOSITY salt resistance
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Hydrophobic silica nanoparticle-stabilized invert emulsion as drilling fluid for deep drilling 被引量:8
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作者 Maliheh Dargahi-Zaboli Eghbal Sahraei Behzad Pourabbas 《Petroleum Science》 SCIE CAS CSCD 2017年第1期105-115,共11页
An oil-based drilling fluid should be stable and tolerant to high temperatures for use in deep drilling. An invert emulsion of water in oil is a good choice as an oil- based drilling fluid which is a mixture of a soli... An oil-based drilling fluid should be stable and tolerant to high temperatures for use in deep drilling. An invert emulsion of water in oil is a good choice as an oil- based drilling fluid which is a mixture of a solid phase and two immiscible liquid phases stabilized by a polymeric surfactant. In deep drilling, due to high temperatures, the polymeric surfactant degrades and a phase separation occurs. Here, octadecyltrimethoxysilane-modified silica nanoparticles were used to form a stable invert emulsion of water in oil for the drilling fluid model which resulted in a milky fluid with the formation of 60 gm water droplets. In addition, rheological study showed that using hydrophobic silica nanoparticles resulted in a stable water in oil invert emulsion with desired properties for a drilling fluid that can be modified by adjusting the nanoparticle nature and content. Aging experiments at 120 ℃ indicated that they also have good stability at high temperatures for challenging drilling operations. 展开更多
关键词 Deep drilling drilling fluid model High-temperature aging RHEOLOGY Silica nanoparticles Stable invert emulsion
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Development and applications of solids-free oil-in-water drilling fluids 被引量:5
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作者 Yue Qiansheng Ma Baoguo 《Petroleum Science》 SCIE CAS CSCD 2008年第2期153-158,共6页
The increasing application of near balanced drilling technology to low-pressure and depleted fractured reservoirs requires the use of low-density drilling fluids to avoid formation damage. Solidsfree oil-in-water (O/... The increasing application of near balanced drilling technology to low-pressure and depleted fractured reservoirs requires the use of low-density drilling fluids to avoid formation damage. Solidsfree oil-in-water (O/W) emulsion drilling fluid is one type of low-density drilling fluid suitable for depleted fractured reservoirs. In this paper, the solids-free O/W drilling fluid was developed and has been successfully used in the Bozhong 28-1 oil and gas field, by which lost circulation, a severe problem occurred previously when drilling into fractured reservoir beds, was controlled, thereby minimizing formation damage. The O/W emulsion drilling fluid was prepared by adding 20% (by volume) No. 5 mineral oil (with high flash point, as dispersed phase) into seawater (as continuous phase). Surfactant HTO-1 (as a primary emulsifier) and non-ionic surfactant HTO-2 (as a secondary emulsifier) were added into the drilling fluid system to stabilize the emulsion; and YJD polymer was also added to seawater to improve the viscosity of the continuous phase (seawater). The drilling fluid was characterized by high flash point, good thermal stability and high stability to crude oil contamination. 展开更多
关键词 Oil-in-water emulsion drilling fluids solids-free drilling fluids lost circulation depletedreservoir fractured reservoir
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Gas-hydrate formation,agglomeration and inhibition in oil-based drilling fluids for deep-water drilling 被引量:9
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作者 Fulong Ning Ling Zhang +2 位作者 YunzhongTu Guosheng Jiang Maoyong Shi 《Journal of Natural Gas Chemistry》 EI CAS CSCD 2010年第3期234-240,共7页
One of the main challenges in deep-water drilling is gas-hydrate plugs,which make the drilling unsafe.Some oil-based drilling fluids(OBDF) that would be used for deep-water drilling in the South China Sea were teste... One of the main challenges in deep-water drilling is gas-hydrate plugs,which make the drilling unsafe.Some oil-based drilling fluids(OBDF) that would be used for deep-water drilling in the South China Sea were tested to investigate the characteristics of gas-hydrate formation,agglomeration and inhibition by an experimental system under the temperature of 4 ?C and pressure of 20 MPa,which would be similar to the case of 2000 m water depth.The results validate the hydrate shell formation model and show that the water cut can greatly influence hydrate formation and agglomeration behaviors in the OBDF.The oleophobic effect enhanced by hydrate shell formation which weakens or destroys the interfacial films effect and the hydrophilic effect are the dominant agglomeration mechanism of hydrate particles.The formation of gas hydrates in OBDF is easier and quicker than in water-based drilling fluids in deep-water conditions of low temperature and high pressure because the former is a W/O dispersive emulsion which means much more gas-water interfaces and nucleation sites than the later.Higher ethylene glycol concentrations can inhibit the formation of gas hydrates and to some extent also act as an anti-agglomerant to inhibit hydrates agglomeration in the OBDF. 展开更多
关键词 oil-based drilling fluids gas hydrates water cut formation and agglomeration INHIBITOR
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High temperature and high pressure rheological properties of high-density water-based drilling fluids for deep wells 被引量:10
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作者 Wang Fuhua Tan Xuechao +3 位作者 Wang Ruihe Sun Mingbo Wang Li Liu Jianghua 《Petroleum Science》 SCIE CAS CSCD 2012年第3期354-362,共9页
To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines... To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines temperature effects on the rheological properties of two types of high-density water-based drilling fluids (fresh water-based and brine-based) under high temperature and high pressure (HTHP) with a Fann 50SL rheometer. On the basis of the water-based drilling fluid systems formulated in laboratory, this paper mainly describes the influences of different types and concentration of clay, the content of a colloid stabilizer named GHJ-1 and fluid density on the rheological parameters such as viscosity and shear stress. In addition, the effects of aging temperature and aging time of the drilling fluid on these parameters were also examined. Clay content and proportions for different densities of brine-based fluids were recommended to effectively regulate the rheological properties. Four theological models, the Bingham, power law, Casson and H-B models, were employed to fit the rheological parameters. It turns out that the H-B model was the best one to describe the rheological properties of the high-density drilling fluid under HTHP conditions and power law model produced the worst fit. In addition, a new mathematical model that describes the apparent viscosity as a function of temperature and pressure was established and has been applied on site. 展开更多
关键词 High-density water-based drilling fluid rheological behavior CLAY high temperature high pressure linear fitting rheological model mathematical model
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Novel Water-Based Drilling and Completion Fluid Technology to Improve Wellbore Quality During Drilling and Protect Unconventional Reservoirs 被引量:18
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作者 Guancheng Jiang Jinsheng Sun +5 位作者 Yinbo He Kaixiao Cui Tengfei Dong Lili Yang Xukun Yang Xingxing Wang 《Engineering》 SCIE EI CAS 2022年第11期129-142,共14页
The efficient exploration and development of unconventional oil and gas are critical for increasing the self-sufficiency of oil and gas supplies in China.However,such operations continue to face serious problems(e.g.,... The efficient exploration and development of unconventional oil and gas are critical for increasing the self-sufficiency of oil and gas supplies in China.However,such operations continue to face serious problems(e.g.,borehole collapse,loss,and high friction),and associated formation damage can severely impact well completion rates,increase costs,and reduce efficiencies.Water-based drilling fluids possess certain advantages over oil-based drilling fluids(OBDFs)and may offer lasting solutions to resolve the aforementioned issues.However,a significant breakthrough with this material has not yet been made,and major technical problems continue to hinder the economic and large-scale development of unconventional oil and gas.Here,the international frontier external method,which only improves drilling fluid inhibition and lubricity,is expanded into an internal-external technique that improves the overall wellbore quality during drilling.Bionic technologies are introduced into the chemical material synthesis process to imitate the activity of life.A novel drilling and completion fluid technique was developed to improve wellbore quality during drilling and safeguard formation integrity.Macroscopic and microscopic analyses indicated that in terms of wellbore stability,lubricity,and formation protection,this approach could outperform methods that use typical OBDFs.The proposed method also achieves a classification upgrade from environmentally protective drilling fluid to an ecologically friendly drilling fluid.The developed technology was verified in more than 1000 unconventional oil and gas wells in China,and the results indicate significant alleviation of the formation damage attributed to borehole collapse,loss,and high friction.It has been recognized as an effective core technology for exploiting unconventional oil and gas resources.This study introduces a novel research direction for formation protection technology and demonstrates that observations and learning from the natural world can provide an inexhaustible source of ideas and inspire the creation of original materials,technologies,and theories for petroleum engineering. 展开更多
关键词 Formation protection Wellbore quality Unconventional oil and gas drilling and completion fluid BIONICS
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Rheological properties of oil-based drilling fluids at high temperature and high pressure 被引量:3
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作者 赵胜英 鄢捷年 +1 位作者 舒勇 张洪霞 《Journal of Central South University》 SCIE EI CAS 2008年第S1期457-461,共5页
The rheological properties of two kinds of oil-based drilling fluids with typically composition were studied at pressures up to 138 MPa and temperatures up to 204 ℃ using the RheoChan 7400 Rheometer.The experimental ... The rheological properties of two kinds of oil-based drilling fluids with typically composition were studied at pressures up to 138 MPa and temperatures up to 204 ℃ using the RheoChan 7400 Rheometer.The experimental results show that the apparent viscosity,plastic viscosity and yield point decrease with the increase of temperature,and increase with the increase of pressure.The effect of pressure on the apparent viscosity,plastic viscosity and yield point is considerable at ambient temperature.However,this effect gradually reduces with the increase of temperature.The major factor influencing the rheological properties of oil-based drilling fluids is temperature instead of pressure in the deep sections of oil wells.On the basis of numerous experiments,the model for predict the apparent viscosity,plastic viscosity and yield point of oil-based drilling fluids at high temperature and pressure was established using the method of regressive analysis.It is confirmed that the calculated data are in good agreement with the measured data,and the correlation coefficients are more than 0.98.The model is convenient for use and suitable for the application in drilling operations. 展开更多
关键词 OIL-BASED drilling fluidS HIGH temperature HIGH pressure RHEOLOGICAL property MATHEMATICAL model
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