Experiments on thermal decomposition of nano-sized calcium carbonate were carried out in a thermo-gravimetric analyzer under non-isothermal condition of different heating rates (5 to 20K·min-1). The Coats and Red...Experiments on thermal decomposition of nano-sized calcium carbonate were carried out in a thermo-gravimetric analyzer under non-isothermal condition of different heating rates (5 to 20K·min-1). The Coats and Redfern's equation was used to determine the apparent activation energy and the pre-exponential factors. The mechanism of thermal decomposition was evaluated using the master plots, Coats and Redfern's equation and the kinetic compensation law. It was found that the thermal decomposition property of nano-sized calcium carbonate was different from that of bulk calcite. Nano-sized calcium carbonate began to decompose at 640℃, which was 180℃lower than the reported value for calcite. The experimental results of kinetics were compatible with the mechanism of one-dimensional phase boundary movement. The apparent activation energy of nano-sized calcium carbonate was estimated to be 151kJ·mol-1 while the literature value for normal calcite was approximately 200kJ·mol-1. The order of magnitude of pre-exponential factors was estimated to be 10~9 s-1.展开更多
In order to reduce the cost and improve the performance of wood/plastic composite(WPC),the effects of additive amount of calcium carbonate on preparation and mechanical properties of high density polyethylene(HDPE)bas...In order to reduce the cost and improve the performance of wood/plastic composite(WPC),the effects of additive amount of calcium carbonate on preparation and mechanical properties of high density polyethylene(HDPE)based WPC were studied.The results showed that the calcium carbonate can improve preparation and mechanical properties effectively.The 20%calcium carbonate additive could effectively improve the melt fluidity of the composites and reduce the energy consumption in the processing.The calcium carbonate had a favorable toughening effect on polymer and was effectively filled in WPC.For the best tensile,flexural and impact properties of WPC,the appropriate additive amounts of calcium carbonate were 25%,10%and 30%,respectively.The additive amount for preparation of WPC should be based on the processing requirements and the demands for different working conditions.展开更多
基金Supported by the Key Research of Science & Technology of Education(No.0202)and the Fundamental Research Plan of HuoYingdong(No.81063).
文摘Experiments on thermal decomposition of nano-sized calcium carbonate were carried out in a thermo-gravimetric analyzer under non-isothermal condition of different heating rates (5 to 20K·min-1). The Coats and Redfern's equation was used to determine the apparent activation energy and the pre-exponential factors. The mechanism of thermal decomposition was evaluated using the master plots, Coats and Redfern's equation and the kinetic compensation law. It was found that the thermal decomposition property of nano-sized calcium carbonate was different from that of bulk calcite. Nano-sized calcium carbonate began to decompose at 640℃, which was 180℃lower than the reported value for calcite. The experimental results of kinetics were compatible with the mechanism of one-dimensional phase boundary movement. The apparent activation energy of nano-sized calcium carbonate was estimated to be 151kJ·mol-1 while the literature value for normal calcite was approximately 200kJ·mol-1. The order of magnitude of pre-exponential factors was estimated to be 10~9 s-1.
基金the Key research and development project of Shandong Province(2016ZDJS11A01)。
文摘In order to reduce the cost and improve the performance of wood/plastic composite(WPC),the effects of additive amount of calcium carbonate on preparation and mechanical properties of high density polyethylene(HDPE)based WPC were studied.The results showed that the calcium carbonate can improve preparation and mechanical properties effectively.The 20%calcium carbonate additive could effectively improve the melt fluidity of the composites and reduce the energy consumption in the processing.The calcium carbonate had a favorable toughening effect on polymer and was effectively filled in WPC.For the best tensile,flexural and impact properties of WPC,the appropriate additive amounts of calcium carbonate were 25%,10%and 30%,respectively.The additive amount for preparation of WPC should be based on the processing requirements and the demands for different working conditions.
