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Temperature-programmed pyrolysis of magnesium ammonium phosphate and removal of ammonia-nitrogen by its pyrolysate 被引量:3
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作者 唐建军 陈益清 +2 位作者 钟振辉 李文龙 尹娟 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第9期2502-2508,共7页
In order to achieve the dual goals of complete deamination of magnesium ammonium phosphate(MAP) and ensure the pyrolysate's good removal properties towards ammonia-nitrogen, a temperature-programmed method for the ... In order to achieve the dual goals of complete deamination of magnesium ammonium phosphate(MAP) and ensure the pyrolysate's good removal properties towards ammonia-nitrogen, a temperature-programmed method for the pyrolysis of MAP was studied, as well as the thermodynamic and kinetic processes involved in the removal reaction system between MAP pyrolysate and aqueous ammonium. It was found that the pyrolysis method and pyrolysis final temperature had significant effects on the MAP pyrolysate's removal properties towards aqueous ammonium, and the following conditions were deemed to be more appropriate: pyrolysis final temperature and heating rate at 180 ℃ and 5 ℃/min, respectively, and a pH level of 9.5 for the removal reaction system. The resultant ammonium removal capacity by the MAP pyrolysate was 95.62 mg/g. After 120 min, the removal rate with an initial concentration of 1000 mg/L was 82%. The kinetic and thermodynamic results indicated that the removal of aqueous ammonium by MAP pyrolysate was the exchange process between H^+ and NH4^+ via MAP precipitation. The kinetics complied with the Lagergren quasi second-order model with an equilibrium time of 120 min, while the isothermal curves complied with the Freundlich model. 展开更多
关键词 magnesium ammonium phosphate temperature-programmed heating pyrolysate ammonia-nitrogen
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Distribution of aromatic bio-markers in pyrolysates of co-ccolithophore 被引量:2
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作者 ZHOU Wen WU Qingyu +3 位作者 WANG Ruiyong SONG Yitao ZHANG Linye LIU Zhili 《Chinese Science Bulletin》 SCIE EI CAS 2001年第3期246-252,共7页
Analyses of the original and pyrolytic products of coccolithophore at various temperatures suggest that the contribution of coccolithophore to the formation of large immature oil reservoirs should attract keen interes... Analyses of the original and pyrolytic products of coccolithophore at various temperatures suggest that the contribution of coccolithophore to the formation of large immature oil reservoirs should attract keen interest. Through biochemical processes algae can change inorganic sulphur into organic sulphur, which could be one of the most important precursors of organic sulphur compounds in oil and source rocks. When Methylphenanthrene Index (MPI) and Methylphenanthrene Ratio (MPR) indices were used to evaluate the evolution degree of source rocks and oil maturity, other maturity indices must be used together for correction. In low maturity, the relative abundances of diben-zothiophene (DBT), fluorine (F) and dibenzofuran (DBF) can be used to identify the oxidation-reduction environments. 展开更多
关键词 COCCOLITHOPHORE pyrolysates AROMATIC biomarkers.
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n-Alkane bound biomarker fingerprints from asphaltenes in the bitumens of Eastern Dahomey Basin,Nigeria:Source and genetic implications
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作者 Modupe A.Egbeola Olubunmi C.Adeigbe Olajide J.Adamolekun 《Petroleum Research》 EI 2024年第1期85-91,共7页
The asphaltene fractions of the bitumens of Eastern Dahomey Basin in Nigeria,were analyzed by flash pyrolysis-gas chromatography(Py-GC)method in order to unravel its geochemical history and properties.The distribution... The asphaltene fractions of the bitumens of Eastern Dahomey Basin in Nigeria,were analyzed by flash pyrolysis-gas chromatography(Py-GC)method in order to unravel its geochemical history and properties.The distributions of the initial biomarkers of the original oils from the pyrolysates are related to the assessment of organic matter source,paleo-redox conditions and source environment during deposition.Also,it effectively establishes the genetic relationship of the bitumens.The n-alkane distributions in the pyrolysates reveal nC_(9)-nC_(32)n-alkanes,maximizing at nC_(14),isoprenoids-pristane(Pr)and phytane(Ph),and some n-alkene peaks.High peaks of low to medium-weight nC_(9)-nC20 n-alkanes and low peaks of nC_(21)+n-alkanes characterize the distributions.These reveal that abundant algal organic matter with some terrigenous inputs contributed to the source rock of the bitumens.The high concentration of marine organic matter inputs to the source rock is further confirmed by the nC_(17)/nC27 ratios which range from 5.39 to 19.82 and shows the predominance of nC_(17)alkanes.The general unimodal n-alkane distributions in the bitumens indicate derivation from similar organic matter types showing that they are genetically related.The anoxic to suboxic environmental conditions that prevailed during the deposition of the sediments is revealed by the isoprenoids,Pr/Ph ratios(0.72-1.28).Pristane/nC_(17)and Phytane/nC_(18)range from 0.16 to 0.33 and 0.22 to 0.56,revealing that the bitumens were from predominantly marine organic matter(type II kerogen)preserved in a reducing environment with no evidence of biodegradation.However,the Ph/nC_(18)ratio and the cross plot of Pr+Ph/nC_(17)+nC_(18)allow the classification of the bitumens into two subfamilies/groups(A and B).The bitumen samples have low wax content as indicated by the degree of waxiness ranging from 0.21 to 0.38 which confirms low terrigenous input.Based on the carbon preference index(CPI:0.92 to 1.55)and odd-even predominance(OEP:0.70 to 1.36),it is concluded that the bitumens are immature to marginally mature. 展开更多
关键词 Genetic relationship Flash pyrolysis BIOMARKER ASPHALTENE pyrolysates
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Influences of Bacterial Degradation on Gases Generated by Pyrolysis of Heterotrophically Yellowing Algae
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作者 章冰 吴庆余 +1 位作者 盛国英 傅家谟 《Chinese Science Bulletin》 SCIE EI CAS 1994年第23期2018-2022,共5页
The large amount of microplanktonic algae in nature are not all thermally degraded directly into organic matter from their original green autotrophic state. When the algae are old or dead and deposited at the bottom o... The large amount of microplanktonic algae in nature are not all thermally degraded directly into organic matter from their original green autotrophic state. When the algae are old or dead and deposited at the bottom of lake or ocean, some changes may take place in the cells, including the disappearance of the chlorophyll, the 展开更多
关键词 BACTERIAL degradation heterotrophically YELLOWING ALGAE natural GAS pyrolysate gas.
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Hydrocarbons pyrolysed from nannoplanktonic algae:An experimental organism system for study on the origin of petroleum and natural gas
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作者 Qingyu Wu Ruiyong Wang +2 位作者 Junbiao Dai Yitao Song Yoshihiro Shiraiwa 《Chinese Science Bulletin》 SCIE EI CAS 1999年第8期767-770,共4页
Enukuania huxleyi is marine nanoplanktonic alga with calcify scale called coccolith om its cell surface.This ubiquitous species with the Lafgest biomass in marice forms gigantic blooms covering thousands
关键词 Hydrocarbons pyrolysed from nannoplanktonic algae
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