A novel intumescent flame retardant coating, consisting of poly（vinylphosphonic acid） （PVPA） as the acid source and branched polyethylenimine （BPEI） as the blowing agent, was constructed on the surface of ramie ...A novel intumescent flame retardant coating, consisting of poly（vinylphosphonic acid） （PVPA） as the acid source and branched polyethylenimine （BPEI） as the blowing agent, was constructed on the surface of ramie fabrics by alternate assembly to remarkably improve the flame retardancy of ramie. The PVPA/BPEI coating on the surface of individual fibers of ramie fabric pyrolyzes to form protective char layer upon heating/burning and improves the flame retardancy of ramie. Thermogravimetric analysis reveals that the PVPA/BPEI-coated ramie fabrics left as much as 25.8 wt% residue at 600 ~C, while the control （uncoated） fabric left less than 1.4 wt% residue. Vertical flame test shows that all PVPA/BPEI-coated fabrics have shorter after-flame time, and the residues well preserved the original weave structure and fiber morphology, whereas, the uncoated fabric left only ashes. Microscale combustion calorimetry shows that the PVPA/BPEI coatings greatly reduce the total heat release by as much as 66% and the heat release capacity by 76%, relative to those of the uncoated fabric.展开更多
This paper in the light of the structure parameters of the ramie fabric to research and evaluation it＇s heart-moisture comfort. Selected 15 kinds of ramie fabric to test the average density, the thickness, the tightn...This paper in the light of the structure parameters of the ramie fabric to research and evaluation it＇s heart-moisture comfort. Selected 15 kinds of ramie fabric to test the average density, the thickness, the tightness, the heat rate, the heat transfer coefficient, the Clo, the air permeability, the water vapor permeability and other performance index, used SPSS factor analysis to explore the main influence factors of porous ramie fabric＇s heat moisture comfort. Results shows that： the main influence factors of ramie fabric＇s heat-moisture is the heat preservation material, the air permeability and the moisture permeability, get the equation of porous ramie fabric＇ s heat-moisture comfort： F=0.45855y1＋0.30588y2＋0.13549y3, evaluated and sorted the sample fabric＇ s heat-moisture comfort.展开更多
基金financially supported by the National Basic Research Program of China(Nos.2010CB631105 and 2011CB612307)
文摘A novel intumescent flame retardant coating, consisting of poly（vinylphosphonic acid） （PVPA） as the acid source and branched polyethylenimine （BPEI） as the blowing agent, was constructed on the surface of ramie fabrics by alternate assembly to remarkably improve the flame retardancy of ramie. The PVPA/BPEI coating on the surface of individual fibers of ramie fabric pyrolyzes to form protective char layer upon heating/burning and improves the flame retardancy of ramie. Thermogravimetric analysis reveals that the PVPA/BPEI-coated ramie fabrics left as much as 25.8 wt% residue at 600 ~C, while the control （uncoated） fabric left less than 1.4 wt% residue. Vertical flame test shows that all PVPA/BPEI-coated fabrics have shorter after-flame time, and the residues well preserved the original weave structure and fiber morphology, whereas, the uncoated fabric left only ashes. Microscale combustion calorimetry shows that the PVPA/BPEI coatings greatly reduce the total heat release by as much as 66% and the heat release capacity by 76%, relative to those of the uncoated fabric.
文摘This paper in the light of the structure parameters of the ramie fabric to research and evaluation it＇s heart-moisture comfort. Selected 15 kinds of ramie fabric to test the average density, the thickness, the tightness, the heat rate, the heat transfer coefficient, the Clo, the air permeability, the water vapor permeability and other performance index, used SPSS factor analysis to explore the main influence factors of porous ramie fabric＇s heat moisture comfort. Results shows that： the main influence factors of ramie fabric＇s heat-moisture is the heat preservation material, the air permeability and the moisture permeability, get the equation of porous ramie fabric＇ s heat-moisture comfort： F=0.45855y1＋0.30588y2＋0.13549y3, evaluated and sorted the sample fabric＇ s heat-moisture comfort.
