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基于腔体单元和Rebar单元的空气弹簧性能分析 被引量:9
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作者 鲍卫宁 2陈立平 +2 位作者 张云清 王书亭 任卫群 《汽车技术》 北大核心 2007年第10期21-24,共4页
建立了空气弹簧有限元离散模型,研究了空气弹簧内压-位移、容积-位移、最大外径-位移以及载荷-位移关系,仿真结果与实测结果对比表明,两者具有很好的一致性。研究了工作高度和帘线角度对空气弹簧承载能力、刚度特性以及空气弹簧在工作... 建立了空气弹簧有限元离散模型,研究了空气弹簧内压-位移、容积-位移、最大外径-位移以及载荷-位移关系,仿真结果与实测结果对比表明,两者具有很好的一致性。研究了工作高度和帘线角度对空气弹簧承载能力、刚度特性以及空气弹簧在工作过程中直径变化的影响,结果表明空气弹簧的工作高度和帘线角度是影响空气弹簧性能的重要因素。 展开更多
关键词 空气弹簧 性能 腔体单元 rebar 单元
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基于rebar单元的载重子午线轮胎模型建立及验证 被引量:13
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作者 应世洲 陈方 王国林 《轮胎工业》 CAS 2007年第8期462-465,共4页
运用ABAQUS非线性有限元分析软件并基于rebar单元建立12.00R20载重子午线轮胎有限元分析模型,同时进行装配、充气和静态加载仿真模拟分析。对比轮胎载荷-下沉量仿真模拟和试验结果,证明了模型建立的有效性。该模型有助于进一步分析轮胎... 运用ABAQUS非线性有限元分析软件并基于rebar单元建立12.00R20载重子午线轮胎有限元分析模型,同时进行装配、充气和静态加载仿真模拟分析。对比轮胎载荷-下沉量仿真模拟和试验结果,证明了模型建立的有效性。该模型有助于进一步分析轮胎的力学特性。 展开更多
关键词 载重子午线轮胎 有限元模型 rebar单元
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基于rebar单元的航空轮胎模型建立与分析 被引量:6
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作者 马连湘 任侠 《青岛科技大学学报(自然科学版)》 CAS 2015年第3期318-321,共4页
运用ABAQUS非线性有限元分析软件并基于rebar单元建立H44.5×16.5-21型航空轮胎有限元分析模型,同时进行装配、充气和静态加载仿真模拟分析。着重研究了二维轴对称模型充气后各部位产生的变形量、变形分布规律,获得了充气轮胎的断... 运用ABAQUS非线性有限元分析软件并基于rebar单元建立H44.5×16.5-21型航空轮胎有限元分析模型,同时进行装配、充气和静态加载仿真模拟分析。着重研究了二维轴对称模型充气后各部位产生的变形量、变形分布规律,获得了充气轮胎的断面和半径变化量。并分析了充气轮胎各层帘布和橡胶产生的应力和应变。证明了建模的有效性。 展开更多
关键词 ABAQUS有限元分析 航空轮胎 rebar单元 加强筋模型
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基于REBAR模型的空气弹簧有限元分析 被引量:2
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作者 张广世 袁志富 赵洪伦 《铁道车辆》 2002年第8期4-5,共2页
利用 MARC非线性有限元分析软件建立空气弹簧有限元模型 ,帘线增强结构采用 REBAR单元 ,计算研究了胶囊基体和帘线增强各自的应力情况 ,分析了帘线材料参数对胶囊强度和刚度的影响。
关键词 rebar模型 有限元分析 空气弹簧 胶囊 强度 刚度 帘线 铁路车辆
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基于Rebar实体单元的子午线轮胎加载过程模拟 被引量:3
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作者 刁向红 《轮胎工业》 CAS 2005年第8期456-462,共7页
利用MSC.Marc2000通用非线性有限元分析软件,用Rebar实体单元和Herrmann实体单元建立模型,仿真模拟分析215/45R17轿车子午线轮胎从安装轮辋到轮胎充气、加载和轮胎下沉全过程的情况。通过过程模拟,可以直观地观察轮胎各部位力学特性的... 利用MSC.Marc2000通用非线性有限元分析软件,用Rebar实体单元和Herrmann实体单元建立模型,仿真模拟分析215/45R17轿车子午线轮胎从安装轮辋到轮胎充气、加载和轮胎下沉全过程的情况。通过过程模拟,可以直观地观察轮胎各部位力学特性的分布及变化状况。计算结果与试验结果相近。 展开更多
关键词 非线性有限元分析 子午线轮胎 模拟 rebar单元 力学特性
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Explicit reinforcement models for fully-grouted rebar rock bolts 被引量:11
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作者 Navid Bahrani John Hadjigeorgiou 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2017年第2期267-280,共14页
This paper investigates the explicit use of rock reinforcement in a discontinuous stress analysis model.A series of numerical experiments was undertaken to evaluate the performance of local and global reinforcement mo... This paper investigates the explicit use of rock reinforcement in a discontinuous stress analysis model.A series of numerical experiments was undertaken to evaluate the performance of local and global reinforcement models implemented in universal distinct element code(UDEC).This was made possible by calibrating the reinforcement models to the laboratory behavior of a fully-grouted rebar bolt tested under pure pull and pure shear loading conditions.The model calibration focuses on matching different loading stages of the force-displacement curve including the initial elastic response,the hardening behavior and the bolt rupture.The paper concludes with a discussion on the suitability of the different reinforcement models in UDEC including their advantages and limitations.Finally,it addresses the choice of input parameters required for a realistic simulation of fully-grouted rebar bolts. 展开更多
关键词 Rock REINFORCEMENT Fully-grouted rebar DISTINCT element method Local REINFORCEMENT Global REINFORCEMENT PULL-OUT TEST Shear TEST
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Effects of Deformation Conditions on Dynamic Recrystallization of a Nb Microalloyed Anti-seismic Rebar 被引量:2
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作者 黄敏 曹建春 +3 位作者 陈伟 周晓龙 杨银辉 钟仲华 《Journal of Donghua University(English Edition)》 EI CAS 2015年第5期879-886,共8页
The hot deformation behavior of a Nb microalloyed anti-seismic rebar was investigated at deformation temperatures of 950-1 100 ℃ and strain rates of 0. 01-0. 1 s- 1 on a Gleeble-3800 thermo-mechnical simulator. The f... The hot deformation behavior of a Nb microalloyed anti-seismic rebar was investigated at deformation temperatures of 950-1 100 ℃ and strain rates of 0. 01-0. 1 s- 1 on a Gleeble-3800 thermo-mechnical simulator. The flow stress-strain curves show the typical dynamic recrystallization with a peak,before reaching the steady state flow at higher deformation temperatures and lower strain rates. The constitutive equation governing the dynamic recrystallization( DRX) was obtained and the average activation energy of deformation was calculated as Q = 389. 5 kJ / mol by the regression analysis. The DRX grain size was also found to decrease with the increasing strain rate and the decreasing deformation temperature. The austenite grain size was refined from 118. 0 μm to 15. 07-40. 01 μm by DRX. The DRX grain size under diverse deformation conditions predicted by mathematical model agrees well with experimental results. 展开更多
关键词 dynamic recrystallization(DRX) deformation temperature strain rate Nb microalloyed rebar
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Improvement to anti-rust property of hot rolled rebar by compact oxide scale 被引量:1
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作者 陈庆安 刘立忠 +1 位作者 刘鑫 刘相华 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第12期2813-2818,共6页
A method was proposed to improve the anti-rust property of hot rolled rebar, which uses oil–water emulsion cooling instead of water cooling after hot rolling. The experiments were carried out by two cooling methods, ... A method was proposed to improve the anti-rust property of hot rolled rebar, which uses oil–water emulsion cooling instead of water cooling after hot rolling. The experiments were carried out by two cooling methods, one cooled by water, the other cooled by oil–water emulsion. The results of wet/dry cyclic accelerated corrosion test showed that the anti-rust property of rebar cooled by oil–water emulsion was better than that by water obviously. The results of OM, SEM and EPMA analysis indicated that these two scales contained three layers: an outer Fe_3O_4 layer, an intermediate Fe O layer with island-shaped pro-eutectoid Fe_3O_4, an inner eutectoid Fe_3O_4 layer. For the water cooled rebar, all three layers of oxide scale were relatively thin. Moreover, the scale had plenty of defects such as porosity, and crack. However, for the oil–water emulsion cooled rebar, all three layers of oxide scale were relatively thick and compact, which played an important role in protecting the rebar from atmospheric rust. 展开更多
关键词 hot rolled rebar anti-rust PROPERTY COMPACT oxide scale oil–water EMULSION cooling
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基于RebarSmart的廊道结构数字化钢筋设计 被引量:2
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作者 李竞波 黄志澎 蒋媛媛 《科技创新与应用》 2017年第32期1-2,6,共3页
RebarSmart是成都勘测设计研究院有限公司基于CATIA平台开发的混凝土结构钢筋数字化设计软件,可用于电水利工程的配筋设计,具有直观准确的优点。文章以某水电工程的基础廊道为例,介绍了三维钢筋软件RebarSmart在水电工程中的应用。
关键词 rebarSmart 钢筋图 三维配筋 廊道
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STUDY ON CORROSION RESISTANCE OF REBAR IN HYBRID GRINDING FLY ASH -LIME SILICATE CONCRETE
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作者 CHEN Yinzhou Wuhan University of Technoloyg 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 1999年第2期18-22,共5页
The corrosion resistance of rebar in fly ash-Lime silicate concrete as well as its marco properties and pore distribution is investigated. The results show that the fly ash is activated, the compressrve strength of th... The corrosion resistance of rebar in fly ash-Lime silicate concrete as well as its marco properties and pore distribution is investigated. The results show that the fly ash is activated, the compressrve strength of the silicate concrete is strengthened and its pore structure is modified after fly ash and lime being hybrid ground. Also the corrosion resistance of rebar in the silicate concrete is improved. 展开更多
关键词 corrosion resistance rebar HYBRID GRINDING SILICATE CONCRETE
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Strengthening of High Strength Rebars
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作者 张晓刚 姚卫薰 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1990年第3期193-199,共7页
The influence of alloying elements and coolingconditions after rolling on the microstructures andmechanical properties of a series of medium carbonSi-Mn-Mo-V high-strength precision-formedrebars were investigated.It i... The influence of alloying elements and coolingconditions after rolling on the microstructures andmechanical properties of a series of medium carbonSi-Mn-Mo-V high-strength precision-formedrebars were investigated.It is found that steel withcombined addition of Mo and V appears to be themost promising one than those containing V andNb or containing V alone under the same pro-cessing conditions.From CCT curve of the steeland the cooling curve of the bar determined by sim-ulating the cooling rate in mill practice,the reasonwhy 40Si2MnMoV bar has excellent combinationof strength and ductility is clarified. 展开更多
关键词 HIGH STRENGTH STEEL COMPOSITION design rebar
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Effect of Chromium Micro-alloying on the Corrosion Behavior of a Low-carbon Steel Rebar in Simulated Concrete Pore Solutions
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作者 宋丹 蒋金洋 +5 位作者 孙伟 MA Han ZHANG Jianchun CHENG Zhaojun JIANG Jinghua AI Zhiyong 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2017年第6期1453-1463,共11页
A new low-cost corrosion-resistant rebar(HRB400 R) was designed and fabricated by chromium micro-alloying. The effects of Cr on the passivation and corrosion behavior of this rebar in the simulated concrete pore solut... A new low-cost corrosion-resistant rebar(HRB400 R) was designed and fabricated by chromium micro-alloying. The effects of Cr on the passivation and corrosion behavior of this rebar in the simulated concrete pore solutions were studied systematically, and its improved corrosion resistance was revealed. In the Cl--free saturated Ca(OH)_2 solution, the HRB400 R rebar presented nearly the same passive film and similar passivation ability compared to the common carbon steel rebar. In the long-term immersion corrosion test in the Cl--contained Ca(OH)_2 solution, the HRB400 R rebar presented improved corrosion resistance and obvious longer passivation-maintaining period. Micro-alloying of Cr element in the rebar matrix enhanced its corrosion resistance against Cl--attack and retarded the corrosion initiation in the matrix. In the alkaline Na Cl salt spraying test, the HRB400 R rebar also presented obviously lower mass-loss rate. The enrichment of Cr element in the rust layer improved its retardant effect to the penetration of aggressive medium, and decreased the corrosion propagation rate of the rebar. 展开更多
关键词 Cr micro-alloying corrosion-resistant rebar improved corrosion resistance simulated concrete pore solutions
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Chest, pericardium, abdomen, and thigh penetrating injury by a steel rebar: A case report
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作者 Xian-Wei Yang Wen-Tao Wang 《World Journal of Clinical Cases》 SCIE 2020年第20期5025-5029,共5页
BACKGROUND Combined penetrating trauma involving the chest, pericardium, abdomen, and thigh is rare and lethal. It is difficult to quickly rescue patients with penetrating injuries from long steel bars.CASE SUMMARY A ... BACKGROUND Combined penetrating trauma involving the chest, pericardium, abdomen, and thigh is rare and lethal. It is difficult to quickly rescue patients with penetrating injuries from long steel bars.CASE SUMMARY A previously healthy 56-year-old male worker presented with a length of rebar that penetrated the chest-abdomen-pelvic cavity and was palpable on the anterior side of the neck and thigh. On radiological imaging, the left chest wall-left chest cavity-mediastinum-abdominal cavity-right groin area-right thigh demonstrated a strip-like density shadow, about 1.5 cm thick, with the heart, stomach wall, and part of the intestine involved. There was a left-sided pleural effusion, left lung compression of about 50%-60%, and a small amount of left pleural effusion/blood accumulation;possible perforation of hollow organs;and double multiple ribs fractures on the side. An emergency green channel was opened to provide a rescue process for smooth and timely diagnostic and treatment to save the patient's life. The patient was followed at 4 mo after discharge and showed good recovery.CONCLUSION For pre-hospital emergency treatment in locations that are not fully prepared for surgery, we do not recommend cutting the steel bars outside the body. We advocate pulling out foreign bodies intact to reduce secondary injuries. 展开更多
关键词 Penetrating trauma rebar Diaphragm injury THORACOABDOMINAL Pre-hospital emergency Case report
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Effect of Calcium Nitrate and Sodium Nitrite on the Rebar Corrosion of Medium Carbon Steel in Seawater and Cassava Fluid
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作者 Mohammed Adamu Lasisi Ejibunu Umoru Oladeji Oluremi Ige 《Journal of Minerals and Materials Characterization and Engineering》 2014年第3期223-229,共7页
Inhibitors are regularly used as one of the principal prevention and control techniques in reinforcement corrosion. Hence this study investigates the effect of calcium nitrate and sodium nitrite inhibitors on the reba... Inhibitors are regularly used as one of the principal prevention and control techniques in reinforcement corrosion. Hence this study investigates the effect of calcium nitrate and sodium nitrite inhibitors on the rebar corrosion of medium carbon steel in seawater and cassava fluid with a view to determining inhibitive potentials of the different inhibitors in the two media. Gravimetric and voltametric techniques were employed in this study and a total of forty-five corrosion coupons of different dimensions were produced. Forty coupons were used for gravimetric analysis and the remaining five for corrosion potentials measurements. Eight of the samples were used as control;while other eight samples each were admixed with calcium nitrate and sodium nitrite in concrete cubes. It was later immersed in seawater and cassava fluid for a total duration of 32 days and the measurements were taken at the interval of 4 days in order to determine the corrosion rates in mils per year (mmpy). Two controls and admixed samples each were later immersed in seawater and cassava fluid, respectively, for durations of 32 days to determine the corrosion potentials using a voltmeter and a Copper-Copper Sulphate Electrode (Cu/CuSO4). The pH of each medium was measured throughout the period of exposure. The results obtained expressed that all the samples except the control samples, displayed some degree of inhibition. The inhibition levels for the admixed samples in seawater were higher compared with those in cassava fluid. Inhibition efficiencies for various inhibitors followed different trends in different environment. The inhibition efficiencies for calcium nitrate in cassava fluid and seawater were 26.81% and 64.85% respectively. The study concluded that inorganic inhibitors were effective in inhibiting corrosion in cyanide and chloride contaminated concrete cubes. 展开更多
关键词 INHIBITOR rebar CORROSION STEEL Seawater CASSAVA FLUID
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Effect of Toluene and Dioctylphthalate on the Rebar Corrosion of Medium Carbon Steel in Seawater and Cassava Fluid
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作者 Mohammed Adamu Lasisi Ejibunu Umoru Oladeji Oluremi Ige 《Journal of Minerals and Materials Characterization and Engineering》 2014年第1期1-7,共7页
Chemical mitigation is regularly used as one of the principal prevention and control techniques in reinforcement corrosion. Hence this study presents the effect of toluene and dioctylphthalate on the rebar corrosion o... Chemical mitigation is regularly used as one of the principal prevention and control techniques in reinforcement corrosion. Hence this study presents the effect of toluene and dioctylphthalate on the rebar corrosion of medium carbon steel in seawater and cassava fluid with a view to determining inhibitive potentials of the different inhibitors in the two media. Gravimetric and voltametric techniques were employed in this study and a total of forty-five corrosion coupons of different dimensions were produced. Forty coupons were used for gravimetry and the remaining five for corrosion potentials measurements. Eight of the samples were used as control;while other eight samples were admixed with dioctylphthalate and toluene in concrete cubes. It was later immersed in seawater and cassava fluid for a total duration of 32 days and the measurements were taken at interval of 4 days in order to determine the corrosion rates in mils per year (mmpy). Two controls and admixed samples were later immersed in seawater and cassava fluid, respectively, for durations of thirty-two days to determine the corrosion potentials using a voltmeter and a Copper-Copper Sulphate Electrode (Cu/CuSO4). The pH of each medium was also measured throughout the period of exposure. The results obtained showed that all the samples except the control samples, displayed some degree of inhibition. The inhibition levels for the admixed samples in seawater were on the higher side compared with those in cassava fluid. The inhibition efficiencies for different inhibitors followed different trends in different environment. The inhibition efficiencies for toluene in cassava fluid and seawater were 21.64% and 45.78% respectively. The study concluded that organic inhibitors were effective in inhibiting corrosion in cyanide and chloride contaminated concrete cubes. 展开更多
关键词 INHIBITOR rebar CORROSION Steel Seawater CASSAVA FLUID
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Rebar Impalement Injury Throughout Bilateral Hemithorax and Pericardium
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作者 Tevfik Ilker Akcam Ayse Gul Ergonul +2 位作者 Ali Ozdil Alpaslan Cakan Ufuk Cagirici 《Open Journal of Thoracic Surgery》 2015年第3期31-34,共4页
Thoracic traumas have an important place among all injuries as they can cause significant mortality and morbidity. The thoracic injuries are the large part of trauma with head and extremity injuries. Thoracic traumas ... Thoracic traumas have an important place among all injuries as they can cause significant mortality and morbidity. The thoracic injuries are the large part of trauma with head and extremity injuries. Thoracic traumas are divided into two groups, including penetrating and blunt. The primary causes for penetrating traumas are wounds caused by gunshot and sharp objects. The lungs are the most injured organ in penetrating thoracic traumas with many organ injuries accompanied. This case report is about a rebar impalement into bilateral hemitoraces and pericardium after falling down in spite of any injury is not occurred in heart, lung and great vessels. The fact that an injury to such an extent does not cause any intrathoracic catastrophic event is something that has not been reported in the past. 展开更多
关键词 rebar INJURY Hemithoraces PERICARDIUM
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Mechanical behavior of segment rebar of shield tunnel in construction stage 被引量:11
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作者 Jun-sheng CHEN Hai-hong MO 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2008年第7期888-899,共12页
In this paper,a 3D finite element(FE) program ADINA was applied to analyzing a tunnel with 9 segment rings. The loads acting on these segment rings included the squeezing action of tail brush of shield machine under a... In this paper,a 3D finite element(FE) program ADINA was applied to analyzing a tunnel with 9 segment rings. The loads acting on these segment rings included the squeezing action of tail brush of shield machine under attitude deflection,the jacking forces,the grouting pressure and the soil pressure. The analyses focused on the rebar stress in two statuses:(1) normal construction status without shield machine squeezing;(2) squeezing action induced by shield machine under attitude deflection. The analyses indicated that the rebar stress was evidently affected by the construction loads. In different construction status,the rebar stress ranges from -80 MPa to 50 MPa,and the rebar is in elastic status. Even some cracks appear on segments,the stress of segment rebar is still at a low level. It is helpful to incorporate a certain quantity of steel fiber to improve the anti-crack and shock resistance performance. 展开更多
关键词 隧道 螺纹钢筋 有限元法 力学行为
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Bond strength improvement of GFRP rebars with different rib geometries 被引量:12
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作者 HAO Qing-duo WANG Yan-lei +1 位作者 ZHANG Zhi-chun OU Jin-ping 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2007年第9期1356-1365,共10页
Based on the Canadian Standards Association (CSA) criteria,105 pullout specimens were tested to investigate the effect of different rib geometries on bond strength of glass fiber reinforced polymer (GFRP) rebars embed... Based on the Canadian Standards Association (CSA) criteria,105 pullout specimens were tested to investigate the effect of different rib geometries on bond strength of glass fiber reinforced polymer (GFRP) rebars embedded in concrete. Two kinds of conventional reinforcing rebars were also studied for comparison. Each rebar was embedded in a 150 mm concrete cube,with the embedded length being four times the rebar diameter. The experimental parameters were the rebar type,rebar component,rebar diameter,rebar surface texture,rib height,rib spacing and rib width. Theoretical analysis was also carried out to explain the experimental phenomena and results. The experimental and theoretical results indicated that the bond strength of GFRP rebars was about 13%~35% lower than that of steel rebars. The bond strength and bond-slip behavior of the specially machined rebars varied with the rebar type,rebar diameter,rebar surface texture,rib height,rib spacing and rib width. Using the results,design recom-mendations were made concerning optimum rib geometries of GFRP ribbed rebars with superior bond-slip characteristics,which concluded that the optimal rib spacing of ribbed rebars is the same as the rebar diameter,and that the optimal rib height is 6% of the rebar diameter. 展开更多
关键词 玻璃纤维增强聚合物钢筋 钢筋混凝土 拉拔试验 键强度
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Effect of Ca(OH)_2, NaCl, and Na_2SO_4 on the corrosion and electrochemical behavior of rebar 被引量:2
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作者 金祖权 赵霞 +2 位作者 赵铁军 侯保荣 刘影 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2017年第3期681-692,共12页
The corrosion of rebar in reinforced concrete in marine environments causes significant damage to structures built in ocean environments. Studies on the process and mechanism of corrosion of rebar in the presence of m... The corrosion of rebar in reinforced concrete in marine environments causes significant damage to structures built in ocean environments. Studies on the process and mechanism of corrosion of rebar in the presence of multiple ions may help to control damage and predict the service life of reinforced concrete structures in such environments. The effect of interactions between sulfate and chloride ions and calcium hydroxide on the electrochemical behavior of rebar are also important for evaluation of structure durability. In this work, electrochemical impedance spectroscopy(EIS) plots of rebar in Ca(OH)_2 solution and cement grout, including NaCl and Na_2SO_4 as aggressive salts, were measured for different immersion times. The results show that corrosion of rebar was controlled by the rate of charge transfer as the rebar was exposed to chloride solution. In the presence of high concentrations of sulfate ions in the electrolyte, generation and dissolution of the passive film proceeded simultaneously and corrosion was mainly controlled by the diffusion rate. When Na_2SO_4 and NaCl were added to Ca(OH)_2 solution, the instantaneous corrosion rate decreased by a factor of 10 to 20 as a result of the higher p H of the corroding solution. 展开更多
关键词 NA2SO4 钢筋锈蚀 腐蚀控制 电化学行为 NACL CA(OH)2 钢筋混凝土结构 CA(OH)2
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Electrochemical study on semiconductive properties of the passive film on rebar in concrete 被引量:4
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作者 ZHANG Yun-lian LI Qi-ling 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2006年第8期1447-1452,共6页
The electrochemical behavior of metallic passive film on rebar in concrete is characterized by its semiconductive nature. The charge distribution at the interface between a semiconductor and an electrolyte is often de... The electrochemical behavior of metallic passive film on rebar in concrete is characterized by its semiconductive nature. The charge distribution at the interface between a semiconductor and an electrolyte is often determined by measuring the capacitance of the space-charge layer (CSC) as a function of the electrode potential (E). When the space charge-layer serves as the depletion layer, the relation of CS?C2 vs E resembles a Mott-Schottky plot (M-S plot). The semiconductive properties of the passive film on rebar in concrete were analyzed with M-S plots to study the effect of chloride ions and mineral admixtures on rebar passive films. Some rebar electrodes were immersed in simulated concrete pore solutions, while others were embedded in concrete with/without mineral admixtures. In saturated Ca(OH)2 solutions, the relation of CS ?C2 -E of rebar electrodes shows linear Mott- Schottky relationship indicating that the passive film on rebar is a highly disordered n-type semiconductor, with donor density (ND) in the order of 1026 m?3. After adding chloride ions (Cl? wt%<0.2%) in system solutions, the M-S plot slopes significantly de-creased and ND increased, suggesting that chloride ion will cause passive film corrosion and breakdown. The M-S plots of the passive film on rebar electrodes embedded in concrete were similar to those immersed in simulated system solution. However, ND of those in concrete with mineral admixtures tended to be a little smaller, indicating that introducing proper quantity admixtures into concrete could make the rebar passive film have a thicker space-charge layer and therefore a thicker passive film layer. 展开更多
关键词 钢筋电极 钝化膜 矿物材料 混凝土 电化学研究 导电性能
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