Clean and efficient recycling of spent lithium-ion batteries(LIBs)has become an urgent need to promote sustainable and rapid development of human society.Therefore,we provide a critical and comprehensive overview of th...Clean and efficient recycling of spent lithium-ion batteries(LIBs)has become an urgent need to promote sustainable and rapid development of human society.Therefore,we provide a critical and comprehensive overview of the various technologies for recycling spent LIBs,starting with lithium-ion power batteries.Recent research on raw material collection,metallurgical recovery,separation and purification is highlighted,particularly in terms of all aspects of economic efficiency,energy consumption,technology transformation and policy management.Mechanisms and pathways for transformative full-component recovery of spent LIBs are explored,revealing a clean and efficient closed-loop recovery mechanism.Optimization methods are proposed for future recycling technologies,with a focus on how future research directions can be industrialized.Ultimately,based on life-cycle assessment,the challenges of future recycling are revealed from the LIBs supply chain and stability of the supply chain of the new energy battery industry to provide an outlook on clean and efficient short process recycling technologies.This work is designed to support the sustainable development of the new energy power industry,to help meet the needs of global decarbonization strategies and to respond to the major needs of industrialized recycling.展开更多
Melamine formaldehyde foam(MFF)generates many poisonous chemicals through the traditional recycling methods for organic resin wastes.Herein,a high MFF degradation ratio of ca.97 wt.%was achieved under the mild conditi...Melamine formaldehyde foam(MFF)generates many poisonous chemicals through the traditional recycling methods for organic resin wastes.Herein,a high MFF degradation ratio of ca.97 wt.%was achieved under the mild conditions(160℃)in a NaOH–H2O system with ammelide and ammeline as the main degradation products.The alkaline solvent had an obvious corrosion effect for MFF,as indicated by scanning electron microscopy(SEM).The reaction process and products distribution were studied by Fourier-transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS),and ^(13)C nuclear magnetic resonance(NMR).Besides,the MFF degradation products that have the similar chemical structures and bonding performances to those of melamine can be directly used as the raw material for synthesis of melamine urea-formaldehyde resins(MUFs).Moreover,the degradation system demonstrated here showed the high degradation efficiency after reusing for 7 times.The degradation process generated few harmful pollutants and no pre-or post-treatments were required,which proves its feasibility in the safe removal or recovery of waste MFF.展开更多
The recycling and reutilization of spent lithium-ion batteries(LIBs)have become an important measure to alleviate problems like resource scarcity and environmental pollution.Although some progress has been made,batter...The recycling and reutilization of spent lithium-ion batteries(LIBs)have become an important measure to alleviate problems like resource scarcity and environmental pollution.Although some progress has been made,battery recycling technology still faces challenges in terms of efficiency,effectiveness and environmental sustainability.This review aims to systematically review and analyze the current status of spent LIB recycling,and conduct a detailed comparison and evaluation of different recycling processes.In addition,this review introduces emerging recycling techniques,including deep eutectic solvents,molten salt roasting,and direct regeneration,with the intent of enhancing recycling efficiency and diminishing environmental repercussions.Furthermore,to increase the added value of recycled materials,this review proposes the concept of upgrading recycled materials into high value-added functional materials,such as catalysts,adsorbents,and graphene.Through life cycle assessment,the paper also explores the economic and environmental impacts of current battery recycling and highlights the importance that future recycling technologies should achieve a balance between recycling efficiency,economics and environmental benefits.Finally,this review outlines the opportunities and challenges of recycling key materials for next-generation batteries,and proposes relevant policy recommendations to promote the green and sustainable development of batteries,circular economy,and ecological civilization.展开更多
Lithium-ion batteries(LIBs)containing graphite as anode material and LiCoO_(2),LiMn_(2)O_(4),and LiNi_(x)Mn_(y)Co_(z)O_(2) as cathode materials are the most used worldwide because of their high energy density,capacita...Lithium-ion batteries(LIBs)containing graphite as anode material and LiCoO_(2),LiMn_(2)O_(4),and LiNi_(x)Mn_(y)Co_(z)O_(2) as cathode materials are the most used worldwide because of their high energy density,capacitance,durability,and safety.However,such widespread use implies the generation of large amounts of electronic waste.It is estimated that more than 11 million ton of LIBs waste will have been generated by 2030.Battery recycling can contribute to minimizing environmental contamination and reducing production costs through the recovery of high-value raw materials such as lithium,cobalt,and nickel.The most common processes used to recycle spent LIBs are pyrometallurgical,biometallurgical,and hydrometallurgical.Given the current scenario,it is necessary to develop environmentally friendly methods to recycle batteries and synthesize materials with multiple technological applications.This study presents a review of industrial and laboratory processes for recycling spent LIBs and producing materials that can be used in new batteries,energy storage devices,electrochemical sensors,and photocatalytic reactions.展开更多
Electric arc furnace dust(EAFD)is a hazardous waste but can also be a potential secondary resource for valuable metals,such as Zn and Fe.Given the increased awareness of carbon emission reduction,energy conservation,a...Electric arc furnace dust(EAFD)is a hazardous waste but can also be a potential secondary resource for valuable metals,such as Zn and Fe.Given the increased awareness of carbon emission reduction,energy conservation,and environmental protection,hydrometallurgical technologies for the detoxification and resource use of EAFD have been developing rapidly.This work summarizes the generation mechanisms,compositions,and characteristics of EAFD and presents a critical review of various hydrometallurgical treatment methods for EAFD,e.g.,acid leaching,alkaline leaching,salt leaching,and pretreatment–enhanced leaching methods.Simultaneously,the phase transformation mechanisms of zinc-containing components in acid and alkali solutions and pretreatment processes are expounded.Finally,two novel combined methods,i.e.,oxygen pressure sulfuric acid leaching combined with composite catalyst preparation,and synergistic roasting of EAFD and municipal solid waste incineration fly ash combined with alkaline leaching,are proposed,which can provide future development directions to completely recycling EAFD by recovering valuable metals and using zinc residue.展开更多
Dining lampblack as a source of atmospheric pollution,urban residents had to spend a lot of economic costs all year round to solve its impact.However,traditional treatment methods often carry the risk of secondary pol...Dining lampblack as a source of atmospheric pollution,urban residents had to spend a lot of economic costs all year round to solve its impact.However,traditional treatment methods often carry the risk of secondary pollution.The use of phase change absorption solvent(PCAS)controlled by CO_(2)can effectively absorb the oily components in dining lampblack,and smoothly avoid the generation of secondary pollutants and squandering of resources.The reversibility of PCASs under CO_(2)control was explained by pH changes and macroscopic visualizations.The absorption effects of favorable absorbents and PCASs on dining lampblack were compared and analyzed.The fatty acid(FA)in the oil absorption mixture was desorbed by interacting with D230.The results of GC/MS analysis on the oil components separated by desorption showed that the desorption of PCASs was effective for these refractory oil components.FAs can be enriched and applied to the subsequent dining lampblack treatment link to realize the waste recycling.In addition,the absorption and desorption of oily components by PCASs were combined with the CO_(2)-controlled phase transformation of PCASs itself to achieve the absorption circulation of treating dining lampblack by using PCASs.展开更多
The synergistic pyrolysis has been increasingly used for recycling spent lithium-ion batteries(LIBs)and organic wastes(hydrogen and carbon sources),which are in-situ transformed into various reducing agents such as H_...The synergistic pyrolysis has been increasingly used for recycling spent lithium-ion batteries(LIBs)and organic wastes(hydrogen and carbon sources),which are in-situ transformed into various reducing agents such as H_(2),CO,and char via carbothermal and/or gas thermal reduction.Compared with the conventional roasting methods,this“killing two birds with one stone”strategy can not only reduce the cost and energy consumption,but also realize the valorization of organic wastes.This paper concluded the research progress in synergistic pyrolysis recycling of spent LIBs and organic wastes.On the one hand,valued metals such as Li,Co,Ni,and Mn can be recovered through the pyrolysis of the cathode materials with inherent organic materials(e.g.,separator,electrolyte)or graphite anode.During the pyrolysis process,the organic materials are decomposed into char and gases(e.g.,CO,H_(2),and CH_(4))as reducing agents,while the cathode material is decomposed and then converted into Li_(2)CO_(3) and low-valent transition metals or their oxides via in-situ thermal reduction.The formed Li_(2)CO_(3) can be easily recovered by the water leaching process,while the formed transition metals or their oxides(e.g.,Co,CoO,Ni,MnO,etc.)can be recovered by the reductant-free acid leaching or magnetic separation process.On the other hand,organic wastes(e.g.,biomass,plastics,etc.)as abundant hydrogen and carbon sources can be converted into gas(e.g.,H_(2),CO,etc.)and char via pyrolysis.The cathode materials are decomposed and subsequently reduced by the pyrolysis gas and char.In addition,the pyrolysis oil and gas can be upgraded by catalytic reforming with the active metals derived from cathode material.Finally,great challenges are proposed to promote this promising technology in the industrial applications.展开更多
Heavy metal(HM)pollution is a serious environment problem.Recovering HM from industrial wastewater by efficient adsorbents is a sustainable method due to recycling HM and acquiring reusable water.However,popular effic...Heavy metal(HM)pollution is a serious environment problem.Recovering HM from industrial wastewater by efficient adsorbents is a sustainable method due to recycling HM and acquiring reusable water.However,popular efficient adsorbents are usually expensive or non-reusable.In this paper,methods of efficient HM recycling and water reuse from industrial wastewater were developed using efficient adsorbents,new polyphenylene sulfide derivatives,which are recyclable and stable in an acidic,alkaline or oxidative aqueous solution.Moreover,they can efficiently and quickly adsorb HM ions.The maximum adsorption capacities of these adsorbents for HM ions are at the range from 51.3-184.2 mg·g^(-1).The adsorption equilibrium times of them for HM ions are at the range from 10 to 80 min.Therefore,this paper suggests sustainable methods of HM recovery and water reuse from industrial wastewater.展开更多
Solid-state lithium batteries(SSLBs)solve safety issues and are potentially energy-dense alternatives to next-generation energy storage systems.Battery green recycling routes are responsible for the widespread use of ...Solid-state lithium batteries(SSLBs)solve safety issues and are potentially energy-dense alternatives to next-generation energy storage systems.Battery green recycling routes are responsible for the widespread use of SSLBs due to minimizing environmental contamination,reducing production costs,and providing a sustainable solution for resources,e.g.,saving rare earth elements(La,Ta,etc.).Herein,a solid-state recycling strategy is proposed to achieve green recycling of the crucial component solidstate electrolytes(SSEs)in spent SSLBs.The short-circuited garnet Li_(6.5)La_(3)Zr_(1.5)Ta_(0.5)O_(12)(LLZTO)is broken into fine particles and mixed with fresh particles to improve sintering activity and achieve high packing density.The continuous Li absorption process promotes sufficient grain fusion and guarantees the transformation from tetragonal phase to pure cubic phase for high-performance recycled LLZTO.The Li-ion conductivity reaches 5.80×10^(-4)S cm-1with a relative density of 95.9%.Symmetric Li cell with asrecycled LLZTO shows long-term cycling stability for 700 h at 0.3 mA cm^(-2)without any voltage hysteresis.Full cell exhibits an excellent cycling performance with a discharge capacity of 141.5 mA h g^(-1)and a capacity retention of 92.1%after 400 cycles(0.2C).This work develops an environmentally friendly and economically controllable strategy to recycle SSE from spent SSLBs,guiding future directions of SSLBs large-scale industrial application and green recycling study.展开更多
Copper-indium-gallium-diselenide(CIGS)is a fast-evolving commercial solar cell.The firm demand for global carbon reduction and the rise of potential environmental threats necessitate spent CIGS solar cell recycling.In...Copper-indium-gallium-diselenide(CIGS)is a fast-evolving commercial solar cell.The firm demand for global carbon reduction and the rise of potential environmental threats necessitate spent CIGS solar cell recycling.In this paper,the sources and characteristics of valuable metals in spent CIGS solar cells were reviewed.The potential environmental impacts of CIGS,including service life,critical material,and material toxicity,were outlined.The main recovery methods of valuable metals in the various types of spent CIGS,including hydrometallurgy,pyrometallurgy,and comprehensive treatment processes,were compared and discussed.The mechanism of different recovery processes was summarized.The challenges faced by different recycling processes of spent CIGS were also covered in this review.Finally,the economic viability of the recycling process was assessed.The purpose of this review is to provide reasonable suggestions for the sustainable development of CIGS and the harmless disposal of spent CIGS.展开更多
Under the background of a transformation of the global energy structure,coal gasification technology has a wide application prospect,but its by-product,the coal gasification residue(CGR),is still not being efficiently...Under the background of a transformation of the global energy structure,coal gasification technology has a wide application prospect,but its by-product,the coal gasification residue(CGR),is still not being efficiently utilized for recycling.The CGR contains abundant carbon components,which could be applied to the microwave absorption field as the carbon matrix.In this study,Fe/CGR composites are fabricated via a two-step method,including the impregnation of Fe^(3+)and the reduction process.The influence of the different loading capacities of the Fe component on the morphology and electromagnetic properties is studied.Moreover,the loading content of Fe and the surface morphology of the Fe/CGR can be reasonably controlled by adjusting the concentration of the ferric nitrate solution.Meanwhile,Fe particles are evenly inserted on the CGR framework,which expands the Fe/CGR interfaces to enhance interfacial polarization,thus further improving the microwave-absorbing(MA)properties of composites.Particularly,as the Fe^(3+)concentration is 1.0 mol/L,the Fe/CGR composite exhibits outstanding performance.The reflection loss reaches-39.3 dB at 2.5 mm,and the absorption bandwidth covers 4.1 GHz at 1.5 mm.In this study,facile processability,resource recycling,appropriately matched impedance,and excellent MA performance are achieved.Finally,the Fe/CGR composites not only enhance the recycling of the CGR but also pioneer a new path for the synthesis of excellent absorbents.展开更多
Recently,urbanization becomes a major concern for developing as well as developed countries.Owing to the increased urbanization,one of the important challenging issues in smart cities is waste management.So,automated ...Recently,urbanization becomes a major concern for developing as well as developed countries.Owing to the increased urbanization,one of the important challenging issues in smart cities is waste management.So,automated waste detection and classification model becomes necessary for the smart city and to accomplish better recyclable waste management.Effective recycling of waste offers the chance of reducing the quantity of waste disposed to the land fill by minimizing the requirement of collecting raw materials.This study develops a novel Deep Consensus Network with Whale Optimization Algorithm for Recycling Waste Object Detection(DCNWORWOD)in Smart Cities.The goal of the DCNWO-RWOD technique intends to properly identify and classify the objects into recyclable and non-recyclable ones.The proposed DCNWO-RWOD technique involves the design of deep consensus network(DCN)to detect waste objects in the input image.For improving the overall object detection performance of the DCN model,the whale optimization algorithm(WOA)is exploited.Finally,Na飗e Bayes(NB)classifier is used for the classification of detected waste objects into recyclable and non-recyclable ones.The performance validation of theDCNWO-RWOD technique takes place using the open access dataset.The extensive comparative study reported the enhanced performance of the DCNWO-RWOD technique interms of several measures.展开更多
Pb contamination in aquatic environments causes severe pollution;therefore,harmless absorbents are required.In this study,we report a novel synthesis of whitlockite(WH,Ca_(18)Mg_(2)(HPO_(4))_(2)(PO_(4))_(12)),which is...Pb contamination in aquatic environments causes severe pollution;therefore,harmless absorbents are required.In this study,we report a novel synthesis of whitlockite(WH,Ca_(18)Mg_(2)(HPO_(4))_(2)(PO_(4))_(12)),which is the second most abundant biomineral in human bone,and its application as a high-performing Pb^(2+)absorbent.Hydroxyapatite(HAP)and WH are prepared via a simple precipitation method.The Pb2+absorption performance and mechanism of the synthesized biominerals are investigated in aqueous solutions at neutral pH.The results demonstrate that WH exhibits an excellent Pb2+absorption capacity of 2339 mg g^(−1),which is 1.68 times higher than the recorded value for HAP.Furthermore,the absorbed Pb^(2+) ions are recycled into high-purity PbI_(2).This is employed as a precursor for the fabrication of perovskite solar cells(PSCs),resulting in a conversion efficiency of 19.00%comparable to that of commercial PbI2 powder(99.99%purity).Our approach provides an efficient way to remove Pb^(2+)ions from water and reuse them in the recycling of PSCs.展开更多
Electrical and electronic waste(e-waste)is a growing challenge,matching the widespread boom in the use of information and communication technology.Opposite to an alarming increasing amount of e-waste,a low rate of con...Electrical and electronic waste(e-waste)is a growing challenge,matching the widespread boom in the use of information and communication technology.Opposite to an alarming increasing amount of e-waste,a low rate of consumer engagement in ensuring the proper disposal of such materials intensifies the pressure on the exist‐ing e-waste crisis.To deal with this thorny problem,it is of great interest to grasp consumers’disposal and re‐cycling behavioral intentions.Therefore,this study attempts to understand complementary perspectives around consumers’e-waste recycling intention based on the integration of the valence theory and the norm activation theory.Four data mining models using classification and prediction-based algorithms,namely Chi squared automatic interaction detector(CHAID),Neural network,Discriminant analysis,and Quick,unbiased,efficient statistical tree(QUEST),were employed to analyze a set of the 398 data collected in Vietnam.The re‐sults revealed that the social support value is by far the most critical predictor,followed by the utilitarian value,task difficulty,and monetary risk.It is also noteworthy that the awareness of consequences,education background,the ascription of responsibility,and age were also ranked as critical affecting factors.The lowest influential predictors found in this study were income and gender.In addition,a comparison was made in terms of the classification performance of the four utilized data mining techniques.Based on several evalua‐tion measurements(confusion matrix,accuracy,precision,recall,specificity,F-measure,ROC curve,and AUC),the aggregated results suggested that CHAID and Neural network performed the best.The findings of this research are expected to assist policymakers and future researchers in updating all information surround‐ing consumer behavioral intention-related topics focusing on e-waste.Furthermore,the adoption of data min‐ing algorithms for prediction is another insight of this study,which may shed the light on data mining applica‐tions in such environmental studies in the future.展开更多
Greenhouse gas emissions from waste plastics have caused global warming all over the world,which has been a central threat to the ecological environment for humans,flora and fauna.Among waste plastics,waste polyethyle...Greenhouse gas emissions from waste plastics have caused global warming all over the world,which has been a central threat to the ecological environment for humans,flora and fauna.Among waste plastics,waste polyethylene terephthalate(PET)is attractive due to its excellent stability and degradation-resistant.Therefore,merging China’s carbon peak and carbon neutrality goals would be beneficial.In this review,we summarize the current state-of-the-art of carbon emission decrease from a multi-scale perspective technologically.We suggest that the carbon peak for waste PET can be achieved by employing the closed-loop supply chain,including recycling,biomass utilization,carbon capture and utilization.Waste PET can be a valuable and renewable resource in the whole life cycle.Undoubtedly,all kinds of PET plastics can be ultimately converted into CO_(2),which can also be feedstock for various kinds of chemical products,including ethyl alcohol,formic acid,soda ash,PU,starch and so on.As a result,the closed-loop supply chain can help the PET plastics industry drastically reduce its carbon footprint.展开更多
The growing number of decarbonization standards in the transportation sector has resulted in an increase in demand for electric cars.Renewable energy sources have the ability to bring the fossil fuel age to an end.Ele...The growing number of decarbonization standards in the transportation sector has resulted in an increase in demand for electric cars.Renewable energy sources have the ability to bring the fossil fuel age to an end.Electrochemical storage devices,particularly lithium-ion batteries,are critical for this transition’s success.This is owing to a combination of favorable characteristics such as high energy density and minimal self-discharge.Given the environmental degradation caused by hazardous wastes and the scarcity of some resources,recycling used lithium-ion batteries has significant economic and practical importance.Many efforts have been undertaken in recent years to recover cathode materials(such as high-value metals like cobalt,nickel,and lithium).Regrettably,the regeneration of lower-value-added anode materials(mostly graphite)has received little attention.However,given the widespread use of carbon-based materials and the higher concentration of lithium in the anode than in the environment,anode recycling has gotten a lot of attention.As a result,this article provides the most recent research progress in the recovery of graphite anode materials from spent lithium ion batteries,analyzing the strengths and weaknesses of various recovery routes such as direct physical recovery,heat treatment recovery,hydrometallurgy recovery,heat treatment-hydrometallurgy recovery,extraction,and electrochemical methods from the perspectives of energy,environment,and economy;additionally,the reuse of recycled anode mats is discussed.Finally,the problems and future possibilities of anode recycling are discussed.To enable the green recycling of wasted lithium ion batteries,a low energy-consuming and ecologically friendly solution should be investigated.展开更多
The deterioration of recycled fibers especially unbleached kraft with high wet strength resin content due to the irreversible structural changes caused by drying and added chemicals makes the raw material difficult to...The deterioration of recycled fibers especially unbleached kraft with high wet strength resin content due to the irreversible structural changes caused by drying and added chemicals makes the raw material difficult to repulp.The mechanical effect in the pulper over time with chemical treatment has a negative impact on the recycled fibers.At lab scale,different compositions of enzymatic treatment C022L were under investigation to select the most efficient laccase Lacc1,Lacc2 or Lacc3 and to observe the impact of lipases during repulping at low and high consistencies.Pulp disintegration at different times was evaluated to define the level of rejects and to analyze the morphology of fibers after treatments.These results were more significant for Lacc2,by increasing the pulp consistency to 15%in the pulper.Combining lipases with CELODASE 022L appeared to decrease the efficiency of enzymes.The results showed a high reduction of energy power with the enzymatic treatment and a significant reduction of fines level in fibers’suspension.The most efficient version of C022L was used at industrial scale to compare directly with the standard conditions used in a paper mill.展开更多
Now, a rapidly growing concern for the environmental protection and resource utilization has stimulated many new activities in the in dustrialized world for coping with urgent environmental problems created by the ste...Now, a rapidly growing concern for the environmental protection and resource utilization has stimulated many new activities in the in dustrialized world for coping with urgent environmental problems created by the steadily increasing consumption of industrial products. Increasingly stringent r egulations and widely expressed public concern for the environment highlight the importance of disposing solid waste generated from industrial and consumable pr oducts. How to efficiently recycle and tackle this problem has been a very impo rtant issue over the world. Designing products for recyclability is driven by environmental and economic goals. To obtain good recyclability, two measures can be adopted. One is better recycling strategy and technology; the other is design for recycling (DFR). The recycling strategies of products generally inclu de: reuse, service, remanufacturing, recycling of production scraps during the p roduct usage, recycle (separation first) and disposal. Recyclability assessment is a very important content in DFR. This paper first discusses the content of D FR and strategies and types related to products recyclability, and points out th at easy or difficult recyclability depends on the design phase. Then method and procedure of recyclability assessment based on ANN is explored in detail. The pr ocess consists of selection of the ANN input and output parameters, control of t he sample quality and construction and training of the neural network. At la st, the case study shows this method is simple and operative.展开更多
Increasing production and use of various novel plastics products,a low recycling rate,and lack of effective recycling/disposal methods have resulted in an exponential growth in plastic waste accumulation in landfills ...Increasing production and use of various novel plastics products,a low recycling rate,and lack of effective recycling/disposal methods have resulted in an exponential growth in plastic waste accumulation in landfills and in the environment.To better understand the effects of plastic waste,Life Cycle Analysis(LCA)was done to compare the effects of various production and disposal methods.LCA shows the specific effects of the cradle-to-grave or cradle-to-cradle scenarios for landfill,incineration,and mechanical recycling.The analysis clearly indicates that increasing recycling of plastics can significantly save energy and eliminate harmful emissions of various carcinogens and GHGs into the environment.As recycling increases,the need for virgin-plastic production can be greatly reduced.Furthermore,the results of this study may help improve current mechanical recycling processes as well as potential future recycling methods,such as chemical recycling.Concerns about the current recycling/disposal methods for plastics have brought increasing attention to the waste accumulation problem.However,with the current COVID-19 pandemic,plastic accumulation is expected to increase significantly in the near future.A better understanding of the quantitative effects of the various disposal methods can help guide policies and future research toward effective solutions of the plastic waste problem.展开更多
Moisture contribution and transport pathways for Central Asia(CA)are quantitatively examined using the Lagrangian water cycle model based on reanalysis and observational data to explain the precipitation seasonality a...Moisture contribution and transport pathways for Central Asia(CA)are quantitatively examined using the Lagrangian water cycle model based on reanalysis and observational data to explain the precipitation seasonality and the moisture transport variation during 1979-2015.Westerly-related(northwesterly and westerly)transport explains 42%of CA precipitation and dominates in southwest CA,where precipitation is greatest in the cold season.Southeast CA,including part of Northwest China,experiences its maximum precipitation in the warm season and is solely dominated by southerly transport,which explains about 48%of CA precipitation.The remaining 10%of CA precipitation is explained by northerly transport,which steadily impacts north CA and causes a maximum in precipitation in the warm season.Most CA areas are exposed to seasonally varying moisture transport,except for southeast and north CA,which are impacted by southerly and northerly transport year-round.In general,the midlatitude westerlies-driven transport and the Indian monsoon-driven southerly-related transport explain most of the spatial differences in precipitation seasonality over CA.Moreover,the contribution ratio of local evaporation in CA to precipitation exhibits significant interdecadal variability and a meridionally oriented tripole of moisture transport anomalies.Since the early 2000s,CA has experienced a decade of anomalously low local moisture contribution,which seems jointly determined by the weakened moisture contribution from midlatitudes(the Atlantic,Europe,and CA itself)and the enhanced contribution from high latitudes(West Siberia and the Arctic)and tropical areas(South Asia and the Indian Ocean).展开更多
基金supported by the National Key R&D Program of China,China(2022YFC3902600)CAS Project for Young Scientists in Basic Research,China(YSBR-044)+1 种基金Guangdong Basic and Applied Basic Research Foundation,China(2021B1515020068)China Postdoctoral Science Foundation,China(2023M733510).
文摘Clean and efficient recycling of spent lithium-ion batteries(LIBs)has become an urgent need to promote sustainable and rapid development of human society.Therefore,we provide a critical and comprehensive overview of the various technologies for recycling spent LIBs,starting with lithium-ion power batteries.Recent research on raw material collection,metallurgical recovery,separation and purification is highlighted,particularly in terms of all aspects of economic efficiency,energy consumption,technology transformation and policy management.Mechanisms and pathways for transformative full-component recovery of spent LIBs are explored,revealing a clean and efficient closed-loop recovery mechanism.Optimization methods are proposed for future recycling technologies,with a focus on how future research directions can be industrialized.Ultimately,based on life-cycle assessment,the challenges of future recycling are revealed from the LIBs supply chain and stability of the supply chain of the new energy battery industry to provide an outlook on clean and efficient short process recycling technologies.This work is designed to support the sustainable development of the new energy power industry,to help meet the needs of global decarbonization strategies and to respond to the major needs of industrialized recycling.
基金supported by the National Natural Science Foundation of China(No.21774139)China,Key Research and Development Program of Shanxi Province,China(No,202102040201009)special fund of Beijing Key Laboratory of Clean Fuels and Efficient Catalytic Emission Reduction Technology and the Fund for Shanxi“1331 Project”.Thanks to Ningbo Kejiang Culture Sci.&Tech.Development Co.,Ltd.for the help in schematic drawing。
文摘Melamine formaldehyde foam(MFF)generates many poisonous chemicals through the traditional recycling methods for organic resin wastes.Herein,a high MFF degradation ratio of ca.97 wt.%was achieved under the mild conditions(160℃)in a NaOH–H2O system with ammelide and ammeline as the main degradation products.The alkaline solvent had an obvious corrosion effect for MFF,as indicated by scanning electron microscopy(SEM).The reaction process and products distribution were studied by Fourier-transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS),and ^(13)C nuclear magnetic resonance(NMR).Besides,the MFF degradation products that have the similar chemical structures and bonding performances to those of melamine can be directly used as the raw material for synthesis of melamine urea-formaldehyde resins(MUFs).Moreover,the degradation system demonstrated here showed the high degradation efficiency after reusing for 7 times.The degradation process generated few harmful pollutants and no pre-or post-treatments were required,which proves its feasibility in the safe removal or recovery of waste MFF.
基金financially supported by the National Natural Science Foundation of China(NSFC)(52274295)the Natural Science Foundation of Hebei Province(E2020501001,E2021501029,A2021501007,E2022501028,E2022501029)+5 种基金the Natural Science Foundation-Steel,the Iron Foundation of Hebei Province(No.E2022501030)the Performance subsidy fund for Key Laboratory of Dielectric and Electrolyte Functional Material Hebei Province(22567627H)the Science and Technology Project of Hebei Education Department(ZD2022158)the Central Guided Local Science and Technology Development Fund Project of Hebei province(226Z4401G)the China Scholarship Council(No.202206080061,202206050119)the 2023 Hebei Provincial Postgraduate Student Innovation Ability training funding project(CXZZSS2023195)。
文摘The recycling and reutilization of spent lithium-ion batteries(LIBs)have become an important measure to alleviate problems like resource scarcity and environmental pollution.Although some progress has been made,battery recycling technology still faces challenges in terms of efficiency,effectiveness and environmental sustainability.This review aims to systematically review and analyze the current status of spent LIB recycling,and conduct a detailed comparison and evaluation of different recycling processes.In addition,this review introduces emerging recycling techniques,including deep eutectic solvents,molten salt roasting,and direct regeneration,with the intent of enhancing recycling efficiency and diminishing environmental repercussions.Furthermore,to increase the added value of recycled materials,this review proposes the concept of upgrading recycled materials into high value-added functional materials,such as catalysts,adsorbents,and graphene.Through life cycle assessment,the paper also explores the economic and environmental impacts of current battery recycling and highlights the importance that future recycling technologies should achieve a balance between recycling efficiency,economics and environmental benefits.Finally,this review outlines the opportunities and challenges of recycling key materials for next-generation batteries,and proposes relevant policy recommendations to promote the green and sustainable development of batteries,circular economy,and ecological civilization.
基金the Brazilian Federal Agency for Support and Evaluation of Graduate Education(CAPES)the Brazilian National Council for Scientific and Technological Development(CNPq,306239/2019-1)for their financial support。
文摘Lithium-ion batteries(LIBs)containing graphite as anode material and LiCoO_(2),LiMn_(2)O_(4),and LiNi_(x)Mn_(y)Co_(z)O_(2) as cathode materials are the most used worldwide because of their high energy density,capacitance,durability,and safety.However,such widespread use implies the generation of large amounts of electronic waste.It is estimated that more than 11 million ton of LIBs waste will have been generated by 2030.Battery recycling can contribute to minimizing environmental contamination and reducing production costs through the recovery of high-value raw materials such as lithium,cobalt,and nickel.The most common processes used to recycle spent LIBs are pyrometallurgical,biometallurgical,and hydrometallurgical.Given the current scenario,it is necessary to develop environmentally friendly methods to recycle batteries and synthesize materials with multiple technological applications.This study presents a review of industrial and laboratory processes for recycling spent LIBs and producing materials that can be used in new batteries,energy storage devices,electrochemical sensors,and photocatalytic reactions.
基金financially supported by the National Natural Science Foundation of China(No.52074035)the Fundamental Research Funds for the Central Universities(No.00007720)the National Key Research and Development Program of China(No.2020YFC1910000)。
文摘Electric arc furnace dust(EAFD)is a hazardous waste but can also be a potential secondary resource for valuable metals,such as Zn and Fe.Given the increased awareness of carbon emission reduction,energy conservation,and environmental protection,hydrometallurgical technologies for the detoxification and resource use of EAFD have been developing rapidly.This work summarizes the generation mechanisms,compositions,and characteristics of EAFD and presents a critical review of various hydrometallurgical treatment methods for EAFD,e.g.,acid leaching,alkaline leaching,salt leaching,and pretreatment–enhanced leaching methods.Simultaneously,the phase transformation mechanisms of zinc-containing components in acid and alkali solutions and pretreatment processes are expounded.Finally,two novel combined methods,i.e.,oxygen pressure sulfuric acid leaching combined with composite catalyst preparation,and synergistic roasting of EAFD and municipal solid waste incineration fly ash combined with alkaline leaching,are proposed,which can provide future development directions to completely recycling EAFD by recovering valuable metals and using zinc residue.
基金supported by the Chengdu Science and Technology Project of the Chengdu Bureau of Science and Technology(2021-YF05-00194-SN)the Foundation of Department of Science and Technology of Sichuan Province(2022NSFSC0203)。
文摘Dining lampblack as a source of atmospheric pollution,urban residents had to spend a lot of economic costs all year round to solve its impact.However,traditional treatment methods often carry the risk of secondary pollution.The use of phase change absorption solvent(PCAS)controlled by CO_(2)can effectively absorb the oily components in dining lampblack,and smoothly avoid the generation of secondary pollutants and squandering of resources.The reversibility of PCASs under CO_(2)control was explained by pH changes and macroscopic visualizations.The absorption effects of favorable absorbents and PCASs on dining lampblack were compared and analyzed.The fatty acid(FA)in the oil absorption mixture was desorbed by interacting with D230.The results of GC/MS analysis on the oil components separated by desorption showed that the desorption of PCASs was effective for these refractory oil components.FAs can be enriched and applied to the subsequent dining lampblack treatment link to realize the waste recycling.In addition,the absorption and desorption of oily components by PCASs were combined with the CO_(2)-controlled phase transformation of PCASs itself to achieve the absorption circulation of treating dining lampblack by using PCASs.
基金supported by the National Key Research and Development Program of China(Grant 2022YFC3701504)。
文摘The synergistic pyrolysis has been increasingly used for recycling spent lithium-ion batteries(LIBs)and organic wastes(hydrogen and carbon sources),which are in-situ transformed into various reducing agents such as H_(2),CO,and char via carbothermal and/or gas thermal reduction.Compared with the conventional roasting methods,this“killing two birds with one stone”strategy can not only reduce the cost and energy consumption,but also realize the valorization of organic wastes.This paper concluded the research progress in synergistic pyrolysis recycling of spent LIBs and organic wastes.On the one hand,valued metals such as Li,Co,Ni,and Mn can be recovered through the pyrolysis of the cathode materials with inherent organic materials(e.g.,separator,electrolyte)or graphite anode.During the pyrolysis process,the organic materials are decomposed into char and gases(e.g.,CO,H_(2),and CH_(4))as reducing agents,while the cathode material is decomposed and then converted into Li_(2)CO_(3) and low-valent transition metals or their oxides via in-situ thermal reduction.The formed Li_(2)CO_(3) can be easily recovered by the water leaching process,while the formed transition metals or their oxides(e.g.,Co,CoO,Ni,MnO,etc.)can be recovered by the reductant-free acid leaching or magnetic separation process.On the other hand,organic wastes(e.g.,biomass,plastics,etc.)as abundant hydrogen and carbon sources can be converted into gas(e.g.,H_(2),CO,etc.)and char via pyrolysis.The cathode materials are decomposed and subsequently reduced by the pyrolysis gas and char.In addition,the pyrolysis oil and gas can be upgraded by catalytic reforming with the active metals derived from cathode material.Finally,great challenges are proposed to promote this promising technology in the industrial applications.
基金supported by National Natural Science Foundation of China(21473092)Industry-University-Research Cooperation Project of Jiangsu Province(BY2021600)Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX21_0985 and SJCX21_0375)。
文摘Heavy metal(HM)pollution is a serious environment problem.Recovering HM from industrial wastewater by efficient adsorbents is a sustainable method due to recycling HM and acquiring reusable water.However,popular efficient adsorbents are usually expensive or non-reusable.In this paper,methods of efficient HM recycling and water reuse from industrial wastewater were developed using efficient adsorbents,new polyphenylene sulfide derivatives,which are recyclable and stable in an acidic,alkaline or oxidative aqueous solution.Moreover,they can efficiently and quickly adsorb HM ions.The maximum adsorption capacities of these adsorbents for HM ions are at the range from 51.3-184.2 mg·g^(-1).The adsorption equilibrium times of them for HM ions are at the range from 10 to 80 min.Therefore,this paper suggests sustainable methods of HM recovery and water reuse from industrial wastewater.
基金supported by the China National Postdoctoral Program for Innovative Talents(BX20220384)the National Natural Science Foundation of China(52175301)。
文摘Solid-state lithium batteries(SSLBs)solve safety issues and are potentially energy-dense alternatives to next-generation energy storage systems.Battery green recycling routes are responsible for the widespread use of SSLBs due to minimizing environmental contamination,reducing production costs,and providing a sustainable solution for resources,e.g.,saving rare earth elements(La,Ta,etc.).Herein,a solid-state recycling strategy is proposed to achieve green recycling of the crucial component solidstate electrolytes(SSEs)in spent SSLBs.The short-circuited garnet Li_(6.5)La_(3)Zr_(1.5)Ta_(0.5)O_(12)(LLZTO)is broken into fine particles and mixed with fresh particles to improve sintering activity and achieve high packing density.The continuous Li absorption process promotes sufficient grain fusion and guarantees the transformation from tetragonal phase to pure cubic phase for high-performance recycled LLZTO.The Li-ion conductivity reaches 5.80×10^(-4)S cm-1with a relative density of 95.9%.Symmetric Li cell with asrecycled LLZTO shows long-term cycling stability for 700 h at 0.3 mA cm^(-2)without any voltage hysteresis.Full cell exhibits an excellent cycling performance with a discharge capacity of 141.5 mA h g^(-1)and a capacity retention of 92.1%after 400 cycles(0.2C).This work develops an environmentally friendly and economically controllable strategy to recycle SSE from spent SSLBs,guiding future directions of SSLBs large-scale industrial application and green recycling study.
基金financially supported by the Beijing Natural Science Foundation of China (No. 2232038)the National Natural Science Foundation of China (Nos. 52034002 and U1802253)the Fundamental Research Funds for the Central Universities (No. FRF-TT-19-001)
文摘Copper-indium-gallium-diselenide(CIGS)is a fast-evolving commercial solar cell.The firm demand for global carbon reduction and the rise of potential environmental threats necessitate spent CIGS solar cell recycling.In this paper,the sources and characteristics of valuable metals in spent CIGS solar cells were reviewed.The potential environmental impacts of CIGS,including service life,critical material,and material toxicity,were outlined.The main recovery methods of valuable metals in the various types of spent CIGS,including hydrometallurgy,pyrometallurgy,and comprehensive treatment processes,were compared and discussed.The mechanism of different recovery processes was summarized.The challenges faced by different recycling processes of spent CIGS were also covered in this review.Finally,the economic viability of the recycling process was assessed.The purpose of this review is to provide reasonable suggestions for the sustainable development of CIGS and the harmless disposal of spent CIGS.
基金supported by the National Nature Science Foundation of China(No.51802212)the National College Students’Innovation and Entrepreneurship Training Program(No.2021465)+2 种基金the Natural Science Foundation of Shanxi Province,China(No.201801D221119)the Open Foundation of China-Belarus Belt and Road Joint Laboratory on Electromagnetic Environment Effect(Nos.ZBKF2022030802 and ZBKF2022030702)the Graduate Education Innovation Programs of Taiyuan University of Science and Technology(No.XCX212003)。
文摘Under the background of a transformation of the global energy structure,coal gasification technology has a wide application prospect,but its by-product,the coal gasification residue(CGR),is still not being efficiently utilized for recycling.The CGR contains abundant carbon components,which could be applied to the microwave absorption field as the carbon matrix.In this study,Fe/CGR composites are fabricated via a two-step method,including the impregnation of Fe^(3+)and the reduction process.The influence of the different loading capacities of the Fe component on the morphology and electromagnetic properties is studied.Moreover,the loading content of Fe and the surface morphology of the Fe/CGR can be reasonably controlled by adjusting the concentration of the ferric nitrate solution.Meanwhile,Fe particles are evenly inserted on the CGR framework,which expands the Fe/CGR interfaces to enhance interfacial polarization,thus further improving the microwave-absorbing(MA)properties of composites.Particularly,as the Fe^(3+)concentration is 1.0 mol/L,the Fe/CGR composite exhibits outstanding performance.The reflection loss reaches-39.3 dB at 2.5 mm,and the absorption bandwidth covers 4.1 GHz at 1.5 mm.In this study,facile processability,resource recycling,appropriately matched impedance,and excellent MA performance are achieved.Finally,the Fe/CGR composites not only enhance the recycling of the CGR but also pioneer a new path for the synthesis of excellent absorbents.
基金The authors extend their appreciation to the Deanship of Scientific Research at King Khalid University for funding this work under grant number(RGP2/42/43)Princess Nourah bint Abdulrahman UniversityResearchers Supporting Project number(PNURSP2022R114)Princess Nourah bint Abdulrahman University,Riyadh,Saudi Arabia.
文摘Recently,urbanization becomes a major concern for developing as well as developed countries.Owing to the increased urbanization,one of the important challenging issues in smart cities is waste management.So,automated waste detection and classification model becomes necessary for the smart city and to accomplish better recyclable waste management.Effective recycling of waste offers the chance of reducing the quantity of waste disposed to the land fill by minimizing the requirement of collecting raw materials.This study develops a novel Deep Consensus Network with Whale Optimization Algorithm for Recycling Waste Object Detection(DCNWORWOD)in Smart Cities.The goal of the DCNWO-RWOD technique intends to properly identify and classify the objects into recyclable and non-recyclable ones.The proposed DCNWO-RWOD technique involves the design of deep consensus network(DCN)to detect waste objects in the input image.For improving the overall object detection performance of the DCN model,the whale optimization algorithm(WOA)is exploited.Finally,Na飗e Bayes(NB)classifier is used for the classification of detected waste objects into recyclable and non-recyclable ones.The performance validation of theDCNWO-RWOD technique takes place using the open access dataset.The extensive comparative study reported the enhanced performance of the DCNWO-RWOD technique interms of several measures.
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korea Government(MSIT)(NRF-2018M3C1B7021994)the Technology Development Program to Solve Climate Changes(2018M1A2A2058207)+3 种基金Institute of Information&Communications Technology Planning&Evaluation(IITP)grant funded by the Korea Government(MSIT)(No.2020-0-00541,Flexible Photovoltaic Device Module with Autonomous Power Supply for Smart Farm Wireless Composite IoT Sensor)Korea Institute of Energy Technology Evaluation and Planning(KETEP)grant funded by the Korea government(MOTIE)(20203040010320)the Korea Evaluation Institute of Industrial Technology(KEIT)(20016588)funded by the Korea Governmentsupported by the Research Institute of Advanced Materials(RIAM)and National Center for Inter-university Research Facilities(NCIRF)at Seoul National University.
文摘Pb contamination in aquatic environments causes severe pollution;therefore,harmless absorbents are required.In this study,we report a novel synthesis of whitlockite(WH,Ca_(18)Mg_(2)(HPO_(4))_(2)(PO_(4))_(12)),which is the second most abundant biomineral in human bone,and its application as a high-performing Pb^(2+)absorbent.Hydroxyapatite(HAP)and WH are prepared via a simple precipitation method.The Pb2+absorption performance and mechanism of the synthesized biominerals are investigated in aqueous solutions at neutral pH.The results demonstrate that WH exhibits an excellent Pb2+absorption capacity of 2339 mg g^(−1),which is 1.68 times higher than the recorded value for HAP.Furthermore,the absorbed Pb^(2+) ions are recycled into high-purity PbI_(2).This is employed as a precursor for the fabrication of perovskite solar cells(PSCs),resulting in a conversion efficiency of 19.00%comparable to that of commercial PbI2 powder(99.99%purity).Our approach provides an efficient way to remove Pb^(2+)ions from water and reuse them in the recycling of PSCs.
文摘Electrical and electronic waste(e-waste)is a growing challenge,matching the widespread boom in the use of information and communication technology.Opposite to an alarming increasing amount of e-waste,a low rate of consumer engagement in ensuring the proper disposal of such materials intensifies the pressure on the exist‐ing e-waste crisis.To deal with this thorny problem,it is of great interest to grasp consumers’disposal and re‐cycling behavioral intentions.Therefore,this study attempts to understand complementary perspectives around consumers’e-waste recycling intention based on the integration of the valence theory and the norm activation theory.Four data mining models using classification and prediction-based algorithms,namely Chi squared automatic interaction detector(CHAID),Neural network,Discriminant analysis,and Quick,unbiased,efficient statistical tree(QUEST),were employed to analyze a set of the 398 data collected in Vietnam.The re‐sults revealed that the social support value is by far the most critical predictor,followed by the utilitarian value,task difficulty,and monetary risk.It is also noteworthy that the awareness of consequences,education background,the ascription of responsibility,and age were also ranked as critical affecting factors.The lowest influential predictors found in this study were income and gender.In addition,a comparison was made in terms of the classification performance of the four utilized data mining techniques.Based on several evalua‐tion measurements(confusion matrix,accuracy,precision,recall,specificity,F-measure,ROC curve,and AUC),the aggregated results suggested that CHAID and Neural network performed the best.The findings of this research are expected to assist policymakers and future researchers in updating all information surround‐ing consumer behavioral intention-related topics focusing on e-waste.Furthermore,the adoption of data min‐ing algorithms for prediction is another insight of this study,which may shed the light on data mining applica‐tions in such environmental studies in the future.
基金The authors acknowledge the financial support provided by the Key R&D Program of Shaanxi Province(No.2022SF-168)Xi’an Programs for Science and Technology Plan(Nos.2020KJRC0090 and 21XJZZ0045)+5 种基金Xi’an Beilin District Programs for Science and Technology Plan(No.GX2247)the Outstanding Chinese and Foreign Youth Exchange Program of China Association for Science and Technology(CAST)in 2019the Opening Project of Shanxi Key Laboratory of Advanced Manufacturing Technology(No.XJZZ202001)the Scientific Research Project of Shaanxi Education Department(No.20JS108)Open Foundation of Key Laboratory of Auxiliary Chemistry and Technology for Chemical Industry,Ministry of Education,Shaanxi University of Science and Technology(No.KFKT2021-01)Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology,Shaanxi University of Science and Technology(No.KFKT2021-01).
文摘Greenhouse gas emissions from waste plastics have caused global warming all over the world,which has been a central threat to the ecological environment for humans,flora and fauna.Among waste plastics,waste polyethylene terephthalate(PET)is attractive due to its excellent stability and degradation-resistant.Therefore,merging China’s carbon peak and carbon neutrality goals would be beneficial.In this review,we summarize the current state-of-the-art of carbon emission decrease from a multi-scale perspective technologically.We suggest that the carbon peak for waste PET can be achieved by employing the closed-loop supply chain,including recycling,biomass utilization,carbon capture and utilization.Waste PET can be a valuable and renewable resource in the whole life cycle.Undoubtedly,all kinds of PET plastics can be ultimately converted into CO_(2),which can also be feedstock for various kinds of chemical products,including ethyl alcohol,formic acid,soda ash,PU,starch and so on.As a result,the closed-loop supply chain can help the PET plastics industry drastically reduce its carbon footprint.
基金Deanship of Scientific Research at Taif University for the grant received for this research.This research was supported by Taif University with research grant(TURSP-2020/77).
文摘The growing number of decarbonization standards in the transportation sector has resulted in an increase in demand for electric cars.Renewable energy sources have the ability to bring the fossil fuel age to an end.Electrochemical storage devices,particularly lithium-ion batteries,are critical for this transition’s success.This is owing to a combination of favorable characteristics such as high energy density and minimal self-discharge.Given the environmental degradation caused by hazardous wastes and the scarcity of some resources,recycling used lithium-ion batteries has significant economic and practical importance.Many efforts have been undertaken in recent years to recover cathode materials(such as high-value metals like cobalt,nickel,and lithium).Regrettably,the regeneration of lower-value-added anode materials(mostly graphite)has received little attention.However,given the widespread use of carbon-based materials and the higher concentration of lithium in the anode than in the environment,anode recycling has gotten a lot of attention.As a result,this article provides the most recent research progress in the recovery of graphite anode materials from spent lithium ion batteries,analyzing the strengths and weaknesses of various recovery routes such as direct physical recovery,heat treatment recovery,hydrometallurgy recovery,heat treatment-hydrometallurgy recovery,extraction,and electrochemical methods from the perspectives of energy,environment,and economy;additionally,the reuse of recycled anode mats is discussed.Finally,the problems and future possibilities of anode recycling are discussed.To enable the green recycling of wasted lithium ion batteries,a low energy-consuming and ecologically friendly solution should be investigated.
文摘The deterioration of recycled fibers especially unbleached kraft with high wet strength resin content due to the irreversible structural changes caused by drying and added chemicals makes the raw material difficult to repulp.The mechanical effect in the pulper over time with chemical treatment has a negative impact on the recycled fibers.At lab scale,different compositions of enzymatic treatment C022L were under investigation to select the most efficient laccase Lacc1,Lacc2 or Lacc3 and to observe the impact of lipases during repulping at low and high consistencies.Pulp disintegration at different times was evaluated to define the level of rejects and to analyze the morphology of fibers after treatments.These results were more significant for Lacc2,by increasing the pulp consistency to 15%in the pulper.Combining lipases with CELODASE 022L appeared to decrease the efficiency of enzymes.The results showed a high reduction of energy power with the enzymatic treatment and a significant reduction of fines level in fibers’suspension.The most efficient version of C022L was used at industrial scale to compare directly with the standard conditions used in a paper mill.
文摘Now, a rapidly growing concern for the environmental protection and resource utilization has stimulated many new activities in the in dustrialized world for coping with urgent environmental problems created by the steadily increasing consumption of industrial products. Increasingly stringent r egulations and widely expressed public concern for the environment highlight the importance of disposing solid waste generated from industrial and consumable pr oducts. How to efficiently recycle and tackle this problem has been a very impo rtant issue over the world. Designing products for recyclability is driven by environmental and economic goals. To obtain good recyclability, two measures can be adopted. One is better recycling strategy and technology; the other is design for recycling (DFR). The recycling strategies of products generally inclu de: reuse, service, remanufacturing, recycling of production scraps during the p roduct usage, recycle (separation first) and disposal. Recyclability assessment is a very important content in DFR. This paper first discusses the content of D FR and strategies and types related to products recyclability, and points out th at easy or difficult recyclability depends on the design phase. Then method and procedure of recyclability assessment based on ANN is explored in detail. The pr ocess consists of selection of the ANN input and output parameters, control of t he sample quality and construction and training of the neural network. At la st, the case study shows this method is simple and operative.
基金The authors would like to thank the University of Massachusetts Lowell for providing start-up funds.N.F.andW.-T.C.would like to thank the financial support by the U.S.Department of Energy’s Office of Energy Efficiency and Renewable Energy(EERE)under the Advanced Manufacturing Office Award No.DE-EE0007897。
文摘Increasing production and use of various novel plastics products,a low recycling rate,and lack of effective recycling/disposal methods have resulted in an exponential growth in plastic waste accumulation in landfills and in the environment.To better understand the effects of plastic waste,Life Cycle Analysis(LCA)was done to compare the effects of various production and disposal methods.LCA shows the specific effects of the cradle-to-grave or cradle-to-cradle scenarios for landfill,incineration,and mechanical recycling.The analysis clearly indicates that increasing recycling of plastics can significantly save energy and eliminate harmful emissions of various carcinogens and GHGs into the environment.As recycling increases,the need for virgin-plastic production can be greatly reduced.Furthermore,the results of this study may help improve current mechanical recycling processes as well as potential future recycling methods,such as chemical recycling.Concerns about the current recycling/disposal methods for plastics have brought increasing attention to the waste accumulation problem.However,with the current COVID-19 pandemic,plastic accumulation is expected to increase significantly in the near future.A better understanding of the quantitative effects of the various disposal methods can help guide policies and future research toward effective solutions of the plastic waste problem.
基金supported by the Strategic Priority Research Program of Chinese Academy of Sciences Sci-ences under Grant No.XDA20020201the National Natural Sci-ence Foundation of China(NSFC)under Grant Nos.41975099,U2006210,and 41475072.
文摘Moisture contribution and transport pathways for Central Asia(CA)are quantitatively examined using the Lagrangian water cycle model based on reanalysis and observational data to explain the precipitation seasonality and the moisture transport variation during 1979-2015.Westerly-related(northwesterly and westerly)transport explains 42%of CA precipitation and dominates in southwest CA,where precipitation is greatest in the cold season.Southeast CA,including part of Northwest China,experiences its maximum precipitation in the warm season and is solely dominated by southerly transport,which explains about 48%of CA precipitation.The remaining 10%of CA precipitation is explained by northerly transport,which steadily impacts north CA and causes a maximum in precipitation in the warm season.Most CA areas are exposed to seasonally varying moisture transport,except for southeast and north CA,which are impacted by southerly and northerly transport year-round.In general,the midlatitude westerlies-driven transport and the Indian monsoon-driven southerly-related transport explain most of the spatial differences in precipitation seasonality over CA.Moreover,the contribution ratio of local evaporation in CA to precipitation exhibits significant interdecadal variability and a meridionally oriented tripole of moisture transport anomalies.Since the early 2000s,CA has experienced a decade of anomalously low local moisture contribution,which seems jointly determined by the weakened moisture contribution from midlatitudes(the Atlantic,Europe,and CA itself)and the enhanced contribution from high latitudes(West Siberia and the Arctic)and tropical areas(South Asia and the Indian Ocean).
