Although lots of basic studies , such as the hydrolysis and dissolution of lignocelluloses has made great progress in recent years , the hydrolysates containing complex mixture of pentose and hexose are very hard to b...Although lots of basic studies , such as the hydrolysis and dissolution of lignocelluloses has made great progress in recent years , the hydrolysates containing complex mixture of pentose and hexose are very hard to be separated , and these process sometimes cause serious environmental problems in practical application of cellulose polymer degradation science.Herein , an efficient two-stage method for selective hydrolysis of lignocelluloses biomass is being developed in this paper by controlling of pH in an ionic liquid.The lignin-hemicelluloses matrix in corn stalk was hydrolyzed into xylose in 23.1% yield in the first stage ; and cellulose-rich residues from the first stage was by farther hydrolyzed to provide a glucose in 26.9%yield.Structure of the products were identified by 13 C NMR.It should be mentioned that , the ionic liquid which can be regenerated and reused throughout the process. The present work significantly opens an a new path to utilize each component of lignocellulose as raw materials producing biofuels , renewable energy and fine chemicals.展开更多
文摘Although lots of basic studies , such as the hydrolysis and dissolution of lignocelluloses has made great progress in recent years , the hydrolysates containing complex mixture of pentose and hexose are very hard to be separated , and these process sometimes cause serious environmental problems in practical application of cellulose polymer degradation science.Herein , an efficient two-stage method for selective hydrolysis of lignocelluloses biomass is being developed in this paper by controlling of pH in an ionic liquid.The lignin-hemicelluloses matrix in corn stalk was hydrolyzed into xylose in 23.1% yield in the first stage ; and cellulose-rich residues from the first stage was by farther hydrolyzed to provide a glucose in 26.9%yield.Structure of the products were identified by 13 C NMR.It should be mentioned that , the ionic liquid which can be regenerated and reused throughout the process. The present work significantly opens an a new path to utilize each component of lignocellulose as raw materials producing biofuels , renewable energy and fine chemicals.
