Shape memory polymers(SMPs)usually have a one-way shape memory effect.In this paper,an easy-operating method to realize a two-way shape memory effect was demonstrated in a ring-shaped bilayer structure where the two l...Shape memory polymers(SMPs)usually have a one-way shape memory effect.In this paper,an easy-operating method to realize a two-way shape memory effect was demonstrated in a ring-shaped bilayer structure where the two layers are SMPs with different thermal transition temperatures.By designing specific thermomechanical processes,the mismatched deformation between the two layers leads to a morphology change of ring-shaped bilayer structures from a smooth ring to a gear-like buckling shape under cooling and a reversible recovery to the smooth shape under heating.Such a morphology change is ascribed to occurrence and recovery of thermoelastic buckling.This method was validated by finite element simulation.We experimentally investigated the influence of pre-strain on buckling,and it was found that both the buckling occurrence and recovery temperature vary with pre-strain.Furthermore,considering a ring-shaped SMP-SMP bilayer structure,finite element analysis was conducted to study the influence of film thickness and modulus ratio of two layers on buckling behavior.The results showed that the critical buckling wavelength was greatly influenced by film thickness and modulus ratio.W e made a theoretical analysis that accorded well with the numerical results.展开更多
The effects of aging temperature on shape memory effect, mechanical properties and microstruc- ture of Fe-14Mn-5Si-8Cr-4Ni-0.2C shape memory alloy have been studied. The results showed that the second phase particles ...The effects of aging temperature on shape memory effect, mechanical properties and microstruc- ture of Fe-14Mn-5Si-8Cr-4Ni-0.2C shape memory alloy have been studied. The results showed that the second phase particles rich in chromium. manganese and silicon precipitate during aging. and thereby increase the hardness and strength of the alloy. The shape recovery ratio can be remarkably improved by aging and a maximum value can be obtained at 1223K, which is 68% higher than that of the specimen in solid solution state. When the aging temperature is below 1223 K, the amount of second phase particles increases as the aging temperature increases. The size of austenite grain increases with increasing aging temperature. When the temperature is over 1223 K, the second phase particles can not precipitate. The lack of second phase particles and the increase of grain size make the hardness and shape recovery ratio drastically decrease, when the temperature is over 1223 K.展开更多
A two-way shape memory effect (TWSM E) in the Ti46.3Ni44.7Nb9 alloy has been systematically investigated by means of bending test and transmission electron microscopy (TEM ) observations. Based on the analysis of the ...A two-way shape memory effect (TWSM E) in the Ti46.3Ni44.7Nb9 alloy has been systematically investigated by means of bending test and transmission electron microscopy (TEM ) observations. Based on the analysis of the microstructure after training. the mechanism of TWSME in the Ti46.3 Ni44.7Nb9 alloy has been discussed.展开更多
Laser additive manufacturing (AM) of lattice structures with light weight, excellent impact resistance, and energy absorption performance is receiving considerable attention in aerospace, transportation, and mechanica...Laser additive manufacturing (AM) of lattice structures with light weight, excellent impact resistance, and energy absorption performance is receiving considerable attention in aerospace, transportation, and mechanical equipment application fields. In this study, we designed four gradient lattice structures (GLSs) using the topology optimization method, including the unidirectional GLS, the bi-directional increasing GLS, the bi-directional decreasing GLS and the none-GLS. All GLSs were manufactureed by laser powder bed fusion (LPBF). The uniaxial compression tests and finite element analysis were conducted to investigate the influence of gradient distribution features on deformation modes and energy absorption performance of GLSs. The results showed that, compared with the 45° shear fracture characteristic of the none-GLS, the unidirectional GLS, the bi-directional increasing GLS and the bi-directional decreasing GLS had the characteristics of the layer-by-layer fracture, showing considerably improved energy absorption capacity. The bi-directional increasing GLS showed a unique combination of shear fracture and layer-by-layer fracture, having the optimal energy absorption performance with energy absorption and specific energy absorption of 235.6 J and 9.5 J g-1 at 0.5 strain, respectively. Combined with the shape memory effect of NiTi alloy, multiple compression-heat recovery experiments were carried out to verify the shape memory function of LPBF-processed NiTi GLSs. These findings have potential value for the future design of GLSs and the realization of shape memory function of NiTi components through laser AM.展开更多
The effect of thermal cycling under loading on martensitic transformation and two-way shape memory effect was investigated for Ti-49.8 at. pci Ni alloy. It is shown that Ms and Mf temperature increase with increasing ...The effect of thermal cycling under loading on martensitic transformation and two-way shape memory effect was investigated for Ti-49.8 at. pci Ni alloy. It is shown that Ms and Mf temperature increase with increasing the number of cycles, while As and Af temperature decrease during thermal cycling. The total strain et and permanent strain ep increase with increasing applied stress and number of cycles. The two-way shape memory effect can be improved by proper thermal cycling training under loading, while excessively high applied stress results in the deterioration of TWSME. The reason for the changes in martensitic transformation characteristics and two-way shape memory effect during thermal cycling under loading is discussed based on the analysis of microstructure by TEM observations.展开更多
The effect of ageing on the microstructure, mechanical properties and shape memory effect (SME) in a newly developed Fe-24Mn-5Si-8Co-4Mo shape memory alloy has been studied. It was found that Fe2Mo particles precipita...The effect of ageing on the microstructure, mechanical properties and shape memory effect (SME) in a newly developed Fe-24Mn-5Si-8Co-4Mo shape memory alloy has been studied. It was found that Fe2Mo particles precipitate during ageing and thereby increase hardness and strength of the alloy The SME of the alloy can be remarkably improved by ageing and a maximum SME can be obtained when aged at 873 K. When the ageing temperature is over 873 K, the SME decreases with increasing ageing temperature. The reason for the improvement of SME by ageing in the Fe-Mn-Si-Co-Mo alloy is展开更多
A number of specimens of Ti-51Ni (at. pct) allOy showing reversible shape memory effect (RSME) have been measured as to reversibility and S-lineshape parameter of positron annihilation. It is found that the Ti-51Ni sp...A number of specimens of Ti-51Ni (at. pct) allOy showing reversible shape memory effect (RSME) have been measured as to reversibility and S-lineshape parameter of positron annihilation. It is found that the Ti-51Ni specimens showing good memory effect contain Structural defects. Not all specimens including Structural defects (or Structural impedrition) are able to exhibit good memory effect. The structural defects have to be appropriate in density neither too much nor too little. With no or too much Structural defects a good RSME could not take place. It is fully as important that the Structural defects exist as it is for the structural defects to be appropriate in density in order to obtain a good RSME.展开更多
An intrinsic two-way shape memory effect with a fully recoverable strain of 1.0%was achieved in an as-prepared Ni50Mn37.5Sn12.5 metamagnetic shape memory microwire fabricated by Taylor-Ulitovsky method.This two-way sh...An intrinsic two-way shape memory effect with a fully recoverable strain of 1.0%was achieved in an as-prepared Ni50Mn37.5Sn12.5 metamagnetic shape memory microwire fabricated by Taylor-Ulitovsky method.This two-way shape memory effect is mainly owing to the internal stress caused by the retained martensite in austenite matrix,as revealed by transmission electron microscopy observations and highenergy X-ray diffraction experiments.After superelastic training for 30 loading/unloading cycles at room temperature,the amount of retained martensite increased and the recoverable strain of two-way shape memory effect increased significantly to 2.2%.Furthermore,a giant recoverable strain of 11.2%was attained under a bias stress of 300 MPa in the trained microwire.These properties confer this microwire great potential for micro-actuation applications.展开更多
In this study, two Cu-Al-Mn-Fe polycrystalline alloys were prepared, and their microstructure, reversible martensitic transformation, mechanical properties and shape memory effects were investigated. The results show ...In this study, two Cu-Al-Mn-Fe polycrystalline alloys were prepared, and their microstructure, reversible martensitic transformation, mechanical properties and shape memory effects were investigated. The results show that the reversible martensitic transformation temperatures of the studied alloys are between room temperature and 373 K, which are suitable for practical applications. Two typed martensites of 18R and 2H coexist both in two alloys. The bcc β(FeAl) nanoparticles are Fe-rich, Mnrich and Cu-poor, whereas the martensite is Cu-rich, Fe-poor and Mn-poor. The size of nanoparticles ranges from tens to hundreds of nanometers. Full shape recovery property is displayed in Cu-12.9Al-4.5Mn-2.6Fe alloy all the time while applying different deformation from 5% to 8%. The maximum recoverable strain is up to 4.4% with a recovery rate of 100%.展开更多
It is not clear whether a shape memory effect(SME) can be realized by stress-induced α' martensite in metastable austenitic stainless steels although the stress-induced ε martensite in these materials can result...It is not clear whether a shape memory effect(SME) can be realized by stress-induced α' martensite in metastable austenitic stainless steels although the stress-induced ε martensite in these materials can result in the SME. To clarify this problem, the relationship between the shape recovery and the reverse transformation of the stress-induced ε and α' martensite in a 304 stainless steel was investigated. The results show that the stress-induced α' martensite can result in the SME when heating above 773 K. After deformation at 77 K and step heating or directly holding at 1073 K, two-stage shape recoveries below 440 K and above 773 K can be obtained due to the reverse transformation of the stress-induced e martensite and α' martensite, respectively. After deformation at room temperature, the α' martensite produced can result in the SME only when directly holding at 1073 K. The intrusion of more dislocations before the formation of the α' martensite at room temperature than at 77 K is the reason that the α' martensite induced at room temperature cannot result in the SME in the case of slow heating. The recovered strains resulting from the stress-induced ε and α' martensite are proportional to the amounts of their reverse transformation, respectively.展开更多
Polymers with reversible plasticity shape memory effect(RPSME)have attracted considerable attention due to their simple programming and large deformation.However,the exact mechanisms of RPSME are still not thoroughly ...Polymers with reversible plasticity shape memory effect(RPSME)have attracted considerable attention due to their simple programming and large deformation.However,the exact mechanisms of RPSME are still not thoroughly understood.In this work,the RPSME of SEBS/crystallizable paraffin was investigated by comparatively analyzing the performances and microstructures of samples with different paraffin content.It was found the shape fixing ratios(Rfs)of samples increased with the paraffin content,and interestingly,a significant improvement in Rf was observed when the paraffin content exceeded 60 wt%.Tensile test results showed that the deformation characteristics of samples changed from elastic to plastic as the paraffin content increased above 60 wt%.By exploring the crystallization behaviors of paraffin in various SEBS/paraffin samples,it was revealed that the microstructures of SEBS/paraffin were different when the paraffin content was below 50 wt%and above 60 wt%.In samples with low paraffin content(below 50 wt%),nearly all paraffin was co-crystallized with ethylene-co-butylene(EB)chains and its crystallization was severely restricted;while in samples with high paraffin content(above 60 wt%),“excess”paraffin appeared and this part of paraffin crystallized on the template of the EB/paraffin co-crystals,which might be responsible for the elastic-to-plastic transition and the sharp increase in Rf.Based on the above results,a possible structural model was proposed to explain the exact mechanism of RPSME in SEBS/paraffin.展开更多
The effect of Ta addition on the martensitic transformation characteristics and the X-ray visibility on NiTi shape memory alloy have been studied in (Ni51Ti49)1-x Tax system. It was found that the transformation tempe...The effect of Ta addition on the martensitic transformation characteristics and the X-ray visibility on NiTi shape memory alloy have been studied in (Ni51Ti49)1-x Tax system. It was found that the transformation temperatures of the Ni51Ti49 binary alloy increased drastically by an addition of 0-4 at. pct Ta, but only slightly when the concentration exceeded 4 at. pct, the addition of Ta greatly decreases the sensitivity of the martensitic transformations to the variation in the Ni-Ti ratio. The addition of Ta to the NiTi binary alloy can improve its X-ray visibility.展开更多
This paper aims to verify the Cu9Al4 phase influence on the nanomechanical behavior of the Cu-14Al-4Ni-xTi alloy obtained by rapid solidification with addition of different amounts of Ti.Using the Scanning Electron Mi...This paper aims to verify the Cu9Al4 phase influence on the nanomechanical behavior of the Cu-14Al-4Ni-xTi alloy obtained by rapid solidification with addition of different amounts of Ti.Using the Scanning Electron Microscopy(SEM),Atomic Force Microscopy(AFM),Energy Dispersion Spectroscopy(EDS)and X-Ray Diffraction(XRD),it was possible to perform the samples’microstructural characterization.In addition,the reduction of the Cu9Al4 phase precipitation and the X-phase appearance were verified according to the increase of the titanium percentage added.The nanomechanical behavior was evaluated by nanoindentation tests,which showed a significant decrease of the elastic modules and an increase of the Poisson coefficient’s according to the titanium amount.This research establishes that the reduction of Cu9Al4 phase implies on the increase of the capacity to dissipate energy.Therefore,the high damping capacity combined with the X-phase presence increases the super elasticity and the alloy ductility.展开更多
The inelastic deformations of shape memory alloys(SMAs)always show poor controllability due to the avalanche-like martensite transformation,and the effective control for the deformation of precision de-vices has been ...The inelastic deformations of shape memory alloys(SMAs)always show poor controllability due to the avalanche-like martensite transformation,and the effective control for the deformation of precision de-vices has been not yet mature.In this work,the phase field method was used to investigate the shape memory effects(SMEs)of NiTi SMAs undergoing grain size(GS)engineering,to obtain tunable one-way and stress-assisted two-way SMEs(OWSME and SATWSME).The OWSME and SATWSME of the systems with various gradient-nanograin structures and bimodal grain structure,as well as that with geometric gradients were simulated.The simulated results indicate that due to the GS dependences of martensite transformation and reorientation,the occurrence and expansion of martensite reorientation,martensite transformation and its reverse can be efficaciously controlled via the GS engineering.When combining the GS engineering and geometric gradient design,since the effects of GS and stress gradient can be su-perimposed or competing,and the responses of martensite reorientation,martensite transformation and its reverse to this are different,the OWSME and SATWSME of the geometrically graded systems with various nanograin structures can exhibit different improvements in controllability.In short,the reorienta-tion hardening modulus during OWSME is increased and the transformation temperature window during SATWSME is widened by GS engineering,indicating the improved controllability of SMEs.The optimal GS engineering schemes revealed in this work provide the basic reference and guidance for designing tun-able SMEs and producing NiTi-based driving devices catering to desired functional performance in various engineering fields.展开更多
The effects of 1 Me V electron irradiation in air at a fixed accumulated dose and dose rates of 393.8,196.9,78.8,and 39.4 Gy s^(-1)on a shape memory epoxy(SMEP)resin were studied.Under low-dose-rate irradiation,accele...The effects of 1 Me V electron irradiation in air at a fixed accumulated dose and dose rates of 393.8,196.9,78.8,and 39.4 Gy s^(-1)on a shape memory epoxy(SMEP)resin were studied.Under low-dose-rate irradiation,accelerated degradation of the shape memory performance was observed;specifically,the shape recovery ratio decreased exponentially with increasing irradiation time(that is,with decreasing dose rate).In addition,the glass transition temperature of the SMEP,as measured by dynamic mechanical analysis,decreased overall with decreasing dose rate.The dose rate effects of 1 Me V electron irradiation on the SMEP were confirmed by structural analysis using electron paramagnetic resonance(EPR)spectroscopy and Fourier transform infrared(FTIR)spectroscopy.The EPR spectra showed that the concentration of free radicals increased exponentially with increasing irradiation time.Moreover,the FTIR spectra showed higher intensities of the peaks at 1660 and 1720 cm^(-1),which are attributed to stretching vibrations of amide C=O and ketone/acid C=O,at lower dose rates.The intensities of the IR peaks at 1660 and 1720 cm^(-1) increased exponentially with increasing irradiation time,and the relative intensity of the IR peak at 2926 cm^(-1)decreased exponentially with increasing irradiation time.The solid-state13 C nuclear magnetic resonance(NMR)spectra of the SMEP before and after 1 Me V electron irradiation at a dose of 1970 k Gy and a dose rate of 78.8 Gy s^(-1) indicated damage to the CH_(2)–N groups and aliphatic isopropanol segment.This result is consistent with the detection of nitrogenous free radicals,a phenoxy-type free radical,and several types of pyrolytic carbon radicals by EPR.During the subsequent propagation process,the free radicals produced at lower dose rates were more likely to react with oxygen,which was present at higher concentrations,and form the more destructive peroxy free radicals and oxidation products such as acids,amides,and ketones.The increase in peroxy free radicals at lower dose rates was thought to accelerate the degradation of the macroscopic performance of the SMEP.展开更多
It is of theoretical and engineering interest to establish a macro-mechanical constitutive model of the shape memory polymer (SMP), which includes the mechanical constitutive equation and the material parameter functi...It is of theoretical and engineering interest to establish a macro-mechanical constitutive model of the shape memory polymer (SMP), which includes the mechanical constitutive equation and the material parameter function, from the viewpoint of practical application. In this paper, a new three-dimensional macro-mechanical constitutive equation, which describes the mechanical behaviors associated with the shape memory effect of SMP, is developed based on solid mechanics and the viscoelasticity theorem. According to the results of the DMA test, a new material parameter function is established to express the relationship of the material parameters and temperature during the glass transition of SMP. The new macro-mechanical constitutive equation and material parameter function are used to numerically simulate the process producing the shape memory effect of SMP, which includes deforming at high temperature, stress freezing, unloading at low temperature and shape recovery. They are also used to investigate and analyze the influences of loading rate and temperature change rate on the thermo-mechanical behaviors of SMP. The numerical results and the comparisons with Zhou’s material parameter function and Tobushi’s mechanical constitutive equation illustrate that the proposed three-dimensional macro-mechanical constitutive model can effectively predict the thermo-mechanical behaviors of SMP under the state of complex stress.展开更多
Each specific structure of organisms is the best choice under specific circumstances.The excellent characteristic structures of these organisms have great application potential in the design and multi-functional optim...Each specific structure of organisms is the best choice under specific circumstances.The excellent characteristic structures of these organisms have great application potential in the design and multi-functional optimization of energy-absorbing structures such as vehicle collisions,satellite landings,and military equipment.In this paper,using the principle of structural bionics,using the advantages of the honeycomb structure and the light weight and high strength of beetle elytra,four bionic lattice structures are studied:CH,ZPRH,SCH and IBE.Using NiTi shape memory alloy,a unique material as the base material,samples are prepared using selective laser melting(SLM)technology.By comparing the test results of the quasi-static compression test with the results of the numerical simulation,it is found that compared with the other three bionic lattice structures,the SCH structure has the best energy absorption effect in the effective stroke in the test,and the specific energy absorption can reach 6.32 J/g.ZPRH,SCH,and IBE structures not only have good and stable deformation behavior,but also have excellent impact resistance and shape memory properties.The design of these structures provides a reference for the design of anti-shock cushioning structures with self-recovery functions in the future.展开更多
Shape memory alloys can recover the deformed shape due to their superelasticity or shape memory effect. In this study, a novel Cu-Al-Mn-Fe shape memory single crystal is reported. The results show that it has excellen...Shape memory alloys can recover the deformed shape due to their superelasticity or shape memory effect. In this study, a novel Cu-Al-Mn-Fe shape memory single crystal is reported. The results show that it has excellent superelasticity and shape memory effect simultaneously when deformed at room temperature, as well as tunably wide response temperature range with near-zero interval of reverse phase transformation. When deforming one single crystal at room temperature, it not only possesses full superelasticity of 7%, but also tunable shape memory effects up to 8.8 %. The full shape recovery during heating exhibits near-zero response interval and tunably wide response temperature range of 166 K depending on the deformation. The functional characteristics of the alloys result from the controllable reverse phase transformation hinging on the stabilization of stress-induced martensite. This class of Cu-Al-Mn-Fe alloy may be used as both superelastic materials, and shape memory materials with wide working temperature range as high-sensitive detector, driver or sensor.展开更多
Machining of shape memory alloys(SMAs)without losing the shape memory effect could immensely extend their applications.Herein,the wire electric discharge machining process was used to machine NiTi—a shape memory allo...Machining of shape memory alloys(SMAs)without losing the shape memory effect could immensely extend their applications.Herein,the wire electric discharge machining process was used to machine NiTi—a shape memory alloy.The experimental methodology was designed using a Box-Behnken design approach of the response surface methodology.The effects of input variables including pulse on time,pulse off time,and current were investigated on the material removal rate,surface roughness,and microhardness.ANOVA tests were performed to check the robustness of the generated empirical models.Optimization of the process parameters was performed using a newly formulated,highly efficient heat transfer search algorithm.Validation tests were conducted and extended for analyzing the retention of the shape memory effect of the machined surface by differential scanning calorimetry.In addition,2D and 3D Pareto curves were generated that indicated the trade-offs between the selected output variables during the simultaneous output variables using the multi-objective heat transfer search algorithm.The optimization route yielded encouraging results.Single objective optimization yielded a maximum material removal rate of 1.49 mm^(3)/s,maximum microhardness 462.52 HVN,and minimum surface roughness 0.11μm.The Pareto curves showed conflicting effects during the wire electric discharge machining of the shape memory alloy and presented a set of optimal non-dominant solutions.The shape memory alloy machined using the optimized process parameters even indicated a shape memory effect similar to that of the starting base material.展开更多
The shape memory effect and nanoindentation response of various phases of sputtered NiTi shape memory thin films were investigated as a function of temperature.The phase transformation temperatures of NiTi films were ...The shape memory effect and nanoindentation response of various phases of sputtered NiTi shape memory thin films were investigated as a function of temperature.The phase transformation temperatures of NiTi films were observed to be sensitive to a compositional shift.The mechanical properties of NiTi thin films also presented a significant response to phase transformations.At the same load,the maximum indentation depth for austenite is smaller than for martensite,indicating that martensite is softer than austenite.A martensite thin film was converted to austenite via in situ heating nanoindentation and displayed the mechanical properties similar to the austenite film at room temperature.These results underscore the validity of elevated temperature nanoindentation methods as a means of interrogating the mechanical properties of materials that undergo thermally-induced phase transformations.The details of the load–displacement curves are also described.展开更多
基金This work was supported by the National Natural Science Foundations of China(Grant 11272044)the Fundamental Research Funds for the Central Universities(Grant 2018JBM305).
文摘Shape memory polymers(SMPs)usually have a one-way shape memory effect.In this paper,an easy-operating method to realize a two-way shape memory effect was demonstrated in a ring-shaped bilayer structure where the two layers are SMPs with different thermal transition temperatures.By designing specific thermomechanical processes,the mismatched deformation between the two layers leads to a morphology change of ring-shaped bilayer structures from a smooth ring to a gear-like buckling shape under cooling and a reversible recovery to the smooth shape under heating.Such a morphology change is ascribed to occurrence and recovery of thermoelastic buckling.This method was validated by finite element simulation.We experimentally investigated the influence of pre-strain on buckling,and it was found that both the buckling occurrence and recovery temperature vary with pre-strain.Furthermore,considering a ring-shaped SMP-SMP bilayer structure,finite element analysis was conducted to study the influence of film thickness and modulus ratio of two layers on buckling behavior.The results showed that the critical buckling wavelength was greatly influenced by film thickness and modulus ratio.W e made a theoretical analysis that accorded well with the numerical results.
文摘The effects of aging temperature on shape memory effect, mechanical properties and microstruc- ture of Fe-14Mn-5Si-8Cr-4Ni-0.2C shape memory alloy have been studied. The results showed that the second phase particles rich in chromium. manganese and silicon precipitate during aging. and thereby increase the hardness and strength of the alloy. The shape recovery ratio can be remarkably improved by aging and a maximum value can be obtained at 1223K, which is 68% higher than that of the specimen in solid solution state. When the aging temperature is below 1223 K, the amount of second phase particles increases as the aging temperature increases. The size of austenite grain increases with increasing aging temperature. When the temperature is over 1223 K, the second phase particles can not precipitate. The lack of second phase particles and the increase of grain size make the hardness and shape recovery ratio drastically decrease, when the temperature is over 1223 K.
文摘A two-way shape memory effect (TWSM E) in the Ti46.3Ni44.7Nb9 alloy has been systematically investigated by means of bending test and transmission electron microscopy (TEM ) observations. Based on the analysis of the microstructure after training. the mechanism of TWSME in the Ti46.3 Ni44.7Nb9 alloy has been discussed.
基金supported by the financial support from the National Natural Science Foundation of China(Nos.51735005 and U1930207)the Basic Strengthening Program(No.2019-JCJQ-JJ-331)+1 种基金National Natural Science Founda-tion of China for Creative Research Groups(No.51921003)the 15th Batch of‘Six Talents Peaks’Innovative Talents Team Program(No.TD-GDZB-001).
文摘Laser additive manufacturing (AM) of lattice structures with light weight, excellent impact resistance, and energy absorption performance is receiving considerable attention in aerospace, transportation, and mechanical equipment application fields. In this study, we designed four gradient lattice structures (GLSs) using the topology optimization method, including the unidirectional GLS, the bi-directional increasing GLS, the bi-directional decreasing GLS and the none-GLS. All GLSs were manufactureed by laser powder bed fusion (LPBF). The uniaxial compression tests and finite element analysis were conducted to investigate the influence of gradient distribution features on deformation modes and energy absorption performance of GLSs. The results showed that, compared with the 45° shear fracture characteristic of the none-GLS, the unidirectional GLS, the bi-directional increasing GLS and the bi-directional decreasing GLS had the characteristics of the layer-by-layer fracture, showing considerably improved energy absorption capacity. The bi-directional increasing GLS showed a unique combination of shear fracture and layer-by-layer fracture, having the optimal energy absorption performance with energy absorption and specific energy absorption of 235.6 J and 9.5 J g-1 at 0.5 strain, respectively. Combined with the shape memory effect of NiTi alloy, multiple compression-heat recovery experiments were carried out to verify the shape memory function of LPBF-processed NiTi GLSs. These findings have potential value for the future design of GLSs and the realization of shape memory function of NiTi components through laser AM.
文摘The effect of thermal cycling under loading on martensitic transformation and two-way shape memory effect was investigated for Ti-49.8 at. pci Ni alloy. It is shown that Ms and Mf temperature increase with increasing the number of cycles, while As and Af temperature decrease during thermal cycling. The total strain et and permanent strain ep increase with increasing applied stress and number of cycles. The two-way shape memory effect can be improved by proper thermal cycling training under loading, while excessively high applied stress results in the deterioration of TWSME. The reason for the changes in martensitic transformation characteristics and two-way shape memory effect during thermal cycling under loading is discussed based on the analysis of microstructure by TEM observations.
文摘The effect of ageing on the microstructure, mechanical properties and shape memory effect (SME) in a newly developed Fe-24Mn-5Si-8Co-4Mo shape memory alloy has been studied. It was found that Fe2Mo particles precipitate during ageing and thereby increase hardness and strength of the alloy The SME of the alloy can be remarkably improved by ageing and a maximum SME can be obtained when aged at 873 K. When the ageing temperature is over 873 K, the SME decreases with increasing ageing temperature. The reason for the improvement of SME by ageing in the Fe-Mn-Si-Co-Mo alloy is
文摘A number of specimens of Ti-51Ni (at. pct) allOy showing reversible shape memory effect (RSME) have been measured as to reversibility and S-lineshape parameter of positron annihilation. It is found that the Ti-51Ni specimens showing good memory effect contain Structural defects. Not all specimens including Structural defects (or Structural impedrition) are able to exhibit good memory effect. The structural defects have to be appropriate in density neither too much nor too little. With no or too much Structural defects a good RSME could not take place. It is fully as important that the Structural defects exist as it is for the structural defects to be appropriate in density in order to obtain a good RSME.
基金the National Natural Science Foundation of China(Nos.51731005,51822102 and 51527801)the Fundamental Research Funds for the Central Universities(grant No.FRF-TP-18-008C1)Use of the Advanced Photon Source was supported by the U.S.Department of Energy,Office of Science,Office of Basic Energy Science,under Contract No.DE-AC02-06CH11357.
文摘An intrinsic two-way shape memory effect with a fully recoverable strain of 1.0%was achieved in an as-prepared Ni50Mn37.5Sn12.5 metamagnetic shape memory microwire fabricated by Taylor-Ulitovsky method.This two-way shape memory effect is mainly owing to the internal stress caused by the retained martensite in austenite matrix,as revealed by transmission electron microscopy observations and highenergy X-ray diffraction experiments.After superelastic training for 30 loading/unloading cycles at room temperature,the amount of retained martensite increased and the recoverable strain of two-way shape memory effect increased significantly to 2.2%.Furthermore,a giant recoverable strain of 11.2%was attained under a bias stress of 300 MPa in the trained microwire.These properties confer this microwire great potential for micro-actuation applications.
基金supported by the National Natural Science Foundation of China (Grant No. 51971185)the Guangdong Basic and Applied Basic Research Foundation (Grant No. 2020A1515010069)the Shenzhen Science and Technology Project (Grant No. JCYJ20190809162401686)。
文摘In this study, two Cu-Al-Mn-Fe polycrystalline alloys were prepared, and their microstructure, reversible martensitic transformation, mechanical properties and shape memory effects were investigated. The results show that the reversible martensitic transformation temperatures of the studied alloys are between room temperature and 373 K, which are suitable for practical applications. Two typed martensites of 18R and 2H coexist both in two alloys. The bcc β(FeAl) nanoparticles are Fe-rich, Mnrich and Cu-poor, whereas the martensite is Cu-rich, Fe-poor and Mn-poor. The size of nanoparticles ranges from tens to hundreds of nanometers. Full shape recovery property is displayed in Cu-12.9Al-4.5Mn-2.6Fe alloy all the time while applying different deformation from 5% to 8%. The maximum recoverable strain is up to 4.4% with a recovery rate of 100%.
基金supported by the National Natural Science Foundation of China(Nos.51271128 and 51671138)
文摘It is not clear whether a shape memory effect(SME) can be realized by stress-induced α' martensite in metastable austenitic stainless steels although the stress-induced ε martensite in these materials can result in the SME. To clarify this problem, the relationship between the shape recovery and the reverse transformation of the stress-induced ε and α' martensite in a 304 stainless steel was investigated. The results show that the stress-induced α' martensite can result in the SME when heating above 773 K. After deformation at 77 K and step heating or directly holding at 1073 K, two-stage shape recoveries below 440 K and above 773 K can be obtained due to the reverse transformation of the stress-induced e martensite and α' martensite, respectively. After deformation at room temperature, the α' martensite produced can result in the SME only when directly holding at 1073 K. The intrusion of more dislocations before the formation of the α' martensite at room temperature than at 77 K is the reason that the α' martensite induced at room temperature cannot result in the SME in the case of slow heating. The recovered strains resulting from the stress-induced ε and α' martensite are proportional to the amounts of their reverse transformation, respectively.
基金financially supported by the National Natural Science Foundation of China (Nos.51773040 and 52173056)。
文摘Polymers with reversible plasticity shape memory effect(RPSME)have attracted considerable attention due to their simple programming and large deformation.However,the exact mechanisms of RPSME are still not thoroughly understood.In this work,the RPSME of SEBS/crystallizable paraffin was investigated by comparatively analyzing the performances and microstructures of samples with different paraffin content.It was found the shape fixing ratios(Rfs)of samples increased with the paraffin content,and interestingly,a significant improvement in Rf was observed when the paraffin content exceeded 60 wt%.Tensile test results showed that the deformation characteristics of samples changed from elastic to plastic as the paraffin content increased above 60 wt%.By exploring the crystallization behaviors of paraffin in various SEBS/paraffin samples,it was revealed that the microstructures of SEBS/paraffin were different when the paraffin content was below 50 wt%and above 60 wt%.In samples with low paraffin content(below 50 wt%),nearly all paraffin was co-crystallized with ethylene-co-butylene(EB)chains and its crystallization was severely restricted;while in samples with high paraffin content(above 60 wt%),“excess”paraffin appeared and this part of paraffin crystallized on the template of the EB/paraffin co-crystals,which might be responsible for the elastic-to-plastic transition and the sharp increase in Rf.Based on the above results,a possible structural model was proposed to explain the exact mechanism of RPSME in SEBS/paraffin.
基金Shanxi Province Natural Science FOundation State Key Laboratory of Solidilication Processing.
文摘The effect of Ta addition on the martensitic transformation characteristics and the X-ray visibility on NiTi shape memory alloy have been studied in (Ni51Ti49)1-x Tax system. It was found that the transformation temperatures of the Ni51Ti49 binary alloy increased drastically by an addition of 0-4 at. pct Ta, but only slightly when the concentration exceeded 4 at. pct, the addition of Ta greatly decreases the sensitivity of the martensitic transformations to the variation in the Ni-Ti ratio. The addition of Ta to the NiTi binary alloy can improve its X-ray visibility.
基金The authorswould like to thankthe Federal Institute of Science and Technology of Bahia,the University of Sao Paulo and the University of Brasilia for all the support to carry out this research.
文摘This paper aims to verify the Cu9Al4 phase influence on the nanomechanical behavior of the Cu-14Al-4Ni-xTi alloy obtained by rapid solidification with addition of different amounts of Ti.Using the Scanning Electron Microscopy(SEM),Atomic Force Microscopy(AFM),Energy Dispersion Spectroscopy(EDS)and X-Ray Diffraction(XRD),it was possible to perform the samples’microstructural characterization.In addition,the reduction of the Cu9Al4 phase precipitation and the X-phase appearance were verified according to the increase of the titanium percentage added.The nanomechanical behavior was evaluated by nanoindentation tests,which showed a significant decrease of the elastic modules and an increase of the Poisson coefficient’s according to the titanium amount.This research establishes that the reduction of Cu9Al4 phase implies on the increase of the capacity to dissipate energy.Therefore,the high damping capacity combined with the X-phase presence increases the super elasticity and the alloy ductility.
基金The National Natural Science Foundation of China(12022208)the Project funded by China Postdoctoral Science Foundation(2022M712243)the Fundamental Research Funds for the Cen-tral Universities are acknowledged.
文摘The inelastic deformations of shape memory alloys(SMAs)always show poor controllability due to the avalanche-like martensite transformation,and the effective control for the deformation of precision de-vices has been not yet mature.In this work,the phase field method was used to investigate the shape memory effects(SMEs)of NiTi SMAs undergoing grain size(GS)engineering,to obtain tunable one-way and stress-assisted two-way SMEs(OWSME and SATWSME).The OWSME and SATWSME of the systems with various gradient-nanograin structures and bimodal grain structure,as well as that with geometric gradients were simulated.The simulated results indicate that due to the GS dependences of martensite transformation and reorientation,the occurrence and expansion of martensite reorientation,martensite transformation and its reverse can be efficaciously controlled via the GS engineering.When combining the GS engineering and geometric gradient design,since the effects of GS and stress gradient can be su-perimposed or competing,and the responses of martensite reorientation,martensite transformation and its reverse to this are different,the OWSME and SATWSME of the geometrically graded systems with various nanograin structures can exhibit different improvements in controllability.In short,the reorienta-tion hardening modulus during OWSME is increased and the transformation temperature window during SATWSME is widened by GS engineering,indicating the improved controllability of SMEs.The optimal GS engineering schemes revealed in this work provide the basic reference and guidance for designing tun-able SMEs and producing NiTi-based driving devices catering to desired functional performance in various engineering fields.
基金support of the 111 Project(No.B18017)the National Equipment Pre-Research Project of the 13th Five-Year Plan(No.30508040601)。
文摘The effects of 1 Me V electron irradiation in air at a fixed accumulated dose and dose rates of 393.8,196.9,78.8,and 39.4 Gy s^(-1)on a shape memory epoxy(SMEP)resin were studied.Under low-dose-rate irradiation,accelerated degradation of the shape memory performance was observed;specifically,the shape recovery ratio decreased exponentially with increasing irradiation time(that is,with decreasing dose rate).In addition,the glass transition temperature of the SMEP,as measured by dynamic mechanical analysis,decreased overall with decreasing dose rate.The dose rate effects of 1 Me V electron irradiation on the SMEP were confirmed by structural analysis using electron paramagnetic resonance(EPR)spectroscopy and Fourier transform infrared(FTIR)spectroscopy.The EPR spectra showed that the concentration of free radicals increased exponentially with increasing irradiation time.Moreover,the FTIR spectra showed higher intensities of the peaks at 1660 and 1720 cm^(-1),which are attributed to stretching vibrations of amide C=O and ketone/acid C=O,at lower dose rates.The intensities of the IR peaks at 1660 and 1720 cm^(-1) increased exponentially with increasing irradiation time,and the relative intensity of the IR peak at 2926 cm^(-1)decreased exponentially with increasing irradiation time.The solid-state13 C nuclear magnetic resonance(NMR)spectra of the SMEP before and after 1 Me V electron irradiation at a dose of 1970 k Gy and a dose rate of 78.8 Gy s^(-1) indicated damage to the CH_(2)–N groups and aliphatic isopropanol segment.This result is consistent with the detection of nitrogenous free radicals,a phenoxy-type free radical,and several types of pyrolytic carbon radicals by EPR.During the subsequent propagation process,the free radicals produced at lower dose rates were more likely to react with oxygen,which was present at higher concentrations,and form the more destructive peroxy free radicals and oxidation products such as acids,amides,and ketones.The increase in peroxy free radicals at lower dose rates was thought to accelerate the degradation of the macroscopic performance of the SMEP.
基金supported by the National Natural Science Foundation of China (Grant No. 95505010)the National High Technology Research and Development Program of China (Grant No. 2006AA03Z109)+2 种基金the China Postdoctoral Science Foundation (Grant No. 20080430933)the Harbin Talent Foundation of Scientific and Technical Innovation (Grant No.RC2009QN017046)the Fundamental Research Funds for Central Universities (Grant No. HEUCF: Z1004).
文摘It is of theoretical and engineering interest to establish a macro-mechanical constitutive model of the shape memory polymer (SMP), which includes the mechanical constitutive equation and the material parameter function, from the viewpoint of practical application. In this paper, a new three-dimensional macro-mechanical constitutive equation, which describes the mechanical behaviors associated with the shape memory effect of SMP, is developed based on solid mechanics and the viscoelasticity theorem. According to the results of the DMA test, a new material parameter function is established to express the relationship of the material parameters and temperature during the glass transition of SMP. The new macro-mechanical constitutive equation and material parameter function are used to numerically simulate the process producing the shape memory effect of SMP, which includes deforming at high temperature, stress freezing, unloading at low temperature and shape recovery. They are also used to investigate and analyze the influences of loading rate and temperature change rate on the thermo-mechanical behaviors of SMP. The numerical results and the comparisons with Zhou’s material parameter function and Tobushi’s mechanical constitutive equation illustrate that the proposed three-dimensional macro-mechanical constitutive model can effectively predict the thermo-mechanical behaviors of SMP under the state of complex stress.
基金National Key R&D Program of China(No.2018YFB1105100)National Natural Science Foundation of China(No.51975246)+5 种基金Jilin Province Science and Technology Development Plan(No.YDZJ202101ZYTS134)State Key Laboratory of Automotive Simulation and Control—ziyoutansuoxiangmu(202013)Open Project Program of Key Laboratory for Cross-Scale Micro and Nano Manufacturing,Ministry of Education,Changchun University of Science and Technology(CMNM-KF202109)Program for JLU Science and Technology Innovative Research Team(No.2019TD-34)Interdisciplinary Research Fund for Doctoral Postgraduates of Jilin University(No.101832020DJX052)Interdisciplinary Cultivation Project for Young Teachers and Students(No.415010300078)。
文摘Each specific structure of organisms is the best choice under specific circumstances.The excellent characteristic structures of these organisms have great application potential in the design and multi-functional optimization of energy-absorbing structures such as vehicle collisions,satellite landings,and military equipment.In this paper,using the principle of structural bionics,using the advantages of the honeycomb structure and the light weight and high strength of beetle elytra,four bionic lattice structures are studied:CH,ZPRH,SCH and IBE.Using NiTi shape memory alloy,a unique material as the base material,samples are prepared using selective laser melting(SLM)technology.By comparing the test results of the quasi-static compression test with the results of the numerical simulation,it is found that compared with the other three bionic lattice structures,the SCH structure has the best energy absorption effect in the effective stroke in the test,and the specific energy absorption can reach 6.32 J/g.ZPRH,SCH,and IBE structures not only have good and stable deformation behavior,but also have excellent impact resistance and shape memory properties.The design of these structures provides a reference for the design of anti-shock cushioning structures with self-recovery functions in the future.
基金financially supported by the National Natural Science Foundation of China (No. 51971185)the National Key R&D Program of China (No. 2017YFB0702901)。
文摘Shape memory alloys can recover the deformed shape due to their superelasticity or shape memory effect. In this study, a novel Cu-Al-Mn-Fe shape memory single crystal is reported. The results show that it has excellent superelasticity and shape memory effect simultaneously when deformed at room temperature, as well as tunably wide response temperature range with near-zero interval of reverse phase transformation. When deforming one single crystal at room temperature, it not only possesses full superelasticity of 7%, but also tunable shape memory effects up to 8.8 %. The full shape recovery during heating exhibits near-zero response interval and tunably wide response temperature range of 166 K depending on the deformation. The functional characteristics of the alloys result from the controllable reverse phase transformation hinging on the stabilization of stress-induced martensite. This class of Cu-Al-Mn-Fe alloy may be used as both superelastic materials, and shape memory materials with wide working temperature range as high-sensitive detector, driver or sensor.
文摘Machining of shape memory alloys(SMAs)without losing the shape memory effect could immensely extend their applications.Herein,the wire electric discharge machining process was used to machine NiTi—a shape memory alloy.The experimental methodology was designed using a Box-Behnken design approach of the response surface methodology.The effects of input variables including pulse on time,pulse off time,and current were investigated on the material removal rate,surface roughness,and microhardness.ANOVA tests were performed to check the robustness of the generated empirical models.Optimization of the process parameters was performed using a newly formulated,highly efficient heat transfer search algorithm.Validation tests were conducted and extended for analyzing the retention of the shape memory effect of the machined surface by differential scanning calorimetry.In addition,2D and 3D Pareto curves were generated that indicated the trade-offs between the selected output variables during the simultaneous output variables using the multi-objective heat transfer search algorithm.The optimization route yielded encouraging results.Single objective optimization yielded a maximum material removal rate of 1.49 mm^(3)/s,maximum microhardness 462.52 HVN,and minimum surface roughness 0.11μm.The Pareto curves showed conflicting effects during the wire electric discharge machining of the shape memory alloy and presented a set of optimal non-dominant solutions.The shape memory alloy machined using the optimized process parameters even indicated a shape memory effect similar to that of the starting base material.
基金the National Science Foundation(Grant No.0907090).
文摘The shape memory effect and nanoindentation response of various phases of sputtered NiTi shape memory thin films were investigated as a function of temperature.The phase transformation temperatures of NiTi films were observed to be sensitive to a compositional shift.The mechanical properties of NiTi thin films also presented a significant response to phase transformations.At the same load,the maximum indentation depth for austenite is smaller than for martensite,indicating that martensite is softer than austenite.A martensite thin film was converted to austenite via in situ heating nanoindentation and displayed the mechanical properties similar to the austenite film at room temperature.These results underscore the validity of elevated temperature nanoindentation methods as a means of interrogating the mechanical properties of materials that undergo thermally-induced phase transformations.The details of the load–displacement curves are also described.
