We improved the adhesion between silicon based insulating materials and epoxy resin composites by adding the adhesion promoter cycloborosiloxane(BSi,cyclo-1,3,3,5,7,7-hexaphenyl-1,5-diboro-3,7-disiloxane).The experime...We improved the adhesion between silicon based insulating materials and epoxy resin composites by adding the adhesion promoter cycloborosiloxane(BSi,cyclo-1,3,3,5,7,7-hexaphenyl-1,5-diboro-3,7-disiloxane).The experimental results show that the addition of BSi in the silicone rubber(SR)system significantly increases the tensile shear strength between BSi and epoxy resin(EP),reaching 309%of the original value.On this basis,the mechanism of BSi to enhance the adhesion effect was discussed.The electron deficient B in BSi attracted the electron rich N and O in EP to enhance the chemical interaction,combined with the interfacial migration behavior in the curing process,to improve the adhesion strength.This study provides the design and synthesis ideas of adhesive aids,and a reference for further exploring the interface mechanism of epoxy resin matrix composites.展开更多
Carbon nanotube (CNT) filled silicone rubber (SR) composites were synthesized by in situ polymerization.The effect of strain on the electrical resistance of the CNT/SR composites and the structure evolution of CNT net...Carbon nanotube (CNT) filled silicone rubber (SR) composites were synthesized by in situ polymerization.The effect of strain on the electrical resistance of the CNT/SR composites and the structure evolution of CNT networks during tensile deformation were investigated.The results showed that the CNT/SR composites had high sensitivity of resistance-strain response.In a wide strain range (0-125%),the change of resistivity could reach 107,which was closely associated with the evolution process of the conductive CNT-network structure.The volume expansion of the composites in the tensile process led to a gradual decrease in the volume fraction of CNTs with the strain increase.When CNT loading was lower than the percolation threshold,CNT network was in disconnected state with a rapid increase in electrical resistance of the composites.Furthermore,the CNT loading had remarkable effect on the sensitivity of resistance-strain response in the composites.展开更多
Slow positron beam was applied to study the depth profile structure of the virgin and the aged high-temperature vulcanized silicone rubber(HTV). Scanning electron microscope(SEM) images show that the surface of virgin...Slow positron beam was applied to study the depth profile structure of the virgin and the aged high-temperature vulcanized silicone rubber(HTV). Scanning electron microscope(SEM) images show that the surface of virgin sample is smooth, while the outdoor aged samples are all rough. According to the S(E) curves obtained by slow positron beam, in a depth of more than 1 μm, the S parameter of the sample aged at low-potential side keeps the same value with the virgin one;while the S values of the highpotential side aged sample remain rather low in a depth of about 5 μm. Thermo gravimetric analysis(TGA) results show that the sample in high potential side contains more inorganic constituents than that of other samples. The results are attributed to the strong electric field induced corona aging at high potential side of the composite insulator.展开更多
In recent years,more and more high-voltage overhead transmission lines were built passing through the karst regions in southwestern China.This type of special landform seems to have an adverse effect on the aging of t...In recent years,more and more high-voltage overhead transmission lines were built passing through the karst regions in southwestern China.This type of special landform seems to have an adverse effect on the aging of the sheds of the line suspension composite insulators,which may lead to unexpected flashover and line tripping.In order to find out the particularity of the aging characteristics of insulators operating in the karst regions,samples in operation were selected from both the karst regions and the flatlands.Hydrophobicity,amount of surface contamination,and contaminant composition of the sheds were studied,then a comparison of performance between the two was made,and the possible influencing factors that cause such differences were discussed.The results show that the overall aging of the sheds of the composite insulators operating at the karst regions is more aggravated,which is caused by the combined influence of factors including the special topography,climate,and pollution in the area.The strong wind crossing the col will bring about the mutual scraping on the edges and stress concentration at the root of the sheds,leaving scratches and root cracks;the infiltration from these rupture of acid liquid,if any,will accelerate the aging and corroding of the internal silicone rubber material;moreover,the carbonates enriched on the surface of the sheds will gradually transform into more corrosive sulfates in an acidic environment,leading to further deterioration and chalking of the sheds of the insulators.The research work in this paper can provide guidance for the current operation and maintenance of composite insulators in the karst areas,as well as having important reference values for the layout design and insulation configuration of transmission lines to be built across karst landforms in the future.展开更多
Polymer composites as thermal interface materials have been widely used in modern electronic equipment.In this work,we report a novel method to prepare highly through-plane thermally conductive silicone rubber(SR)comp...Polymer composites as thermal interface materials have been widely used in modern electronic equipment.In this work,we report a novel method to prepare highly through-plane thermally conductive silicone rubber(SR)composites with vertically aligned silicon carbide fibers(VA-SiCFs)entangled by SiC nanowires(SiCNWs)networks.First,a series of carbon fibers(CFs)skeletons were fabricated in sequence of coating poor thermally conductive polyacrylonitrile-based CFs with polydopamine,icetemplated assembly,and freeze-drying processes.Furthermore,VA-SiCFs networks,i.e.,long-range continuous SiCFs-SiCNWs networks,based on the prepared CFs skeletons,were in-situ obtained via template-assisted chemical vapor deposition method.The thermal conductivity enhancement mechanism of VA-SiCFs networks on its SR composites was also intensively studied by finite element simulation,based on the first principles investigation of SiC,and Foygel’s theory.The in-situ grown VA-SiCFs networks possess high intrinsic thermal conductivity without the thermal interface between fillers,acting as the high-efficiency through-plane long-range continuous thermal conduction path,in which the SiCNWs were the in-plane“thermal spreader”.The VA-SiCFs/SR composites reached a high through-plane thermal conductivity,2.13 W/(m·K),at the filler loading of 15 vol.%,which is 868.2%,and 249.2%higher than that of pure SR sample,and random-CFs@polydopamine(PDA)/SR composites at the same content,respectively.The VA-SiCFs/SR composites also exhibited good electrical insulation performance and excellent dimensional stability,which guaranteed the stable interfacial heat transfer of high-power density electronic devices.展开更多
基金the Core Research Facilities of College of Chemistry and Molecular Sciences and Wuhan University Test Center and Open Fund of Hubei Key Laboratory of Aerospace Power Advanced Technologythe Open Fund of Hubei Key Laboratory of Aerospace Power Advanced Technologythe Special Fund for Industrial and informatization Industry Foundation Reconstruction and High Quality Development of Manufacturing Industry(No.TC220H068)。
文摘We improved the adhesion between silicon based insulating materials and epoxy resin composites by adding the adhesion promoter cycloborosiloxane(BSi,cyclo-1,3,3,5,7,7-hexaphenyl-1,5-diboro-3,7-disiloxane).The experimental results show that the addition of BSi in the silicone rubber(SR)system significantly increases the tensile shear strength between BSi and epoxy resin(EP),reaching 309%of the original value.On this basis,the mechanism of BSi to enhance the adhesion effect was discussed.The electron deficient B in BSi attracted the electron rich N and O in EP to enhance the chemical interaction,combined with the interfacial migration behavior in the curing process,to improve the adhesion strength.This study provides the design and synthesis ideas of adhesive aids,and a reference for further exploring the interface mechanism of epoxy resin matrix composites.
基金Funded by Liaoning Education Department (No.LS2010128)the Scientific Research Fund of University of Jinan (No.XKY0901)
文摘Carbon nanotube (CNT) filled silicone rubber (SR) composites were synthesized by in situ polymerization.The effect of strain on the electrical resistance of the CNT/SR composites and the structure evolution of CNT networks during tensile deformation were investigated.The results showed that the CNT/SR composites had high sensitivity of resistance-strain response.In a wide strain range (0-125%),the change of resistivity could reach 107,which was closely associated with the evolution process of the conductive CNT-network structure.The volume expansion of the composites in the tensile process led to a gradual decrease in the volume fraction of CNTs with the strain increase.When CNT loading was lower than the percolation threshold,CNT network was in disconnected state with a rapid increase in electrical resistance of the composites.Furthermore,the CNT loading had remarkable effect on the sensitivity of resistance-strain response in the composites.
基金Funded by the National Natural Science Foundation of China(No.21174108)the Science and Technology Project of China Southern Power Grid Co,Ltd(No.GDKJQQ20161197)
文摘Slow positron beam was applied to study the depth profile structure of the virgin and the aged high-temperature vulcanized silicone rubber(HTV). Scanning electron microscope(SEM) images show that the surface of virgin sample is smooth, while the outdoor aged samples are all rough. According to the S(E) curves obtained by slow positron beam, in a depth of more than 1 μm, the S parameter of the sample aged at low-potential side keeps the same value with the virgin one;while the S values of the highpotential side aged sample remain rather low in a depth of about 5 μm. Thermo gravimetric analysis(TGA) results show that the sample in high potential side contains more inorganic constituents than that of other samples. The results are attributed to the strong electric field induced corona aging at high potential side of the composite insulator.
基金supported by Science and Technology Project of Southern Power Grid EHV Transmission Company of China(010700KK52190003).
文摘In recent years,more and more high-voltage overhead transmission lines were built passing through the karst regions in southwestern China.This type of special landform seems to have an adverse effect on the aging of the sheds of the line suspension composite insulators,which may lead to unexpected flashover and line tripping.In order to find out the particularity of the aging characteristics of insulators operating in the karst regions,samples in operation were selected from both the karst regions and the flatlands.Hydrophobicity,amount of surface contamination,and contaminant composition of the sheds were studied,then a comparison of performance between the two was made,and the possible influencing factors that cause such differences were discussed.The results show that the overall aging of the sheds of the composite insulators operating at the karst regions is more aggravated,which is caused by the combined influence of factors including the special topography,climate,and pollution in the area.The strong wind crossing the col will bring about the mutual scraping on the edges and stress concentration at the root of the sheds,leaving scratches and root cracks;the infiltration from these rupture of acid liquid,if any,will accelerate the aging and corroding of the internal silicone rubber material;moreover,the carbonates enriched on the surface of the sheds will gradually transform into more corrosive sulfates in an acidic environment,leading to further deterioration and chalking of the sheds of the insulators.The research work in this paper can provide guidance for the current operation and maintenance of composite insulators in the karst areas,as well as having important reference values for the layout design and insulation configuration of transmission lines to be built across karst landforms in the future.
基金The authors gratefully acknowledge the financial support of this work by the National Natural Science Foundation of China(Nos.21978240,52003219,and 52006057)Youth project of basic research program of Natural Science in Shaanxi Province(No.2020JQ-179)+5 种基金the Fundamental Research Funds for the Central Universities(Nos.3102018AX004,3102017jc01001,and 531119200237)Shenzhen Xuni University Lab Construction Funding(No.YFJGJS1.0,20191024213117281)Guangdong Province Key Field R&D Project(No.2020B010178001)the student innovation fund of Northwestern Polytechnical University(No.202110699234)the Open Testing Foundation of the Analytical&Testing Center of Northwestern Polytechnical University(No.2020T020)the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University(No.CX2022072).
文摘Polymer composites as thermal interface materials have been widely used in modern electronic equipment.In this work,we report a novel method to prepare highly through-plane thermally conductive silicone rubber(SR)composites with vertically aligned silicon carbide fibers(VA-SiCFs)entangled by SiC nanowires(SiCNWs)networks.First,a series of carbon fibers(CFs)skeletons were fabricated in sequence of coating poor thermally conductive polyacrylonitrile-based CFs with polydopamine,icetemplated assembly,and freeze-drying processes.Furthermore,VA-SiCFs networks,i.e.,long-range continuous SiCFs-SiCNWs networks,based on the prepared CFs skeletons,were in-situ obtained via template-assisted chemical vapor deposition method.The thermal conductivity enhancement mechanism of VA-SiCFs networks on its SR composites was also intensively studied by finite element simulation,based on the first principles investigation of SiC,and Foygel’s theory.The in-situ grown VA-SiCFs networks possess high intrinsic thermal conductivity without the thermal interface between fillers,acting as the high-efficiency through-plane long-range continuous thermal conduction path,in which the SiCNWs were the in-plane“thermal spreader”.The VA-SiCFs/SR composites reached a high through-plane thermal conductivity,2.13 W/(m·K),at the filler loading of 15 vol.%,which is 868.2%,and 249.2%higher than that of pure SR sample,and random-CFs@polydopamine(PDA)/SR composites at the same content,respectively.The VA-SiCFs/SR composites also exhibited good electrical insulation performance and excellent dimensional stability,which guaranteed the stable interfacial heat transfer of high-power density electronic devices.
