In order to evaluate the feasibility of steel slag powder as filler,the coating properties of steel slag and limestone aggregate were compared by water boiling test,the micro morphology difierences between steel slag ...In order to evaluate the feasibility of steel slag powder as filler,the coating properties of steel slag and limestone aggregate were compared by water boiling test,the micro morphology difierences between steel slag powder and mineral powder(limestone powder)were compared by scanning electron microscope(SEM),and the high-temperature rheological properties of asphalt mortar with difierent ratio of filler quality to asphalt quality(F/A)and difierent substitution rates of mineral powder(S/F)were studied by dynamic shear rheological test.The results show that the surface microstructure of steel slag powder is more abundant than that of mineral powder,and the adhesion of steel slag to asphalt is better than that of limestone.At the same temperature,the lower the ratio of S/F is,the greater the rutting factor and complex modulus will be.In addition,the complex modulus and rutting factor of the asphalt mortar increase with the increase of F/A,and the filler type and F/A have a negligible efiect on the phase angle.展开更多
In order to increase use ratio of steel slag solid waste,the concrete containing steel slag powder and zeolite powder as admixtures was prepared by using the orthogonal test method.The effects of water-binder ratio,s...In order to increase use ratio of steel slag solid waste,the concrete containing steel slag powder and zeolite powder as admixtures was prepared by using the orthogonal test method.The effects of water-binder ratio,sand ratio,steel slag powder content and zeolite powder on working properties,mechanical strength and chloride ion permeability of the concrete was studied.It was found that the early strength of the concrete had a decrease with the mixing of steel slag and zeolite powders,but its later strength approached to pure concrete.Moreover,the physical filling and pozzolanic activity of the admixtures increased the density of the concrete,resulting in the improvement of the durability of the concrete by the migration speed of Cl−reducing.The optimum mix ratio of C40 steel slag powder-zeolite powder concrete is obtained,and which had the slump of 220 mm,the 3 d,7 d and 28 d compressive strengths of 27.8 MPa,37.5 MPa and 48.4 MPa,the 6 h electric flux of 950 C and the diffusion coefficient of 1.65×10−12 m2/s.展开更多
The oxidation pathway and kinetics of titania slag powders in air were analyzed using differential scanning calorimetry(DSC)and thermogravimetry(TG).The oxidation pathway of titania slag powder in air was divided into...The oxidation pathway and kinetics of titania slag powders in air were analyzed using differential scanning calorimetry(DSC)and thermogravimetry(TG).The oxidation pathway of titania slag powder in air was divided into three stages according to their three exothermic peaks and three corresponding mass gain stages indicated by the respective non-isothermal DSC and TG curves.The isothermal oxidation kinetics of high titania slag powders of different sizes were analyzed using the ln-ln analysis method.The results revealed that the entire isothermal oxidation process comprises two stages.The kinetic mechanism of the first stage can be described as f(α) = 1.77(1-α) [-ln (1-α)]^((1.77-1)/1.77),f(α)= 1.97(1-α) [-ln (1-α)]^((1.97-1)/1.97),and f (α) = 1.18(1-α) [-ln (1-α)]^((1.18-1)/1.18).The kinetic mechanism of the second stage for all samples can be described as f (α)=1.5(1-α)^(2/3)[1-(1-α)^(1/3)]^(-1).The activation energies of titania slag powders with different sizes(d_(1)<0.075 mm,0.125 mm<d_(2)<0.150 mm,and 0.425 mm<d_(3)<0.600 mm)for different reaction degrees were calculated.For the given experimental conditions,the rate-controlling step in the first oxidation stage of all the samples is a chemical reaction.The rate-controlling steps of the second oxidation stage are a chemical reaction and internal diffusion(for powders d_(1)<0.075 mm)and internal diffusion(for powders 0.125 mm<d_(2)<0.150 mm and 0.425 mm<d_(3)<0.600 mm).展开更多
Dry ball milling and wet ball milling were used to treat converter slag with particle size < 10 mm and the converter slag powder was stabilized by H2O only and H2O coupled with CO2.respectively.Results showed that ...Dry ball milling and wet ball milling were used to treat converter slag with particle size < 10 mm and the converter slag powder was stabilized by H2O only and H2O coupled with CO2.respectively.Results showed that when CO2 &H2O was used,the free-calcium oxide（f-CaO） content in converter slag decreased significantly and after an-hour treatment the f-CaO content was reduced to 3%;however,when only treated by H2O without CO2, f-CaO needed 3-hour stabilization to decrease its content to 3%.When f-CaO in converter slag powder was treated by CO2 &H2O,its main reaction products were CaCO3 and then Ca（OH）2;however,when only H2O was used, the f-CaO content decreased gently and the main products were Ca（OH）2.展开更多
Hydration heat evolution, non-evaporative water, setting time and SEM tests were performed to investigate the effect of fine steel slag powder on the hydration process of Portland cement and its mechanism. The results...Hydration heat evolution, non-evaporative water, setting time and SEM tests were performed to investigate the effect of fine steel slag powder on the hydration process of Portland cement and its mechanism. The results show that the effect of fine steel slag powder on the hydration process of Portland cement is closely related to its chemical composition, mineral phases, fineness, etc. Fine steel slag powder retards the hydration of portland cement at early age. The major reason for this phenomenon is the relative high content of MgO, MnO2, P2O5 in steel slag, and MgO solid solved in C3S contained in steel slag.展开更多
To decrease the cement and SF content of RPC by using ultra-fine fly ash (UFFA) and steel slag powder (SS), the effect of these mineral admixtures on compressive strength of RPC were investigated. The experimental res...To decrease the cement and SF content of RPC by using ultra-fine fly ash (UFFA) and steel slag powder (SS), the effect of these mineral admixtures on compressive strength of RPC were investigated. The experimental results indicate that the utilization of UFFA and SS in RPC is feasible and has prominent mechanical performance. The microstructure analysis (SEM and TG-DTG-DSC) demonstrated that the excellent mechanical properties of RPC containing SS and UFFA were mainly attributed to the sequential hydration filling effect of the compound system.展开更多
The workability and durability of a type of sustainable concrete made with steel slag powder were investigated. The hydrated products of cement paste with ground granulated blast furnace slag(GGBFS) alone or with a co...The workability and durability of a type of sustainable concrete made with steel slag powder were investigated. The hydrated products of cement paste with ground granulated blast furnace slag(GGBFS) alone or with a combined admixture of GGBFS-steel slag powder were investigated by X-ray diffraction(XRD). Furthermore, the mechanism of chemically activated steel slag powder was also studied. The experimental results showed that when steel slag powder was added to concrete, the slumps through the same time were lower. The initial and fi nal setting times were slightly retarded. The dry shrinkages were lower, and the abrasion resistance was better. The chemically activated steel slag powder could improve compressive strengths, resistance to chloride permeation and water permeation, as well as carbonization resistance. XRD patterns indicated that the activators enhanced the formation of calcium silicate hydrate(C-S-H) gel and ettringite(AFt). This research contributes to sustainable disposal of wastes and has the potential to provide several important environmental benefi ts.展开更多
The feasibility of flue gas desulphurization(FGD) as concrete admixture was studied. A combined concrete admixture of the thermally-treated FGD gypsum and slag powder was explored. The FGD gypsum was roasted at 200 ℃...The feasibility of flue gas desulphurization(FGD) as concrete admixture was studied. A combined concrete admixture of the thermally-treated FGD gypsum and slag powder was explored. The FGD gypsum was roasted at 200 ℃ for 60 min and then mixed with the slag powder to form FGD gypsum-slag powder combined admixture in which the SO 3 content was 3.5wt%. Cement was partially and equivalently replaced by slag powder alone or FGD gypsum-slag powder, at concentration of 25wt%, 40wt%, and 50wt%, respectively. The setting times, hydration products, total porosity and pore size distributions of the paste were determined. The compressive strength and drying shrinkage of cement mortar and concrete were also tested. The experimental results show that, in the presence of FGD gypsum, the setting times are much slower than those of pastes in the absence of FGD gypsum. The combination of FGD gypsum and slag powder provides synergistic benefits above that of slag powder alone. The addition of FGD gypsum provides benefit by promoting ettringite formation and forms a compact microstructure, increasing the compressive strength and reduces the drying shrinkage of cement mortar and concrete.展开更多
A superfine slag powder (SP) made from granulated blast furnace slag incorporating activators by using special millingtechnique, was used as supplementary cementitious material in high performance concrete (HPC), repl...A superfine slag powder (SP) made from granulated blast furnace slag incorporating activators by using special millingtechnique, was used as supplementary cementitious material in high performance concrete (HPC), replacing part ofthe mass of normal Portland cement. The effects of the SP on the workability, mechanical and crack self-healingproperties of HPC were studied. The hydration process and microstructure characteristics were investigated by X-raydiffraction (XRD) and scanning electron microscopy (SEM) techniques, respectively. The crack self-healing capacitywas evaluated by Brazilian test. The test results indicate that the SP has especially supplementary effect on waterreducing and excellent property of better control of slump loss. The concrete flowability increases remarkably withthe increase of SP replacement level in the range of 20% to 50%. The compressive and splitting tensile strengthsof HPC containing SP are higher than the corresponding strength of the control concrete at all ages. The crackself-healing ability is highly dependent on SP content of HPC.展开更多
This study investigated the effect of silica fume(SF) on mechanical properties of concrete incorporating steel slag powder(SSP). The compressive strength and splitting strength tests of concrete with different content...This study investigated the effect of silica fume(SF) on mechanical properties of concrete incorporating steel slag powder(SSP). The compressive strength and splitting strength tests of concrete with different content of SF(0%, 4%, 8% and 12%) and of SSP(0%, 10%, 20%, 30% and 40%) were carried out, and the test results were analyzed and fitted. Obtained results showed that the brittleness, compressive strength and compressive strength discreteness of concrete increased due to the incorporation of SF. SSP weakened the compressive strength of concrete, which reduced within 10% when the content of SSP was less than 20%. SF and SSP showed synergistic hydration effect when they were mixed, and the optimal group was SF8 SSP30, whose compressive strength was close to that of plain concrete, and whose brittleness as well as discreteness of compressive strength were lower relatively. With the content of SSF and of SSP as variables, the tension-compression ratio and compressive strength of concrete can be well estimated by surface fitting.展开更多
A rapid analysis method of determining content of eight compounds of open-hearth furnace slag was developed using X-ray fluorescence spectrometry and pressed powder briquettes. Matrix effect was corrected using theore...A rapid analysis method of determining content of eight compounds of open-hearth furnace slag was developed using X-ray fluorescence spectrometry and pressed powder briquettes. Matrix effect was corrected using theoretical alpha coefficient. Grains-size effect was eliminated by optimized sample preparation technique parameters. Mineral effect was corrected with standard curve of specially made standard samples. The analysis results of TiO2, TFe, SiO2, MgO, Al2O3, CaO, MnO and P2O5 in slag samples showed that both precision and accuracy are comparable with that of chemical method.展开更多
The reduction rate of Fe_tO in CaO-SiO_2-Al_2O_3-Fe_tO slags with graphite powder has been determined in an alumina crucible at 1 673-1 823 K.The effects of temperature,slag basicity and Fe_tO content on the reduction...The reduction rate of Fe_tO in CaO-SiO_2-Al_2O_3-Fe_tO slags with graphite powder has been determined in an alumina crucible at 1 673-1 823 K.The effects of temperature,slag basicity and Fe_tO content on the reduction rate have also been discussed.Test results show that the reduction rate increases with the increase of temperature or Fe_tO concentration in slags,and the reduction rate has a parabolic relation with slag simple basicity or optical basicity.The maximum reduction rate is observed around CaO/SiO_2 = l.5 of molten slags.The reaction order is 1.26 or 1.31,and the reduction activation energy is 126.8 or 129.7 kJ/mol respectively in regard to Fe_tO content or Fe_tO activity calculated by using regular solution model.The reduction rate of Fe_tO in CaO-SiO_2-Al_2O_3-Fe_tO slags with graphite powder is in the range of 0.15×10^(-4)- 0.86×10^(-4) mol-O/cm^2 · s.展开更多
The prevention and treatment of mercury in coal-fired power plants has always been the focus and difficulty.How to control the pollution of mercury to human body and ecological environment quickly and effectively is a...The prevention and treatment of mercury in coal-fired power plants has always been the focus and difficulty.How to control the pollution of mercury to human body and ecological environment quickly and effectively is a hot research topic nowadays.As a low cost and potential adsorbent,there is a huge space for the development of coal dry powder gasification coarse slag.In this paper,Mercury osmotic tubes are heated by water bath tank as mercury source,and the scavenging effect of adsorbent on Mercury monomer under different influence conditions is explored.The adsorbent plays an important role in adsorption of mercury monomer because of its special active sites on the surface.The reason is that the adsorbent surface is rich in carboxyl group,hydroxyl functional group,combined with mercury to form complexes.This shows that chemical adsorption facilitates the adsorption process.展开更多
基金Funded by National Natural Science Foundation of China(No.52278446)。
文摘In order to evaluate the feasibility of steel slag powder as filler,the coating properties of steel slag and limestone aggregate were compared by water boiling test,the micro morphology difierences between steel slag powder and mineral powder(limestone powder)were compared by scanning electron microscope(SEM),and the high-temperature rheological properties of asphalt mortar with difierent ratio of filler quality to asphalt quality(F/A)and difierent substitution rates of mineral powder(S/F)were studied by dynamic shear rheological test.The results show that the surface microstructure of steel slag powder is more abundant than that of mineral powder,and the adhesion of steel slag to asphalt is better than that of limestone.At the same temperature,the lower the ratio of S/F is,the greater the rutting factor and complex modulus will be.In addition,the complex modulus and rutting factor of the asphalt mortar increase with the increase of F/A,and the filler type and F/A have a negligible efiect on the phase angle.
基金This work was supported by the Gui Ke Neng(19-J-21-7 and 19-J-21-12).
文摘In order to increase use ratio of steel slag solid waste,the concrete containing steel slag powder and zeolite powder as admixtures was prepared by using the orthogonal test method.The effects of water-binder ratio,sand ratio,steel slag powder content and zeolite powder on working properties,mechanical strength and chloride ion permeability of the concrete was studied.It was found that the early strength of the concrete had a decrease with the mixing of steel slag and zeolite powders,but its later strength approached to pure concrete.Moreover,the physical filling and pozzolanic activity of the admixtures increased the density of the concrete,resulting in the improvement of the durability of the concrete by the migration speed of Cl−reducing.The optimum mix ratio of C40 steel slag powder-zeolite powder concrete is obtained,and which had the slump of 220 mm,the 3 d,7 d and 28 d compressive strengths of 27.8 MPa,37.5 MPa and 48.4 MPa,the 6 h electric flux of 950 C and the diffusion coefficient of 1.65×10−12 m2/s.
基金This work was financially supported by the National Key Research and Development Program of China(No.2018YFC1900500)Graduate Research and Innovation Foundation of Chongqing,China(No.CYB17002).
文摘The oxidation pathway and kinetics of titania slag powders in air were analyzed using differential scanning calorimetry(DSC)and thermogravimetry(TG).The oxidation pathway of titania slag powder in air was divided into three stages according to their three exothermic peaks and three corresponding mass gain stages indicated by the respective non-isothermal DSC and TG curves.The isothermal oxidation kinetics of high titania slag powders of different sizes were analyzed using the ln-ln analysis method.The results revealed that the entire isothermal oxidation process comprises two stages.The kinetic mechanism of the first stage can be described as f(α) = 1.77(1-α) [-ln (1-α)]^((1.77-1)/1.77),f(α)= 1.97(1-α) [-ln (1-α)]^((1.97-1)/1.97),and f (α) = 1.18(1-α) [-ln (1-α)]^((1.18-1)/1.18).The kinetic mechanism of the second stage for all samples can be described as f (α)=1.5(1-α)^(2/3)[1-(1-α)^(1/3)]^(-1).The activation energies of titania slag powders with different sizes(d_(1)<0.075 mm,0.125 mm<d_(2)<0.150 mm,and 0.425 mm<d_(3)<0.600 mm)for different reaction degrees were calculated.For the given experimental conditions,the rate-controlling step in the first oxidation stage of all the samples is a chemical reaction.The rate-controlling steps of the second oxidation stage are a chemical reaction and internal diffusion(for powders d_(1)<0.075 mm)and internal diffusion(for powders 0.125 mm<d_(2)<0.150 mm and 0.425 mm<d_(3)<0.600 mm).
文摘Dry ball milling and wet ball milling were used to treat converter slag with particle size < 10 mm and the converter slag powder was stabilized by H2O only and H2O coupled with CO2.respectively.Results showed that when CO2 &H2O was used,the free-calcium oxide（f-CaO） content in converter slag decreased significantly and after an-hour treatment the f-CaO content was reduced to 3%;however,when only treated by H2O without CO2, f-CaO needed 3-hour stabilization to decrease its content to 3%.When f-CaO in converter slag powder was treated by CO2 &H2O,its main reaction products were CaCO3 and then Ca（OH）2;however,when only H2O was used, the f-CaO content decreased gently and the main products were Ca（OH）2.
基金Funded by National 973 Project (No.2001CB610704-2)
文摘Hydration heat evolution, non-evaporative water, setting time and SEM tests were performed to investigate the effect of fine steel slag powder on the hydration process of Portland cement and its mechanism. The results show that the effect of fine steel slag powder on the hydration process of Portland cement is closely related to its chemical composition, mineral phases, fineness, etc. Fine steel slag powder retards the hydration of portland cement at early age. The major reason for this phenomenon is the relative high content of MgO, MnO2, P2O5 in steel slag, and MgO solid solved in C3S contained in steel slag.
基金Funded by the Guide Project in National Science & Technology Pillar Program during the 10th Five-Year Plan Period (2003BA652C)
文摘To decrease the cement and SF content of RPC by using ultra-fine fly ash (UFFA) and steel slag powder (SS), the effect of these mineral admixtures on compressive strength of RPC were investigated. The experimental results indicate that the utilization of UFFA and SS in RPC is feasible and has prominent mechanical performance. The microstructure analysis (SEM and TG-DTG-DSC) demonstrated that the excellent mechanical properties of RPC containing SS and UFFA were mainly attributed to the sequential hydration filling effect of the compound system.
基金Funded by the National Natural Science Foundation of China(Nos.51208370,51172164)the Fundamental Research Funds for the Central Universities(No.0500219170)
文摘The workability and durability of a type of sustainable concrete made with steel slag powder were investigated. The hydrated products of cement paste with ground granulated blast furnace slag(GGBFS) alone or with a combined admixture of GGBFS-steel slag powder were investigated by X-ray diffraction(XRD). Furthermore, the mechanism of chemically activated steel slag powder was also studied. The experimental results showed that when steel slag powder was added to concrete, the slumps through the same time were lower. The initial and fi nal setting times were slightly retarded. The dry shrinkages were lower, and the abrasion resistance was better. The chemically activated steel slag powder could improve compressive strengths, resistance to chloride permeation and water permeation, as well as carbonization resistance. XRD patterns indicated that the activators enhanced the formation of calcium silicate hydrate(C-S-H) gel and ettringite(AFt). This research contributes to sustainable disposal of wastes and has the potential to provide several important environmental benefi ts.
基金Funded by the National Natural Science Foundation of China(Nos.51208370,51172164)the Doctoral Program of Higher Education of China(No.20110072120046)+1 种基金the Fundamental Research Funds for the Central Universities(No.0500219170)the Opening Measuring Fund of LargeApparatus of Tongji University(No.0002012011)
文摘The feasibility of flue gas desulphurization(FGD) as concrete admixture was studied. A combined concrete admixture of the thermally-treated FGD gypsum and slag powder was explored. The FGD gypsum was roasted at 200 ℃ for 60 min and then mixed with the slag powder to form FGD gypsum-slag powder combined admixture in which the SO 3 content was 3.5wt%. Cement was partially and equivalently replaced by slag powder alone or FGD gypsum-slag powder, at concentration of 25wt%, 40wt%, and 50wt%, respectively. The setting times, hydration products, total porosity and pore size distributions of the paste were determined. The compressive strength and drying shrinkage of cement mortar and concrete were also tested. The experimental results show that, in the presence of FGD gypsum, the setting times are much slower than those of pastes in the absence of FGD gypsum. The combination of FGD gypsum and slag powder provides synergistic benefits above that of slag powder alone. The addition of FGD gypsum provides benefit by promoting ettringite formation and forms a compact microstructure, increasing the compressive strength and reduces the drying shrinkage of cement mortar and concrete.
基金The research work presented in this paper was conducted with partial support from the Foundation for University Key Teacher by the Ministry of EducationThe first author also gratefully acknowledges the financial support from NSFC (No. 59908007) t
文摘A superfine slag powder (SP) made from granulated blast furnace slag incorporating activators by using special millingtechnique, was used as supplementary cementitious material in high performance concrete (HPC), replacing part ofthe mass of normal Portland cement. The effects of the SP on the workability, mechanical and crack self-healingproperties of HPC were studied. The hydration process and microstructure characteristics were investigated by X-raydiffraction (XRD) and scanning electron microscopy (SEM) techniques, respectively. The crack self-healing capacitywas evaluated by Brazilian test. The test results indicate that the SP has especially supplementary effect on waterreducing and excellent property of better control of slump loss. The concrete flowability increases remarkably withthe increase of SP replacement level in the range of 20% to 50%. The compressive and splitting tensile strengthsof HPC containing SP are higher than the corresponding strength of the control concrete at all ages. The crackself-healing ability is highly dependent on SP content of HPC.
文摘This study investigated the effect of silica fume(SF) on mechanical properties of concrete incorporating steel slag powder(SSP). The compressive strength and splitting strength tests of concrete with different content of SF(0%, 4%, 8% and 12%) and of SSP(0%, 10%, 20%, 30% and 40%) were carried out, and the test results were analyzed and fitted. Obtained results showed that the brittleness, compressive strength and compressive strength discreteness of concrete increased due to the incorporation of SF. SSP weakened the compressive strength of concrete, which reduced within 10% when the content of SSP was less than 20%. SF and SSP showed synergistic hydration effect when they were mixed, and the optimal group was SF8 SSP30, whose compressive strength was close to that of plain concrete, and whose brittleness as well as discreteness of compressive strength were lower relatively. With the content of SSF and of SSP as variables, the tension-compression ratio and compressive strength of concrete can be well estimated by surface fitting.
文摘A rapid analysis method of determining content of eight compounds of open-hearth furnace slag was developed using X-ray fluorescence spectrometry and pressed powder briquettes. Matrix effect was corrected using theoretical alpha coefficient. Grains-size effect was eliminated by optimized sample preparation technique parameters. Mineral effect was corrected with standard curve of specially made standard samples. The analysis results of TiO2, TFe, SiO2, MgO, Al2O3, CaO, MnO and P2O5 in slag samples showed that both precision and accuracy are comparable with that of chemical method.
文摘The reduction rate of Fe_tO in CaO-SiO_2-Al_2O_3-Fe_tO slags with graphite powder has been determined in an alumina crucible at 1 673-1 823 K.The effects of temperature,slag basicity and Fe_tO content on the reduction rate have also been discussed.Test results show that the reduction rate increases with the increase of temperature or Fe_tO concentration in slags,and the reduction rate has a parabolic relation with slag simple basicity or optical basicity.The maximum reduction rate is observed around CaO/SiO_2 = l.5 of molten slags.The reaction order is 1.26 or 1.31,and the reduction activation energy is 126.8 or 129.7 kJ/mol respectively in regard to Fe_tO content or Fe_tO activity calculated by using regular solution model.The reduction rate of Fe_tO in CaO-SiO_2-Al_2O_3-Fe_tO slags with graphite powder is in the range of 0.15×10^(-4)- 0.86×10^(-4) mol-O/cm^2 · s.
文摘The prevention and treatment of mercury in coal-fired power plants has always been the focus and difficulty.How to control the pollution of mercury to human body and ecological environment quickly and effectively is a hot research topic nowadays.As a low cost and potential adsorbent,there is a huge space for the development of coal dry powder gasification coarse slag.In this paper,Mercury osmotic tubes are heated by water bath tank as mercury source,and the scavenging effect of adsorbent on Mercury monomer under different influence conditions is explored.The adsorbent plays an important role in adsorption of mercury monomer because of its special active sites on the surface.The reason is that the adsorbent surface is rich in carboxyl group,hydroxyl functional group,combined with mercury to form complexes.This shows that chemical adsorption facilitates the adsorption process.
