The photodissociation dynamics of isocyanic acid (HNCO) has been studied by the time- sliced velocity map ion imaging technique at 193 nm. The NH(a1△) products were measured via (2+1) resonance enhanced multip...The photodissociation dynamics of isocyanic acid (HNCO) has been studied by the time- sliced velocity map ion imaging technique at 193 nm. The NH(a1△) products were measured via (2+1) resonance enhanced multiphoton ionization. Images have been accumulated for the NH(a1△) rotational states in the ground and vibrational excited state (v=0 and 1). The center-of-mass translational energy distribution derived from the NH(a1△) images implies that the CO vibrational distributions are inverted for most of the measured 1NH(v|j) internal states. The anisotropic product angular distribution observed indicates a rapid dissociation process for the N-C bond cleavage. A bimodal rotational state distribution of CO(v) has been observed, this result implies that isocyanic acid dissociates in the S1 state in two different pathways.展开更多
针对传统林权地籍调查普遍存在的难度大、效率低、成果质量差等问题,本文基于安卓移动平板与三维高清影像模型、ArcGIS for Android、栅格切片地图、动态表单等技术设计了移动三维林权地籍调查系统,实现了“内业为主、外业为辅”林权地...针对传统林权地籍调查普遍存在的难度大、效率低、成果质量差等问题,本文基于安卓移动平板与三维高清影像模型、ArcGIS for Android、栅格切片地图、动态表单等技术设计了移动三维林权地籍调查系统,实现了“内业为主、外业为辅”林权地籍调查的相关功能。福建省三明市沙县林权类不动产登记规范化制度建设试点的应用实践表明,该系统能有效减轻林权地籍调查的内外业工作难度,提高工作效率和调查成果质量,对沙县林权类不动产登记工作具有显著的提质增效作用。展开更多
基金The experimental work is supported by the National Natural Science Foundation of China(No.22241304,No.22225303)the National Natural Science Foundation of China(NSFC Center for Chemical Dynamics,No.22288201)+3 种基金the Scientific Instrument Developing Project of the Chinese Academy of Sciences(No.GJJSTD20220001)the Innovation Program for Quantum Science and Technology(No.2021ZD0303304)Xueming Yang also thanks the Guangdong Science and Technology Program(No.2019ZT08L455 and No.2019JC01X091)the Shenzhen Science and Technology Program(No.ZDSYS20200421111001787).
基金supported by the National Natural Science Foundation of China(No.21573227,N0.11604052)the National Science Foundation of Anhui Province of China(No.1608085QA19)+2 种基金the Natural Science Research Project of Education Department of Anhui Province of China(No.2014KJ020)the Open Foundation of State Key Laboratory(No.SKLMRDK201503,No.SKLMRD-K201611,and No.SKLMRDK201711)the Doctoral Foundation of Fuyang Normal University(No.FSB201501005)
文摘The photodissociation dynamics of isocyanic acid (HNCO) has been studied by the time- sliced velocity map ion imaging technique at 193 nm. The NH(a1△) products were measured via (2+1) resonance enhanced multiphoton ionization. Images have been accumulated for the NH(a1△) rotational states in the ground and vibrational excited state (v=0 and 1). The center-of-mass translational energy distribution derived from the NH(a1△) images implies that the CO vibrational distributions are inverted for most of the measured 1NH(v|j) internal states. The anisotropic product angular distribution observed indicates a rapid dissociation process for the N-C bond cleavage. A bimodal rotational state distribution of CO(v) has been observed, this result implies that isocyanic acid dissociates in the S1 state in two different pathways.
文摘针对传统林权地籍调查普遍存在的难度大、效率低、成果质量差等问题,本文基于安卓移动平板与三维高清影像模型、ArcGIS for Android、栅格切片地图、动态表单等技术设计了移动三维林权地籍调查系统,实现了“内业为主、外业为辅”林权地籍调查的相关功能。福建省三明市沙县林权类不动产登记规范化制度建设试点的应用实践表明,该系统能有效减轻林权地籍调查的内外业工作难度,提高工作效率和调查成果质量,对沙县林权类不动产登记工作具有显著的提质增效作用。