Salinized soil is an important reserved arable land resource in China.The management and utilization of salinized soil can safeguard the current size of arable land and a stable grain yield.Salt accumulation will lead...Salinized soil is an important reserved arable land resource in China.The management and utilization of salinized soil can safeguard the current size of arable land and a stable grain yield.Salt accumulation will lead to the deterioration of soil properties,destroy soil production potential and damage soil ecological functions,which in turn will threaten global water and soil resources and food security,and affect sustainable socio-economic development.Microorganisms are important components of salinized soil.Microbial remediation is an important research tool in improving salinized soil and is key to realizing sustainable development of agriculture and the ecosystem.Knowledge about the impact of salinization on soil properties and measures using microorganisms in remediation of salinized soil has grown over time.However,the mechanisms governing these impacts and the ecological principles for microbial remediation are scarce.Thus,it is imperative to summarize the effects of salinization on soil physical,chemical,and microbial properties,and then review the related mechanisms of halophilic and halotolerant microorganisms in salinized soil remediation via direct and indirect pathways.The stability,persistence,and safety of the microbial remediation effect is also highlighted in this review to further promote the application of microbial remediation in salinized soil.The objective of this review is to provide reference and theoretical support for the improvement and utilization of salinized soil.展开更多
Bacterial populations isolated from treated soil,artificially contaminated with lead(Pb)and cadmium(Cd)and undergoing a phytoremediation process were studied to determine their potential application in soil remediatio...Bacterial populations isolated from treated soil,artificially contaminated with lead(Pb)and cadmium(Cd)and undergoing a phytoremediation process were studied to determine their potential application in soil remediation.The physicochemical parameters evaluated in the soil varied significantly.Ten bacterial strains were selected from each polluted soil to test tolerance and growth in contaminated media.The concentrations of heavy metals tested were 1,000 ppm for lead and 850 ppm for cadmium.These strains were morphologically identified through Gram staining.Four strains showing the most significant growth in both contaminants were then selected to verify their tolerance to different concentrations of heavy metals.The results demonstrated that the selected bacteria have high tolerance to Pb,resisting inhibition up to 2,000 ppm.In contrast,strains exposed to cadmium tended to slow their growth as the concentration increased.展开更多
This study aimed to remediate in-situ leach mining contaminated soil by amendment-plant synergism. The results showed that plant species exhibited ex-tremely significant effects on the concentration of nitrate nitroge...This study aimed to remediate in-situ leach mining contaminated soil by amendment-plant synergism. The results showed that plant species exhibited ex-tremely significant effects on the concentration of nitrate nitrogen; to be specific, the concentration of nitrate nitrogen in soil planted with wheat was reduced from 692.19 mg/kg to lower than 100 mg/kg; when the mass ratio of amendment to soil reached 3：50 and the amendment particle size was 1-2 mm, the concentration of nitrate ni-trogen in soil planted with wheat was reduced to 43 mg/kg. The amendment type exhibited extremely significant effects on the concentration of ammonium nitrogen; to be specific, when the mass ratio of amendment to soil reached 10：50, the concen-tration of ammonium nitrogen in soil added with 2-3 mm zeolite was reduced from 23 593.75 to 3 300 mg/kg on day 15. Amendments and plants mainly exhibited desorption performance for sulfate radical in soil, and the amendment type extreme-ly significantly affected the concentration of sulfate radical; to be specific, the con-centration of sulfate radical in soil added with limestone increased from 370 mg/kg to 900 mg/kg on day 7.展开更多
A microscopic diffusion-reaction modei was developed to simulate in-situ ozonation for the remediation of contaminated soil, i.e., to predict the temporal and spatial distribution of target contaminant in the subsurfa...A microscopic diffusion-reaction modei was developed to simulate in-situ ozonation for the remediation of contaminated soil, i.e., to predict the temporal and spatial distribution of target contaminant in the subsurface. The sequential strategy was employed to obtain the numerical solution of the modei using finite difference method. A non-uniform grid of discretization points was emploved to increase the accuracy of the numerical solution by means of coordinate transformation. One-dimensional column tests were conducted to verify the modei. The column was packed with simulated soils that were spiked with 2-chlorophenol. Ozone gas passed through the column at a flow rate of 100ml·min-1. The residual 2-chlorophenol content at different depths of the column was determined at fixed time intervals. Compared the experimental data with the simulated values, it was found that the mathematical modei fitted data well during most time of the experiment.展开更多
Experimental study of enhanced in-situ micro-ecological remediation of petroleum contaminated loess soil was carried out in Zhongyuan oil production areas, and the enhanced in-situ micro-ecological remediation techniq...Experimental study of enhanced in-situ micro-ecological remediation of petroleum contaminated loess soil was carried out in Zhongyuan oil production areas, and the enhanced in-situ micro-ecological remediation technique includes optimistic in-situ microbial communities, physical chemistry methods, alfalfa planting and regulation of soil environmental elements. Experiments showed that the oil content in the contaminated soil with oil content about 2 898.25 mg/kg can be reduced about 98.61% after in-situ micro-ecological remediation for 99 days, which demonstrated the effectiveness of in-situ micro-ecological remediation methods for petroleum contaminated soil in central plains of China, and explored the practical and feasible application of these methods.展开更多
A computational fluid dynamics(CFD)numerical simulation and field experiment were used to investigate optimal operating parameters of high-pressure jet grouting equipment and clarify the boundary law of the injection ...A computational fluid dynamics(CFD)numerical simulation and field experiment were used to investigate optimal operating parameters of high-pressure jet grouting equipment and clarify the boundary law of the injection area in the remediation process.The response surface optimization design results show that the optimal injection pressure is 30 MPa,rotation speed is 23 r/min,commission speed is 30 cm/min,and the optimal injection diameter is 147.3 cm.Based on the CFD numerical simulation,the ratio of the injection core,turbulent zone,and seepage zone is approximately 1∶4∶2.The distribution law of jet core,turbulence zone and seepage zone at different cross-sections under 30 MPa operating conditions is as follows:The jet core radius is approximately 100 mm,the turbulence zone is mainly distributed at 100 to 500 mm,the seepage zone is mainly distributed at 500 to 700 mm,the seepage zone could be completed within 2 h,and the proportion of the three boundary zones in the injection zone is similar to that of the numerical simulation.This study provides theoretical parameters and practical reference for the remediation of deep pollution via in-situ chemical oxidation in the Loess Plateau soil environment.展开更多
To improve the conventional electrokinetic remediation of Pb-contaminated soil,the Pb-contaminated soil near a lead acid battery factory in the Pearl River Delta region of China was electrokinetically remedied with po...To improve the conventional electrokinetic remediation of Pb-contaminated soil,the Pb-contaminated soil near a lead acid battery factory in the Pearl River Delta region of China was electrokinetically remedied with polarity exchange technique.The variations in Pb removal efficiency and the soil p H value with the treatment time and the exchange polarity interval were determined.It is found that the removal efficiency of Pb reaches a maximum of 87.7% when the voltage gradient is 1 V/cm and the exchange polarity interval is 48 h.This value is far higher than that obtained with conventional electrokinetic remediation（61.8%）.Additionally,the ＂focusing effect＂ which appears in the conventional electrokinetic remediation can be avoided,and thus additional chemicals are not needed for the polarity exchange technique.The mechanism of Pb electromigration behavior in soil during the treatment with the polarity exchange technique was described.展开更多
[Objective] To study the remediation efficiency of red mud on Pb, Zn and Cd in the heavy metal contaminated paddy soil of mine area, to clarify its remediation mechanism and fertilizer efficiency on heavy metal contam...[Objective] To study the remediation efficiency of red mud on Pb, Zn and Cd in the heavy metal contaminated paddy soil of mine area, to clarify its remediation mechanism and fertilizer efficiency on heavy metal contaminated soil. [Method] The soil incubation experiment was conducted to study the effect of red mud on the pH values and electrical conductivity （EC）, and the remediation efficiency of red mud on lead （Pb）, zinc （Zn） and cadmium （Cd） in heavy metal contaminated soil. [Result] Red mud addition reduced the content of exchangeable Pb, Zn and Cd in the soil significantly. Compared with the control, when incubated for 30, 60 and 90 d with the red mud dosage of 4% （W/W）, the exchangeable Pb content was decreased by 39.25%, 41.38% and 50.19%; exchangeable Zn content was decreased by 49.26%, 57.32% and 47.16%; and exchangeable Cd content was decreased by 19.53%, 24.06% and 25.70%, respectively. The application of red mud had significant impact on the share of Pb, Zn and Cd contents in five forms, and different amounts of red mud application all reduced the proportion of exchangeable Pb, Zn and Cd to the total Pb, Zn and Cd. In addition, the proportion of exchangeable Pb, Zn and Cd to total Pb, Zn and Cd decreased with the increasing amount of red mud addition. [Conclusion] The study provided references for reasonable application of red mud and reduction of heavy metal pollution in paddy soil.展开更多
[Objective] The research aimed to study the effects of fertilization on soil remediation.[Method]Pot fertilizer tests were conducted to remedy the soils which had off-balanced in nutrients resulted by long-term unreas...[Objective] The research aimed to study the effects of fertilization on soil remediation.[Method]Pot fertilizer tests were conducted to remedy the soils which had off-balanced in nutrients resulted by long-term unreasonable fertilization.[Result]The results showed that applying NPK fertilizers with manure was the best method to restore the soil nutrients and increase soil fertility and crop yield;NPK and NP fertilizers could balance soil fertility and increase crop yields,the effects were the same and next to MNPK.Phosphate and nitrogen respectively had the similar restoring effect with NPK fertilizers on soil from long-term NK and PK treatments.[Conclusion]Crops in soil with long-term applying NPK fertilizers had strong dependence on fertilizers.The yields of corn and wheat decreased by 78.6% and 52.8% respectively after stopping applying fertilizers.Meanwhile,The yields of corn and wheat increased by 112% and 182% respectively after stopping applying fertilizers in NK treatment as well as 15.1% and 59% in PK treatment.Manure had strong and last effect on increasing yield.展开更多
Flax is an ideal crop for remedying soil contaminated by heavy metals. It has high tolerance to heavy metals and strong adsorption to heavy metals. Through properly using or adjusting external conditions such as regul...Flax is an ideal crop for remedying soil contaminated by heavy metals. It has high tolerance to heavy metals and strong adsorption to heavy metals. Through properly using or adjusting external conditions such as regulator, moisture, fertilizer, microorganisms, and pH value, it is able to improve ability of flax to absorb, trans- fer, and accumulate heavy metals. To improve the ability of flax in remediating heavy metal contaminated soil, it is recommended to strengthen cultivation of flax varieties and screening of germplasm resources, actively carry out studies on tech- nologies of fax remedying heavy metal contaminated soil, implement large-scale and mechanized planting of flax, and promote control of heavy metal contaminated soil.展开更多
Phytoremediation is becoming a cost-effective technology for the in-situ clean up of sites polluted with hydrophobic organic contaminants （HOCs）. The major factors limiting phytoremediation are the mass transfer, ra...Phytoremediation is becoming a cost-effective technology for the in-situ clean up of sites polluted with hydrophobic organic contaminants （HOCs）. The major factors limiting phytoremediation are the mass transfer, rate of plant uptake, and microbial biodegradation of HOCs. This article discusses the potential of surfactants to enhance desorption, plant uptake, and biodegradation of HOCs in the contaminated sites. Positive effects of surfactants on phytoremediation have been recently observed in greenhouse studies. The presence of some nonionic surfactants including polyoxyethylene sorbltan monooleate （Tween 80） and polyoxyethylene（23）dodecanol （Brij35） at relatively low concentrations resulted in significant positive effects on phytoremediation for pyrene-contaminated soil. However, the anionic surfactant （sodium dodecyl sulfate, SDS） and the cationic surfactant （cetyltrimethylammonium bromide, CTMAB） were not useful because of their phytotoxicity or low efficiency for surfactant-enhanced phytoremediation （SEPR）. The mechanisms of SEPR for HOC-contaminated sites were evaluated by considering experimental observations. In view of concerns about the cost effectiveness and toxicity of surfactants to plants, more research is needed to enhance the use of SEPR technology.展开更多
Soil and land degradation in the tropics can be identified and described interms of physical, chemical, and biological changes from its pristine state brought about by naturaland anthropogenic influences. A characteri...Soil and land degradation in the tropics can be identified and described interms of physical, chemical, and biological changes from its pristine state brought about by naturaland anthropogenic influences. A characteristic of these ecosystems is their capacity to recyclenutrients through soil organic matter (SOM). Following disturbance through changed land management,SOM is rapidly mineralized and there is a corresponding decline in fertility and the variable chargecomponent of the cation exchange capacity. As these ecosystems are strongly dependent on SOM fortheir functionality, changed land use can have irreversible impacts on the productivity of thesesystems. The paper focuses on quantifying chemical degradation through 'benchmarking' using datafrom paired sites in tropical China and Thailand using surface charge fingerprinting. Using valuestaken from the fingerprint of an undisturbed soil, an index of chemical degradation from 'ideality'was calculated. Various management strategies that attempt to reverse degradative trends or improvepoor quality soils in their natural condition are discussed, such as the addition of natural claysand silicated materials. Results are present to show the effect of each of the aforementionedstrategies on surface charge characteristics and associated increases in plant productivity.展开更多
The technology of in situ immobilization with amendments is an important measure that remediates the soil contaminated by heavy metals, and selecting economical and effective amendments is the key. The effects and mec...The technology of in situ immobilization with amendments is an important measure that remediates the soil contaminated by heavy metals, and selecting economical and effective amendments is the key. The effects and mechanism of steel slag, the silicon-rich alkaline byproduct which can remediate acidic soil contaminated by heavy metal, are mainly introduced in this paper to provide theory reference for future research. Firstly, the paper analyzes current research situation of in situ immobilization with amendments. Then, it introduces the main physicochemical properties of steel slag, and the effect on soil pH value as well as heavy metal activity. Besides, the paper elaborates the promoting effect on silicon-requiring plant and the strengthening mechanism for its resistant capability of heavy metal. According to the analysis, the application of steel slag could be a potential valuable strategy to remediate acidic soil contaminated by heavy metal by modifying the transformation of heavy metals in both soil and plant, so that the translocation of heavy metal in food chain is reduced.展开更多
Soil, an important material basis for human activities, is an indispensable natural rasource that is difficult to regenerate. It is also an important part of human ecological environment. Currently, soil pollution has...Soil, an important material basis for human activities, is an indispensable natural rasource that is difficult to regenerate. It is also an important part of human ecological environment. Currently, soil pollution has affected China＇s agricultural production and threatened human health and ecological safety, so it has been paid more attention to by the people and has become a hot spot in environmental field. Through continuous research, a variety of soil remediation patents and technologies also emerge. Here, by retrieving the main words through the website （www. soopat. corn） and Chinese patent net, types of soil pollution and remediation technologies under the authorization status of the patents were analyzed, and the major species of soil pollutants and soil remediation technologies were reviewed.展开更多
Soil pollution endangers human health and ecological balance,which is why finding a highly efficient way to deal with pollutants is necessary.Biological method is an environmentally friendly treatment method.Bioelectr...Soil pollution endangers human health and ecological balance,which is why finding a highly efficient way to deal with pollutants is necessary.Biological method is an environmentally friendly treatment method.Bioelectrochemical systems(BESs),which combine electrochemistry with biological methods,have been widely used to remediate polluted environments,including wastewater,sludge,sediment,and soil.In BESs,redox reactions occur on electrodes with electroactive bacteria,which convert pollutants into low-polluting or nonpolluting substances.With BESs being a promising technology in the remediation field,the decontamination mechanisms and applications in soil conducted by BESs have attracted much attention.Therefore,to better understand the research progress of BESs,this paper mainly summarizes the mechanism of different classified BESs.The applications of microbial fuel cells(MFCs)in four pollutants(petroleum,heavy metals,pesticides,antibiotics)and the possible applications of microbial electrolysis cells(MECs)in soil are discussed.The main problems in BESs and possible future development directions are also evaluated.展开更多
This paper presents the development of a new remediation technology for contaminated sandy soil using humic acid (HA). Distribution of amount of Cr (VI) in the aqueous or solid system containing humic acid and sandy s...This paper presents the development of a new remediation technology for contaminated sandy soil using humic acid (HA). Distribution of amount of Cr (VI) in the aqueous or solid system containing humic acid and sandy soil, was studied using batch experiments, es-pecially for effects of reaction time, pH, concentrations, temperature and irradiation on the reduction of Cr (VI), and the optimum reaction conditions. The results indicated a significant increase of the adsorption of Cr (VI) because of the complexion reaction between HA and Cr (VI) that occurred under acidic condition. The reaction mechanisms of HA with chromium on sand surfaces were certified. Thus it came to a conclusion that HA could be used effectively on remediation of Cr (VI)–contaminated soil and groundwater in a wide range of pH, with or without sunlight. These results suggest that the organic-inorganic complex—such as sandy soils coated with humic substances—is important as a metal reservoir in the environment.展开更多
It is generally known that soil pollution poses a terrible hazard to the environment, but the present techniques of contaminated soil remediation cannot control this growing threat. This paper compares the pollutant e...It is generally known that soil pollution poses a terrible hazard to the environment, but the present techniques of contaminated soil remediation cannot control this growing threat. This paper compares the pollutant extraction efficiency of traditional pumping and treating, which is a typical washing technology for the remediation of contaminated soils, with methods that utilize freeze-thaw cycles. In the soil freezing process, water shifts from unfrozen soils to the freezing front, and the permeability of soil will be enhanced under certain temperature gradients and water conditions. Therefore, this paper discusses the purification of contaminated soil through freeze-thaw action. We conducted a cleansing experiment on clay and silica sand infused with NaCl（simulation of heavy metals） and found that the efficiency of purification was enhanced remarkably in the latter by the freeze-thaw action. To assess the effective extraction of DNAPLs in soil, we conducted an experiment on suction by freezing, predicated on the different freezing points of moisture and pollutants. We found that the permeability coefficient was significantly increased by the freezing-thawing action, enabling the DNAPL contaminants to be extracted selectively and effectively.展开更多
This paper discussed the optimization of conditions for remediation of crude oil-polluted soil based on pot experiment by applying reed-specific degrading bacteria, and using response surfaces methodology. We took the...This paper discussed the optimization of conditions for remediation of crude oil-polluted soil based on pot experiment by applying reed-specific degrading bacteria, and using response surfaces methodology. We took the initial crude oil concentration, the amount of inoculation, the ratio of nitrogen and phosphorus, and the use of surfactant （Tween-80） as independent variables （factors）, and the degrading ratio of crude oil as the dependent variable （response） after a 90-day experiment. The experiment explored the impacts of each independent variable and their interactions on the bioremediation of crude oil-polluted soil using the Box-Behnken design. Working with a simulated forecasting model the study obtained optimization va reed＋specific degrading bacteria, a nitrogen to phosphorus ues for the treatment parameters of 200 g/kg of the ratio of about 6.0. and 0.2% surfactant. Under experimental conditions, for crude oil concentrations of 10, 30 and 50 g/kg, the optimal effects of the treatments achieved 71.87%, 66.61% and 54.52% degradation of the crude oil, respectively. The results can provide a basis for the technical development of plant-microorganism combined bioremediation of crude oil-polluted soil.展开更多
Soil contaminated with typical heavy metals (Pb,Cd,Cu,and Zn) was remedied by using the polymeric aluminum salt coagulants including polyaluminum chloride (PAC) and polyaluminum sulfate (PAS).The remediation efficienc...Soil contaminated with typical heavy metals (Pb,Cd,Cu,and Zn) was remedied by using the polymeric aluminum salt coagulants including polyaluminum chloride (PAC) and polyaluminum sulfate (PAS).The remediation efficiencies are influenced by reaction time,water amount,and dosage of remediation agent.The optimal remediation conditions are as follows:6 h of reaction time,1 kg/kg of water addition amount,and 0.25 kg/kg of remediation agent dosage.After PAC addition,the remediation efficiencies of diethylenetriamine-pentaacetic acid (DTPA)-extractable Pb,Cd,Cu,and Zn reach 88.3%,85.1%,85.4%,and 73.7%,respectively;and those for PAS are 89.7%,88.7%,83.5%,and 72.6%,respectively.The main remediation mechanism of the polymeric aluminum salt may contribute to the ionization and hydrolysis of PAC and PAS.H + released from ionization of polymeric aluminum salt can cause the leaching of heavy metals,while the multinuclear complex produced from hydrolysis may result in the immobilization of heavy metals.For PAC,the immobilization of heavy metals is the main remediation process.For PAS,both leaching and immobilization are involved in the remediation process of heavy metals.展开更多
Phosphate is widely used to immobilize cadmium(Cd)and lead(Pb)in soils through the insoluble metal phosphate precipitation.However,an increase in the phosphorus content of the environment can cause new pollution.In th...Phosphate is widely used to immobilize cadmium(Cd)and lead(Pb)in soils through the insoluble metal phosphate precipitation.However,an increase in the phosphorus content of the environment can cause new pollution.In this study,five slow-release phosphate amendments(SRPAs)were synthesized and their characteristics including BET,SEM,FTIR,swelling ratio,and thephosphorus release were determined.The results show that SRPA was a sphere with a network structure with a specific surface area of 5 to 7.18 m^(2)/g andcontained phosphate,hydroxyl,carboxyl and other functional groups.Among five SRPAs,S3 sample showed good performance for phosphate release.Phosphate release from SRPA was well fitted with Ritger-Peppas model with constant n between 0.45 and 0.85,indicating that the phosphate release was in accordance with non-Fickian diffusion.As compared with monocalcium phosphate(MCP),SRPA application led to a lower concentration of water-soluble phosphorus in the soil sample and higher remediation efficiencies of Cd and Pb.The remediation efficiencies of water-soluble Cd and Pb in soil with SRPA were 97.1%and 97.9%,respectively.The remediation efficiencies of bioavailable Cd and Pb were 71.85%and 76.47%,respectively.The results of Tessier extraction showed that the exchangeable and carbonatebound fractions of Cd and Pb in the soil sample after SRPA application significantly reduced,while the residual fraction increased,indicating the stability of heavy metals increased.展开更多
基金the National Natural Science Foundation of China(No.42107513)the Key Projects of Natural Science Foundation of Gansu Province(No.22JR5RA051)+1 种基金the Gansu Province Science and Technology project(No.21JR7RA070)the Key Research and Development Program of Gansu Province(No.21YF5FA151).
文摘Salinized soil is an important reserved arable land resource in China.The management and utilization of salinized soil can safeguard the current size of arable land and a stable grain yield.Salt accumulation will lead to the deterioration of soil properties,destroy soil production potential and damage soil ecological functions,which in turn will threaten global water and soil resources and food security,and affect sustainable socio-economic development.Microorganisms are important components of salinized soil.Microbial remediation is an important research tool in improving salinized soil and is key to realizing sustainable development of agriculture and the ecosystem.Knowledge about the impact of salinization on soil properties and measures using microorganisms in remediation of salinized soil has grown over time.However,the mechanisms governing these impacts and the ecological principles for microbial remediation are scarce.Thus,it is imperative to summarize the effects of salinization on soil physical,chemical,and microbial properties,and then review the related mechanisms of halophilic and halotolerant microorganisms in salinized soil remediation via direct and indirect pathways.The stability,persistence,and safety of the microbial remediation effect is also highlighted in this review to further promote the application of microbial remediation in salinized soil.The objective of this review is to provide reference and theoretical support for the improvement and utilization of salinized soil.
文摘Bacterial populations isolated from treated soil,artificially contaminated with lead(Pb)and cadmium(Cd)and undergoing a phytoremediation process were studied to determine their potential application in soil remediation.The physicochemical parameters evaluated in the soil varied significantly.Ten bacterial strains were selected from each polluted soil to test tolerance and growth in contaminated media.The concentrations of heavy metals tested were 1,000 ppm for lead and 850 ppm for cadmium.These strains were morphologically identified through Gram staining.Four strains showing the most significant growth in both contaminants were then selected to verify their tolerance to different concentrations of heavy metals.The results demonstrated that the selected bacteria have high tolerance to Pb,resisting inhibition up to 2,000 ppm.In contrast,strains exposed to cadmium tended to slow their growth as the concentration increased.
基金Supported by National Natural Science Foundation of China(Grant No.21067003,5136-4015)Natural Science Foundation of Jiangxi Province(Grant No.20114BAB203024)National High-Tech Research and Development Program of China(Grant No.2012BAC11B07)~~
文摘This study aimed to remediate in-situ leach mining contaminated soil by amendment-plant synergism. The results showed that plant species exhibited ex-tremely significant effects on the concentration of nitrate nitrogen; to be specific, the concentration of nitrate nitrogen in soil planted with wheat was reduced from 692.19 mg/kg to lower than 100 mg/kg; when the mass ratio of amendment to soil reached 3：50 and the amendment particle size was 1-2 mm, the concentration of nitrate ni-trogen in soil planted with wheat was reduced to 43 mg/kg. The amendment type exhibited extremely significant effects on the concentration of ammonium nitrogen; to be specific, when the mass ratio of amendment to soil reached 10：50, the concen-tration of ammonium nitrogen in soil added with 2-3 mm zeolite was reduced from 23 593.75 to 3 300 mg/kg on day 15. Amendments and plants mainly exhibited desorption performance for sulfate radical in soil, and the amendment type extreme-ly significantly affected the concentration of sulfate radical; to be specific, the con-centration of sulfate radical in soil added with limestone increased from 370 mg/kg to 900 mg/kg on day 7.
基金China Scholarship Council(No.97842039)National Natural Science Foundation of China(No.20107005)
文摘A microscopic diffusion-reaction modei was developed to simulate in-situ ozonation for the remediation of contaminated soil, i.e., to predict the temporal and spatial distribution of target contaminant in the subsurface. The sequential strategy was employed to obtain the numerical solution of the modei using finite difference method. A non-uniform grid of discretization points was emploved to increase the accuracy of the numerical solution by means of coordinate transformation. One-dimensional column tests were conducted to verify the modei. The column was packed with simulated soils that were spiked with 2-chlorophenol. Ozone gas passed through the column at a flow rate of 100ml·min-1. The residual 2-chlorophenol content at different depths of the column was determined at fixed time intervals. Compared the experimental data with the simulated values, it was found that the mathematical modei fitted data well during most time of the experiment.
基金financed by the international cooperation project of Ministry of Science and Technology (2005DFA90200)the mine environment management project of Henan Provincial Department of Land and Resources+1 种基金the basic scientific research project fund of Chinese Academy of Geological Sciences (YYWF201519)China Geology Survey Work Program (121201106000150006)
文摘Experimental study of enhanced in-situ micro-ecological remediation of petroleum contaminated loess soil was carried out in Zhongyuan oil production areas, and the enhanced in-situ micro-ecological remediation technique includes optimistic in-situ microbial communities, physical chemistry methods, alfalfa planting and regulation of soil environmental elements. Experiments showed that the oil content in the contaminated soil with oil content about 2 898.25 mg/kg can be reduced about 98.61% after in-situ micro-ecological remediation for 99 days, which demonstrated the effectiveness of in-situ micro-ecological remediation methods for petroleum contaminated soil in central plains of China, and explored the practical and feasible application of these methods.
基金The National Natural Science Foundation of China(No.41967043,52160003)the Natural Science Foundation of Gansu Province(No.20JR5RA461)+1 种基金the Key Project of China Railway Southwest Research Institute Co.,Ltd.(No.2018-KJ003-Z003-XB)the Industrial Support Program of the Higher Education of Gansu Province(No.2020C-40).
文摘A computational fluid dynamics(CFD)numerical simulation and field experiment were used to investigate optimal operating parameters of high-pressure jet grouting equipment and clarify the boundary law of the injection area in the remediation process.The response surface optimization design results show that the optimal injection pressure is 30 MPa,rotation speed is 23 r/min,commission speed is 30 cm/min,and the optimal injection diameter is 147.3 cm.Based on the CFD numerical simulation,the ratio of the injection core,turbulent zone,and seepage zone is approximately 1∶4∶2.The distribution law of jet core,turbulence zone and seepage zone at different cross-sections under 30 MPa operating conditions is as follows:The jet core radius is approximately 100 mm,the turbulence zone is mainly distributed at 100 to 500 mm,the seepage zone is mainly distributed at 500 to 700 mm,the seepage zone could be completed within 2 h,and the proportion of the three boundary zones in the injection zone is similar to that of the numerical simulation.This study provides theoretical parameters and practical reference for the remediation of deep pollution via in-situ chemical oxidation in the Loess Plateau soil environment.
基金Project(21003054)supported by the National Natural Science Foundation of ChinaProject(2013CXZDA013)supported by the Scientific Research Foundation of the Education Department of Guangdong Province,China
文摘To improve the conventional electrokinetic remediation of Pb-contaminated soil,the Pb-contaminated soil near a lead acid battery factory in the Pearl River Delta region of China was electrokinetically remedied with polarity exchange technique.The variations in Pb removal efficiency and the soil p H value with the treatment time and the exchange polarity interval were determined.It is found that the removal efficiency of Pb reaches a maximum of 87.7% when the voltage gradient is 1 V/cm and the exchange polarity interval is 48 h.This value is far higher than that obtained with conventional electrokinetic remediation（61.8%）.Additionally,the ＂focusing effect＂ which appears in the conventional electrokinetic remediation can be avoided,and thus additional chemicals are not needed for the polarity exchange technique.The mechanism of Pb electromigration behavior in soil during the treatment with the polarity exchange technique was described.
基金Supported by the National Natural Science Foundation of China(50874046)the National High-tech Research and Develop Program of China(863 Program)(2010AA065203)the Science and Technology Project of Education Bureau of Hunan Province,China(08A032)~~
文摘[Objective] To study the remediation efficiency of red mud on Pb, Zn and Cd in the heavy metal contaminated paddy soil of mine area, to clarify its remediation mechanism and fertilizer efficiency on heavy metal contaminated soil. [Method] The soil incubation experiment was conducted to study the effect of red mud on the pH values and electrical conductivity （EC）, and the remediation efficiency of red mud on lead （Pb）, zinc （Zn） and cadmium （Cd） in heavy metal contaminated soil. [Result] Red mud addition reduced the content of exchangeable Pb, Zn and Cd in the soil significantly. Compared with the control, when incubated for 30, 60 and 90 d with the red mud dosage of 4% （W/W）, the exchangeable Pb content was decreased by 39.25%, 41.38% and 50.19%; exchangeable Zn content was decreased by 49.26%, 57.32% and 47.16%; and exchangeable Cd content was decreased by 19.53%, 24.06% and 25.70%, respectively. The application of red mud had significant impact on the share of Pb, Zn and Cd contents in five forms, and different amounts of red mud application all reduced the proportion of exchangeable Pb, Zn and Cd to the total Pb, Zn and Cd. In addition, the proportion of exchangeable Pb, Zn and Cd to total Pb, Zn and Cd decreased with the increasing amount of red mud addition. [Conclusion] The study provided references for reasonable application of red mud and reduction of heavy metal pollution in paddy soil.
基金Supported by Preliminary Special Foundation of Major State Basic Research Program(973)(2001CCB00800)Scientific and Technological Projects of Henan Province(072102170004)Key Public Welfare Research Project in Henan Province(081100911500)~~
文摘[Objective] The research aimed to study the effects of fertilization on soil remediation.[Method]Pot fertilizer tests were conducted to remedy the soils which had off-balanced in nutrients resulted by long-term unreasonable fertilization.[Result]The results showed that applying NPK fertilizers with manure was the best method to restore the soil nutrients and increase soil fertility and crop yield;NPK and NP fertilizers could balance soil fertility and increase crop yields,the effects were the same and next to MNPK.Phosphate and nitrogen respectively had the similar restoring effect with NPK fertilizers on soil from long-term NK and PK treatments.[Conclusion]Crops in soil with long-term applying NPK fertilizers had strong dependence on fertilizers.The yields of corn and wheat decreased by 78.6% and 52.8% respectively after stopping applying fertilizers.Meanwhile,The yields of corn and wheat increased by 112% and 182% respectively after stopping applying fertilizers in NK treatment as well as 15.1% and 59% in PK treatment.Manure had strong and last effect on increasing yield.
基金Supported by The Agricultural Sciences and Technology Innovation Program(ASTIPIBFC06)China Agriculture Research System of Bast Fiber Crops(CARS-19-E14)~~
文摘Flax is an ideal crop for remedying soil contaminated by heavy metals. It has high tolerance to heavy metals and strong adsorption to heavy metals. Through properly using or adjusting external conditions such as regulator, moisture, fertilizer, microorganisms, and pH value, it is able to improve ability of flax to absorb, trans- fer, and accumulate heavy metals. To improve the ability of flax in remediating heavy metal contaminated soil, it is recommended to strengthen cultivation of flax varieties and screening of germplasm resources, actively carry out studies on tech- nologies of fax remedying heavy metal contaminated soil, implement large-scale and mechanized planting of flax, and promote control of heavy metal contaminated soil.
基金the National Natural Science Foundation of China (No.20507009)the Program for New Century Excellent Talents in University (NCET) of the Ministry of Education of China,the Natural Science Foundation of Jiangsu Province for Outstanding Young Scientist (No.BK2006518)and the International Foundation for Science (No.C/3958-1).
文摘Phytoremediation is becoming a cost-effective technology for the in-situ clean up of sites polluted with hydrophobic organic contaminants （HOCs）. The major factors limiting phytoremediation are the mass transfer, rate of plant uptake, and microbial biodegradation of HOCs. This article discusses the potential of surfactants to enhance desorption, plant uptake, and biodegradation of HOCs in the contaminated sites. Positive effects of surfactants on phytoremediation have been recently observed in greenhouse studies. The presence of some nonionic surfactants including polyoxyethylene sorbltan monooleate （Tween 80） and polyoxyethylene（23）dodecanol （Brij35） at relatively low concentrations resulted in significant positive effects on phytoremediation for pyrene-contaminated soil. However, the anionic surfactant （sodium dodecyl sulfate, SDS） and the cationic surfactant （cetyltrimethylammonium bromide, CTMAB） were not useful because of their phytotoxicity or low efficiency for surfactant-enhanced phytoremediation （SEPR）. The mechanisms of SEPR for HOC-contaminated sites were evaluated by considering experimental observations. In view of concerns about the cost effectiveness and toxicity of surfactants to plants, more research is needed to enhance the use of SEPR technology.
基金Project financially supported by the Australian Centre for International Agricultural Research(ACIAR) and the Sugar Research and Development Corporation(SRDC),Australia.
文摘Soil and land degradation in the tropics can be identified and described interms of physical, chemical, and biological changes from its pristine state brought about by naturaland anthropogenic influences. A characteristic of these ecosystems is their capacity to recyclenutrients through soil organic matter (SOM). Following disturbance through changed land management,SOM is rapidly mineralized and there is a corresponding decline in fertility and the variable chargecomponent of the cation exchange capacity. As these ecosystems are strongly dependent on SOM fortheir functionality, changed land use can have irreversible impacts on the productivity of thesesystems. The paper focuses on quantifying chemical degradation through 'benchmarking' using datafrom paired sites in tropical China and Thailand using surface charge fingerprinting. Using valuestaken from the fingerprint of an undisturbed soil, an index of chemical degradation from 'ideality'was calculated. Various management strategies that attempt to reverse degradative trends or improvepoor quality soils in their natural condition are discussed, such as the addition of natural claysand silicated materials. Results are present to show the effect of each of the aforementionedstrategies on surface charge characteristics and associated increases in plant productivity.
文摘The technology of in situ immobilization with amendments is an important measure that remediates the soil contaminated by heavy metals, and selecting economical and effective amendments is the key. The effects and mechanism of steel slag, the silicon-rich alkaline byproduct which can remediate acidic soil contaminated by heavy metal, are mainly introduced in this paper to provide theory reference for future research. Firstly, the paper analyzes current research situation of in situ immobilization with amendments. Then, it introduces the main physicochemical properties of steel slag, and the effect on soil pH value as well as heavy metal activity. Besides, the paper elaborates the promoting effect on silicon-requiring plant and the strengthening mechanism for its resistant capability of heavy metal. According to the analysis, the application of steel slag could be a potential valuable strategy to remediate acidic soil contaminated by heavy metal by modifying the transformation of heavy metals in both soil and plant, so that the translocation of heavy metal in food chain is reduced.
基金Supported by the National Natural Science Foundation(41271328)
文摘Soil, an important material basis for human activities, is an indispensable natural rasource that is difficult to regenerate. It is also an important part of human ecological environment. Currently, soil pollution has affected China＇s agricultural production and threatened human health and ecological safety, so it has been paid more attention to by the people and has become a hot spot in environmental field. Through continuous research, a variety of soil remediation patents and technologies also emerge. Here, by retrieving the main words through the website （www. soopat. corn） and Chinese patent net, types of soil pollution and remediation technologies under the authorization status of the patents were analyzed, and the major species of soil pollutants and soil remediation technologies were reviewed.
基金the National Natural Science Foundation of China(21876090)the Tianjin Research Program of Application Foundation and Advanced Technology(18JCZDJC39400 and 19YFZCSF00920)+1 种基金National Key R&D Program of China(2019YFC1804104)the Postdoctoral Science Foundation of China(2019M660985).
文摘Soil pollution endangers human health and ecological balance,which is why finding a highly efficient way to deal with pollutants is necessary.Biological method is an environmentally friendly treatment method.Bioelectrochemical systems(BESs),which combine electrochemistry with biological methods,have been widely used to remediate polluted environments,including wastewater,sludge,sediment,and soil.In BESs,redox reactions occur on electrodes with electroactive bacteria,which convert pollutants into low-polluting or nonpolluting substances.With BESs being a promising technology in the remediation field,the decontamination mechanisms and applications in soil conducted by BESs have attracted much attention.Therefore,to better understand the research progress of BESs,this paper mainly summarizes the mechanism of different classified BESs.The applications of microbial fuel cells(MFCs)in four pollutants(petroleum,heavy metals,pesticides,antibiotics)and the possible applications of microbial electrolysis cells(MECs)in soil are discussed.The main problems in BESs and possible future development directions are also evaluated.
基金supported by the National Key Technologies R&D Program in the 11th Five-year Plan (2004BA901A15)the Key Program of National Natural Science Foundation of China (Grant No. 90702001)
文摘This paper presents the development of a new remediation technology for contaminated sandy soil using humic acid (HA). Distribution of amount of Cr (VI) in the aqueous or solid system containing humic acid and sandy soil, was studied using batch experiments, es-pecially for effects of reaction time, pH, concentrations, temperature and irradiation on the reduction of Cr (VI), and the optimum reaction conditions. The results indicated a significant increase of the adsorption of Cr (VI) because of the complexion reaction between HA and Cr (VI) that occurred under acidic condition. The reaction mechanisms of HA with chromium on sand surfaces were certified. Thus it came to a conclusion that HA could be used effectively on remediation of Cr (VI)–contaminated soil and groundwater in a wide range of pH, with or without sunlight. These results suggest that the organic-inorganic complex—such as sandy soils coated with humic substances—is important as a metal reservoir in the environment.
基金supported by the National Natural Science Foundation of China (No. 41371092)the Scientific Research Foundation for Returned Overseas Students+1 种基金the Education Department of Henan Province Science and Technology Research projects (No.14B170007)the doctoral foundation of Henan Polytechnic University (No. 648349)
文摘It is generally known that soil pollution poses a terrible hazard to the environment, but the present techniques of contaminated soil remediation cannot control this growing threat. This paper compares the pollutant extraction efficiency of traditional pumping and treating, which is a typical washing technology for the remediation of contaminated soils, with methods that utilize freeze-thaw cycles. In the soil freezing process, water shifts from unfrozen soils to the freezing front, and the permeability of soil will be enhanced under certain temperature gradients and water conditions. Therefore, this paper discusses the purification of contaminated soil through freeze-thaw action. We conducted a cleansing experiment on clay and silica sand infused with NaCl（simulation of heavy metals） and found that the efficiency of purification was enhanced remarkably in the latter by the freeze-thaw action. To assess the effective extraction of DNAPLs in soil, we conducted an experiment on suction by freezing, predicated on the different freezing points of moisture and pollutants. We found that the permeability coefficient was significantly increased by the freezing-thawing action, enabling the DNAPL contaminants to be extracted selectively and effectively.
基金supported by the Specialized Research Fund for the Basic Scientific Research of Higher Education of China (27R1204018A)
文摘This paper discussed the optimization of conditions for remediation of crude oil-polluted soil based on pot experiment by applying reed-specific degrading bacteria, and using response surfaces methodology. We took the initial crude oil concentration, the amount of inoculation, the ratio of nitrogen and phosphorus, and the use of surfactant （Tween-80） as independent variables （factors）, and the degrading ratio of crude oil as the dependent variable （response） after a 90-day experiment. The experiment explored the impacts of each independent variable and their interactions on the bioremediation of crude oil-polluted soil using the Box-Behnken design. Working with a simulated forecasting model the study obtained optimization va reed＋specific degrading bacteria, a nitrogen to phosphorus ues for the treatment parameters of 200 g/kg of the ratio of about 6.0. and 0.2% surfactant. Under experimental conditions, for crude oil concentrations of 10, 30 and 50 g/kg, the optimal effects of the treatments achieved 71.87%, 66.61% and 54.52% degradation of the crude oil, respectively. The results can provide a basis for the technical development of plant-microorganism combined bioremediation of crude oil-polluted soil.
基金Project(K1201010-61)supported by the Science and Technology Program of Changsha,ChinaProject(51074191)supported by the National Natural Science Foundation of ChinaProject(2012BAC09B04)supported by National Key Technology Research and Development Program,China
文摘Soil contaminated with typical heavy metals (Pb,Cd,Cu,and Zn) was remedied by using the polymeric aluminum salt coagulants including polyaluminum chloride (PAC) and polyaluminum sulfate (PAS).The remediation efficiencies are influenced by reaction time,water amount,and dosage of remediation agent.The optimal remediation conditions are as follows:6 h of reaction time,1 kg/kg of water addition amount,and 0.25 kg/kg of remediation agent dosage.After PAC addition,the remediation efficiencies of diethylenetriamine-pentaacetic acid (DTPA)-extractable Pb,Cd,Cu,and Zn reach 88.3%,85.1%,85.4%,and 73.7%,respectively;and those for PAS are 89.7%,88.7%,83.5%,and 72.6%,respectively.The main remediation mechanism of the polymeric aluminum salt may contribute to the ionization and hydrolysis of PAC and PAS.H + released from ionization of polymeric aluminum salt can cause the leaching of heavy metals,while the multinuclear complex produced from hydrolysis may result in the immobilization of heavy metals.For PAC,the immobilization of heavy metals is the main remediation process.For PAS,both leaching and immobilization are involved in the remediation process of heavy metals.
基金Projects(2020YFC1808002,2019YFD1100502)supported by the National Key R&D Program of China。
文摘Phosphate is widely used to immobilize cadmium(Cd)and lead(Pb)in soils through the insoluble metal phosphate precipitation.However,an increase in the phosphorus content of the environment can cause new pollution.In this study,five slow-release phosphate amendments(SRPAs)were synthesized and their characteristics including BET,SEM,FTIR,swelling ratio,and thephosphorus release were determined.The results show that SRPA was a sphere with a network structure with a specific surface area of 5 to 7.18 m^(2)/g andcontained phosphate,hydroxyl,carboxyl and other functional groups.Among five SRPAs,S3 sample showed good performance for phosphate release.Phosphate release from SRPA was well fitted with Ritger-Peppas model with constant n between 0.45 and 0.85,indicating that the phosphate release was in accordance with non-Fickian diffusion.As compared with monocalcium phosphate(MCP),SRPA application led to a lower concentration of water-soluble phosphorus in the soil sample and higher remediation efficiencies of Cd and Pb.The remediation efficiencies of water-soluble Cd and Pb in soil with SRPA were 97.1%and 97.9%,respectively.The remediation efficiencies of bioavailable Cd and Pb were 71.85%and 76.47%,respectively.The results of Tessier extraction showed that the exchangeable and carbonatebound fractions of Cd and Pb in the soil sample after SRPA application significantly reduced,while the residual fraction increased,indicating the stability of heavy metals increased.
