It is of vital significance to investigate mass transfer enhancements for chemical engineering processes.This work focuses on investigating the coupling influence of embedding wire mesh and adding solid particles on b...It is of vital significance to investigate mass transfer enhancements for chemical engineering processes.This work focuses on investigating the coupling influence of embedding wire mesh and adding solid particles on bubble motion and gas-liquid mass transfer process in a bubble column.Particle image velocimetry(PIV)technology was employed to analyze the flow field and bubble motion behavior,and dynamic oxygen absorption technology was used to measure the gas-liquid volumetric mass transfer coefficient(kLa).The effect of embedding wire mesh,adding solid particles,and wire mesh coupling solid particles on the flow characteristic and kLa were analyzed and compared.The results show that the gas-liquid interface area increases by 33%-72%when using the wire mesh coupling solid particles strategy compared to the gas-liquid two-phase flow,which is superior to the other two strengthening methods.Compared with the system without reinforcement,kLa in the bubble column increased by 0.5-1.8 times with wire mesh coupling solid particles method,which is higher than the sum of kLa increases with inserting wire mesh and adding particles,and the coupling reinforcement mechanism for affecting gas-liquid mass transfer process was discussed to provide a new idea for enhancing gas-liquid mass transfer.展开更多
A novel method for the preparation of oligothiophene molecular wires is described via a bi-directional solid-phase synthesis. Using an alternating sequence of bromination and Stille coupling reactions, oligomers were ...A novel method for the preparation of oligothiophene molecular wires is described via a bi-directional solid-phase synthesis. Using an alternating sequence of bromination and Stille coupling reactions, oligomers were obtained up to the heptamer in excellent yield and purity.展开更多
为严格控制铝合金焊丝内在氢含量,分析了铝合金焊丝冶炼过程中充氩工艺参数对合金熔体及固体氢含量的影响,并比较了熔体测氢与固体测氢方法的异同。结果表明,2~4吨铝熔体冶炼过程中,减小精炼氩气的流量可以显著减少合金熔体减压凝固测...为严格控制铝合金焊丝内在氢含量,分析了铝合金焊丝冶炼过程中充氩工艺参数对合金熔体及固体氢含量的影响,并比较了熔体测氢与固体测氢方法的异同。结果表明,2~4吨铝熔体冶炼过程中,减小精炼氩气的流量可以显著减少合金熔体减压凝固测氢试样纵切面上的气孔数量和尺寸,降低熔体的氢含量,当充氩流量为8~10 mL/min时,熔体除氢效果达到最佳;固体测氢方法可以准确提取固体焊丝中的真实氢含量(单位:ppm),经过计算1 mL/100 g Al等价于0.899 ppm,当氩气流量控制在8~10 mL/min时固体焊丝合金中的氢含量为0.17~0.18 mL/100 g Al,可满足低氢焊丝生产要求;同等充氩工艺条件下,固体测氢值高于熔体测氢值,二者比值保持在1.7~2.1之间,固体测氢与熔体测氢各有优劣,二者可以互为补充、配合使用。展开更多
Base on the previous work in laboratory, a novel polyaniline doped with polydimethylsiloxane coating was developed on a stainless steel wire for solid phase microextraction（SPME） by electroplating method. This elect...Base on the previous work in laboratory, a novel polyaniline doped with polydimethylsiloxane coating was developed on a stainless steel wire for solid phase microextraction（SPME） by electroplating method. This electroplating method not only has advantages of ease preparation and simple equipments required, but also increases the lifetime of the SPME fiber. The composite fiber（polyaniline/ polydimethylsiloxane（PANI/PDMS）） was evaluated by analyzing n-tridecane, n-tetradecane and n-pentadecane in aqueous sample. The new fiber coating showed comprehensive abilities to extract alkanes compounds. The relative standard deviations were found to be 6.8%-10.33%.展开更多
基金supported by the Key Research and Development Plan of Shandong Province(the Major Scientific and Technological Innovation Projects,2021ZDSYS13)the Natural Science Foundation of Shandong Province(ZR2021MB135)Natural Science Foundation of Shandong Province(ZR2021ME224).
文摘It is of vital significance to investigate mass transfer enhancements for chemical engineering processes.This work focuses on investigating the coupling influence of embedding wire mesh and adding solid particles on bubble motion and gas-liquid mass transfer process in a bubble column.Particle image velocimetry(PIV)technology was employed to analyze the flow field and bubble motion behavior,and dynamic oxygen absorption technology was used to measure the gas-liquid volumetric mass transfer coefficient(kLa).The effect of embedding wire mesh,adding solid particles,and wire mesh coupling solid particles on the flow characteristic and kLa were analyzed and compared.The results show that the gas-liquid interface area increases by 33%-72%when using the wire mesh coupling solid particles strategy compared to the gas-liquid two-phase flow,which is superior to the other two strengthening methods.Compared with the system without reinforcement,kLa in the bubble column increased by 0.5-1.8 times with wire mesh coupling solid particles method,which is higher than the sum of kLa increases with inserting wire mesh and adding particles,and the coupling reinforcement mechanism for affecting gas-liquid mass transfer process was discussed to provide a new idea for enhancing gas-liquid mass transfer.
文摘A novel method for the preparation of oligothiophene molecular wires is described via a bi-directional solid-phase synthesis. Using an alternating sequence of bromination and Stille coupling reactions, oligomers were obtained up to the heptamer in excellent yield and purity.
文摘为严格控制铝合金焊丝内在氢含量,分析了铝合金焊丝冶炼过程中充氩工艺参数对合金熔体及固体氢含量的影响,并比较了熔体测氢与固体测氢方法的异同。结果表明,2~4吨铝熔体冶炼过程中,减小精炼氩气的流量可以显著减少合金熔体减压凝固测氢试样纵切面上的气孔数量和尺寸,降低熔体的氢含量,当充氩流量为8~10 mL/min时,熔体除氢效果达到最佳;固体测氢方法可以准确提取固体焊丝中的真实氢含量(单位:ppm),经过计算1 mL/100 g Al等价于0.899 ppm,当氩气流量控制在8~10 mL/min时固体焊丝合金中的氢含量为0.17~0.18 mL/100 g Al,可满足低氢焊丝生产要求;同等充氩工艺条件下,固体测氢值高于熔体测氢值,二者比值保持在1.7~2.1之间,固体测氢与熔体测氢各有优劣,二者可以互为补充、配合使用。
文摘Base on the previous work in laboratory, a novel polyaniline doped with polydimethylsiloxane coating was developed on a stainless steel wire for solid phase microextraction（SPME） by electroplating method. This electroplating method not only has advantages of ease preparation and simple equipments required, but also increases the lifetime of the SPME fiber. The composite fiber（polyaniline/ polydimethylsiloxane（PANI/PDMS）） was evaluated by analyzing n-tridecane, n-tetradecane and n-pentadecane in aqueous sample. The new fiber coating showed comprehensive abilities to extract alkanes compounds. The relative standard deviations were found to be 6.8%-10.33%.
