By the directional solidification of metal-gas eutectic method(GASAR),porous Cu-Mn alloy with oriented pores was fabricated successfully.The variation of pore structure was studied by experiments.The results show th...By the directional solidification of metal-gas eutectic method(GASAR),porous Cu-Mn alloy with oriented pores was fabricated successfully.The variation of pore structure was studied by experiments.The results show that the pore structure is primarily dependent on the solidification mode(planar,columnar cellular,columnar dendritic,equiaxed dendritic),which is controlled by the solidification process.By numerical simulation,it is noted that along with solidification,the solidification mode of the alloy transforms from cellular to columnar dendritic and finally to equiaxed dendritic.Through increasing melt temperature and mold preheating,the range of equiaxed dendrite could be decreased,which helps to extend the region of oriented pore structure.展开更多
The thermodynamic database of the Fe C Mn-Si system has been developed in the framework of the CALPHAD approach. The sub-ternary systems have been carefully evaluated and revised based on available experimental data. ...The thermodynamic database of the Fe C Mn-Si system has been developed in the framework of the CALPHAD approach. The sub-ternary systems have been carefully evaluated and revised based on available experimental data. A satisfactory description of the liquid phase in the Fe C-Si system has been obtained. The C Mn Si system was assessed treating the liquid phase as a substitutional solution. Phase equilibria in the C- Mn-Si system, especially those involving the liquid phase, can be well described. Based on the extrapolation of the experimental data in the quaternary system, the Fe Mn Si system has been modified to agree well with experimental data at high temperatures. The comparison between the calculated and measured phase transformation tempera tures confirms the reliability of the present quaternary database. Additionally, the solidification process of Fe-0. 16C-1. 5Mn-1. 5Si (wt. %) alloy was simulated by using the thermodynamic database developed.展开更多
基金Project(U0837603)supported by the NSFC-Yunnan Joint Foundation of ChinaProject(2092017)supported by the Natural Science Foundation of Beijing,China
文摘By the directional solidification of metal-gas eutectic method(GASAR),porous Cu-Mn alloy with oriented pores was fabricated successfully.The variation of pore structure was studied by experiments.The results show that the pore structure is primarily dependent on the solidification mode(planar,columnar cellular,columnar dendritic,equiaxed dendritic),which is controlled by the solidification process.By numerical simulation,it is noted that along with solidification,the solidification mode of the alloy transforms from cellular to columnar dendritic and finally to equiaxed dendritic.Through increasing melt temperature and mold preheating,the range of equiaxed dendrite could be decreased,which helps to extend the region of oriented pore structure.
基金the financial support from the Chinese National Key Project of Science and Technology (Grant No. 2012ZX06004-012)the support from the Chinese Scholarship Council (CSC)the support from the Shanghai Municipal Science and Technology Commission (Grant No. 15DZ2260300,15DZ2260301)
文摘The thermodynamic database of the Fe C Mn-Si system has been developed in the framework of the CALPHAD approach. The sub-ternary systems have been carefully evaluated and revised based on available experimental data. A satisfactory description of the liquid phase in the Fe C-Si system has been obtained. The C Mn Si system was assessed treating the liquid phase as a substitutional solution. Phase equilibria in the C- Mn-Si system, especially those involving the liquid phase, can be well described. Based on the extrapolation of the experimental data in the quaternary system, the Fe Mn Si system has been modified to agree well with experimental data at high temperatures. The comparison between the calculated and measured phase transformation tempera tures confirms the reliability of the present quaternary database. Additionally, the solidification process of Fe-0. 16C-1. 5Mn-1. 5Si (wt. %) alloy was simulated by using the thermodynamic database developed.