The number of hazardous waste in our country increased dramatically in recent years,stabilization/solidification technology begins to attract a wide spread attention by domestic scholars.Based on the domestic related ...The number of hazardous waste in our country increased dramatically in recent years,stabilization/solidification technology begins to attract a wide spread attention by domestic scholars.Based on the domestic related literature,this paper discussed the present situation about the treatment of the solid waste using stabilization/solidification technology;meanwhile we have a variety of outlooks on the future of the stabilization/solidification technology.展开更多
The number of hazardous waste in our country increased dramatically in recent years,stabilization/solidification technology begins to attract a wide spread attention by domestic scholars.Based on the domestic related ...The number of hazardous waste in our country increased dramatically in recent years,stabilization/solidification technology begins to attract a wide spread attention by domestic scholars.Based on the domestic related literature,this paper discussed the present situation about the treatment of the solid waste using stabilization/solidification technology;meanwhile we have a variety of outlooks on the future of the stabilization/solidification technology.展开更多
One of the challenges faced by sewage sludge treatment and disposal is its higher water content,and how to efficient dewater those hazardous materials properly is welcome in practice. This study stabilized the sewage ...One of the challenges faced by sewage sludge treatment and disposal is its higher water content,and how to efficient dewater those hazardous materials properly is welcome in practice. This study stabilized the sewage sludge via the using of conventional curing agents and calcined aluminum salts,and the corresponding dewatering mechanisms and structural changes of the stabilized sludge were further comparable analyzed.Experimental results showed that wollastonite and kaolin exhibit a relative higher dewatering efficiency as compared to other conventional curing agents; however the releasing rate of heavy metals of Cu,Cr,Ni for kaolin solidification and Zn,Pb for wollastonite solidification is higher than the sludge samples solidified by other curing agents. For comparison,the sludge samples solidified by calcined aluminum salts (AS),calcium ash,Mg-based curing agent,tricalcium aluminate( C_3A) show a lower heavy metals leaching potential and unconfined compressive strength. In addition,the economic characteristics and local availability of AS,calcium ash,C_3A and CaO makes it have a broad prospect in extension and application. These findings are of great significance for stabilization and dewatering of sewage sludge.展开更多
This work experimentally examined the optimal proportioning of sludge curing agent for dewatered sludge curing on solidified sludge,two components sludge curing agent consisted of cement and slag,and three components ...This work experimentally examined the optimal proportioning of sludge curing agent for dewatered sludge curing on solidified sludge,two components sludge curing agent consisted of cement and slag,and three components consisted of cement,slag and inorganic salt. The results showed that,increasing of curing ages could increase unconfined compressive strength and reduce moisture content for solidified sludge. For the test of two components,the biggest unconfined compressive strength of the solidified sludge achieved to 543. 72 kPa and the minimum moisture content achieved to 3. 56% of 21 d. The optimum proportion of the sludge curing agent of two components is sludge: cement: slag = 1 ∶ 0. 05 ∶ 0. 2 which selected by Design-expert. It could rapidly increasing the unconfined compressive strength of solidified sludge when added three components sludge curing agent( sludge: cement: slag: MgSO4= 1 ∶ 0. 05 ∶ 0. 2 ∶ 0. 03) on sludge curing. The results showed that,curing ages of 7 d,the unconfined compressive strength could achieve to 126. 74 kPa,which was more than 11 times comparison with the solidified sludge curing by two components curing agent. Two or three components sludge curing agent all could stabilize the heavy metals on solidified sludge and the leaching of heavy metals was below the government standard,while the stability of the heavy metals was superior for three components sludge curing agent.展开更多
The possibilities of MSWI fly ash as a major constituent of novel solidification/stabilization matrices for secure landfill were investigated by mixing MSWI fly ash with rich aluminum components,which was added as bau...The possibilities of MSWI fly ash as a major constituent of novel solidification/stabilization matrices for secure landfill were investigated by mixing MSWI fly ash with rich aluminum components,which was added as bauxite cement or metakaolinite instead,to form Friedel and Ettringite phases with high fixing capacities for heavy metals.The physical properties,heavy metals-fixing capacity,mineral phases and its vibration bands in the novel matrices were characterized by compressive strength,TCLP(toxic characteristic leaching procedure),XRD (x-ray diffraction),DTG (derivative thermogravimetry),and FTIR (fourier transform infrared spectroscopy),respectively.The Tessier's five-step sequential extraction procedure was used to analyze the fractions of chemical speciation for Pb,Cd and Zn ions.The experimental results indicate that Friedel-Ettringite based novel solidification/stabilization matrices can incorporate Pb,Cd and Zn ions effectively by physical en-capsulation and chemical fixation,and it exhibits a great potential in co-landfill treatment of MSWI fly ash with some heavy metals-bearing hazardous wastes.展开更多
Based on theoretical analyses, the effect of electric current density on stability of solidification interface morphology of QAl 4 alloy was studied experimentally. The results show that the experimental results agree...Based on theoretical analyses, the effect of electric current density on stability of solidification interface morphology of QAl 4 alloy was studied experimentally. The results show that the experimental results agree well with the theoretical analyses, and the following conclusions can be drawn: the increase of electric current density improves the stability of the solidification interface morphology under the condition of no convection of the liquid metal. Otherwise this convection will slow down the trend of solidification interface developing to stability caused by increasing electric current density.展开更多
Phase field investigation reveals that the stability of the planar interface is related to the anisotropic intensity of surface tension and the misorientation of preferred crystallographic orientation with respect to ...Phase field investigation reveals that the stability of the planar interface is related to the anisotropic intensity of surface tension and the misorientation of preferred crystallographic orientation with respect to the heat flow direction. The large anisotropic intensity may compete to determine the stability of the planar interface. The destabilizing effect or the stabilizing effect depends on the misorientation. Moreover, the interface morphology of initial instability is also affected by the surface tension anisotropy.展开更多
In recent years, the invert anomalies of operating railway tunnels in water-rich areas occur frequently,which greatly affect the transportation capacity of the railway lines. Tunnel drainage system is a crucial factor...In recent years, the invert anomalies of operating railway tunnels in water-rich areas occur frequently,which greatly affect the transportation capacity of the railway lines. Tunnel drainage system is a crucial factor to ensure the invert stability by regulating the external water pressure(EWP). By means of a threedimensional(3D) printing model, this paper experimentally investigates the deformation behavior of the invert for the tunnels with the traditional drainage system(TDS) widely used in China and its optimized drainage system(ODS) with bottom drainage function. Six test groups with a total of 110 test conditions were designed to consider the design factors and environmental factors in engineering practice,including layout of the drainage system, blockage of the drainage system and groundwater level fluctuation. It was found that there are significant differences in the water discharge, EWP and invert stability for the tunnels with the two drainage systems. Even with a dense arrangement of the external blind tubes, TDS was still difficult to eliminate the excessive EWP below the invert, which is the main cause for the invert instability. Blockage of drainage system further increased the invert uplift and aggravated the track irregularity, especially when the blockage degree is more than 50%. However, ODS can prevent these invert anomalies by reasonably controlling the EWP at tunnel bottom. Even when the groundwater level reached 60 m and the blind tubes were fully blocked, the invert stability can still be maintained and the railway track experienced a settlement of only 1.8 mm. Meanwhile, the on-site monitoring under several rainstorms further showed that the average EWP of the invert was controlled within 84 k Pa, while the maximum settlement of the track slab was only 0.92 mm, which also was in good agreement with the results of model test.展开更多
Because of urbanization,land resources in China’s cities has become increasingly scarce.Therefore,modern buildings are becoming taller,making high-rise steel frame structures the new favorite of the construction indu...Because of urbanization,land resources in China’s cities has become increasingly scarce.Therefore,modern buildings are becoming taller,making high-rise steel frame structures the new favorite of the construction industry.However,the construction of high-rise steel frame structures requires advanced technology.If the construction technology is effectively implemented and the welding techniques of the construction personnel align with the requirements for high-rise steel frame structures,it can help mitigate deformations in the steel structure,thus preserving the overall construction quality of high-rise steel frame structures.To enhance the applicability of steel frame structures in high-rise buildings,this paper focuses on analyzing the optimization path for the construction process of high-rise steel frame structures.It introduces a tailored approach to control welding-induced deformations in steel frame structures,aiming to make a valuable contribution to the advancement of China’s construction industry.展开更多
To ameliorate the defects of insufcient support resistance of traditional roadside flling bodies for gob-side entry retaining(GER),overcome the inability to adapt to the deformation of surrounding rock,and isolate the...To ameliorate the defects of insufcient support resistance of traditional roadside flling bodies for gob-side entry retaining(GER),overcome the inability to adapt to the deformation of surrounding rock,and isolate the goaf efectively,a new type of high-water material as a roadside flling body for GER technology with double roadways was proposed.The instability analysis and control technology of GER with double roadways by flling high-water material into a gently inclined coal seam were studied.The basic mechanical properties of the new high-water material were investigated through laboratory experiments,and their main advantages were identifed.The reasonable width of the roadside flling wall of a high-water material was obtained by combining ground pressure observation and theoretical calculations.The distribution characteristics of the stress and plastic zone of surrounding rock of GER after being stabilized by the disturbance of the working face were studied using numerical simulations,and the failure range of GER by flling with high-water material was revealed.Based on this,a coupling control technology of anchor cables and bolts+single props+metal mesh+anchor bolts is proposed.Through the coupling methods of arranging borehole peeping and observing the convergences of surrounding rock,the results demonstrate that GER with double roadways by flling with a 1.8-m-wide high-water material has a good control efect.The above research will play an active role in promoting the application of high-water materials in GER roadside flling.展开更多
Tip splitting instability of cellular interface morphology in directional solidification is analyzed based on the bias field method proposed recently by Glicksman. The physical mechanism of tip instability is explaine...Tip splitting instability of cellular interface morphology in directional solidification is analyzed based on the bias field method proposed recently by Glicksman. The physical mechanism of tip instability is explained by analyzing the interface potential, the tangential energy flux, and the normal energy flux. A rigorous criterion for tip-splitting instability is established analytically, i.e., the ratio of the cellular tip radius to the cellular width α >3/2/π≈ 0.3899, which is in good agreement with simulation results. This study also reveals that the cellular tip splitting instability is attributable to weak Gibbs–Thomson energy acting on the interface.展开更多
Relaxed Stable Stability(RSS) in an important part of the active control technology.It is a new way to raise the flying speed,distance and maneuverability of missile.Depth study of RSS technology plays an important ro...Relaxed Stable Stability(RSS) in an important part of the active control technology.It is a new way to raise the flying speed,distance and maneuverability of missile.Depth study of RSS technology plays an important role for the new concept missile design.This paper describes the detailed definition of RSS and its advantages,presents the research status and prospects for its application in the design of new missiles.展开更多
Maintenance and risk estimation of a weak roadbed condition during the construction period are described.Risk-management procedure for unstable,weak soils is proposed through adjusting the technological loads and real...Maintenance and risk estimation of a weak roadbed condition during the construction period are described.Risk-management procedure for unstable,weak soils is proposed through adjusting the technological loads and real-time monitoring of their influence.The efficiency of implementing maximum allowable vibroloads and the drainage system for strengthening weak soils is shown in the example of the Northern Latitudinal Railway area.展开更多
Toxicity characteristic leaching procedure(TCLP) of zinc plating sludge was carried out to assess the leaching potential of the sludge and the leachates were analyzed for heavy metals. The concentration of zinc, chrom...Toxicity characteristic leaching procedure(TCLP) of zinc plating sludge was carried out to assess the leaching potential of the sludge and the leachates were analyzed for heavy metals. The concentration of zinc, chromium, and lead in the leachate were 371 5 mg/L, 1 95 mg/L and 1 99 mg/L respectively Solidification of zinc sludge was carried out using four different binder systems consisting of cement mortar, fly ash, clay and lime and cured for 28 d. The ratio of sludge added varied from 60% to 80% by volume. The solidified products were tested for metal fixing efficiency and physical strength. It was observed that the volume of sludge added that resulted in maximum metal stabilization was 60% for all the combinations, above which the metal fixation efficiency decreased resulting in high values of zinc in the leachate. Addition of 5% sodium silicate enhanced the chemical fixation of metals in all the binder systems. Among the four fixing agents studied, mixture of fly ash: lime, and cement mortar: lime stabilized zinc and other metals in the sludge effectively than other combinations. Addition of lime increased the stabilization of zinc whereas cement mortar increased the strength of the solidified product.展开更多
文摘The number of hazardous waste in our country increased dramatically in recent years,stabilization/solidification technology begins to attract a wide spread attention by domestic scholars.Based on the domestic related literature,this paper discussed the present situation about the treatment of the solid waste using stabilization/solidification technology;meanwhile we have a variety of outlooks on the future of the stabilization/solidification technology.
文摘The number of hazardous waste in our country increased dramatically in recent years,stabilization/solidification technology begins to attract a wide spread attention by domestic scholars.Based on the domestic related literature,this paper discussed the present situation about the treatment of the solid waste using stabilization/solidification technology;meanwhile we have a variety of outlooks on the future of the stabilization/solidification technology.
基金Sponsored by the National Natural Science Foundation of China(Grant No.51408159)the China Postdoctoral Science Foundation of China(Grant No.2013T60375 and 2012M520744)
文摘One of the challenges faced by sewage sludge treatment and disposal is its higher water content,and how to efficient dewater those hazardous materials properly is welcome in practice. This study stabilized the sewage sludge via the using of conventional curing agents and calcined aluminum salts,and the corresponding dewatering mechanisms and structural changes of the stabilized sludge were further comparable analyzed.Experimental results showed that wollastonite and kaolin exhibit a relative higher dewatering efficiency as compared to other conventional curing agents; however the releasing rate of heavy metals of Cu,Cr,Ni for kaolin solidification and Zn,Pb for wollastonite solidification is higher than the sludge samples solidified by other curing agents. For comparison,the sludge samples solidified by calcined aluminum salts (AS),calcium ash,Mg-based curing agent,tricalcium aluminate( C_3A) show a lower heavy metals leaching potential and unconfined compressive strength. In addition,the economic characteristics and local availability of AS,calcium ash,C_3A and CaO makes it have a broad prospect in extension and application. These findings are of great significance for stabilization and dewatering of sewage sludge.
基金Sponsored by the Technology Research Projects of Harbin Science and Technology Bureau(Grant No.2010AA4CS024)the Fundamental Research Funds for the Central Universities(Grant No.HIT.NSRIF.201192)+1 种基金the National Natural Science Key Foundation of China(Grant No.51206036)the State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology(Grant No.2013DX04)
文摘This work experimentally examined the optimal proportioning of sludge curing agent for dewatered sludge curing on solidified sludge,two components sludge curing agent consisted of cement and slag,and three components consisted of cement,slag and inorganic salt. The results showed that,increasing of curing ages could increase unconfined compressive strength and reduce moisture content for solidified sludge. For the test of two components,the biggest unconfined compressive strength of the solidified sludge achieved to 543. 72 kPa and the minimum moisture content achieved to 3. 56% of 21 d. The optimum proportion of the sludge curing agent of two components is sludge: cement: slag = 1 ∶ 0. 05 ∶ 0. 2 which selected by Design-expert. It could rapidly increasing the unconfined compressive strength of solidified sludge when added three components sludge curing agent( sludge: cement: slag: MgSO4= 1 ∶ 0. 05 ∶ 0. 2 ∶ 0. 03) on sludge curing. The results showed that,curing ages of 7 d,the unconfined compressive strength could achieve to 126. 74 kPa,which was more than 11 times comparison with the solidified sludge curing by two components curing agent. Two or three components sludge curing agent all could stabilize the heavy metals on solidified sludge and the leaching of heavy metals was below the government standard,while the stability of the heavy metals was superior for three components sludge curing agent.
基金Funded by the National Natural Science Foundation of China(No.20477024)2003 Shanghai Education Research Fund
文摘The possibilities of MSWI fly ash as a major constituent of novel solidification/stabilization matrices for secure landfill were investigated by mixing MSWI fly ash with rich aluminum components,which was added as bauxite cement or metakaolinite instead,to form Friedel and Ettringite phases with high fixing capacities for heavy metals.The physical properties,heavy metals-fixing capacity,mineral phases and its vibration bands in the novel matrices were characterized by compressive strength,TCLP(toxic characteristic leaching procedure),XRD (x-ray diffraction),DTG (derivative thermogravimetry),and FTIR (fourier transform infrared spectroscopy),respectively.The Tessier's five-step sequential extraction procedure was used to analyze the fractions of chemical speciation for Pb,Cd and Zn ions.The experimental results indicate that Friedel-Ettringite based novel solidification/stabilization matrices can incorporate Pb,Cd and Zn ions effectively by physical en-capsulation and chemical fixation,and it exhibits a great potential in co-landfill treatment of MSWI fly ash with some heavy metals-bearing hazardous wastes.
文摘Based on theoretical analyses, the effect of electric current density on stability of solidification interface morphology of QAl 4 alloy was studied experimentally. The results show that the experimental results agree well with the theoretical analyses, and the following conclusions can be drawn: the increase of electric current density improves the stability of the solidification interface morphology under the condition of no convection of the liquid metal. Otherwise this convection will slow down the trend of solidification interface developing to stability caused by increasing electric current density.
基金Project supported by the National Natural Science Foundation of China (Grant No. 50401013)the State Key Laboratory of Solidification Processing in Northwestern Polytechnical University of China (NWPU) (Grant No. KP200903)
文摘Phase field investigation reveals that the stability of the planar interface is related to the anisotropic intensity of surface tension and the misorientation of preferred crystallographic orientation with respect to the heat flow direction. The large anisotropic intensity may compete to determine the stability of the planar interface. The destabilizing effect or the stabilizing effect depends on the misorientation. Moreover, the interface morphology of initial instability is also affected by the surface tension anisotropy.
基金supported by the National Natural Science Foundation of China (Grant No. U1934211)the Open Foundation of National Engineering Research Center of High-speed Railway Construction Technology (Grant No. HSR202005)Scientific Research Project of Hunan Education Department (Grant No.20B596)。
文摘In recent years, the invert anomalies of operating railway tunnels in water-rich areas occur frequently,which greatly affect the transportation capacity of the railway lines. Tunnel drainage system is a crucial factor to ensure the invert stability by regulating the external water pressure(EWP). By means of a threedimensional(3D) printing model, this paper experimentally investigates the deformation behavior of the invert for the tunnels with the traditional drainage system(TDS) widely used in China and its optimized drainage system(ODS) with bottom drainage function. Six test groups with a total of 110 test conditions were designed to consider the design factors and environmental factors in engineering practice,including layout of the drainage system, blockage of the drainage system and groundwater level fluctuation. It was found that there are significant differences in the water discharge, EWP and invert stability for the tunnels with the two drainage systems. Even with a dense arrangement of the external blind tubes, TDS was still difficult to eliminate the excessive EWP below the invert, which is the main cause for the invert instability. Blockage of drainage system further increased the invert uplift and aggravated the track irregularity, especially when the blockage degree is more than 50%. However, ODS can prevent these invert anomalies by reasonably controlling the EWP at tunnel bottom. Even when the groundwater level reached 60 m and the blind tubes were fully blocked, the invert stability can still be maintained and the railway track experienced a settlement of only 1.8 mm. Meanwhile, the on-site monitoring under several rainstorms further showed that the average EWP of the invert was controlled within 84 k Pa, while the maximum settlement of the track slab was only 0.92 mm, which also was in good agreement with the results of model test.
文摘Because of urbanization,land resources in China’s cities has become increasingly scarce.Therefore,modern buildings are becoming taller,making high-rise steel frame structures the new favorite of the construction industry.However,the construction of high-rise steel frame structures requires advanced technology.If the construction technology is effectively implemented and the welding techniques of the construction personnel align with the requirements for high-rise steel frame structures,it can help mitigate deformations in the steel structure,thus preserving the overall construction quality of high-rise steel frame structures.To enhance the applicability of steel frame structures in high-rise buildings,this paper focuses on analyzing the optimization path for the construction process of high-rise steel frame structures.It introduces a tailored approach to control welding-induced deformations in steel frame structures,aiming to make a valuable contribution to the advancement of China’s construction industry.
基金supported by the National Natural Science Foundation of China(Nos.52074296,52004286)the China Postdoctoral Science Foundation(Nos.2020T130701,2019M650895)the Fundamental Research Funds for the Central Universities(Nos.2022YJSNY18,2022XJNY02)。
文摘To ameliorate the defects of insufcient support resistance of traditional roadside flling bodies for gob-side entry retaining(GER),overcome the inability to adapt to the deformation of surrounding rock,and isolate the goaf efectively,a new type of high-water material as a roadside flling body for GER technology with double roadways was proposed.The instability analysis and control technology of GER with double roadways by flling high-water material into a gently inclined coal seam were studied.The basic mechanical properties of the new high-water material were investigated through laboratory experiments,and their main advantages were identifed.The reasonable width of the roadside flling wall of a high-water material was obtained by combining ground pressure observation and theoretical calculations.The distribution characteristics of the stress and plastic zone of surrounding rock of GER after being stabilized by the disturbance of the working face were studied using numerical simulations,and the failure range of GER by flling with high-water material was revealed.Based on this,a coupling control technology of anchor cables and bolts+single props+metal mesh+anchor bolts is proposed.Through the coupling methods of arranging borehole peeping and observing the convergences of surrounding rock,the results demonstrate that GER with double roadways by flling with a 1.8-m-wide high-water material has a good control efect.The above research will play an active role in promoting the application of high-water materials in GER roadside flling.
基金Project supported by the National Basic Research Program of China(Grant No.2011CB610401)the National Natural Science Foundation of China(Grant No.51371151)the Free Research Fund of State Key Laboratory of Solidification Processing,China(Grant No.100-QP-2014)
文摘Tip splitting instability of cellular interface morphology in directional solidification is analyzed based on the bias field method proposed recently by Glicksman. The physical mechanism of tip instability is explained by analyzing the interface potential, the tangential energy flux, and the normal energy flux. A rigorous criterion for tip-splitting instability is established analytically, i.e., the ratio of the cellular tip radius to the cellular width α >3/2/π≈ 0.3899, which is in good agreement with simulation results. This study also reveals that the cellular tip splitting instability is attributable to weak Gibbs–Thomson energy acting on the interface.
文摘Relaxed Stable Stability(RSS) in an important part of the active control technology.It is a new way to raise the flying speed,distance and maneuverability of missile.Depth study of RSS technology plays an important role for the new concept missile design.This paper describes the detailed definition of RSS and its advantages,presents the research status and prospects for its application in the design of new missiles.
文摘Maintenance and risk estimation of a weak roadbed condition during the construction period are described.Risk-management procedure for unstable,weak soils is proposed through adjusting the technological loads and real-time monitoring of their influence.The efficiency of implementing maximum allowable vibroloads and the drainage system for strengthening weak soils is shown in the example of the Northern Latitudinal Railway area.
文摘Toxicity characteristic leaching procedure(TCLP) of zinc plating sludge was carried out to assess the leaching potential of the sludge and the leachates were analyzed for heavy metals. The concentration of zinc, chromium, and lead in the leachate were 371 5 mg/L, 1 95 mg/L and 1 99 mg/L respectively Solidification of zinc sludge was carried out using four different binder systems consisting of cement mortar, fly ash, clay and lime and cured for 28 d. The ratio of sludge added varied from 60% to 80% by volume. The solidified products were tested for metal fixing efficiency and physical strength. It was observed that the volume of sludge added that resulted in maximum metal stabilization was 60% for all the combinations, above which the metal fixation efficiency decreased resulting in high values of zinc in the leachate. Addition of 5% sodium silicate enhanced the chemical fixation of metals in all the binder systems. Among the four fixing agents studied, mixture of fly ash: lime, and cement mortar: lime stabilized zinc and other metals in the sludge effectively than other combinations. Addition of lime increased the stabilization of zinc whereas cement mortar increased the strength of the solidified product.
基金Foundation item： Projects（41172273, 40802079, 51108288） supported by the National Natural Science Foundation of China Project（KLE-TJGE-B1106） supported by the Opening Fund of Key Laboratory of Geotechnical and Underground Engineering of Ministry of Education （Tongji University）, China
