Solid-state electrolyte Li_(10)GeP_(2)S_(12)(LGPS)has a high lithium ion conductivity of 12 mS cm^(-1)at room temperature,but its inferior chemical stability against lithium metal anode impedes its practical applicati...Solid-state electrolyte Li_(10)GeP_(2)S_(12)(LGPS)has a high lithium ion conductivity of 12 mS cm^(-1)at room temperature,but its inferior chemical stability against lithium metal anode impedes its practical application.Among all solutions,Ge atom substitution of the solid-state electrolyte LGPS stands out as the most promising solution to this interface problem.A systematic screening framework for Ge atom substitution including ionic conductivity,thermodynamic stability,electronic and mechanical properties is utilized to solve it.For fast screening,an enhanced model Dop Net FC using chemical formulas for the dataset is adopted to predict ionic conductivity.Finally,Li_(10)SrP_(2)S_(12)(LSrPS)is screened out,which has high lithium ion conductivity(12.58 mS cm^(-1)).In addition,an enhanced migration of lithium ion across the LSr PS/Li interface is found.Meanwhile,compared to the LGPS/Li interface,LSrPS/Li interface exhibits a larger Schottky barrier(0.134 eV),smaller electron transfer region(3.103?),and enhanced ability to block additional electrons,all of which contribute to the stabilized interface.The applied theoretical atom substitution screening framework with the aid of machine learning can be extended to rapid determination of modified specific material schemes.展开更多
The capture and characterization of oligomers are extremely important in the studies of amyloid aggregation of proteins and peptides.Oligomers are critical intermediates that can impact the structures of amyloid fibri...The capture and characterization of oligomers are extremely important in the studies of amyloid aggregation of proteins and peptides.Oligomers are critical intermediates that can impact the structures of amyloid fibrils.Moreover,it is widely accepted that oligomers are the most toxic species along the aggregation pathway[1e4].The studies of oligomers are believed to shed light on the molecular mechanism of amyloid fibrillation and probably the medical clues for related diseases.In vitro investigations of amyloid oligomers are challenging due to their transient and polymorphic nature[5].This is particularly evident in the case of human type-2 diabetes-associated islet amyloid polypeptide(hIAPP),which tends to rapidly form polymorphic fibrils within minutes[6].Notably,hIAPP demonstrates a higher propensity for rapid aggregation compared to other amyloid proteins such as a-synuclein[7].展开更多
The warm and ice-rich frozen soil is characterized by high unfrozen water content, low shear strength and large compressibility, which is unreliable to meet the stability requirements of engineering infrastructures an...The warm and ice-rich frozen soil is characterized by high unfrozen water content, low shear strength and large compressibility, which is unreliable to meet the stability requirements of engineering infrastructures and foundations in permafrost regions. In this study, a novel approach for stabilizing the warm and ice-rich frozen soil with sulphoaluminate cement was proposed based on chemical stabilization. The mechanical behaviors of the stabilized soil, such as strength and stress-strain relationship, were investigated through a series of triaxial compression tests conducted at -1.0℃, and the mechanism of strength variations of the stabilized soil was also explained based on scanning electron microscope test. The investigations indicated that the strength of stabilized soil to resist failure has been improved, and the linear Mohr-Coulomb criteria can accurately reflect the shear strength of stabilized soil under various applied confining pressure. The increase in both curing age and cement mixing ratio were favorable to the growth of cohesion and internal friction angle. More importantly, the strength improvement mechanism of the stabilized soil is attributed to the formation of structural skeleton and the generation of cementitious hydration products within itself. Therefore, the investigations conducted in this study provide valuable references for chemical stabilization of warm and ice-rich frozen ground, thereby providing a basis for in-situ ground improvement for reinforcing warm and ice-rich permafrost foundations by soil-cement column installation.展开更多
In recent years,there has been growing interest in developing methods for mitigating greenhouse effect,as greenhouse gas emissions continue to contribute to global temperature rise.On the other hand,investigating geop...In recent years,there has been growing interest in developing methods for mitigating greenhouse effect,as greenhouse gas emissions continue to contribute to global temperature rise.On the other hand,investigating geopolymers as environmentally friendly binders to mitigate the greenhouse effect using soil stabilization has been widely conducted.However,the effect of CO_(2)exposure on the mechanical properties of geopolymer-stabilized soils is rarely reported.In this context,the effect of CO_(2)exposure on the mechanical and microstructural features of sandy soil stabilized with volcanic ash-based geopolymer was investigated.Several factors were concerned,for example the binder content,relative density,CO_(2)pressure,curing condition,curing time,and carbonate content.The results showed that the compressive strength of the stabilized sandy soil specimens with 20%volcanic ash increased from 3 MPa to 11 MPa.It was also observed that 100 kPa CO_(2)pressure was the optimal pressure for strength development among the other pressures.The mechanical strength showed a direct relationship with binder content and carbonate content.Additionally,in the ambient curing(AC)condition,the mechanical strength and carbonate content increased with the curing time.However,the required water for carbonation evaporated after 7 d of oven curing(OC)condition and as a result,the 14-d cured samples showed lower mechanical strength and carbonate content in comparison with 7-d cured samples.Moreover,the rate of strength development was higher in OC cured samples than AC cured samples until 7 d due to higher geopolymerization and carbonation rate.展开更多
CaCl_(2)·6H_(2)O/expanded vermiculite shape stabilized phase change materials(CEV)was prepared by atmospheric impregnation method.Using gold mine tailings as aggregate of cemented paste backfill(CPB)material,the ...CaCl_(2)·6H_(2)O/expanded vermiculite shape stabilized phase change materials(CEV)was prepared by atmospheric impregnation method.Using gold mine tailings as aggregate of cemented paste backfill(CPB)material,the CPB with CEV added was prepared,and the specific heat capacity,thermal conductivity,and uniaxial compressive strength(UCS)of CPB with different cement-tailing ratios and CEV addition ratios were tested,the influence of the above variables on the thermal and mechanical properties of CPB was analyzed.The results show that the maximum encapsulation capacity of expanded vermiculite for CaCl_(2)·6H_(2)O is about 60%,and the melting and solidification enthalpies of CEV can reach 98.87 J/g and 97.56 J/g,respectively.For the CPB without CEV,the specific heat capacity,thermal conductivity,and UCS decrease with the decrease of cement-tailing ratio.For the CPB with CEV added,with the increase of CEV addition ratio,the specific heat capacity increases significantly,and the sensible heat storage capacity and latent heat storage capacity can be increased by at least 10.74%and 218.97%respectively after adding 12%CEV.However,the addition of CEV leads to the increase of pores,and the thermal conductivity and UCS both decrease with the increase of CEV addition.When cement-tailing ratio is 1:8 and 6%,9%,and 12%of CEV are added,the 28-days UCS of CPB is less than 1 MPa.Considering the heat storage capacity and cost price of backfill,the recommended proportion scheme of CPB material presents cement-tailing ratio of 1:6 and 12%CEV,and the most recommended heat storage/release temperature cycle range of CPB with added CEV is from 20 to 40℃.This work can provide theoretical basis for the utilization of heat storage backfill in green mines.展开更多
Steel slag is characterized by high strength,good wear resistance and micro-expansion.This study aims at exploring the potential of steel slag in cement stabilized aggregates,mainly including mechanical properties,shr...Steel slag is characterized by high strength,good wear resistance and micro-expansion.This study aims at exploring the potential of steel slag in cement stabilized aggregates,mainly including mechanical properties,shrinkage and compensation mechanisms.For this purpose,the compressive strength and compressive resilient modulus of cement stabilized aggregates with different steel slag contents(CSMS)were initially investigated.Subsequently,the effects of steel slag and cement on dry shrinkage,temperature shrinkage,and total shrinkage were analyzed through a series of shrinkage test designs.Additionally,in combination with X-ray diffraction(XRD)and Scanning electron microscope(SEM),the characteristic peaks and microscopic images of cement,steel slag and cement-steel slag at different hydration ages were analyzed to identify the chemical substances causing the expansion volume of steel slag and reveal the compensation mechanism of CSMS.The results show that the introduction of 20%steel slag improved the mechanical properties of CSMS by 16.7%,reduced dry shrinkage by 21%,increased temperature shrinkage by 5.8%and reduced its total shrinkage by 19.2%.Compared with the hydration reaction of cement alone,the composite hydration reaction of steel slag with cement does not produce new hydrates.Furthermore,it is noteworthy that the volume expansion of the f-CaO hydration reaction in steel slag can compensate for the volume shrinkage of cement-stabilized macadam.This research can provide a solid theoretical basis for the application and promotion of steel slag in cement-stabilized macadam and reduce the possibility of shrinkage cracking.展开更多
The key challenge of industrial water electrolysis is to design catalytic electrodes that can stabilize high current density with low power consumption(i.e.,overpotential),while industrial harsh conditions make the ba...The key challenge of industrial water electrolysis is to design catalytic electrodes that can stabilize high current density with low power consumption(i.e.,overpotential),while industrial harsh conditions make the balance between electrode activity and stability more difficult.Here,we develop an efficient and durable electrode for water oxidation reaction(WOR),which yields a high current density of 1000 mA cm−2 at an overpotential of only 284 mV in 1M KOH at 25°C and shows robust stability even in 6M KOH strong alkali with an elevated temperature up to 80°C.This electrode is fabricated from a cheap nickel foam(NF)substrate through a simple one-step solution etching method,resulting in the growth of ultrafine phosphorus doped nickel-iron(oxy)hydroxide[P-(Ni,Fe)O_(x)H_(y)]nanoparticles embedded into abundant micropores on the surface,featured as a self-stabilized catalyst–substrate fusion electrode.Such self-stabilizing effect fastens highly active P-(Ni,Fe)O_(x)H_(y)species on conductive NF substrates with significant contribution to catalyst fixation and charge transfer,realizing a win–win tactics for WOR activity and durability at high current densities in harsh environments.This work affords a cost-effective WOR electrode that can well work at large current densities,suggestive of the rational design of catalyst electrodes toward industrial-scale water electrolysis.展开更多
A low-cost eco-friendly aqueous foam,especially the robust foam with great tolerance to high salinity and high temperature,is in great demand in the oil industry,e.g.,oil and gas well or geothermal well drilling.Herei...A low-cost eco-friendly aqueous foam,especially the robust foam with great tolerance to high salinity and high temperature,is in great demand in the oil industry,e.g.,oil and gas well or geothermal well drilling.Herein,an ultra-stable aqueous foam was developed using the biodegradable cellulose microfiber(CMF)as a foam stabilizer.The foam stabilized by CMF shows excellent tolerance to the high concentration of NaCl(6.0 wt%)and CaCl_(2)(0.25 wt%)and the related drainage half-life times(T_(0.5))reach 1750 and 2340 s respectively.By contrast,the foams without CMF are completely drained(T_(0.5)=0 s)when NaCl concentration is greater than 6.0 wt%or CaCl_(2) concentration is greater than 0.20 wt%.Notably,T0.5 of the foams stabilized by CMF at these saline concentrations still can maintain above 1000 s even after aging at 120℃ for 16 h,exhibiting an outstanding foam-stabilizing performance at high temperature.Experimental results suggest that the salt and high-temperature tolerance of CMF in foam stabilization is attributed to the electrically uncharged surfaces,the formation of a gel-like structure and the excellent thermal stability.This work not only provides a promising candidate of aqueous foam stabilizer to deal with high temperature and high salinity but also presents a natural-based solution for an environmentally friendly drilling industry in the future.展开更多
In this paper the use of lime stabilized subgrade for low volume roads in two regions with high mountains and different frost penetration conditions in Türkiye was investigated in terms of design,performance,and ...In this paper the use of lime stabilized subgrade for low volume roads in two regions with high mountains and different frost penetration conditions in Türkiye was investigated in terms of design,performance,and cost.Pavements on unstabilized and stabilized subgrade were designed for two regions(Izmir and Van),covering all climate variations.The resilient modulus of the lime stabilized subgrade with different soil pulverization levels for non-freezing and freezing conditions were taken from a previous laboratory study.Frost effects were considered in pavement design using two different approaches,including limited subgrade frost penetration method and reduced subgrade strength method.Detailed application and evaluation were performed for all steps.Lime stabilized subgrades significantly reduced the thickness of base courses,and the benefit of lime stabilization was highly dependent on soil pulverization level.A detailed cost analysis on the unstabilized and stabilized cases found that the use of lime stabilization in the subgrade provided significant initial cost savings.Comparative analysis by using the AASHTO(1993)method and KENPAVE software,and quantity effect of soil pulverization level on the performance of low volume roads from a service life perspective,show that subgrade resilient modulus can be estimated.It is also possible to make correct performance estimation in the field.The results of the study show that lime stabilization is a good solution for low volume roads in the mountainous regions of Türkiye.展开更多
Oxygen redox is considered a new paradigm for increasing the practical capacity and energy density of the layered oxide cathodes for Na-ion batteries. However, severe local structural changes and phase transitions dur...Oxygen redox is considered a new paradigm for increasing the practical capacity and energy density of the layered oxide cathodes for Na-ion batteries. However, severe local structural changes and phase transitions during anionic redox reactions lead to poor electrochemical performance with sluggish kinetics.Here, we propose a synergy of Li-Cu cations in harnessing the full potential of oxygen redox, through Li displacement and suppressed phase transition in P3-type layered oxide cathode. P3-type Na_(0.7)[Li_(0.1)Cu_(0.2)Mn_(0.7)]O_(2) cathode delivers a large specific capacity of ~212 mA h g^(-1)at 15 mA g^(-1). The discharge capacity is maintained up to ~90% of the initial capacity after 100 cycles, with stable occurrence of the oxygen redox in the high-voltage region. Through advanced experimental analyses and first-principles calculations, it is confirmed that a stepwise redox reaction based on Cu and O ions occurs for the charge-compensation mechanism upon charging. Based on a concrete understanding of the reaction mechanism, the Li displacement by the synergy of Li-Cu cations plays a crucial role in suppressing the structural change of the P3-type layered material under the oxygen redox reaction, and it is expected to be an effective strategy for stabilizing the oxygen redox in the layered oxides of Na-ion batteries.展开更多
The present work investigated the effect of polyethylene terephthalate (PET) plastic waste on the physico-mechanical and thermal properties of cement-stabilized laterite bricks to see the durability of the modified br...The present work investigated the effect of polyethylene terephthalate (PET) plastic waste on the physico-mechanical and thermal properties of cement-stabilized laterite bricks to see the durability of the modified bricks (CSLB). Samples were formulated by mixing laterite, cement, and different percentages of PET (0%, 3%, 5%, and 7%) by volume. The bricks were produced using the M7MI Hydraform standard interlocking block and kept in the shade for a curing period of 28 days. The addition of 3% to 5% PET to the laterite stabilized with 10% cement results in a decrease in both dry and wet compressive strength, which is determined using the Controlab compression machine. However, the obtained results are in concordance with the standards. The thermal conductivity of CSLB, determined using the box method with the EI700 measurement cell, decreases as the PET content of the mixture increases. A decrease in bulk density from 1.67 to 1.58 g/cm<sup>3</sup> was observed.展开更多
In the field of soil stabilization, only calcium silicate hydrate(CSH) and ettringite(AFt) as hydration products have been reported to directly contribute to the strength enhancement of the soil. A chloride dredger fi...In the field of soil stabilization, only calcium silicate hydrate(CSH) and ettringite(AFt) as hydration products have been reported to directly contribute to the strength enhancement of the soil. A chloride dredger fill, an artificial chloride saline soil, and a non-saline soil were stabilized by Portland cement(PC) and PC with Ca(OH)_2(CH) with different contents. A series of unconfined compressive strength(UCS) tests of stabilized soil specimen after curing for 7 d and 28 d were carried out, and the hydration products and microstructure of the specimens were observed by X-ray diffractometry(XRD), scanning electronic microscopy(SEM), and energy-dispersive X-ray analysis(EDXA). The results showed that the strengths of PC+CH-stabilized chloride saline soils were much higher than those of PC-stabilized soils. A new hydration product of calcium aluminate chloride hydrate, also known as Friedel's salt, appeared in the PC+CH-stabilized chloride saline soils. The solid-phase volume of Friedel's salt expanded during the formation of the hydrate; this volume filled the pores in the stabilized soil. This pore-filling effect was the most important contribution to the significantly enhanced strength of the PC+CH-stabilized chloride saline soils. On the basis of this understanding, a new optimized stabilizer was designed according to the concept that the chloride in saline soil could be utilized as a component of the stabilizer. The strength of the chloride saline soils stabilized by the optimized stabilizer was even further increased compared with that of the PC+CH-stabilized soils.展开更多
A magnetically stabilized fluidized bed (MSB) is a highly efficient filter that takes the advantage of both fluidized beds and fixed beds. This paper presents the research to collect aerosol in airflow with a MSB. The...A magnetically stabilized fluidized bed (MSB) is a highly efficient filter that takes the advantage of both fluidized beds and fixed beds. This paper presents the research to collect aerosol in airflow with a MSB. The filtering model of MSB is established with its parameters including magnetic field intensity, gas superficial velocity, average grain size, and bed height on the collection efficiency of MSB. The model is verified by experiments.展开更多
A dream long held by physicists has been to raise the critical temperature(Tc)—the temperature below which the material exhibits no electrical resistance—of a superconductor to room temperature.The most recent excit...A dream long held by physicists has been to raise the critical temperature(Tc)—the temperature below which the material exhibits no electrical resistance—of a superconductor to room temperature.The most recent excitement in that regard has centered on rare-earth superhydrides,of which LaH10 at 190 GPa has a remarkably high Tc of 260 K.展开更多
As "the third pole", the Tibetan Plateau(TP) is sensitive to climate forcing and has experienced rapid warming in recent decades. This study analyzes annual and seasonal near-surface air temperature changes ...As "the third pole", the Tibetan Plateau(TP) is sensitive to climate forcing and has experienced rapid warming in recent decades. This study analyzes annual and seasonal near-surface air temperature changes on the TP in response to transient and stabilized 2.0℃/1.5℃ global warming targets based on simulations of the Community Earth System Model(CESM). Elevation-dependent warming(EDW) with faster warming at higher elevations is predicted. A surface energy budget analysis is adopted to uncover the mechanisms responsible for the temperature changes. Our results indicate a clear amplified warming on the TP with positive EDW in 2.0℃/1.5℃ warmer futures, especially in the cold season. Mean TP warming relative to the reference period(1961–90) is dominated by an enhanced downward longwave radiation flux, while the variations in surface albedo shape the detailed pattern of EDW. For the same global warming level, the temperature changes under transient scenarios are ~0.2℃ higher than those under stabilized scenarios, and the characteristics of EDW are broadly similar for both scenarios. These differences can be primarily attributed to the combined effects of differential downward longwave radiation, cloud radiative forcing, and surface sensible and latent heat fluxes. These findings contribute to a more detailed understanding of regional climate on the TP in response to the long-term climate goals of the Paris Agreement and highlight the differences between transient and stabilized warming scenarios.展开更多
Aimed at requirements, a kind of radar stabilized platform with external rotor and orthogonal shafts is designed. Its dynamic characters are analyzed by using finite element theory and ANSYS software. Also, a traditio...Aimed at requirements, a kind of radar stabilized platform with external rotor and orthogonal shafts is designed. Its dynamic characters are analyzed by using finite element theory and ANSYS software. Also, a traditional stabilized platform with inner rotor is designed for comparison. It is shown that the new platform reduces two transmission links and 20% of precise components, its weight decreases by 20%, its natural frequency and rigidity are enlarged, the operating accuracy and stationary are increased. The new stabilized platform is more superiority and practicability. Its design method and analysis results have already been used in development mission. It provides helpful reference for similar structure designs.展开更多
This study compares the effect of treated pineapple leaves fibres (T-PALF) with sodium hydroxide solution and untreated fibres (N-PALF) on the compressive and flexural strength of earth bricks stabilized with 3% and 5...This study compares the effect of treated pineapple leaves fibres (T-PALF) with sodium hydroxide solution and untreated fibres (N-PALF) on the compressive and flexural strength of earth bricks stabilized with 3% and 5% cement. The fibre content ranged from 0% to 5% in steps of 1% by weight. The compressive strength tests were made at 7, 14, 21 and 28 days of curing;the flexural strength test were conducted at 28th day only. The results show that the T-PALF had a higher compressive strength when comparing to the N-PALF. The highest compressive strength of the bricks was obtained at 28 days of curing. The compressive strength at 28 days of stabilized brick at 3% and 5% of cement reinforced with T-PALF were 4.01 and 4.81 MPa, respectively, while the one reinforced with N-PALF was 3.19 and 4.63 MPa, respectively. The results further show that the highest flexural strength of both stabilized bricks at 3% and 5% of cement reinforced with T-PALF and N-PALF was obtained with the bricks stabilized with 5% of cement reinforced with T-PALF. This results show that bricks stabilized with 5% cement and reinforced with 3% of treated fibres content are good for construction of load bearing walls. It was observed;a significant improvement of the reinforced blocks under flexure than under compression.展开更多
A moisturizing cream containing 25 wt% of an organic solvent, diethylene glycol monoethyl ether (DEGEE), is observed to be stabilized by an emulsifying wax blend of cetearyl alcohol, dicetyl phosphate, and ceteth-10 p...A moisturizing cream containing 25 wt% of an organic solvent, diethylene glycol monoethyl ether (DEGEE), is observed to be stabilized by an emulsifying wax blend of cetearyl alcohol, dicetyl phosphate, and ceteth-10 phosphate (tradename Crodafos CES). Polarized light microscopy indicates that the Crodafos CES helps to produce a liquid-crystal stabilized oil-in-water emulsion, which is physically stable for months under accelerated aging conditions and chemically stable over the full topical pH range of 3.5 to 9. Emulsion globule size in the cream is observed to be dependent on the degree of emulsifying wax neutralization, with the globule size decreasing with increasing cream pH. The superior solubilizing properties of DEGEE combined with the full pH range and liquid-crystal stabilizing properties of the Crodafos CES give this formulation the potential for a wide range of applications in the topical delivery of active pharmaceutical ingredients.展开更多
Alkenyl succinic anhydride(ASA) is a popular paper-sizing agent that is generally added to papermaking systems as an aqueous emulsion. Herein, we reviewed the recent work focusing on ASA emulsions stabilized by solid ...Alkenyl succinic anhydride(ASA) is a popular paper-sizing agent that is generally added to papermaking systems as an aqueous emulsion. Herein, we reviewed the recent work focusing on ASA emulsions stabilized by solid particles. Solid particle-stabilized ASA emulsions generally possess high ASA content and exhibit good sizing performance. The particles that have been used to stabilize ASA emulsions typically include montmorillonite, laponite, alumina, TiO_2, Fe_3O_4, polyaluminum sulfate(PAS), and cellulose nanocrystals(CNCs). Montmorillonite is the first extensively studied particle stabilizer for ASA emulsions. Laponite is undoubtedly the most competent particle stabilizer for preparing ASA emulsions with high sizing efficiency. Montmorillonite and laponite can be used individually as stabilizers after modification or as co-stabilizers with other particles or polymers. TiO_2, alumina, PAS, and CNCs are commonly used as stabilizers either individually or with other particles.展开更多
基金support from the National Natural Science Foundation of China (No.51806072)。
文摘Solid-state electrolyte Li_(10)GeP_(2)S_(12)(LGPS)has a high lithium ion conductivity of 12 mS cm^(-1)at room temperature,but its inferior chemical stability against lithium metal anode impedes its practical application.Among all solutions,Ge atom substitution of the solid-state electrolyte LGPS stands out as the most promising solution to this interface problem.A systematic screening framework for Ge atom substitution including ionic conductivity,thermodynamic stability,electronic and mechanical properties is utilized to solve it.For fast screening,an enhanced model Dop Net FC using chemical formulas for the dataset is adopted to predict ionic conductivity.Finally,Li_(10)SrP_(2)S_(12)(LSrPS)is screened out,which has high lithium ion conductivity(12.58 mS cm^(-1)).In addition,an enhanced migration of lithium ion across the LSr PS/Li interface is found.Meanwhile,compared to the LGPS/Li interface,LSrPS/Li interface exhibits a larger Schottky barrier(0.134 eV),smaller electron transfer region(3.103?),and enhanced ability to block additional electrons,all of which contribute to the stabilized interface.The applied theoretical atom substitution screening framework with the aid of machine learning can be extended to rapid determination of modified specific material schemes.
文摘The capture and characterization of oligomers are extremely important in the studies of amyloid aggregation of proteins and peptides.Oligomers are critical intermediates that can impact the structures of amyloid fibrils.Moreover,it is widely accepted that oligomers are the most toxic species along the aggregation pathway[1e4].The studies of oligomers are believed to shed light on the molecular mechanism of amyloid fibrillation and probably the medical clues for related diseases.In vitro investigations of amyloid oligomers are challenging due to their transient and polymorphic nature[5].This is particularly evident in the case of human type-2 diabetes-associated islet amyloid polypeptide(hIAPP),which tends to rapidly form polymorphic fibrils within minutes[6].Notably,hIAPP demonstrates a higher propensity for rapid aggregation compared to other amyloid proteins such as a-synuclein[7].
基金supported by the National Natural Science Foundation of China (No. 41471062, No. 41971085, No. 41971086)。
文摘The warm and ice-rich frozen soil is characterized by high unfrozen water content, low shear strength and large compressibility, which is unreliable to meet the stability requirements of engineering infrastructures and foundations in permafrost regions. In this study, a novel approach for stabilizing the warm and ice-rich frozen soil with sulphoaluminate cement was proposed based on chemical stabilization. The mechanical behaviors of the stabilized soil, such as strength and stress-strain relationship, were investigated through a series of triaxial compression tests conducted at -1.0℃, and the mechanism of strength variations of the stabilized soil was also explained based on scanning electron microscope test. The investigations indicated that the strength of stabilized soil to resist failure has been improved, and the linear Mohr-Coulomb criteria can accurately reflect the shear strength of stabilized soil under various applied confining pressure. The increase in both curing age and cement mixing ratio were favorable to the growth of cohesion and internal friction angle. More importantly, the strength improvement mechanism of the stabilized soil is attributed to the formation of structural skeleton and the generation of cementitious hydration products within itself. Therefore, the investigations conducted in this study provide valuable references for chemical stabilization of warm and ice-rich frozen ground, thereby providing a basis for in-situ ground improvement for reinforcing warm and ice-rich permafrost foundations by soil-cement column installation.
基金This study was supported by MatSoil Company(Grant No.04G/2022)This research was funded by the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie(Grant No.778120).
文摘In recent years,there has been growing interest in developing methods for mitigating greenhouse effect,as greenhouse gas emissions continue to contribute to global temperature rise.On the other hand,investigating geopolymers as environmentally friendly binders to mitigate the greenhouse effect using soil stabilization has been widely conducted.However,the effect of CO_(2)exposure on the mechanical properties of geopolymer-stabilized soils is rarely reported.In this context,the effect of CO_(2)exposure on the mechanical and microstructural features of sandy soil stabilized with volcanic ash-based geopolymer was investigated.Several factors were concerned,for example the binder content,relative density,CO_(2)pressure,curing condition,curing time,and carbonate content.The results showed that the compressive strength of the stabilized sandy soil specimens with 20%volcanic ash increased from 3 MPa to 11 MPa.It was also observed that 100 kPa CO_(2)pressure was the optimal pressure for strength development among the other pressures.The mechanical strength showed a direct relationship with binder content and carbonate content.Additionally,in the ambient curing(AC)condition,the mechanical strength and carbonate content increased with the curing time.However,the required water for carbonation evaporated after 7 d of oven curing(OC)condition and as a result,the 14-d cured samples showed lower mechanical strength and carbonate content in comparison with 7-d cured samples.Moreover,the rate of strength development was higher in OC cured samples than AC cured samples until 7 d due to higher geopolymerization and carbonation rate.
基金supported by the National Natural Science Foundation of China(Nos.51974225,51874229,51674188,51904224,51904225)the Shaanxi Innovative Talents Cultivate Program-New-star Plan of Science and Technology,China(No.2018KJXX-083)+2 种基金the Natural Science Basic Research Plan of Shaanxi Province of China(Nos.2018JM 5161,2018JQ5183,2019JM-074)the Scientific Research Program funded by the Shaanxi Provincial Education Department,China(No.19JK0543)the Outstanding Youth Science Fund of Xi’an University of Science and Technology,China(No.2018YQ2-01)。
文摘CaCl_(2)·6H_(2)O/expanded vermiculite shape stabilized phase change materials(CEV)was prepared by atmospheric impregnation method.Using gold mine tailings as aggregate of cemented paste backfill(CPB)material,the CPB with CEV added was prepared,and the specific heat capacity,thermal conductivity,and uniaxial compressive strength(UCS)of CPB with different cement-tailing ratios and CEV addition ratios were tested,the influence of the above variables on the thermal and mechanical properties of CPB was analyzed.The results show that the maximum encapsulation capacity of expanded vermiculite for CaCl_(2)·6H_(2)O is about 60%,and the melting and solidification enthalpies of CEV can reach 98.87 J/g and 97.56 J/g,respectively.For the CPB without CEV,the specific heat capacity,thermal conductivity,and UCS decrease with the decrease of cement-tailing ratio.For the CPB with CEV added,with the increase of CEV addition ratio,the specific heat capacity increases significantly,and the sensible heat storage capacity and latent heat storage capacity can be increased by at least 10.74%and 218.97%respectively after adding 12%CEV.However,the addition of CEV leads to the increase of pores,and the thermal conductivity and UCS both decrease with the increase of CEV addition.When cement-tailing ratio is 1:8 and 6%,9%,and 12%of CEV are added,the 28-days UCS of CPB is less than 1 MPa.Considering the heat storage capacity and cost price of backfill,the recommended proportion scheme of CPB material presents cement-tailing ratio of 1:6 and 12%CEV,and the most recommended heat storage/release temperature cycle range of CPB with added CEV is from 20 to 40℃.This work can provide theoretical basis for the utilization of heat storage backfill in green mines.
基金National Natural Science Foundation of China(Grant No.52078051)Fundamental Research Funds for the Central Universities(Grant No.310821163502)+1 种基金Technology Innovation Project of Shandong Department of Industry and Information(Grant No.Lugongxinji 2020-8)the Transportation Department of Shandong Province(Grant No.Lujiaokeji 2017-28).
文摘Steel slag is characterized by high strength,good wear resistance and micro-expansion.This study aims at exploring the potential of steel slag in cement stabilized aggregates,mainly including mechanical properties,shrinkage and compensation mechanisms.For this purpose,the compressive strength and compressive resilient modulus of cement stabilized aggregates with different steel slag contents(CSMS)were initially investigated.Subsequently,the effects of steel slag and cement on dry shrinkage,temperature shrinkage,and total shrinkage were analyzed through a series of shrinkage test designs.Additionally,in combination with X-ray diffraction(XRD)and Scanning electron microscope(SEM),the characteristic peaks and microscopic images of cement,steel slag and cement-steel slag at different hydration ages were analyzed to identify the chemical substances causing the expansion volume of steel slag and reveal the compensation mechanism of CSMS.The results show that the introduction of 20%steel slag improved the mechanical properties of CSMS by 16.7%,reduced dry shrinkage by 21%,increased temperature shrinkage by 5.8%and reduced its total shrinkage by 19.2%.Compared with the hydration reaction of cement alone,the composite hydration reaction of steel slag with cement does not produce new hydrates.Furthermore,it is noteworthy that the volume expansion of the f-CaO hydration reaction in steel slag can compensate for the volume shrinkage of cement-stabilized macadam.This research can provide a solid theoretical basis for the application and promotion of steel slag in cement-stabilized macadam and reduce the possibility of shrinkage cracking.
基金National Natural Science Foundation of China,Grant/Award Numbers:11974303,12074332Qinglan Project of Jiangsu Province,Grant/Award Number:137050317the Interdisciplinary Research Project of Chemistry Discipline,Grant/Award Number:yzuxk202014 and High‐End Talent Program of Yangzhou University,Grant/Award Number:137080051。
文摘The key challenge of industrial water electrolysis is to design catalytic electrodes that can stabilize high current density with low power consumption(i.e.,overpotential),while industrial harsh conditions make the balance between electrode activity and stability more difficult.Here,we develop an efficient and durable electrode for water oxidation reaction(WOR),which yields a high current density of 1000 mA cm−2 at an overpotential of only 284 mV in 1M KOH at 25°C and shows robust stability even in 6M KOH strong alkali with an elevated temperature up to 80°C.This electrode is fabricated from a cheap nickel foam(NF)substrate through a simple one-step solution etching method,resulting in the growth of ultrafine phosphorus doped nickel-iron(oxy)hydroxide[P-(Ni,Fe)O_(x)H_(y)]nanoparticles embedded into abundant micropores on the surface,featured as a self-stabilized catalyst–substrate fusion electrode.Such self-stabilizing effect fastens highly active P-(Ni,Fe)O_(x)H_(y)species on conductive NF substrates with significant contribution to catalyst fixation and charge transfer,realizing a win–win tactics for WOR activity and durability at high current densities in harsh environments.This work affords a cost-effective WOR electrode that can well work at large current densities,suggestive of the rational design of catalyst electrodes toward industrial-scale water electrolysis.
基金This work was supported by the National Natural Science Foundation of China(Grant No.51991361 and Grant No.51991362)the foundation of China University of Petroleum(Beijing)(Grant No.2462021YXZZ002).
文摘A low-cost eco-friendly aqueous foam,especially the robust foam with great tolerance to high salinity and high temperature,is in great demand in the oil industry,e.g.,oil and gas well or geothermal well drilling.Herein,an ultra-stable aqueous foam was developed using the biodegradable cellulose microfiber(CMF)as a foam stabilizer.The foam stabilized by CMF shows excellent tolerance to the high concentration of NaCl(6.0 wt%)and CaCl_(2)(0.25 wt%)and the related drainage half-life times(T_(0.5))reach 1750 and 2340 s respectively.By contrast,the foams without CMF are completely drained(T_(0.5)=0 s)when NaCl concentration is greater than 6.0 wt%or CaCl_(2) concentration is greater than 0.20 wt%.Notably,T0.5 of the foams stabilized by CMF at these saline concentrations still can maintain above 1000 s even after aging at 120℃ for 16 h,exhibiting an outstanding foam-stabilizing performance at high temperature.Experimental results suggest that the salt and high-temperature tolerance of CMF in foam stabilization is attributed to the electrically uncharged surfaces,the formation of a gel-like structure and the excellent thermal stability.This work not only provides a promising candidate of aqueous foam stabilizer to deal with high temperature and high salinity but also presents a natural-based solution for an environmentally friendly drilling industry in the future.
基金a joint venture project between Istanbul University and the Turkish General Directorate of Highways by project number KGM-ARGE/2012-25funded by Istanbul University-Cerrahpasa Scientific Research Projects under Project No:ACIP 54739。
文摘In this paper the use of lime stabilized subgrade for low volume roads in two regions with high mountains and different frost penetration conditions in Türkiye was investigated in terms of design,performance,and cost.Pavements on unstabilized and stabilized subgrade were designed for two regions(Izmir and Van),covering all climate variations.The resilient modulus of the lime stabilized subgrade with different soil pulverization levels for non-freezing and freezing conditions were taken from a previous laboratory study.Frost effects were considered in pavement design using two different approaches,including limited subgrade frost penetration method and reduced subgrade strength method.Detailed application and evaluation were performed for all steps.Lime stabilized subgrades significantly reduced the thickness of base courses,and the benefit of lime stabilization was highly dependent on soil pulverization level.A detailed cost analysis on the unstabilized and stabilized cases found that the use of lime stabilization in the subgrade provided significant initial cost savings.Comparative analysis by using the AASHTO(1993)method and KENPAVE software,and quantity effect of soil pulverization level on the performance of low volume roads from a service life perspective,show that subgrade resilient modulus can be estimated.It is also possible to make correct performance estimation in the field.The results of the study show that lime stabilization is a good solution for low volume roads in the mountainous regions of Türkiye.
基金supported by the National Research Foundation of Korea grant funded by the Korea government (NRF2021R1A2C1014280)the Fundamental Research Program of the Korea Institute of Material Science (PNK9370)。
文摘Oxygen redox is considered a new paradigm for increasing the practical capacity and energy density of the layered oxide cathodes for Na-ion batteries. However, severe local structural changes and phase transitions during anionic redox reactions lead to poor electrochemical performance with sluggish kinetics.Here, we propose a synergy of Li-Cu cations in harnessing the full potential of oxygen redox, through Li displacement and suppressed phase transition in P3-type layered oxide cathode. P3-type Na_(0.7)[Li_(0.1)Cu_(0.2)Mn_(0.7)]O_(2) cathode delivers a large specific capacity of ~212 mA h g^(-1)at 15 mA g^(-1). The discharge capacity is maintained up to ~90% of the initial capacity after 100 cycles, with stable occurrence of the oxygen redox in the high-voltage region. Through advanced experimental analyses and first-principles calculations, it is confirmed that a stepwise redox reaction based on Cu and O ions occurs for the charge-compensation mechanism upon charging. Based on a concrete understanding of the reaction mechanism, the Li displacement by the synergy of Li-Cu cations plays a crucial role in suppressing the structural change of the P3-type layered material under the oxygen redox reaction, and it is expected to be an effective strategy for stabilizing the oxygen redox in the layered oxides of Na-ion batteries.
文摘The present work investigated the effect of polyethylene terephthalate (PET) plastic waste on the physico-mechanical and thermal properties of cement-stabilized laterite bricks to see the durability of the modified bricks (CSLB). Samples were formulated by mixing laterite, cement, and different percentages of PET (0%, 3%, 5%, and 7%) by volume. The bricks were produced using the M7MI Hydraform standard interlocking block and kept in the shade for a curing period of 28 days. The addition of 3% to 5% PET to the laterite stabilized with 10% cement results in a decrease in both dry and wet compressive strength, which is determined using the Controlab compression machine. However, the obtained results are in concordance with the standards. The thermal conductivity of CSLB, determined using the box method with the EI700 measurement cell, decreases as the PET content of the mixture increases. A decrease in bulk density from 1.67 to 1.58 g/cm<sup>3</sup> was observed.
基金Project(51008007)supported by the National Natural Science Foundation of ChinaProject(2013318J01100)supported by the Science and Technology Project of Ministry of Communications,China
文摘In the field of soil stabilization, only calcium silicate hydrate(CSH) and ettringite(AFt) as hydration products have been reported to directly contribute to the strength enhancement of the soil. A chloride dredger fill, an artificial chloride saline soil, and a non-saline soil were stabilized by Portland cement(PC) and PC with Ca(OH)_2(CH) with different contents. A series of unconfined compressive strength(UCS) tests of stabilized soil specimen after curing for 7 d and 28 d were carried out, and the hydration products and microstructure of the specimens were observed by X-ray diffractometry(XRD), scanning electronic microscopy(SEM), and energy-dispersive X-ray analysis(EDXA). The results showed that the strengths of PC+CH-stabilized chloride saline soils were much higher than those of PC-stabilized soils. A new hydration product of calcium aluminate chloride hydrate, also known as Friedel's salt, appeared in the PC+CH-stabilized chloride saline soils. The solid-phase volume of Friedel's salt expanded during the formation of the hydrate; this volume filled the pores in the stabilized soil. This pore-filling effect was the most important contribution to the significantly enhanced strength of the PC+CH-stabilized chloride saline soils. On the basis of this understanding, a new optimized stabilizer was designed according to the concept that the chloride in saline soil could be utilized as a component of the stabilizer. The strength of the chloride saline soils stabilized by the optimized stabilizer was even further increased compared with that of the PC+CH-stabilized soils.
文摘A magnetically stabilized fluidized bed (MSB) is a highly efficient filter that takes the advantage of both fluidized beds and fixed beds. This paper presents the research to collect aerosol in airflow with a MSB. The filtering model of MSB is established with its parameters including magnetic field intensity, gas superficial velocity, average grain size, and bed height on the collection efficiency of MSB. The model is verified by experiments.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.11534003,11874175,11874176,12074138,and 11974134)the Science Challenge Project(Grant No.TZ2016001)+3 种基金the Fundamental Research Funds for the Central Universities(Jilin University,JLU)the Program for JLU Science and Technology Innovative Research Team(JLUSTIRT)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB33000000)the Jilin Province Outstanding Young Talents Project(Grant No.20190103040JH).
文摘A dream long held by physicists has been to raise the critical temperature(Tc)—the temperature below which the material exhibits no electrical resistance—of a superconductor to room temperature.The most recent excitement in that regard has centered on rare-earth superhydrides,of which LaH10 at 190 GPa has a remarkably high Tc of 260 K.
基金the National Natural Science Foundation of China(Grant Nos.41971072,41771069).
文摘As "the third pole", the Tibetan Plateau(TP) is sensitive to climate forcing and has experienced rapid warming in recent decades. This study analyzes annual and seasonal near-surface air temperature changes on the TP in response to transient and stabilized 2.0℃/1.5℃ global warming targets based on simulations of the Community Earth System Model(CESM). Elevation-dependent warming(EDW) with faster warming at higher elevations is predicted. A surface energy budget analysis is adopted to uncover the mechanisms responsible for the temperature changes. Our results indicate a clear amplified warming on the TP with positive EDW in 2.0℃/1.5℃ warmer futures, especially in the cold season. Mean TP warming relative to the reference period(1961–90) is dominated by an enhanced downward longwave radiation flux, while the variations in surface albedo shape the detailed pattern of EDW. For the same global warming level, the temperature changes under transient scenarios are ~0.2℃ higher than those under stabilized scenarios, and the characteristics of EDW are broadly similar for both scenarios. These differences can be primarily attributed to the combined effects of differential downward longwave radiation, cloud radiative forcing, and surface sensible and latent heat fluxes. These findings contribute to a more detailed understanding of regional climate on the TP in response to the long-term climate goals of the Paris Agreement and highlight the differences between transient and stabilized warming scenarios.
基金Sponsored by Optic-mechanical Integration Research and Design Technology Innovation Platform(20082108)
文摘Aimed at requirements, a kind of radar stabilized platform with external rotor and orthogonal shafts is designed. Its dynamic characters are analyzed by using finite element theory and ANSYS software. Also, a traditional stabilized platform with inner rotor is designed for comparison. It is shown that the new platform reduces two transmission links and 20% of precise components, its weight decreases by 20%, its natural frequency and rigidity are enlarged, the operating accuracy and stationary are increased. The new stabilized platform is more superiority and practicability. Its design method and analysis results have already been used in development mission. It provides helpful reference for similar structure designs.
文摘This study compares the effect of treated pineapple leaves fibres (T-PALF) with sodium hydroxide solution and untreated fibres (N-PALF) on the compressive and flexural strength of earth bricks stabilized with 3% and 5% cement. The fibre content ranged from 0% to 5% in steps of 1% by weight. The compressive strength tests were made at 7, 14, 21 and 28 days of curing;the flexural strength test were conducted at 28th day only. The results show that the T-PALF had a higher compressive strength when comparing to the N-PALF. The highest compressive strength of the bricks was obtained at 28 days of curing. The compressive strength at 28 days of stabilized brick at 3% and 5% of cement reinforced with T-PALF were 4.01 and 4.81 MPa, respectively, while the one reinforced with N-PALF was 3.19 and 4.63 MPa, respectively. The results further show that the highest flexural strength of both stabilized bricks at 3% and 5% of cement reinforced with T-PALF and N-PALF was obtained with the bricks stabilized with 5% of cement reinforced with T-PALF. This results show that bricks stabilized with 5% cement and reinforced with 3% of treated fibres content are good for construction of load bearing walls. It was observed;a significant improvement of the reinforced blocks under flexure than under compression.
文摘A moisturizing cream containing 25 wt% of an organic solvent, diethylene glycol monoethyl ether (DEGEE), is observed to be stabilized by an emulsifying wax blend of cetearyl alcohol, dicetyl phosphate, and ceteth-10 phosphate (tradename Crodafos CES). Polarized light microscopy indicates that the Crodafos CES helps to produce a liquid-crystal stabilized oil-in-water emulsion, which is physically stable for months under accelerated aging conditions and chemically stable over the full topical pH range of 3.5 to 9. Emulsion globule size in the cream is observed to be dependent on the degree of emulsifying wax neutralization, with the globule size decreasing with increasing cream pH. The superior solubilizing properties of DEGEE combined with the full pH range and liquid-crystal stabilizing properties of the Crodafos CES give this formulation the potential for a wide range of applications in the topical delivery of active pharmaceutical ingredients.
基金funded by the National Natural Science Foundation of China(Grant Nos.31270625 and 21406122)
文摘Alkenyl succinic anhydride(ASA) is a popular paper-sizing agent that is generally added to papermaking systems as an aqueous emulsion. Herein, we reviewed the recent work focusing on ASA emulsions stabilized by solid particles. Solid particle-stabilized ASA emulsions generally possess high ASA content and exhibit good sizing performance. The particles that have been used to stabilize ASA emulsions typically include montmorillonite, laponite, alumina, TiO_2, Fe_3O_4, polyaluminum sulfate(PAS), and cellulose nanocrystals(CNCs). Montmorillonite is the first extensively studied particle stabilizer for ASA emulsions. Laponite is undoubtedly the most competent particle stabilizer for preparing ASA emulsions with high sizing efficiency. Montmorillonite and laponite can be used individually as stabilizers after modification or as co-stabilizers with other particles or polymers. TiO_2, alumina, PAS, and CNCs are commonly used as stabilizers either individually or with other particles.
