The NaCl-H_2O binary system is a major component of solutions coexisting with ores. Observation ofsaturated solutions of NaCl-H_2O by using the method of hydrothermal diamond anvil cell (HDAC) is a new approach tothe ...The NaCl-H_2O binary system is a major component of solutions coexisting with ores. Observation ofsaturated solutions of NaCl-H_2O by using the method of hydrothermal diamond anvil cell (HDAC) is a new approach tothe study of ore-forming fluids. The salinities of NaCl-H_2O solutions in experimental observation are in a range of 32-55%. The observed temperature range is 25℃-850℃, and the pressure range 1 atm-10 kb. In this temperature-pressure range, the supercritical single phase, two phases (L,V) close to the critical state and two-phased (L+V) immis-cible region were observed. And for the salinity of 35% the two phase L+V immiscible region of NaCl-H_2O solutionwas observed in a range of 253-720℃. Another temperature range, 400-817℃, was observed for the immiscible two-phased region of 50% salinity solution. In the high-temperature part of the two-phased immiscible region, the phase na-ture is very unstable. A "critical phenomenon" was observed when the heating path was very close to the critical state.It is possible to observe a 'critical phenomenon': an "explosion" occurred almost constantly at the interface between theliquid and vapour and the interface is rather obscure. A continuous transition between phases L and V could be foundin the immiscible L+V phase while heating continuously. Moreover, as the NaCl-H_2O solution was separated into liq-uid and vapour phases, static charges surrounding each vapour bubble could be seen, and these bubbles were attractedtogether by the static charges to form a special solution structure. Besides, critical states of different salinities of NaCl-H_2O were observed in order to study the properties of the fluids occurring in the rocks in the earth interior, the origin ofore-bearing fluids and the significance of supercritical fluid with respect to the ore formation. The comparison of the sa-linity data of the fluid inclusions in the minerals of ore deposits with observations of NaCl-H_2O under HDAC in theconditions of high temperatures and pressures, combined with further thermodynamic analysis of ore-formation condi-tions would explain in depth the factors determining the ore formation.展开更多
The directing mechanisms of liquid directing agents of zeolite Y and zeolite L were studied by means of light transmission, ultracentrifugation, NMR, XRD and “cross-exchange” experiments. It was discovered that not ...The directing mechanisms of liquid directing agents of zeolite Y and zeolite L were studied by means of light transmission, ultracentrifugation, NMR, XRD and “cross-exchange” experiments. It was discovered that not only microcfystals of zeolites, but also cage structures of zeolites play the directing role for crystallization of zeolites.展开更多
It was revealed that an average energy of special boundaries is proportional to APB energy in the alloys with the L12 superstructure. This fact proves the appearance of the GAPBs in the planes of location of special b...It was revealed that an average energy of special boundaries is proportional to APB energy in the alloys with the L12 superstructure. This fact proves the appearance of the GAPBs in the planes of location of special boundaries in coincidence sites of ordered alloys. It was determined that the more energy of special boundaries in ordered alloys, the more energy of complex stacking fault. There is a correlation between the distribution of special boundaries as a function its relative energy and ordering energy: the more ordering energy, the more degree of washed away of distribution. The correlation between average relative energy of special boundaries and ordering energy was detected: the more ordering energy, the more average energy of special boundaries. The reverse dependence between ordering energy and average number of special boundaries in grains limited by boundaries of general type was discovered.展开更多
The relations between catalytic activities and compositions of the systems Mg_xZn_(1-x)Fe_2O_4, Co_xZn_(1-x)Fe_2O_4, Co_xMg_(1-x)Fe_2O_4, Cd_xZn_(1-x)Fe_2O_4 and Mg_xZn_(1-x)Fe_2O_4·0.17Fe_2O_3 have been studied ...The relations between catalytic activities and compositions of the systems Mg_xZn_(1-x)Fe_2O_4, Co_xZn_(1-x)Fe_2O_4, Co_xMg_(1-x)Fe_2O_4, Cd_xZn_(1-x)Fe_2O_4 and Mg_xZn_(1-x)Fe_2O_4·0.17Fe_2O_3 have been studied by flow differential reactor, XRD, and derivative IR techniques. It has been found that the appropriate normal-inverse spinel combination substantially increases the activity for the title raction. The structure of the active site and the role of the bivalent cation in the title catalyst have been inferred.展开更多
The related work to reveal the primary characteristics of roles underlying the existing approaches is analyzed. Then, it is demonstrated that the representation of roles is rather complex and error-prone in these appr...The related work to reveal the primary characteristics of roles underlying the existing approaches is analyzed. Then, it is demonstrated that the representation of roles is rather complex and error-prone in these approaches. Especially, the constraints among roles in the same context cannot be expressed by the current web ontology language (OWL). To solve these problems, a novel model of role is presented and a corresponding ontology language is provided for representing this model. The key idea underlying the solution is that a role should be regarded as an element of a certain context and a context as a structured thing which is comprised of some internal elements. The structure of context possesses inherent modularity and local semantics, whereby the representation of roles and context is significantly simplified.展开更多
Teamwork is gaining increasing attention in a broader management research. In addition to previous research on the relationship between team structure and innovation performance, this study draws from an interesting e...Teamwork is gaining increasing attention in a broader management research. In addition to previous research on the relationship between team structure and innovation performance, this study draws from an interesting experience-based theory advanced by Kelley and Littman (2005), which examines teams from design thinking perspective, and tests its contributions and effects on team's innovation performance. According to Kelley and Littman any team should include the following team roles: The anthropologist, the experimenter, the cross-pollinator, the hurdler, the collaborator, the director, the experience architect, the set designer, the storyteller, and the caregiver. We develop theoretical logics to explain how team structure that includes these key team roles and competences lead to a better innovation performance, and propose pertinent hypotheses. Experimental-empirical research and quantitative analysis were used in the study. The study conducted multiple experiments on three samples: a group of foreign entrepreneurship students, a group of technical students, and an additional group of randomly selected individuals, aged between 20 and 58, with diverse backgrounds. A special approach was implemented and a new instrument was developed to evaluate individuals in teams. While the results show that team that possess the major competences proposed by Kelley and Littman are more innovative, preliminary results also show that not all team roles are equally important. Moreover, team roles should be allocated equally among members for better collaboration, member satisfaction, and quick response, and within one team, one prevailing personality is optimal in terms of innovativeness. We discuss the implications of our findings for future research and managerial practice.展开更多
文摘The NaCl-H_2O binary system is a major component of solutions coexisting with ores. Observation ofsaturated solutions of NaCl-H_2O by using the method of hydrothermal diamond anvil cell (HDAC) is a new approach tothe study of ore-forming fluids. The salinities of NaCl-H_2O solutions in experimental observation are in a range of 32-55%. The observed temperature range is 25℃-850℃, and the pressure range 1 atm-10 kb. In this temperature-pressure range, the supercritical single phase, two phases (L,V) close to the critical state and two-phased (L+V) immis-cible region were observed. And for the salinity of 35% the two phase L+V immiscible region of NaCl-H_2O solutionwas observed in a range of 253-720℃. Another temperature range, 400-817℃, was observed for the immiscible two-phased region of 50% salinity solution. In the high-temperature part of the two-phased immiscible region, the phase na-ture is very unstable. A "critical phenomenon" was observed when the heating path was very close to the critical state.It is possible to observe a 'critical phenomenon': an "explosion" occurred almost constantly at the interface between theliquid and vapour and the interface is rather obscure. A continuous transition between phases L and V could be foundin the immiscible L+V phase while heating continuously. Moreover, as the NaCl-H_2O solution was separated into liq-uid and vapour phases, static charges surrounding each vapour bubble could be seen, and these bubbles were attractedtogether by the static charges to form a special solution structure. Besides, critical states of different salinities of NaCl-H_2O were observed in order to study the properties of the fluids occurring in the rocks in the earth interior, the origin ofore-bearing fluids and the significance of supercritical fluid with respect to the ore formation. The comparison of the sa-linity data of the fluid inclusions in the minerals of ore deposits with observations of NaCl-H_2O under HDAC in theconditions of high temperatures and pressures, combined with further thermodynamic analysis of ore-formation condi-tions would explain in depth the factors determining the ore formation.
基金Department of Envirenmental Medicine, Bethune University of Medical Sciences
文摘The directing mechanisms of liquid directing agents of zeolite Y and zeolite L were studied by means of light transmission, ultracentrifugation, NMR, XRD and “cross-exchange” experiments. It was discovered that not only microcfystals of zeolites, but also cage structures of zeolites play the directing role for crystallization of zeolites.
基金B.V.Konovalova., N.A. Koneva and E.V.Kozlov acknowledge the INTAS for the partial support of this research under INTAS97-319
文摘It was revealed that an average energy of special boundaries is proportional to APB energy in the alloys with the L12 superstructure. This fact proves the appearance of the GAPBs in the planes of location of special boundaries in coincidence sites of ordered alloys. It was determined that the more energy of special boundaries in ordered alloys, the more energy of complex stacking fault. There is a correlation between the distribution of special boundaries as a function its relative energy and ordering energy: the more ordering energy, the more degree of washed away of distribution. The correlation between average relative energy of special boundaries and ordering energy was detected: the more ordering energy, the more average energy of special boundaries. The reverse dependence between ordering energy and average number of special boundaries in grains limited by boundaries of general type was discovered.
基金Project supported by National Natural Science Foundation of P. R. China.
文摘The relations between catalytic activities and compositions of the systems Mg_xZn_(1-x)Fe_2O_4, Co_xZn_(1-x)Fe_2O_4, Co_xMg_(1-x)Fe_2O_4, Cd_xZn_(1-x)Fe_2O_4 and Mg_xZn_(1-x)Fe_2O_4·0.17Fe_2O_3 have been studied by flow differential reactor, XRD, and derivative IR techniques. It has been found that the appropriate normal-inverse spinel combination substantially increases the activity for the title raction. The structure of the active site and the role of the bivalent cation in the title catalyst have been inferred.
基金The National Natural Science Foundation of China(No.90612009,60403050),the National Basic Research Program of China (973Program)(No.2005CB321802).
文摘The related work to reveal the primary characteristics of roles underlying the existing approaches is analyzed. Then, it is demonstrated that the representation of roles is rather complex and error-prone in these approaches. Especially, the constraints among roles in the same context cannot be expressed by the current web ontology language (OWL). To solve these problems, a novel model of role is presented and a corresponding ontology language is provided for representing this model. The key idea underlying the solution is that a role should be regarded as an element of a certain context and a context as a structured thing which is comprised of some internal elements. The structure of context possesses inherent modularity and local semantics, whereby the representation of roles and context is significantly simplified.
文摘Teamwork is gaining increasing attention in a broader management research. In addition to previous research on the relationship between team structure and innovation performance, this study draws from an interesting experience-based theory advanced by Kelley and Littman (2005), which examines teams from design thinking perspective, and tests its contributions and effects on team's innovation performance. According to Kelley and Littman any team should include the following team roles: The anthropologist, the experimenter, the cross-pollinator, the hurdler, the collaborator, the director, the experience architect, the set designer, the storyteller, and the caregiver. We develop theoretical logics to explain how team structure that includes these key team roles and competences lead to a better innovation performance, and propose pertinent hypotheses. Experimental-empirical research and quantitative analysis were used in the study. The study conducted multiple experiments on three samples: a group of foreign entrepreneurship students, a group of technical students, and an additional group of randomly selected individuals, aged between 20 and 58, with diverse backgrounds. A special approach was implemented and a new instrument was developed to evaluate individuals in teams. While the results show that team that possess the major competences proposed by Kelley and Littman are more innovative, preliminary results also show that not all team roles are equally important. Moreover, team roles should be allocated equally among members for better collaboration, member satisfaction, and quick response, and within one team, one prevailing personality is optimal in terms of innovativeness. We discuss the implications of our findings for future research and managerial practice.