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Multi-layer phenomena in petawatt laser-driven acceleration of heavy ions
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作者 苏琬晴 曹喜光 +2 位作者 马春旺 王玉廷 张国强 《Plasma Science and Technology》 SCIE EI CAS CSCD 2024年第2期70-76,共7页
Laser-accelerated high-flux-intensity heavy-ion beams are important for new types of accelerators.A particle-in-cell program(Smilei) is employed to simulate the entire process of Station of Extreme Light(SEL) 100 PW l... Laser-accelerated high-flux-intensity heavy-ion beams are important for new types of accelerators.A particle-in-cell program(Smilei) is employed to simulate the entire process of Station of Extreme Light(SEL) 100 PW laser-accelerated heavy particles using different nanoscale short targets with a thickness of 100 nm Cr, Fe, Ag, Ta, Au, Pb, Th and U, as well as 200 nm thick Al and Ca. An obvious stratification is observed in the simulation. The layering phenomenon is a hybrid acceleration mechanism reflecting target normal sheath acceleration and radiation pressure acceleration, and this phenomenon is understood from the simulated energy spectrum,ionization and spatial electric field distribution. According to the stratification, it is suggested that high-quality heavy-ion beams could be expected for fusion reactions to synthesize superheavy nuclei. Two plasma clusters in the stratification are observed simultaneously, which suggest new techniques for plasma experiments as well as thinner metal targets in the precision machining process. 展开更多
关键词 petawatt laser-plasma interaction laser-driven heavy-ion accelerator for synthesizing superheavy nuclei PARTICLE-IN-CELL multi-layer phenomena target fabrication
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Researchers Propose Electrodriven Chemical Looping Ammonia Synthesis Mediated by Lithium Imide 被引量:1
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《Bulletin of the Chinese Academy of Sciences》 2023年第1期48-48,共1页
Ammo n i a(N H 3)i s a promising energy vector for the storage and utilization of renewable energies.Artificially synthesizing NH3 from its elements(Haber-Bosch process)requires harsh reaction conditions(400-500°... Ammo n i a(N H 3)i s a promising energy vector for the storage and utilization of renewable energies.Artificially synthesizing NH3 from its elements(Haber-Bosch process)requires harsh reaction conditions(400-500°C,10-30 MPa)because N2 is inert and nonpolar with a strong N≡N bond.The synthesis of NH3 under mild conditions is still challenging. 展开更多
关键词 AMMONIA synthesizing SYNTHESIS
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Challenges and opportunities in plasma-activated reactions of CO_(2) with light alkanes
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作者 Lea R.Winter Jingguang G.Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期424-427,共4页
Mitigation of the deleterious environmental impacts associated with CO_(2) emissions requires the development of more sustainable processes for synthesizing fuels and chemicals.Selective conversion of abundant yet dif... Mitigation of the deleterious environmental impacts associated with CO_(2) emissions requires the development of more sustainable processes for synthesizing fuels and chemicals.Selective conversion of abundant yet difficult to activate molecules such as CO_(2) and surplus light alkanes from shale gas to desirable products can potentially reduce reliance upon conventional fossil-based feedstocks.Therefore,co-conversion of CO_(2) with abundant light alkanes such as methane and ethane using atmospheric-pressure. 展开更多
关键词 ALKANES METHANE synthesizing
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Numerical simulation of the sensor output on Macao Science Satellite-1
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作者 XiZhi Li LiGang Li +4 位作者 Kai Tang YaBing Wang JianXia Cheng Qing Yan Zhong Huang 《Earth and Planetary Physics》 EI CSCD 2023年第1期136-143,共8页
Macao Science Satellite-1(MSS-1)will be launched at the early of 2023 into a near-circular orbit.The mission is designed to measure the Earth’s geomagnetic field with unpreceded accuracy through a new perspective.The... Macao Science Satellite-1(MSS-1)will be launched at the early of 2023 into a near-circular orbit.The mission is designed to measure the Earth’s geomagnetic field with unpreceded accuracy through a new perspective.The most important component installed on the satellite,to ensure high accuracy,is the deployable boom(Optical Bench).A Vector Field Magnetometer(VFM),an Advanced Stellar Compass(ASC),and a Couple Dark State Magnetometers(CDSM)are deployed on the deployable boom.In order to maximize the mission’s scientific output,a numerical simulator on MSS-1’s deployable boom was required to evaluate the adaptability of all devices on the deployable boom and assist the satellite’s data pre-processing.This paper first briefly describes the synthesis of the Earth’s total magnetic field and then describes the method simulating the output of scalar and vector magnetometers.Finally,the calibration method is applied to the synthetic magnetometer data to analyze the possible noise/error of the relevant instruments.Our results show that the simulator can imitate the disturbance of different noise sources or errors in the measuring system,and is especially useful for the satellite’s data processing group. 展开更多
关键词 synthesize Earth’s magnetic field simulate satellite orbit numerical simulation of satellite’s measurement system
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基于综合健康指数与RVM的系统级失效预测 被引量:6
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作者 陈雄姿 于劲松 +1 位作者 陆文高 李行善 《系统工程与电子技术》 EI CSCD 北大核心 2015年第10期2298-2305,共8页
针对具有多维状态变量、多种工作模式和故障模式的复杂工程系统,提出一种基于综合健康指数(synthesized health index,SHI)与相关向量机(relevance vector machine,RVM)的系统级失效预测方法。在离线训练阶段,先根据有限失效历史数据建... 针对具有多维状态变量、多种工作模式和故障模式的复杂工程系统,提出一种基于综合健康指数(synthesized health index,SHI)与相关向量机(relevance vector machine,RVM)的系统级失效预测方法。在离线训练阶段,先根据有限失效历史数据建立各工作模式下的健康评估模型,并据此获得各历史退化轨迹的SHI序列;然后再使用RVM对这些序列进行回归处理,进而辨识出与回归曲线最为匹配的函数模型。在线预测阶段,先运用健康评估模型计算当前设备的SHI序列并进行RVM回归,再拟合出离线阶段确定的函数模型并添加时变噪声;最后,外推预测出系统剩余使用寿命的概率密度分布。该方法成功应用到涡轮发动机的失效预测案例。 展开更多
关键词 失效预测 综合健康指数 相关向量机 不确定性管理 SYNTHESIZED health index (SHI) RELEVANCE vector machine (RVM)
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Synthes线缆系统置入内固定治疗全髋关节置换后股骨假体周围骨折 被引量:9
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作者 刘燚 严建军 +1 位作者 崔胜宇 崔志明 《中国组织工程研究》 CAS CSCD 2014年第13期1988-1993,共6页
背景:近年来股骨假体周围骨折已经成为是全髋关节置换后最常见的并发症之一,Vancourver B1型骨折因为股骨柄假体稳定同时无明显骨缺损,目前多主张积极行内固定治疗。目的:探讨Synthes线缆系统置入内固定治疗全髋关节置换后Vancouver B1... 背景:近年来股骨假体周围骨折已经成为是全髋关节置换后最常见的并发症之一,Vancourver B1型骨折因为股骨柄假体稳定同时无明显骨缺损,目前多主张积极行内固定治疗。目的:探讨Synthes线缆系统置入内固定治疗全髋关节置换后Vancouver B1型股骨假体周围骨折的临床效果。方法:2009年5月至2012年10月南通市第一人民医院骨科采用Synthes线缆系统置入内固定治疗18例全髋关节置换后Vancouver B1型股骨假体周围骨折患者,女10例,男8例;年龄45-80岁,平均(62.67±8.67)岁。治疗后第1,3,6个月复诊,按Harris评分标准评定髋关节功能,满分为100分,≥90分为优,80-89分为较好,70-79分为良,<70分为差。结果与结论:18例患者均获得随访,18例获得随访6-43个月,患者平均骨折愈合时间为(19.06±4.04)周。18例治疗前Harris评分为(22.3±3.6)分,治疗后第1,3,6个月髋关节Harris评分均较治疗前显著提高(P<0.01),髋关节功能恢复良好。提示Synthes线缆系统能最大程度恢复股骨正常解剖结构,操作简便,损伤小,稳定性强,安全性高,是治疗Vancouver B1型股骨假体周围骨折的理想方法。 展开更多
关键词 植入物 骨植入物 Synthes线缆系统 Vancouver分型 B1型股骨假体周围骨折 Harrris评分 髋关节置换
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Design of Down Scalers in Mixed-Signal GHz Frequency Synthesizer 被引量:1
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作者 徐勇 王志功 +3 位作者 仇应华 李智群 胡庆生 闵锐 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2005年第9期1711-1715,共5页
An optimized method is presented to design the down scalers in a GHz frequency synthesizer. The down scalers are comprised of dual modulus prescaler (DMP) and programmable & pulse swallow divider,different methods ... An optimized method is presented to design the down scalers in a GHz frequency synthesizer. The down scalers are comprised of dual modulus prescaler (DMP) and programmable & pulse swallow divider,different methods of high frequency analog circuit and digital logical synthesis are adopted respectively. Using a DMP high speed, lower jitter and lower power dissipation are obtained,and output frequency of 133.0MHz of the DMP working at divide-by-8 shows an RMS jitter less than 2ps. The flexibility and reusability of the progrs, mmable divider is high;its use could be extended to many complicated frequency synthesizers. By comparison,it is a better design on performance of high-frequency circuit and good design flexibility. 展开更多
关键词 PLL frequency synthesizer dual-modulus prescaler PROGRAMMABLE pulse swallow divider
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A Programmable 2.4GHz CMOS Multi-Modulus Frequency Divider 被引量:1
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作者 李志强 陈立强 +1 位作者 张健 张海英 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2008年第2期224-228,共5页
A programmable multi-modulus frequency divider is designed and implemented in a 0. 35μm CMOS process. The multi-modulus frequency divider is a single chip with two dividers in series,which are divided by 4 or 5 presc... A programmable multi-modulus frequency divider is designed and implemented in a 0. 35μm CMOS process. The multi-modulus frequency divider is a single chip with two dividers in series,which are divided by 4 or 5 prescaler and by 128-255 multi-modulus frequency divider. In the circuit design, power and speed trade-offs are analyzed for the prescaler, and power optimization techniques are used according to the input frequency of each divider cell for the 128-255 multimodulus frequency divider. The chip is designed with ESD protected I/O PAD. The dividers chain can work as high as 2.4GHz with a single ended input signal and beyond 2.6GHz with differential input signals. The dual-modulus prescaler consumes 11mA of current while the 128-255 multi-modulus frequency divider consumes 17mA of current with a 3.3V power supply. The core area of the die without PAD is 0.65mm × 0.3mm. This programmable multi-modulus frequency divider can be used for 2.4GHz ISM band PLL-based frequency synthesizers. To our knowledge, this is the first reported multi-modulus frequency divider with this structure in China. 展开更多
关键词 PRESCALER frequency divider PROGRAMMABLE multi-modulus frequency synthesizer
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A 2.4GHz Quadrature Output Frequency Synthesizer 被引量:1
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作者 衣晓峰 方晗 +1 位作者 杨雨佳 洪志良 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2005年第10期1910-1915,共6页
A design and implementation for a 2.4GHz quadrature output frequency synthesizer intended for bluetooth in 0. 35μm CMOS technology are presented. A differentially controlled quadrature voltage-controlled oscillator ... A design and implementation for a 2.4GHz quadrature output frequency synthesizer intended for bluetooth in 0. 35μm CMOS technology are presented. A differentially controlled quadrature voltage-controlled oscillator (QVCO) is employed to generate quadrature (I/Q) signals. A second-order loop filter, with a unit gain transconductance amplifier having the performance of a third-order loop filter,is exploited for low cost. The measured spot phase noise is -106.15dBc/Hz@ 1MHz. Close-in phase noise is less than -70dBc/Hz. The synthesizer consumes 13.5mA under a 3.3V voltage supply. The core size is 1.3mm×0. 8mm. 展开更多
关键词 frequency synthesizer phase locked loop quadrature VCO phase noise BLUETOOTH
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A CMOS Fully Integrated Frequency Synthesizer with Stability Compensation 被引量:1
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作者 何捷 唐长文 +1 位作者 闵昊 洪志良 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2005年第8期1524-1531,共8页
A complete closed-loop third order s-domain model is analyzed for a frequency synthesizer. Based on the model and root-locus technique, the procedure for parameters design is described, and the relationship between th... A complete closed-loop third order s-domain model is analyzed for a frequency synthesizer. Based on the model and root-locus technique, the procedure for parameters design is described, and the relationship between the process,voltage,and temperature variation of parameters and the loop stability is quantitatively analyzed. A variation margin is proposed for stability compensation. Furthermore,a simple adjustable current cell in the charge pump is proposed for additional stability compensation and a novel VCO with linear gain is adopted to limit the total variation. A fully integrated frequency synthesizer from 1 to 1.05GHz with 250kHz channel resolution is implemented to verify the methods. 展开更多
关键词 frequency synthesizer closed-loop third-order s-domain loop parameters PVT variation STABILITY variation margin
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A New High Performance FM Transmitter 被引量:1
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作者 曹政新 李学初 +3 位作者 李振 吴岳 宋树贵 熊绍珍 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2007年第5期655-660,共6页
A new FM transmitter is reported. It adopts a fractional-N PLL synthesizer to realize the FM modulator. An extra offset current has also been applied to eliminate the effects of the mismatch in CP. The chip is fabrica... A new FM transmitter is reported. It adopts a fractional-N PLL synthesizer to realize the FM modulator. An extra offset current has also been applied to eliminate the effects of the mismatch in CP. The chip is fabricated with CSMC 0.5μm DPTM CMOS technology. Experiments show that it achieves THD≤0.08% and SNR≤ 82dB,and the maximum outband emission energy ≤ 90dBc/Hz. Furthermore,it also uses an auto frequency adjusting method to avoid tuning up the external inductances. All these merits are very suitable for FM transmission. 展开更多
关键词 FM fraction N frequency synthesizer in-band phase noise
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A new method to construct reservoir capillary pressure curves using NMR log data and its application 被引量:5
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作者 肖亮 张伟 《Applied Geophysics》 SCIE CSCD 2008年第2期92-98,共7页
By analyzing hundreds of capillary pressure curves, the controlling factors of shape and type of capillary pressure curves are found and a novel method is presented to construct capillary pressure curves by using rese... By analyzing hundreds of capillary pressure curves, the controlling factors of shape and type of capillary pressure curves are found and a novel method is presented to construct capillary pressure curves by using reservoir permeability and a synthesized index. The accuracy of this new method is verified by mercury-injection experiments. Considering the limited quantity of capillary pressure data, a new method is developed to extract the Swanson parameter from the NMR T2 distribution and estimate reservoir permeability. Integrating with NMR total porosity, reservoir capillary pressure curves can be constructed to evaluate reservoir pore structure in the intervals with NMR log data. An in-situ example of evaluating reservoir pore structure using the capillary pressure curves by this new method is presented. The result shows that it accurately detects the change in reservoir pore structure as a function of depth. 展开更多
关键词 NMR log pore structure Swanson parameter synthesized index capillary pressure curves
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Synthesis of C_3S by Sol-Gel Technique and Its Features 被引量:3
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作者 何真 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2010年第1期138-141,共4页
Sol-gel method is a technique to synthesize inorganic materials based on wet-chemical reaction theory. The results have shown that reactants tetraethyl orthosilicate (TEOS) and Ca(NO3)2·4H2O can form sol and ... Sol-gel method is a technique to synthesize inorganic materials based on wet-chemical reaction theory. The results have shown that reactants tetraethyl orthosilicate (TEOS) and Ca(NO3)2·4H2O can form sol and gel in solution at 50-60 ℃, and the cosolvents are propyl alcohol (NPA) and H2O, the catalyst is HNO3. This sol-gel is burned for 12 hat 1 350-1 450 ℃ so that the organic matter, free water (moisture) in sol-gel system are removed and a solid reaction has taken place to form the resulting product. The product has been confirmed to be C3S by XRD, SEM and 29Si MAS NMR, as well as free lime content of the product which is less than 0.2% was determined by propanetriol-ethanol-method. The analysis determined by EDXA has indicated that the n(Ca)/n(Si) ratio in corresponding to micro-region is close to theoretical value of 3∶1. This resulting product is C3S with Si sites of Q0 polymerization, and has higher purity and hydraulic activities at earlier age of hydration. 展开更多
关键词 sol-gel technique synthesization PURITY tricalcium silicate MORPHOLOGY 29Si MAS NMR
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Low Jitter,Dual-Modulus Prescalers for RF Receivers
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作者 唐路 王志功 +4 位作者 何小虎 李智群 徐勇 李伟 郭峰 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2007年第12期1930-1936,共7页
Dual-modulus prescalers (DMP) for RF receivers are studied. An improved D-latch is proposed to increase the speed and the driving capability of the DMP. A novel D-latch architecture integrated with ‘OR' logic is p... Dual-modulus prescalers (DMP) for RF receivers are studied. An improved D-latch is proposed to increase the speed and the driving capability of the DMP. A novel D-latch architecture integrated with ‘OR' logic is proposed to decrease the complexity of the circuit. A divided-by-16/17 DMP for application in a digital video broadcasting-terrestrial receiver is realized with a TSMC 0.18μm mixed-signal CMOS process. The programmable & pulse swallow divider in this receiver is designed with a 0.18μm CMOS standard cell library and realized in the same process. The measured results show that the DMP has an output jitter of less than 0.03% and works well with the programmable & pulse swallow divider. 展开更多
关键词 PLL frequency synthesizer DMP programmable pulse swallow divider
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Key technologies of frequency-hopping frequency synthesizer for Bluetooth RF front-end
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作者 徐勇 王志功 +3 位作者 李智群 章丽 闵锐 徐光辉 《Journal of Southeast University(English Edition)》 EI CAS 2005年第3期260-262,共3页
A scheme of a frequency-hopping frequency-synthesizer applied to a Bluetooth ratio frequency (RF) front-end is presented,and design of a voltage controlled oscillator (VCO) and dual-modulus prescaler are focused o... A scheme of a frequency-hopping frequency-synthesizer applied to a Bluetooth ratio frequency (RF) front-end is presented,and design of a voltage controlled oscillator (VCO) and dual-modulus prescaler are focused on.It is fabricated in a 0.18 μm mixed-signal CMOS (complementary metal-oxide-semiconductor transistor) process.The power dissipation of VCO is low and a stable performance is gained.The measured phase noise of VCO at 2.4 GHz is less than -114.32 dBc/Hz.The structure of the DMP is optimized and a novel D-latch integrated with "OR" logic gate is used.The measured results show that the chip can work well under a 1.8 V power supply.The power dissipation of the core part in a dual modulus prescaler is only 5.76 mW.An RMS jitter of 2 ps is measured on the output signal at 118.3 MHz.It is less than 0.02% of the clock period. 展开更多
关键词 BLUETOOTH frequency hopping frequency synthesizer voltage controlled oscillator (VCO) dualmodulus prescaler programmable divider
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Frequency synthesizer for DRM/DAB/AM/FM RF front-end
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作者 雷雪梅 王志功 +1 位作者 王科平 沈连丰 《Journal of Southeast University(English Edition)》 EI CAS 2013年第3期242-246,共5页
This paper describes a wideband low phase noise frequency synthesizer.It operates in the multi-band including digital radio mondiale DRM digital audio broadcasting DAB amplitude modulation AM and frequency modulation ... This paper describes a wideband low phase noise frequency synthesizer.It operates in the multi-band including digital radio mondiale DRM digital audio broadcasting DAB amplitude modulation AM and frequency modulation FM .In order to cover the signals of the overall frequencies a novel frequency planning and a new structure are proposed. A wide-band low-phase-noise low-power voltage-control oscillator VCO and a high speed wide band high frequency division ratio pulse swallow frequency divider with a low power consumption are presented.The monolithic DRM/DAB/AM/FM frequency synthesizer chip is also fabricated in a SMIC's 0.18-μm CMOS process.The die area is 1 425 μm ×795 μm including the test buffer and pads. The measured results show that the VCO operating frequency range is from 2.22 to 3.57 GHz the measured phase noise of the VCO is 120.22 dBc/Hz at 1 MHz offset the pulse swallow frequency divider operation frequency is from 0.9 to 3.4 GHz.The phase noise in the phase-locked loop PLL is-59.52 dBc/Hz at 10 kHz offset and fits for the demand of the DRM/DAB/AM/FM RF front-end. The proposed frequency synthesizer consumes 47 mW including test buffer under a 1.8 V supply. 展开更多
关键词 frequency synthesizer wideband voltage-controloscillator pulse swallow frequency divider low phase noise
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A Novel 4/5 Prescaler with Automatic Power Down
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作者 曾隆月 朱思奇 阎跃鹏 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2008年第8期1449-1452,共4页
An "automatic power down" method is introduced to design a 4/5 prescaler,with the characteristic of making one of its D-flip-flops power down when it operates in divide-by-4 mode. Implemented with the TSMC 0.25vm mi... An "automatic power down" method is introduced to design a 4/5 prescaler,with the characteristic of making one of its D-flip-flops power down when it operates in divide-by-4 mode. Implemented with the TSMC 0.25vm mixed-sig- nal CMOS process,the 4/5 MOS current mode logic prescaler is designed with this automatic power down technique. The simulation results show that the new 4/5 prescaler is immune to the "wake-up" issue and thereby retains the same maxi- mum operating frequency as the conventional prescaler. An integer-N divider with this proposed prescaler and with the di- vision ratio 66/67 is manufactured,and it is estimated to save more than 20% of the power compared with the conventional 4/5 prescaler. 展开更多
关键词 MCML prescaler automatic power down frequency synthesizer
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0.18μm CMOS programmable frequency divider design for DVB-T
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作者 胡庆生 仲建锋 何小虎 《Journal of Southeast University(English Edition)》 EI CAS 2008年第2期159-162,共4页
The implementation of a programmable frequency divider, which is one of the components of the phase-locked loop (PLL) frequency synthesizer for digital video broadcastingterrestrial (DVB-T) and other modem communi... The implementation of a programmable frequency divider, which is one of the components of the phase-locked loop (PLL) frequency synthesizer for digital video broadcastingterrestrial (DVB-T) and other modem communication systems, is presented. By cooperating with a dual-modulus prescaler, this divider can realize an integer frequency division from 926 to 1 387. Besides the traditional standard cell design flow, such as logic synthesis, placement and routing, the interactions between front-end and back-end are also considered to optimize the design flow under deep submicron technology. By back-annotating the back-end information to front-end design, a custom wire-load model is created which is more practical compared with the default model. This divider has been fabricated in TSMC 0. 18μm CMOS technology using Artisan standard cell library. The chip area is 675 μm × 475 μm and the power consumption is about 2 mW under a 1.8 V power supply. Measurement results show that it works correctly and can realize a frequency division with high precision. 展开更多
关键词 programmable frequency divider frequency synthesizer standard cell DVB-T
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A wideband low-phase-noise LC VCO for DRM/DAB frequency synthesizer
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作者 雷雪梅 王志功 王科平 《Journal of Southeast University(English Edition)》 EI CAS 2010年第4期528-531,共4页
The wideband CMOS voltage-controlled oscillator(VCO)with low phase noise and low power consumption is presented for a DRM/DAB(digital radio mondiale and digital audio broadcasting)frequency synthesizer.In order to... The wideband CMOS voltage-controlled oscillator(VCO)with low phase noise and low power consumption is presented for a DRM/DAB(digital radio mondiale and digital audio broadcasting)frequency synthesizer.In order to obtain a wide band and a large tuning range,a parallel switched capacitor bank is added in the LC tank.The proposed VCO is implemented in SMIC 0.18-μm RF CMOS technology and the chip area is 750 μm×560 μm,including the test buffer circuit and the pads.Measured results show that the tuning range is 44.6%;i.e.,the frequency turning range is from 2.27 to 3.57 GHz.The measured phase noise is-122.22 dBc/Hz at a 1 MHz offset from the carrier.The maximum power consumption of the core part is 6.16 mW at a 1.8 V power supply. 展开更多
关键词 CMOS voltage-controlled oscillator switched capacitor bank MOS varactors WIDEBAND low phase noise DRM/DAB frequency synthesizer
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某些钴(Ⅲ)氨基酸络合物的活性炭催化合成
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作者 章慧 俞鼎琼 +1 位作者 徐志固 陈玉 《厦门大学学报(自然科学版)》 CAS CSCD 北大核心 1991年第6期626-628,共3页
在研究光学活性络合物的手性识别及拆分机理的过程中,需要合成一系列有特征构型的光学活性钻(Ⅲ)络合物,其配体皆为含N、O配位原子的多齿配体。但是按文献方法合成具有光学活性的u-fac-[Co(ida)<sub>2</sub>](ida<s... 在研究光学活性络合物的手性识别及拆分机理的过程中,需要合成一系列有特征构型的光学活性钻(Ⅲ)络合物,其配体皆为含N、O配位原子的多齿配体。但是按文献方法合成具有光学活性的u-fac-[Co(ida)<sub>2</sub>](ida<sup>2</sup>;亚氨基二乙酸根)、fac-[Co(β-ala)<sub>3</sub>](β-ala:β-丙氨酸根)时,均存在着产率低或产物纯度低,反应时间长等问题,为其后续拆分带来不少困难。为此。 展开更多
关键词 Charcoal-catalyzed SYNTHESES Iminodiacetic ACID Β-ALANINE
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