As the characteristic pollutant, terephthalic acid(TA)was in charge of 40%—78% of the total COD of terylene artificial silk printing and dyeing wastewater(TPW-water). The studies on biodegradability of TA were conduc...As the characteristic pollutant, terephthalic acid(TA)was in charge of 40%—78% of the total COD of terylene artificial silk printing and dyeing wastewater(TPW-water). The studies on biodegradability of TA were conducted in a serial of activated sludge reactors with TPW-water. TA appeared to be readily biodegradable with removal efficiency over 96.5% under aerobic conditions, hardly biodegradable with removal efficiency below 10% under anoxic conditions and slowly biodegradable with a turnover between 31.4% and 56.0% under anaerobic conditions. TA also accounted for the majority of BOD in TPW-water. The process combined by anoxic, anaerobic and aerobic activated sludge reactor was suitable for TA degradation and TPW-water treatment. Further, the aerobic process was essentially much more effective than the anaerobic or anoxic one to degrade TA in TPW-water.展开更多
By using a self-made carbon/polytetrafluoroethylene (C/PTFE) O2-fed as cathode and Ti/IrO2/RuO2 as anode, the effects of electrochemical oxidation of phenol and the coal-gas wastewater containing phenol were studied...By using a self-made carbon/polytetrafluoroethylene (C/PTFE) O2-fed as cathode and Ti/IrO2/RuO2 as anode, the effects of electrochemical oxidation of phenol and the coal-gas wastewater containing phenol were studied. The terylene diaphragm which kept pH〉12 in cathodic compartment and pH〈1 in the anodic compartment was selected in the experiment in comparison with the other types of diaphragm. Furthermore, hydroxyl radical (HO·) was determined in the cathodic compartment of the diaphragm cell by electron spin resonance spectrum(ESR) and the fluorescence spectra. Compared with pH, the accumulated HzO2 and the COD removal of the no-diaphragm cell, the mechanism of electrochemical oxidation in the terylene diaphragm cell was supposed. The degradation of phenol was supposed to be cooperative oxidation by direct or indirect electrochemical oxidation at the anode and H2O2, HO· produced by oxygen reduction at the cathode. The mineralization of phenol in the diaphragm cell was better than that in the no-diaphragm cell. When the coal-gas wastewater was treated by the electrolysis system with terylene diaphragm, the average removal efficiency of the volatile phenol and COD were 100% and 79.6%, respectively.展开更多
文摘As the characteristic pollutant, terephthalic acid(TA)was in charge of 40%—78% of the total COD of terylene artificial silk printing and dyeing wastewater(TPW-water). The studies on biodegradability of TA were conducted in a serial of activated sludge reactors with TPW-water. TA appeared to be readily biodegradable with removal efficiency over 96.5% under aerobic conditions, hardly biodegradable with removal efficiency below 10% under anoxic conditions and slowly biodegradable with a turnover between 31.4% and 56.0% under anaerobic conditions. TA also accounted for the majority of BOD in TPW-water. The process combined by anoxic, anaerobic and aerobic activated sludge reactor was suitable for TA degradation and TPW-water treatment. Further, the aerobic process was essentially much more effective than the anaerobic or anoxic one to degrade TA in TPW-water.
文摘By using a self-made carbon/polytetrafluoroethylene (C/PTFE) O2-fed as cathode and Ti/IrO2/RuO2 as anode, the effects of electrochemical oxidation of phenol and the coal-gas wastewater containing phenol were studied. The terylene diaphragm which kept pH〉12 in cathodic compartment and pH〈1 in the anodic compartment was selected in the experiment in comparison with the other types of diaphragm. Furthermore, hydroxyl radical (HO·) was determined in the cathodic compartment of the diaphragm cell by electron spin resonance spectrum(ESR) and the fluorescence spectra. Compared with pH, the accumulated HzO2 and the COD removal of the no-diaphragm cell, the mechanism of electrochemical oxidation in the terylene diaphragm cell was supposed. The degradation of phenol was supposed to be cooperative oxidation by direct or indirect electrochemical oxidation at the anode and H2O2, HO· produced by oxygen reduction at the cathode. The mineralization of phenol in the diaphragm cell was better than that in the no-diaphragm cell. When the coal-gas wastewater was treated by the electrolysis system with terylene diaphragm, the average removal efficiency of the volatile phenol and COD were 100% and 79.6%, respectively.
文摘Viscose and terylene staple fi ber market is very hot as prices rise this year.The main reason for the positive market activity is that cotton prices