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Sulfur/nitrogen/oxygen tri-doped carbon nanospheres as an anode for potassium ion storage 被引量:3
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作者 Xiaoyan Chen Wang Zhou +2 位作者 Jilei Liu Yingpeng Wu Zhigang Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第2期338-347,I0009,共11页
Carbonaceous materials are considered as ideal anode for potassium ion batteries(PIBs)due to their abundant resources and stable physical and chemical properties.However,improvements of reversible capacity and cycle p... Carbonaceous materials are considered as ideal anode for potassium ion batteries(PIBs)due to their abundant resources and stable physical and chemical properties.However,improvements of reversible capacity and cycle performance are still needed,aiming to the practical application.Herein,S/N/O tridoped carbon(SNOC)nanospheres are prepared by in-situ vulcanized polybenzoxazine.The S/N/O tridoped carbon matrix provides abundant active sites for potassium ion adsorption and effectively improves potassium storage capacity.Moreover,the SNOC nanospheres possess large carbon interlayer spacing and high specific surface area,which broaden the diffusion pathway of potassium ions and accelerate the electron transfer speed,resulting in excellent rate performance.As an anode for PIBs,SNOC shows attractive rate performance(438.5 mA h g^(-1) at 50 mA g^(-1) and 174.5 mA h g^(-1) at2000 mA g^(-1)),ultra-high reversible capacity(397.4 mA h g^(-1) at 100 mA g^(-1) after 700 cycles)and ultra-long cycling life(218.9 mA h g^(-1) at 2000 mA g^(-1) after 7300 cycles,123.1 mA h g^(-1) at3000 mA g^(-1) after 16500 cycles and full cell runs for 4000 cycles).Density functional theory calculation confirms that S/N/O tri-doping enhances the adsorption and diffusion of potassium ions,and in-situ Fourier-transform infrared explores explored the potassium storage mechanism of SNOC. 展开更多
关键词 Potassium ion batteries S/N/O tri-doped Carbon nanospheres ANODE
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A comparative study of physicochemical and photocatalytic properties of visible light responsive Fe,Gd and P single and tri-doped TiO_2 nanomaterials 被引量:9
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作者 seyed mohsen adyani mohammad ghorbani 《Journal of Rare Earths》 SCIE EI CAS CSCD 2018年第1期72-85,共14页
High performance Fe-Gd-P tri-doped TiO2 nanoparticles (1 at% for each dopant) were successfully synthesized by a modified sol-gel method. Various analytical and spectroscopic techniques were carried out to determine... High performance Fe-Gd-P tri-doped TiO2 nanoparticles (1 at% for each dopant) were successfully synthesized by a modified sol-gel method. Various analytical and spectroscopic techniques were carried out to determine the physicochemical properties of the prepared samples, including XRD, EDX, FESEM, BET, FFIR, XPS, PL, EIS and UV-Vis diffuse reflectance spectroscopy. The photocatalytic activities of prepared samples were evaluated by photo degradation of methyl orange (MO) and 4-chlorophenol (4- CP) as model pollutants under visible light irradiation. Effects of each dopant on different properties of TiO2 nanoparticles were investigated. Results show that Gd and P doping enhances Ti02 surface textural properties by forming Ti O Gd and Ti-O-P bonds. It is found that Gd plays a superior role in increasing oxygen vacancies and organic species on TiO2 surface. Gd doping also facilitates transferring of the photo-induced charge carriers to the surface adsorbed species. The enhanced electronic band structure and visible light response, as well as high electron lifetime of Fe-Gd-P tri-doped sample is mainly attributed to Fe and Gd doping. The tri-doped TiO2 with rate constant ofkapp - 1.28 ~ 10-2 min-1 for MO and kapp ~ 0.94 ~ 10-2 min-1 for 4-CP, shows the highest photodegradation rate among all samples including undoped and single doped samples. The improved photocatalytic performance of Fe-Gd-P tri- doped Ti02 is due to the synergistic effect of enhanced surface chemistry and textural properties, increased number of surface adsorbed hydroxyl groups and organic species, improved visible light ab- sorption, increased lifetime of the photo-induced electron/hole pairs and boosted interfacial charge transfer. 展开更多
关键词 Fe-Gd-P tri-doped TiO2Sol-gel synthesisPhotodegradationVisible light responseSynergistic effectRare earths
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Enhancement of up-conversion luminescence properties in Yb^(3+)/Tm^(3+)/Er^(3+) tri-doped transparent oxyfluoride tellurite glass ceramics
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作者 于春雷 何冬兵 +2 位作者 汪国年 张军杰 胡丽丽 《Chinese Optics Letters》 SCIE EI CAS CSCD 2010年第2期197-198,共2页
Optically transparent Er3+/Tm3+/Yb3+ tri-doped oxyfluoride tellurite based nano-crystallized glass ceramics with the batching composition of 73TeO2-15ZnO-7ZnF2-3YF3-1.5YbF3-0.3ErF3-0.2TmF3 (mol%) is prepared by a... Optically transparent Er3+/Tm3+/Yb3+ tri-doped oxyfluoride tellurite based nano-crystallized glass ceramics with the batching composition of 73TeO2-15ZnO-7ZnF2-3YF3-1.5YbF3-0.3ErF3-0.2TmF3 (mol%) is prepared by a conventional melting quenching and the subsequent heat treatment processes. The sizes of grown nano-crystals in glass matrix appear to be smaller than 100 nm from the scanning electron mi- croscope measurement. Visible up-conversion luminescence of the as melted glass and glass ceramics is investigated. The three-color up-conversion luminescence intensities by 980-nm pumping are increased significantly due to the heat treatment, and the blue intensity increases with a higher magnitude than other wavelengths after heat treatment. 展开更多
关键词 Tm Enhancement of up-conversion luminescence properties in Yb Er tri-doped transparent oxyfluoride tellurite glass ceramics
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Sulfur-encapsulated in heteroatom-doped hierarchical porous carbon derived from goat hair for high performance lithium–sulfur batteries 被引量:12
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作者 Juan Ren Yibei Zhou +3 位作者 Huali Wu Fengyu Xie Chenggang Xu Dunmin Lin 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第3期121-131,共11页
Biomass-derived carbon materials have aroused widespread concern as host material of sulfur to enhance electrochemical performances for lithium–sulfur batteries. Herein, goat hair, as a low-cost and eco-friendly prec... Biomass-derived carbon materials have aroused widespread concern as host material of sulfur to enhance electrochemical performances for lithium–sulfur batteries. Herein, goat hair, as a low-cost and eco-friendly precursor, is employed to fabricate cauliflower-like in-situ nitrogen, oxygen and phosphorus tri-doped porous biomass carbon(NOPC) by a facile activation with H_3PO_4 and carbonization process.The morphology and microstructure of NOPC can be readily tuned by altering pyrolysis temperature. The as-prepared NOPC matrix material carbonized at 600 °C possesses 3D hierarchical porous structure, high specific surface area(535.352 m^2 g^(-1)), and appropriate pore size and pore size distribution. Encapsulating sulfur into the NOPC depends on a stem-melting technology as cathode materials of Li–S batteries. Due to the synergistic effect of special physical structure and inherent tri-doping of N, O and P, electrons and ions transfer and utilization of active sulfur in the materials are improved, and the shuttle behaviors of soluble lithium polysulfides are also mitigated. Consequently, the S/NOPC-600 composite exhibits excellent electrochemical performance, giving a high initial discharge capacity of 1185 mA h g^(-1) at 0.05 C and maintaining a relatively considerable capacity of 489 m A h g^(-1) at 0.2 C after 300 cycles. Our work shows that a promising candidate for cathode material of Li–S batteries can be synthesized using low-cost and renewable biomass materials by a facile process. 展开更多
关键词 Biomass-derived carbon materials GOAT HAIR Nitrogen Oxygen and phosphorus tri-doping LITHIUM SULFUR BATTERIES
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Synergetic effects of lanthanum,nitrogen and phosphorus tri-doping on visiblelight photoactivity of TiO_2 fabricated by microwave-hydrothermal process 被引量:5
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作者 姜洪泉 刘彦铎 +1 位作者 李井申 王海燕 《Journal of Rare Earths》 SCIE EI CAS CSCD 2016年第6期604-613,共10页
Effects of La, N, and P doping on the structural, electronic and optical properties of TiO_2 synthesized from TiCl_4 hydrolysis via a microwave-hydrothermal process were investigated by X-ray diffraction, transmission... Effects of La, N, and P doping on the structural, electronic and optical properties of TiO_2 synthesized from TiCl_4 hydrolysis via a microwave-hydrothermal process were investigated by X-ray diffraction, transmission electron microscopy, N_2 adsorption-desorption isotherm, X-ray photoelectron spectroscopy, electron paramagnetic resonance, UV-vis absorbance spectroscopy, photoelectrochemical measurements, and photoluminescence spectroscopy. The results showed that the presence of La in the tri-doped TiO_2 played a predominant role in inhibiting the recombination of the photogenerated electrons and holes. The existence of the substitutional N, interstitial N, and oxygen vacancies in TiO_2 lattices led to the band gap narrowing. It was P-doping rather than La or N doping that played a key role in inhibiting both anatase-to-rutile phase transformation and crystal growth, in stabilizing the mesoporous textural properties, and in increasing the content of surface bridging hydroxyl. Moreover, the tri-doping significantly enhanced the surface Ti^(4+)-O^(2-)-Ti^(4+)-O^(-·) species. All above-mentioned factors cooperated to result in the enhanced photoactivity of the tri-doped TiO_2. As a result, it exhibited the highest photoactivity towards the degradation of 4-chlorophenol(4-CP) under visible-light irradiation among all samples, which was much superior to commercial P25 TiO_2. 展开更多
关键词 TiO_2 tri-doping microwave-hydrothermal visible-light photoactivity synergetic effect rare earths
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