Pt-based magnetic nano catalysts are one of the most suitable cand idates for electrocatalytic materials due to their high electrochemistry activity and retrievability.Unfortunately,the inferior durability prevents th...Pt-based magnetic nano catalysts are one of the most suitable cand idates for electrocatalytic materials due to their high electrochemistry activity and retrievability.Unfortunately,the inferior durability prevents them from being scaled-up,limiting their commercial applications.Herein,an antiferromagnetic element Mn was introduced into PtCo nanostructured alloy to synthesize uniform Mn-PtCo truncated octahedral nanoparticles(TONPs)by one-pot method.Our results show that Mn can tune the blocking temperature of Mn-PtCo TONPs due to its an tiferromag netism.At low temperatures,Mn-PtCo TONPs are ferromag netic,and the coercivity in creases gradually with in creasi ng Mn contents.At room temperature,the Mn-PtCo TONPs display superparamag netic behavior,which is greatly helpful for in dustrial recycling.Mn doping can not only modify the electronic structure of PtCo TONPs but also enhanee electrocatalytic performance for methanol oxidation reaction.The maximum specific activity of Mn-PtCo-3 reaches 8.1 A`m^-2,3.6 times of commercial Pt/C(2.2 A·m^-2)and 1.4 times of PtCo TONPs(5.6 A`m^-2),respectively.The mass activity decreases by only 30%after 2,000 cycles,while it is 45%and 99%(nearly inactive)for PtCo TONPs and commercial Pt/C catalysts,respectively.展开更多
基于会话初始化协议(SIP)的VoIP系统在Internet上已经取得了广泛应用,但在目前的实际网络环境中,由于大量NAT设备的存在,使对等网络(P2P,Peer to Peer)之间的呼叫和数据通信难以实现。分析了四种NAT的类型特点,介绍了现有的NAT穿越方法...基于会话初始化协议(SIP)的VoIP系统在Internet上已经取得了广泛应用,但在目前的实际网络环境中,由于大量NAT设备的存在,使对等网络(P2P,Peer to Peer)之间的呼叫和数据通信难以实现。分析了四种NAT的类型特点,介绍了现有的NAT穿越方法,提出了一种基于STUN与TURN方式相结合的实现各种NAT穿越的VoIP系统设计方案。该方案对SIP信令采用可靠的TCP传输方式,对流媒体数据采取最大交付的UDP传输方式。经过校园网内部之间的网络环境测试,该方案达到了很好的接通率。展开更多
基金The work was supported by the National Natural Science Foundation(Nos.51625101,51431009,5180118&and 51701202)the State Key Development Program for Basic Research of China(No.2015CB921401)+3 种基金the Fundamental Research Funds for the Central University Universities of China(No.FRF-TP-16-001C2)the China Postdoctoral Science Foundation(No.2018M632792)Startup Research Fund of Zhengzhou University(No.32210815)Bejing Natural Science Foundation(No.Z180014).
文摘Pt-based magnetic nano catalysts are one of the most suitable cand idates for electrocatalytic materials due to their high electrochemistry activity and retrievability.Unfortunately,the inferior durability prevents them from being scaled-up,limiting their commercial applications.Herein,an antiferromagnetic element Mn was introduced into PtCo nanostructured alloy to synthesize uniform Mn-PtCo truncated octahedral nanoparticles(TONPs)by one-pot method.Our results show that Mn can tune the blocking temperature of Mn-PtCo TONPs due to its an tiferromag netism.At low temperatures,Mn-PtCo TONPs are ferromag netic,and the coercivity in creases gradually with in creasi ng Mn contents.At room temperature,the Mn-PtCo TONPs display superparamag netic behavior,which is greatly helpful for in dustrial recycling.Mn doping can not only modify the electronic structure of PtCo TONPs but also enhanee electrocatalytic performance for methanol oxidation reaction.The maximum specific activity of Mn-PtCo-3 reaches 8.1 A`m^-2,3.6 times of commercial Pt/C(2.2 A·m^-2)and 1.4 times of PtCo TONPs(5.6 A`m^-2),respectively.The mass activity decreases by only 30%after 2,000 cycles,while it is 45%and 99%(nearly inactive)for PtCo TONPs and commercial Pt/C catalysts,respectively.
文摘基于会话初始化协议(SIP)的VoIP系统在Internet上已经取得了广泛应用,但在目前的实际网络环境中,由于大量NAT设备的存在,使对等网络(P2P,Peer to Peer)之间的呼叫和数据通信难以实现。分析了四种NAT的类型特点,介绍了现有的NAT穿越方法,提出了一种基于STUN与TURN方式相结合的实现各种NAT穿越的VoIP系统设计方案。该方案对SIP信令采用可靠的TCP传输方式,对流媒体数据采取最大交付的UDP传输方式。经过校园网内部之间的网络环境测试,该方案达到了很好的接通率。
